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^ UNITED STATES ENVIRONMENTAL PROTECTION AGENCYin'lur- REGION viSt il'- HOUSTON BRANCH
6608 HORNWOOD DRIVE
HOUSTON. TEXAS 77074
DATE:/.2-^>- -
SUBJECT: CLP Data Review ^ /. /y
FROM: William Langley, Deputy Project Officer /VVL'I^" ' '^Region VI ' f COn-' .
TO: Keith Bradley LTiHazardous Waste Section (6ES-SH) Q
0A review of the laboratory raw data for case # S6 7 has been completedby members of the Laboratory Section. Attached please find copies of therelevant QC notices for the following samples.
INORGANIC:
ORGANIC: ^V/^/ - ^//33 ^-Z^/^^3
/^^ ___________ _________ _
^^2 S^
Please call me if you have any question '~y
^Attachments
C^c 1<rn ^L I?«TT^W7A<. T^u^ (S^-^o
iVtV^ORGANIC QA CHECKLIST '
Contractor •U STijg fe- Contract <• (•>? - 01 ' fpl HO ^
Case No.____70 gi7______ Matrix /O^ (ev^f go[L
Site VE .T^C. USTW 1 0 4 - 7 7 1 1 3
Smple No. p^l Zl - F 1 3 3 (IN-LL.U.UKCJ______ _________
F^fW _________ _________ _________
OVERALL COMMENTS (TO BE COMPLETED BY EPA PERSONNEL)
Data Completeness ____ Acceptable____ Not Acceptable v \ 5^^ I———— [-'CWtMfc-MTl J
Instrument Tune ____ Acceptable____ Not Acceptable____~
Ctiromatography ____ Acceptable____ Not Acceptable____
Blank Analysts ____ Acceptable____ Not Acceptable____
Matrix Spikes ____ Acceptable____ Not Acceptable____
Duplicates ____ Acceptable____ Not Acceptable____
Surrogate ____ Acceptable____ Not Acceptable____
field Blank ____ Acceptable____ Not Acceptable____
OTHER COMMENTS OR CLARIFICATIONSThe QC submissions required with this Case data were woefully deficient
and many resubmissions were requested. When these are received and reviewed
and found to be acceptable, then the Case data submitted by UST will also
be acceptable. The deficiencies are cited in the TEL to SMO (attached),
but basicly are those of poor/incomplete/missing required forms. For the
most part the data appears to be complete in so far as the analysis,stand-
ards, spikes,etc., requirements were met. Without the resubmissions
SEE ATTACHED COMTINUATIOK SHEET
mCD
ORGANIC QA CHECKLIST ^CONTINUATION PAGE LT»
0CASE NO. 3089______________ SITE VERTAC______________ 0
COMMENTS:
the Case 30^9 data by UST must be considered only as semi-quantitative
at best or rejected totally. For the most part, the analysis found lowluvul ur lidLkal uuuJ uuiupuiiunLij In Lliu uLlaille fJ'acLluns and Cne samefor the semi-volatiles, except for the following samples;
F 4131 SV had 5-6 unknowns at low 5-20 ppb;
F 4132 SV diluted 1:30 had 6 unknowns at higher levels;
F 4133 VOA had very large MIBK peak (also common lab backgroundp e a k ) a t about ii-uuu ppo.some other peaks o±' hydrocarbonnature appear to be present also. The S? fraction,1:10diluted, had no HSL but had 1 unknowl at about 4000 ppb;
F 4229 Voa again large MIBK peak at 5450 ppb, with many other______________peaks as Well. The SV Showed sevgl-al nnlfnnwnaat-. 1n-J|n ppm,
____F 4230 Only VOA fraction was analyzed and showed low TOlatj1es;
__________The SV fraction of this sample was not reported and presum-ably, the lack of analysis was known to 5MO or was not a
__________requiremnt____________________________________
Because of difficulties with the pesticide analysis under the new
prot o c ol,a separate submission of this data was received on 11/14/JJ4.The narrative supplied stated that F4131 and F4132 samples had to be
re-analyzed with another case and results -for those two were not inclu4
ed. To date,this data has not been received by 6ES_HL. See the TRL toSMO relative to F 4229 pesticide fraction, wherein the lab reported
466 ppb of DDE based on what this reviewer thought was poor results.
QA summary and results with this fraction were satisfactory,although many
samples had to be diluted causing poor surrogate recovery of DBC. The
matrix spike/duplicate results were good,with only dieldrin out of limits.
Of most concern with the pesticide samples was that for p,p'-DDT, the
% RSD was>10 % in the calibration linearity check. As a result, thevalues given for DDT should be considered as qualified to semi-quant
\0cc
ORGA1IIC QA CHECKLIST <;:!'CONTINlTAIIOlt PAGE LPi
CASE NO. 3089________________ SITE 7Ee-^_____________ S
COMMENTS:
itatlve. The sample results in paricular for F 4125 ( 76 ppb) and
F 4126 ( 210 ppb) where DDT was reported should be considered asCUEF*''*' °° t" *h° °'"•'"''' irainc.———————————————————————————The high level of endrin and DDT breakdown on the confirmation GC
column was another area of concern for which the lab either was unawarep—————————————————————————————————————————————————or took no action. Because this was on the confirming and not the quant-
itatlon column, the breakdown level did not effect the results.
Considering the overall pesticide data, most of the results were good.
~7!SW&• ^AW
In Reference to Case No(s); r~-^os-7 "o
———————————————_1 •;3-Contract Laboratory Program ir\
REGIONAL/LABORATORY COMMUNICATION SYSTEM0Telephone Record Log
Date of Call:
Laboratory Name: if, ?', 7'g;7"/f^^___________
Lab Contact: Jft-f^ Lpff^?5 l5eV fe- fe'0l ) 7 ?-2 -o7^0-0. — ^ — — - /
Region: YT - 1-kr^-ri^___________Regional Contact: FA, L. Y^tTTg'g- Ql C?l q yV-C, 77 |
Call Initiated By: __ Laboratory ^* Region
In reference to data for the following sample number(s);
£A-Sg P^T<^ USTC.^--7-71 1 3 9ur7,^-rrey 'VS-A^
fJS^c^-SS. /^r^L •ff-i-cj" 0-f f3Ji\J lA^-'- CfWv.sa^.Summary of Questions/Issues DiscuMesb--^^ ^^^ RNV\ cJ^'cA-^ ^4^4 {'
I. pgft.<AS' ^v^.v^s^'^r(J7^(^c(-sft^?^Tg---^^^»^^fe'^g)^L-y Fee-LegU-U.T INTCL-^pg ^J^nZ-tVA •SZI ^B^^ \^!'y^feftC. C<^^l^RATKt^>ptrgfA "C5C y^gP rfrglsTr ^LPtM'- SOW.M.ftIg.Y (\/dL-A/(Lgi) *^^^FfffcrA TgL •R.fi.S. (_fth^,s -fAt«l'N'&-')^ Fv^lMXEC frNP Fb>t gTTIt^f^tf^gg-^Y C-f,L.c .i,fttgr; "/'o lg-S>3 ftT,A3 yo0 Vfti-^g? Ftfg^v/ o Lpm. es ft^A? F ng. ffw^r ^ to'-si r\mz.< . ^z_u_. l iDg-iM. sc. o^="a^;
^. Pe-iTvClOg <^sN\t-fSI:J y?ft-T(\ '>&WL£ I'-^-Z-a-^ —^K____L^ftYS. TO ^gCftTtl<- Pr ro WneJ.'F-r TtV\i rWftL>f?l's____'JsAA-^g-^- •>^Cru up l-i (r^t- POg wftii tS.Q^Ma-TVi . ('.l TgJ iaT'-
[rs^-eii't- f i-^Yz-g i'. f^o^-Qseg ftTT^iA ^ver-n .
SH^P'Ve^^ OP .f?.E^OC-UTl6^_;______________________________ITfcX \ TCi ^C Y^C 'JLfiM.ITT'FO •. iTfcl^V 2- TO V^g C^Te-C.fa-lO
mJ L. ^JT} - (z.//y^Signature Date '
Distribution: ^Lab Copy, (2) Region Copy, (3) SMO Copy (^ j (_ ft5f /PfrTP, (.Wl
In Reference to Case No(s): CO
3o^ °5_______ • t-Contract Laboratory Program \r\
REGIONAL/LABORATORY COMMUNICATION SYSTEM QTelephone Record Log _
Date of Call: l 2 . 1 i ^ l f { V_______________
Laboratory Name: L/. Y. TIZ^T It^r-___________
Lab Contact: '3{\r^ Lftr>A'?5 rgF^C-r- fe'0l) 7 ?-2 -'^T'O'O
Region: Yl — tj-tf^S ~Z'y<\]__________Regional Contact; fA, L. Y^lTTe-g- C'7( ' ; l I 5 -C, 77 |
Call Initiated By; __ Laboratory ^ Region
In reference to data lor the following sample number(s);
CA-Se P( T^ [A STC. ^ S F - 7 - ^ 1 1 3 <^i7^T-rEt7 ^{s-fsj-
Summary of Questions/Issues Discussed:
1 . pg<?.^\S fA^'SSt'lsTCJ- fN-C-uv^r'LgTC U . (^^fofyOg-L-Y FtC-LCIOcnA-T ll\fLL^.<3C FcnZ-M •SZI ffir^P^i^L Q\L(t?K.P,TfcMJ
Pve_fA •GC v?.eWrt>JT nL^^vip. sa.(vMv\.ftig.Y (ygt^ftTU-ediVFa-g.fA -EL ^.fi.S. ^fti^fts -fAi«i'N-&-\ FvygM .gE- ftwopi^ggI fA.^>^f^>fft.^Y L.A^C- .L-ftTgr? "Ai tg-;t3 ftr^J ?u D \^mgS F^\] a Lp.-n' c; fii>A? Fvrfe •\3;NAQr t t>M fiJ-a. vrr, l ryg^M -y lOp-rppFy«. 0\=-nT 3tg jnve- I f(f(rf - T'c're- '.fer CF -rnv ftig.g-f Ai-r '-vig-ig-et-T Fwe-fA. -z. (_o^:0s) Rrie- ftivyi t i»,Tit.tX: si^cfcE-
h^> n^CLULft-re- cF^I^? 1^^ /^SO) ftaF ^3^-^w^..
„?. Pe-iTlciQg <>^^>-~/';LJ y7ft-T^ ^&v^r»Lg l=-^2.a.y —ftS,KLfeYS. TQ fecttCT^ Pn \A-^F-? -T-frv'S ft-r^L- l'S_
____wv<p?e-^- >-^ru not-) a-^- Ogg- WA^ l fY ig-Ttfff. C-1-hg. ar-tr&^p-eri i-^-yfe-^ i & fua^Qsps- ftTTft<nA »v\gN'n.
_____ITev^ I TO V?€" V^C^^-Bm-^TfO •, iTa^ 2_ TO t^g C 'ng -fa'O
/tU^ L. fc7t^~ ^A^Signature Date /
Distribution: (1) Lab Copy, (2) Region Copy, (3) SMO Copy
Envifoncnontal Protection Agency, CLP Sample Mfln«o«m«nt Office.P. 0. Box a 18. AlexDndrit. Virgin.. 22313 703/5S7-2490
Organics Analysis Data Sheet(Page 3)
Sample Number
V^^
Pesticide/PC BsConce.niraiion: (tow) Medium
Date Extracted/Prepared: 8 | \
Date Analyzed: _^pS 4 ^ | N
Cone/Oil Factor: ^.1^-——> ^0^-——>\6T)^ (U-.
(Circle One)
^-
CAS- .- - ug/lortg/Kg'Number (Circte-enBr319-84-6319-65-7319-86-858-89-976-W-8309-00-21024-S7-3959-98-860-57-172-55-972-20-833213-65-972-54-87421-93-41031-07-850-29-372-43-553494.70-557-74-98001.35-212674-11-2"11104-28-21 1 1 4 1 - 1 6 - 553469-21-912672-29-611097-69-1
11096.82-S
Alpha-BHCBeia-BHCOelia-BhcGamma-BHC (Lindane)HepiachlorAldrin | -Hepiachlor EpoxideEodosulfan 1 'Dieldrin4. 4'.DDEEndrin :Endosulfan 114.4"-DDOEndrin AldehydeEndosutfan Sulfale4.4"-DDTMethoxychlorEndrin KeloneChlonfaneToxapheneAroclor-1016Aroclw-1221Aroclor-1232Aroclor-1242Aroclor-1248Aroclor-1254
Aroclor-1260
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S01L SURROGATE PERCENT RECOVERY SUMMARY
^O?-^ '_______ Oomract Laboratory H ST^^,________ Conlr.ct No. 6^-0/-^7^0Case Ho.Lnw- . Maclluni -
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- ,--------VOLATILE--- T- --------- / ------------—- SEUI-VOLA TILE-----------------
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VALUES ARE OUTSIDE OF CONTRACT REQUIRED QC LIMITS"ADVISORY LIMITS ONLY
Comm, . V 6 G -•MS^1\US -F^-S.O-^^-
»1'5rf>^»X<- Kl-di.ui. A^-A. AiAAJX(^ - •SJUJM<W-),AA'•> . CT
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SOIL MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY
C
Lo
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RPD
Con
G u, \ • ' v> . y > -
FORM,
....NO ^9 0
FRACTION
VGASMO
SAMPLE NO.
F^SC
amSMO
SAMPLE NO,
AlACIDSMO
SAMPLE NO.
?-1
PESTSMO
SAMPLE NO.
ERISKED VALUES ARE OUTSIDE QC LI
: VOAs ^\ out ol "> ; oul
T«n»K.- :
'SO-- L » i M^4- Aa A-^. •s^1 o
COMPOUND
1.1-DlcholoretheneTrichloroeiheneChlorobenreneToluene
1,2,4-TrichloroberueneAcenaphihene2.4 DinitroioluenaOi-n-ButYlphthalatePyrcneN-NHroiodi-n-ftoDvlaminc
PentachlofophenolPhenol2-Chlorophenol4-Chloro-3-Mei hy Ipheno 1
LindaneHepiachloi •Aldrin • "Diekfiin : 1Endrin4,4'-DDT
CONC. SPIKEADDED (ua)
yo
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-V————————
MITS.
ide QC limitside QC limitsde QC limits * 'de QC limits
ontraci
odium
^
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SAMPLERESULT
——^'—,•——.^^—-*^
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———
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n2421212123194747363827
- 47...356033
5031433B45
. 50
-!°:
RECOVERY
69-17262.13760.13369.13966.1423810731.13728-892S-13536-14241 -12628.10417.10926-9025-10226-103
46-12735.13034.13231-13442-13923-134
outside QC limoutside QC limoutside QC limoutside QC lim
itsillitsits
Case No..
REAGENT BLANK SUMMARY -^ ^ i LL / |\f
Contractor L^nedir^_________- Contract No. ^-O'-^W
: -/f£E"iii
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OtTC OF1NAI.T313
——————-
FRACTION
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UiTDIX L% ~TWT.ill... CA3 NUUBER;
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COMPOUND (HSL.TIC OR UNKNOWN)
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CONC. UNITS CBOL
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Comments:
FORM IV 0 0 5 4 9 4
REAGENT BLANk |$UMlVIARY -^. F\ L-L- ^ IV
.,. - L... ___ Contracto. 0 f , 1 Contrac. No.M-£Jl 3 -^ . . . '~~~-~^ ,; 1^ -'/
F 1.6 10
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Comments:
DATE OFtNALVSIS FRACTION MATRIX
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Decaf luorotriphenylphosphine (DFTPP)CasBNo.-SAl^____ Contractor U-^—ISiSllt Z______r-nnt«,t M» ^Ol-VTI^O
instrument ID A^__ Date _^__________Time-^li^L
nin-tnxffl'fi y \ ^ r D a t a " Release Authorized 'By: "___\^_T-iin-trm-n-p-om/« ION ABUNDANCE CRITERIA XREbftTIVE ABUNDANCE
51
68
69
70
127
197
198
199
275
365
441
442
443
30.0-6Q.OXof nuu 198
ka than 2.0% of msa 69
maa 69 niatin •bundince '
leu than 2.0% of nua 69
40.0 • 60.0% of nua 198
less thin 1.0X of mass 198
base peak. 100% relative abundance
5.0 -9.0% of mass 198
10.0 • 30.0% of mast 198
greater than 1.00% of mass 198
present, but less than mass 443
greater than 40.0% of mass 198
17.0 - 23.0% of mass 442
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. VYn : WValue in parenthesis is % maff 69.Value in parenthesis is % mass 442.
THIS PERFORMANCE TUNE APPLIES TO THE FOLLOWING. SAMPLES, BLANKS AND STANDARDS.
SAMPLE ID
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United States Testing Company, Inc.Metals and Environmental Chemistry Division141B PARK AVENUEMOBOKIN, NEW JERSEY 07030 001) 702-2400 (212)043-0488
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