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Validation of TCCON Observations of CO 2 , CH 4 , and CO at Sodankyla Using AirCore Huilin Chen 1,2 , Bert Kers 1 , Rigel Kivi 3 , Pauli Heikkinen 3 , Juha Hatakka 4 , Tuomas Laurila 4 , Colm Sweeney 2,5 and Pieter Tans 5 1. CIO, University of Groningen, The Netherlands 2. CIRES, University of Colorado, Boulder, USA 3. FMI, Arctic Research Centre, Sodankyla, Finland 4. FMI, Helsinki, Finland 5. NOAA ESRL, Boulder, Colorado, USA

Validation of TCCON Observations of CO CH4, and CO at ...€¦ · Validation of TCCON Observations of CO 2, CH 4, and CO at Sodankyla Using AirCore Huilin Chen1,2, Bert Kers1, Rigel

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Page 1: Validation of TCCON Observations of CO CH4, and CO at ...€¦ · Validation of TCCON Observations of CO 2, CH 4, and CO at Sodankyla Using AirCore Huilin Chen1,2, Bert Kers1, Rigel

Validation of TCCON Observations of CO2, CH4, and CO at Sodankyla Using AirCore

Huilin Chen1,2, Bert Kers1, Rigel Kivi3, Pauli Heikkinen3, Juha Hatakka4, Tuomas Laurila4, Colm Sweeney2,5 and Pieter Tans5

1.  CIO, University of Groningen, The Netherlands 2.  CIRES, University of Colorado, Boulder, USA 3.  FMI, Arctic Research Centre, Sodankyla�, Finland 4.  FMI, Helsinki, Finland 5.  NOAA ESRL, Boulder, Colorado, USA

Page 2: Validation of TCCON Observations of CO CH4, and CO at ...€¦ · Validation of TCCON Observations of CO 2, CH 4, and CO at Sodankyla Using AirCore Huilin Chen1,2, Bert Kers1, Rigel

AirCore measurements!

The! AirCore! with! magnesium! perchlorate!driers!and!shut6off!valves!a9ached!on!each!end,!152!m!long,!7!kg![Karion(et(al.(2010]

Page 3: Validation of TCCON Observations of CO CH4, and CO at ...€¦ · Validation of TCCON Observations of CO 2, CH 4, and CO at Sodankyla Using AirCore Huilin Chen1,2, Bert Kers1, Rigel

Validation of TCCON AirCore vs. Aircraft

Sampling)pla*orm)

Sampling)range)

Cost)($))

Error)in)

XCO2)

Error)in)XCH4)

Regular launch?

Low6

aircraA!

0!–!4!

km! 1.5K!

1.0!

ppm! 10!ppb! Yes

High6!

aircraA

0!–!12!

km! 10K!

0.50!

ppm! 6!ppb! NA

AirCore! 0!–!30!

km! 4.2K!

0.10!

ppm! 2!ppb! Yes

Page 4: Validation of TCCON Observations of CO CH4, and CO at ...€¦ · Validation of TCCON Observations of CO 2, CH 4, and CO at Sodankyla Using AirCore Huilin Chen1,2, Bert Kers1, Rigel

AirCore measurements over Sodankyla!

TCCON!staMon!

LocaMon!67°!North!

AirCore:!40!m!1/4”!+!60!m!1/8”!!Coils:!! ! !!!!!!!2.8!kg!!Total!package:!!3.6!kg!!Analysis:!! ! ! ! ! !Picarro!CO2/CH4/CO/H2O!

Page 5: Validation of TCCON Observations of CO CH4, and CO at ...€¦ · Validation of TCCON Observations of CO 2, CH 4, and CO at Sodankyla Using AirCore Huilin Chen1,2, Bert Kers1, Rigel

Landing!sites!

AirCore campaign September 2013!

Page 6: Validation of TCCON Observations of CO CH4, and CO at ...€¦ · Validation of TCCON Observations of CO 2, CH 4, and CO at Sodankyla Using AirCore Huilin Chen1,2, Bert Kers1, Rigel

AirCore profiles October 2013!Landing!sites!

Page 7: Validation of TCCON Observations of CO CH4, and CO at ...€¦ · Validation of TCCON Observations of CO 2, CH 4, and CO at Sodankyla Using AirCore Huilin Chen1,2, Bert Kers1, Rigel

AirCore Analysis System!

Picarro

Aircore sampling system 14-10-2013

1/8”

1/4”

1/8”

1/8”

QC - NC 1/4”

QC - NC 1/4”

QC - NC 1/4”

QC - NC 1/4”

QC - NO 1/4”

QC - NC 1/4”

QC - NC 1/4”

QC - NO 1/4”

QC - NC 1/4”

QC - NC 1/4”

Cal tank

valve

QC - NC 1/4”

gluedconnection

gluedconnection

drying tube

Picarromembranepump

Criticalorifice

Pressurecontroller

Page 8: Validation of TCCON Observations of CO CH4, and CO at ...€¦ · Validation of TCCON Observations of CO 2, CH 4, and CO at Sodankyla Using AirCore Huilin Chen1,2, Bert Kers1, Rigel

AirCore Analysis on Picarro!

±)0.1)CO

2)ppm

)±)2)CH

4)ppb

)

Time)(min))

±)8)CO

)ppb

)

Page 9: Validation of TCCON Observations of CO CH4, and CO at ...€¦ · Validation of TCCON Observations of CO 2, CH 4, and CO at Sodankyla Using AirCore Huilin Chen1,2, Bert Kers1, Rigel

Sodankyla AirCore profiles!

Page 10: Validation of TCCON Observations of CO CH4, and CO at ...€¦ · Validation of TCCON Observations of CO 2, CH 4, and CO at Sodankyla Using AirCore Huilin Chen1,2, Bert Kers1, Rigel

TCCON validations – CO2 (preliminary)!

~!0.1%!normal!~!0.5!%!polar!vortex!

Page 11: Validation of TCCON Observations of CO CH4, and CO at ...€¦ · Validation of TCCON Observations of CO 2, CH 4, and CO at Sodankyla Using AirCore Huilin Chen1,2, Bert Kers1, Rigel

TCCON validations - CH4 and CO (preliminary)!

~!1%!normal!~!4%!polar!vortex!

~!5%!normal!~!20!polar!vortex!

Page 12: Validation of TCCON Observations of CO CH4, and CO at ...€¦ · Validation of TCCON Observations of CO 2, CH 4, and CO at Sodankyla Using AirCore Huilin Chen1,2, Bert Kers1, Rigel

TCCON validations – CO2 (preliminary)!

Page 13: Validation of TCCON Observations of CO CH4, and CO at ...€¦ · Validation of TCCON Observations of CO 2, CH 4, and CO at Sodankyla Using AirCore Huilin Chen1,2, Bert Kers1, Rigel

TCCON validations - CH4 and CO (preliminary)!

Page 14: Validation of TCCON Observations of CO CH4, and CO at ...€¦ · Validation of TCCON Observations of CO 2, CH 4, and CO at Sodankyla Using AirCore Huilin Chen1,2, Bert Kers1, Rigel

Figure 2. A Balloon AirCore flight on March 12, 2011

1. Regular AirCore profiles measurements in Sodankyla, Finland (67° North)

2. Polar vortex measurements: ~0.5% for CO2, ~4% for CH4, ~20% for CO

3. Technical improvements •  automatic valve •  reducing the pressure drop across dryers •  weight reductions

4. AirCore campaign scheduled in July 2014

Conclusions and future work!

Page 15: Validation of TCCON Observations of CO CH4, and CO at ...€¦ · Validation of TCCON Observations of CO 2, CH 4, and CO at Sodankyla Using AirCore Huilin Chen1,2, Bert Kers1, Rigel

Thanks!for!your!a9enMon!!