Embed Size (px)
Citation preview
GANNETT FLEMINGBALTIMORE
U.S. ERA Region IIIOffice of Analytical Services
arid Quality AssuranceAnnapolis, Maryland
ANALYTICAL REPORT
KEYSTONE SANITATIONSUPERFUND REMOVAL/REMEDIAL
Account #: 96 T 03N TFA 03COL900Lab Request # REQ96192
October 10,1996
U.S. EPA Region IIIOffice of Analytical Services
and Quality AssuranceAnnapolis, Maryland
October 10, 1996
ANALYTICAL RESULTS: KEYSTONE SANITATION [REQ96192]. * * • , ' - . . - . . ^ - •
Dear Christopher Corbett (3HW24),
Enclosed is our analytical report for the above case. It is organized intoseveral sections: Analytical Request and Sample Descriptions, Organic,inorganic, and Microbiological Results. . All data were peer reviewed. ',
Analytical Request and Sample Descriptions: (General)Each laboratory assigned number, station, description, matrix, sample dateand locational data is reported. A table summarizes the tests assigned toeach sample. A glossary and qualifier code definition is provided.
Inorganic Results: .For requests assigned inorganic tests, results are grouped by servicegroup, e.g.. Metals. Sample results are reported; non-detects are providedwith the actual quantitation limit. Method description and quality controlprotocols, are described in analyst narratives.
Organic Results: ' :For requests assigned organic tests, results are grouped by service group,e.g.. Volatile Organic Compounds. Only detected analytes are reported.Nominal Quantitation Limit (NQL).tables are provided for each servicegroup. Specific information for the calculation of Actual QuantitationLimits (AQL) achieved for a given sample is included. Quality control .' •values are provided in summary tables with acceptance criteria. Methoddescription and. quality control protocols are- described in analyst.narratives.
Microbiological Results: . " .For requests assigned microbiological tests, sample results and qualitycontrol values are incorporated into a single table. Method descriptionand quality control protocols are described in analyst narratives.
If you have any questions we may be reached at 410-573-2600. ' .t • ' • .
Approval for Release:
cc: Christopher Corbett (3HW24)Scott Beeman (NUS (HALLIBURTON))
AR32I
S S S S S S SEE E S E E S E E E S E E S• -V 'N, " •«» .'<*• •<>.>.>.»^>*^v.>.«^^,>»^ r^f^f^ c^ r ^ v n f l p n o B c o v v f l o v - f l s c D f l o A vo o o o o e o o p o o o o o o p o o p o o
* «• <9 <S
*J
' 6•H ao >b« <
!«JIH
81
o o e o m mm tn m o_ _. _ _ _ . . _ . . _ . _ . _ o r- i» o o o m o r« r- oo « » w « i-i «n m <w w «H o o o o « m' m o o inif> mw o o PI •«•*»'«! '£'•>•*! IH' w <o w we>r! H oO (-TfHtl tH t-4«-l.*4 O O O IH «H O 1H <-t rt O 11 >4 <Ht e v c < o w \ a u > < o i o i o < c > o v > w < c u > u > u i v > < o0 01 CV ' 01t 01 C* 0\ 0V 0\ 0\ 0V 0V 0V 0V 0V 0V 0V 0V 0V«»N.>.X.^^.«W>.'^,X.>.X.«»>.-V>.V.'».'>.
•
s i J £ iII Hl I * • • -I 1
a? 3 •- - Ji ij W i4 ' 14 li til • • ll & 14 '• 14« « i-l « B E • M 0 fH & • iH »H r-l iH rt iH *<HA> 4J«4 It U. t> &•¥!*>•* S A > « 4 * H - « 4 v 4 * H ' < H *>•**U ti *>•*&•* p 4J -< -rt -H -H
£ £ £ S £ S t £ S S S S 5
aCa a a •' • - 2 .OBB fi D - ' D H Mm <c. te P E E e* «t '»* :-*H P «s n n « in w r- r- r-
O O
<-i r« m « in to «-i n m w m w r * « n o t 4 r « m « i nO O OSO O O <-» rt rt > - < < - l t - l t - < < - l r 4 N N r < n < M nr t r i < H x < - i r < 0 \ v > « i o t o t V i » « i a > e v e v a t « i a i - o to o . o o o o o ,00000000000000CD 4D CDOD A O OiDfD.tD CO 00 43 0 flQ-tD CD CD OD 4D flDS f i . S S - S « f i f f « » . . S . e e f i e e p p p e p o -«o w-w> «o «ow IB 10 w to <o ic <oot e> at 0> et 01 at •> ot <K 01 m ei ov et o> e>
AR32liii2
A
IOb Ol
*ico Oo H§9 fr»tn - - aaa [3B&I Bass* x iaei x
M _ _ _"IX
frti
0«o,__ _____ ___ __ 1 V
o " " ' ' ' '
aoo
HHH
§-d(9
»„!• ota 'd*: 2 9'9 w (0
co
w
&i.Tl (B_J 4a
•H &
DEC Qi '
X
&Q
Id]
I
X
X
i
§
I!
X
•• • i 1-:. :.-••'£.;. .v.-r*.•>.'. - •* •
ii
O.iiS
I?:jf<F q i-,«• -••: '• '•' : J ;'•;•
V i -!•I
•S£,
£
*'• •I £! ; ' IV:.••'.-I
Ip
I* " - ' I E - « * ~ ~ ' f-•"«'
f ,! I'- '
A
£
•£3-a e e jj
. }• fT
ItiS
•fi
'!'i i
i
6" 13
-
;*'
JI-Bfififi-a -i .5 -1 *£ J I
' i: ~ r
111
J9
Ii
1 i
I
,f
1 F ef: 1
1
'II f ' J'fs
lfi
5 i- •••* : 84 «• * r *
•Si. .!
1 ^r
8M
1 J!,3£
_« «,
1
.:
15*5*^a a E A .e» K a, ii H * • E* r « E fi o
[* J
•i* !lft'-"I*? :•:;-*|l 3*i{i:'l* s ^i^"f|ja
Illii
I
e
mi K K - K A I xiMb^^^qy^avs •~«ii»i2fi\4}:'
HBBBe.ti-a-afHEff! £ f K H
I V\ "9
?l
iitiiijiifilliliiiilllii liJiiil"| " * '''..''• • •••••_• « « i i _.•.•• | J/'i'll.1! ii i iv v A < B, o a B, « « w j z: i
•• - . . . - - . .•.. :AR32i'lW
HIIio
feo
o
0
Qm oZ 2 O ,_
< g.£'. :;8. 8O S § .< f?
O -
Section: InorganicsPage: 1
PERCENT DRY WEIGHT DETERMINATIONS
I
Analyst!
Mike EllicksonChemist
Method: . I .
The soil/solid samples from Keystone Sanitation (Batch 3D $REQ96192) wereanalyzed for Percent Dry Weight as required by EPA analytical methods.Samples were dried at 105*C following the procedure outlined in EPA Region IIICentral Regional Laboratory's SOP IR30AOS6.0.
These results are to be used to convert analyte concentrations to a dry weightbasis for organic and non-metal analyses.fBsrmally, analytical values are——reported on a wet weight basis tor orgazUcs and non-metals'. Alj of the metalsthat are reported use a 60 *C drying temperature for the percent~dry weigEF~~determinations, as required by the methodology. The 60*C percent dry~veightvalues are reported with the metals results, if applicable.
Weighing dishes used for these samples were sequentially numbered, oven-driedovernight at 105*C, and then cooled in a desiccator before the empty dishweights were recorded. Five to ten grams of each sample was then placed oh anempty dish and the total weight recorded. .The samples were then placed in anoven and oven-dried overnight at 105 °C. When the samples were removed fromthe oven they were cooled in a desiccator before their weights were recordedfor the determination of percent dry weight. All weights were recorded after...all appropriate calibration checks were completed on the balance using Class"S« weights. . • " , ' . • '."<;>". ' : , • ; • . • . -
AR32I
oo
' - • - ' • e n
1 ss3 • fr»H
O 4JQ •• QDJ 3fr <D
I* I"w
tao ta
H(4 0-0
H 9 3 3H 01 a isH MHH 3 N
g IS O El OS S J »3d t» r«* '*'.'*. « ( 9 » » « » » I 9o 3 f • » 9 c i t i * ) m e t m n c t n<*a i» • i . . ' . . . . . .o t i d - «a o o o n o o o e o e
rt-H-H Hit! dHH EHU^ gO 3 8wa **• 0ta
<H
o gq §
^
^
ca
•HO
04
.s*
O bS &
:s3 ^3 oo >-<• a• (•
* «
10 vo o'
O ' O . • 0
o•>«o
«~~93
3i
o
N.^ff F30tila i - t i - t« O i>
i
c» * * . . i . j
2
*
A
m •> a
8 o ? S . 3
r s-s •».» o . S
o ? 5
s m. °o ? 5 3
I?!1
AR32IU7
ooo
U
gcj J5oiO *U n Oo u•• •• S
o tn *•«H « U3 «: ,———*>(U Ci £P 4* I S S «i fc - oW «: O
§Boo15 -a
H HiHH S >t§« o EVO 0 C
>«>tD
H
YT
• 00 C<O « U
I
03
RU
•a M
>«0«0»1S
TR
0
Blf
I
00
Oin
t I . • « ,'*" . 1 1 , 1 . : *
g«8 ASi
* 1
» F• S
n H« qS 9i
• •r- -i •v. »- •v.* °
W • m
*1 ! ** •: f*
I
. »9
•f-I 8 i ••:•-••• s I 5 s J s* * & I s S I .3 .- 1 * I
*J PF
II
AR32I
ooot§O
on
aoo0 tSH fl» d dM w 3 9
S3
I1a
as8
3
5
9« - - o
OtH
«So a
» w • --- _••_•M fn n 3B4J CU 01O 43o M aCQ * 9
00
H i* a
8cu
CQHH
I
H ^gl?- , CQ
O3
S ii
i
ss
11 -
4"• O U>
*• * H £
<•* 5 s s
<n n 1/1
* P« O lHr4 <4 <4
' 3 R s«Sr» v*i3 S
•. . < < •in n r>
* S S *
, a s sT* H
. •' .'
4<4 t> H* n ot IH
4» 5 a s
r4 «H
j 23sfo. ° ;* S C £
' • 1 ''1A
{
lUtrixi SOUW
Brooofluorob
«U-l,2-Dichl
da-Toluene
' ' ' ' -. '
t
• . • ' , ' . .
•* 3 "*23 at n m3d * H o »
S M
'••HUH
•''' '-1 .1- ^
• ''''-I'- •!"•'3'iJ< j o! :.i'|i'!i••'•-.'•
| 1 * S ot §
as -,. •', «*j j A n 2
So
.;J.j.-n«sd * * g s
a bi '5 3 » A at *O VIs 9.• T\l + .s a s
* g ' ' • • ' - .i s # a ; sSo rts e •" i1 d -.s s s* 33o a«• 3 .* a3 &l « -* e33 * .01 01 o
a 33 J • S S S3
. ; - } : ' ; •1! ....I'l 1" S o
i • \-^ 1 •1 a |l? i• < 3 *!( •* rt4 g « 1 •? f3 G *
AR32I 1
•
. . : ' - . . . ' ' , ' ' »*- _-
, '. ' ' •
» = \ )a ; . « « N_X. a e . • • -H ' ,
S E , ,. :n
2 E in <n inS e * « o 01S E •- H •S .E
5 j in 5 o
I ...1
' ' • ' '
| S
3 i ia \ o
'?• i S r t < I / '
1 I M «*
i»9
oo
«*»o
I '•**;'o «*O O nO
O CQ. •• •• ^
o tn •••H « V> *
« •• O **|CQ «: C CQ& r o
H
§•3.• «*OO
••|g -• HH O C C CQH TO « B)M M H »<
0 B *
I O« T! -H
• O
-•»8
g|*3 tr>gqj 135CQ
p faEH «CQ W
Ofa
^
Kjj *) ^&Q
•wO
0O
, ^6 *
*
g«.,5r
t S n J7 Si t»X* <r m i» n ,ma H H H v< H2 i i i i i** w e « «> nn£ £ £ £ £
I i ill? iI l'J'*3.-3'IS;
AR32M50
8
s
„
1V •
r- oi i i i iw in rt t* .Hi» • »»• ID r» r«
ci « n n AO O O O A
\
I
ji "i
AH32II5I
oO o
rt O .O UPSH en v_.on o« •• ft, CJCO b O>o tn HHjj pi fiz Co en aO o WW PS
H
••to
V COgp;1 OOflO « CO< £•"
O - " DO M•H . H> C Sfc 0«0
HO C C MH CO « D ZH MH 2_i-e ;»{>>• 3
. 8 S 8 3 n-ri«ri < £ H
tfH 43 B O^ 8J-H-H <O! CHH Kp< < c o SW £ ft"WOO >H• 0 C P!
•H S«H O<M mO rt
1LJ JL * l
S 5HO
H i0 '
M aH Q••
|I
O Ofcl ft
/;; "'•'' ••'•: '"• ' •' : '; : '••-.•-.••. , ,;-';"' ".-,- "' • • . . " . . ' -'" ' ' :
' • ' ' . • ' : ' . ' " . . ' • ' ' • • . . • -. ; , • - • - • • ' • • " ' ' ' _ • ' " -
• ' ' - ' ' ' , - ' • ' . • ' . . •
• , •. ' • • -•'• •'. • • - , ". " '
'.."•'•,'.'•"• • • . ;. , : ' . • , . *, _ . '•
/ . • ' " • • • • ; ' " ' • , - • ' ' • '• • t '
- ' ' . ' ; , - - • • ' , ' ' •• • ' • ' ' . ' • • . . • • • • . • •
' • • ' . • : . ' : '••'"'. .. '• . . - ' • ' !
S j r- in r- £ S1 r > . « o n < n « e r - a > t o ' i eS M ' C o o i - i o S c« r> c t 3 < H o i ^ o « o o o o e e og j p O t e t f H g ' c o o o g ^ r< o> H g ' r t o o o o o o o o o o e e
' ' . ' . - . • H . • " ' •H . . . . . . . - . - ' . _
8 • • ' ' ' • ' • - ' - ' . . " . • ' , . - . ' • • ' . '• < ' , , . ' . . wS ft ft g § ftu> j) £ . «e S S§ i 1 8 s s1 I ' ;:J ': '. j § f
j •. '.'.•' • • ' • t ' r . , ••' • - . / ' " " " ' '
•* • ;';/' " '. :^. • ' ' •''.' • • '• • ' ' -.-'-: "•
'I-. v/^^iV •;.;""".: ' ', -'." .; :,.""-1 •'. ' •.•''.f :.- '.. ; . .' '.- '. - ' '-.''•:
• • « • • ' • . - . " . " " . . - ' . • ' . • ', v ' , . . - . , ; , . '
j. g'-|.v-;; v'-,;-"" • j ." - , gg.| ,;.C . * * $ O N O V ' D N N N v
2 " * * S . C ^ *6o ' C * J E J) Jp -.0 c> ^• f. ^ 1^8 11 f §^« '1 .J.1 gl II I!''!.6 «q S S R S *S 5 01 2 7? F £ £ K 3 * M * > , H r J r i P >- '•••!«« I /-ffl'S-*!'* '• f a « l a'* S I sS fi l-ll*'*':!1 |l«? is'-ls I Is? 1 1,1 1 A i a S i 33-Hr<i A-
AR32I152
oO oS O J
gc oold coOQ o•• •• t£ ft§9 h 01tn HHu oi a <no PI aO 0 WM 3
M Q
if-3 Qjg™J'i o
o . a9 DO W•H tafc o a
HM S 9 MH MH 2•H 3 >. ad <i o w tnO q g il•H -H i S H
Cfl-H-rl - rf5K< d«-«H H
• o°d S5sl^ 1<M O44 CQO 3
'• ft
*% (t *.
H!ifCO U?J H4
2 CO
^ i•H 3Htjy<
SOJ4
DuO*
• - . . ' . ' '
.' * . • . ' ' * - '
— • v -, .'
* • :
- - ••
' . . . ' • - •• ' • - •
. • • ,• • ' . ' ' > • - - ' • . •
m r t i H i - i o o o r H H a 3 ° > ? > 3 t n n n m « nO O O O O O O O O 3, ^ |H A 01 ^ H O O O O O
• •* • . ' • • . ' ' . .
' :- ' • a • - .•"'."•• • • ; J • •s 8 §\» . 0 3: i 8 8" a - . " • ' " ' ^ ' •. .. | 2 . ,2 ••
- • ' . . • '
- ' *
' ' ' • -
s s s ' :• ,..'« « • < • a» f i a•§ g d < 2 3 •§ a
o ]]•]' | § o I
s ll! • 't « • ." o
lfg«ftisft|l g l ^ l . M • ' i' * « § 1fl i, S, 4 w « « St i § 1 7 7 I « 3 £ 3 S1 A2 3 « g H H H* 6 2 | 3 3 3 I 3 i « e o 1
AR32 IJ53
oocv
mo i« cv
Pj H Si cvOH neto u•• •• K8&- H«•rt « VO**3 Pi CVO 43« , « oCO «: O
OOu.1
S<
0o-dH c c,cH CO tf 0H MHH S tsfj
O«J 00 0
43 OBJ-H-H
.s!• 0 C& o «&oS^ 6•H K•w O
6-CO»iCQ i<3CO
oPi
|
1
iniiiig
iii•9 . «
s s g•H 5 SI .*•i
i£
•v . r*t^ ' . O N
•i ss- e
•>n
iffV
o
n-• O__ H L. ^
ui r-•o
I n <v n •« n n no m o o o e. o o
if•3*9: «B'I3»3«.'3»9n n > a m c « n r i N «o o N o o e p o o
- - • -f C£ £ •Ifi g
., 4_i. M< _. .. A > ' . r * v n « . . IA U Li 0 *^. * M Bi ' . I . • • * . - » E Z *•
Si"O -a« «
i
&
?". -» .Jn o H
*M '
• » t»o «:w o«
« • « • • * $If" '51 111£ £ £ S 2 1 3t fr ^ P ? 1 -S -J g -
oo
8o
£0tH
O3 OHMM K
*» PI - .01o n9 M oto • *' ~
8 K5
s -. .o.
o 6 *o s:Ho en"MlH 01 3 3H MH
HH^d n 0%, « 3 ,.op q3 _ s 3 s ff
• o• «
^
|cOS
«M OmO
o
,sl ! , ss a » . <•
i^n<«
U
S I(I
rsU
s
Is ii' gl
o
t* 51S 8 2
D
i
a
2
•Aa
• 1
S|Hi* i• H
o
1
*a I
i111^ 8
? ;.. •:.-.iij
ii» .: Mft 3 " o
:ng
" • MT '„ ' «51 '•a 858
ff
AR32I155
I? Section: Organics?e: 1
VOft. Analysis bv CC/HS
Analyst!
Frederick ForemanChemist
Method: ." ' • • • • ' • . ' t : - - - ^ ' - - ' - . ' ' "
The eleven coil and ten aqueous samples from Keystone Sanitation (SF/RR) wereanalyzed for the presence of volatile organic compounds amenable to purge andtrap and identifiable by mass spectrometry. Samples were collected on July 30& 31, 1996 and August 7 & 8, ,1996. Samples were initially analyzed on August 14.621, 1996. Samples 960801-01 t -02 were analyzed'! day beyond the 14 day holdingtime for aqueous samples" preserved at pH<2 however, no compounds at significantconcentrations were detected in either of these samples. The analyses wereperformed following CRL's draft SOP8R3-QA214. This is a consolidated methodderived from EPA methods SDWA 524.2, KPDES £24, RCRA. 8260 and the Superfund CLPStatement of Work. The analyses were performed using fused silica capillarycolumn/gas chromatography/mass spectrometry. Concentrations of. compounds weredetermined using the relative response of authentic standards to the closestinternal standard. Only detected results are reported. Sample target compoundvalues outside the quantitation range were labeled with a "J". This indicatesthat the mass spectrum obtained for the compound met the identification criteria,yet the quantity present was outside the range for which the instrument accurate-ly quantitates. All results qualified With a "J" are estimated quantities.
The NQLs (nominal quantitation limits) are the quantitation limits that have beendetermined for each parameter analyzed by this method. The actual quantitationlimit is the NQL multiplied by a factor specific for each sample. .All aqueoussamples were analyzed at an NQL factor, of 1. The table below lists the NQLfactors soil samples were "analyzed at as well as NQL factors used for dilutions.All values reported from dilutions are qualified with a *C".
XR32I156
Section; OrganicsPage: 2
Sample Number
960301-03
950809-12acetone2-butanona,
960809-14acetone2-butanona v
960809-17toluene
950809-13
960809-19
960809-20
950809-21
960309-22acetone
960309-24toluene
NQL Factor ,0.91
1.015.0 -5,0
0.895.105.10
0.9450
0.95
0.57 ^
0.95
0.93
1.015.00 . . • • - .
0.8050.
The samples were also examined for the presence of • compounds in addition to thetarget compounds listed. Tentative identification of these compounds was madeby comparison of sample spectra to the EPA/NIST Mass Spectral Library. Authenticstandards were not available to verify these results. Concentrations for thesecompounds were estimated based on the response of the nearest internal standardused for quantitation and the assumption that the instrument response for a givententatively identified compound (TIC) was the same as the response for theinternal standard. All reported concentrations are estimated and qualified "T".
Quality Control: • •
Before acquisition of any sample data, the mass spectrometer, is calibrated usingFC43. The calibration is verified by obtaining the spectrum of a known compound(BFB). All mass assignments and relative abundances are found to be inacceptable ranges or the instrument is adjusted until an acceptable spectrum of•the known is obtained.
Immediately before analysis, each sample is spiked with three (3) internalstandards obtained commercially. All quantitation or estimates of concentrationare made in comparison to the internal standard nearest the compound of interest.
157-
Section: Organics?e: 3
Quantitation was done using a four-point calibration curve (5, 10, 20 and 40 ug/Lstandards), For soil samples, the heated purge method was utilized. Hie averageresponse factor of the standards was used to determine concentrations.
For each group-of samples analyzed, a method blank was prepared and examined forlaboratory introduced contamination. Values qualified with a "B" representcontaminants whose concentrations are less than ten times the amount' found in theblanks. ' ' . ; -.:,.;••;'.- . • . ; ' -. .
The samples were spiked with a mixture of three surrogate compounds prior toanalysis. Recovery for each was.determined to check for matrix interferences.The target limits are those established by the CLP. 55 out of 63 surrogaterecoveries were within acceptable recovery limits. Surrogate recoveries outsideacceptable limits are qualified with an 'A1L «
Two aliquots of sample 960809-18 (soil) and 960809-23 (aqueous) were spiked withthe five matrix spike compounds at a concentration of 20 ug/L. The recovery foreach compound was determined to check for matrix interferences. Recoveries havebeen corrected for target compounds present in the sample. The target limits arethose established by the CLP. All MS/MSD recoveries and RFDs were within CLPtarget limits. . ;
. Tentatively Identified Compounds
Sample No: 960801-01 ;CAS« R.T. COMPOtlND NAME_______________CONC (uq/L)
. None Detected .
Sample No: 960801-02 -GAS* ' R.T. ____COMPOUND NAME____________________CONC (uq/L)
None Detected
Sample No? 960801-03 . .CAS«_______R.T. COMPOUND NAME ___________CONC> (uq/Kql
None Detected . . • • ' . .
Sample Noi 960801-04 'CAS« R.T._______COMPOUND KRME _________________ COWC fucr/Ll
None Detected
Sample No: 960801-05CASl_______R.T_____ COMPOUND NAME ___ ' ______CONC (uer/L)
None Detected
Sample No: 960801-06R.T._______COMPOOTTD NAME____-• ______;______CX3NC (ua/H
None Detected •
AR32I158
Section: Organics, • ' ... • . ' . •..,-.-. Page: -.4 , ~\"
Sample No: 960309-11CASJ_______R_JT_._____. COMPOUND NAME____'______________ CONC
None Detected
Sample No:CASt
Sample No: .CASi '
Sample No:CASi
Sample -No:CASi
Sample No:CASi
Sample No:CASi
Sample No:CASi
Sample No:CASi
Sample No:CASt
Sample No:CASi
Sample No:CASi
Sample No:CASi
Sample No:CASi
Sample No:CASi
960309-12R.T.
1 m
960809-13R.T.
960809-14R.T.
960809-15R.T. .
960809-16R.T.
960309-17R.T:
960809-13R.T.
960309-19R.T.
960809-20R.T.
950809-219 in*•'•*• ————
960309-22R.T.
960809-23R.T.
960809-24R.T.
960309-25R.T.
None Detected
COMPOUND MAMSNone Detected
COMPOUND NAMHNone Detected
COMPOUND NAMENone Detected
COMPOUND NAMHNone Detected
COMPOUND NAMHNone Detected
COMPOUND NAMENone Detected
COMPOUND NAMHNone Detected
COMPOUND TIAMENone Detected
COMPOUND NAMENone Detected •
COMPOUND NAMENone, Detected
COMPOUND NAMENone Detected. . . . - iCOMPOUND NAMENone Detected
COMPOUND NAMENone Detected
COMPOUND NAME
CONC
CONC
CONC
• CONC
' CONC
CONC
CONC
CONC
CONC
CONC
CONC
CONC
CONC
CONC
fua/Kal
(ua/L)
fua/Ka)i
i(uer/LL
fua/L)
fua/Ka)
<iia/Jta)
(ua/Ka)
(ucryKaV
(ua/Ka)
(ucr/Kcr)
Juct Ll
(ucr/Ka)
(uer/H
flR32l159
Central Regional Laboratory - Region fflVolatile Organics Analysis
Nominal Quantitation Limits (NQL)
Unto: Solids - vg/bg (wet)' NPTC « Non-Priority Pollutant Target Compound
Actual Quantitation Limit - (NQL Factor) X NQL
SHCASi SlW75-71-874-87-375-01-474-83-975-00-375-69-4
• 75-35-475-15-067-64-175-09-2156-60-575-34-3108-05-4590-20-7156-59-478-93-374-97-565-66-371-55-656-23-5563-58-671-43-2107-06-279-01-678-87-574-95-375-27-4110-75-810061-01-6108-10-1108-83-310061-01-579-00-5127-18-4
Dichlorodlf luoromethaneChlorotnethane • •Vinyl Chloride•Bromoraethane ' •ChloroethaneTrichlozof luoromethane1,1-Dichloroethvlene ,Carbon Distilfide ' KPTCAcetone •• KPTCMethylene Chloridetrans-l, 2-richloroethene1,1-Dichloroe thaneVinyl Acetate KPTC2 , 2-Dichloropropaneci»-l,2-Dichloroethene KPTC2-Butanone KPTCBromochloromethahe KPTCChloroform1,1,1-Tri ChloroethaneCarbon Tetrachloride1,1-Dichloro-l-propeneBenzene ' •1,2-DichloroethaneTrichloroethylene :1, 2-DichloropropaneDibromomethane KPTCBromodiehlorome thane2-Chloroethylvinyl ethertrana -1,3 -Dichloropropene KPTC4-Methyl-2-pentanoneTolueneci»-l, 3 -Dichloropropene1 , 1 , 2 -TriehloroethaneTetrachloroethylene / •'
NQ®''.'<*••''•tS
•'•:-5 'S5
• '5 -••'"•'•S: 5'•. 5•'- $• 55
..• 5;"55
•-" 5 ' '"•,•* '••:..'S .•" 5S
' • ''5: .•. '555S
'. '' 5'••• ;55
• ''555
• 5;''••" s
-
*
apgsss gsl«2-2E-9591-78-6124-48-1106-93-4108-90-7630-20-6100-41-4108-38-3106-42-395-47-6100-42-575-25-298-82-8108-86-179-34-596-18-103-65-95-49-106-43-108-67-98-06-93-63-6135-98-8541-73-1106-46-799-87-695-50-1104-51-896-12-8120-82-191-20-387-68-387-61-6
1.3-Dichloropropane . KPTC2-Kexanone KPTCDibronoehloromethane1, 2-Dibromoethane (EDB) KPTCChlorobenzene1,1,1,2-Tetrachloroethane KPTCEthvlbenienem-XYlene) (« S p icomers KPTCp-Xylene together) . KPTCo-XYlene • KPTCStyrene KPTCBromofonnlaopropylbenzene ' KPTCBromobenrene ' KPTC1,1,2,2-Tetrachloroethane1,2,3-Triehloropropane KPTCn-Propylbenzene - : KPTC2-Chlorotoluene KPTC4-Chlorotoluene • KPTC1,3,5-Trinethylbenzene KPTCtert-Butylbenrene -. KPTC1,2,4-Trimethylbenzene KPTCcec-Butylbenzene KPTC1,3-Dlchlorobenzene '1 . 4 -Dichlorobenzenep-Iaopropyl toluene KPTC1,2 -Dichlorobenzenen-Butylbenzene • KPTC1 , 2 -Dibromo-3 -chloropropane1,2, 4 -Tri Chlorobenzene 'NaphthaleneEexachlorobutadlene1,2,3-Trichlorobenzene KPTC
55Ss5
's .'S -''Ss ^
• s5 •5' •S5S555 '5 •5555S555SS
• 5S .55
The "Nominal Quantitation Limit" factor is an overall correction factor applied to the method's NQLs for analytical adjustments madeduring the analysis (Le., for analyses of moreor less than the ideal 5 gramsfor soil samples, for sample dilutions pifaHoanalysis). • • ^r'
For example, if the NQL factor for a CRL soil sample is 2, the estimated Actual Quantitation Limit for vinyl chloride would be 10 ug/kg(i.e., 2 x 5 ug/kg). . •.' - -
1 j • ; • . ' . . ::.V:I •.. . . ' " ' ' • • ' . ' ' ' . • ' •"" ... Rev.JuIyl4,»»95
AR32I160
Central Regional Laboratory - Region HIVolatile Organics Analysis
Nominal Quantitation Limits (NQL)
Units: Wtttr - Bg/L NPTC - Non-Priority Pollutmf Target Compound• - _ . • ; • • ' ' .
Actual Quantitation Liiait-(NQL Factor) X NQL
ffgRSXT*-**"-75-71-8 .74-87-375-01-474-83-975-00-375-69-475-35-475-15-067-64-175-09-2156-60-575-34-3108-05-4590-20-7156-59-478-93-374-97-565-66-371-55-656-23-5563-58-671-43-2107-06-279-01-678-87-574-95-375-27-4110-75-810061-01-6108-10-1108-83-310061-01-579-00-5127-18-4
mffSf S ?*Mt»Mt8*SmMS»i ^ ^Oichlorodif luoromethane :ChlororaethaneVinyl ChlorideBromomathaneChloroethaneTrichlorof luoromethane1,1-DichloroethyleneCarbon Disulfida NPTCAcetone • NPTCMethylene Chloridetrans-l,2-Dichloroethene1,1-Di ChloroethaneVinyl Acetate • NPTC2 , 2-Dichloropropanecia-1, 2-Dichloroethene NPTC2-Butanone NPTCBromochloromethane NPTCChloroform1,1, 1-TrichloroethaneCarbon Tetrachloride1, 1-DichloropropeneBenzene '1, 2-DichloroethaneTrichloroethylene1. 2-DichloropropaneDlbromomethana • ' NPTCBromodichlorotnethane •2-Chloroethylvinyl ethertrana- 1 ,3 -Dichloropropene NPTC4-Hethyl-2-pentanoneTolueneei»-l, 3 -Dichloropropene1 . 1 , 2-TrichloroethaneTetr achloroethyl one
• 55
• 5 '•5555S55•s5S5S55S5
' 55
• • 55 'S555555SS55
'
142-28-9591-78-6124-48-1106-93-4108-90-7630-20-6100-41-4108-38-3106-42-395-47-6100-42-575-2S-298-82-8108-86-179-34-596-18-4103-65-195-49-8106-43-4108-67-898-06-693-63-6135-98-8541-73-1106-46-799-87-695-50-1104-S1-896-12-8120-82-191-20-387-68-387-61-6
1,3-Dichloropropane - NPTC2-Hexanone • NPTCDibromochloromethanel,2-Dibrorooethane(SDB) NPTCChlorobenzene • •1,1,1,2-Tetrachloroethane NPTCEthylbenzenem-Xylena) (a & p isomers NPTCp-Xylena together) NPTCo-Xylene NPTCStyrena - NPTCBromoformZsopropylbenzene / NPTCBromobenzene NPTC1, 1, 2, 2-Tetrachloroethane1,2,3-Trlehloropropane ' NPTCn-Propylbenzene • NPTC2-Chlorotoluene NPTC4-Chlorotoluene NPTC1,3,5 -Trimethylbenzene NPTCtert-Butylbenzene NPTC1,2,4-Trimethyibenzene KPTCsec-Butylbenzene ' NPTC1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzenep-Isopropyl toluene NPTC1, 2 -Dichlorobenzenen-Butylbenzene . . NPTC1, 2-Dibromo-3-chloropropane1 , 2 , 4-TrichlorobenzeneNaphthaleneHexachlorobutadiene1,2,3 -Trlchlorobenzene NPTC
ttNQfiS5S5S555SS555
••S.• 5S555
- 5'S 'S
•515 V
- 55SS5S555S
J
,
The "Nominal Quantitation Limit" factor is an overall correction factor applied to the method's NQLs for analytical adjustments madeduring the analysis (i.e., for analyses of less than the ideal 3 mis for aqueous samples, and for sample dilutions p«w toanalysis). *r*f
For example, if the NQL factor for a CRL water sample is 2, the estimated Actual Quantitation Limit for vinyl chloride would be 10 ug/L(L&,2x5ug/L). - •
Rev. July 14,1995
f l R 3 2 i 1 6 1
A •* '*
?
Ml
C>\\
~>
1&Cx
?
\
O r^ r r* »-• r , ? —
siss
00
3
STA.O
ICOMP.
GRAB
§
of .S. ?MB TO
S1 3
is a ffp1 - *or- m
s •to
HEG
=" --«
6WVN AGE
CODV
RD
1R-32.N62
AR32II63
0)Region III, Central Regional Laboratory
j Annapolis. .Haryland:|r•• '|TmT?n AHD RISC ZTPOSDEZ il/T?i SHEET
LEVELS OF PEESOHAL PEDTZCTIOE DDEIEG SAHPLXHG
BACKGROUND
Under the authority of Section 104 of the Comprehensive Environmental Response;Compensation, and Liability Act (CERCLA or Superfund) of 1980, Section 311 of .the CleanWater Act, and Subtitle I of the Resource Conservation and Recovery .Act (RCRA), E2A.hu'been delegated the responsibility Co undertake response actions vith respect to therelease or potential release of oily petroleum, or hazardous substances that pose a.substantial threat to human health or welfare, or the environment.
GENERAL ' . ' . , ' •: •''. '•.' ' '. ... , ' . . . . . ' ''.•-" . . r .'.-... - , - ' . <V
This form is to be used vhen.-collecting' Environmental Samples (i.e. streams, farmponds, veils, soils etc.) and for Hazardous Samples (i.e. drums, storage tanks,lagoons, leachates, hazardous waste cites). This information is intended for use as aguide for the safe handling of these laboratory samples in accordance vith EPA and OSHAregulations. The sample classificacion(s) and levels.of personal protection used bythe sampler in all situations vill enable the analyse to be better avare of potentialexposure to substances in air,, splashes of liquids, or other direct contact vithmaterial due to vork being done, i • •
DEGREE OF' PROTECTTON . ; . • ' , . ' . ' /
___ Level A: Highest level of. respiratory, skin, and eye protection needed.Felly encapsulated suit, respirator self-contained (Tank type)
__•_ Level Be Highest level of respiratory protection but lesser level ofskin protection needed. . /.' 'Chemical suit, respirator self-ccneained (Tank type)
_ Level C: Lesser level of respiratory protection than Level B. Skin •.protection criteria are similar to Level B.Chemical suit, cacnister respirator/cartridge , (
Level D: Vork uniform vithout any respirator or skin, hazar ds. •Lib ,'coar, gloves etc. •••'_..' . • ' . • •••
CLASSIFIED FIELD SAMPLES - • /
___Environmental ;__Hazardous X Comb. (Env. t Haz.) Radioactivei • • • ' • ' ' . - • • '
Site Name; k&C$T&<*£- £-*<(>•>££LL _____:_____ Sampling Date;
Sta Ho.Field pH: 7. T* -7.73.
(must be taken prior to submission of aqueous samples)
Sampler; SZb*?}- J*. Cts/LA ts _____ ?°ck Phone Number: fyo ¥f)
Personal observations at time of sampling (surroundings) ; ^n
Sample collection observations (physical sample, odors
AR32I
N
oC
SS•*» vi
V* P -
Date /TimeReceived by
oM3
Received by
s I
*'••»
Date /TitSiynt
x)6
53
K
\
og
I
i
CO
VJ-^
K*.
1\
M;
f3v=s
sN
ry
Ml
vO
tos 1
—a
Ok
1CD
?s
v s*•>s /
Si
o5=!m
COMP.
GRAB
STALOCATION
§"£-SfV * rS
! |ft
PROJECAME
m za •in
o z" o
- JO
z
Q
vz'
20O
m22y 5
fe$
1R32II65
.,*-• •
i
V
I
I
Ier
ps
18 O gm Z . •" Px •
n
2OO
I€ 1 r. .(X X »
§30
I
«' •-*•'?!:.
Ir
OT
Cis
o*>
*P>ȣ
^
I
i
I
Im
COMP.
GRAB
I
^ ^_ ^ S^g §^^ ^>
in
• .,2*O
if.g»|
n* 2'«
olX 3 S S 2DDDD
AR32II67
Gannett FlemingP"fc I SIk tfmfmf^f^ A k I IPS ni A k Ift lf*F ft VV
GANNETT FLEMING, INC.Suite 200
ENGINEERS AND PLANNERS —— Tte XW£oss KeysBaltimore, MD 21210Fax:(410)433-6520Office: (410) 433-8832
Augusts, 1996 .
Ms. Robin CostasUSEPA Central Regional Laboratory839 Bestgate Road •Annapolis, Maryland 21401 ' /
Re: EPA Contract No.: 68-W8-0037EPA Work Assignment: 37-34-3JZZ
•- Keystone Sanitation Landfill SiteEPA Region III DAS Case Number R3247:Shipping Date: August 8, 1996 ,Federal Express Airbill No.: 4405013012 ,
Dear Ms. Costas:
The purpose of this letter is to correct errors on EPA Chain of Custody Form 3-16630 in the abovereferenced shipment. .
1. For Station Number SD-76 (EPA Sample #2470807076) the Station Location wasincorrectly identified as KS-SD-75; the Station Location for this sample is actually KS-SD-76.
\_J 2. For Station Number SD-77 (EPA Sample #2470808077) the time appears to read 0430; thetime was actually 0930 for this sample, as verified in the Field Logbook.
3. For Station Number SW-72D (EPA Sample 02470807WDU) the Station Location wasincorrectly identified as KS-SD-72D; the Station Location for this sample is actuallyKS-SW-72D.
We apologize for any inconvenience these discrepancies may have caused. '
Sincerely, -GANNETT FLEMING, INC. ,
<4**<y ftSidney J. Curran
cc Annette Lage (CRL) •'*•:Christopher Corbett (EPA Region III)Chen Yeh(GF)William Wentworth (HNUS)
« - - • . - '
File: 29529.001/4.0
A Tradition of Excellence Since 1915
AR32I168
