Ally Lewis, University of York, U.K

Data from Katie Read, Jim Hopkins, Jacqui Hamilton.

NMHCs, & DMS measurements by GC-FID

Remote automated NMHC, - simple robust instrument.

Addition of OVOC measurements 2 columns / detectors

CASLab, British Antarctic Survey Halley Base, AntarcticaYear round NMHC 2005 Jan-Mar O3 / HOx experimentLong term NMHC measurements: Halley Antarctic

Seasonal distribution of alkanes at Halley, Antarctica

From previous work the seasonal trend should follow a sinusoidal oscillation1,2,3, this work showed a deviation in early Spring, particularly for ethane. OH chemistry is not thought to be significant at this time. Could potentially be an influence of Cl chemistry over this period?

1Sharma, U. K., Y. Kajii, et al. (2000). "Seasonal variation of C2-C6 NMHCs at Happo, a remote site in Japan." Atmos. Env. 34: 447-4458.2Swanson, A. L., N. Blake, et al. (2003). "Seasonal variations of C1-C4 nonmethane hydrocarbons and C1-C4 alkyl nitrates at the Summit research station in Greenland." J. Geophys. Res 108(D2): 4065, doi:10.1029/2001JD001445.3Clarkson, T. S., R. J. Martin, et al. (1997). "Ethane and propane in the southern marine troposphere." Atmos. Environ. 31(22): 3763-3771.DeviationOH dependence of ethane and propane concentrations

Used the behaviour of NMHC and Cl kinetics to determine the [Cl] (and [Br] during periods of ozone depletion1

[RH]LO = [RH]BKG exp(-kCl[Cl]dt)

A plot of ln([RH]LO/[RH]BKG should give a linear relationship with a gradient equal to -[Cl]dt. So by integrating over set time periods we can obtain [Cl]. [Br] can also be calculated from the additional ethene and acetylene removal.

[-kBr [Br]dt =ln([C2H2]LO/[C2H2]BKG)observed-ln([C2H2]LO/[C2H2]BKG)Clatom

For this depletion period this analysis gives a [Cl] of between 1.7 x 103 and 3.4 x 104 atom cm-3 and a [Br] of between 1.4 x 106 to 2.9 x 107 atom cm-3 . 1Jobson, B. T., H. Niki, et al. (1994). "Measurements of C2-C6 hydrocarbons during the Polar Sunrise 1992 Experiment: Evidence for Cl atom and Br atom chemistry." J. Geophys. Res 99(D12): 25355-25368.Halogen atom presence during NMHC and O3 depletion episodes

black carbon

Excel datevalueBC/ng m^-3

27/02/0430.1667

27/02/0429.432

27/02/048.775

27/02/044.48696

27/02/049.908

28/02/049.08333

28/02/040.143478

28/02/040.092

28/02/042.3375

28/02/043.11304

28/02/046.172

28/02/045.20417

28/02/043.5087

28/02/046.592

28/02/043.70417

28/02/046.95218

28/02/040.84

29/02/043.28333

29/02/048.83043

29/02/047.624

29/02/043.6875

29/02/041.89565

29/02/04-0.8

29/02/048.42083

29/02/049.53043

29/02/04-9.392

29/02/045.83333

29/02/042.32174

29/02/0413.228

01/03/04-5.125

01/03/047.44783

01/03/0410.26

01/03/04-0.629167

01/03/045.81739

01/03/048.256

01/03/04-2.42083

01/03/043.4913

01/03/040.824

01/03/040.504167

01/03/04-4.65217

01/03/04-11.952

02/03/047.5875

02/03/040.486956

02/03/041.176

02/03/040.725

02/03/042.54348

02/03/047.464

02/03/0426.5792

02/03/04-30.7174

02/03/04-19.3187

02/03/0412.45

02/03/0410.2

02/03/044.36667

03/03/041.1

03/03/04-2.2

03/03/041.1

03/03/04-0.65

03/03/04-12.8

03/03/0426.3

03/03/048.15

03/03/04-5.4

03/03/045.93333

03/03/047.1

03/03/0412.3

03/03/04-2.3

04/03/043.65

04/03/048.6

04/03/04-1.26667

04/03/041.35

04/03/048.4

04/03/04-1.66667

04/03/0413.35

04/03/04-1.2

04/03/043.6

04/03/0412.95

04/03/041

04/03/041.76667

05/03/042.6

05/03/043.4

05/03/044.43333

05/03/046.5

05/03/047

05/03/04-4.2

05/03/0421.65

05/03/04109

05/03/0417.8

05/03/0435.5

05/03/04-10

05/03/047.26667

06/03/04-13.25

06/03/047.6

06/03/043.2

06/03/049.8

06/03/04-6.5

06/03/048.23333

06/03/04-4.95

06/03/0424.4

06/03/04-1.73333

06/03/047.7

06/03/047.4

06/03/042.06667

07/03/042.05

07/03/04-6.1

07/03/04-2.1

07/03/046.6

07/03/048.2

07/03/047.1

07/03/04-7.6

07/03/04-4.9

07/03/04-2.33333

07/03/04-0.45

07/03/043.9

07/03/0412.9667

08/03/04-6.75

08/03/04-5.8

08/03/040.933333

08/03/046.55

08/03/046.1

08/03/042.86667

08/03/04-10

08/03/042.6

08/03/045.2

08/03/0421.15

08/03/0420.4

08/03/043.03333

09/03/04-2.35

09/03/04-6.7

09/03/043.53333

09/03/0422.55

09/03/04-24.9

09/03/04-5

09/03/0459.35

09/03/04204

09/03/047.4

09/03/0422.75

09/03/0430

09/03/0424.7333

10/03/0413.2

10/03/04-5.9

10/03/048.23333

10/03/04-7.4

10/03/04-14

10/03/0414.5667

10/03/045.8

10/03/04-15.1

10/03/043.86667

10/03/041.2

10/03/045.8

10/03/04-12.4667

11/03/0425.4

11/03/04-0.9

11/03/04-7.5

11/03/0413.7

11/03/045.2

11/03/049.56667

11/03/0423.1

11/03/04-40

11/03/04-16.1

11/03/045.1

11/03/042.7

11/03/046.73333

12/03/046.5

12/03/0427.2

12/03/04-7.03333

12/03/04-1.9

12/03/04-8.4

12/03/043.1

12/03/04-3.55

12/03/040.6

12/03/045.46667

12/03/042.35

12/03/0416.6

12/03/047.8

13/03/041.3

13/03/045

13/03/04-0.266667

13/03/044.65

13/03/045

13/03/041.33333

13/03/046.6

13/03/046

13/03/042.26667

13/03/04-8.35

13/03/04-0.5

13/03/04-0.366667

14/03/04-5.15

14/03/047.9

14/03/047.1

14/03/0424.7

14/03/0416.6

14/03/046.66667

14/03/04-0.3

14/03/045.8

14/03/0421.5

14/03/041.15

14/03/045.4

14/03/041.6

15/03/044.1

15/03/04-7.2

15/03/041.46667

15/03/045.75

15/03/04-2.1

15/03/044.03333

15/03/041.75

15/03/04-13.1

15/03/042.6

15/03/0415.35

15/03/0419.4

15/03/0411.0667

16/03/0427.45

16/03/0423

16/03/0441

16/03/0431.5

16/03/0443

16/03/0441.3333

16/03/0417.8

16/03/0422.5667

16/03/040.9

16/03/0413.7

16/03/0459

17/03/0447.5

17/03/0421.4

17/03/0438.6667

17/03/0434.75

17/03/0430

17/03/045.86667

17/03/04-11

17/03/04-21.5

17/03/044.35

17/03/043.1

17/03/044.13333

18/03/04-1.1

18/03/043.8

18/03/041.4

18/03/044.4

18/03/040.8

18/03/04-1.46667

18/03/041.65

18/03/04-5.5

18/03/049.93333

18/03/0413.85

18/03/0414.1

18/03/045.8

19/03/048.3

19/03/044.9

19/03/047.46667

19/03/046.65

19/03/047.5

19/03/049.26667

19/03/04-3.25

19/03/045.8

19/03/041.4

19/03/041.7

19/03/042.9

19/03/048.63333

20/03/0412.4

20/03/041.9

20/03/0479.3667

20/03/041.75

20/03/0432

20/03/04-6.96667

20/03/04-6.5

20/03/0413.5

20/03/045.3

20/03/0414.2

20/03/04-4.9

20/03/045.96667

21/03/041.55

21/03/043.3

21/03/042.56667

21/03/048.4

21/03/049.4

21/03/04-3.6

21/03/043.15

21/03/04-9.5

21/03/044.8

21/03/045.7

21/03/045.8

21/03/044.36667

22/03/04-7.45

22/03/0416.6

22/03/043.73333

22/03/042.4

22/03/046.1

22/03/043.63333

22/03/043.35

22/03/04-14.6

22/03/041.03333

22/03/046.25

22/03/041.3

22/03/04-5.86667

23/03/045.25

23/03/04-7.9

23/03/042.06667

23/03/0412.55

23/03/04-12.5

23/03/04-3.13333

23/03/04-0.700001

23/03/04-5.1

23/03/040.6

23/03/041.6

23/03/041.63333

24/03/04-2

24/03/047.4

24/03/042.46667

24/03/048.8

24/03/0410.6

24/03/04-3.1

24/03/04-1.05

24/03/043.6

24/03/04-0.4

24/03/040.75

24/03/04-1.5

24/03/042.63333

25/03/042

25/03/04-0.3

25/03/044.93333

25/03/044.05

25/03/043.5

25/03/042.33333

25/03/041.55

25/03/0435

25/03/04-6.23333

25/03/04-6.25

25/03/043.6

25/03/041.93333

26/03/04-0.25

26/03/04-1

26/03/040.666667

26/03/043.25

26/03/046.5

26/03/043.83333

26/03/04-1.2

26/03/04-0.3

26/03/044.56667

26/03/043.95

26/03/043.6

26/03/042.26667

27/03/042.65

27/03/0411.9

27/03/042.73333

27/03/049.4

27/03/04-11.8

27/03/040.566667

27/03/044.15

27/03/048.8

27/03/044.96667

27/03/044.4

27/03/048.8

27/03/045.13333

28/03/042.5

28/03/0416.3

28/03/041.63333

28/03/043.75

28/03/04-0.6

28/03/041.6

28/03/041.55

28/03/047.4

28/03/04-0.933333

28/03/043.05

28/03/040

28/03/04-0.866667

29/03/040.6

29/03/043.3

29/03/04-0.2

29/03/04-0.95

29/03/042.4

29/03/04-0.2

29/03/04-0.7

29/03/048.4

29/03/04-0.966667

29/03/041.35

29/03/041.8

29/03/04-0.933333

30/03/042.2

30/03/04-2

30/03/041.2

30/03/041.85

30/03/043.7

30/03/040.233333

30/03/04-2.5

30/03/04-5

30/03/044.56667

30/03/04-5.7

30/03/042.9

30/03/042.33333

31/03/043.35

31/03/04-2.8

31/03/042.3

31/03/043.65

31/03/04-5.4

31/03/042.4

31/03/041.95

31/03/04-5.5

31/03/044.83333

31/03/04-4.8

31/03/042.6

31/03/042.8

01/04/04-7.65

01/04/0430

01/04/04-1.46667

01/04/047.75

01/04/04-4.4

01/04/04-0.1

01/04/04-1

01/04/04-5.8

01/04/0443.1

01/04/04-3.05

01/04/04-8.2

01/04/04-1.1

02/04/041.5

02/04/0449

02/04/04-12.6333

02/04/049.2

02/04/04-19.3

02/04/04-5.03333

02/04/043.3

02/04/043.7

02/04/04-0.566667

02/04/04-3.35

02/04/04-4

02/04/042.16667

03/04/0411.15

03/04/04-0.4

03/04/04-0.9

03/04/040.8

03/04/045.8

03/04/049.16667

03/04/04-11.1

03/04/046.2

03/04/04-10.3333

03/04/0415.1

03/04/040

03/04/040.0333333

04/04/040.85

04/04/042

04/04/042.96667

04/04/040.75

04/04/04-2.8

04/04/04-1.5

04/04/047.65

04/04/0410.6

04/04/04-11.2333

04/04/04-9.45

04/04/046.7

04/04/041.76667

05/04/0410.15

05/04/042.9

05/04/04-1.73333

05/04/04-4.5

05/04/048.5

05/04/04-3.36667

05/04/043.6

05/04/044.7

05/04/04-3.2

05/04/0419

05/04/04-18

05/04/045.23333

06/04/041.85

06/04/0413.7

06/04/04-0.166667

06/04/04-8.8

06/04/0430

06/04/04-17.5333

06/04/041.8

06/04/040.7

06/04/04-0.0333331

06/04/04-1.95

06/04/0413.6

06/04/044.76667

07/04/04-14.3

07/04/0439

07/04/04-6.03333

07/04/0419.85

07/04/044.9

07/04/04-1.86667

07/04/04-8.15

07/04/04-2.5

07/04/04-3.26667

07/04/0439.95

07/04/048.1

07/04/0450.4333

08/04/04-0.3

08/04/04-5.6

08/04/044.76667

08/04/044.65

08/04/0416

08/04/041.33333

08/04/04-4.8

08/04/045.6

08/04/042.63333

08/04/041.6

08/04/04-0.4

08/04/0410.3

09/04/04-0.05

09/04/04-5.5

09/04/04-1.63333

09/04/042.05

09/04/0412

09/04/04-2.73333

09/04/04-6.6

09/04/040.2

09/04/041.96667

09/04/044.3

09/04/04-2.3

09/04/04-3.93333

10/04/04-0.45

10/04/043.3

10/04/0425.6

10/04/0477.25

10/04/0412.2

10/04/0418.9333

10/04/044.4

10/04/0414.5

10/04/048.23333

10/04/04-6.1

10/04/0411

10/04/045.9

11/04/0412.65

11/04/042.6

11/04/048

11/04/048.3

11/04/0419.8

11/04/041.93333

11/04/046.25

11/04/04-0.9

11/04/045.33333

11/04/046.45

11/04/044.3

11/04/041.96667

12/04/043.65

12/04/04-19.2

12/04/044.7

12/04/044.95

12/04/041.9

12/04/04-5.16667

12/04/0410.9

12/04/04-10.9

12/04/047.2

12/04/0432.15

12/04/043.4

12/04/042.53333

13/04/049.65

13/04/04-0.7

13/04/04-2.1

13/04/0412.55

13/04/0419.7

13/04/049

13/04/0425.6

13/04/04-55

13/04/0416.8

13/04/047.85

13/04/0411.3

13/04/043.6

14/04/04-2.65

14/04/0416.4

14/04/04-3.8

14/04/04-13.8

14/04/0420.5

14/04/04-3.8

14/04/047.4

14/04/04-6.2

14/04/044.73333

14/04/040.65

14/04/041.4

14/04/04-3.56667

15/04/04-15.8

15/04/048.1

15/04/04-4.06667

15/04/048.1

15/04/0416

15/04/04-6.4

15/04/041.9

15/04/04-9.6

15/04/040.933333

15/04/046.45

15/04/046.7

15/04/044.56667

16/04/041.9

16/04/04-7.2

16/04/044.03333

16/04/04-5.55

16/04/04-4.2

16/04/04-4.93333

16/04/0411.45

16/04/04-17.6

16/04/04-1.23333

16/04/045.25

16/04/043.4

16/04/041.3

17/04/040.7

17/04/04-0.1

17/04/044.13333

17/04/04-2.35

17/04/044.5

17/04/041.76667

17/04/042.85

17/04/04-7.9

17/04/040.4

17/04/048.85

17/04/041.2

17/04/049.23333

18/04/042.4

18/04/041.3

18/04/04-3.06667

18/04/04-0.6

18/04/040.7

18/04/04-3.53333

18/04/040.45

18/04/04-0.8

18/04/04-0.666667

18/04/04-1.1

18/04/046.7

18/04/041.1

19/04/0413.1

19/04/04-11.8

19/04/047.66667

19/04/04-1.05

19/04/044.2

19/04/040.666667

19/04/041.3

19/04/04-2.5

19/04/042.5

19/04/044.85

19/04/045.3

19/04/045.43333

20/04/044.05

20/04/040

20/04/040.966667

20/04/042.65

20/04/043.7

20/04/040.833333

20/04/042.6

20/04/04-4.3

20/04/040.2

20/04/042.2

20/04/040.6

20/04/049.7

21/04/0416.35

21/04/04-1.2

21/04/043.13333

21/04/04-2.85

21/04/042.8

21/04/04-7.6

21/04/046.25

21/04/044.7

21/04/04-1.76667

21/04/041.15

21/04/042.7

21/04/045.3

22/04/041.8

22/04/04-2.3

22/04/043.3

22/04/041.5

22/04/041.8

22/04/040

22/04/0427

22/04/04-21.7

22/04/04-4.1

22/04/040.3

22/04/043.9

22/04/041.03333

23/04/04-1.45

23/04/04-1.2

23/04/042.8

23/04/04-1.65

23/04/04-2.1

23/04/04-6.3

23/04/04-1.55

23/04/0412.5

23/04/043.93333

23/04/045.2

23/04/044.1

23/04/040.733333

24/04/04-7.9

24/04/04-4.3

24/04/042.8

24/04/049.85

24/04/04-0.9

24/04/04-2.46667

24/04/043.3

24/04/04-7.3

24/04/042.46667

24/04/040.65

24/04/04-0.7

24/04/044.23333

25/04/040.4

25/04/042.9

25/04/041.26667

25/04/04-5.2

25/04/041.5

25/04/041

25/04/041.25

25/04/04-3.4

25/04/041.43333

25/04/040.65

25/04/042.3

25/04/04-3.93333

26/04/047.8

26/04/049.6

26/04/042.23333

26/04/0422.75

26/04/04-43

26/04/04-3.4

26/04/04-11.2

26/04/04-14

26/04/049.5

26/04/042.7

26/04/04-2.1

26/04/041.16667

27/04/04-1.65

27/04/04-10

27/04/041.8

27/04/041.1

27/04/04-5.2

27/04/04-0.6

27/04/044.35

27/04/04-23.8

27/04/049.36667

27/04/042.9

27/04/04-4.4

27/04/044.06667

28/04/047.85

28/04/044.1

28/04/042.3

28/04/041.6

28/04/040.7

28/04/04-3.3

28/04/0415.05

28/04/040.2

28/04/045.96667

28/04/044

28/04/045.5

28/04/04-1.56667

29/04/04-0.15

29/04/043.5

29/04/040.0666666

29/04/046.8

29/04/04-6.6

29/04/041.46667

29/04/04-4.7

29/04/04-1.9

29/04/040.933333

29/04/04-3.85

29/04/040.2

29/04/04-0.9

30/04/042

30/04/047.7

30/04/043.63333

30/04/041.35

30/04/041.9

30/04/048.03333

30/04/04-19.7

30/04/04-25.8

30/04/046.36667

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15/02/05-1.8375

15/02/05-9.63913

15/02/058.252

15/02/05-1.59583

15/02/053.44348

15/02/053.244

16/02/05-15.2792

16/02/053.06956

16/02/0513.892

16/02/054.57083

16/02/051.84783

16/02/052.296

16/02/053.59167

16/02/05-10.5565

16/02/051.976

16/02/05-9.10909

new cal

DatafileTime (after 10minsampling)00Date & Time (of sampling)mid-point of samplingethaneethenepropanepropenet-2-butene1-buteneI-butenec-2-butenei-pentanet-2-pentenecyclohexanebenzenetoluenei-butanen-butaneacetylenen-pentanemid-point of samplingdmsiso-butane/propaneiso-butane/n-butaneethene/propene ratio

c:\chablis\chroma~1\010105\010105.67800.56527777783839138391.52013888892/8/05 12:364062/8/05 12:36

c:\chablis\chroma~1\010105\010105.67700.56041666673839138391.51527777782/8/05 12:294062/8/05 12:290.00

c:\chablis\chroma~1\010105\010105.67600.46805555563839138391.42291666672/8/05 10:1640597.700.0010.8214.860.000.0010.500.000.0071.5916.600.000.000.000.000.000.002/8/05 10:1638

c:\chablis\chroma~1\010105\010105.67500.41736111113839138391.37222222222/8/05 9:034052/8/05 9:03

c:\chablis\chroma~1\010105\010105.67400.36666666673839138391.32152777782/8/05 7:504052/8/05 7:50

c:\chablis\chroma~1\010105\010105.67300.31666666673839138391.27152777782/8/05 6:384052/8/05 6:38

c:\chablis\chroma~1\010105\010105.67200.26597222223839138391.22083333332/8/05 5:254052/8/05 5:25

c:\chablis\chroma~1\010105\010105.67100.21527777783839138391.17013888892/8/05 4:124052/8/05 4:12

c:\chablis\chroma~1\010105\010105.67000.16458333333839138391.11944444442/8/05 2:594052/8/05 2:59

c:\chablis\chroma~1\010105\010105.66900.11388888893839138391.068752/8/05 1:464052/8/05 1:46

c:\chablis\chroma~1\010105\010105.66800.06388888893839138391.018752/8/05 0:344052/8/05 0:34

2/6/05 23:2070.00

c:\chablis\chroma~1\010105\010105.66700.01253839038389.96736111112/6/05 23:20404117.050.000.0010.950.000.000.000.000.0070.6516.380.000.000.000.000.000.002/7/05 22:07110.00

c:\chablis\chroma~1\010105\010105.66600.96180555563839038390.91666666672/7/05 22:07405155.270.0024.9315.180.000.000.000.000.0056.8313.172.250.0017.010.000.000.002/7/05 20:54190.680.00

c:\chablis\chroma~1\010105\010105.66500.91111111113839038390.86597222222/7/05 20:54405137.350.008.477.200.000.000.000.000.0041.459.610.000.000.006.4818.450.002/7/05 19:42281.72

c:\chablis\chroma~1\010105\010105.66400.86111111113839038390.81597222222/7/05 19:42405123.5010.7521.486.260.000.000.000.000.0049.3011.430.000.000.000.000.000.002/7/05 18:2942

c:\chablis\chroma~1\010105\010105.66300.81041666673839038390.76527777782/7/05 18:29405100.810.009.560.000.000.000.000.000.0079.4418.420.000.000.000.0016.190.002/7/05 17:1620

c:\chablis\chroma~1\010105\010105.66200.75972222223839038390.71458333332/7/05 17:16405106.300.000.000.000.000.000.000.000.0093.8821.760.000.0012.1314.080.000.002/7/05 16:03170.860.00

c:\chablis\chroma~1\010105\010105.66100.70902777783839038390.66388888892/7/05 16:03405120.870.0013.9528.160.000.000.000.000.0070.3316.300.000.000.0025.420.000.002/7/05 14:5001.54

c:\chablis\chroma~1\010105\010105.66000.65833333333839038390.61319444442/7/05 14:5040586.2426.1913.9517.050.000.000.000.000.00105.8224.530.000.000.000.000.000.002/7/05 13:37151.74

c:\chablis\chroma~1\010105\010105.65900.60763888893839038390.56252/7/05 13:37405134.4916.5723.059.5420.420.000.000.000.00100.4823.290.000.000.000.000.000.002/7/05 12:2451.02

c:\chablis\chroma~1\010105\010105.65800.55694444443839038390.51180555562/7/05 12:24405119.9213.2123.8312.990.000.000.000.000.00104.5624.240.000.000.0014.330.000.002/7/05 11:1019

c:\chablis\chroma~1\010105\010105.65700.50555555563839038390.46041666672/7/05 11:1040476.4411.1928.850.000.000.000.000.000.0097.9722.710.000.0015.763.990.000.002/7/05 9:57190.553.95

c:\chablis\chroma~1\010105\010105.65600.45486111113839038390.40972222222/7/05 9:57404114.4231.5725.870.000.000.000.000.000.0081.9519.000.000.000.000.000.000.002/7/05 8:4413

c:\chablis\chroma~1\010105\010105.65500.40416666673839038390.35902777782/7/05 8:44404106.060.0016.780.000.000.000.000.000.0078.8118.270.000.000.000.000.000.002/7/05 7:3123

c:\chablis\chroma~1\010105\010105.65400.35347222223839038390.30833333332/7/05 7:31404121.1128.2125.240.000.000.000.000.000.0097.3422.560.000.000.000.000.000.002/7/05 6:18155.80

c:\chablis\chroma~1\010105\010105.65300.30277777783839038390.25763888892/7/05 6:18404147.1548.130.008.290.000.000.000.000.0092.6321.470.000.000.000.000.000.002/7/05 5:0559

c:\chablis\chroma~1\010105\010105.65200.25208333333839038390.20694444442/7/05 5:05404124.9312.0916.300.000.000.000.000.000.00101.1123.440.000.000.000.000.000.002/7/05 3:5227

c:\chablis\chroma~1\010105\010105.65100.20138888893839038390.156252/7/05 3:52404111.800.0030.730.000.000.000.000.000.00109.9025.480.000.000.000.000.000.002/7/05 2:38171.43

c:\chablis\chroma~1\010105\010105.65000.153839038390.10486111112/7/05 2:38404119.4415.6718.5010.950.000.006.360.000.00111.1525.770.000.006.006.980.000.002/7/05 1:24340.320.86

c:\chablis\chroma~1\010105\010105.64900.09861111113839038390.05347222222/7/05 1:2440494.830.0026.650.000.000.000.000.000.00136.9031.740.000.000.000.000.000.002/7/05 0:1037

c:\chablis\chroma~1\010105\010105.64800.04722222223839038390.00208333332/7/05 0:1040498.9036.0452.050.000.000.000.000.000.00160.1437.120.000.000.000.000.000.002/6/05 22:5649

c:\chablis\chroma~1\010105\010105.64700.99583333333838938389.95069444442/6/05 22:56404103.430.000.000.000.000.0013.820.000.00150.0934.790.000.000.000.000.000.002/6/05 21:4132

c:\chablis\chroma~1\010105\010105.64600.943753838938389.89861111112/6/05 21:41404137.350.000.000.000.000.000.000.000.00160.4537.190.000.000.000.000.000.002/6/05 20:2739

c:\chablis\chroma~1\010105\010105.64500.89236111113838938389.84722222222/6/05 20:2740498.6620.820.000.000.000.000.000.000.00170.5039.520.000.000.000.000.000.002/6/05 19:1232

c:\chablis\chroma~1\010105\010105.64400.84027777783838938389.79513888892/6/05 19:12404123.2614.5526.970.000.000.0033.710.000.00187.1443.380.000.000.000.000.000.002/6/05 17:5839

c:\chablis\chroma~1\010105\010105.64300.78888888893838938389.743752/6/05 17:58404129.470.000.000.000.000.003.320.000.00155.7436.100.000.000.000.000.000.002/6/05 16:4335

c:\chablis\chroma~1\010105\010105.64200.73680555563838938389.69166666672/6/05 16:4340483.850.0019.910.000.000.000.000.000.00196.2545.490.000.000.000.000.000.002/6/05 15:29401.38

c:\chablis\chroma~1\010105\010105.64100.68541666673838938389.64027777782/6/05 15:29404105.3538.7322.1128.000.000.006.080.000.00171.7539.820.000.000.000.000.000.002/6/05 14:1429

c:\chablis\chroma~1\010105\010105.64000.63333333333838938389.58819444442/6/05 14:14404134.250.000.000.000.000.000.000.000.00163.5937.920.000.000.000.000.000.002/6/05 13:0039

c:\chablis\chroma~1\010105\010105.63900.58194444443838938389.53680555562/6/05 13:00404137.120.0016.620.000.000.006.360.000.00166.1038.500.000.000.000.000.000.002/6/05 11:4622

c:\chablis\chroma~1\010105\010105.63800.53055555563838938389.48541666672/6/05 11:46403109.1729.5512.390.000.000.000.000.000.00142.5533.050.000.000.000