7
VOLUME 54 NUMBER 5  FEBRUARY 2016 1 Newsletter of the Palisades - New Jersey Section Communication Excellence Pinnacle Gold 2015 Section Awards Continued on page 2 The Society of Plastics Engineers February 2016 Table of Contents This Month . . . . . . . . . . . . . . . . . . . . . . . . 1,2 Upcoming Meeting Dates . . . . . . . . . . . . . . 1 President’s Message . . . . . . . . . . . . . . . . . . 2 Scholarship Opportunities . . . . . . . . . . . . . . 3 Sponsor Pages . . . . . . . . . . . . . . . . . . . 4,5,6 PlastiVan Letters . . . . . . . . . . . . . . . . . . . . . 7 BOD Contact List . . . . . . . . . . . . . . . . . . . . 7 FEBRUARY 18, 2016 NANOCOMPOSITES OF POLYMERS COMPOUNDED WITH VARIOUS NANOINCLUSIONS: EFFECTS ON VISCOELASTICITY, CRYSTALLIZATION, CROSS- LINKING AND DEVELOPMENT OF ULTIMATE PROPERTIES DILHAN M. KALYON, STEVENS INSTITUTE OF TECHNOLOGY Polymer nanocomposites (PNCs) consist of a polymeric binder into which various  particles  of  nanoscale  dimensions,  including  single  and  multi- walled carbon nanotubes, graphene and nanoclays, are incorporated. The different functionalities of the polymeric binder and the nanoinclusions and the possibility of heterogeneous structuring at multiscales enable the use of PNCs in myriad industrial applications (e.g., scaffolds for tissue engi- neering, nanomedicine, membranes, intumescent and other functional coatings, solar cells, electronic devices, sensing and high-strength applications). The promises of PNCs are especially encouraging since their ultimate properties are superior to those of conventional composites even at rela- tively low concentrations of the nanoinclusions. however, there are significant challenges associated with the processing of the PNCs and especially the dispersion control of the nanoinclusions within the polymer phase that severely limit their utilities. Furthermore, the incorporation of nanoinclusions introduces very substantial changes in the development of crystallinity and crystalline morphologies for semi-crystalline polymers  and  alters the rates of curing for thermosetting polymers, to in turn significantly affect the ulti- MEETING LOCATION:   Olde Mill Inn Passaic Room 225 Morristown Rd. (Rt. 202) Basking Ridge, NJ 07920 ThURSDAY FEBRUARY 18, 2016 4:00 PM Board Meeting 5:30 PM Networking 6:00 PM Dinner and Speaker Presentation Member Non-Member Advance (before Noon 02/17/16) $40 $45 At Door $45 $50 Prosp. Mbr/Sig.Other/Guest $25 Unempl. Mbr. $15 Students (show I.D.)  $15 R.S.V.P. to: Mr. Pete Hayles, Jr. [email protected] 732 239-8984 UPCOMING MEETING DATES Feb. 18 Section Meeting March 24 Cook Campus, Rutgers April TBD Stevens Institute of Technology May 23-25  ANTEC ® 2016 June 7                Golf Outing June 16 Awards Meeting Sept. 20-22 Vinyltec, Iselin, NJ

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Page 1: The Society of Plastics Engineers February 2016 2015 ...s3.amazonaws.com/rdcms-spe/files/production/public/Documents/S… · members who have demonstrated excellence in various fields

VOLUME 54 NUMBER 5  FEBRUARy 20161

Newsletter of the Palisades - New Jersey Section

Communication Excellence

Pinnacle Gold

2015 Section Awards

Continued on page 2

The Society of Plastics Engineers February 2016

Table of Contents

This Month . . . . . . . . . . . . . . . . . . . . . . . . 1,2

Upcoming Meeting Dates . . . . . . . . . . . . . . 1

President’s Message . . . . . . . . . . . . . . . . . . 2

Scholarship Opportunities . . . . . . . . . . . . . . 3

Sponsor Pages . . . . . . . . . . . . . . . . . . . 4,5,6

PlastiVan Letters . . . . . . . . . . . . . . . . . . . . . 7

BOD Contact List . . . . . . . . . . . . . . . . . . . . 7

FEBRUARY 18, 2016

NANOCOMPOSITES OF POLYMERS COMPOUNDED

WITH VARIOUS NANOINCLUSIONS:EFFECTS ON VISCOELASTICITY, CRYSTALLIZATION, CROSS-LINKING AND DEVELOPMENT OF ULTIMATE PROPERTIES

DILHAN M. KALYON, STEVENS INSTITUTE OF TECHNOLOGY

Polymer nanocomposites (PNCs) consist of a polymeric binder into whichvarious  particles  of  nanoscale  dimensions,  including  single  and  multi-walled carbon nanotubes, graphene and nanoclays, are incorporated. Thedifferent functionalities of the polymeric binder and the nanoinclusions andthe possibility of heterogeneous structuring at multiscales enable the useof PNCs in myriad industrial applications (e.g., scaffolds for tissue engi-neering, nanomedicine, membranes,  intumescent and other  functionalcoatings, solar cells, electronic devices, sensing and high-strength applications).The  promises  of  PNCs  are  especially  encouraging  since  their  ultimateproperties are superior to those of conventional composites even at rela-tively low concentrations of the nanoinclusions. however, there are significantchallenges associated with the processing of the PNCs and especially thedispersion control of the nanoinclusions within the polymer phase thatseverely limit their utilities. Furthermore, the incorporation of nanoinclusionsintroduces very substantial changes in the development of crystallinity andcrystalline morphologies for semi-crystalline polymers  and  alters the ratesof curing for thermosetting polymers, to in turn significantly affect the ulti-

MEETING LOCATION:  Olde Mill InnPassaic Room225 Morristown Rd. (Rt. 202)Basking Ridge, NJ 07920

ThURSDAy FEBRUARy 18, 20164:00 PM Board Meeting 5:30 PM Networking6:00 PM Dinner and Speaker Presentation

Member Non-Member

Advance (before Noon 02/17/16) $40 $45At Door $45 $50Prosp. Mbr/Sig.Other/Guest $25Unempl. Mbr. $15Students (show I.D.)  $15

R.S.V.P. to: Mr. Pete Hayles, [email protected] 732 239-8984

UPCOMING MEETING DATES

Feb. 18 Section Meeting

March 24 Cook Campus, Rutgers

April TBD Stevens Institute of Technology

May 23-25  ANTEC®2016

June 7                Golf Outing

June 16 Awards Meeting

Sept. 20-22 Vinyltec, Iselin, NJ

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VOLUME 54 NUMBER 5  FEBRUARy 20162

Continued from page 1

President’s Message

For the past several years, the Palisades-New Jersey Section has been actively in-volved  with  our  student  chapter  atRutgers and we will have a joint meetingwith them in March. At that meeting, wewill continue our presentations on how topresent  oneself  and  how  to  look  for  a

better  job or  just a  job. Beginning  last year, we  initiatedworking with Stevens Institute of Technology to explore thepossibility of establishing a student chapter there. Stevensis a remarkable regional center of polymer research and de-velopment. This year, the Stevens students won the Surehouse competition, officially known as the U.S. Departmentof Energy Solar Decathlon 2015. The name Sure is a com-bination of the key characteristics of the house, SUstainableand REsilient. By innovative use of plastics, particularly vinyland fiber composites, the Stevens Sure house is fully solarpowered and uses 90% less energy than a conventionalhouse of  its size and composition.  It’s  intended  to be ahouse of the future, adaptable to a changing climate andable to withstand extreme weather events such as hurri-cane Sandy. For a detailed article on how the Stevens stu-dents built  the house to win the competition, check thecurrent issue of Plastics Engineering (January, 2016, pp.34-5). Later this year, we plan to have a joint meeting withthe students at Stevens to explore further the possibility ofa chapter there and to meet some of the talented studentswho will be so important to the future of plastics professionals.

In  the  upcoming  February  meeting,  we  will  have  as  ourspeaker, Prof. Dilhan Kalyon from Stevens, who is the Insti-tute Professor there and also, among his many honors, aFellow of the Society of Plastics Engineers. he will discussthe  use  of  various  nanoparticles,  such  as  carbon  nan-otubes, graphene, and nanoclays, in commodity and engi-neering polymers to form polymer nanocomposites (PNC’s).Prof. Kalyon will show by review of case studies how PNC’scan attain superior properties, which is the good news. hewill also show how processing and procedures have to beadapted to work with them, which are the challenges. Thismeeting will be a step toward our ongoing relationship withStevens and will give us an insight into a still developingtechnology that has great potential for the future. 

Mike Fisch

mate properties. The various properties including the viscoelas-ticity, swelling behavior, and flammability of the shaped PNCsare intimately related to the dispersion state of the nanoinclu-sions and the processing methods and procedures need to beselected accordingly.  In  this presentation a number of casestudies involving the compounding of multi-walled nanotubesand nanoclays into various engineering and commodity plastics(e.g., poly(butylene terephthalate),   poly(ether ether ketone),poly(vinylidene  fluoride),  Nylon  11,  poly(ethylene  glycolmonoacrylate) and epoxies) and the development of structureand ultimate properties of the resulting PNCs will be presented. 

BIography:Dilhan Kalyon holds the Institute Professor Chair at Stevens Instituteof Technology and is affiliated with the Chemical Engineering andMaterial Science as well as the Biomedical Engineering, Chemistryand Biological Sciences Departments. He is also the founding di-rector of the Highly Filled Materials Institute since 1989. Prof. Kalyonhas received the Thomas Baron award in fluid-particle systems ofAmerican Institute of Chemical Engineers (2008), the InternationalResearch award of Society of Plastics Engineers (2008), and anHonorary M. Eng. degree, honoris causa (1994) from Stevens In-stitute of Technology. He was elected Fellow of the Society of Plas-tics Engineers (2004) and Fellow of the American Institute ofChemical Engineering (2006). He can be reached [email protected].

PNC’S (CONTINUED)

100532 O-Halogen PE 100% Compound

103132 O-Halogen EVA 100% Compound

11371 Brominated PE 18-20% Concentrate

401155 Brominated PP 18-20% Concentrate

Carrier UsageCode Type Resin LDR For V-0

Other flame retardant, foams and specialty additive concentratesfor various resin types (hTPE, PVC, PP) are available.

Contact Joe Serbaroli at: [email protected] or:

Ampacet Corp.,Tarrytown, NY 800-888-4267

Flame RetardantConcentrates & Compounds

Managing the Elements of Success TM

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VOLUME 54 NUMBER 5  FEBRUARy 20163

young people are not only our pride and joy but they are also the futureleaders of the world.  So, they deserve our blessings and support. Withthat in mind, the Palisades-New Jersey Section of the Society of PlasticsEngineers (SPE) is proud to offer academic scholarships to associatedmembers who have demonstrated excellence in various fields of study.The scholarship categories and criteria are listed below.  If you, or a fam-ily member, are interested in participating please submit the requireddocuments by April 30, 2016.

If you are not a current member of SPE but you are interested in joining or becoming affiliated with the SPE Palisades-New Jersey Section, please contact Mike Carnese, 732-208-4333, [email protected] or visithttp://www.4spe.org

To apply for a scholarship, please submit the documents listed below.  Official transcripts must be submitted by postal mail orcourier (i.e. FedEx, UPS) to the address below. Transcripts are considered confidential and will not be viewed by anyone outsideof the evaluation team.  Essays and membership information may be submitted by email to [email protected] Submit official transcripts to: Mark Lavach, ARKEMA INC. 900 First Avenue, King of Prussia PA 19406Required Documents:

n Official Transcriptn A one to two page essay describing your contributions to your chosen field of study and how the scholarship 

award might help you to achieve your future goals. Submit to [email protected] n your SPE membership number or the number of the member to whom you are related (as necessary).

The deadline for submissions April 30, 2016. Awards will be announced inn May 2016 and will be distributed at the final Palisade-NewJersey Section Meeting of the year on June 16, 2016.

The Palisades-New Jersey Section of the Society of Plastics Engineers offers academic scholarships

Scholarship Scholarship Number Academic Society of Plastics Engineers (SPE), Name Award Available Criteria Palisades-New Jersey Section Criteria

WHITNEY(FORMERLY GERSON)

RYAN

UNDERGRADUATE

HIGH SCHOOL SCHOLARSHIP

BOARD OF DIRECTORS'DISCRETIONARYSCHOLARSHIPS

$4,000.00

$4,000.00

$2,000.00

$2,000.00

varied

Graduate Study InAny Field

Undergraduate Studyin Any Field

Undergraduate studyin Physical, Chemicalor Material Scienceor Engineering

Any Fieldof Study

Graduate or Undergraduatestudy in any field

None

Child or Grandchild of an active Palisades-NewJersey Section Member and/or any Full, Affiliate or

Student SPE Member

Children or Grandchildren of active Palisades-NewJersey Section Members and/or

any Full, Affiliate or Student SPE Member

Children or Grandchildren of active SPE, Palisades-New Jersey Section Members

Child or Grandchild of an active Palisades-NewJersey Section Member and/or any Full, Affiliate or

Student SPE Member

1

1

2

2

TBD

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VOLUME 54 NUMBER 5  FEBRUARy 20164

HHiigghh PPeerrffoorrmmaannccee AAddddiittiivveess ffoorr PPllaassttiiccss

AAnnttiiooxxiiddaannttss:: DDoovveerrpphhooss®® SS--99222288 DDoovveerrnnooxx®® 1100 && 7766

HHeeaatt SSttaabbiilliizzeerrss:: DDoovveerrpphhooss®® lliiqquuiidd pphhoosspphhiitteess

DDoovveerrpphhooss®® HHiiPPuurree 44

LLuubbrriicciittyy AAddddiittiivveess:: DDoovveerrlluubbee®® CCaa && ZZnn sstteeaarraatteess

FFllaammee RReettaarrddaannttss:: CChhlloorreezz®®,, PPaarrooiill®®,, DDoovveerrgguuaarrdd®®

- - - -

VOLUME 54 NUMBER 1 SEPTEMBER 20156

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Rabun LewisKey Account Manager Polymers

Tel (770) [email protected]

www.omya.com

OMYA, INC.9987 Carver Road, Suite 300

Cincinnati, OH 45242

Manufacturers of high quality Polymer Additives to the global Polymer Industry

Santicizer® Fast Fusing and Phosphate Ester Plasticizers*Synpro® Stearates

!erm-Chek® Mixed Metal Heat Stabilizers *Petrac Waxes, Stearic Acid

* Micro-Check® Antimicrobials * Plas-Chek® Epoxidized Soybean Oil

Benzyl Chloride * UV-Chek® UV Stabilizers

Joe Cairoli National Account Manager * Phone 908-510 -1217

S P E C I A L T Y C H E M I C A L S

Rabun LewisKey Account Manager Polymers

Tel (770) [email protected]

www.omya.com

OMYA, INC.9987 Carver Road, Suite 300

Cincinnati, OH 45242

Manufacturers of high quality Polymer Additives to the global Polymer Industry

Santicizer® Fast Fusing and Phosphate Ester Plasticizers*Synpro® Stearates

erm-Chek® Mixed Metal Heat Stabilizers *Petrac Waxes, Stearic Acid

* Micro-Check® Antimicrobials * Plas-Chek® Epoxidized Soybean Oil

Benzyl Chloride * UV-Chek® UV Stabilizers

Joe Cairoli National Account Manager * Phone 908-510 -1217

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VOLUME 54 NUMBER 5  FEBRUARy 20165

Your Global Source for Additivesv Akcrostab® and Interstab® heat and Light Stabilizers 

for PVC (Mixed Metal and Tins)

v Intercide® Microbiocidesv Bonding Agentsv Plastoflex® Epoxy Plasticizersv Interstab® Lubricants

For research, technical service, manufacturing, marketingand customer service, contact Akcros today.

Akcros Chemicals500 Jersey Avenue, New Brunswick, New Jersey 08901

Tel: 732-247-2202 Fax: 732-247-8416ISO 9002 and ISO 14001 Certified

www.akcros.com

Fillers•Extenders•Oils•Lubricants

Phone:1-800-257-9365 Web: www.recarroll.comEmail: [email protected]

Chicago • Dalton • Dallas • Ewing • Fullerton • Kent

• Organic Pigments • Titanium Dioxide• Stearates • Aluminum Trihydrate• Calcium Carbonate • White Oils

H.M. Royal, Inc., Trenton, New Jersey 08618 d (609) 396-9176 d (800) 257-9452 d www.hmroyal.com

We’re Material People

e’re Material PeopleWd8y 0861seerw Jon, NeentrTTral, Inc., yo RH.M.

e’re Material Peopleyo.hmrwwwd-9452(800) 257(800) 257-9452d67(609) 396-91 al.comy

ARKEMA PVC ADDIT IVESMEANS PRODUCT PERFORMANCE

Selling to the extrusion and injection moldingindustry for over 50 years, with the continuinginnovation and quality products you’ve come toexpect from Arkema.

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6

RK Tech Inc.Leader in PVC Technology

35 Hamilton LanePlainsboro, NJ 08536

[email protected]/FX 609.799.9034

Let NORAC show you how our high qualitymetallic stearates and related products pro-vide solutions for your polymer processingproblems and enhance your profitability

Our products find use as lubricants, mold release agents,acid  scavengers,  and  costabilizers  in  the  PVC,Polyolefin,Thermoset, and Rubber Industries. Our line in-cludes Stearates of Calcium, Zinc, Magnesium, Aluminum,Lithium, and Sodium.

NORAC, Inc.405 SOUTH MOTOR AVENUE

AZUSA, CALIFORNIA 91702-3232(626) 334-2908 FAX (626) 334-3512

NORAC® ADDITIVESCOAD® and

MATHE® Metallic Stearates

®

PVC TECHNOLOGY AT ITS BESTl PVC Low Smoke Plenum Technologyl PVC Compoundingl PVC Processing – Extrusion and Moldingl PVC Wire and Cable, Profile, Clear, Medical,

Alloys and Foamed Compounds

Keep tomorrow in mind with all that we do today.

With continuous innovation for over 50 years,we created LOXIOL®, today’s most sought after natural-based plastic additive. This pavedthe way for more application of plastics in variousindustries, making us one of the world’s leading natural-based chemicals producers. With a 170-year-old heritage, global distribution networkand commitment to research and technology,we can help formulators meet market demands forsustainable and high performance solutions whileworking towards a greener future for plastics too.

Member of National Association of Chemical Distributors

Providing the highest quality raw materials and superior serviceto the plastics, polymer, and coatings industries for over 20 years.

•Metallic Stearates •Fillers•Plasticizers •Waxes •Pigments•Heat Stabilizers •UV Absorbers•Antioxidants •HALS •Biocides•Optical Brighteners •Much More!Phone 908-526-6800 Fax 908-526-7430/7432See us on the internet at www.monsonco.com

(908) 874-4700 x451Direct:  732.208.4333

Email: [email protected] Route 206, hillsborough, NJ 08844

Employment OpportunitiesAdvertise here for open positions 

or for positions wantedFree to sponsor companies and 

section members!

Contact the editor at:[email protected]

Palisades - New Jersey SectionPlease “Like” us on Facebook. Click on facebook icon below!

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VOLUME 54 NUMBER 5  FEBRUARy 20167

2015-16 OfficersDr. Michael Fisch Consultant President 201-888-9066 [email protected] Kapp American Leistritz 1st Vice President 908-685-2333 [email protected] Dispenza Design Results 2nd Vice President 908-876-5774 [email protected] McAndrew Retired Treasurer 908-273-3152(hm) [email protected] Smith Arkema, Inc. Secretary 215-495-3247 [email protected] Martin Retired Councilor 201-600-6874 [email protected]. Lee Sealed Air Past President 201-712-7142 [email protected]

2016-17 DirectorsRich Bradley Shawnee Chemical Director 203-938-3003 [email protected] Klein Daikin Americas, Inc Director 732-735-4028 [email protected] Krauskopf Vinyl Consulting Co. Director 609-275-4561 [email protected] Monte Kenrich Petrochemicals Director 201-823-9000 [email protected]

2017-18 DirectorsMike Carnese Consultant Director 732-208-4333 [email protected] Finkle BASF Director 203-371-6677 [email protected] Tewatia  Rutgers University Director 908-565-1231 [email protected]

2018-19 DirectorsMatthew Bobertz CW Brabender, Inc Director 201-655-2552 [email protected] Schipper Akcros Chemicals, Inc. Director 610-745-6244 [email protected] Kappus R Kappus LLC Director 908-619-5858 [email protected]

Emeritus DirectorJay Kotak RK Tech Director 732-447-3093 [email protected]

Committee ChairsAwards: Paul Nardone 973-670-0234 [email protected]: Art Finkle 203-371-6677 [email protected] Chair: Mark Lavach 610-878-6985 [email protected] Fund: J. Stephen Duerr 908-500-9333 [email protected]: Pete hayles 732 239-8984 [email protected]: Mike Carnese 732-208-4333 [email protected]: Jay Kotak 609-799-9034 [email protected]: Jennifer Markarian 908-638-5669 [email protected] & Org.: Robert MacFarlane, Jr. 973-410-0590 [email protected] Media Mgr.: Peggy Schipper 610-745-6244 [email protected] Events: Jim Williamson 610-662-7779 [email protected]: Pete hayles 732-239-8984 [email protected]

BOARD OF DIRECTORS AND COMMITTEE LIST

The PlastiVan STEM Education Program was outstanding! Thank you very much for your hard work and for providing this op-portunity for the sixth grade classes at our school. Margie Weiner's talents are very evident. I really enjoyed her teaching approachand the way she conducts activities that best engage students. The expressions on the students' faces were priceless. Thankyou for your community-minded efforts, generosity, and commitment to science education. Our students and staff really appre-ciate your contribution to this program and send our deepest appreciation.

Jeff Lichter, Sixth Grade Teacher, Roy W. Brown Middle School, Bergenfield, NJ

On behalf of the students and staff of Schuyler-Colfax Middle School, I would like to thank you for once again bringing MargieWeiner  and  the  PlastiVan  program  to  our  school.    The  enthusiasm  shown  by  our  students  is  a  testament  to  Margie  andthe  hands-on nature of the program. 

Mrs. Aimee Toth, M.Ed., Principal, Schuyler-Colfax Middle School, Wayne Township Public Schools

Thanks to Our Section for Supporting the PlastiVan Program