Robert MannD. Kubiznak, N. Altimirano, S. Gunasekaran, B. Dolan, D. Kastor, J. Traschen, Z. Sherkatgnad

D.Kubiznak, R.B. Mann JHEP 1207 (2012) 033 S. Gunasekaran, D.Kubiznak, R.B. Mann JHEP 1211 (2012) 110

B. Dolan, D. Kastor, D.Kubiznak, R.B. Mann, J. Traschen Phys. Rev. D87 (2013) 104017N. Altimirano, D.Kubiznak, R.B. Mann Phys. Rev. D88 (2013) 101502

N. Altimirano, D. Kubiznak, Z. Sherkatgnad, R.B. Mann CQG 31 (2014) 042001 N. Altimirano, D. Kubiznak, Z. Sherkatgnad, R.B. Mann Galaxies 2 (2014) 89

The Everyday Phenomena of Black

Hole Chemistry

Black Hole Thermodynamics

Thermodynamics Gravity

?

Smarr Formula

Schwarzschild Black hole

Schwarzschild-AdS Black hole

Smarr

L. Smarr PRL 30, 71 (1973) [Err. 30, 521 (1973)].

Smarr?

Scaling ArgumentsSuppose

S-AdS Black Hole

Caldarelli/Cognola/Klemm, CQG 17, 399

(2000)

Schwarzschild-AdS Black hole

Smarr First Law

Pressure from the Vacuum?

Provided

Thermodynamic Pressure

Thermodynamic Volume

Dolan CQG 28 (2011) 125020; 235017

The Chemistry of AdS Black HolesInclude gauge charges:

First Law

Smarr Relation

Thermodynamic Potential: Gibbs Free Energy

• Equilibrium: Global minimum of Gibbs Free Energy• Local Stability: Positivity of the Specific Heat

Mass as EnthalpyThermodynamics Gravity

Mass= Total Energy

- Vacuum Contribution

(infinite)

Everyday AdS Black Hole Thermodynamics

• Hawking Page Transition• Van der Waals Fluid and Charged AdS Black

Holes• Reentrant Phase Transitions• Black Hole Triple Points Solid/Liquid/Gas

• AF black holes evaporate by Hawking radiation• AdS is like a confining box static black holes in thermal equilibrium

1st order transition between gas of particles and large black holes at Tc

Hawking-Page TransitionD-dim’l Schwarzschild-AdS Black hole

S.W. Hawking & D.N. PageComm Math. Phys. 87 (1983) 577

Phase transition in dual CFT (quark-gluon plasma)

Fluid interpretation: solid/liquid PT (infinite coexistence line)

Planar black holes ideal gas

Equation of state

depends on the horizon topology

Witten (1998)

D. Kubiznak/RBM arXiv [1404.2126]

Van der Waals Fluids

Critical Point

law of corresponding states

PV Diagram for a VdW Fluid

Maxwell’s Equal Area Law

First Law

Gibbs Free Energy

characteristic of the gas

Clausius-Clapeyron equation

Line of Coexistence

Critical Exponents

For a VdW Fluid

Specific Heat

Order Parameter

Isothermal Compressibili

tyCritical

Isotherm

Charged AdS Black Holes as Van der Waals Fluids

Temperature

Entropy

Potential

Pressure

Volume

Smarr Relation First Law

Kubiznak/MannJHEP 1207

(2012) 033

Equation of State

Physical Equation of State

Thermodynamic Volume

Van der Waal’s Equatio

n

Gibbs Free Energy of AdS RN BH

Just like a VdW Fluid!

Fixed Charge

NB: Disagree with Chamblin et.al. PRDD60 (1999) 064018; 104026

Critical Behaviour

Just like a VdW Fluid!

law of corresponding states

Just like a VdW Fluid!

govern volume, compressibility, specific heat, and pressure near the critical point

RPT: If a monotonic variation of any thermodynamic quantity that results in two (or more) phase transitions such that the final state is macroscopically similar to the initial state.

Reentrant Phase Transitions

T. Narayanan and A. Kumar Physics Reports 249 (1994) 135

• multicomponent fluid systems

• gels• ferroelectrics• liquid crystals• binary gases

First observed in nicotine/water C. Hudson

Z. Phys. Chem. 47

(1904) 113.

Single-Rotation Black Holes

Smarr Relation First Law

Dimensional Dependence of G

Zeroth-Order Phase Transition

Reentrant Phase Transitions in D>5

Zeroth-Order Phase Transition

Reentrant Phase Transitions in D>5

Coexistence Lines

NO BLACK

HOLES

Slow and Ultraspinning Limits

RPTs do not require variable cosmological constant

J/T Phase DiagramN. Altimirano, D. Kubiznak, Z. Sherkatgnad, R.B. Mann

Galaxies 2 (2014) 89

Triple Points in Multiply Rotating Black Holes

Triple Point!

N. Altimirano, D. Kubiznak, Z. Sherkatgnad, R.B. Mann CQG 31 (2104) 042001 arXiV:1308.2672

Reentrant Phase transitionEnding in a Triple Point

N. Altimirano, D. Kubiznak, Z. Sherkatgnad, R.B. Mann CQG 31 (2014) 042001

The Black Hole Triple Point

• Continuous variation of N is probably OK.

• Classical gravity corresponds to (similar to TD limit…can vary number of moles continuously) Quantized N…quantum gravity effects?

• “Grand-canonical ensemble of stringy vacua” with conjugate quantity playing role of “chemical potential”?

Variable and AdS/CFT?

Summary• Cosmological Pressure can be understood as a

Thermodynamic Quantity– First Law is modified to include a pressure-volume term

• Smarr Law needs to be modified to respect scaling • Mass becomes Enthalpy• “Everyday Chemical Thermodynamics” is manifest

– Van der Waals Transitions• Small/large liquid/gas phase • Critical Phenomena analogous

– Reentrant Phase Transitions– Triple Points

These phenomena do not require a

variable cosmological

constant!

Open Questions

• Meaning of Conjugate Volume?• Compressibility and Stability?• Gauge/Gravity Duality interpretation?• More exotic black holes?

– Lovelock Black Holes?– Lifshitz Black Holes?

• 1+1 Pressure-Volume?• Meaning of de Sitter Thermodynamics?• Other “everyday analogues”?

D. Kubiznak, N. Altimirano, W. Brenna, M. Park, F. Simovic, Z. Sherkatgnad, J. Mureika, S. Solodukhin

Mo/Li/Liu; Wei/Liu; Ballik/LakeDutta/Jain/Soni; Zhou/Zhang/Wang

Breton/Vergliaffa; Cai/Cao/Zhang;Allahverdizadeh/Lemos/Sheykhi;

Lu/Pang/Pope/Vasquez-Portiz