Gardobond 24d Imu Sds Ver1

8/10/2019 Gardobond 24d Imu Sds Ver1

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SAFETY DATA SHEETaccording to Regulation (EC) No. 1907/2006

Gardobond 24D IMU

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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE

COMPANY/UNDERTAKING

English

Product information

Commercial Product Name Gardobond 24D IMU

Recommended use :Phosphating solution for metal surfaces.

Company: Chemetall plc

Denbigh RoadBletchley Milton Keynes MK1 1PB

Lead Organisation:Contact person:Telephone: 01908 649333Telefax: 01908 373939

Product safety:Telephone: +44(0)1908 649333

E-mail address: [email protected]

Emergency telephone: 01908 649333

2. HAZARDS IDENTIFICATION

Risk advice to man and the environment

Classification:

Carcinogenic Category 3 R40Limited evidence of a carcinogenic effect.

sensitizing R42/43May cause sensitization by inhalation and skin contact.

Dangerous for the

environment

R51/53Toxic to aquatic organisms, may cause long-term

adverse effects in the aquatic environment.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous components

Zinc bis (dihydrogen phosphate) 10.00 - 25.00 %CAS-No.:13598-37-3 EINECS-No.: 237-067-2

Classification: Xn; R22 N; R50/53

Orthophosphoric acid 5.00 - 10.00 %

CAS-No.:7664-38-2 EINECS-No.: 231-633-2Classification: C; R34


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Nickel(II) nitrate 2.50 - 10.00 %

CAS-No.:13138-45-9 EINECS-No.: 236-068-5Classification: O; R 8 Xn; R22 Carc.Cat.3; R40 R42/43 N; R50/53

WEL substance:Manganese bis(dihydrogen phosphate) 2.50 - 10.00 %

CAS-No.:18718-07-5 EINECS-No.: 242-520-2

4. FIRST AID MEASURES

General advice:

Take off contaminated clothing and shoes immediately.

Eye contact:In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Skin contact:

Wash off immediately with soap and plenty of water.

Inhalation:Move to fresh air. If symptoms persist, call a physician.

Ingestion:Clean mouth with water and drink afterwards plenty of water. Call a physician immediately.

5. FIRE-FIGHTING MEASURES

Specific hazards during fire fighting:Combustion may cause: nitrogen oxides (NOx)

Special protective equipment for fire-fighters:

In the event of fire, wear self-contained breathing apparatus.

Suitable extinguishing media:Carbon dioxide (CO2), Dry powder, Water spray, Alcohol-resistant foam

Further information:Collect contaminated fire extinguishing water separately. This must not be discharged intodrains.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions:Use personal protective equipment.

Environmental precautions:Do not flush into surface water or sanitary sewer system.

Methods for cleaning up:

Soak up with liquid binder (sand, kieselguhr, acid binder, universal binder). Sweep up or vacuumup spillage and collect in suitable container for disposal. Ensure adequate ventilation.

7. HANDLING AND STORAGE

Handling

Safe handling advice:

Have eye wash bottle or eye rinse ready at the work place. Avoid contact with eyes. Providesufficient air exchange and/or exhaust in work rooms.


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Advice on protection against fire and explosion:

No special protective measures against fire required.

Storage

Requirements for storage areas and containers:

Keep container tightly closed in a dry and well-ventilated place. Store at room temperature in theoriginal container.

Further information:

Avoid contact with metals.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Orthophosphoric acid 7664-38-2

Value Update Basis

TWA 1.00 mg/m3 02 2006 EU ELV

STEL 2.00 mg/m3 02 2006 EU ELV

TWA 1.00 mg/m3 2007 EH40 WEL

STEL 2.00 mg/m3 2007 EH40 WEL

Nickel(II) nitrate 13138-45-9

Value Update Basis

TWA 0.10 mg/m3 as Ni 2007 EH40 WEL

SKIN_DES as NiCan be absorbed through the skin.

2007 EH40 WEL

TWA 0.50 mg/m3 as Ni 2007 EH40 WEL

SKIN_DES as NiCan be absorbed through the skin.

2007 EH40 WEL

Manganese bis(dihydrogen phosphate) 18718-07-5

Value Update Basis

TWA 0.50 mg/m3 as Mn 2007 EH40 WEL

Personal protective equipment

Respiratory protection:

Not required; except in case of aerosol formation.

Hand protection:Material: NeopreneGeneral advice: The selected protective gloves have to satisfy the specifications of EU Directive

89/689/EEC and the standard EN 374 derived from it., The exact break through time can beobtained from the protective glove producer and this has to be observed.

Eye protection:Tightly fitting safety goggles

Skin and body protection:

Protective suit

Hygiene measures:

Avoid contact with the skin and the eyes. Keep away from food, drink and animal feedingstuffs.Take off contaminated clothing and shoes immediately. Wash hands before breaks and at theend of workday.


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9. PHYSICAL AND CHEMICAL PROPERTIES

Form: liquidColour: green

Odour: none

Flash point: not applicable

Density: ca. 1.4 g/cm3

Solubility/qualitative: completely miscible

pH: ca.3.0at: 50 g/Lat: 20 C

Viscosity: ca. 15 sat 20 C

10. STABILITY AND REACTIVITY

Conditions to avoid:

To avoid thermal decomposition, do not overheat.

Materials to avoid:

Contact with organic substances or other reducing agents can form mixed nitrous gases (toxic).,Incompatible with bases.

Hazardous decomposition products:

nitrogen oxides (NOx)

Hazardous reactions:Gives off hydrogen by reaction with metals.

Thermal decomposition:

> 320 C

11. TOXICOLOGICAL INFORMATION

Skin irritation:Irritating to skin.

Eye irritation:Irritating to eyes.

Sensitisation:May cause sensitization by inhalation and skin contact.

Further toxicological information:Limited evidence of a carcinogenic effect.


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12. ECOLOGICAL INFORMATION

Elimination information (persistence and degradability):

Further information:Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration.

13. DISPOSAL CONSIDERATIONS

Waste key for the unused product:

060300 wastes from the MFSU of salts and their solutions and metallic oxides

Product:

Dispose of as hazardous waste in compliance with local and national regulations.

Contaminated packaging:

Dispose of as hazardous waste in compliance with local and national regulations.

14. TRANSPORT INFORMATION

Regulation : ADR

UN/ID No.: 1805

Proper shipping name: Phosphoric acidPackaging group: III

Class: 8ADR/RID-Labels: 8

Regulation : RIDUN/ID No.: 1805

Proper shipping name: Phosphoric acidPackaging group: IIIClass: 8

ADR/RID-Labels: 8

Regulation : IMDGUN/ID No.: 1805

Proper shipping name: PHOSPHORIC ACIDPackaging group: IIIClass: 8EmS: F-A S-B

Regulation : IATA_CUN/ID No.: 1805Proper shipping name: PHOSPHORIC ACID

Packaging group: IIIClass: 8

Regulation : IATA_P

UN/ID No.: 1805Proper shipping name: PHOSPHORIC ACID

Packaging group: IIIClass: 8


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15. REGULATORY INFORMATION

Hazardous components which must be listed on the label:

Nickel(II) nitrate

Labelling: Harmful

Dangerous for the environment

R-phrase(s): R40 Limited evidence of a carcinogenic effect.R42/43 May cause sensitization by inhalation and skin

contact.

R51/53 Toxic to aquatic organisms, may cause long-termadverse effects in the aquatic environment.

S-phrase(s): S23 Do not breathe spray.S36/37 Wear suitable protective clothing and gloves.S45 In case of accident or if you feel unwell, seek

medical advice immediately (show the label wherepossible).

S60 This material and its container must be disposed of

as hazardous waste.S61 Avoid release to the environment. Refer to special

instructions/ Safety data sheets.

Other regulations:

The product is classified and labelled in accordance with EC directives or respective nationallaws.

16. OTHER INFORMATION

Text of R phrases mentioned in Section 3R 8 Contact with combustible material may cause fire.

R22 Harmful if swallowed.R34 Causes burns.R40 Limited evidence of a carcinogenic effect.

R42/43 May cause sensitization by inhalation and skin contact.R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.

Text of R phrases mentioned in Section 3

The information provided is based on our current knowledge and experience and apply to the

product as delivered. Regarding the product properties, these are not guaranteed. The delivery ofthis safety datasheet does not free the recipient of the product from his own responsibility to

follow the relevant rules and regulations concerning this product.

Documents

Gardobond 24d Imu Sds Ver1