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1 Sustainable Transport Rational Use of Energy Francesco Contino Follow us source: io9.com

Sustainable transport

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What is sustainable transport?( )

Transport is mainly by road

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Final energy consumption (Mtoe, EU 2010)

All sectors 1153

Transport 365Road 300Air 50

Rail 7Water 8

32%

82%

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What is sustainable transport?Transport is sustainable if…

Fuel stock is replenished or no change on the time scale of humanity

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Fuel stock replenished biomass

No change of stock at our time scale

source: wikipedia.com

Fuel stock is replenished or no change on the time scale of humanity

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Fuel stock is replenished or no change on the time scale of humanity

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Unconventional oil extends the reserves Oil sands Oil shale Gas conversion (Fischer Tropsch)Canadian Tar Sands:

World’s  largest  earthmoving  operation

Truck is bigger than a house, costs $5M. ~5 tons of sand and peat moved and ~1 barrel of wastewater produced per barrel of oil. At 2 mbd, that is a lot of polluted water!

Aerial view of one of the Tar Sand upgrading facilities

CO2 is taking care of = 0 net emissions

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Either 0 emissions local and global

Or CO2 is recycled how?

CO2 is taking care of = 0 net emissions

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We have a challenging target : -60% by 2050 compared to 1990

source:europa.eu

There is no local effect

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Welcome in Brussels 1900

watch out where you are walking

There is no local effect

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Welcome in Brussels 2015

watch out where you are breathing

There is no local effect

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Materials can be recycled

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Like CO2, materials should be recovered

Directive 2000/53/EC 95% target of car mass recycling but still some issues with batteries

Research project in Burn group: Phoebus (Dr. Coussement, Prof. Parente) recycling car plastics to make fuel

Transport, as we use it, needs to have sustainability, autonomy, and scalability

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autonomy: the giga joule threshold

scalability: the giga cars threshold

sustainability: the giga years threshold?

To maintain autonomy, it should be compact

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Need to carry around 1 GJ for current functionality of cars

Need a fuel with >>10kJ/g

Weight of this autonomy (fuel) should be lower than 100 kg

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43 of 42

Elements with enthalpy of oxidation > 10 kJ g-1

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44 of 42

Elements with non-solid oxides

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45 of 42

Elements with enthalpy of oxidation > 10 kJ g-1 and non- solid (or non-toxic) oxides.

Hydrogen and Carbon

source: wikipedia MJ/kg

MJ/l

Energy density of the fuel is important

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source: Jiang et al., 2010

Energy density of the system even more

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Energy density of the system even more

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source: xkcd.com

Fuel tank AA batteries

The solutions are scalable

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source: Elysium, 2013

Work for the majority Not only for privileged

Easy access to materials

Alternative to China: Afghanistan $1 trillion 1 000 000 000 000 $

600 US 44 China

The solutions are scalable

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1960 2012 2035

125

1000

2000

Millions of cars

source: Stacy et al., 2014

??

Any solution should meet the demand

# per 1000 persons

Scalability also means using the “legacy infrastructure”

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source: thesun.co.uk

source: suncountryhighway.ca

What about other forms of transport

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Professional transport: more constraints on the user is possible

Air: big limit on weight

Marine: very flexible and no constraint on weight and volume but well on emissions

source: solarimpulse.com

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How much power do we need to sustain our daily life?

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How much power do we need to sustain our daily life?

17 terawatt17 000 000 000 000 W

540 1018 J / year (exajoule)31.5 106 s / year

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What are the possible solutions?

The best energy is the one not consumed

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changing habits signs of accomplishments logistics

Working locally: improving the top/mean efficiency

new combustion technologieshybridation and electrification

downsizing, downspeeding traditional engines

lightweight vehicles

Working globally: reducing overall consumption

What is the potential from renewable energy

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Current consumption: 17 TW

Biomass: 7 TW

Hydraulic: 7 TW

Wave: 14 TW

Geothermal: 44 TW

Wind: 72 TW

Solar: 85000 TW far, far away…

source: Verhelst, UBIA

What is the potential from renewable energy

35Map data ©2015 Google 500 m

Total distance: 5 km (3.1 mi)

TrafBc, Bicycling, Terrain, Directions

What is the potential from renewable energy

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Biomass

Hydraulic

Wave

Geothermal

Wind

Solar

Primary energy sources

fuel

Fuels from biomass are already used

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In 2010 in the world , 100 109 liters2.7% of the fuel used for road transport

Ethanol : ~80%90% of production in the US and Brazil

EU Renewable energy directive (2009/28) target for 2020 : >10% of biofuels in transport

EU Fuel quality directive (2009/30) includes criteria for sustainable biofuel production

Biodiesel : ~20%2/3 of production in Europe

Jean Ziegler, Special Rapporteur on the Right to Food from 2000 to 2008

27 octobre 2007: « It's a crime against humanity to convert agricultural productive soil into soil ... which will be burned into biofuel... What has to be stopped is ... the growing catastrophe of the massacre (by) hunger in the world. »

But they don’t have a good reputation

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But they don’t have a good reputation

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Biofuels are not sustainable by default

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85

5148

17

sans LUC avec LUC ref. fossile

111

gCO2eq/MJ

source : JRC, 2010

Direct and indirect LUCGreat uncertainty

Amortization scheme?

mix of biofuelsgCO2eq/MJ

111

5148

17

85

without LUC with LUC fossil ref.

20 years selected by EU

Next generations, new hope?

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Biofuels from non food crops

Big potential but the limits remain

lignocellulose, algae, jatropha, hemp, …

we still need food for a growing populationphotosynthesis efficiency (0.5-2%)accessible land/waterenvironmental risk?

What is the potential from renewable energy

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Biomass

Hydraulic

Wave

Geothermal

Wind

Solar

Primary energy sources

fuel or electricity

electricity

Electricity from the sun, not as you might think

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Production is energy intensive

Some material needed are rare

Recycling?

Low level/well known tech.

No rare material

High efficiency

Electric cars THE solution for everybody?

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Electric cars are very efficient, clean, and flexible

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Well-to-wheel efficiency: 2x gasoline

No local emissions (from combustion) tires? brakes?

Very flexible: electricity can be produced by many sources and existing infrastructure can be used

Electric cars are not the best option (yet)

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Rare materials, what about recycling

ScalabilityExisting infrastructure cannot sustain electric vehicles at full scale

Sustainability

Life time?

AutonomyEnergy density of batteries are low

source: adapted from Verhelst, UBIA

The same autonomy (with packaging)

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gasoline 60 kg

1150 kg

800 kg

What is the potential from renewable energy

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Biomass

Hydraulic

Wave

Geothermal

Wind

Solar

Primary energy sources

fuel or electricity

electricity fuel

Electricity can be converted in many fuels

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electricity H2

waterused as fuel

Fuel cells are very efficient

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High efficiency up to 70%

Use H2 and produce H2O

Fuel cells are expensive, and not scalable

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Production cost is very high

Life-time?

Need Platinum => scalable?

We can use the traditional engine instead

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Well known technology

Dual fuel gasoline/H2

Scalable

H2 has a low energy density

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source: adapted from Verhelst, UBIA

The same autonomy (with packaging)

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gasoline 60 kg

1150 kg

100 kg

H2 storage is expensive

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about 10000€

Electricity can be converted in many fuels

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electricity H2

water

capture of CO2

used as fuel

CH4, methanol, …

capture of N2ammonia (NH3)

Compressed Natural Gas (CNG) is already used but same issues than H2

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Already commercial for production cars

Problem of storage: even at 200 bars low energy density compared to liquids

Ammonia is easily produced and stored

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Easy to store: Liquid at 9 bars and ambient T Storage similar to LPG

Does not required CO2 capture

N2 in high concentration in the atmosphere

But still some combustion issue to use it efficiently

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Laminar flame velocity (cm/s)ammoniagasoline 42

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Ignition energy (mJ)ammoniagasoline 0.25

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electrostatic discharge 20-30 mJ

Research work focuses on how to mix it with H2

60source: Koike et al., 2012

Laminar flame velocity (cm/s)ammoniagasoline 42

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hydrogen 291

Methanol is a very good contender

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Easy storage (liquid)

Easy mixture with gasoline or ethanol

Potential for higher engine efficiency: high octane number, high evaporation heat

Can be used as a drop-in fuel

Methanol is a very good contender

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Easy storage (liquid)

Easy mixture with gasoline or ethanol

Potential for higher engine efficiency: high octane number, high evaporation heat

Can be used as a drop-in fuel

Dimethylether for diesel

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Dimethylether (CH3OCH3) similar to diesel (high cetane number)

Better combustion (no C-C)

Investigated for trucks and marine engines

66source: xkcd.com

References:

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Sebastian Verhelst, UGent, UBIA, 2014