Thermal SprayMeeting the challengesof the 21st Century

Proceedings of the

15th International Thermal Spray Conference

25-29 May 1998

Nice,France

Edited byChristian Coddet

Organized byCommissariat a l'Energie Atomique

Institut Polytechnique de Sevenans

Universite de LimogesEcole Nationale Superieure des Mines de Paris

Ecole Centrale de LyonInstitut de Soudure

on behalf of the

Select Committee

on Surfacing and Thermal Sprayingof the International Institute of Welding

Co-sponsored byThe ASM Thermal Spray SocietyThe German Welding Society

The High Temperature Society of Japan

Volume 2

Symposium 6 : Industrial applications 923

THE PLACE OF THERMAL SPRAYING IN INDUSTRY TODAY AND THE PROSPECTS FOR THE

FUTURE 925

HUCHIN J.P., SOCHATA, CHATELLERAULT, FRANCE

SOFC COMPONENTS PRODUCTION - AN INTERESTING CHALLENGE FOR DC- AND RF-PLASMA

SPRAYING 933

HENNE R„ SCHILLER G„ BORCK V., MUELLER M., LANG M., RUCKDASCHEL R., DLR Stuttgart, InstitutfUrtechnische Thermadynamik, STUTTGART, GERMANY

COATINGS FOR PLASMA-FACING COMPONENTS OF NUCLEAR FUSION DEVICES 9 3 9

MALLENER W., RAUWALD K.H., DUWE R., Forschungszentrum Julich GmbH, Institutfilr Werkstoffe tier

Energielechnik, JULICH, GERMANY

PLASMA SPRAYED BORON CARBIDE COATINGS AS FIRST WALL MATERIAL FOR LASER FUSION

TARGET CHAMBER 945

BIANCHI L., BRELIVET P., FRESLON A., CEA Le Ripault, MONTS, FRANCE

FORNIER A., CORDILLOTC, CEA Limed, VJLLENEUVE SAINT GEORGES, FRANCE

JEQUJER F„ SCHIRMANN D., CEA, BRUYERESLE CHATEL, FRANCE

UNUSUAL APPLICATION OF PLASMA SPRAYED COATING FOR BOILER TUBES IN OIL-FIRED

BOILERS 9 5 1

TANI K„ HARADA Y„ KOBAYASHI Y„ Tocalo Co. Ltd, KOBE, JAPAN

W AND B4C COATINGS FOR NUCLEAR FUSION REACTORS 957

CAVASIN A., BRZEZ1NSKI T„ GRENIER S„ SMAGOR1NSKI M„ TSANTRIZOS P., PyroGenesk Inc., MONTREAL,

QUEBEC, CANADA

INTERNAL PLASMA SPRAY PROCESS FOR CYLINDER BORES IN AUTOMOTIVE INDUSTRY 9 63

BARBEZAT G., KELLER S., Sulzer Metco AG, WOHLEN, SWITZERLAND

WUESTG., Sulzer Metco Inc., WESTBURY, NY, U.S.A.

COMPONENT REPAIR AND CHROME PLATING REPLACEMENT WITH NEW THERMAL SPRAY IN

THE UNITED STATES NAVY : SUCCESSES AND THE FUTURE 975

R1GNEY R.W., Integrated Systems Analysis, Inc., CHESAPEAKE, VIRGINIA, U.S.A.

GRUBOWSKI A., NAVSEA 03M2, U.S. Navy, ARLINGTON, VA, U.S.A.

McCAW R„ Naval Surface Warfare Center, CARDEROCK, MD, U.S.A.

SCANDELL K„ Naval Surface Warfare Center, PHILADELPHIA, PA, U.S.A.

IN-SERVICE MECHANICAL PROPERTY DEGRADATION OF CoCrAlY COATINGS IN LAND-BASED

GAS TURBINE BLADES 9 8 1

KAMEDA J., BLOOMER T.E., Ames Laboratory (US Dept. ofEnergy), AMES, IA, U.S.A.

SAKURAI S., Mechanical Engineering Research Laboratory, HITACHI, JAPAN

WEAR RESISTANT COATINGS FOR RADIAL SHAFT SEALING SYSTEMS 987

HAAS W., HA1SER H„ Universitat Stuttgart, Institut fur Maschinenelemente, STUTTGART, GERMANY

PUTZIER U., PUTZIER J., Putzier Oberfltichentechnik GmbH, LEICIILINGEN, GERMANY

XXVlll

THERMO-MECHANICAL CHARACTERIZATIONS OF PLASMA-SPRAYED MCrAlY COATINGS FORHP TURBINES 993

BOUDOT A., CRABOS F„ MONGE-CADET P., Turbomeca, BORDES, FRANCEMONCEAU D,, PIERAGGI B., ENSCT, Lahoratoire de Cristallochimie, reactivite et protection des materiaux,UPRESA 5071, TOULOUSE, FRANCE

HYDROXYAPATITE-BOND COAT SYSTEMS FOR IMPROVED MECHANICAL AND BIOLOGICALPERFORMANCE OF HIP IMPLANTS 999

HEIMANN R.B., Freiberg University ofMining and Technology, Institut ofMineralogy, FREIBERG, GERMANY

KURZWEG H., Surfatec GmbH, Elektroschmelze Zschomewitz, ZSCHORNEWITZ, GERMANYVU T.A., Westerwald Industriekeramik GmbH, WIRGES, GERMANY

PROPERTIES OF COATED TOOLS FOR IMPROVED PERFORMANCES 1007ROSSO M., Polytechnic of Torino, Material Science Department, TORINO, ITALY

BENNANI A., Cogne Powder, AOSTA, ITALY

RASTRELLI R„ Sert, LEINl, TO, ITALY

APPLICATIONS OF PTA POWDER WELDING IN PETROLEUM CHEMICAL INDUSTRY 1013HUANG X., WANG R., XU L., LUO H., YIN X., Chinese Academy ofAgricultural Mechanization Sciences,BEIJING, CHINA

A CONTRIBUTION TO METHODOLOGY AND PROTOCOL DEFINITION FOR THERMAL SPRAY

COATED SURFACE COMPATIBILITY ANALYSIS IN FOOD PROCESSING APPLICATIONS 1019

SCRIVANI A., ANTOLOTTI N., BERTINI S., VIOLA G., Flametal SpA, FORNOVO TARO, PARMA, ITALY

GROPPETTI R., GUTEMA T., Universita degli Studi di Parma, Dipartimento di Ingegneria Industriale,

PARMA, ITALY

MANGIA A., MUCCHINO C„ Universita degli Studi di Parma, Dipartimento di Chimica Generate ed Inorganica,Chimica Analitica, Chimica Fisica, PARMA, ITALY

THE INFLUENCE OF COATED MOULD ON HEAT TRANSFER AND MICROSTRUCTURE FOR

HORIZONTAL STRIP CASTING OF ALUMINIUM ALLOYS 1025

ISAC M„ NETTO P., GUTHRIE R.I.L., McGill University, McGill Metals Processing Centre, Mining and

Metallurgical Engineering Department, MONTREAL, CANADA

TAVARES R., Universidade Federal de Minas Gerais, BELA HORIZONTE, MG, BRAZIL

THE DEVELOPMENT AND IMPLEMENTATION OF THERMAL SPRAY COATINGS FOR HELICOPTER

COMPONENTS 1033

GUILLEMETTE R., Sikorsky Aircraft, STRATFORD, CT, U.S.A.

THE EXPERIMENTAL STUDY ON ARC SPRAYED MOULDMAKING FOR PLASTIC PRODUCTS 10 39

XU B., MA S., Surface Engineering Research Institute ofCMES, BEIJING, P.R. CHINA

LIU X„ China Academy of Railway Sciences, Metal and Chesmistiy Research Institute, BEIJING, CHINA

CHEN Z., Dalian Railway Institute, DALIAN, CHINA

PLASMA SPRAY CERAMIC PLUNGER FOR POLYMER PUMP 1043

WU C.J., Beijing Research Institute of Materials & Technology, BEIJING, CHINA

SHAO T.M., Tsinghua University, National Tribology Lab., BEIJING, CHINA

MU A.G., DU W.L., Daqing Kidco Pumps Inc., HE1LONGJ1ANG, CHINA

A NEW ALUMINIUM SILICON-BORON NITRIDE ABRADABLE FOR COMPRESSOR COMPONENTS. . . 1049

BODDENBERG K, KOCK B„ Demag Delaval Turbomachinery, DUISBURG, GERMANY

DORFMAN M., RUSSO L„ Sulzer Metco Inc., WESTBURY, NY, U.S.A.

NESTLER M., Sulzer Metco, HATTERSHEIM A.M., GERMANY

xxtx

Ca/P RATIO AND BIOCOMPATIBILITY OF HYDROXYAPATITE COATINGS 1055

FRAYSSINET P., TOURENNE P., ROUQUET N., DePuy-Bioland, TOULOUSE, FRANCE

PRIMOUT I., Universite Paul Sabatier, Laboratoire du Tissu Osseux et des Pathologies Oslioarticulaires,

TOULOUSE, FRANCE

MATHON D„ Ecole Nationale Veterinaire, TOULOUSE, FRANCE

ADVANTAGES OF INDUCTION HEAT TREATMENT IN THE APPLICATION OF SELF-FLUXING

ALLOY TO BOILER TUBES 10 61

TOMIGUCHI A., SOCHI Y., MATSUBARA Y„ Dai-khi High Frequency Co. Ltd, KAWASAKI, JAPAN

DEVELOPMENT OF FABRICATION PROCESSES FOR TUBULAR SOLID OXIDE FUEL CELL (SOFC)BY PLASMA SPRAYING 1067

JU W.T., HONG S.H., Seoul National University, Departement ofNuclear Engineering, SEOUL, KOREA

HVOF-SPRAYING VS. HARD CHROME PLATING - COATING CHARACTERISTICS AND AIRCRAFT

APPLICATIONS 1073

NESTLER M.C., Sulzer Metco, HATTERSHEIM A.M., GERMANY

PRENZEL G., Lufthansa Technik AG, Dept. WU 534, HAMBURG, GERMANY

SEITZT., Lufthansa Technik AG, Dept. HAM WG 425, HAMBURG, GERMANY

INFLUENCES OF METAL SPRAYED COATING ARTIFICIAL DENTAL ROOT ON THE VITAL

TISSUE 1079MAGOME M., Osaka Sangyo University, Faculty of Engineering, OSAKA, JAPAN

HARA K., SANO K„ Dental clinic, OSAKA, JAPAN

UEDA Y., Dental clinic, NARAKEN, JAPAN

COMBINED METALLURGICAL AND CERAMIC COATING IN THE DEVELOPMENT OF TUBULAR

OZONE GENERATORS 1083

GADOW R., KILLINGER A., VOSS A., FRIEDRICH C, University ofStuttgart, Institut for ManufacturingTechnologies of Ceramic Components and Composites, STUTTGART, GERMANY

Fe-Al INTERMETALLIC COATING APPLICATIONS TO THERMAL ENERGY CONVERSION

ADVANCED SYSTEMS 10 91

MAGNEE A., Centre de RecherchesMetallurgiques (CRM), LIEGE, BELGIUM

OFFERGELD E., Cockerill Mechanical Industry (CMI), SERAING, BELGIUM

LEROY M., Quest Coating, SAINT NAZAIRE, FRANCE

LEFORT A., CEA - ANVAR, CLERMONT-FERRAND, FRANCE

APPLICATIONS OF HVOF SPRAYED WC CERMET COATINGS FOR PAPER MILLS 1097

TANI K., NAKAHIRA A., Tocalo Co. Ltd, KOBE, JAPAN

THE APPLICATION OF THERMAL SPRAYING TECHNOLOGY IN THE OIL AND GAS INDUSTRY 1103

PRICE J.C., Brown and Root. HOUSTON, TX, U.S.A.

CERAMIC-CLAD CERAMIC SYSTEM FOR ULTRASONIC WAVE GUIDANCE 1109MARPLE B.R., JEN C.-K., VOYER J„ National Research Council Canada, BOUCHERVILLE, QUEBEC, CANADA

FATIGUE BEHAVIOR OF TYPE 316L STAINLESS STEEL COATED WITH PLASMA-SPRAYEDALUMINA IN CORROSIVE ENVIRONMENT 1115

KISUKI H., SUGANO M., OSHIMA T., NASU Y., OKAZAKI K., Yamagata University, Faculty ofEngineering,YONEZAWA, YAMAGATA, JAPAN

NAKATA K., Osaka University, Joining and Welding Research Institute, OSAKA, JAPAN

XXX

INTERFACE CHARACTERIZATION OF DIFFERENT APATITE COATINGS 1121

ANTOLOTTI N„ BERTINI S., SCRIVANI A., Flametal SpA, FORNOVO TARO, PARMA, ITALY

FANARA C, RUSTICHELLI F., Universita di Ancona, Instituto Nazionale di Fisica della Materia, ANCONA, ITALY

RANZ X., REY C, ENSCT-INPT, Laboratoire des Materiaux - Physico Chimie des Solides, URA CNRS 445,TOULOUSE, FRANCE

THERMAL SPRAYING APPLIED ONTO HIGH ENERGY RAILWAY BRAKING : CHARACTERIZATION

OF FRICTION PERFORMANCES 1127

BARTYS H„ GUERIN J.D., BRICOUT J.P., OUDIN J„ Universite de Valenciennes et du Hainaut Cambresis,Lab. d'Automatique et de Mecanique Industrielles et Humaines (LAMIH URA CNRS 1775),, VALENCIENNES,FRANCE

ANALYSIS OF RETRIEVED HYDROXYAPATITE COATED ORTHOPAEDIC IMPLANTS 1133

GROSS K.A., BEN-NISSAN B., University of Technology Sydney, Department of Materials Science,

BROADWAY, NSW, AUSTRALIA

WALSH W.R., Orthopaedic Research Laboratory, RANDWICK, AUSTRALIA

SWARTS E„ Royal Perth Hospital, Deptartment of Medical Physics, GPO PERTH, AUSTRALIA

Symposium 7 : Composite structures, free standing shapes, polymercoatings and feedstock 1139

NITRIDING OF METAL DROPLETS IN SYNTHESIS OF INTERMETALLIC MATRIX COMPOSITE

COATINGS BY REACTIVE RF PLASMA SPRAYING 1143

TSUNEKAWA Y„ HIROMURA M., OKUMIYA M„ Toyota Technological Institute, NAGOYA, JAPAN

INVESTIGATIONS ON THERMAL SPRAYING OF SILICON NITRIDE-BASED POWDERS 114 9

BERGER L.-M,, HERRMANN M., NEBELUNG M., Fraunhofer Institute ofCeramic Technologies and Sintered

Materials, DRESDEN, GERMANY

THIELE S., HEIMANN R.B., Freiberg University of Mining and Technology, Institut ofMineralogy, FREIBERG,

GERMANY

SCHNICKT., WIELAGE B., Technical University Chemnitz, Institute for Composite Materials, CHEMNITZ,

GERMANY

VUORISTO P„ Tampere University of Technology, Institute ofMaterials Science, TAMPERE, FINLAND

OBTENTION AND DEVELOPMENT OF BLENDS OF POWDER TO OBTAIN FREE-STANDING

COMPONENTS PRODUCED BY HVOF SPRAY-FORMING 1155

GUILEMANY J.M., DE PACO J.M., MIGUEL J.R., Universite of Barcelona, Department of Chemical Engineering

and Metallurgy, BARCELONA, SPAIN

LLIBRE J., Carburos Metalicos S.A., BARCELONA, SPAIN

FABRICATION OF COMPOSITE SiC-MoSi2 POWDERS THROUGH PLASMA REACTION PROCESS... 1161

FAN X., ISHIGAKI T„ National Institute for Research in Inorganic Materials, Research Center ofAdvanced

Materials, IBARAKI, JAPAN

NEW POWDERED SILICIDE MATERIALS FOR THERMAL SPRAYING PROCESS AND COATINGS

ON THE NIOBIUM BASE ALLOYS 11«?

TERENTIEVA V., BOGATCHKOVA 0„ Moscow State aviation Institute, MOSCOW, GSP, RUSSIA

CORNU D„ Society European Propulsion, VERNON, FRANCE

MECHANICAL PROPERTIES OF SPRAY-FORMED COMPOSITE STRUCTURES 1173

BROGAN J. A., BERNDT C.C., SUNY at Stony Brook, Thermal Spray Laboratory (TSL), STONY BROOK, NY, U.S.A.

CLAUDON A., CODDET C, IPSe, Laboratoire d'Etudes et de Recherches sur les Materiaux et Proprietes de Surface(LERMPS), BELFORT, FRANCE

OXIDATION THERMO-MECHANICAL AND NOVEL LATTICE-GAS PARTICLE DEPOSITION

MODELING ASPECTS IN PLASMA SPRAYING OF Ti-6AI-4V/SiC FIBER COMPOSITES 1179

COCHELIN E., BORIT F., FROT G., JEANDIN M„ Ecole des Mines de Paris/ClP Centerfor Plasma Processing,EVRY, FRANCE

DECKER L., JEULIN D„ Ecole des Mines de Paris - Centre de Morphologic Mathematique, FONTAINEBLEAU,

FRANCE

AL TAWEEL B„ MICHAUD V., Ecole Centrale de Paris/MSSMAT, CHATENAY-MALABRY, FRANCE

NOEL P., MATRA-BAe Dynamics, VELIZY, FRANCE

A NEW ALUMINUM-SILICON/BORON NITRIDE POWDER FOR CLEARANCE CONTROL

APPLICATIONS 118 7

MORRELL P., BETTRIDGE D,F„ GREAVES M.D., Rolls-Royce pic, DERBY, U.K.

DORFMAN M.R., RUSSO L,D., Sulzer Metco Inc., WESTBURY, NY, U.S.A.

BRITTON C, HARRISON K„ Sulzer Metco Ltd., FARNBOROUGH, HAMPSHIRE, U.K.

OPTIMISATION OF CONCURRENT FIBRE WINDING AND LOW PRESSURE PLASMA SPRAYING

FOR THE MANUFACTURE OF TITANIUM MATRIX COMPOSITE RINGS 1193

BAIK K.H., GRANT P.S., Oxford University, Centre for Advanced materials and Composites ,OXFORD, U.K.

MOLYBDENUM DISILICIDE COMPOSITES PRODUCED BY PLASMA SPRAYING 1199

CASTRO R.G., KUNG H„ MOLLIS K.J., Los Alamos National Laboratory, LOS ALAMOS, NM, U.S.A.

BARTLETT A.H., Norsam Technology, WHITE ROCK, NM, U.S.A.

FREE-FORM PROCESSING OF NEAR-NET SHAPES USING DIRECTED LIGHT FABRICATION 1205

THOMA D.J., LEWIS G.K., MILEWSKI J.O., NEMEC R.B., Los Alamos National Laboratory, ,LOS ALAMOS,

NM, U.S.A.

REALIZATION OF MIRROR SHELLS FOR X-RAY TELESCOPE BY PLASMA FORMING 1211

ROUSSEL E, FROMENTIN J.P., FRESLON A„ CEA Le Ripault, MONTS, FRANCE

MECHANICAL AND MICROSTRUCTURAL CHARACTERISATION OF A FREE STANDING PLASMA

SPRAYED ALUMINA 1217

DAMANI R.J., Montanuversitat Leoben, Institut fiir struktw- und Funktionskeramik, LEOBEN, AUSTRIA

THE ELECTRIC ARC SPRAY MANUFACTURE OF RAPID PRODUCTION TOOLING :

A CASE STUDY 1223

NEWBERY A.P., GRANT P.S., Oxford University, Centre for Advanced materials and Composites, OXFORD, U.K.

JORDAN R.M., ROCHE A.D., Sprayform Tools & Dies, Ltd., SWANSEA, U.K.

CARR T.C., Hasbro Inc., PANTUCKET, RHODE ISLAND, U.S.A.

NEAR NET-SHAPE FORMING OF THERMAL BARRIER COATED COMPONENTS FOR GAS TURBINE

ENGINE APPLICATIONS 1229

KIM G.E., TSANTRIZOS P.G., GRENIER S., CAVASIN A., BRZEZINSKI T„ PyroGenesis Inc., MONTREAL,QUEBEC, CANADA

NOVEL Zr02-MULLITE COMPOSITES PRODUCED BY PLASMA SPRAYING 1233KHOR K.A., LI Y., Nanyang Technological University, School of Mechanical & Production Engineering,SINGAPORE, SINGAPORE

xxxii

IMPACT TOUGHNESS OF THICK MULTILAYER THERMAL SPRAY DEPOSITS 1239VERDY C, CODDET C, IPSe, Laboratoire d'Etudes et de Recherches sur les Materiaux et Proprietes de Surface(LERMPS), BELFORT, FRANCE

MARTIN J.B., GARCIA J.C., PELLERIN F„ Turbomeca, TARNOS, FRANCE

ON THE FABRICATION AND PROPERTIES OF A CERAMIC CLADDED ALUMINIUM POWDERUSING THE SPRAY DRYING PROCESS 1245

COMAS B„ MATEUS C, HANSZ B., CODDET C, IPSe, Laboratoire d'Etudes et de Recherches sur les Materiaux et

Proprietes de Surface (LERMPS), BELFORT, FRANCE

VPS COATINGS USING NANOSTRUCTURAL IRON-BASED ALLOYS 1249

BRANDT 0„ SIEGMANN S.D., Swiss Federal Laboratoriesfor Materials Testing and Research (EMPA), THUN,SWITZERLAND

THERMAL SPRAY COATINGS FOR FIBER REINFORCED POLYMER COMPOSITES 1255

ASHARI A.A., TUCKER R.C., Praxair Surface Technologies, Inc., INDIANAPOLIS, IN, U.S.A.

PLASMA SPRAY FORMING OF FREE STANDING W-Al FUNCTIONALLY GRADED MATERIALS 12 5 9

BLEIN F„ FRESLON A„ CEA Le Ripault, MONTS, FRANCE

THERMAL STABILITY OF NANOCRYSTALLINE INCONEL 718 AND Ni PREPARED BY HIGH

VELOCITY OXY-FUEL (HVOF) THERMAL SPRAYING 1265

JIANG H,G., LAU M.L., LAVERNIA E.J., University of California, Department of Chemical and Biochemical

Engineering and Materials Science, IRVINE, CA, U.S.A.

INCREASING PERFORMANCE OF PLASMA SPRAY FORMED COMPONENTS 1271

O'DELL J.S., MCKECHNIE T.N., Plasma Processes Inc., HUNTSVILLE, AL, U.S.A.

HOLMES R.R., NASA-MSFC, Georges C. Marshall Space Flight Center, HUNTSVILLE, AL, U.S.A.

VPS DEPOSITION OF SPHERICAL Ti-BASED POWDERS PRODUCED BY PLASMA ATOMIZATION. . .1277

GRENIER S„ BRZEZINSKI T„ TSANTRIZOS P., PyroGenesis Inc., MONTREAL.QUEBEC, CANADA

ALLAIRE F„ LTEE, Hydro-Quebec, SHAWINIGAN, QUEBEC, CANADA

FABRICATION OF SIMULATED NUCLEAR FUEL PELLETS BY INDUCTION PLASMA DEPOSITION. . . 1283

GITZHOFER F., MAILHOT K., BOULOS M.I., Universite de Sherbrooke, Fac. des Sciences Appliquees, Departmentde Genie Chimique, SHERBROOKE, CANADA

JUNG I.H., LEE J.S., PARK H.S., Korea Atomic Energy Research Institute, TAEJON, KOREA

Symposium 8 : Spraying and associated processes 1289

C02 COOLING IN THERMAL SPRAYING 1293

GOURLAOUEN V., REMY F., Air Liquide CTAS, SAINT OUEN LAUMONE, FRANCE

HANSZ B., CODDET C, IPSe, Laboratoire d'Etudes et de Recherches sur les Materiaux et Proprietes de Surface(LERMPS), BELFORT, FRANCE

POROSITY CONTROL OF THERMALLY SPRAYED CERAMIC DEPOSITS 1299

CHRASKA P., BROZEK V„ KOLMAN B.J„ ILAVSKY J., NEUFUSS K„ DUBSKY J., VOLENIK K., Institute

of Plasma Physics, Academy of Sciences of the Czech Republic (AVCR), PRAHA 8, CZECH REPUBLIC

xxxiii

A GAS SHROUD NOZZLE FOR HVOF SPRAY DEPOSITION 1305

PERSHIN V., MOSTAGHIMI J., CHANDRA S„ COYLET., University of Toronto, Department of Mechanicaland Industrial Engineering, TORONTO, ONTARIO, CANADA

PREPARATION OF FILMS FOR SOLID OXIDE FUEL CELLS BY CENTER-INJECTION LOW

PRESSURE PLASMA SPRAYING 1309

CHEN H.C., HEBERLEIN J., University of Minnesota, Department ofMechanical Engineering, MINNEAPOLIS,

MN, U.S.A.

YOSHIDA T., University of Tokyo, Department of Materials Science, TOKYO, JAPAN

REACTIVE PLASMA SPRAYING OF 80:20 Ni/Cr AND MCrAlY POWDERS WITH HYDROCARBON

REACTIVE GASES 1315

AL-SABOUNI O., STEPHENSON D.J., NICHOLLS J.R., Cranfield University, School of Industrial and ManufacturingScience, BEDFORD, U.K.

CREFFIELD G., BOC Gases Europe, Sales Development Dept., LONDON, U.K.

SURFACE PREPARATION AND THERMAL SPRAY IN A SINGLE STEP : THE PROTAL® PROCESS... 1321

CODDET C, MONTAVON G„ IPSe, Laboratoire d'Etudes et de Recherches sur les Materiaux et Proprie'tes de Surface(LERMPS), BELFORT, FRANCE

MARCHIONET., FRENEAUX O., IREPA-Laser, ILLKIRCH, FRANCE

CERAMIC COATINGS OBTAINED ON SUPERALLOYS MODIFIED BY LASER TREATMENT 1327

KOBYLANSKA-SZKARADEK K„ Sileskm Technical University, Institute of Physics, KATOWICE, POLAND

SWADZBA L., Silesian Technical University, Institute of Materials Science and Engineering, KATOWICE, POLAND

LOCAL LASER TREATMENT OF TRIBOLOGICAL PLASMA SPRAYED COATINGS 13 33

OTMIANOWSKI T„ ANTOSZEWSK1 B., ZORAWSK1 W., Technical University of Kielce, KIELCE, POLAND

PHYSICO-CHEMICAL TREATMENT OF ZIRCONIA COATINGS FOR THERMAL BARRIERS 1337

TROCZYNSKI T., THIRD N„ University of British Columbia, VANCOUVER, BC, CANADA

PAWLOWSK1 L„ Universite d'Artois, Faculty ofApplied Sciences, BETHUNE, FRANCE

COVELLI L., Institute of Autmation, CNR, MILANO, ITALY

SMUROV I., Institute of Science and Engineering ofMaterials and Processes, FONT ROMEU, FRANCE

PHASES TRANSFORMATIONS IN LASER TREATED HYDROXYAPATITE COATINGS 1343

RANZ X., ASLANIAN T., DePuy-Bioland, TOULOUSE, FRANCE

PAWLOWSKI L., Universite d'Artois, Faculty ofApplied Sciences, BETHUNE, FRANCE

SABATIER L., FABBRO R., Centre Laser Franco-Allemand, ARCUEIL, FRANCE

REFRACTORY CARBIDE COATINGS SPRAYED BY ELECTROTHERMAL EXPLOSION OF

CONDUCTIVE-CERAMIC POWDERS 13 5 1

SODA T„ TAMURA H„ SAWAOKA A.B., Tokyo Institute ofTechnology, Department ofMaterials Science and

Engineering, YOKOHAMA, JAPAN

FREE FORM FABRICATION OF METALLIC COMPONENTS USING THE DIRECTED LIGHT

FABRICATION PROCESS 1357LEWIS G.K., MILEWSKI J.O., NEMEC R.B., THOMA D.B., Los Alamos National Laboratory, ,

LOS ALAMOS, NM,U.S.A.

PREPARATION OF PEROVSKITE POWDERS AND COATINGS BY RF-SUSPENSION PLASMA

SPRAYING 13 6 3

SCHILLER G., MULLER M„ DLR Stuttgart, Institut filr technische Thermodynamik, STUTTGART, GERMANYGITZHOFER F., University de Sherbrooke, Fac. des Sciences Appliquees, Department de Genie Chimique,SHERBROOKE, CANADA

XXXIV

SPLAT FORMATION FIRST STEP OF MULTITECHNIQUE DEPOSITION PLASMA SPRAYING AND

MICROWAVE PLASMA ENHANCED CVD 1369

DENOIRJEAN A., GRIMAUD A., FAUCHAIS P., Universite de Limoges, Laboratoire de Materiaux Ceramiques et

Traitements de Surface ESA CNRS 6015, Equipe Plasma Laser Materiaux, LIMOGES, FRANCE

TRISTANT P„ TIXIER C, DESMAISON J., Universite de Limoges, Laboratoire de Materiaux Ceramiques et

Traitements de Surface ESA CNRS 6015, Equipe Ceramiques Nouvelles, LIMOGES, FRANCE

TRIPLEX - AN INNOVATIVE THREE-CATHODE PLASMA TORCH 1375

ZIERHUT J., HASLBECK P., LANDES K.D., Universitat der Bundeswehr Munchen, Plasma Techniques Laboratory,NEUBIBERG, GERMANY

BARBEZAT G„ MULLER M., SCHUTZ M„ Sulzer Metco AG, WOHLEN, SWITZERLAND

STUDY ON UNDERWATER THERMAL SPRAYING 13 81

MINAMI N„ HONGAWA T„ Kochi Prefectural Industrial Technology Center, KOCH1-SHI, JAPAN

NOJIRI Y., NISHIDA M„ ARAKI T., Ehime University, MATSUYAMA-SHI, JAPAN

KATSUMURA M„ Shikoku National Industrial Research Institute, TAKAMATSU-SHI, JAPAN

VACUUM HEAT TREATMENT AND LOW PRESSURE CARBURIZING OF APS NiCr COATINGS 13 8 7

GAUDIN C, JACQUOT P., Innovatique, CHASSIEU, FRANCE

PRINCE P., Vide Express, CHESSIEU, FRANCE

RIVOLET D„ VVHAMELi.P., Sulzer Metco, VILLEFONTAINE, FRANCE

PRACTICAL EXPERIENCES WITH A NEW PORTABLE HVOF SPRAYING AND CUTTING SYSTEM. . . 13 93

VORONETSKY A.V., JAGODNIKOV D.A., FILIMONOV L.A., SUCHKOV S.A., SHIRJAEVA N.V., ELISSEEV A.A.,

BORONIN E.V., MGTU Bauman, MOSKVA, RUSSIA

THE HIGH-VELOCITY PLASMA SPRAYING 1399

KLUBNIKIN V.S., State Technical University of Sankt-Petersburg, Polypiasma Ltd., SANKT-PETERSBURG,

RUSSIA

REACTIVE PLASMA SPRAY FORMING FOR FERROMAGNETIC MATERIALS SYNTHESIS ON Al

SUBSTRATE 1405

FOLIO F., LACOUR A., Universite Blaise Pascal, LIMA-CUST, AUBIERE CEDEX, FRANCE

THERMAL SPRAY DEPOSITION OF A COPPER COATING ON ALUMINIUM USING THE PROTAL

PROCESS 1409

AYRAULT-COSTIL S., MONTAVON G., CODDET G, IPSe, Laboratoire d'Etudes et de Recherches sur les Materiaux

et Proprietes de Surface (LERMPS), BELFORT, FRANCE

RIGOLLET F„ FRENEAUX O., IREPA-Laser, ILLKIRCH, FRANCE

FOLIO F„ BARBEZAT G., Sulzer Metco AG, WOHLEN, SWITZERLAND

WASEN P., DIARD A., QUANTEL, LES ULIS, FRANCE

POST TREATMENT OF PLASMA SPRAYED WC-Co-Ni COATINGS BY HIGH FREQUENCYINDUCTION HEATING 1415

MATSUBARA Y„ TOMIGUCHI A., Dai-Ichi High Frequency Co. Ltd, KAWASAKI, JAPAN

HARAGUCHI H„ HAYASHI H., ITO H„ Koei Seiko Co., Ltd, FUKUOKA, JAPAN

SUPERSONIC INDUCTION PLASMA SPRAYING OF YTTRIA STABILISED ZIRCONIA FILMS 1419

MAILHOT K„ GITZHOFER F., BOULOS M.I., Universite de Sherbrooke, Fac. des Sciences Appliquees, Department

de Genie Chimique, SHERBROOKE, CANADA

XXXV

AN IMPROVEMENT OF Cr3C2-NiCr SPRAYED COATINGS FOLLOWED BY CHROMIUM DIFFUSIONTREATMENT 1425

TAKEUCHI J., MURATA Y., HARADA Y„ Tocalo Co. Ltd, KOBE, JAPAN

TOMITA T., Hyogo Prefectual Institute of Industrial Research, Technical Centerfor Machinery and Metals,

HYOGO-KEN, JAPAN

NAKAHAMA S., GO T., Ebara Co., Welding Technical Center, CH1BA PREF, JAPAN

LATEST GAS TURBINE REPAIR TECHNIQUES USING LASER TECHNOLOGY 1431

WILLIAMS A.D., HUMPHRIES J.L., Wood Group Heavy Industrial Turbines Ltd, DUNDEE, SCOTLAND

EFFECT OF SPRAY PARAMETERS ON THE PLASMA IN HIGH PRESSURE PLASMA SPRAYING

UP TO 300 kPa 14 3 7

SODEOKA S„ SUZUKI M., INOUE T., UENO K., Osaka National Research Institute, A1ST, OSAKA, JAPAN

BASIC RESEARCFI FOR REACTIVE PLASMA SPRAYING OF Ti02 1443

SUZUKI M„ SODEOKA S., INOUE T„ UENO K., Osaka National Research Institute, AIST, OSAKA, JAPAN

ELECTRON BEAM POST-TREATMENT OF COATINGS PLASMA SPRAYED ONTO MAGNESIUM

ALLOYS 1449WIELAGE B., FLEISCHER K., Technical University Chemnitz, Institute for Composite Materials, CHEMNITZ,GERMANY

CHARACTERISATION OF MOLYBDENUM COATINGS BY A NEWLY DEVELOPED FLAME SPRAY

PROCESS 1455

CALLA E„ MODI S.C., Metallizing Equipment Co. PVT. Ltd., JODHPUR, INDIA

NIKU-LARI A., Institut Industriel de Transferts de Technologie-International (llTT-International),GOURNAYSUR MARNE, FRANCE

MICROPLASMA SPRAYING 14 61YUSHCHENKO K., BORISOV Y„ PEREVERZEV Y., VOJNAROVITCH S., DARMOCHVAL V„ BOBRIC V.,E.O, Paton Electric Welding Institute, KIEV, UKRAINE

RAMAEKERS P., TNO Metaalinstituut, APELDOORN, NETHERLANDS

RAA G., Philips CMTI, EINDHOVEN, NETHERLANDS

ROLE OF ATMOSPHERE DURING PLASMA PROCESSING FOR APPLICATION TO PLASMA

SPRAYING OF ALUMINUM ONTO POLYETHYLENETEREPHTALATE (PET) 1469

HUBERT H„ BLEIN F„ FRESLON A., CEA Le Ripautt, MONTS, FRANCE

JEANDIN M., Ecole des Mines de Paris/C2P - Centerfor Plasma Processing, EVRY, FRANCELE PAVEN C, HOUDY P„ Universite d'Evry Val d'Essonne/C2P, EVRY, FRANCE

COMPUTATIONAL CODE FOR DETONATION SPRAYING PROCESS 1475

GAVRILENKO T.P., NIKOLAEV Y.A., ULIANITSKY V.Y., Institute ofHydrodynamics ofLavrentyev,NOVOSIBIRSK, RUSSIA

KIM M,C„ Research Institut ofIndustrial Science and Technology ,POHANG, KOREA

HONG J.W„ Samchully Co.,KOREA

APPLICATION OF OVERDRIVEN GASEOUS DETONATION FOR SPRAYING 1485

GAVRILENKO T.P., NIKOLAEV Y.A., ULIANITSKY V.Y., Institute ofHydrodynamics ofLavrentyev,NOVOSIBIRSK, RUSSIA

A NEW ARC SPRAY SYSTEM TO SPRAY HIGH DENSITY, LOW OXIDE COATINGS 1489UNGER R.H., BELASHCHENKO V.E., KRATOCHVIL W.R., DUNKERLEY J.P., SEDOV V., SMITH E.A., TafaIncorporated, CONCORD, NH, U.S.A.

xxxvi

PRACTICAL EXPERIENCE WITH THE NEW GENERATION OF LOW-COST, PORTABLE HVOFs 14 95

HEATH G.R., DUMOLA R.J., Eutectic Corporation, CHARLOTTE, NC, U.S.A.

HEATING AND ACCELERATION OF CERAMIC PARTICLES IN 20-kA PULSED PLASMA 1501

MIYAMOTO M„ Fuji electric corporation R&D, Ltd., ICHIHARA, JAPAN

SAKUTA T„ TAGO M., Kanazawa University, Department ofElectrical & Computer Eng., KANAZAWA, JAPAN

THERMAL SPRAYING ON GRAPHITE 1507

MESRATI N., Ecole Nationale Polytechnique d!Alger, Departement de Metallurgie, ALGER, ALGERIE

AJHROURH H„ DU N., TREHEUX D„ Ecole Centrale de Lyon, UMR 5621, Ingenierie et Fonctionnalisation des

Surfaces - MMP, ECULLY, FRANCE

PREBRAZING OF CERAMICS BY PLASMA SPRAYING FOR METAL-CERAMIC JOINING 1513

KARA-SLIMANE A., TREHEUX D., Ecole Centrale de Lyon, UMR 5621, Ingenierie et Fonctionnalisation des

Surfaces - MMP, ECULLY, FRANCE

NiCrAIY COATINGS IN YAG LASER COMBINED LOW PRESSURE PLASMA SPRAYING 1517

EGUCHI N„ ZHOU Z„ SHIRASAWA H„ The Advanced Materials Processing Institute Kinki, HYOGO, JAPAN

OHMORI A., Osaka University, Joining and Welding Research Institute (JWRI), OSAKA, JAPAN

RADIO-FREQUENCY SUSPENSION PLASMA SPRAYING OF COBALT SPINEL ANODES FOR

ALKALINE WATER ELECTROLYSIS 1523

MUELLER M., HENNE R., SCHILLER G„ DLR Stuttgart, Institutfur technische Thermodynamic STUTTGART,

GERMANY

BOULOS M.I., GITZHOFER F., Universite de Sherbrooke, Fac. des Sciences Appliquees, Department de Genie

Chimique, SHERBROOKE, CANADA

HEIMANN R.B., Freiberg University of Mining and Technology, Institut of Mineralogy, FREIBERG, GERMANY

Symposium 9 : Thermal barrier coatings 1529

THERMAL BARRIER COATINGS - WHY, HOW, WHERE AND WHERE TO 15 31

WIGREN J., PEJRYD L., Volvo Aero Corporation, Combustor Division, Thermal Spray Coatings, TROLLHATTAN,

SWEDEN

PLASMA SPRAYING OF FUNCTIONALLY GRADED Zr02/NiCoCrAlY COATING SYSTEM USING

COMPOSITE POWDERS 1543

KHOR K.A., GU Y.W., DONG Z.L., Nanyang Technological University, School of Mechanical & Production

Engineering, SINGAPORE, SINGAPORE

INFLUENCE OF BONDCOAT SURFACE CHARACTERISTICS ON THE PERFORMANCE OF TBC

SYSTEMS 15 49

KNIGHT R., SMITH R.W., Drexel University, Dept. of Materials Engineering, Center for the Plasma Processing of

Materials (CPPM), PHILADELPHIA, U.S.A.

ZHANGXIONG D„ Wuhan transportation University, Dept. of Marine Mechanical Engineering, WUHAN, CHINA

KIM E.-H,, Korean Electric Power Research Institute (KEPRI), Power Generation Research Laboratory, TAEJEON,

KOREA

SAHOO P., BUCCI D., Sermatech International, Inc., LIMERICK, PA, U.S.A.

xxxvii

INFLUENCE OF INTERFACIAL TEMPERATURE ON THE ADHESION PROPERTIES OF

PLASMA-SPRAYED METAL-CERAMIC COATINGS 1555

LIMA C.R.C., Methodist University of Piracicaba, Technology Center, SANTA BARBARA D'VESTE, SP, BRAZIL

TREVISAN R.D.E., State University of Campinas, Dept. de Engenharia de FabricacaoFaculdade de EngenhariaMecanica, CAMPINAS, SP, BRAZIL

HIGH TEMPERATURE OXIDATION OF BOND COATS IN THERMAL BARRIER SYSTEMS 15 61

PERALDI R., MONCEAU D., PIERAGGI B., ENSCT, Laboratoire de Cristallochimie, reactiviti et protection des materiaux,

UPRESA 5071, TOULOUSE, FRANCE

MALIE A., SOCHATA, CHATELLERAULT, FRANCE

THE EFFECT OF BOND COAT CREEP ON RESIDUAL STRESSES AND DEBONDING IN PLASMA

SPRAYED THERMAL BARRIER SYSTEMS 1565

TSUI Y.C., THOMPSON J.A., CLYNE T.W., University of Cambridge, Department of Materials Science and

Metallurgy, CAMBRIDGE, U.K.

HIGH HEAT FLUX THERMAL CYCLING OF MULTI-LAYERED DEPOSITS USING A HVOF GUN ;

MODELISATION AND EXPERIMENTS 15 71

VERDY C, RIAD H„ RAVIART 0„ ABBOUDI S„ CODDET C, IPSe, Laboratoire d'Etudes et de Recherches sur les

Materiaux et PropriMs de Surface (LERMPS), BELFORT, FRANCE

CORNU D„ DE MONICAULT J.-M., Society European Propulsion, VERNON, FRANCE

ANISOTROPIC MICROSTRUCTURE OF PLASMA-SPRAYED DEPOSITS 1577

ILAVSKY J„ Institute of Plasma Physics, Academy of Sciences of the Czech Republic (AVCR), PRAHA 8,CZECH REPUBLIC

LONG G.G., ALLEN A.J., Nat. Inst, ofStandards and Technology (N1ST), GAITHERSBURG MD, U.S.A.

LEBLANC L„ PRYSTAY M., MOREAU C, National Research Council Canada, BOUCHERVILLE, QUEBEC,CANADA

ENHANCED ATMOSPHERIC PLASMA SPRAYING OF THICK TBCs BY IMPROVED PROCESS

CONTROL AND DEPOSITION EFFICIENCY 1583

LUGSCHEIDER E„ LADRU P., Aachen University of Technology, Materials Science Institute, AACHEN,

GERMANY

GOURLAOUEN V„AirLiquide CTAS, SAINTOUEN L'AUMONE, FRANCE

GUALCO C, Ansaldo Richerche, GENOVA, ITALY

OXYGEN TRANSPORT THROUGH THE ZIRCONIA TOP COAT IN THERMAL BARRIER COATING

SYSTEMS 15 8 9

FOX A.C., CLYNE T.W., University of Cambridge, Department ofMaterials Science and Metallurgy,CAMBRIDGE, U.K.

THERMAL EXPANSION OF THERMALLY SPRAYED COATINGS 1595

BEGHINI M., BERTINI L., FRENDO F., University of Pisa, Dipartimento di costruzioni Meccaniche e Nucleari,

PISA, ITALY

THERMAL SHOCK RESISTANCE OF PLASMA-SPRAYED CERAMIC COATINGS WITH TWO- AND

THREE-LAYERS 16 01

KWEON Y.-G„ KIM H.-J., Research Institut ofIndustrial Science and Technology , POHANG, KOREA

STUDY OF DAMAGE PROCESSES IN PLASMA SPRAYED BOND COAT UNDER THERMAL

CYCLING 1607

BONNET P., ABBOUDI S„ NORMAND B., IPSi, Laboratoire d'Etudes et de Recherches sur les MatMaux et

ProprUt&s de Surface (LERMPS), BELFORT, FRANCE

xxxviii

PHASE COMPOSITION CHANGES IN PLASMA SPRAYED ZIRCON - ALUMINA TUBES 1613

DUBSKY J., KOLMAN B.J., Institute ofPlasma Physics, Academy of Sciences of the Czech Republic (AVCR),PRAHA 8, CZECH REPUBLIC

BUCHAL A., Technical University in Brno, FS-UMI-OSFA, BRNO, CZECH REPUBLIC

COMPARISON OF THERMAL CYCLING EXPERIMENTS ON THICK THERMAL BARRIER COATINGS. . 1617

HAUBOLD T., BMW, Rolls-Royce AeroEngines, OBERURSEL, GERMANY

WIGREN J., Volvo Aero Corporation, Combustor Division, Thermal Spray Coatings, TROLLHATTAN, SWEDEN

GUALCO C, Ansaldo Richerche, GENOVA, ITALY

EVALUATION OF RESIDUAL STRESSES WITHIN PLASMA-SPRAYED ZIRCONIA (Zr02-Y203 8%wt)COATINGS 1623

BARADEL N., BIANCHIL., BLEIN F„ FRESLON A., CEA Le Ripault, MONTS, FRANCE

JEANDIN M., Ecole des Mines de Paris/C2P - Centerfor Plasma Processing, EVRY, FRANCE

CERETTI M., CENSaclay, LLB, GIF SUR YVETTE, FRANCE

LU J., Universite1 de Technologie de Troyes, GSM/LASMIS, TROYES, FRANCE

THERMAL EXPANSION PROPERTIES OF PLASMA-SPRAYED THICK COATINGS 1629

LEE Y.-K., KIM H.-J., CHANG R.-W., Research Institut of Industrial Science and Engineering (RIST), POHANG,

KOREA

DESIGN AND EXPERIMENTS OF GRADED THERMAL BARRIER COATINGS BY PLASMA

SPRAYINGS 1635

AHN H., HONG S.H., Seoul National University, Departement ofNuclear Engineering, SEOUL, KOREA

EVOLUTION OF THE MICROSTRUCTURE OF PLASMA-SPRAYED DEPOSITS DURING HEATING 1641

ILAVSKY J., Institute of Plasma Physics, Academy of Sciences of the Czech Republic (AVCR), PRAHA 8,

CZECHREPUBLIC

LONG G.G., ALLEN A.J., Nat. Inst, ofStandards and Technology (NIST), GAITHERSBURG MD, U.S.A.

VACUUM PLASMA SPRAYED Zr02-BASED THERMAL BARRIER COATINGS FOR AEROSPACE

APPLICATIONS 1645

BRZEZINSKIT., CAVASIN A., GRENIER S„ KHARLANOVA E, KIM G., TSANTRIZOS P., ProTeCa division of

PyroGenesis Inc., MONTREAL, QUEBEC, CANADA

STRESS INTENSITY FACTORS FOR INTERFACIAL CRACKS IN THICK THERMAL BARRIER

COATINGS 16 51

BJERKEN C, PERSSON C, Lund University, Department Materials Engineering, LUND, SWEDEN

PROPERTIES OF FUNCTIONALLY GRADED ZIRCONIA COATING BY GAS TUNNEL TYPE PLASMA

SPRAYING 1657

KOBAYASHI A., Osaka University, Joining and Welding Research Institute (JWR1), OSAKA, JAPAN

MICROSTRUCTURES AND CHARACTERIZATION OF ZIRCONIA COATINGS FORMED BY LASER

COMBINED PLASMA SPRAYING 1663

ZHOU Z„ EGUCHI N., SHIRASAWA H„ The Advanced Materials Processing Institute Kinki, HYOGO, JAPAN

OHMORI A., Osaka University, Joining and Welding Research Institute (JWRI), OSAKA, JAPAN

NEW THERMAL BARRIER COATING SYSTEM FOR HIGH TEMPERATURE APPLICATIONS 1669

WILDEN J., WANK M., Technical University Chemnitz, Institute for Composite Materials, CHEMNITZ,

GERMANY

STEFFENS H.D., BRUNE M., University of Dortmund, Institute of Materials Technology , DORTMUND,

GERMANY

xxxix

Symposium 10 : Thermal spray for the next millennium 161 s

THERMAL SPRAY APPLICATION FOR THE NEXT MILLENNIUM A BUSINESS DEVELOPMENT

PERSPECTIVE 1677

KASSABJI F., JACQ G., EDF, Direction des Etudes et Recherches, Dept. Systemes Energitiques,MORETSUR LOING, FRANCE

DURAND J.P., Magetex, ,FRANCE

TOWARDS A BETTER CONTROL OF THERMAL SPRAY PROCESSES 16 8 1

MOREAU C. National Research Council Canada, Industrial Materials Institute, BOUCHERVILLE, QUEBEC,CANADA

KEY WORD INDEX 1-1

AUTHORINDEX 2-1

COMPANIES AND INSTITUTIONS INDEX 3-1

xl