Colour Coated Steel

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    Colour coated sheets

    industry in India:An overview

    Perspective

    - Sanjay Sengupta

    he Indian producers of colour coated steel have introduced state-of-Tthe-art technology and are capable of producing high quality material ina cost-effective and eco-friendly manner. They should seriously considethe switchover to the use of chromate-free processes in pre-treatment andcoil coating paints. With construction and domestic appliances set to posrobust growths in future, the Indian colour coated steel industry is expectedto record a much better performance in the next few years

    SEPTEMBER 201026

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    Perspective

    SEPTEMBER 201028

    Steel is a versatile material. Theunique position of steel remainsunchallenged even today and lifewithout iron and steel remains almostunimaginable.Steel has a wide range ofapplications from the manufacturing asmall pen to automobile, railwaysystem, aircraft for both civil andmilitary operations, big engineeringand construction projects, nuclearpower stations, generation of power,housing, port construction, irrigationprojects and so on.During the last three decades or so,the world has seen many innovations inthe process of steelmaking and vasttechnological up-gradation to makesteel competitive. Steel producers allover the world are giving major thruston value addition to produce superiorquality of products in a cost effectiveand eco-friendly manner.Both long and flat steel productshave undergone remarkable orientationin product mix to suit high endapplications conforming to verystringent specifications as required bythe demanding end-users.In the flat product segment,galvanised steel in India has seen manynew applications in sectors likeconstruction (including housing),automobile, consumer durables etc.

    One of the most remarkableachievements in the Indian galvanisedstee l industry has been thedevelopment of colour coated sheets.Colour Coated SheetsColour coating usually refers to theapplication of liquid paint coat over thesubstrate in an automatic continuousprocess after pretreatment. The pre-printed colour coated steel is a veryhigh value-added product thatcombines the best properties of thesubstrates and organic coatingadditionally, imparting it an aesthetic

    finish, high degree of durability andhigh corrosion resistance capability.Basics of Coil CoatingCoil coatings, the continuouscoating of aluminium and steel coils, isa step in the manufacture of industrialsemi-finished products for use in

    building facades, washing machinesand other white goods.Coatings provide corrosionresistance, colour and surface texture.Once the metal strip has been coated,the panels are cut, shaped and fitted,which after involves high complexprocessing stages such as deepdrawing and roll forming. The coatingsurfaces should be able to withstandmechanical damage, heat chemicalsand moisture.For instance, a building has towithstand the adverse effects of wind,

    rain and sun attack and in the whitegoods sector, surfaces are exposed tovariety of abuses during use. Besidesthe above, there is a multiplicity ofapplications for coil coated materials.For each material and each step in thevarious production stages, there is anacknowledged state-of-the-art, whichrepresents current knowledge aboutthe material and its processing.ColourThe construction industry and whitegoods manufacturers have followed thecarmakers' trend towards metalliccolours for many years. While

    historically these colours were onlyavailable in polyester, polyurethane orpolyvinylidene fluoride (PVDF)topcoats, a special formulation processnow permits brilliant metallic coloursa l s o t o b e p r o v i d e d f o rpolyvinylchloride (PVC) plastisols.

    During the last three

    decades or so, the worldhas seen many innovations

    in the process of

    steelmaking and vast

    technological up-gradation

    to make steel competitive

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    SEPTEMBER 201029

    SubstratesColour coating is done

    on various substrates to

    produce the most cost

    effective, quality assured

    products with top coat

    c o m p a t i b l e w i t h

    e n v i r o n m e n t . T h e

    substrates usually used

    are:

    lhot dipper galvanised steel

    lelectro-galvanised steel

    lGalvalume

    lGalbosheets

    lAluminium

    For selecting the right kind of

    substrate, it is imperative to know that

    each material used and each step taken

    in various production stages. The

    producer should possess a thorough

    and in-depth knowledge about the

    material and its processing.

    PretreatmentPretreatment of the substrate is a

    very important operation required for

    better adhesion formability of the

    preprinted steel sheets. Major

    producers of colour coated sheets in

    India have introduced No-Rinse

    technology in place of phospating

    (phosphate coat ing) over the

    galvanised strip because of better bath

    maintenance, uniform clear structure of

    coating as well as to meet the demands

    of end-users for more flexibility of

    coated sheet.

    No-Rinse coating pre-treatment is

    a very thin layer of chemical treatment

    that bonds the coating surface of steel

    to the subsequently applied point toensure excellent point adhesion,

    corrosion resistance and durability of

    steel substrate.

    PrimerAfter pre-treatment, the primer of

    uniform layer is applied on the pre-

    treated surface. The primer provide

    flexibility to the paint system and help

    corrosion resistance to a great exten

    since it contains corrosion inhibitors

    The primer is cured in the oven with

    temperature control with greaprecision.

    Various types of primers are

    available based on different resins like

    epoxy, polyester, polyurethane and

    PVC. Epoxy primers are preferred fo

    use in roofing as it contains chromate

    pigment for better.

    Chromate Coating andChromate - free Coil Coating

    Historically, chromium compound

    have been the key anti-corrosive

    agents in coil coating paints and pre-

    treatment. Normally, a two coat system

    consisting of a top coat and a primer iapplied to pretreated metal substrate.

    The vast majority of traditional coi

    coating primers contains chromium

    compounds such as strontium and zin

    chromate to achieve the necessary

    corrosion resistance of the fina

    product. Hexavalent chromium

    compounds (Chromium VI) serve as an

    electro-chemical coupler that can

    inhibit corrosive reactions on mos

    surfaces.

    However, hexavalent chromium

    compounds widely used in industria

    metal coatings are classified a

    carcinogens (category 1 & 2) as well asbeing toxic and dangerous to

    environment by Dangerous Substanceth

    Directive by EEC, 9 Amendment, 28

    adaptation to technical progress. It i

    true that once the pigments are

    embedded in the paint film, there are no

    imminent health hazards. But in

    considering the risks associated with

    production of the materials at each

    stage of their life and each process ha

    to be taken into account.

    The AlternativeUnder its sustainable developmen

    and responsible care programmeBASF Coatings started to explore

    options for replacing toxic chromate

    pigments in the early 1980s. It wa

    clear from the start that an alternative

    to chromate containing primers had no

    only to be chromate-free but had to

    Perspective

    Major producers of colour

    coated sheets in India have

    introduced No-Rinse

    technology in place of

    phospating (phosphate

    coating) over the

    galvanised strip because

    of better bath maintenance,

    uniform clear structure

    of coating

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    Perspective

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    match or surpass the overallperformance of its chromate-containing rivals. By the middle of1980s, these requirements were metfor household appl iances, asweathering and corrosion-resistantdemands of the indoor applications areless stringent than for outdoor panels.

    By 1992, the first generationuniversal chromate-free primers forexterior applications were introducedand in 1995, there was a furtherdecisive breakthrough; BASF'schromate-free universal primer ongalvanised steel surfaces gavesuperior results over both chromate-free and chromate-contain ingpretreated coal. Continuous adaptationand optimization during the subsequentyears led to further improvements.The main resin system ofchromate-free primers consists of amixture of high molecular weightpolyester and epoxy resins, cross-linked in a system based on aminoresins. The pigment is also not onlychromate-free but also for free of anyother heavy metal or carcinogenicmaterials.Accord ing to experts , theconstruction industry is somewhatconservative and will need to haveconfirmation of the benefits and longlife performance advantages of using

    chromate-free coatings. There will bea clear advantage for coil-coaters thatmake the switchover and establish aclear track record with the technologyof chromate-free coil coatings.TopcoatAfter pre-treatment, the primersurface is coated at uniformly coatedthickness and then cured in the oven.The top coat contains a combination ofcolour pigments and additives whichprovide the required colour of thecolour-coated sheets and infuse otherproperties like ultraviolet resistance.The coated product is then rigorouslytested before clearing for furtherapplications.Most of the roofing and constructionmarkets for colour coated sheets usetop coats which are based on polyester,polyvinylidene fluoride (PVDF), siliconmodified polyester (SMP) and

    plastisols for cost effectiveness anddurability.Benefits of Paint Coating onGalvanised SteelWhen paint and galvanised steel are

    used together, the corrosion controlprovided is superior to either systemused alone. The galvanised coatingprotects the base steel, supplyingcathodic and barrier protection and thepaint slows down the rate at which thezinc is consumed greatly extending thelife of the galvanised steel. Once thepaint has weathered down or damaged,the zinc is available to provide cathodicand barrier protection to avoid rustafter paint peels off.Because of this synergistic effectfor a duplex coating, it provides

    corrosion protection 1.5 to 2.5 timeslonger than the sum of the lifetimes ofzinc and paint used individually. Forexample if the galvanised coating lifeon steel is expected to be 15 years andthe paint coating life on steel isexpected to be five years, thegalvanising and paint when usedtogether, gives a life of 35 years, whichis 1.7 times the sum of both systemsused individually.Textured SurfaceThe topography of the coating

    The main resin system of

    chromate-free primers

    consists of a mixture of

    high molecular weight

    polyester and epoxy resins,

    cross-linked in a system

    based on amino resins

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    Perspective

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    surface is a significant design element.

    Roll application of coating actually

    results in a smooth surface in the coil

    coating process. Thus when in 1980s,

    the white goods inducting began using

    pre-coated panels in combination withsprayed components, there was a

    mismatch in surface appearances. The

    coating process was required to look as

    if it had been painted using spray

    application including the typical orange

    peel effect.

    The challenge was met by the

    introduction of special texture primer

    which was over-coated with a top coat

    adapted to the primers. However,

    enormous efforts were needed initially

    to achieve reproducible texture, but the

    innovation that was launched as a result

    became established by mid-1990s and

    now represents the coil coatingstandard not only in Europe but in other

    industrialized countries of the world.

    In addition to its design aspects, the

    textured coil surface offers advantages

    in processing. The friction properties in

    dies are lower than those of a

    conventional smooth coating. Also the

    surface is more robust and not so easily

    damaged during the assembly process

    and unevenness and flaws are

    masked by the texture.

    Ultimately, the surface

    requires less care by

    the consumer.

    The advantages in the processing otextured coil surfaces can also beexploited with textures produced inother ways. Their appearance isdifferent, but they are easier to processand the more wear resistant thansmooth surfaces. For examplepolyamide in a fine particle distributioncan be incorporated into the colouringtopcoat. Roller blind elements veryoften use a surface of this kind wherethe flexible polyamide particles ensureenhanced wear resistance for thecoating to cope with the frequenopening and closing of the roller blinds.Colour Coated Steel Industryin India

    India was a late starter in colourcoating business. The presenstructure of the industry is as follows:A : Number of units : 7Number of working units: 7Estimated capacity: 800,000 tonnesEstimated production in 2009-10680.000 tonnes

    Construction sector

    Including buildings

    Domestic appliances

    Including white goods

    Others

    TOTAL

    40

    55

    5

    100

    B. Domestic DemandThe domestic demand for colou

    coated sheets in India is steadily

    increasing over the years. The

    estimated demand in 2005-06 wa

    85,000 tonnes which has gradually

    increased to 215,000 tonnes in 2009-

    10.

    The details are furnished below

    year-wise:

    YearDomestic Demand

    ('000 tonnes)Y-O-Y growth

    (%)

    2005-062006-07

    2007-08

    2008-09

    2009-10(e)

    85110

    140

    175

    215

    29.41

    27.27

    25.00

    22.86

    (e) = estimated

    Domestic Demand of Colour Coated Sheets In India

    Consumption Pattern (%)

    The coating process was

    required to look as if it had

    been painted using spray

    application including the

    typical orange peel effect.

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    Producers of Colour CoatedSheets in India

    Originally, Ispat Industries Ltd and

    Shree Precoated Steels Ltd (SPSL)

    were the only two producers of colour

    coated sheets in India, each having acapacity of 50,000tpy. At present

    Ispat's capacity is being expanded to

    100,000tpy. SPSL, which has since

    been acquired by Essar Steel Ltd, has a

    present capacity of 400,000 tpy of its

    colour coating line.

    Bhushan Steel and Strips has

    commissioned a 120,000tpy capacity

    colour coating line at Khopoli in

    Maharashtra.

    Tata Bluescope joint venture on

    50:50 basis has installed a metallic and

    colour coating and painting facility at a

    metallic and colour coating and paintingfacility at Bara near Jamshedpur in

    Jharkhand with a capacity of 25,000 tpy

    of premium zinc and aluminium coated

    material called Zincalume (also called

    Galvalume) and pre-painted zinc and

    aluminium coated steel called

    COLORBOND whose capacity is

    150,000 tpy.

    Uttam Galva Steels Ltd has set up

    80,000 tpy capacity colour coating line

    at Khopoli (Maharashtra).

    Steel Corporation of Gujarat Ltd,

    now owned by Essar Steel Ltd, has set

    up a new colour coating line with a

    capacity of 50,000 tpy.

    Jindal Iron & Steel Co (JISCO) is

    setting up a colour coating with an

    annual capacity of 1,00,000 tonnes at

    Tarapore.

    In the PipelineBokaro Steel Ltd's New Cold

    Roll MillAmong the features of Siemens VAI

    for the major portion of the new 1.3

    mtpy capacity cold rolling mill coming

    up in SAIL's Bokaro Steel plant at

    Jharkhand are Siroll CIS CM and PL

    product line. The first link of the

    production chain will be in tandem withcold mill coupled to a pickling line. The

    state-of-the-art PLTCM will be first of

    its kind in India equipped with heavy

    gauge laser welder (LW 2 IH) pickling

    section, horizontal looper and side

    trimmer; 5 and 6 High cold mill and a

    carrousel coiler.Bokaro's new CRmill will have a mostmodern colour coatingline of 50,000 tpy

    capacity initially.ConclusionC o l o u r c o a t e dsheets are high value-added products thatcombines the bestproperties of thesubstrates and organic coatingadditionally importing it an aestheticfinish, high level of durability and stiffcorrosion resistance.While selecting a substrate, theproducers are required to know thebasic characteristics of the material to

    be used. Textured coil surfacesprovide advantages in processing ofthe coil. The surface is more robust andnot so easily damaged during theassembly process.The Indian producers of colourcoated steel have introduced state-of-the-art technology and are capable ofproducing high quality material in acost-effective and eco-friendlymanner. They should seriouslyconsider the switchover to the use ofchromate-free processes in pre-treatment and coil coating paints.With construction and domesticappliances set to post robust growths infuture, the Indian colour coated steelindustry is expected to record a muchbetter performance in the next fewyears. With pre-fab construction trendbecoming increasingly popular in Indiacolour coated steel demand hasimproved significantly. The userindustries find these sheets more eco-friendly.Acknowledgments

    1.`Innovative surface design with coil coating'by Lother Sandel of BASF, published in MillenniumSteel 2006.

    2.Article in `Steel Times International,'January 2005 issue on chromate-free coil coatingprocess.

    3.Various articles by L Pugazhenthy, ED,ILZDA

    4.Article by G D Patange, Former GM, UttamGalva Steels Ltd, in `Steelworld' in January 2009issue

    Textured coil surfaces

    provide advantages in

    processing of the coil.

    The surface is more robustand not so easily damaged

    during the assembly process.

    Perspective