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NAMING MOLECULES
Taurine - The stimulant in the 'energy drink' Red Bull
NAMING BINARY MOLECULES Remember:
Molecules are substances that are covalently bonded together.
They contain a nonmetal bonded to a nonmetal.
How can you tell the difference between a polyatomic ion and a molecule?Poly-ions have a charge when not
bonded to a metal – ex. (PO4)3- or K3PO4
Molecules contain only nonmetals and NO overall charge – ex. P2O3
BINARY COVALENT COMPOUNDS – NAMING/FORMULAS
FIRST WORD:NAME OF ELEMENT THAT APPEARS FIRST IN FORMULA
PREFIX TO SHOW # ATOMSIF “ONE/MONO”– NO PREFIX
SECOND WORD:PREFIX TO SHOW # ATOMS“STEM” OF SECOND ELEMENTEND IN “IDE”
MOLECULAR PREFIXES
1 mono- 6 hexa-
2 di- 7 hepta-
3 tri- 8 octa-
4 tetra- 9 nona-
5 penta- 10 deca-
In order to be effective in naming molecules, these prefixes must be committed to memory:
BINARY COVALENT COMPOUNDS – NAMING/FORMULAS
PCl3Phosphorous trichloride
Cl2O7Dichlorine heptoxide
COCarbon monoxide
BINARY COVALENT COMPOUNDS – NAMING/FORMULAS
Nitrogen dioxideNO2
Sulfur hexafluorideSF6
Tetraiodine nonoxideI4O9
NAMING BINARY MOLECULES – LEARNING CHECK
EX: SO3 is ____________________
Sulfur trioxidePBr5 is ____________________
Phosphorus pentabromideICl3 is _____________________
Iodine trichlorideH20 is _____________________
Dihydrogen monoxide
WRITING BINARY MOLECULESNow… let’s look at writing the molecular formula from the name. When writing the formula of a
molecule, an atom’s prefix is its subscript.
Do not cross anything. When there is only one of the first atom, a prefix is not used.
Let’s view some examples…
Example #1-Names to Formulas
Sulfur trioxide
SO32. Write number of atoms
1. Write symbols of elements
Final FormulaIf no prefix, then 1 is
implied and not written
Example #2-Names to Formulas
dichlorine heptoxide
Cl O2 72. Write number of atoms
1. Write symbols of elements
Final Formula
Example #3-Names to Formulas
phosphorus pentachloride
PCl52. Write number of atoms
1. Write symbols of elements
Final FormulaIf no prefix, then 1 is implied and
not written
Example #4-Names to Formulas
dinitrogen monoxide
N O22. Write number of atoms
1. Write symbols of elements
Final FormulaIf no prefix, then 1 is implied and
not written
Example #5-Names to Formulas
carbon monoxide
CO2. Write number of atoms
1. Write symbols of elements
Final FormulaIf no prefix, then 1 is implied and
not written
Example #6-Names to Formulas
dinitrogen trisulfide
N S2 32. Write number of atoms
1. Write symbols of elements
Final Formula
STRANGE NAMES FOR MOLECULES
ANOL
BUTANOL
MORONIC ACID
CRAPINON
NAMING ACIDS
Exactly four water molecules and one hydrogen chloride molecule are
necessary to form the smallest droplet of acid
NAMING ACIDS Acids are molecular compounds that
contain hydrogen bonded to a nonmetal or to a group of polyatomic ions.
Acids can be either binary or ternary compounds.
Names of binary acids have the form hydro-…ic acid.
Names of ternary acids use a series of prefixes and suffixes to specify the # of oxygen atoms in the molecule.
hydrochloric acid
NAMING BINARY ACIDSNames of binary acids have the form
hydro-…ic acid
EX: Binary acid: HF is hydrofluoric acid HCl is hydrochloric acid
Try:
H2S is _____________________
Hydrosulfuric acidHI is _____________________
Hydroiodic acidHBr is _____________________
Hydrobromic acid
NAMING TERNARY ACIDS When naming ternary acids, identify
polyatomic ion in the formula. For polyions that end in “ate” change the
ending to “ic”. (Something I “ate” made me feel “ic”.)
For polyions that end in “ite” change the ending to “ous”.
(A snake b“ite” is poison“ous”)
EX: nitrate nitricnitrite nitroussulfite sulfoussulfate sulfic
NAMING TERNARY ACIDS Some ternary acids have more than one
oxygen possibility. When naming ternary acids from
polyions that have up to four oxygen possibilities: per-… -ic greatest # of oxygen atoms.
-ic greater -ous smaller
hypo-… -ous smallest # of oxygen atoms.
*Know all forms of ClO3-1 and IO3
-1
NAMING TERNARY ACIDS
Polyion Acid Formula Acid Name ClO4
-1 HClO4 perchloric acid ClO3
-1 HClO3 chloric acid ClO2
-1 HClO2 chlorous acid ClO-1 HClO hypochlorous acid
Name:HIO
Hypoiodous acidHIO2
Iodous acid
HIO3
Iodic acid
HIO4
Periodic acid
NAMING ACIDS – LEARNING CHECK
EX: HCl is ____________________ Hydrochloric acid
H2SO4is ____________________
Sulfuric acidH3PO4 is _____________________
Phosphoric acidHF is _____________________
Hydroflouric acidHNO3 is _____________________
Nitric acidHNO2 is _____________________
Nitrous acid
WRITING FORMULAS OF ACIDS Acids are molecules that are covalently
bonded yet they have properties of ionic compounds so use rules for creating neutral ionic compounds.
Formulas for acids begin with Hydrogen. The oxidation state for hydrogen is +1.
Identify if the acid is binary or ternary. If the acid is binary, it will have a “hydro” prefix, all others will be ternary.
FORMULAS OF BINARY ACIDS
Write H+1 Identify the monotomic anion by its root
name in the acid. Determine its charge by following the
oxidation trend for the groups. Write the element symbol and its negative
oxidation. Criss Cross charges to create neutral acid
formulas.
FORMULAS OF BINARY ACIDSEX: hydrosulfuric acid
H+1 S-2
H2S
Now Try: hydrochloric acid hydrobromic acidhydrophosphoric acid hydrofluoric acid
H+ + Cl- = HCl
H+ + Br- = HBrH+ + P-3 = H3P H+ + F- = HF
FORMULAS OF TERNARY ACIDS
Write H+1
Identify polyion by: 1. ic ate and ous ite suffixes2. prefixes of per and hypo to indicate numbers of oxygen atoms for chlorates and iodates.
Write formula of polyion including oxidation.
Criss Cross charges for neutral formula.
FORMULAS OF TERNARY ACIDSEX: sulfuric acid
H+1 SO4-2
H2SO4
Now try:phosphoric acid nitric acid(ate to ic) H+ + PO4
-3 = H3PO4 (ate to ic) H+ + NO3- = HNO3
nitrous acid sulfurous acid(ite to ous) H+ + NO2
- = HNO2 (ite to ous) H+ + SO3-2 =
H2SO3
perchloric acid hypoiodous acid(ate to ic) H+ + ClO4
- = HClO4 H+ + IO- = HIOacetic acid(ate to ic) H+ + C2H3O2
- = HC2H3O2
THE END!
REVIEW FOR TEST - NOMENCLATURE
1. Ionic CompoundsBinary Ionic Compounds Ionic Compounds with Polyatomic Ions
Oxidation #s must add to zero (criss cross) Some elements have more than one oxidation # Metal & Non-metal
2. Molecular CompoundsBinary Molecular Compounds
Non-metal & non-metal Use prefixes
REVIEW FOR TEST - NOMENCLATURE
3. Acids Binary Acids Acids with Polyatomic Ions
Hydrogen in front of elements Oxidation #s must add to zero (criss cross)
4. NAMING COMPOUNDS Hint … identify the first element… if it is…
METAL – know it is an IONIC COMPOUND (think oxidation# & criss cross)
NON-METAL – know it is a MOLECULAR COMPOUND ( think prefixes)
HYDROGEN – know it is an ACID (think oxidation# & criss cross… or ate/ic & ite/ous)