16
T FEATURE PRESENTATIONS: he Ontario Section of the Society of Plastics Engineers is hosting the 11th Industry-University Night on March 19, 2009. This is a vibrant meeting with industry and university communities coming together. This year the event will take place at the University of Guelph, in Guelph, Ontario. Dr. Amar Mohanty Dr. Manju Misra Tour of the Biocomposite Bioproducts Discovery & Development Centre Technical seminars from graduate students Poster session of current research on plastics in Ontario. Poster competition for graduate students with cash award. Dinner at the Delta Hotel in Guelph. The SPE Ontario’s Industry-University Night is an event that should not be overlooked. This is an evening in which multi-faceted networking can be accomplished in a relaxed setting that provides you with an opportunity to learn about new and innovative research in various fields of the plastic industry. Over the course of the evening, you’ll have ample opportunity to meet with other professionals in the industry, but more importantly, an opportunity to meet the new young faces that will one day be part of our industry. You don’t need to look any further than myself to see an example of how successful these partnerships can be. Nine years ago I attended my first University Night as a graduate student, and met Alex Henderson from AT Plastics – a meeting that provided me with the opportunity to be where I am today, as I joined the company a few short months later. And I’m sure I’m just one of many success stories that can be traced back to these events. On behalf of SPE Ontario, I encourage you to come out to our next University Night, on March 19th at the University of Guelph, Centre for Bioplastics and Biomaterials. You never know who you’ll meet…it just might be your company’s next shining star. Don’t miss this event! Attendance is limited, so be sure to pre-register to guarantee your spot. AT Plastics Industry-University Night – you never know who you’ll meet Chris Gilmor, the Newsletter of the Ontario Section of SPE www.4spe.org March 2009 SPE Ontario Meeting – Thursday, March 19, 2009 SPE Ontario University Night The Bioproducts Discovery & Development Centre Crop Science Building University of Guelph, 50 Stone Road East, Guelph, Ontario Members $40.00. Non-members $50.00. Students $20.00 (Cash, cheque or Visa). Joe DeRose, VP Program, 416-410-2286. Email: [email protected] Cost: For further information please contact: University of Guelph Campus map

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Page 1: SPE Ontario Meeting – Thursday, March 19, 2009s3.amazonaws.com/rdcms-spe/files/production/public/FileDownload… · Ontario Spectator 3 March 2009 DATE SPE Ontario Section 2009

T

FEATURE PRESENTATIONS:

he Ontario Section of the Society of Plastics

Engineers is hosting the 11th Industry-University

Night on March 19, 2009. This is a vibrant meeting

with industry and university communities coming together.

This year the event will take place at the University of

Guelph, in Guelph, Ontario.

Dr. Amar Mohanty

Dr. Manju Misra

Tour of the Biocomposite Bioproducts Discovery

& Development Centre

Technical seminars from graduate students

Poster session of current research on plastics in

Ontario. Poster competition for graduate students

with cash award.

Dinner at the Delta Hotel in Guelph.

The SPE Ontario’s Industry-University Night is an event

that should not be overlooked. This is an evening in which

multi-faceted networking can be accomplished in a relaxed

setting that provides you with an opportunity to learn about

new and innovative research in various fields of the plastic

industry. Over the course of the evening, you’ll have ample

opportunity to meet with other professionals in the industry,

but more importantly, an opportunity to meet the new young

faces that will one day be part of our industry.

You don’t need to look any further than myself to see an

example of how successful these partnerships can be. Nine

years ago I attended my first University Night as a graduate

student, and met Alex Henderson from AT Plastics – a

meeting that provided me with the opportunity to be where I

am today, as I joined the company a few short months later.

And I’m sure I’m just one of many success stories that can be

traced back to these events.

On behalf of SPE Ontario, I encourage you to come out to our

next University Night, on March 19th at the University of

Guelph, Centre for Bioplastics and Biomaterials. You never

know who you’ll meet…it just might be your company’s next

shining star.

Don’t miss this event! Attendance is limited, so be sure to

pre-register to guarantee your spot.

AT Plastics

Industry-University Night

– you never know who you’ll meet

Chris Gilmor,

the Newsletter of the Ontario Section of SPE

www.4spe.org

March 2009

SPE Ontario Meeting – Thursday, March 19, 2009

SPE Ontario University NightThe Bioproducts Discovery & Development Centre Crop Science Building

University of Guelph, 50 Stone Road East, Guelph, Ontario

Members $40.00. Non-members $50.00.

Students $20.00 (Cash, cheque or Visa).

Joe DeRose, VP Program, 416-410-2286.

Email: [email protected]

Cost:

For further information please contact:

University of Guelph

Campus map

Page 2: SPE Ontario Meeting – Thursday, March 19, 2009s3.amazonaws.com/rdcms-spe/files/production/public/FileDownload… · Ontario Spectator 3 March 2009 DATE SPE Ontario Section 2009

Ontario Spectator2

March 2009

MARCH 2009 P ’ MRESIDENT S ESSAGE

Kistler Instrument Corp. helps launch our 2009 schedule

Given the economic climate, 2009 is shaping up

to offer many challenges. Companies are

constantly looking at different ways to become

more efficient, productive, and competitive. We,

the board members of the SPE Ontario section,

are always looking for interesting speakers and

topics to provide value to your organization,

where information gathered at the dinner

meetings can be of benefit. Please encourage your

employees to participate at these dinner

meetings where applicable.

Our first such meeting of 2009 featured a

presentation by Paul Lagonegro, application

manager with Kistler Instrument Corp. Kistler is

a privately-owned Swiss company which

develops and manufactures sensors and

electronics for measuring pressure, force, torque,

and acceleration. Kistler has a diverse product

line that meets the needs of different

applications. Their first product was a peizo

electric sensor for the internal combustion

engine, which has a wide range in operating

temperatures. Kistler now grows their own quartz

for sensors in truck

scales, measuring forces

on bridges, crash test and

modal analysis to name a

few. The Quartz crystal

would take 1 ½ months

to grow to a size of a

football. In injection

molding circles, Kistler is

well known for their cavity pressure, nozzle

pressure and tie bar extension sensors. Lastly, the

company has a patented single wire cable

approximately three metres long with is

customizable for each of maintenance and

service.

For further information, you can visit their

website at www.kistler.com or contact Paul

Lagonegro at (716) 691-5100, or our own board

member Bruce Lypps at (519) 473-2459.

Phil Lem,

President 2009

SPE Ontario Section

PHIL LEM

The current month's newsletter can be viewed and printed during the first week of the month by going to

www.4spe.org and selecting SPE Communities, and then Local Affiliations. Use the navigation tools to

direct you to Ontario.

Alternatively, you can do directly to http://www.4spe.org/communities/sections/28.php.

Please drop a line to [email protected] to indicate whether this option

for obtaining the monthly newsletter is of interest.

Monthly Newsletters Available Via Internet

Page 3: SPE Ontario Meeting – Thursday, March 19, 2009s3.amazonaws.com/rdcms-spe/files/production/public/FileDownload… · Ontario Spectator 3 March 2009 DATE SPE Ontario Section 2009

Ontario Spectator3

March 2009

DATE

SPE Ontario Section

2009 Program

Jan 22 2009, 6 pm

February 19 2009, 6 pm

March 19 2009, 5 pm

May 14 2009 , 8 am to 5 pm

June 12, 2009, 8 am

Advances in Measurement Technology for Plastics Processing

Delta Toronto Airport West Hotel (Dixie Road and 401)

Innovative Technologies for Thermoplastic Elastomers

Delta Toronto Airport West Hotel (Dixie Road and 401)

University of Guelph Centre for Bioplastics and Biomaterials

Delta Toronto Airport West Hotel (Dixie Road and 401)

Rolling Hills golf course

Mark the above dates on your calendars.

http://www.4spe.org/communities/sections/s28.php

Registration forms are available on the SPE Ontario section web page at

Dinner meetings are held at the Delta Toronto Airport West 5444 Dixie Rd. Mississauga

Joe DeRose, 416-410-2286; [email protected]

6:00 - 7:00 PM • 7:00 PM • 7:45 PM

Members $40.00, Guests $50.00, Students $20.00 (Cash, Cheque or VISA)

Social Hour Dinner Presentation

For further information, please contact:

Kistler Instrument Corp

Kraton Polymers LLC

David Law

University Night

April 16 2009, 5 pm Plastiflex Plant, Orangeville, OntarioPlastiflex Plant Tour and Dinner

SPE Ontario Extrusion Minitec

SPE Golf Tournament

Dear members,

The Board of Directors for SPE Ontario is pleased to present its line-up of meetings through 2008. The

monthly meetings provide a great opportunity for members to expand their knowledge and their

networks. Additionally, the social hour and the dinner make for a highly enjoyable evening.

Here's what's coming up in the near future. Unless otherwise stated, all meetings are at the Delta

Toronto Airport West Hotel in Mississauga, Ontario.

COMPANY & SPEAKER TOPIC & LOCATION

EVOPRENE® THERMOPLASTIC ELASTOMERS

FLEXIBLE PVC AND TPR COMPOUNDS

ARIFF WAKANI

PRESIDENT

ISO 9001 REGISTERED

UK • CANADA • US

TEL (905) 662 5735 xt 5007

FAX (905) 662 1683

[email protected]

AlphaGaryMarket Leadership in Specialty Compounds

Page 4: SPE Ontario Meeting – Thursday, March 19, 2009s3.amazonaws.com/rdcms-spe/files/production/public/FileDownload… · Ontario Spectator 3 March 2009 DATE SPE Ontario Section 2009

The SPE is a non-profit plastics industry association, and therefore relies on member support for The

Spectator, the newsletter of the Ontario chapter.

The Spectator is mailed to over 800 plastics industry professionals, and viewed by over 10,000 people on the

SPE Website.

Through these mediums we are able to inform our membership of monthly meetings, industry news, our

annual Christmas dance, our annual Minitec, University Night, and our golf tournament, as well as other

activities within the plastics industry.

This also offers a valuable opportunity for advertisers. A consistent advertising campaign in our newsletter will

put your company’s name before thousands of professional engineers and other decision-makers in the plastics

industry. The benefits can be substantial.

SPEctator 2009 Advertising RatesSPEctator 2009 Advertising Rates

$100.00

Special Trial offer for one issue (Business Card size):

(GST INCLUDED #128754025)

$100.00

Business card size:

¼ page:

½ page:

$650.00

$1300.00

$2600.00

2009 Rates for 9 issues:

For more information please contact:

To place an advertisement, please complete the following form and send to:

, Advertising, SPE ONTARIO

Tel: 647-223-7876 • Fax: 905-820-6938 • Email: [email protected]

, Treasurer, SPE ONTARIO • Fax: 905-820-6938 • Email: [email protected]

Mailing Address: Penny Perdis, P.O.Box 2234 Square One, Mississauga, ON L5B 3C7

LAURIE BROWN

PENNY PERDIS

Contact Person:

Fax:

Company Name:

Advertisement Size:

Cheque Enclosed VISA MC #

Signature: Name On Card:

Tel:

Email:

Total $:

Exp: /

Page 5: SPE Ontario Meeting – Thursday, March 19, 2009s3.amazonaws.com/rdcms-spe/files/production/public/FileDownload… · Ontario Spectator 3 March 2009 DATE SPE Ontario Section 2009

TPE helps give mosquitoes the brush-off

PRODUCT SPOTLIGHT

SOCIETY OF PLASTICS ENGINEERS, ONTARIO SECTION

2009 Golf Tournament Rolling Hills Golf Club, Gormley, ON, Friday June 12, 2009

At first glance, Bug Bam repellent products from Bug Bam

Products LLC seem simple enough to make. These flexible,

colorful wristbands, pet tags, and hanging grids use a

proprietary formula of all-natural essential oils to ward off

annoying and potentially harmful mosquitoes. However,

finding the right material for Bug Bam items was no picnic

for company founder and CEO Joseph Symond. With a long

list of performance, aesthetic, and safety requirements, and

negative experiences with both low-density polyethylene

(LDPE) and silicone, Symond called GLS Corporation, a

PolyOne company and a global leader in the manufacture of

highperformance, custom-formulated thermoplastic elastomers

(TPEs). DYNAFLEX 2755 TPE not only met all of Bug Bam

Products LLC's requirements, but also provided outstanding flow

characteristics for demanding new applications.

Thanks to the soft-touch feel, flexibility, resilience, and FDA

compliance of DYNAFLEX 2755 TPE, Bug Bam Products LLC

has been extremely successful with the Bug Bam line. These easy-

to-use, all-natural (DEET-free) repellent products are proving

very popular. Retail outlets include QVC home shopping, BJ's

Wholesale Club and Wal-Mart stores. As a result, Symond has

expanded the product array; the latest version will be a plug-in

vehicle fan containing an insert of the TPE material for use at

tailgate parties and other open-air scenarios.

Before contacting GLS, Symond had a vision of what the ideal

material would provide. “We had been using LDPE but found that

when users bent the wristbands, an unattractive, permanent

white line would form,” said Symond. “We wanted the upscale

look and feel of silicone, but encountered two issues. The first was

silicone's high cost, but the real deal-breaker was incompatibility

with our proprietary essential oils and fragrance that are

incorporated into the material. Frankly, when our compounder

heated up the mixture, the silicone gave off an unpleasant

odour.”

Still seeking the appearance of silicone without its drawbacks,

Symond found everything he was looking for in DYNAFLEX

2755 TPE. This grade provided an economical solution for a wide

variety of applications while delivering a soft, flexible feel; good

weatherability; ease of coloring and processing; and FDA

compliance. “Unlike silicone, DYNAFLEX 2755 TPE is

completely compatible with our oil-based formula, and can be

processed at the lower temperatures necessary to preserve the

properties of the plant oils and fragrance,” he said. “Compared to

our old material, LDPE, it's much more flexible and does not show

any effects from bending.”

The versatility of DYNAFLEX 2755 TPE is helping Bug Bam

Products LLC expand and tailor its offerings. For example, the

combination of FDA compliance with softness enables the

company to create products for babies and children. When a

major retailer asked Bug Bam Products LLC to create a special

one-size-fits-all wristband, the excellent flow characteristics of

DYNAFLEX enabled the company to create a design with a snap-

off tab having a molded-in groove that would have created

problems if done in LDPE or other lower-flow materials. “The

properties of the GLS TPE allowed us to make some minor

alterations to the mold and, within a very short period of time, we

had our customized product ready to show the buyer, who was

thrilled with it,” Symond recalled.

RegistrationMake cheques payable to:

Send To:

SPE Ontario Section

Eric Yeung

[email protected]

100 Buttermill Ave., L4K 3X7

Name:

Company Name:

Email:

Paid by: Cheque VISA MC

Name on card:

Card Number:

Expiry:

Signature:

GST# R128754025

Shotgun Start at 9:00am

Registration Opens at 8:00am

Banquet to follow at Rolling Hills

Golf & Dinner Golf OnlyChampionship Course (par 72)

Individual

Foursome

Challenge Course (par 70)

Individual

Foursome

Dinner Only

We are currently working on a Potential Guest Speaker, Texas

Mickey Challenge,

$175 $130

$650 $470

$165 $120

$600 $430

$90Donation

Pricing

Remember - No Refunds

NEW THIS YEAR

Get a Hole-in-One and Win a Car!

Page 6: SPE Ontario Meeting – Thursday, March 19, 2009s3.amazonaws.com/rdcms-spe/files/production/public/FileDownload… · Ontario Spectator 3 March 2009 DATE SPE Ontario Section 2009

Ontario Spectator6

March 2009

FEATURE RTICLEA

Abstract:

1. Introduction

2. Biobased Polyurethanes

In this review, the paths to produce polyurethane from the biological

resources are documented with the new developments in the

biotechnology. New improvements in the composites and

nanocomposites are described for the polyurethane materials. This

review gives an overview on the basic of polyurethane materials and

outlines new approaches for greener polymers with better properties

and affordable prices.

Polyurethane materials are very important class of polymers that are

used in many different types of applications. They were first discovered

in 1937 by Bayer [1] and they were in the market at the end of 1940s.

Initially, they were used as elastomers and foams [2]. Their use was

spread after further developments in the polyurethane materials. One

of the most important features of the polyurethane is that it makes all

the three basic forms of polymers; namely thermoplastic, thermoset and

elastomer. This made this polymer novel and different from the other

polymers. The polyurethanes are used widely due to the variety of

chemicals used in the synthesis of the polyurethane, different reaction

conditions and varying amounts of the reactants, creating

polyurethanes with different material properties [2]. The main

application areas for the polyurethanes today are given in Figure 1 [3].

The polyurethane is made up of 2 main groups, the isocyanates and the

polyols. There are other chemicals such as the certain catalysis,

solvents, foaming agents and chain extenders, but isocyanates and the

polyols are the major chemicals of the polyurethane forming a urethane

linkage. The basic variety of the polyurethanes comes from the variety

of these two chemicals [4].

The increased use of composite materials in the materials industry,

especially significant increase in the polymer composites after 1980’s,

also increased the use of polyurethane in composite structure materials

[5]. The polymeric composite materials have been used since 1950’s but

in the last 2-3 decades; the composite materials have become reality in

many different applications such as transportation and structural

applications. These developments in the composite materials were well

implemented to polyurethane materials, creating very novel materials

[6].

The new developments in the nanotechnology and nano materials

enable the polyurethanes to be reinforced with the nano size fillers in

the form of nanocomposites. The effects of the composite materials and

the nanocomposite materials are significant in terms of the increase in

the mechanical properties, toughness, thermal stability, flame

retardancy and biodegradability [7].

The composite and nanocomposite materials include the traditional

glass fibre, natural fibre and carbon fibre reinforced polyurethanes

where as nanocomposites include advanced composites with the

nanofillers such as nano clays, nano silica and nano cellulose [7-10].

Besides nanotechnology, biotechnology advances resulted in

production of polyurethanes made from natural resources. Plant oils

have been used for some decades. The uses of castor oil, palm oil and soy

bean oil are the commonly used for polyols toward the synthesis of the

polyurethanes [11]. The use of wood based polyols enables new routes

for polyurethane synthesis. The use of biobased materials leads to the

green polymers and the polyurethanes.

The use of the biobased resources is very critical in many different

aspects. First, the reduction in the use of the petroleum based products

is very critical. Also, natural fibres can be used as reinforcing phase at

the micro- and nano-scale. Thirdly, some of the wastes, such as lignins

and recycled paper, can be utilized with these chemical routes. Lastly,

the use of biobased materials can lower the cost of the final product [12].

Polyurethanes derived from plant material are considered as semi-

biobased materials, due to the presence of isocyanates which are

derived from petroleum products. Current industrial polyurethanes

almost exclusively come from polyols derived from the petroleum-

based products. The commonly used polyols are the polyester polyols,

polyether polyols and polycarbonate polyols [3]. The critical path to

biobased polyurethanes is the use of natural polyols instead of

petroleum-based polyols [11]. Alternatively, use of natural fibres as

Biobased Polyurethane and Polyurethane Composite Materials

for Automotive Applications

M.Ozgur Seydibeyoglu , Amar K. Mohanty *, Manjusri Misra

1) Bioproducts Discovery and Development Centre, Department of Plant Agriculture,

Crop Science Building, University of Guelph, Guelph, N1G 2W1, ON, Canada.

2) School of Engineering, Thornbrough Building, University of Guelph, Guelph, N1G 2W1, ON, Canada.

*E mail: [email protected]

1 1,2, 1,2

Figure 1: Different Applications of Polyurethanes

29 %, the insulation

27 %, the furniture and mattress

12 %, the automotive

5 %, the shoes

27 %, other applications

Page 7: SPE Ontario Meeting – Thursday, March 19, 2009s3.amazonaws.com/rdcms-spe/files/production/public/FileDownload… · Ontario Spectator 3 March 2009 DATE SPE Ontario Section 2009

Ontario Spectator7

March 2009

FEATURE RTICLEA

reinforcing material or filler is another path to get green materials [12].

Current annual consumption is 3000 million pounds of polyurethane

foam and 400 million pounds of polyurethane fillers and binders [11].

The use of biobased polyols is very important in terms of the

polyurethane consumed. The polyols used in these polymers can be

easily replaced with biopolyols.

The biobased polyols vary, depending on the plant resource. The plants

can be from the agriculture or from the forestry products. The

agriculture-based polyols are more widely used for the polyurethane

production compared to wood-based materials. Some of the important

polyols from agricultural resources used are [11];

i. Soybean oil

ii. Castor oil

iii. Palm oil

The synthesis methods of the polyurethane from the natural oil-based

polyols have to be very specific, as these oils have wide range of

molecular weight and variation of double bonds content, affecting the

final properties and the viscosity of the polyurethanes [11]. Results from

Guo et al. [13] on the production of polyurethanes with soybean oil and

halogenated soybean oil [14] and Janvil et al. [15] on the production of

polyurethanes from vegetable oil, showed that the polymers were

comparable with the petrochemical products and had better thermal

stability. The effect of the NCO/OH ratio was also studied for the

soybean oil-based polyurethanes [16]. It was shown that as the ratio

decreased from 1.05 to 0.4 the mechanical properties and the Tg values

decreased significantly. Singh and Battacharya [17] studied the cell

openings and viscoelastic changes in the formation of polyurethanes

with soybean oil. Dwan’Isa et al. [18] studied the thermomechanical

behaviour of polyurethanes prepared with soybean phosphate ester

polyol and determined the optimum curing conditions and hydroxyl

content for the rigid polyurethane materials. There are various studies

on castor oil [19-21], palm oil [22] and other oil based polyurethanes

showing the use of different plant oils as polyols [23-24].

Besides agricultural polyols, wood based polyols are very important in

terms of the abundance of the wood and forest products.

Wood contains different materials such as lignin (17-35%), cellulose

(40-45%) and hemicellulose (15-35%). There are additional

compounds such as gums, fats, resins, oils, alkaloids, starches, tannins

and some inorganic materials. Wood can be used as polyols if it is

liquefied [3]. Chemical transformation can be used to obtain liquefied

oil, but recently wood is liquefied mainly with certain solvents.

Polyurethanes are obtained in the form of foams or sheets with two

different processes. Kurimoto et al. [25] obtained some films with

liquefied wood. Madas and Shiraishi [26] obtained polyurethane foams

with liquefied wood.

The other important family of the polyols comes from the lignin family

which can be wood- based or agriculture-based. Lignin is a waste

product of different industries, such as paper and alcohol. These

different lignins were used for the production of polyurethanes. Saraf

and Glasser [27] used kraft lignins and steam explosion lignins to

synthesize polyurethanes which were stiff and brittle. Yoshido et al. [28]

also used kraft lignins with different isocyanates to produce

polyurethane. Hatakeyema et al. [29] prepared polyurethanes from

kraft lignin and organosolv lignin in the presence of polyethylenglycol

and polypropylene glycol. In all these studies, the stiffness of the

polyurethane increased with the increase of the lignin polyols. Saraf

and Glasser [30] improved the flexibility with the addition of

polyethyleneglycol. Thring et al. [31] studied the effect of the Alcell

lignin (organosolv lignin)-polyetheyleneglycol-isocyanate reactions to

produce the polyurethane. Sarkar and Adhikari [32] investigated the

incorporation of the hydroxyl terminated polybutadiene (HTPB)

structure to the polyurethane and lignin. In this way they eliminated

the process of oxyalkylation process. Instead of incorporating the lignin

in the polyurethane structure, the lignin was incorporated into the

HTPB-PU polymer resulting in a more flexible material. Hatakeyama

et al. [33] studied the polyurethane materials produced from lignin and

molasses to be used as geocomposite materials in the construction of

tunnels. Natansohn et al. [34] discovered the good interactions and

blending with the detailed nuclear magnetic resonance (NMR)

analysis. Ciobanu et al. [35] prepared composite materials of

polyurethane and lignin with solvent casting method and obtained

interactions of the polyurethane and lignin. They optimized with 5 wt

% of lignin in the polyurethane material with improved mechanical

properties and improved biodegradation.

Polyols can also be obtained from starch and cellulose from the plants.

These materials are also first liquefied. There are few studies on these

materials, showing the importance of natural resources as a renewable

and affordable material. Cellulose, being most abundant molecule in

the nature, should be well utilized and it should not be wasted [36].

There are other polyol resources such as the nut shells and the cork

materials [37-38].

The natural fibre-reinforced polymers are considered green materials

due to inherent properties of the natural fibres and the increased rate of

degradation rate with the natural fibres. The origin of natural fibres is

various plants and forestry products [12]. The uses of natural fibre-

reinforced composites are shown for different industries in Figure 2 [39].

The incorporation of the natural fibres, specifically cellulose materials,

at the nanoscale improves the properties of the polymer enormously.

There are other nanomaterials used to make nanocomposites of

polyurethane, such as nanoclays, nano silica and some carbon

nanofibres. Besides nanocarbon and nanosilica, nanoclays help the

polyurethane degrade faster as they have similar structure with the

natural clays which are a form of the soil [7].

For the natural fibre-reinforced polyurethanes, several research studies

have been conducted. The natural fibres were utilized at the micron

and the nanoscale in the polyurethane matrix. Wu and Mohanty [40]

used distillers’ dried grains with solubles (DDGS) to obtain

biocomposites of polyurethane and improve the properties of DDGS

Polyols from wood based materials

3. Biobased Polyurethane Composites

Figure 2: The application areas of natural fibre composites.

31 %, automotive

26 %, construction

12 %, marine

10 %, electronic

8 %, appliances

8 %, consumer products

4 %, miscellaneous

1 %, aerospace

Page 8: SPE Ontario Meeting – Thursday, March 19, 2009s3.amazonaws.com/rdcms-spe/files/production/public/FileDownload… · Ontario Spectator 3 March 2009 DATE SPE Ontario Section 2009

Ontario Spectator8

March 2009

with hydrophobic polyurethane. Rials and Wolcott [41] used wood

fibres to reinforce the polyurethane and significant increase was

observed with the increase in the wood fibre content of the

polyurethane matrix. Wu et al. [42] and Auad et al. [43] showed the

importance of the nanowhiskers of cellulose to reinforce the

polyurethane. Seydibeyoglu and Oksman [44] showed the importance

of fibrillation for the cellulose fibres to obtain cellulose nano fibrils and

they have shown that the impact of the nano sized fibrils was more

significant than the micron size cellulose.

The nano clays were used for many different polymer systems in order to

increase the mechanical properties with increase in the toughness

values [45]. The other benefits of the use of the clays are the increase in

biodegradation and flame retardancy [7]. Wang and Pinnavaia [46]

were the first to incorporate the montmorillonite clay in the

polyurethane material. Then there were studies in 2000’s to understand

the effect of different isocyanates and different polyols in the formation

of polyurethane [47-49]. Pattanayak and Jana [50] studied different

polymerization techniques. There are some studies conducted with

carbon fibres at the micron scale and some recent studies with the

nanocarbon fibres for certain biomedical, electronic applications and

structural applications [51].

For future polyurethane materials, natural resources offer new

opportunities and challenges with the rapid developments of the

nanotechnology. The soy polyols are used in some polyurethanes for

automotive applications [52-53]. The use of soy bean oils can be further

improved with the genetic modification of the soy-based materials

specifically designed for the polymeric materials which can be

biodegradable and developed to meet certain criteria. The use of

natural fibres from various plants can be utilized as polyol for the

polyurethane, or as reinforcing fibre - for the polyurethane composite

materials.

The rapid developments in the nanotechnology will enable optimized

mechanical properties of the polyurethane with high precision

technology. The use of the natural fibres at the nanoscale enormously

improves the mechanical properties of the polyurethanes, while

helping the polyurethane degrade faster in the soil. The use nanoclays

offer faster degradation of the polymers in the soil, as the natural clays

are part of the soil on this earth.

The new developments will bring additional material benefits for the

automotive industry in terms of lighter materials, better sound effects

and better mechanical properties which can be renewable and

degradable.

In this review, the historical backgrounds of polyurethanes with special

emphasis on the production of polyurethanes from the biobased

materials are given. Like in the other polymer systems, there is dense

research to obtain polyurethanes from renewable resources which can

degrade in the soil after certain time. The recent developments are

presented. The new developments of the composites and

nanotechnology are explained. Possible future materials from the

polyurethane are proposed as possible research topics for the

researchers in the industry and the academia.

A K Mohanty is thankful to the Ontario Ministry of Research and

Innovation (MRI) for the financial support under MRI-Postdoc

program. M.Ozgur Seydibeyoglu is thankful for a postdoctoral

fellowship under this MRI-postdoc program. M. Misra is thankful to

2008 Ontario Soybean Growers’ fund for the support.

O. Bayer, W. Siefken, H. Rinke, L. Orthner and H. Schild,

German Patent DRP 728981, 1937.

P. Krol, Prog. in Mat. Sci.; 52, 915–1015 (2007).

J.P.L. Dwan’Isa, A. K. Mohanty, M. Misra and Lawrence T. Drzal

“Biobased Polyurethanes and Their Composites: Present Status

and Future Perspective” in Biopolymers, Natural Fibres and

Biocomposites, Taylor and Francis Publisher, 2005.

M. Szycher, Szycher's Handbook of Polyurethanes CRC Press,

1999 p. 2-6

“New Materials for Next Generation Commercial Transports”

National Academies Press Committee on New Materials for

Advanced Civil Aircraft, Commission on Engineering and

Technical Systems, National Research Council, 1996, p.37.

A. Buekers, E. V. Hinte, “Lightness, The inevitable renaissance of

minimum energy structures” 010 Publishers, 2005, p.15.

S. S. Ray and M. Okamoto, Prog. Polym. Sci.; 28, 1539-1641

(2003).

P. C. LeBaron, Z. Wang and T. J. Pinnavaia, Appl. Clay Sci.; 15,

11–29 (1999).

J. Shen, Z. Zhang and G.Wu, J. Chem. Eng. Japan; 36, 1270-1275

(2003).

Cellulose Nanocomposites Processing, Characterization and

Properties Edited by Kristiina Oksman and Mohini Sain, Oxford

Press, p. 1-274

V. Sharma and P.P. Kundu, Prog. in Polym. Sci.; 33, 1199-1215

(2008).

A.K.Mohanty, M.Misra, L.T. Drzal, S.E. Selke, B.R. Harte and G.

Hinrichsen, “Natural Fibres, Biopolymers, and Biocomposites:

An Introduction”, in Biopolymers, Natural Fibres and

Biocomposites, Taylor and Francis Publisher, 2005.

A. Guo, I. Javni and Z. Petrovic, J Appl Polym Sci; 77,467–73

(2000).

A. Guo, Y. Cho and Z.S. Petrovic ZS. J. Polym. Sci. Part A: Polym.

Chem.; 38, 3900-3910 (2000).

I. Javni, Z.S. Petrovic, A. Guo A and R. Fuller, J. Appl. Polym.

Sci.; 77, 1723–34 (2000).

Z.S. Petrovic, W. Zhang, A. Zlatanic, C.C. Lava and M. Ilavsky. J.

Polym. Environ.; 10,5-12 (2002).

A.P. Singh and M. Bhattacharya. Polym Eng. Sci.; 44, 1977-1986

(2004).

J.P. Dwan’Isa, A.K. Mohanty, M. Misra, L.T. Drzal and M.

Kazemizadeh. J. Polym. Environ.;11, 161–168 (2003).

S. Ajithkumar, S.S. Kansara and N.K. Patel. Euro Polym. J.;

34,1273-1276 (1998).

K.P. Somani, S.S. Kansara, N.K. Patel and A.K. Rakshit, Int. J.

Adhesion Adhesives; 23, 269–275 (2003).

H. Yeganeh and M.R. Mehdizadeh, Euro. Polym. J.; 40,1233-1238

(2004).

K.S. Chian and L.H. Gan, J. Appl. Polym. Sci.; 68, 509-515

(1998).

N. Dutta, N. Karak and S.K. Dolui, Progr. Org. Coat.; 49, 146-152

4. Future Directions

Conclusions

Acknowledgements

References

1.

2.

3.

4.

5.

6.

7.

8.

9.

10.

11.

12.

13.

14.

15.

16.

17.

18.

19.

20.

21.

22.

23.

FEATURE RTICLEA

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Ontario Spectator9

March 2009

FEATURE RTICLEA

(2004).

S.S. Mahapatra and N. Karak, Progr. Org.

Coat.; 51, 103-108 (2004).

Y. Kurimoto, M. Takeda, A. Koizumi, S.

Yamauchi, S. Doi and Y. Tamura, Bioresour.

Technol.; 74, 151–157 (2000).

D. Madas and N. Shiraishi, Int. J. Polym.

Mater.; 33, 61-71 (1996).

V.P. Saraf and W.P. Glasser, J. Appl. Polym.

Sci.; 29, 1831-1841 (1984).

H. Yoshida, R. Morck, K.P. Kringstad and H.

Hatakeyama, J. Appl. Polym. Sci.; 34, 1187

(1987).

H. Hatakeyama, S. Sirose, K. Nakamura and T.

Hatakeyama, Cellulosics : Chemical ,

Biomedical and Material Aspects, Kennedy,

J.F., Phillips, G.O., and Williams, P.A., Eds.,

Ellis Horwood, New York, (1993), p. 523–536.

V.P. Saraf, W.G. Glasser, G.L. Wilkes and J.E.

McGraph, J. Appl. Polym. Sci.; 30, 2207-2224

(1985).

R. W. Thring, M. N. Vanderlaan and S. L.

Griffin, Biomass and Bioenergy 13, 125-132

(1997).

S.Sarkar and B.Adhikari, Eur. Polym. J.;

37,1391-1401 (2001).

H. Hatakeyama, A. Nakayachi and T.

Hatakeyama, Composites: Part A; 36,

698–704, (2005).

A. Natansohn, M. Lacasse, D. Banu and D.

Feldman, J. of Appl. Polym. Sci.; 40, 899-904

(1990).

C. Ciobanu, M. Ungureanu, L. Ignat, D.

Ungureanu and V.I. Popa, Ind. Crops and Prod;

20, 231–241 (2004).

S.H. Lee, Y. Teramoto and N. Shiraishi, J.

Appl. Polym. Sci.; 83, 1482-1489 (2002).

H.P. Bhunia, R.N. Jana, A. Basak, S. Lenka and

G.B. Nando, J. Polym. Sci. Chem.; 36, 391-400

(1998).

M. Evtiouguina, A.M. Barros, J.J. Cruz-Pinto,

C.P. Neto, N. Belgacem and A. Gandini,

Biomacromolecules; 3, 57–62 (2002).

M. J. John and S. Thomas, Carbo. Polym.; 71,

343-364 (2008)

Q. Wu and A.K.Mohanty, J. Biobas. Mat.

Bioener.; 1, 257-265 (2007).

T.G. Rials, M.P. Wolcott and J.M. Nassar. J. Appl. Polym. Sci.;

80, 546-55 (2001).

Q. Wu, X. Liu and L.A. Berglund, In: Proceedings of the 23rd Riso

International Symposium on Materials Science: Sustainable

Natural and Polymeric Composites-Science and Technology,

Roskilde, Denmark, 2002

M.L. Auad, V.S. Contos, S. Nutt, M.I. Aranguren and N.E.

Marcovich. In: Proceedings of COMAT 2005. International

Conference on Science and Technology of Composite Materials:

Argentina, 2005, p. 35–36.

M. Ozgur Seydibeyoglu and K. Oksman, Comp. Sci. Tech.; 68,

908–914 (2008).

A. Pattanayak and S.C. Jana, Polym. Eng. Sci.; 45, 1532-1539

(2005).

Z. Wang and T. J. Pinnavaia, Chem. Mater.; 10, 3769-3771

(1998).

X. Cao, L. J. Lee, T. Widya, C. Macosko, Polymer; 46, 775-783

(2005).

W. J. Choi, S. H. Kim, Y. J. Kim, S. C. Kim, Polymer; 45, 6045-

6057 (2004).

M. Tortora, G. Gorrasia, V. Vittoria, G. Galli, S. Ritrovati and E.

Chiellini, Polymer; 43, 6147-6157 (2002).

A. Pattanayak, and S.C. Jana, Polymer; 46, 3275-3288 (2005).

R. Verdejo, G. Jell, L. Safinia, A. Bismarck, M. M. Stevens and

M.S.P. Shaffer, J. Biomed. Mat. Res. Part A; 88A, 65-73 (2008).

http://www.woodbridgegroup.com , (Accessed on 24 February,

2009)

http://www.soynewuses.com/downloads/biobased/Biobased

SolutionsSept2007b.pdf (Accessed on 24 February, 2009)

24.

25.

26.

27.

28.

29.

30.

31.

32.

33.

34.

35.

36.

37.

38.

39.

40.

41.

42.

43.

44.

45.

46.

47.

48.

49.

50.

51.

52.

53.

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Might I inquire, fair reader, how you spent your

Christmas vacation? “At home with family,”

you say? Truly, I'm glad to hear it. What did I

do, you ask? Well, I was fortunate enough to go to South

Africa.

The reasons to go were compelling: I'd never been

before, the weather would be sunny and hot, we could

see long lost friends and stay with them , and –

almost best of all – I could skip the dreaded holiday

shopping season for the first time in my adult life. (And,

of course, if anything chanced to be happening on the

South African plastics front I could always report on it,

but I can't honestly describe that as a compelling

motive.)

The three-week trip had the following itinerary: spend a

few days with some friends on a safari trip north of

Johannesburg, travel down to the seaside town of

Hermanus to stay with a particularly close friend over

Christmas and New Years, and then return to

Johannesburg for a few days before flying back to

Canada.

Having only experienced Ontario's own African Lion

Safari to that point in my life, an authentic safari was

not to be missed – nor did it disappoint. Maybe it's a

union-requirement kind of thing, but the elephants,

lions, rhinos, zebras, giraffes, etc. all cooperated by

turning out en masse to be seen when we took driving

trips into the wild. I also managed to sneak in a round of

golf, although my joy at imagining friends shoveling

snow back home whilst I drew back the blade was

tempered slightly by my almost hitting an ostrich

standing on the 9th fairway. (But, said I to my golf

partner, it's better than almost hitting one that's

standing in the rough. My golf partner was a real joker,

by the way: while identifying and describing the local

birds to me, he explained the almost fearful sounding

cry emitted by one airborne bird by telling me that the

species was afraid of heights…and I actually believed

him for a few seconds.)

Hermanus, a resort town near the African continent's

southernmost tip, is famous for its whale watching. Of

whales, however, I saw none. But I'd be remiss if I didn't

mention Sam. Sam is a wonderful Border Collie owned

by the friend with whom we stayed. Like most dogs, one

of the great joys of Sam's life was to be taken for a long

walk (preferably about 20 times a day), and I was happy

to volunteer to be the

walker . Sam had the

unusual habit, though, of

continually looking back at

me while running ahead –

with predictable results.

Despite my warnings, he ran

into each of the following at

least once: a tree, a mailbox,

a picket fence, and a parked

car.

Back in Johannesburg, I

noticed that, although

beautiful, the city has its rough edges – or, to be blunt,

neighbourhoods that make Toronto's notorious Jane

and Finch area look ritzy by comparison. Denizens of

“Jo'burg”, I was told, are accustomed to taking such

precautions as keeping their windows up and car doors

locked while driving, their hand firmly on their wallet

while taking a stroll, etc. The lesson refused to sink in

with me, however. I wish I could say that I had an

unshakeable faith in the decency of my fellow man, but

the simple truth is that I was slightly scatterbrained and

regularly forgot to watch my back. One night, friends

gave me a particularly strong scolding – to put it

mildly – after I withdrew some cash from a bank

machine and then blithely strolled down the street

openly counting the bills. I suspect they made bets

among themselves as to how long it would take me to

get mugged, and how many muggings it would take until

I learned my lesson.

That's not to say that I escaped the city entirely

unscathed. I had also been warned against purchasing

hand-carved souvenirs at any one of Johannesburg's

numerous flea markets without proper supervision, lest I

get talked into buying something for ten times its real

value. I resented the imputation – i.e., that I had

“sucker” written all over me – and deliberately struck off

on my own at a flea market one afternoon. I drove a

reasonably hard bargain with one vendor and acquired a

splendid set of zebra bookends…or so I thought. Having

selected them, I let my mind wander while the fellow

wrapped them securely in bubblewrap and then

newspaper, and didn't open the parcel until after

arriving home in Canada a week later – only to find

that, while my back had been turned, he'd switched the

immaculate looking bookends I'd chosen for a damaged

pair, and wrapped those instead.

gratis

Editorially akingSPE

MARK STEPHEN

Hunting plastics in South Africa

Ontario Spectator10

March 2009

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Ontario Spectator11

Editorially akingSPE

As I believe I mentioned at the outset, researching

plastics didn't exactly figure at the top of my to-do list.

Sometimes, though, the good ole journalistic instincts,

while to all appearances at rest, burst forth suddenly

into uncontrollable life. To wit: I couldn't help but

notice that many of the South African towns and cities

that I went through had stores selling nothing but

plastics products – with the corollary that it was very

hard to find plastic goods anywhere except in these

stores. The shops bore names like “Plastics for Africa”

and “Plastics Etc.” Was there a system of plastics

apartheid at work here? I (sort of) burned to learn the

answer. Donning my metaphorical investigative

reporter's hat, I marched into one or two of these stores

and asked the employees to enlighten me as to the

rational for keeping plastics, as it were, in isolation.

They couldn't enlighten me, however, and so I chalked

the whole thing up to cultural differences and got back

on with my vacation, secure in the knowledge that I'd

done my best for our industry – that I'd summoned up

every iota of my skill, but that the mystery was

ultimately unsolvable.

Of course, if my publisher chooses to send me back to

ask these tough questions again – at company expense,

of course – my golf clubs and I stand ready to make the

trip.

Mark Stephen is the managing editor of Canadian

Plastics magazine. He's still searching for a good set of

zebra bookends.

March 2009

Plastics apartheid?

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