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    OLED DISPLAY AKSHAY RAJESH

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    1.INTRODUCTION

    An OLED (organic light-emitting diode) is a light-emitting diode (LED) in which

    the emissive electroluminescent layer is a film oforganic compound which emits

    light in response to an electric current. This layer oforganic semiconductoris

    situated between two electrodes. Generally, at least one of these electrodes is

    transparent. OLEDs are used to create digital displays in devices such as

    television screens, computer monitors, portable systems such as mobile

    phones, handheld games consoles and PDAs.

    An OLED display consists of very thin sandwiched layers of materials. When an

    electric current is supplied, the negatively charged electrons in the cathode layer

    move through the organic substances towards the positively charged anode

    layer. The reverse happens from the anode's side, as positively charged

    electrons are drawn towards the cathode leaving holes in the conductive

    material. These positively charged holes jump to the organic material to

    recombine with electrons, which causes electroluminescent light. The chemical

    composition of the organic material dictates which colors of light are produced

    Contents.

    FIG.1. Basic OLED diagram

    Organic light emitting diodes (OLEDs) offer great promise in displays of all sizes

    and shapes, and in both commercial and home lighting solutions. OLEDs, or

    organic electro-luminescent (OEL) devices as some call them, are already in use

    as mobile device displays and mobile phone displays. Prototype large screen

    and HD OLED televisions always draw the eye away from any other model

    http://en.wikipedia.org/wiki/Light-emitting_diodehttp://en.wikipedia.org/wiki/Emission_(electromagnetic_radiation)http://en.wikipedia.org/wiki/Electroluminescencehttp://en.wikipedia.org/wiki/Organic_compoundhttp://en.wikipedia.org/wiki/Organic_semiconductorhttp://en.wikipedia.org/wiki/Digital_displayhttp://en.wikipedia.org/wiki/Computer_monitorhttp://en.wikipedia.org/wiki/Mobile_phoneshttp://en.wikipedia.org/wiki/Mobile_phoneshttp://en.wikipedia.org/wiki/Handheld_games_consolehttp://en.wikipedia.org/wiki/Personal_digital_assistanthttp://en.wikipedia.org/wiki/Personal_digital_assistanthttp://en.wikipedia.org/wiki/Handheld_games_consolehttp://en.wikipedia.org/wiki/Mobile_phoneshttp://en.wikipedia.org/wiki/Mobile_phoneshttp://en.wikipedia.org/wiki/Computer_monitorhttp://en.wikipedia.org/wiki/Digital_displayhttp://en.wikipedia.org/wiki/Organic_semiconductorhttp://en.wikipedia.org/wiki/Organic_compoundhttp://en.wikipedia.org/wiki/Electroluminescencehttp://en.wikipedia.org/wiki/Emission_(electromagnetic_radiation)http://en.wikipedia.org/wiki/Light-emitting_diode
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    regardless of its size. In addition OLED technology lends itself to innovative solid-

    state lighting, as well as flexible lighting solutions and flexible displays, even

    displays based on organic TFTs.

    OLED-A provides a forum for the interchange of technical and market

    information. Our membership includes companies involved in small-molecule

    OLED technology and polymer technology (PLED or light-emitting polymers).

    OLED-A serves its membership by fostering the more rapid development of

    OLED technology and OLED products; serving as a resource on OLED markets

    and products for media and investors; functioning as a catalyst in the

    development of standards for OLEDs; and providing a forum to promote and

    market OLED technology products.

    OLEDs are used in television screens, computer monitors, small, portable

    system screens such as mobile phones and PDAs, watches, advertising,

    information, and indication. OLEDs are also used in light sources for space

    illumination and in large-area light-emitting elements. Due to their early stage of

    development, they typically emit less light per unit area than inorganic solid-state

    based LED point-light sources.

    There are two main families of OLEDs: those based on small molecules and

    those employing polymers. Adding mobile ions to an OLED creates a light-emitting electrochemical cell or LEC, which has a slightly different mode of

    operation. OLED displays can use eitherpassive-matrix (PMOLED) oractive-

    matrix addressing schemes. Active-matrix OLEDs (AMOLED) require a thin-film

    transistorbackplane to switch each individual pixel on or off, but allow for higher

    resolution and larger display sizes.

    An OLED display works without a backlight. Thus, it can display deep black

    levels and can be thinner and lighter than a liquid crystal display (LCD). In low

    ambient light conditions such as a dark room an OLED screen can achieve a

    highercontrast ratio than an LCD, whether the LCD uses cold cathodefluorescent lamps orLED backlight.

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    2. HISTORY OF OLED DISPLAY

    FIG.2.Sony XEL-1, the world's first OLED TV.

    The first observations ofelectroluminescence in organic materials were in the

    early 1950s by Andr Bernanose and co-workers at the Nancy-Universit,

    France. They applied high-voltage alternating current (AC) fields in air to

    materials such as acridine orange, either deposited on or dissolved in cellulose

    or cellophane thin films. The proposed mechanism was either direct excitation of

    the dye molecules or excitation of electrons.

    In 1960, Martin Pope and co-workers at New York University developed ohmic

    dark-injecting electrode contacts to organic crystals. They further described the

    necessary energetic requirements (work functions) for hole and electron injecting

    electrode contacts. These contacts are the basis of charge injection in all modern

    OLED devices. Pope's group also first observed direct current (DC)

    electroluminescence under vacuum on a pure single crystal ofanthracene and

    on anthracene crystals doped with tetracene in 1963 using a small area silver

    electrode at 400 V. The proposed mechanism was field-accelerated electron

    excitation of molecular fluorescence.

    Pope's group reported in 1965

    that in the absence of an external electric field, theelectroluminescence in anthracene crystals is caused by the recombination of a

    thermalized electron and hole, and that the conducting level of anthracene is

    higher in energy than the exciton energy level. Also in 1965, W. Helfrich and W.

    G. Schneider of the National Research Council in Canada produced double

    injection recombination electroluminescence for the first time in an anthracene

    single crystal using hole and electron injecting electrodes, the forerunner of

    modern double injection devices. In the same year, Dow Chemical researchers

    http://en.wikipedia.org/wiki/Sony_XEL-1http://en.wikipedia.org/wiki/Electroluminescencehttp://en.wikipedia.org/wiki/Nancy-Universit%C3%A9http://en.wikipedia.org/wiki/Alternating_currenthttp://en.wikipedia.org/wiki/Acridine_orangehttp://en.wikipedia.org/wiki/Martin_Popehttp://en.wikipedia.org/wiki/New_York_Universityhttp://en.wikipedia.org/wiki/Work_functionhttp://en.wikipedia.org/wiki/Anthracenehttp://en.wikipedia.org/wiki/National_Research_Council_(Canada)http://en.wikipedia.org/wiki/Dow_Chemicalhttp://en.wikipedia.org/wiki/File:XEL-1_0.jpghttp://en.wikipedia.org/wiki/Dow_Chemicalhttp://en.wikipedia.org/wiki/National_Research_Council_(Canada)http://en.wikipedia.org/wiki/Anthracenehttp://en.wikipedia.org/wiki/Work_functionhttp://en.wikipedia.org/wiki/New_York_Universityhttp://en.wikipedia.org/wiki/Martin_Popehttp://en.wikipedia.org/wiki/Acridine_orangehttp://en.wikipedia.org/wiki/Alternating_currenthttp://en.wikipedia.org/wiki/Nancy-Universit%C3%A9http://en.wikipedia.org/wiki/Electroluminescencehttp://en.wikipedia.org/wiki/Sony_XEL-1
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    patented a method of preparing electroluminescent cells using high voltage

    (5001500 V) AC-driven (1003000 Hz) electrically insulated one millimetre thin

    layers of a melted phosphor consisting of ground anthracene powder, tetracene,

    and graphite powder. Their proposed mechanism involved electronic excitation at

    the contacts between the graphite particles and the anthracene molecules.

    Device performance was limited by the poor electrical conductivity of

    contemporary organic materials. This was overcome by the discovery and

    development of highly conductive polymers.

    Electroluminescence from polymer films was first observed by Roger Partridge at

    the National Physical Laboratory in the United Kingdom. The device consisted of

    a film of poly(n-vinylcarbazole) up to 2.2 micrometres thick located between two

    charge injecting electrodes. The results of the project were patented in 1975and

    published in 1983.

    The first diode device was reported at Eastman Kodak by Ching W.Tang and Steven Van Slyke in 1987. This device used a novel two-layer

    structure with separate hole transporting and electron transporting layers such

    that recombination and light emission occurred in the middle of the organic layer.

    This resulted in a reduction in operating voltage and improvements in efficiency

    and led to the current era of OLED research and device production.

    Research into polymer electroluminescence culminated in 1990 with J. H.

    Burroughes et al. at the Cavendish Laboratory in Cambridge reporting a highefficiency green light-emitting polymer based device using 100 nm thick films

    ofpoly(p-phenylene vinylene).

    http://en.wikipedia.org/wiki/Tetracenehttp://en.wikipedia.org/wiki/Conductive_polymershttp://en.wikipedia.org/wiki/National_Physical_Laboratory_(United_Kingdom)http://en.wikipedia.org/wiki/N-Vinylcarbazolehttp://en.wikipedia.org/wiki/Ching_W._Tanghttp://en.wikipedia.org/wiki/Ching_W._Tanghttp://en.wikipedia.org/wiki/Steven_Van_Slykehttp://en.wikipedia.org/wiki/Cavendish_Laboratoryhttp://en.wikipedia.org/wiki/Poly(p-phenylene_vinylene)http://en.wikipedia.org/wiki/Poly(p-phenylene_vinylene)http://en.wikipedia.org/wiki/Cavendish_Laboratoryhttp://en.wikipedia.org/wiki/Steven_Van_Slykehttp://en.wikipedia.org/wiki/Ching_W._Tanghttp://en.wikipedia.org/wiki/Ching_W._Tanghttp://en.wikipedia.org/wiki/N-Vinylcarbazolehttp://en.wikipedia.org/wiki/National_Physical_Laboratory_(United_Kingdom)http://en.wikipedia.org/wiki/Conductive_polymershttp://en.wikipedia.org/wiki/Tetracene
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    3. OLED Components

    FIG.3. OLED structure

    Like an LED, an OLED is a solid-state semiconductordevice that is 100 to 500

    nanometers thick or about 200 times smaller than a human hair. OLEDs can

    have either two layers or three layers of organic material; in the latter design, the

    third layer helps transport electrons from the cathode to the emissive layer. In

    this article, we'll be focusing on the two-layer design.

    An OLED consists of the following parts:

    Substrate (clear plastic, glass, foil) - The substrate supports the OLED.

    Anode (transparent) The anode removes electrons (adds electron

    "holes") when a current flows through the device.

    Organic layers - These layers are made of organic molecules or

    polymers.

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    Conducting layer- This layer is made of organic plastic molecules that

    transport "holes" from the anode. One conducting polymer used in OLEDs

    is polyaniline.

    Emissive layer- This layer is made of organic plastic molecules (different

    ones from the conducting layer) that transport electrons from the cathode;

    this is where light is made. One polymer used in the emissive layer is

    polyfluorene.

    Cathode (may or may not be transparent depending on the type of OLED)

    - The cathode injects electrons when a current flows through the device.

    The biggest part of manufacturing OLEDs is applying the organic layers tothe substrate. This can be done in three ways:

    Vacuum deposition orvacuum thermal evaporation (VTE) - In a vacuum

    chamber, the organic molecules are gently heated (evaporated) and allowed to

    condense as thin films onto cooled substrates. This process is expensive and

    inefficient.

    Organic vapor phase deposition (OVPD) - In a low-pressure, hot-walled

    reactor chamber, a carrier gas transports evaporated organic molecules onto

    cooled substrates, where they condense into thin films. Using a carrier gas

    increases the efficiency and reduces the cost of making OLEDs.

    Inkjet printing - With inkjet technology, OLEDs are sprayed onto substrates just

    like inks are sprayed onto paper during printing. Inkjet technology greatly reduces

    the cost of OLED manufacturing and allows OLEDs to be printed onto very largefilms for large displays like 80-inch TV screens or electronic billboards.

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    4. How do OLEDs Emit Light?

    FIG.4. OLED creating light

    OLEDs emit light in a similar manner to LEDs, through a process called

    electrophosphorescence.

    The process is as follows:

    1. The battery or power supply of the device containing the OLED applies a voltage

    across the OLED.

    2. An electrical current flows from the cathode to the anode through the organic

    layers (an electrical current is a flow of electrons). The cathode gives electrons to

    the emissive layer of organic molecules. The anode removes electrons from the

    conductive layer of organic molecules. (This is the equivalent to giving electron

    holes to the conductive layer.)

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    3. At the boundary between the emissive and the conductive layers, electrons find

    electron holes. When an electron finds an electron hole, the electron fills the hole

    (it falls into an energy level of the atom that's missing an electron). When thishappens, the electron gives up energy in the form of a photon of light (see How

    Light Works).

    4. The OLED emits light.

    5. The color of the light depends on the type of organic molecule in the emissive

    layer. Manufacturers place several types of organic films on the same OLED to

    make color displays.

    6. The intensity or brightness of the light depends on the amount of electricalcurrent applied: the more current, the brighter the light.

    5. WORKING OF OLED

    FIG.5.Schematic of a bilayer OLED:

    1. Cathode () 2. Emissive Layer. 3. Emission of radiation.4. Conductive Layer 5. Anode (+).

    A typical OLED is composed of a layer of organic materials situated between two

    electrodes, the anode and cathode, all deposited on a substrate. The organic

    molecules are electrically conductive as a result ofdelocalization ofpi

    electrons caused by conjugation over all or part of the molecule. These materials

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    have conductivity levels ranging from insulators to conductors, and therefore are

    considered organic semiconductors. The highest occupied and lowest

    unoccupied molecular orbitals (HOMO and LUMO) of organic semiconductors

    are analogous to the valence and conduction bands of inorganic semiconductors.

    Originally, the most basic polymer OLEDs consisted of a single organic layer.

    One example was the first light-emitting device synthesized by J. H. Burroughs et

    al., which involved a single layer ofpoly(p-phenylene vinylene). However

    multilayer OLEDs can be fabricated with two or more layers in order to improve

    device efficiency. As well as conductive properties, different materials may be

    chosen to aid charge injection at electrodes by providing a more gradual

    electronic profile, or block a charge from reaching the opposite electrode and

    being wasted. Many modern OLEDs incorporate a simple bilayer structure,

    consisting of a conductive layer and an emissive layer. More recentdevelopments in OLED architecture improves quantum efficiency (up to 19%) by

    using a graded heterojunction. In the graded heterojunction architecture, the

    composition of hole and electron-transport materials varies continuously within

    the emissive layer with a dopant emitter. The graded heterojunction architecture

    combines the benefits of both conventional architectures by improving charge

    injection while simultaneously balancing charge transport within the emissive

    region.

    During operation, a voltage is applied across the OLED such that the anode is

    positive with respect to the cathode. A current ofelectrons flows through thedevice from cathode to anode, as electrons are injected into the LUMO of the

    organic layer at the cathode and withdrawn from the HOMO at the anode. This

    latter process may also be described as the injection ofelectron holes into the

    HOMO. Electrostatic forces bring the electrons and the holes towards each other

    and they recombine forming an exciton, a bound state of the electron and hole.

    This happens closer to the emissive layer, because in organic semiconductors

    holes are generally more mobile than electrons. The decay of this excited state

    results in a relaxation of the energy levels of the electron, accompanied by

    emission ofradiation whose frequency is in the visible region. The frequency of

    this radiation depends on the band gap of the material, in this case the differencein energy between the HOMO and LUMO.

    As electrons and holes are fermions with half integerspin, an exciton may either

    be in a singlet state or a triplet state depending on how the spins of the electron

    and hole have been combined. Statistically three triplet excitons will be formed

    for each singlet exciton. Decay from triplet states (phosphorescence) is spin

    forbidden, increasing the timescale of the transition and limiting the internal

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    efficiency of fluorescent devices. Phosphorescent organic light-emitting

    diodes make use ofspinorbit interactions to facilitate intersystem

    crossing between singlet and triplet states, thus obtaining emission from both

    singlet and triplet states and improving the internal efficiency.

    Indium tin oxide (ITO) is commonly used as the anode material. It is transparent

    to visible light and has a high work function which promotes injection of holes into

    the HOMO level of the organic layer. A typical conductive layer may consist

    ofPEDOT:PSSas the HOMO level of this material generally lies between the

    workfunction of ITO and the HOMO of other commonly used polymers, reducing

    the energy barriers for hole injection. Metals such as barium and calcium are

    often used for the cathode as they have low work functionswhich promote

    injection of electrons into the LUMO of the organic layer. Such metals are reactive, so

    they require a capping layer ofaluminium to avoid degradation.

    Single carrier devices are typically used to study the kinetics and charge

    transport mechanisms of an organic material and can be useful when trying to

    study energy transfer processes. As current through the device is composed of

    only one type of charge carrier, either electrons or holes, recombination does not

    occur and no light is emitted. For example, electron only devices can be obtained

    by replacing ITO with a lower work function metal which increases the energy

    barrier of hole injection. Similarly, hole only devices can be made by using a

    cathode comprised solely of aluminium, resulting in an energy barrier too large

    for efficient electron injection.

    6.TYPES OF OLED

    6.1.Classification according to Organic Material used

    http://en.wikipedia.org/wiki/Phosphorescent_organic_light-emitting_diodehttp://en.wikipedia.org/wiki/Phosphorescent_organic_light-emitting_diodehttp://en.wikipedia.org/wiki/Spin%E2%80%93orbit_interactionhttp://en.wikipedia.org/wiki/Spin%E2%80%93orbit_interactionhttp://en.wikipedia.org/wiki/Spin%E2%80%93orbit_interactionhttp://en.wikipedia.org/wiki/Intersystem_crossinghttp://en.wikipedia.org/wiki/Intersystem_crossinghttp://en.wikipedia.org/wiki/Indium_tin_oxidehttp://en.wikipedia.org/wiki/Work_functionhttp://en.wikipedia.org/wiki/PEDOT:PSShttp://en.wikipedia.org/wiki/PEDOT:PSShttp://en.wikipedia.org/wiki/Bariumhttp://en.wikipedia.org/wiki/Calciumhttp://en.wikipedia.org/wiki/Work_functionhttp://en.wikipedia.org/wiki/Aluminiumhttp://en.wikipedia.org/wiki/Chemical_kineticshttp://en.wikipedia.org/wiki/Chemical_kineticshttp://en.wikipedia.org/wiki/Aluminiumhttp://en.wikipedia.org/wiki/Work_functionhttp://en.wikipedia.org/wiki/Calciumhttp://en.wikipedia.org/wiki/Bariumhttp://en.wikipedia.org/wiki/PEDOT:PSShttp://en.wikipedia.org/wiki/Work_functionhttp://en.wikipedia.org/wiki/Indium_tin_oxidehttp://en.wikipedia.org/wiki/Intersystem_crossinghttp://en.wikipedia.org/wiki/Intersystem_crossinghttp://en.wikipedia.org/wiki/Spin%E2%80%93orbit_interactionhttp://en.wikipedia.org/wiki/Phosphorescent_organic_light-emitting_diodehttp://en.wikipedia.org/wiki/Phosphorescent_organic_light-emitting_diode
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    Small molecules

    FIG.6. structure ofAlq3

    Efficient OLEDs using small molecules were first developed by Dr. Ching W.

    Tang et al. at Eastman Kodak. The term OLED traditionally refers specifically to

    this type of device, though the term SM-OLED is also in use.

    Molecules commonly used in OLEDs include organometallic chelates (for

    example Alq3, used in the organic light-emitting device reported by Tang et al.),fluorescent and phosphorescent dyes and conjugated dendrimers. A number of

    materials are used for their charge transport properties, for

    example triphenylamine and derivatives are commonly used as materials for hole

    transport layers. Fluorescent dyes can be chosen to obtain light emission at

    different wavelengths, and compounds such

    as perylene, rubrene and quinacridone derivatives are often used.[30]Alq3 has

    been used as a green emitter, electron transport material and as a host for yellow

    and red emitting dyes.

    The production of small molecule devices and displays usually involves thermalevaporation in a vacuum. This makes the production process more expensive

    and of limited use for large-area devices than other processing techniques.

    However, contrary to polymer-based devices, the vacuum deposition process

    enables the formation of well controlled, homogeneous films, and the

    construction of very complex multi-layer structures. This high flexibility in layer

    design, enabling distinct charge transport and charge blocking layers to be

    formed, is the main reason for the high efficiencies of the small molecule OLEDs.

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    Coherent emission from a laser dye-doped tandem SM-OLED device, excited in

    the pulsed regime, has been demonstrated. The emission is nearly diffraction

    limited with a spectral width similar to that of broadband dye lasers.

    Polymer light-emitting diodes

    FIG.7. poly(p-phenylene vinylene

    Polymer light-emitting diodes (PLED), also light-emitting polymers (LEP), involve

    an electroluminescent conductive polymerthat emits light when connected to an

    external voltage. They are used as a thin film forfull-spectrum colour displays.

    Polymer OLEDs are quite efficient and require a relatively small amount of power

    for the amount of light produced.

    Vacuum deposition is not a suitable method for forming thin films of polymers.

    However, polymers can be processed in solution, and spin coatingis a common

    method of depositing thin polymer films. This method is more suited to forming

    large-area films than thermal evaporation. No vacuum is required, and the

    emissive materials can also be applied on the substrate by a technique derived

    from commercial inkjet printing. However, as the application of subsequent layers

    tends to dissolve those already present, formation of multilayer structures is

    difficult with these methods. The metal cathode may still need to be deposited by

    thermal evaporation in vacuum. An alternative method to vacuum deposition is to

    deposit a Langmuir-Blodgett film.

    Typical polymers used in PLED displays include derivatives ofpoly(p-phenylene

    vinylene) and polyfluorene. Substitution of side chains onto the polymer

    backbone may determine the colour of emitted light or the stability and solubility

    of the polymer for performance and ease of processing.

    http://en.wikipedia.org/wiki/Poly(p-phenylene_vinylene)http://en.wikipedia.org/wiki/Poly(p-phenylene_vinylene)http://en.wikipedia.org/wiki/Poly(p-phenylene_vinylene)http://en.wikipedia.org/wiki/Electroluminescencehttp://en.wikipedia.org/wiki/Conductive_polymerhttp://en.wikipedia.org/wiki/Lighthttp://en.wikipedia.org/wiki/Thin_filmhttp://en.wikipedia.org/wiki/Full-spectrumhttp://en.wikipedia.org/wiki/Spin_coatinghttp://en.wikipedia.org/wiki/Substrate_(printing)http://en.wikipedia.org/wiki/Inkjet_printerhttp://en.wikipedia.org/wiki/Langmuir-Blodgett_filmhttp://en.wikipedia.org/wiki/Poly(p-phenylene_vinylene)http://en.wikipedia.org/wiki/Poly(p-phenylene_vinylene)http://en.wikipedia.org/wiki/Poly(p-phenylene_vinylene)http://en.wikipedia.org/wiki/Poly(p-phenylene_vinylene)http://en.wikipedia.org/wiki/Polyfluorenehttp://en.wikipedia.org/wiki/Substitution_reactionhttp://en.wikipedia.org/wiki/Substitution_reactionhttp://en.wikipedia.org/wiki/Polyfluorenehttp://en.wikipedia.org/wiki/Poly(p-phenylene_vinylene)http://en.wikipedia.org/wiki/Poly(p-phenylene_vinylene)http://en.wikipedia.org/wiki/Langmuir-Blodgett_filmhttp://en.wikipedia.org/wiki/Inkjet_printerhttp://en.wikipedia.org/wiki/Substrate_(printing)http://en.wikipedia.org/wiki/Spin_coatinghttp://en.wikipedia.org/wiki/Full-spectrumhttp://en.wikipedia.org/wiki/Thin_filmhttp://en.wikipedia.org/wiki/Lighthttp://en.wikipedia.org/wiki/Conductive_polymerhttp://en.wikipedia.org/wiki/Electroluminescencehttp://en.wikipedia.org/wiki/Poly(p-phenylene_vinylene)
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    While unsubstituted poly(p-phenylene vinylene) (PPV) is typically insoluble, a

    number of PPVs and related poly(naphthalene vinylene)s (PNVs) that are soluble

    in organic solvents or water have been prepared via ring opening metathesis

    polymerization.

    Phosphorescent materials

    FIG.8. Ir(mppy)3, a phosphorescent dopant which emits green light.

    Phosphorescent organic light emitting diodes use the principle of

    electrophosphorescence to convert electrical energy in an OLED into light in a

    highly efficient manner, with the internal quantum efficiencies of such devices

    approaching 100%.

    Typically, a polymer such as poly(n-vinylcarbazole) is used as a host material to

    which an organometallic complex is added as a dopant. Iridium complexessuch

    as Ir(mppy)3are currently the focus of research, although complexes based on

    other heavy metals such as platinumhave also been used.

    The heavy metal atom at the centre of these complexes exhibits strong spin-orbit

    coupling, facilitating intersystem crossing between singlet andtriplet states. By

    using these phosphorescent materials, both singlet and triplet excitons will be

    able to decay radiatively, hence improving the internal quantum efficiency of the

    device compared to a standard PLED where only the singlet states will contribute

    to emission of light.

    Applications of OLEDs in solid state lighting require the achievement of high

    brightness with good CIE coordinates (for white emission). The use of

    macromolecular species like polyhedral oligomeric silsesquioxanes (POSS) in

    conjunction with the use of phosphorescent species such as Ir for printed OLEDs

    have exhibited brightnesses as high as 10,000 cd/m2.

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    6.2.Classification according to Transparency Transparent OLED

    FIG.9. OLED transparent structure

    Transparent OLEDs have only transparent components (substrate, cathode and

    anode) and, when turned off, are up to 85 percent as transparent as their

    substrate. When a transparent OLED display is turned on, it allows light to pass

    in both directions. A transparent OLED display can be either active- or passive-matrix. This technology can be used for heads-up displays.

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    Top-emitting OLED

    FIG.10. OLED Top-Emitting Structure

    Top-emitting OLEDs have a substrate that is either opaque or reflective. Theyare best suited to active-matrix design. Manufacturers may use top-emitting

    OLED displays insmart cards

    6.3.Foldable OLED

    FIG.11. Demonstration of a flexible OLED device

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    Foldable OLEDs have substrates made of very flexible metallic foils or plastics.

    Foldable OLEDs are very lightweight and durable. Their use in devices such as

    cell phones and PDAs can reduce breakage, a major cause for return or repair.Potentially, foldable OLED displays can be attached to fabrics to create "smart"

    clothing, such as outdoor survival clothing with an integrated computer chip, cell

    phone, GPS receiver and OLED display sewn into it

    6.4.CLASSIFICATION ACCORDING TO PIXELFORMATION USED

    Passive-matrix OLED (PMOLED)

    FIG.12. Passive-matrix OLED

    PMOLED means Passive Matrix Organic light emitting diode. Like the first LCDsto be commercialized, the first OLEDs to reach the marketplace in the late 1990sused a passivematrix drive configuration. Passive-matrix OLEDs are particularlywell suited for small-area display applications, such as cell phones and

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    automotive audio applications. Universal Display Corporations PHOLEDmaterials and technology are currently incorporated in a commercial passive-matrix OLED display product that is manufactured and sold by Pioneer Tohoku

    Corporation for use in a cell phone product (shown above) and under evaluationfor a number of other products. Universal Display Corporation has designed andfabricated several passive matrix OLED prototypes to demonstrate theperformance of its PHOLED technology and materials. The prototype shown hereis a 128 x 64 pixel display built on a glass substrate using our green and redPHOLED materials system.

    OLED displays are activated through a current driving method that relies on

    either a passive-matrix (PM) or an active-matrix (AM) scheme. In a PMOLEDdisplay, a matrix of electrically-conducting rows and columns forms a two-dimensional array of picture elements called pixels. Sandwiched between theorthogonal column and row lines, thin films of organic material are activated toemit light by applying electrical signals to designated row and column lines. Themore current that is applied, the brighter the pixel becomes. For a full image,each row of the display must be charged for 1/N of the frame time needed toscan the entire display, where N is the number of rows in the display. Forexample, to achieve a 100-row display image with brightness of 100 nits, thepixels must be driven to the equivalent of an instantaneous brightness of 10,000nits for 1/100 of the entire frame time.

    While PMOLEDs are fairly simple structures to design and fabricate, theydemand relatively expensive, current-sourced drive electronics to operateeffectively. In addition, their power consumption is significantly higher than thatrequired by a continuous charge mode in an active-matrix OLED. WhenPMOLEDs are pulsed with very high drive currents over a short duty cycle, theydo not typically operate at their intrinsic peak efficiency. These inefficienciescome from the characteristics of the diode itself, as well as power losses in the

    row lines. Power analyses have shown that PMOLED displays are most practicalin sizes smaller than 2 to 3 in diagonal, or having less than approx imately 100row lines. PMOLEDs make great sense for many such display applications,including cell phones, MP3 players and portable games.

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    Active-matrix OLED (AMOLED)

    FIG.13. Active-matrix OLED

    Active-matrix OLED displays provide the same beautiful video-rate performanceas their passive-matrix OLED counterparts, but they consume significantly lesspower. This advantage makes active-matrix OLEDs especially well suited forportable electronics where battery power consumption is critical and for displaysthat are larger than 2 to 3 in diagonal, as shown in this ultra -thin Sony prototypeabove.

    An active-matrix OLED (AMOLED) display consists of OLED pixels that havebeen deposited or integrated onto a thin film transistor (TFT) array to form amatrix of pixels that illuminate light upon electrical activation. In contrast to aPMOLED display, where electricity is distributed row by row, the active-matrixTFT backplane acts as an array of switches that control the amount of currentflowing through each OLED pixel. The TFT array continuously controls thecurrent that flows to the pixels, signaling to each pixel how brightly to shine.Typically, this continuous current flow is controlled by at least two TFTs at eachpixel, one to start and stop the charging of a storage capacitor and the second toprovide a voltage source at the level needed to create a constant current to the

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    pixel. As a result, the AMOLED operates at all times (i.e., for the entire framescan), avoiding the need for the very high currents required for passive matrixoperation.

    Stacked OLEDs

    Stacked OLEDs use a pixel architecture that stacks the red, green, and blue

    subpixels on top of one another instead of next to one another, leading to

    substantial increase ingamut and color depth, and greatly reducing pixel gap.

    Currently, other display technologies have the RGB (and RGBW) pixels mappednext to each other decreasing potential resolution.

    Inverted OLED

    In contrast to a conventional OLED, in which the anode is placed on the

    substrate, an Inverted OLED uses a bottom cathode that can be connected to the

    drain end of an n-channel TFT especially for the low cost amorphous silicon TFT

    backplane useful in the manufacturing ofAMOLED displays..

    6.5.White OLED

    White OLEDs emit white light that is brighter, more uniform and more energy

    efficient than that emitted by fluorescent lights. White OLEDs also have the true-

    color qualities ofincandescent lighting. Because OLEDs can be made in large

    sheets, they can replace fluorescent lights that are currently used in homes and

    buildings. Their use could potentially reduce energy costs for lighting.

    In the next section, we'll discuss the pros and cons of OLED technology and how

    it compares to regular LED and LCD technology.

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    7.ADVANTAGES

    IMPROVED BRIGHTNESS

    It has a higher contrast ratio or improved brightness than TFT or LCD

    display under all the environment conditions.

    Condition OLED TFT-

    LCD

    Dark room > 10,000

    : 1 300 : 1

    Rainy 400 130

    Cloudy 190 10

    Sunlight 50 4

    Light weight & flexible plastic substrates

    OLED displays can be fabricated on flexible plastic substrates leading to

    the possibility offlexible organic light-emitting diodes being fabricated or

    other new applications such as roll-up displays embedded in fabrics or

    clothing. As the substrate used can be flexible such as PET, the displays

    may be produced inexpensively.

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    Wider viewing angles & improved brightness

    FIG.14. Comparision between viewing angle of OLED and LCD

    OLEDs can enable a greater artificial contrast ratio (both dynamic range

    and static, measured in purely dark conditions) and viewing anglecompared to LCDs because OLED pixels directly emit light. OLED pixel

    colours appear correct and unshifted, even as the viewing angle

    approaches 90 from normal.

    Better power efficiency

    LCDs filter the light emitted from a backlight, allowing a small fraction of

    light through so they cannot show true black, while an inactive OLEDelement does not produce light or consume power.

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    Response time

    FIG.15. response graph of OLED and TFT display

    OLEDs can also have a faster response time than standard LCD screens.

    Whereas LCD displays are capable of between 2 and 16 ms response

    time offering a refresh rate of 60 to 480 Hz, an OLED can theoretically

    have less than 0.01 ms response time, enabling up to 100,000 Hz refresh

    rate.

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    8.DISADVANTAGES

    Current costs

    OLED manufacture currently requires process steps that make it

    extremely expensive. Specifically, it requires the use of Low-Temperature

    Polysilicon backplanes; LTPS backplanes in turn require laser annealing

    from an amorphous silicon start, so this part of the manufacturing processfor AMOLEDs starts with the process costs of standard LCD, and then

    adds an expensive, time-consuming process that cannot currently be used

    on large-area glass substrates.

    Lifespan

    The biggest technical problem for OLEDs was the limited lifetime of the

    organic materials. In particular, blue OLEDs historically have had a lifetime

    of around 14,000 hours to half original brightness (five years at 8 hours aday) when used for flat-panel displays. This is lower than the typical

    lifetime of LCD, LED orPDP technologyeach currently rated for about

    25,00040,000 hours to half brightness, depending on manufacturer and

    model. However, some manufacturers' displays aim to increase the

    lifespan of OLED displays, pushing their expected life past that of LCD

    displays by improving light outcoupling, thus achieving the same

    brightness at a lower drive current. In 2007, experimental OLEDs were

    created which can sustain 400 cd/m2 ofluminance for over 198,000 hours

    for green OLEDs and 62,000 hours for blue OLEDs.

    Color balance issues

    Additionally, as the OLED material used to produce blue light degrades

    significantly more rapidly than the materials that produce other colors, blue

    light output will decrease relative to the other colors of light. This variation

    in the differential color output will change the color balance of the display

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    and is much more noticeable than a decrease in overall luminance. This

    can be partially avoided by adjusting colour balance but this may require

    advanced control circuits and interaction with the user, which is

    unacceptable for some users.More commonly, though, manufacturers

    optimize the size of the R, G and B subpixels to reduce the current density

    through the subpixel in order to equalize lifetime at full luminance. For

    example, a blue subpixel may be 100% larger than the green subpixel.

    The red subpixel may be 10% smaller than the green.

    Efficiency of blue OLEDs

    Improvements to the efficiency and lifetime of blue OLEDs is vital to the

    success of OLEDs as replacements for LCD technology. Considerableresearch has been invested in developing blue OLEDs with high external

    quantum efficiency as well as a deeper blue color. External quantum

    efficiency values of 20% and 19% have been reported for red (625 nm)

    and green (530 nm) diodes, respectively. However, blue diodes (430 nm)

    have only been able to achieve maximum external quantum efficiencies in

    the range of 4% to 6%.

    Water damage

    Water can damage the organic materials of the displays. Therefore,

    improved sealing processes are important for practical manufacturing.

    Water damage may especially limit the longevity of more flexible displays.

    Outdoor performance

    As an emissive display technology, OLEDs rely completely upon

    converting electricity to light, unlike most LCDs which are to some extent

    reflective; e-ink leads the way in efficiency with ~ 33% ambient light

    reflectivity, enabling the display to be used without any internal light

    source. The metallic cathode in an OLED acts as a mirror, with reflectance

    approaching 80%, leading to poor readability in bright ambient light such

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    as outdoors. However, with the proper application of a circular polarizer

    and anti-reflective coatings, the diffuse reflectance can be reduced to less

    than 0.1%. With 10,000fcincident illumination (typical test condition for

    simulating outdoor illumination), that yields an approximate photopic

    contrast of 5:1.

    Power consumption

    While an OLED will consume around 40% of the power of an LCD

    displaying an image which is primarily black, for the majority of images it

    will consume 6080% of the power of an LCD: however it can use over

    three times as much power to display an image with a white background

    such as a document or website.This can lead to reduced real-worldbattery life in mobile devices when white backgrounds are used

    9.ORGANIC LED AND LIQUID CRYSTAL DISPLAY

    COMPARISON

    An organic LED panel Liquid crystal Panel

    A luminous form Self emission of light Back light or outside light is

    necessary

    Consumption of Electric power It is lowered to about

    mW though it is a little

    higher than the

    reflection type liquid

    crystal panel

    It is abundant when back light

    is used

    Colour Indication form The flourscent material

    of RGB is arranged in

    order and or a colour

    filter is used.

    A colour filter is used.

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    High brightness 100 cd/m2 6 cd/m2

    The dimension of the panel Several-inches type in

    the future to about 10-

    inch type.Goal

    It is produced to 28-inch type in

    the future to 30-inch type.Goal

    Contrast 100:14 6:1

    The thickness of the panel It is thin with a little

    over 1mm

    When back light is used it is

    thick with 5mm.

    The mass of panel It becomes light weight

    more than 1gm more

    than the liquid crystal

    With the one for the portable

    telephone.10 gm weak degree.

    Answer time Several us Several ns

    A wide use of temperature

    range

    86 *C ~ -40 *C ~ -10 *C

    The corner of the view Horizontal 180 * Horizontal 120* ~ 170*

    10.APPLICATIONS OF OLED DISPLAY

    10.1.Manufacturers and commercial uses

    FIG.16. A 3.8 cm (1.5 in) OLED display from a Creative ZEN V media player

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    OLED technology is used in commercial applications such as displays for mobile

    phones and portable digital media players, car radios and digital camerasamong

    others. Such portable applications favor the high light output of OLEDs forreadability in sunlight and their low power drain. Portable displays are also used

    intermittently, so the lower lifespan of organic displays is less of an issue.

    Prototypes have been made of flexible and rollable displays which use OLEDs'

    unique characteristics. Applications in flexible signs and lighting are also being

    developed. Philips Lighting have made OLED lighting samples under the brand

    name 'Lumiblade' available online.

    FIG.17.DELL MOBILES

    FIG.18.LAPTOP WITH OLED DISPLAY

    OLEDs have been used in most Motorola and Samsung colour cell phones, as

    well as some HTC, LG and Sony Ericsson models. Nokia has also recently

    introduced some OLED products including the N85 and the N86 8MP, both of

    which feature an AMOLED display. OLED technology can also be found in digital

    media players such as the Creative ZEN V, the iriver clix, the Zune HD and the

    Sony Walkman X Series.

    http://en.wikipedia.org/wiki/Digital_media_playerhttp://en.wikipedia.org/wiki/Digital_camerahttp://en.wikipedia.org/wiki/Philipshttp://en.wikipedia.org/wiki/Motorolahttp://en.wikipedia.org/wiki/Samsunghttp://en.wikipedia.org/wiki/HTC_Corporationhttp://en.wikipedia.org/wiki/LGhttp://en.wikipedia.org/wiki/Sony_Ericssonhttp://en.wikipedia.org/wiki/Nokiahttp://en.wikipedia.org/wiki/Nokia_N85http://en.wikipedia.org/wiki/Nokia_N86_8MPhttp://en.wikipedia.org/wiki/AMOLEDhttp://en.wikipedia.org/wiki/ZEN_Vhttp://en.wikipedia.org/wiki/Iriver_clixhttp://en.wikipedia.org/wiki/Zune_HDhttp://en.wikipedia.org/wiki/Walkman_X_Serieshttp://en.wikipedia.org/wiki/Walkman_X_Serieshttp://en.wikipedia.org/wiki/Zune_HDhttp://en.wikipedia.org/wiki/Iriver_clixhttp://en.wikipedia.org/wiki/ZEN_Vhttp://en.wikipedia.org/wiki/AMOLEDhttp://en.wikipedia.org/wiki/Nokia_N86_8MPhttp://en.wikipedia.org/wiki/Nokia_N85http://en.wikipedia.org/wiki/Nokiahttp://en.wikipedia.org/wiki/Sony_Ericssonhttp://en.wikipedia.org/wiki/LGhttp://en.wikipedia.org/wiki/HTC_Corporationhttp://en.wikipedia.org/wiki/Samsunghttp://en.wikipedia.org/wiki/Motorolahttp://en.wikipedia.org/wiki/Philipshttp://en.wikipedia.org/wiki/Digital_camerahttp://en.wikipedia.org/wiki/Digital_media_player
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    The Google and HTC Nexus One Smartphone includes an AMOLED screen, as

    does HTC's own Desire and Legend phones. However due to supply shortages

    of the Samsung-produced displays, certain HTC models will useSony's SLCD displays in the future, while the Google and Samsung Nexus

    S Smartphone will use "Super Clear LCD" instead in some countries.

    Other manufacturers of OLED panels include Anwell Technologies Limited,Chi

    Mei Corporation, LG, and others.

    FIG.19.SAMSUNG OLED TV

    DuPont stated in a press release in May 2010 that they can produce a 50-inch

    OLED TV in two minutes with a new printing technology. If this can be scaled up

    in terms of manufacturing, then the total cost of OLED TVs would be greatly

    reduced. Dupont also states that OLED TVs made with this less expensive

    technology can last up to 15 years if left on for a normal eight hour day.

    10.2. Military Application

    FIG.20.THE NEAR EYE MICRODISPLAY

    http://en.wikipedia.org/wiki/Googlehttp://en.wikipedia.org/wiki/Nexus_Onehttp://en.wikipedia.org/wiki/AMOLEDhttp://en.wikipedia.org/wiki/HTC_Desirehttp://en.wikipedia.org/wiki/HTC_Legendhttp://en.wikipedia.org/wiki/S-LCDhttp://en.wikipedia.org/wiki/Nexus_Shttp://en.wikipedia.org/wiki/Nexus_Shttp://en.wikipedia.org/wiki/Anwell_Technologies_Limitedhttp://en.wikipedia.org/wiki/Chi_Mei_Corporationhttp://en.wikipedia.org/wiki/Chi_Mei_Corporationhttp://en.wikipedia.org/wiki/LGhttp://en.wikipedia.org/wiki/DuPonthttp://en.wikipedia.org/wiki/DuPonthttp://en.wikipedia.org/wiki/LGhttp://en.wikipedia.org/wiki/Chi_Mei_Corporationhttp://en.wikipedia.org/wiki/Chi_Mei_Corporationhttp://en.wikipedia.org/wiki/Anwell_Technologies_Limitedhttp://en.wikipedia.org/wiki/Nexus_Shttp://en.wikipedia.org/wiki/Nexus_Shttp://en.wikipedia.org/wiki/S-LCDhttp://en.wikipedia.org/wiki/HTC_Legendhttp://en.wikipedia.org/wiki/HTC_Desirehttp://en.wikipedia.org/wiki/AMOLEDhttp://en.wikipedia.org/wiki/Nexus_Onehttp://en.wikipedia.org/wiki/Google
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    Low-power Organic Light Emitting Diode (OLED) displays are used in a growing

    numbers of applications supporting dismounted soldiers and commanders in

    situational awareness, thermal imaging, simulation and training. Two types ofOLED applications are currently under various phases of maturation the near-

    eye microdisplays, developed by eMagin and Flexible OLED developed by

    Universal Display Corp. (UDC).

    OLED technology promises to revolutionize everything known about information

    display, from video walls, to dynamic pricing in supermarkets. For the military,

    Top-emitting OLED (TOLED) applications could include wrist-mounted,

    featherweight, rugged PDAs and wearable electronic displays such as "display

    sleeves" Other applications could be conformed, high-contrast automotive

    instrument panels, windshield displays and visor mounted displays to be used byfor pilots, drivers and divers, etc. More futuristic applications could be utilized in

    camouflage systems, "smart" light emitting windows/shades etc.

    Until 2005, OLEDs were used primarily for testing. Yet, in 2004 and mostly by

    2005, this technology is being integrated in more military systems and on the

    long run is expected to replace most small form-factor LCD displays. Among the

    applications where OLED technology is already maturing are near-eye displays

    of virtual images When projected on a head mounted, helmet mounted or visor

    (see-through) display, such image appears like an image in a movie theater or on

    a computer monitor, but is created using magnifying optics from a very small

    display near to the eye. Such an image displayed with very high resolution, canappear solid and real, or made see-through depending on the type optics used.

    Military and industrial customers are moving from the testing and evaluation

    phase into deployment. According to Kenneth Geyer, vice president of

    development at Liteye Systems Inc, the company has ordered OLEDs in

    production quantities, to supply orders received from military users in the USA,

    Europe and Australia. Several systems have also been deployed to war fighters

    in Iraq. "We anticipate additional programs moving into deployment phases in

    2006 - 2007" said Geyer. Other users of OLED displays include SaabTech,

    integrating eMagin's OLED into the prototype

    Soldier.

    http://defense-update.com/features/du-3-05/feature-OLED-4.htmhttp://defense-update.com/features/du-3-05/feature-OLED-4.htm
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    10.3. Application of OLED Module in Intelligent Traffic

    Control System

    OLED display module was used as a man-machine interface in the traffic signal

    system. In this design, the OLED display realizes the 12864 pixels of picture

    and character monochrome display with 16 gray-scales. The intelligent traffic

    signal system with OLED display not only can provide good man-machine

    interface, and adapt to the harsh outdoor environment, but also can achieve

    multi-phase and multi-time control of traffic flow. The intelligent traffic signal

    system with OLED display uses the ARM9 as processor, so a scientific algorithm

    can be embedded in it to carry out effective control of traffic flow.

    10.4. As a source of light

    FIG.21. Source of Lighting That Evenly Illuminates Wide Surface Areas

    Until now, spaces have been illuminated by point or linear light sources, such as

    incandescent light bulbs and fluorescent lamps. OLED lighting, in contrast, has

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    characteristics not found in conventional lighting, emitting a uniform light from the

    whole surface, over a large area. Moreover, OLED lighting closely resembles

    natural light. Not only that, it does not include ultraviolet rays, which reducesnegative impact on the eye.

    10.5. PORTABLE DEVICES DISPLAY

    FIG.22.Lightweight, Thin, Flexible OLED Lighting Has Multiple Potential

    Applications

    With OLED lighting, the light source itself illuminates a wide area evenly. This

    makes it possible to have an entire ceiling or wall serve as an illumination device.

    Moreover, if plastic film is used for the substrate base, then flexibly curved

    lighting becomes a real possibility in the future. OLED lighting offers greater

    potential for applications, including revolutionary design of indoor lighting and

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    new applications in interior spaces, illumination inside vehicles and aircraft, novel

    monuments and artworks, and other exciting lighting options .

    11. CONCLUSION

    From above discussion we conclude that it is a field of rapid development in near

    future. With the development in various technology this not only reduce the price

    but also improve the quality of the display screen As it use organic chemicalwhich found in abundance , it reduce the problem of pollution . Organic molecule

    and polymer have short life span, also they are bio degradable.

    Organic light emitting diode will also improve the efficiency of the electronic

    screen. It has more efficient than the LCD, LED and CRT. It has more brightness

    and contrast ratio as compare with other type of screen. In future we not only

    use this in screen technology but also use as illumination, it will replace LED,

    bulb, CFL completely because of the inexpensive device and greater efficiency.

    It will also open the exciting field of flexible screen which find even more use in

    the near future. The screen which can foldable will find great use in TV,

    wallpaper display, advertizing board etc. Also military use of this technology

    will find it attractive.

    But from the current technology OLED find several hurdle in its path such as

    high cost of production, short life span of the organic compound , fading effect ,

    low brightness ratio and differential power consumption for different colures etc

    .

    With the development of the technology the problems in field of the organic light

    emitting diode will be resolve and. OLED will find greater use in near future .

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    12. REFERENCE

    http://impnerd.com/the-history-and-future-of-oled

    http://www.oled-research.com/oleds/oleds-history.html

    http://www.voidspace.org.uk/technology/top_ten_phone_techs.shtml#keep

    -your-eye-on-flexible-displays-coming-soon

    http://www.cepro.com/article/study_future_bright_for_oled_lighting_market

    /

    http://www.technologyreview.com/energy/21116/page1/

    http://optics.org/cws/article/industry/37032

    http://jalopnik.com/5154953/samsung-transparent-oled-display-pitched-as-

    automotive-hud

    en.wikipedia.org