Suramol materials vatsadze 2014_final

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The set of lectures on the current problems and advances of supramolecular chemistry in material science. In Russian

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2. 2 1. .1. . .2. .3. . .4. . . . . .5. -. . . .6. -. (0D) .7. .8. . .9. . 3. 31987 , - .. . . . . 1987 4. .., .., .. . .-. ..(), .-. .. (), .-. .. (), .., .., .., .. () . [i], [ii], [iii], [iv], [v], [vi], [vii]. .[viii],[ix],[x],[xi] , - , Molecular Design andSynthesis of Supramolecular Architectures, Supramolecular Systems inChemistry and Biology, .[i] . . , , , 2004, 6-25.[ii] . ., . ., . ., . ., , , 1998, 67, 995-1012.[iii] A. Motornaya, I. Vatsouro,. E. Shokova, V. Hubscher-Bruder, M. Alyapyshev, V. Babain, M. Karavan, F. Arnaud-Neu, V. Boehmer, V. Kovalev, Adamantylcalixarenes with CMPOgroups at the wide rim: synthesis and extraction of lanthanides and actinides, Tetrahedron, 2007, 63, 4748-4755.[iv] . . , . . , . , 1999, 68, 381-400.[v] . . , - , , 2006, 1, 29-45.[vi] D. S. Turygin, M. Subat, O. A. Raitman, V. V. Arslanov, B. Knig, M. A. Kalinina, Cooperative self-assembly of adenosine and uridine nucleotides on a 2D synthetic template, Angew.Chem. Int. Ed., 2006, 45, 5340-5344.[vii] E. A. Karakhanov, L. M. Karapetyan, Y. S. Kardasheva, A. L. Maksimov, E. A. Runova, V. A. Skorkin, M. V. Terenina, Molecular Recognition and Catalysis: from MacrocyclicReceptors to Molecularly Imprinted Metal Complexes, Macromol. Symp. 2006, 235, 3951.[viii] A. B Burdukov, D. A. Guschin, N. V. Pervukhina, V. N. Ikorskii, Yu. G. Shvedenkov, V. A. Reznikov, V. I. Ovcharevko, Mixed-ligand copper complexes with stable nitroxide pseudotetrahedral tectons with octahedral coordination core, Cryst. Eng., 1999, 2, 265-279.[ix] D. N. Dybtsev, M. P. Yutkin, E. V. Peresypkina, A. V. Virovets, C Serre, G. Frey, V. P. Fedin, Isoreticular Homochiral Porous Metal-Organic Structures with Tunable Pore Sizes,Inorg. Chem., 2007, 46, 6843-6845.[x] M. N. Kozlova, S. Ferlay, S. E. Solovieva, I. S. Antipin, A. I. Konovalov, N. Kyritsakas, M. W. Hosseini, Molecular tectonics: on the formation of 1-D silver coordination networks bythiacalixarenes bearing nitrile groups, Dalton Transactions, 2007, 5126-5131.[xi] . . , . . , - - : [Ag2(Me4Pyz)]PF6 [Ag2(Me4Pyz)3](BF4)2H2O, . . , 2007, 52, 743-750.4 5. 5 : - . , ,, 1998. . . ., . . , , . ., 2- ., . .. . , : , 2007. C. . , . - , LAP, 2011. H.-J. Schneider, A. K. Yatsimirsky, Principles and Methods in Supramolecular Chemistry, JohnWiley &Sons, 2000. H. Dodziuk, Introduction to Supramolecular Chemistry, Springer, 2002. J. W. Steed, J. L. Atwood (eds.), Encyclopedia of Supramolecular Chemistry, Marcel Dekker,New York, NY, USA, 2004. P. J. Cragg, Practical Supramolecular Chemistry, John Wiley & Sons, Ltd, Chichester, UK, 2006. K. Ariga, T. Kunitake, Supramolecular Chemistry Fundamentals and Applications, Springer-Verlag, Heidelberg, 2006 J. W. Steed, D. R. Turner, K. J. Wallace, Core Concepts in Supramolecular Chemistry andNanochemistry, John Wiley & Sons, Ltd, 2007. 6. , . , 6 6 . , , () ()..-. 7. 7 2130 + 1 8. 8 , 9. 9 ( .-. ): - - ..- - .. - 10. , , ( ), - . ,, , 1998, . 221100 , , , , (, , , ,, , ) 11. 11 ():():- , , ,, , , , 12. 1122 + ,, ,, , pHC 13. , . , 1133 . , , () ()..-. 14. 1154 , () (G.R. Desiraju, Angew. Chem. Int. Ed. 1995, 34, 2311) , (J. Wuest, JACS, 1991, 113, 4696) 15. 1165 == (Desiraju) 16. 1176 == - 100-350 /- 50-200 / 4-120 /-- 50-80 /- 5-50 /- 0-50 / -