Safety Data Sheet - Degafloor · Safety Data Sheet in accordance with regulation (EC) 1907/2006 Status: 10.11.2010 Version: 6.3 VISIOMER® MMA Page 3 of 33 SDB Version: 6.3 System:

Safety Data Sheet in accordance with regulation (EC) 1907/2006

Status: 10.11.2010 Version: 6.3 VISIOMER® MMA Page 1 of 33

SDB Version: 6.3 System: R11/011 GB 07.12.2010 13:53 VA-Nr

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier

VISIOMER® MMA

Substance name: methyl methacrylate

CAS-No.: 80-62-6

CLP-No.: -

REACH-No.: 01-2119452498-28-0000

EINECS-No.: 201-297-1

1.2.

Relevant identified uses of the substance or mixture and uses advised against

Mining, (without offshore industries), Industrial uses: Uses of substances as such or in preparations at industrial sites, Manufacture of pulp, paper and paper products, Manufacture of fine chemicals, Formulation [mixing] of preparations and/or re-packaging (excluding alloys), Manufacture of plastics products, including compounding and conversion, Manufacture of other non-metallic mineral products, e.g. plasters, cement, Manufacture of basic metals, including alloys, Manufacture of fabricated metal products, except machinery and equipment, Manufacture of computer, electronic and optical products, electrical equipment, General manufacturing, e.g. machinery, equipment, vehicles, other transport equipment, Health services, Professional uses: Public domain (administration, education, entertainment, services, craftsmen), Electricity, steam, gas water supply and sewage treatment

Recommended restriction(s) for use: preparations for nail extensions

1.3. Details of the supplier of the safety data sheet

Evonik Röhm GmbH 64275 Darmstadt Germany +49 6151 18 01 E-Mail: [email protected] Information provided by +49 6151 18 40 76 Emergency Number +49 6151 18 43 42

2. HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

This substance is classified as hazardous according to GHS Regulation (EC) No 1272/2008

Flammable liquids Hazard category 2 H225

Caustic burning / irritation of skin Hazard category 2 H315

Sensitization of the skin Hazard category 1 B H317

Specific Target Organ Toxicity - Single exposure (inhalation)

Hazard category 3 H335




2.2. Label elements

Regulation (EC) No 1272/2008

Signal word Danger

GHS pictogram (e)

hazard statement (e) Highly flammable liquid and vapour. (H225) Causes skin irritation. (H315) May cause an allergic skin reaction. (H317) May cause respiratory irritation. (H335)

Precautionary Statement (Prevention) Keep away from heat/sparks/open flames/hot surfaces. No smoking. (P210) Avoid breathing dust/fume/gas/mist/vapours/spray. (P261) Wear protective gloves/protective clothing/eye protection/face protection. (P280)

Precautionary Statement (Response) IF ON SKIN: Wash with plenty of soap and water. (P302 + P352)

Precautionary Statement (Disposal) Dispose of contents/container in accordance with local regulation. (P501)

Further Information Nota D

Hazardous component(s) for labelling

contains methyl methacrylate

Directive 67/548/EC or Directive 1999/45/EC

Labelling in accordance with EC directives

requires labelling

Hazardous component(s) for labelling

contains methyl methacrylate

hazard symbol(s) F Highly flammable Xi Irritant

R-phrase(s) 11 Highly flammable. 37/38 Irritating to respiratory system and skin. 43 May cause sensitisation by skin contact.

S-phrase(s) 24 Avoid contact with skin. 37 Wear suitable gloves. 46 If swallowed, seek medical advice immediately and show this

container or label.

2.3. Other hazards

Polymerization with heat evolution may occur in the presence of radical forming substances (e.g. peroxides), reducing substances, and/or heavy metal ions.




3. COMPOSITION/INFORMATION ON INGREDIENTS

3.1. Substances

Regulation (EC) No 1272/2008

Component EINECS-No. REACH-No. CAS-No.

Content Hazard class / Hazard category / Hazard statement

methyl methacrylate

201-297-1 01-2119452498-28

80-62-6

> 99.9 %

Flam. Liq. 2; H225 Skin Irrit. 2; H315 Skin Sens. 1; H317 STOT SE 3 (inhalation); H335

Directive 67/548/EC or Directive 1999/45/EC

Component

CAS Number

Hazard symbol(s) / R-phrase(s)

Content

methyl methacrylate 80-62-6 F, Xi 11-37/38-43 > 99.9 %

3.2. Mixtures

---

4. FIRST AID MEASURES

4.1. Description of first aid measures

General advice Remove soiled, soaked clothing immediately. Medical treatment is necessary if symptoms occur which are obviously caused by skin or eye contact with the product or by inhalation of its vapours.

Inhalation Move subject to fresh air and keep him calm. See a physician.

Skin contact Wash off immediately with soap and water. If skin irritation occurs consult a physician.

Eye contact Keeping the eyelids apart flush thoroughly with water immediately. If irritation persists, contact a physician.

Ingestion Do not induce vomiting. Contact a doctor immediately.

4.2. Most important symptoms and effects, both acute and delayed

headache, confusion, Causes skin and eye irritation., Skin Sensitisation

4.3. Indication of any immediate medical attention and special treatment needed

no

5. FIRE-FIGHTING MEASURES

5.1. Extinguishing media

Suitable extinguishing media foam, dry chemical, carbon dioxide

Extinguishing media which must not be used for safety reasons

water

5.2. Special hazards arising from the substance or mixture

no

5.3. Advice for firefighters

Wear self-contained breathing apparatus.




6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

Take care for adequate ventilation. Use personal protective clothing. Keep away sources of ignition. Use breathing apparatus if exposed to vapours/dust/mist/aerosol.

6.2. Environmental precautions

Prevent product from getting into drains/surface water/groundwater.

6.3. Methods and material for containment and cleaning up

Larger quantities: Remove mechanically (by pumping). Use explosion-proof equipment! Smaller quantities and/or residues: Contain with absorbent material (e.g. sand, diatomaceous earth, acid absorbent, universal absorbent or sawdust). Dispose of in accordance with regulations.

6.4. Reference to other sections

For personal protection see section 8.

7. HANDLING AND STORAGE

7.1. Precautions for safe handling

Safe handling advice Keep container tightly closed. Ensure the area is well ventilated.

Advice on protection against fire and explosion

Keep away from sources of ignition --- No smoking. Take precautionary measures against static discharges. In the event of fire, cool the endangered containers with water. When heated above the flash point and/or during spraying (atomizing), ignitible mixtures may form in air. Use explosion-proof equipment only.

7.2. Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers

Keep only in the original container at a temperature not exceeding 30 °C. Protect from light. Fill the container by approximately 90 % only as oxygen (air) is required for stabilisation. With large storage containers make sure the oxygen (air) supply is sufficient to ensure stability. Can polymerize with intense heat release.

7.3. Specific end use(s)

no

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Components or products of decomposition according to point 10, with limit values related to the place of work which require monitoring

methyl methacrylate 80-62-6 WEL (long-term) 2009 208 mg/m3 50 ppm WEL (short-term) 2009 416 mg/m3 100 ppm Indicative occupational exposure limit value 2009/161/EC 2009

50 ppm

Indicative occupational exposure limit value 2009/161/EC (15 minutes) 2009

100 ppm

8.2. Exposure controls For monitoring procedures refer to for instance "Empfohlene Analysenverfahren für Arbeitsplatzmessungen", Schriftenreihe der Bundesanstalt für Arbeitsschutz and "NIOSH Manual of Analytical Methods", National Institute for Occupational Safety and Health




DNEL

Critical component Routes of exposure Workers Industry/trade

Note

methyl methacrylate Inhalation Long-term 210 mg/m3

methyl methacrylate dermal Long-term 74.3 mg/m3

methyl methacrylate Oral Long-term -

PNEC

Critical component Routes of exposure Workers Industry/trade

Note

methyl methacrylate water Long-term 0.94 mg/l

methyl methacrylate Soil Long-term -

methyl methacrylate Air Long-term -

Protective measures Do not inhale vapours. Avoid contact with eyes and skin.

Hygiene measures Store work clothing separately. Remove soiled or soaked clothing immediately. Follow the usual good standards of occupational hygiene. Clean skin thoroughly after work; apply skin cream.

Respiratory protection Breathing apparatus in case of high concentrations, short term: filter appliance, filter A

Hand protection butyl rubber gloves (0.7 mm), Break through time 60 min (EN 374) In practice, due to variable exposure conditions, this information can only be an aid to orientation for the selection of a suitable chemical protection glove. In particular, this information does not substitute suitability tests by the end user.

General information Gloves should be replaced regularly, especially after extended contact with the product. For each work-place a suitable glove type has to be selected.

Eye protection tightly fitting goggles

Skin and body protection On handling of larger quantities: face mask, chemical-resistant boots and apron

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Form liquid Colour colourless Odour ester-like

Melting temperature -48.2 °C

Boiling Temperature 100.3 °C (1,013 hPa)

Flash point 10 °C (DIN 51755)

Ignition temperature 430 °C (DIN 51794)

Lower explosion limit 2.1 %(V) at 10,5°C

Upper explosion limit 12.5 %(V)

Vapour pressure 38.7 hPa (20 °C)

Density 0.94 g/cm3 (20 °C)

Relative vapour density (related to air)

> 1 (20 °C)

Solubility in water 15.9 g/l (20 °C)

Solubility (qualitative) miscible with most organic solvents

pH not applicable

n-Octanol/water partition coefficient log Pow 1.38, (measured)

Viscosity (dynamic) 0.63 mPa.s (20 °C), (Brookfield)

9.2. Other information




none

10. STABILITY AND REACTIVITY

10.1. Reactivity

see section 10.2 10.2. Chemical Stability

No decomposition when used as directed.

10.3. Possibility of hazardous reactions

Polymerization with heat evolution may occur in the presence of radical forming substances (e.g. peroxides), reducing substances, and/or heavy metal ions.

10.4. Conditions to avoid

The product is normally supplied in a stabilized form. If the permissible storage period and/or storage temperature is exceeded, the product may polymerize with heat evolution.

10.5. Incompatible materials

Free radical initiators. Reducing agents. Tertiary amines. Heavy metals. peroxides oxidizing agents Mineral acids.

10.6. Hazardous decomposition products

None when used as directed.

11. TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

toxicokinetics, metabolism and distribution

The substance is rapidly metabolized

Acute Oral Toxicity LD50 rat, OECD 401 > 5,000 mg/kg

Acute Inhalational Toxicity LC50 rat 29.8 mg/l

Acute Dermal Toxicity LD50 rabbit > 5,000 mg/kg

Caustic burning / irritation of skin rabbit, not irritating - slightly irritating

If contact with skin is prolonged and/or frequent, irritations cannot be excluded. Skin irritant Category 2 (UN-GHS)

Serious eye damage/eye irritation rabbit, not irritating - slightly irritating

Respiratory/skin sensitization mouse, LLNA (Local Lymph Node Assay), (own study) sensitising

man, In humans various types of allergic reactions have been observed (symptoms: headache, eye irritations, skin affections).

Skin Sensitisation Category 1B (UN-GHS)




Aspiration hazard no evidence for hazardous properties (structure-activity-relationships)

Germ cell mutagenicity Positive as well as negative results in in vitro mutagenicity/ genotoxicity tests. No experimental indication of genotoxicity in vivo available. In summary not mutagenic according to internationally accepted criteria.

Carcinogenicity Non-carcinogenic in inhalation and feeding studies carried out on rats, mice and dogs.

Reprotoxicity / teratogenicity No indications of toxic effects were observed in reproduction studies in animals. non-teratogenic, not embryotoxic

Reprotoxicity / fertility No indications of teratogenic effects in experimental animals.

Human health hazard assessment CMR: no

Specific Target Organ Toxicity - Single exposure

respiratory tract, (irritation)

Specific target organ toxicity – single exposure Category 3 (UN-GHS)

Specific Target Organ Toxicity - Repeated exposure

no evidence for hazardous properties

rat, inhalation, 2 a, 25 - 400 ppm Findings: Damage to mucous membranes in the nose at 400 ppm

NOAEL

25 ppm

rat, in drinking water, 2 a, 6 - 2000 ppm Findings: no toxic effects

NOAEL 2000 ppm

General information Avoid contact with the skin and eyes and inhalation of the product vapours.

12. ECOLOGICAL INFORMATION

12.1. Toxicity

Hazardous to the aquatic environment

Acute aquatic toxicity category 3 (UN-GHS)

Aquatoxicity, fish LC50 Oncorhynchus mykiss, OECD 203, 96 h > 79 mg/l

NOEC Danio rerio, OECD 210, fish early life stage test (own study)

9.4 mg/l

Aquatoxicity, invertebrates EC50 Daphnia magna, OECD 202, 48 h 69 mg/l

NOEC Daphnia magna, OECD 202 part 2, flow through, 21 d 37 mg/l

Aquatoxicity, algae / aquatic plants EC50 Selenastrum capricornutum, OECD 201, 72 h > 110 mg/l

Toxicity in microorganisms EC3 Pseudomonas putida, 16 h 100 mg/l

12.2. Persistence and degradability

Persistence and degradability no evidence for hazardous properties

Biodegradability readily degradable, OECD 301 C, 14 d 94 %

12.3. Bioaccumulative potential

Bioaccumulation no evidence for hazardous properties

12.4. Mobility in soil

Mobility no evidence for hazardous properties

12.5. Results of PBT and vPvB assessment

PBT and vPvB assessment PBT: no vPvB: no




12.6. Other adverse effects

General Information Do not allow to enter soil, waterways or waste water.

13. DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Product Waste is hazardous. It must be disposed of in accordance with the regulations after consultation of the competent local authorities and the disposal company in a suitable and licensed facility.

Uncleaned packaging Contaminated packaging should be emptied optimally and after appropriate professional cleansing may be taken for reuse. Packaging that cannot be cleaned should be disposed of professionally. Uncontaminated packaging may be taken for recycling.

Code of waste EWC 07 02 08 waste from the manufacture, formulation, supply and use (MFSU) of plastics, synthetic rubber and man-made fibres - other still bottoms and reaction residues

Always check the given waste codes according to the actual conditions of manufacturing, formulation or use in your facilities.

14. TRANSPORT INFORMATION

14.1. UN number

see section 14.2

14.2. UN proper shipping name

Land transport ADR/GGVSEB UN 1247 METHYL METHACRYLATE MONOMER, STABILIZED, 3, II, (D/E) Hazard no. 339

Land transport RID/GGVSEB UN 1247 METHYL METHACRYLATE MONOMER, STABILIZED, 3, II Hazard no. 339

Inland waterway transport ADNR/GGVSEB (Germany)

UN 1247 METHYL METHACRYLATE MONOMER, STABILIZED, 3, II

Shipment by sea IMDG/GGVSee

UN number 1247 Class 3 EmS F-E, S-D Marine pollutant No Packaging group II Proper Shipping Name METHYL METHACRYLATE MONOMER, STABILIZED

Air transport ICAO/IATA UN number 1247 Class 3 Packaging group II Proper Shipping Name METHYL METHACRYLATE MONOMER, STABILIZED




14.3. Transport hazard class(es)

see section 14.2

14.4. Packing group

see section 14.2

14.5. Environmental hazards

if not mentioned in Point 14.2 then it does not apply

14.6. Special precautions for user

see section 14.2

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

for transportapproval see regulatory information

15. REGULATORY INFORMATION

15.1.

Safety, health and environmental regulations/legislation specific for the substance or mixture

National legislation

Occupational restrictions Note for juveniles. Note for pregnant woman and nursing mothers (EC Directive 92/85/EEC).

Status of Registration REACH (EU) registered TSCA (USA) listed or exempted DSL (CDN) listed or exempted AICS (AUS) listed or exempted METI (J) listed or exempted ECL (KOR) listed or exempted PICCS (RP) listed or exempted IECSC (CN) listed or exempted HSNO (NZ) listed or exempted HSR001195

16. OTHER INFORMATION

Other information The product is normally supplied in a stabilized form. If the permissible storage period and/or storage temperature is exceeded, the product may polymerize with heat evolution.

Relevant H phrases from chapter 3 methyl methacrylate H225 Highly flammable liquid and vapour. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation.

R-phrases of relevance from chapter 3

11 Highly flammable. 37/38 Irritating to respiratory system and skin. 43 May cause sensitisation by skin contact.




References relevant manuals and publications own examinations own toxicological and ecotoxicological studies toxicological and ecotoxicological studies of other manufacturers SIAR OECD-SIDS RTK public files

Places marked by || have been amended from the last version.

This information and all further technical advice is based on our present knowledge and experience. However, it implies no liability or other legal responsibility on our part, including with regard to existing third party intellectual property rights, especially patent rights. In particular, no warranty, whether express or implied, or guarantee of product properties in the legal sense is intended or implied. We reserve the right to make any changes according to technological progress or further developments. The customer is not released from the obligation to conduct careful inspection and testing of incoming goods. Performance of the product described herein should be verified by testing, which should be carried out only by qualified experts in the sole responsibility of a customer. Reference to trade names used by other companies is neither a recommendation, nor does it imply that similar products could not be used.

Date of printing : 01.12.2010




Exposure assessment

For each level of control measure (indoor, outdoor, engineering control and contained) three categories of protection (no personal protection equipment - No PPE, Gloves - Respiratory protection equipment and Gloves - RPE + Gloves) exist. All applications with a defined level of protection and containment are summarised in one specific GES (generic exposure szenario). Within this specific GES for all applications the boundary conditions regarding time and concentration are to be defined and can vary from substance to substance, due to the level of estimated exposure and the individual DNEL/PNEC of a substance. For example, if an application fails the assessment in GES10 (indoor) with low level of control and without using protection equipment, safe use can be achieved by increasing level of control (local exhaust ventilation LEV, GES4) or level of protection (RPE and gloves, GES12). The matrix of identification of generic exposure scenarios by definition of control measure and level of protective equipment is given in table I. The matrix of the exposure scenarios should be applicable for all methacrylates.

Table I: Overview of exposure scenarios matrix

Protection Equipment GES

Matrix RPE + Gloves

Gloves No PPE

Co

nta

ined

GES3 GES2 GES1

En

gin

eeri

ng

Co

ntr

ol

GES6 GES5 GES4

Ou

tdo

or

GES9 GES8 GES7

Co

ntr

ol M

easu

re

Ind

oo

r

GES12 GES11 GES10




GES1

Short title 1

Use in closed systems with limited opportunity for exposure Description of activities/process(es) covered in the Exposure Scenario Industrial or professional activities involving the production or use within controlled batch or continuous processes. Includes: IU1: Manufacture and use as intermediate, IU2: Use in production of formulations, IU3: Industrial end use as monomer, intermediate or formulation, IU4: Professional end use in formulations. SU3: Industrial Manufacturing (all). SU2a: Mining, (without offshore industries). SU2b: Offshore industries. SU6a: Manufacture of wood and wood products. SU6b: Manufacture of pulp, paper and paper products. SU8: Manufacture of bulk, large scale chemicals (including petroleum products). SU9: Manufacture of fine chemicals. SU10: Chemical formulation and packaging. SU12: Manufacture of plastic products, including compounding and conversion. SU13: Manufacture of other non-metallic mineral products. SU14: Manufacture of basic metals. SU15: Manufacture of fabricated metal products, except machinery and equipment. SU16: Manufacture of computer, electronic and optical products, electrical equipment. SU17: General manufacturing. SU19: Building and construction work. SU23: Recycling. SU20: Health services. SU22: Public domain. PROC1: Use in closed process, no likelihood of exposure. PROC2: Use in closed, continuous process with occasional controlled exposure. PROC3: Use in closed batch process (synthesis or formulation).

2

ERC1: Manufacture of substances. ERC2: Formulation of preparations. ERC3: Formulation in materials. ERC4: Industrial use of processing aids in processes and products, not becoming part of articles. ERC5: Industrial use resulting in inclusion into or onto a matrix. ERC6a: Industrial use resulting in manufacture of another substance (use of intermediates). ERC6b: Industrial use of reactive processing aids. ERC6c: Industrial use of monomers for polymerisation. ERC6d: Industrial use of auxiliaries for polymerisation processes in production of resins, rubbers, polymers. ERC7: Industrial use of substances in closed systems. ERC8a: Wide dispersive indoor use of processing aids in open systems. ERC8b: Wide dispersive indoor use of reactive substances in open systems. ERC8c: Wide dispersive indoor use resulting in inclusion into or onto a matrix. ERC8d: Wide dispersive outdoor use of processing aids in open systems. ERC8e: Wide dispersive outdoor use of reactive substances in open systems. ERC8f: Wide dispersive outdoor use resulting in inclusion into or onto a matrix.

3 Operational conditions Duration and frequency of use

Duration Worker: dependent upon concentration and activity, see section 4.3. Consumer: N/A.

Frequency of exposure at workplace Worker: daily; Consumer: N/A

3.1

Emission days per site 300 d/yr

4 Other operational conditions related to physical properties and boundary conditions 4.1 Physical form of product in which substance is

contained Liquid

4.2 Concentration of substance in preparation or article

≤100%

Maximum used amount of substance (as such or in preparation) per worker/workplace per day

Worker: N/A, closed systems; Consumer: N/A.

Amount used per time or per activity for which RMMs ensure control of risk

RMM: No RMMs identified. OC: Industrial PROC: 1, 2, 3; Professional PROC: 2, 3; Concentration/Duration: 0-100% 0-24hrs. Operational conditions related to environment High tonnage material produced in contained systems.

4.3

Annual amount used per site ≤260 kte/yr

Other operational conditions determining exposure Room size N/A

Ventilation rate N/A

5

Waste water treatment Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.

6 Risk Management Measures: 6.1 Human health measures

Occupational related measures

Oral No eating, drinking or smoking in workplace.

Dermal Wear gloves (butyl; 0.7 mm; EN 374) for splash protection and comply with good occupational hygiene practice. Change gloves, if duration of activity exceeds break through time.

6.1.1

Inhalation N/A

6.1.2 Consumer related measures N/A - Industrial scenario. Environment related measures

Air

Water

6.2

Soil

Use appropriate containment to avoid environmental contamination. Ensure proper process control to avoid excess waste discharge (temperature, concentration, pH value, time).

Waste related measures 7 Obtain the consent of pollution control authorities before discharging to waste water treatment plants.




cont. GES1

8 Prediction of exposure resulting from the conditions described above 8.1 Human exposure estimation

Worker. Predicted exposure and Risk Characterisation Ratio based on DNEL and exposure calculated by ECETOC-TRA. 8.1.1

Dermal Concentration ≤1.37 mg/kg bw/day RCR ≤ 0.10 Inhalative Concentration ≤ 25 ppm RCR ≤ 0.50 Combined RCR ≤ 0.53

Consumer 8.1.2 N/A – Industrial/professional scenario.

8.2 Environmental exposure estimation

Environmental. Risk Characterisation Ratio based on PNEC and PEC calculated by EUSES local compartments. 8.2.1

Air Concentration ≤ 1.92 mg/m3 RCR ≤ 2.6e-02

Aquatic Concentration ≤ 7.1e-02 mg/ml RCR ≤ 9.2e-02 Aquatic Sediment Concentration ≤ 1.7e-01 mg/kg ww RCR ≤ 9.2e-02 Soil Concentration ≤ 1.49 mg/kg ww RCR ≤ 2.3e-02

Other information 9 Risk adequately controlled. Gloves required for splash protection when handling liquids. Change gloves, if duration of activity exceeds break through time. Measured data could be used to confirm exposure levels are within the boundaries of the exposure scenario. Use the exposure assessment tools ECETOC-TRA and EUSES for confirmation that you work inside to boundaries set by the GES (RCR<1 and PEC/PNEC<1).




GES4

Short title 1

Use in systems with engineering control with limited opportunity for exposure Description of activities/process(es) covered in the Exposure Scenario Industrial or professional activities involving the handling of preparations containing monomers. Includes: IU1: Manufacture and use as intermediate. IU2: Use in production of formulations. IU3: Industrial end use as monomer, intermediate or formulation. IU4: Professional end use in formulations. SU3: Industrial Manufacturing (all). SU2a: Mining, (without offshore industries). SU2b: Offshore industries. SU6a: Manufacture of wood and wood products. SU6b: Manufacture of pulp, paper and paper products. SU8: Manufacture of bulk, large scale chemicals (including petroleum products). SU9: Manufacture of fine chemicals. SU10: Chemical formulation and packaging. SU12: Manufacture of plastic products, including compounding and conversion. SU13: Manufacture of other non-metallic mineral products. SU14: Manufacture of basic metals. SU15: Manufacture of fabricated metal products, except machinery and equipment. SU16: Manufacture of computer, electronic and optical products, electrical equipment. SU17: General manufacturing. SU19: Building and construction work. SU20: Health services. SU23: Recycling. SU22: Public domain. PROC4: Use in batch and other process (synthesis) where opportunity for exposure arises. PROC8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities. PROC9: Transfer of substance or preparation into small containers (dedicated filling line, including weighing). PROC12: Use of blow agents in manufacture of foam. PROC14: Production of preparations or articles by tabletting, compression, extrusion, pelletisation. PROC15: Use as laboratory reagent.

2




Frequency of exposure at workplace Daily

3.1



contained Liquid


≤100%


Industrial/Professional: <1000 kg/d; Consumer: N/A See below for detail individual PROCs.


RMM: Engineering control (LEV) required. Butyl gloves (0.7 mm; EN 374) for splash protection. Industrial PROC: 4, 8b, 9, 12, 14, 15; Professional PROC: 4, 8b, 9, 12, 14, 15; Concentration/Duration: 0-100% / 0-8hrs. Operational conditions related to environment Processing and handling with engineering control, indoor and outdoor.

4.3


Other operational conditions determining exposure Room size N/A. Ventilation rate ≥ 90% ECETOC default for industrial worker; ≥ 80% ECETOC default for

professional worker (for details see ECETOC default table).

5




Oral No eating, drinking or smoking in workplace. Dermal Wear gloves (butyl; 0.7 mm; EN 374) for splash protection when handling liquids

and comply with good occupational hygiene practice. Change gloves, if duration of activity exceeds break through time.

6.1.1

Inhalation Use local exhaust ventilation (LEV) or engineering equipment implying comparable efficiency.

6.1.2 Consumer related measures None required.

Environment related measures Air

Water

6.2

Soil


7 Waste related measures




Obtain the consent of pollution control authorities before discharging to waste water treatment plants.

cont. GES4


Worker. Predicted exposure and Risk Characterisation Ratio based on DNEL and exposure calculated by ECETOC-TRA 8.1.1 Dermal Concentration ≤ 6.86 mg/kg bw/day RCR ≤ 0.50 Inhalative Concentration ≤ 20 ppm RCR ≤ 0.40 Combined RCR ≤ 0.90 Consumer 8.1.2

N/A – Industrial/professional scenario.


Environmental. Risk Characterisation Ratio based on PNEC and PEC calculated by EUSUS local compartments 8.2.1 Air Concentration ≤ 1.92 mg/m

3 RCR ≤ 2.6e-02

Aquatic Concentration ≤ 7.1e-02mg/ml RCR ≤ 9.2e-02 Aquatic Sediment Concentration ≤ 1.7e-01mg/kg ww RCR ≤ 9.2e-02 Soil Concentration ≤ 1.49 mg/kg ww RCR ≤ 2.3e-02

9 Other information

Risk adequately controlled. Gloves required for splash protection when handling liquids. Change gloves, if duration of activity exceeds break through time. Measured data could be used to confirm exposure levels are within the boundaries of the exposure scenario. Use the exposure assessment tools ECETOC-TRA and EUSES for confirmation that you work inside to boundaries set by the GES (RCR<1 and PEC/PNEC<1)




GES5

Short title 1

Use in systems with engineering control where opportunity for exposure requires use of gloves Description of activities/process(es) covered in the Exposure Scenario Industrial or professional activities involving the handling of preparations containing monomers. Includes: IU1: Manufacture and use as intermediate. IU2: Use in production of formulations. IU3: Industrial end use as monomer, intermediate or formulation. IU4: Professional end use in formulations. SU3: Industrial Manufacturing (all). SU2a: Mining, (without offshore industries). SU2b: Offshore industries. SU6a: Manufacture of wood and wood products. SU6b: Manufacture of pulp, paper and paper products. SU8: Manufacture of bulk, large scale chemicals (including petroleum products). SU9: Manufacture of fine chemicals. SU10: Chemical formulation and packaging. SU12: Manufacture of plastic products, including compounding and conversion. SU13: Manufacture of other non-metallic mineral products. SU14: Manufacture of basic metals. SU15: Manufacture of fabricated metal products, except machinery and equipment. SU16: Manufacture of computer, electronic and optical products, electrical equipment. SU17: General manufacturing. SU19: Building and construction work. SU20: Health services. SU23: Recycling. SU22: Public domain. PROC5: Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact). PROC6: Calendaring operations. PROC7: Industrial spraying. PROC8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non dedicated facilities. PROC10: Roller application or brushing. PROC11: Non industrial spraying. PROC13: Treatment of articles by dipping and pouring. PROC17: Lubrication at high energy conditions and in partly open process. PROC18: Greasing at high energy conditions. PROC19: Hand-mixing with intimate contact and only PPE available.

2





3.1



contained Liquid


≤100%


Worker: <1000 kg/d; Consumer: N/A. See below for detail individual PROCs.

Amount used per time or per activity for which RMMs ensure control of risk RMM : Engineering control (LEV) required. Butyl gloves (0.7 mm; EN 374) for immersion protection. Industrial PROC: 5, 6, 7, 8a, 10, 13, 17, 18, 19; Professional PROC: 5, 6, 8a, 10, 13, 17, 18, 19; Concentration/Duration: 0-100% / 0-8hrs. RMM : Engineering control (LEV) required. Butyl gloves (0.7 mm; EN 374) for immersion protection. Professional PROC: 11; Concentration/Duration: 0-5% / 0-8hrs, 5-100% / 0-1hr. Operational conditions related to environment Processing and handling with engineering control, indoor and outdoor.

4.3


Other operational conditions determining exposure Room size N/A.

Ventilation rate ≥ 90% ECETOC default for industrial worker; ≥ 80% ECETOC default for professional worker (for details see ECETOC default table).

5





Dermal Wear gloves (butyl; 0.7 mm; EN 374) for immersion protection when handling liquids and comply with good occupational hygiene practice. Change gloves, if duration of activity exceeds break through time.

6.1.1

Inhalation Use local exhaust ventilation (LEV) or engineering equipment implying comparable efficiency.

6.1.2 Consumer related measures N/A – Industrial / Professional Scenario.

Environment related measures

Air

6.2

Water

Use appropriate containment to avoid environmental contamination. Ensure proper process control to avoid excess waste discharge (temperature,




Soil concentration, pH value, time).

cont. GES5




Dermal Concentration ≤ 14.1 mg/kg bw/day RCR ≤ 1.03 (see section 9) Inhalative Concentration ≤ 25 ppm RCR ≤ 0.50 Combined RCR ≤ 1.28 (see section 9)

Consumer 8.1.2

N/A – Industrial / Professional Scenario.

8.2 Environmental exposure estimation Environmental. Risk Characterisation Ratio based on PNEC and PEC calculated by EUSUS local compartments 8.2.1



9 Other information

Risk adequately controlled. Gloves required for immersion protection when handling liquids. Change gloves, if duration of activity exceeds break through time. Then safe handling of high exposure dermal applications (PROC11, 19) is ensured and RCR (dermal) is assumed to be below 0.5. All other PROCs indicate a dermal RCR below 0.5 within the assessed boundaries. Measured data could be used to confirm exposure levels are within the boundaries of the exposure scenario. Use the exposure assessment tools ECETOC-TRA and EUSES for confirmation that you work inside to boundaries set by the GES (RCR<1 and PEC/PNEC<1)




GES6

Short title 1

Use in systems with engineering control where opportunity for exposure requires use of gloves and respiratory protection Description of activities/process(es) covered in the Exposure Scenario Industrial or professional activities involving the handling of preparations containing monomers. Includes: IU4: Professional end use in formulations. SU22: Public domain. PROC11: Non industrial spraying

2

ERC8c: Wide dispersive indoor use resulting in inclusion into or onto a matrix. ERC8f: Wide dispersive outdoor use resulting in inclusion into or onto a matrix.




3.1



contained Liquid


≤100%


Worker: <100 kg/d; Consumer: N/A. See below for detail individual PROCs.


RMM: Engineering control (LEV) required. Butyl gloves (0.7 mm; EN 374) for immersion protection. RPE protection factor 10 (see section 9). Professional PROC: 11; Concentration/Duration: 0-100% / 0-8hrs. Operational conditions related to environment Processing and handling with engineering control, indoor and outdoor.

4.3

Annual amount used per site (relevance for regional scenario)

≤2.2 kte/yr

Other operational conditions determining exposure Room size N/A.

Ventilation rate 80% ECETOC default for professional worker.

5



Occupational related measures Oral No eating, drinking or smoking in workplace.


6.1.1

Inhalation Use local exhaust ventilation (LEV) or engineering equipment implying comparable efficiency. RPE protection factor 10.

6.1.2 Consumer related measures N/A – Industrial / Professional Scenario. Environment related measures

Air

Water

6.2

Soil






cont. GES6



Dermal Concentration ≤ 10.7 mg/kg bw/day RCR ≤ 0.78 (see section 9) Inhalative Concentration ≤ 10 ppm RCR ≤ 0.20 Combined RCR ≤ 0.98

Consumer 8.1.2



Environmental. Risk Characterisation Ratio based on PNEC and PEC calculated by EUSUS local compartments 8.2.1

Air Concentration ≤ 2.1e-04 mg/m3 RCR ≤ 2.8e-06

Aquatic Concentration ≤ 4.1e-14 mg/ml RCR ≤ 4.3e-14 Aquatic Sediment Concentration ≤ 7.9e-14 mg/kg ww RCR ≤ 4.3e-14 Soil Concentration ≤ 1.3e-06 mg/kg ww RCR ≤ 1.9e-09

9 Other information

Risk adequately controlled. Gloves required for immersion protection when handling liquids. Change gloves, if duration of activity exceeds break through time. Then safe handling of high exposure dermal applications (PROC11) is ensured and RCR(dermal) is assumed to be below 0.5. Ensure duration of wearing respiratory protection comply with the requirements of legislation. Measured data could be used to confirm exposure levels are within the boundaries of the exposure scenario. Use the exposure assessment tools ECETOC-TRA and EUSES for confirmation that you work inside to boundaries set by the GES (RCR<1 and PEC/PNEC<1)




GES7

Short title 1

Outdoor use with limited opportunity for exposure Description of activities/process(es) covered in the Exposure Scenario Industrial or professional activities involving the handling of preparations containing monomers. Consumer use with limited exposure of monomers. Includes: IU1: Manufacture and use as intermediate. IU2: Use in production of formulations. IU3: Industrial end use as monomer, intermediate or formulation. IU4: Professional end use in formulations. IU5: Consumer end use in formulations. IU6: Service life in articles. SU3: Industrial Manufacturing (all). SU2a: Mining, (without offshore industries). SU2b: Offshore industries. SU6a: Manufacture of wood and wood products. SU6b: Manufacture of pulp, paper and paper products. SU8: Manufacture of bulk, large scale chemicals (including petroleum products). SU9: Manufacture of fine chemicals. SU10: Chemical formulation and packaging. SU12: Manufacture of plastic products, including compounding and conversion. SU13: Manufacture of other non-metallic mineral products. SU14: Manufacture of basic metals. SU15: Manufacture of fabricated metal products, except machinery and equipment. SU16: Manufacture of computer, electronic and optical products, electrical equipment. SU17: General manufacturing. SU19: Building and construction work. SU20: Health services. SU23: Recycling. SU22: Public domain. SU21: Consumer uses. PROC4: Use in batch and other process (synthesis) where opportunity for exposure arises. PROC8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities. PROC9: Transfer of substance or preparation into small containers (dedicated filling line, including weighing). PROC12: Use of blow agents in manufacture of foam. PROC14: Production of preparations or articles by tabletting, compression, extrusion, pelletisation. PROC21: Low energy manipulation of substances bound in form of massive metal or bound in other materials and/or articles. PROC22: Potentially closed processing operations with minerals/metals at elevated temperature. Industrial setting. PROC23: Open processing and transfer operations with minerals/metals at elevated temperature. PROC24: High (mechanical) energy workup of massive metal or substances bound in materials and/or articles. PC1: Adhesives, sealants. PC2: Adsorbents. PC3: Air care products. PC7: Base metals and alloys. PC8: Biocidal Products (e.g. Disinfectants, pest control). PC9a: Coatings and paints, thinners, paint removers. PC9b: Fillers and putty. PC9c: Finger paints. PC14: Metal surface treatment products, including galvanic and electroplating products. PC15: Non-metal-surface treatment products. PC18: Ink and Toners. PC19: Intermediate. PC21: Laboratory Chemicals. PC20: Products such as ph-regulators, flocculants, precipitants, neutralisation agents, other unspecific uses. PC23: Leather tanning, dye, finishing, impregnation and care products. PC24: Lubricants, Greases and Release products. PC26: Paper and Board dye, finishing and impregnation products: including bleaches and other processing aids. PC31: Polishes and Wax Blends. PC32: Polymer Preparations and Compounds. PC33: Semiconductor. PC34: Textile dyes, finishing and impregnating products: including bleaches and other processing aids. PC35: Washing and Cleaning Products (including solvent based products). PC37: Water treatment chemicals. PC39: Cosmetics, personal care. AC1-1: Passenger cars and motor cycles. AC1-2: Other vehicles: Railway, aircraft, vessels, boats, trucks, and associated transport equipment. AC2: Machinery, mechanical appliances, electrical/electronic articles. AC3: Electrical batteries and accumulators. AC4: Stone, plaster, cement, glass and ceramic articles. AC5-1: Fabrics, textiles and apparel: bedding and clothing. AC5-2: Fabrics, textiles and apparel: curtains, upholstery, carpeting/flooring, rugs. AC6: Leather products: apparel and upholstery. AC7: Metal articles. AC8-1: Paper products: tissue, towels, disposable dinnerware, nappies, feminine hygiene products, adult incontinence products, writing paper. AC10-2: Rubber products: flooring. AC10-5: Other general rubber products. AC11: Wood articles. AC13-1: Commercial and consumer plastic products like disposable dinner ware, food storage, food packaging, baby bottles. AC13-2: Plastic products: Flooring. AC13-3: Plastic products: Toys. AC13*: Plastic, small articles.

2

ERC1: Manufacture of substances. ERC2: Formulation of preparations. ERC3: Formulation in materials. ERC4: Industrial use of processing aids in processes and products, not becoming part of articles. ERC5: Industrial use resulting in inclusion into or onto a matrix. ERC6a: Industrial use resulting in manufacture of another substance (use of intermediates). ERC6b: Industrial use of reactive processing aids. ERC6c: Industrial use of monomers for polymerisation. ERC6d: Industrial use of auxiliaries for polymerisation processes in production of resins, rubbers, polymers. ERC7: Industrial use of substances in closed systems. ERC8d: Wide dispersive outdoor use of processing aids in open systems. ERC8e: Wide dispersive outdoor use of reactive substances in open systems. ERC8f: Wide dispersive outdoor use resulting in inclusion into or onto a matrix. ERC10a: Wide dispersive outdoor use of long-life articles and materials with low release.


Duration Worker: dependent upon concentration and activity, see section 4.3. Consumer: dependent upon concentration and activity, see section 4.3.


3.1





cont. GES7


contained Liquid


≤100%


Industrial/Professional: <1000kg/d Consumer: 9g, duration up to 4 hrs (PC1); product ingredient up to 0.3 g/g product (PC1); defaults ECETOC. See below for detail individual PROCs, PCs.

Amount used per time or per activity for which RMMs ensure control of risk RMM: Butyl gloves (0.7 mm; EN 374) for splash protection. Industrial PROC : 4, 12 ; Concentration/Duration : 0-100% / 0-8hrs.

RMM: Butyl gloves (0.7 mm; EN 374) for splash protection. Industrial PROC : 8b, 9, 14 ; Professional PROC : 4, 8b ; Concentration/Duration : 0-25% / 0-8hrs, 25-100% / 0-4hrs. RMM: Butyl gloves (0.7 mm; EN 374) for splash protection. Professional PROC : 12, 14 ; Concentration/Duration : 0-5% / 0-8hrs, 5-25% / 0-4hrs, 25-100% / 0-1hr. RMM: Butyl gloves (0.7 mm; EN 374) for splash protection. Professional PROC : 9 ; Concentration/Duration : 0-5% / 0-8hrs, 5-100% / 0-1hr. RMM: No RMMs identified. No ECETOC model for volatiles available; solids application only; polymer demonstrated as save use. Industrial PROC: 21, 22, 23, 24; Professional PROC: 21, 23, 24; Concentration/Duration: 0-5% / 0-8hrs, 5-100% / Not covered. See section 9.

RMM: No RMMs identified. Consumer PC: 1; Concentration/Duration/Amount used: 0-70% / 0-8hrs / 21g; maximum for specific parameter using default values for other boundaries. See section 9.

RMM: No RMMs identified. Consumer PC: 1, 2, 3, 7, 8, 9a, 9b, 9c, 14, 15, 18, 19, 20, 21, 23, 24, 26, 31, 32, 33, 34, 35, 37, 39; Consumer AC: 1-1, 1-2, 2, 3, 4, 5-1, 5-2, 6, 7, 8-1, 10-2, 10-5, 11, 13-1, 13-2, 13-3, 13*; Concentration/Duration: 0-5% / 0-8hrs, 5-100% / Not covered. See section 9.

Operational conditions related to environment Outdoor processing and handling.

4.3


Other operational conditions determining exposure Room size N/A – Outdoor scenario. Ventilation rate 70% ECETOC default for outdoor worker.

5





Dermal Wear gloves (butyl; 0.7 mm; EN 374) for splash protection when handling liquids and comply with good occupational hygiene practice. Change gloves, if duration of activity exceeds break through time.

6.1.1

Inhalation Use outdoor. 6.1.2 Consumer related measures None required.


Air

Water

6.2

Soil






Cont. GES7


Worker. Predicted exposure and Risk Characterisation Ratio based on DNEL and exposure calculated by ECETOC-TRA 8.1.1

Dermal Concentration ≤ 6.86 mg/kg bw/day RCR ≤ 0.50 Inhalative Concentration ≤ 25 ppm RCR ≤ 0.50 Combined RCR ≤ 0.92

Consumer 8.1.2

Dermal Concentration ≤ 1.79 mg/kg bw/day RCR ≤ 0.22 Inhalative Concentration ≤ 6.75 mg/m

3 RCR ≤ 0.18

Combined RCR ≤ 0.40 8.2 Environmental exposure estimation




9 Other information

Risk adequately controlled. Gloves required for splash protection when handling liquids. Change gloves, if duration of activity exceeds break through time. Measured data could be used to confirm exposure levels are within the boundaries of the exposure scenario. Consumer scenarios predominantly polymer preparations. PC1 evaluated for higher residual monomer according to ECETOC standard defaults. For changing specific defaults of the model equation [0.5 ≥ RCR(dermal/inhalation) * (amount used / default ECETOC) * (duration / default ECETOC) * product ingredient / default ECETOC)] has to be satisfied. Other PCs and PROCS (polymer applications) evaluated as safe for up to 5% residual MMA related to used amount of MMA. Use the exposure assessment tools ECETOC-TRA and EUSES for confirmation that you work inside to boundaries set by the GES (RCR<1 and PEC/PNEC<1).




GES8

Short title 1

Outdoor use where opportunity for exposure requires use of gloves Description of activities/process(es) covered in the Exposure Scenario Industrial or professional activities involving the handling of preparations containing monomers. Includes: IU1: Manufacture and use as intermediate. IU2: Use in production of formulations. IU3: Industrial end use as monomer, intermediate or formulation. IU4: Professional end use in formulations. SU3: Industrial Manufacturing (all). SU2a: Mining, (without offshore industries). SU2b: Offshore industries. SU6a: Manufacture of wood and wood products. SU6b: Manufacture of pulp, paper and paper products. SU8: Manufacture of bulk, large scale chemicals (including petroleum products). SU9: Manufacture of fine chemicals. SU10: Chemical formulation and packaging. SU12: Manufacture of plastic products, including compounding and conversion. SU13: Manufacture of other non-metallic mineral products. SU14: Manufacture of basic metals. SU15: Manufacture of fabricated metal products, except machinery and equipment. SU16: Manufacture of computer, electronic and optical products, electrical equipment. SU17: General manufacturing. SU19: Building and construction work. SU20: Health services. SU23: Recycling. SU22: Public domain. PROC5: Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact). PROC6: Calendaring operations. PROC7: Industrial spraying. PROC8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non dedicated facilities. PROC10: Roller application or brushing. PROC11: Non industrial spraying. PROC13: Treatment of articles by dipping and pouring. PROC17: Lubrication at high energy conditions and in partly open process. PROC18: Greasing at high energy conditions. PROC19: Hand-mixing with intimate contact and only PPE available.

2

ERC1: Manufacture of substances. ERC2: Formulation of preparations. ERC3: Formulation in materials. ERC4: Industrial use of processing aids in processes and products, not becoming part of articles. ERC5: Industrial use resulting in inclusion into or onto a matrix. ERC6a: Industrial use resulting in manufacture of another substance (use of intermediates). ERC6b: Industrial use of reactive processing aids. ERC6c: Industrial use of monomers for polymerisation. ERC6d: Industrial use of auxiliaries for polymerisation processes in production of resins, rubbers, polymers. ERC7: Industrial use of substances in closed systems. ERC8d: Wide dispersive outdoor use of processing aids in open systems. ERC8e: Wide dispersive outdoor use of reactive substances in open systems. ERC8f: Wide dispersive outdoor use resulting in inclusion into or onto a matrix.

3 Operational conditions Duration and frequency of use Duration Worker: dependent upon concentration and activity, see section 4.3.

Consumer: N/A.


3.1



contained Liquid


≤100%


Worker: <1000kg/d Consumer: N/A. See below for detail individual PROCs.


RMM : Butyl gloves (0.7 mm; EN 374) for immersion protection. Industrial PROC : 5, 6, 8a, 10, 13, 17, 18, 19 ; Concentration/Duration : 0-25% / 0-8hrs, 25-100% / 0-4hrs.

RMM : Butyl gloves (0.7 mm; EN 374) for immersion protection. Professional PROC : 5, 6, 8a, 10, 13, 19 ; Concentration/Duration : 0-5% / 0-8hrs, 5-25% / 0-4hrs, 25-100% / 0-1hr. RMM : Butyl gloves for immersion protection. Professional PROC : 11 ; Concentration/Duration : 0-1% / 0-4hrs, 1-5% / 0-1hr, 5-25% / 0-15min, 25-100% / Not covered. RMM : Butyl gloves (0.7 mm; EN 374) for immersion protection. Industrial PROC : 7 ; Professional PROC : 17, 18 ; Concentration/Duration : 0-1% / 0-8hrs, 1-5% / 0-4hrs, 5-25% / 0-1hr, 25-100% / 0-15min. Operational conditions related to environment Outdoor processing and handling.

4.3


Other operational conditions determining exposure Room size N/A – Outdoor scenario.

Ventilation rate 70% ECETOC default for outdoor worker.

5





cont. GES8




6.1.1

Inhalation Use outdoor.


Environment related measures Air

Water

6.2

Soil






Consumer 8.1.2






9 Other information

Risk adequately controlled. Gloves required for immersion protection when handling liquids. Change gloves, if duration of activity exceeds break through time. Then safe handling of high exposure dermal applications (PROC11, 19) is ensured and RCR (dermal) is assumed to be below 0.5. All other PROCs indicate a dermal RCR below 0.5 within the assessed boundaries. Measured data could be used to confirm exposure levels are within the boundaries of the exposure scenario. Use the exposure assessment tools ECETOC-TRA and EUSES for confirmation that you work inside to boundaries set by the GES (RCR<1 and PEC/PNEC<1)




GES9

Short title 1

Outdoor use where opportunity for exposure requires use of gloves and respiratory protection Description of activities/process(es) covered in the Exposure Scenario Industrial or professional activities involving the handling of preparations containing monomers. Includes: IU1: Manufacture and use as intermediate. IU2: Use in production of formulations. IU3: Industrial end use as monomer, intermediate or formulation. IU4: Professional end use in formulations. SU3: Industrial Manufacturing (all). SU2a: Mining, (without offshore industries). SU2b: Offshore industries. SU6a: Manufacture of wood and wood products. SU6b: Manufacture of pulp, paper and paper products. SU8: Manufacture of bulk, large scale chemicals (including petroleum products). SU9: Manufacture of fine chemicals. SU10: Chemical formulation and packaging. SU12: Manufacture of plastic products, including compounding and conversion. SU13: Manufacture of other non-metallic mineral products. SU14: Manufacture of basic metals. SU15: Manufacture of fabricated metal products, except machinery and equipment. SU16: Manufacture of computer, electronic and optical products, electrical equipment. SU17: General manufacturing. SU19: Building and construction work. SU20: Health services. SU23: Recycling. SU22: Public domain. PROC4: Use in batch and other process (synthesis) where opportunity for exposure arises. PROC5: Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact). PROC6: Calendaring operations. PROC7: Industrial spraying. PROC8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non dedicated facilities. PROC8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities. PROC9: Transfer of substance or preparation into small containers (dedicated filling line, including weighing). PROC10: Roller application or brushing. PROC11: Non industrial spraying. PROC12: Use of blow agents in manufacture of foam. PROC13: Treatment of articles by dipping and pouring. PROC14: Production of preparations or articles by tabletting, compression, extrusion, pelletisation. PROC17: Lubrication at high energy conditions and in partly open process. PROC18: Greasing at high energy conditions. PROC19: Hand-mixing with intimate contact and only PPE available.

2

ERC1: Manufacture of substances. ERC2: Formulation of preparations. ERC3: Formulation in materials. ERC4: Industrial use of processing aids in processes and products, not becoming part of articles. ERC5: Industrial use resulting in inclusion into or onto a matrix. ERC6a: Industrial use resulting in manufacture of another substance (use of intermediates). ERC6b: Industrial use of reactive processing aids. ERC6c: Industrial use of monomers for polymerisation. ERC6d: Industrial use of auxiliaries for polymerisation processes in production of resins, rubbers, polymers. ERC7: Industrial use of substances in closed systems. ERC8d: Wide dispersive outdoor use of processing aids in open systems. ERC8e: Wide dispersive outdoor use of reactive substances in open systems. ERC8f: Wide dispersive outdoor use resulting in inclusion into or onto a matrix.




3.1



contained Liquid


≤100%



Amount used per time or per activity for which RMMs ensure control of risk RMM: Butyl gloves (0.7 mm; EN 374) for immersion protection. RPE protection factor 10 (see section 9). Industrial PROC: 5, 6, 7, 8a, 8b, 9, 10, 13, 14, 17, 18, 19; Professional PROC: 4, 5, 6, 8a, 8b, 9, 10, 12, 13, 14, 17, 18, 19; Concentration/Duration: 0-100% / 0-8hrs. RMM: Butyl gloves (0.7 mm; EN 374) for immersion protection. RPE protection factor 10 (see section 9). Professional PROC: 11; Concentration/Duration: 0-25% / 0-8hrs, 25-100% / 0-4hrs. RMM: Butyl gloves (0.7 mm; EN 374) for immersion protection. RPE protection factor 20 (see section 9). Above scenarios plus: Professional PROC: 11; Concentration/Duration: 0-100% / 0-8hrs. Operational conditions related to environment Outdoor processing and handling.

4.3


Other operational conditions determining exposure Room size N/A – Outdoor scenario. Ventilation rate 70% ECETOC default for outdoor worker.

5





cont. GES9



Oral No eating, drinking or smoking in workplace. Dermal Wear gloves (butyl; 0.7 mm; EN 374) for immersion protection when handling

liquids and comply with good occupational hygiene practice. Change gloves, if duration of activity exceeds break through time.

6.1.1

Inhalation Use outdoor. RPE protection factor 20 or 10 dependent upon PROC and duration.



Air Water

6.2

Soil






Consumer 8.1.2

N/A – Industrial / Professional Scenario. 8.2 Environmental exposure estimation




9 Other information

Risk adequately controlled. Gloves required for immersion protection when handling liquids. Change gloves, if duration of activity exceeds break through time. Then safe handling of high exposure dermal applications (PROC11, 19) is ensured and RCR(dermal) is assumed to be below 0.5. All other PROCs indicate a dermal RCR below 0.5 within the assessed boundaries. Ensure duration of wearing respiratory protection comply with the requirements of legislation. Measured data could be used to confirm exposure levels are within the boundaries of the exposure scenario. Use the exposure assessment tools ECETOC-TRA and EUSES for confirmation that you work inside to boundaries set by the GES (RCR<1 and PEC/PNEC<1)




GES10 Short title 1

Indoor use with limited opportunity for exposure Description of activities/process(es) covered in the Exposure Scenario Industrial or professional activities involving the handling of preparations containing monomers. Consumer use with limited exposure of monomers. Includes: IU1: Manufacture and use as intermediate. IU2: Use in production of formulations. IU3: Industrial end use as monomer, intermediate or formulation. IU4: Professional end use in formulations. IU5: Consumer end use in formulations. IU6: Service life in articles. SU3: Industrial Manufacturing (all). SU2a: Mining, (without offshore industries). SU2b: Offshore industries. SU6a: Manufacture of wood and wood products. SU6b: Manufacture of pulp, paper and paper products. SU8: Manufacture of bulk, large scale chemicals (including petroleum products). SU9: Manufacture of fine chemicals. SU10: Chemical formulation and packaging. SU12: Manufacture of plastic products, including compounding and conversion. SU13: Manufacture of other non-metallic mineral products. SU14: Manufacture of basic metals. SU15: Manufacture of fabricated metal products, except machinery and equipment. SU16: Manufacture of computer, electronic and optical products, electrical equipment. SU17: General manufacturing. SU19: Building and construction work. SU20: Health services. SU23: Recycling. SU22: Public domain. SU21: Consumer uses. PROC4: Use in batch and other process (synthesis) where opportunity for exposure arises. PROC8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities. PROC9: Transfer of substance or preparation into small containers (dedicated filling line, including weighing). PROC12: Use of blow agents in manufacture of foam. PROC14: Production of preparations or articles by tabletting, compression, extrusion, pelletisation. PROC15: Use as laboratory reagent. PROC21: Low energy manipulation of substances bound in form of massive metal or bound in other materials and/or articles. PROC22: Potentially closed processing operations with minerals/metals at elevated temperature. Industrial setting. PROC23: Open processing and transfer operations with minerals/metals at elevated temperature. PROC24: High (mechanical) energy workup of massive metal or substances bound in materials and/or articles. PC1: Adhesives, sealants. PC2: Adsorbents. PC3: Air care products. PC7: Base metals and alloys. PC8: Biocidal Products (e.g. Disinfectants, pest control). PC9a: Coatings and paints, thinners, paint removers. PC9b: Fillers and putty. PC9c: Finger paints. PC14: Metal surface treatment products, including galvanic and electroplating products. PC15: Non-metal-surface treatment products. PC18: Ink and Toners. PC19: Intermediate. PC21: Laboratory Chemicals. PC20: Products such as ph-regulators, flocculants, precipitants, neutralisation agents, other unspecific uses. PC23: Leather tanning, dye, finishing, impregnation and care products. PC24: Lubricants, Greases and Release products. PC26: Paper and Board dye, finishing and impregnation products: including bleaches and other processing aids. PC31: Polishes and Wax Blends. PC32: Polymer Preparations and Compounds. PC33: Semiconductor. PC34: Textile dyes, finishing and impregnating products: including bleaches and other processing aids. PC35: Washing and Cleaning Products (including solvent based products). PC37: Water treatment chemicals. PC39: Cosmetics, personal care. AC1-1: Passenger cars and motor cycles. AC1-2: Other vehicles: Railway, aircraft, vessels, boats, trucks, and associated transport equipment. AC2: Machinery, mechanical appliances, electrical/electronic articles. AC3: Electrical batteries and accumulators. AC4: Stone, plaster, cement, glass and ceramic articles. AC5-1: Fabrics, textiles and apparel: bedding and clothing. AC5-2: Fabrics, textiles and apparel: curtains, upholstery, carpeting/flooring, rugs. AC6: Leather products: apparel and upholstery. AC7: Metal articles. AC8-1: Paper products: tissue, towels, disposable dinnerware, nappies, feminine hygiene products, adult incontinence products, writing paper. AC10-2: Rubber products: flooring. AC10-5: Other general rubber products. AC11: Wood articles. AC13-1: Commercial and consumer plastic products like disposable dinner ware, food storage, food packaging, baby bottles. AC13-2: Plastic products: Flooring. AC13-3: Plastic products: Toys. AC13*: Plastic, small articles.

2

ERC1: Manufacture of substances. ERC2: Formulation of preparations. ERC3: Formulation in materials. ERC4: Industrial use of processing aids in processes and products, not becoming part of articles. ERC5: Industrial use resulting in inclusion into or onto a matrix. ERC6a: Industrial use resulting in manufacture of another substance (use of intermediates). ERC6b: Industrial use of reactive processing aids. ERC6c: Industrial use of monomers for polymerisation. ERC6d: Industrial use of auxiliaries for polymerisation processes in production of resins, rubbers, polymers. ERC7: Industrial use of substances in closed systems. ERC8a: Wide dispersive indoor use of processing aids in open systems. ERC8b: Wide dispersive indoor use of reactive substances in open systems. ERC8c: Wide dispersive indoor use resulting in inclusion into or onto a matrix. ERC11a: Wide dispersive indoor use of long-life articles and materials with low release.


Consumer: dependent upon concentration and activity, see section 4.3.


3.1





cont. GES10


contained Liquid


≤100%


Industrial/Professional: <1000kg/d Consumer: 9g, duration up to 4 hrs (PC1); product ingredient up to 0.3 g/g product (PC1); defaults ECETOC. See below for detail individual PROCs, PCs.

Amount used per time or per activity for which RMMs ensure control of risk RMM: Butyl gloves (0.7 mm; EN 374) for splash protection. Industrial PROC : 4, 12, 15 ; Professional PROC : 15 ; Concentration/Duration : 0-100% / 0-8hrs. RMM: Butyl gloves (0.7 mm; EN 374) for splash protection. Industrial PROC : 8b, 9, 14 ; Professional PROC : 4, 8b ; Concentration/Duration : 0-5% / 0-8hrs, 5-25% / 0-4hrs, 25-100% / 0-1hr. RMM: Butyl gloves (0.7 mm; EN 374) for splash protection. Professional PROC : 9, 12, 14 ; Concentration/Duration : 0-5% / 0-8hrs, 5-100% / 0-1hr. RMM: No RMMs identified. No ECETOC model for volatiles available; solids application only; polymer demonstrated as save use. Industrial PROC: 21, 22, 23, 24; Professional PROC: 21, 23, 24; Concentration/Duration: 0-5% / 0-8hrs. See section 9.

RMM: No RMMs identified. Consumer PC: 1; Concentration/Duration/Amount used: 0-70% / 0-8hrs / 21g; maximum for specific parameter using default values for other boundaries. See section 9.

RMM: No RMMs identified. Consumer PC: 1, 2, 3, 7, 8, 9a, 9b, 9c, 14, 15, 18, 19, 20, 21, 23, 24, 26, 31, 32, 33, 34, 35, 37, 39; Consumer AC: 1-1, 1-2, 2, 3, 4, 5-1, 5-2, 6, 7, 8-1, 10-2, 10-5, 11, 13-1, 13-2, 13-3, 13*; Concentration/Duration: 0-5% / 0-8hrs, 5-100% / Not covered. See section 9.

Operational conditions related to environment Indoor processing and handling.

4.3


Other operational conditions determining exposure Room size > 20 m³ (estimated). Ventilation rate General ventilation of workplaces. 5 – 15 air changes per hour recommended for

general application.

5




Dermal Wear gloves (butyl; 0.7 mm; EN 374) for splash protection when handling liquids and comply with good occupational hygiene practice. Change gloves, if duration of activity exceeds break through time.

6.1.1

Inhalation Use indoor.

6.1.2 Consumer related measures None required.


Air Water

6.2

Soil






cont. GES10


Worker. Predicted exposure and Risk Characterisation Ratio based on DNEL and exposure calculated by ECETOC-TRA 8.1.1

Dermal Concentration ≤ 6.86 mg/kg bw/day RCR ≤ 0.50 Inhalative Concentration ≤ 20 ppm RCR ≤ 0.40 Combined RCR ≤ 0.90

Consumer 8.1.2

Dermal Concentration ≤ 1.79 mg/kg bw/day RCR ≤ 0.22 Inhalative Concentration ≤ 6.75 mg/m

3 RCR ≤ 0.18

Combined RCR ≤ 0.40 8.2 Environmental exposure estimation



Aquatic Concentration ≤ 7.1e-02mg/ml RCR ≤ 9.2e-02 Aquatic Sediment Concentration ≤ 1.7e-01mg/kg ww RCR ≤ 9.2e-02 Soil Concentration ≤ 1.49 mg/kg ww RCR ≤ 2.3e-02

9 Other information

Risk adequately controlled. Gloves required for splash protection when handling liquids. Change gloves, if duration of activity exceeds break through time. Measured data could be used to confirm exposure levels are within the boundaries of the exposure scenario. Consumer scenarios predominantly polymer preparations. PC1 evaluated for higher residual monomer according to ECETOC standard defaults. For changing specific defaults of the model equation [0.5 ≥ RCR(dermal/inhalation) * (amount used / default ECETOC) * (duration / default ECETOC) * product ingredient / default ECETOC)] has to be satisfied. Other PCs and PROCs (polymer applications) evaluated as safe for up to 5% residual MMA related to used amount of MMA. Use the exposure assessment tools ECETOC-TRA and EUSES for confirmation that you work inside to boundaries set by the GES (RCR<1 and PEC/PNEC<1)




GES11

Short title 1

Indoor use where opportunity for exposure requires use of gloves Description of activities/process(es) covered in the Exposure Scenario Industrial or professional activities involving the handling of preparations containing monomers. Includes: IU1: Manufacture and use as intermediate. IU2: Use in production of formulations. IU3: Industrial end use as monomer, intermediate or formulation. IU4: Professional end use in formulations. SU3: Industrial Manufacturing (all). SU2a: Mining, (without offshore industries). SU2b: Offshore industries. SU6a: Manufacture of wood and wood products. SU6b: Manufacture of pulp, paper and paper products. SU8: Manufacture of bulk, large scale chemicals (including petroleum products). SU9: Manufacture of fine chemicals. SU10: Chemical formulation and packaging. SU12: Manufacture of plastic products, including compounding and conversion. SU13: Manufacture of other non-metallic mineral products. SU14: Manufacture of basic metals. SU15: Manufacture of fabricated metal products, except machinery and equipment. SU16: Manufacture of computer, electronic and optical products, electrical equipment. SU17: General manufacturing. SU19: Building and construction work. SU20: Health services. SU23: Recycling. SU22: Public domain. PROC5: Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact). PROC6: Calendaring operations. PROC7: Industrial spraying. PROC8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non dedicated facilities. PROC10: Roller application or brushing. PROC11: Non industrial spraying. PROC13: Treatment of articles by dipping and pouring. PROC17: Lubrication at high energy conditions and in partly open process. PROC18: Greasing at high energy conditions. PROC19: Hand-mixing with intimate contact and only PPE available.

2

ERC1: Manufacture of substances. ERC2: Formulation of preparations. ERC3: Formulation in materials. ERC4: Industrial use of processing aids in processes and products, not becoming part of articles. ERC5: Industrial use resulting in inclusion into or onto a matrix. ERC6a: Industrial use resulting in manufacture of another substance (use of intermediates). ERC6b: Industrial use of reactive processing aids. ERC6c: Industrial use of monomers for polymerisation. ERC6d: Industrial use of auxiliaries for polymerisation processes in production of resins, rubbers, polymers. ERC7: Industrial use of substances in closed systems. ERC8a: Wide dispersive indoor use of processing aids in open systems. ERC8b: Wide dispersive indoor use of reactive substances in open systems. ERC8c: Wide dispersive indoor use resulting in inclusion into or onto a matrix.




3.1



contained Liquid


≤100%




RMM: Butyl gloves (0.7 mm; EN 374) for immersion protection. Industrial PROC: 5, 6, 8a, 10, 13, 17, 18, 19; Concentration/Duration: 0-5% / 0-8hrs, 5-25% / 0-4hrs, 25-100% / 0-1hr. RMM: Butyl gloves (0.7 mm; EN 374) for immersion protection. Industrial PROC: 7; Concentration/Duration: 0-1% / 0-8hrs, 1-5% / 0-1hr, 5-100% / 0-15min. RMM: Butyl gloves (0.7 mm; EN 374) for immersion protection. Professional PROC: 5, 6, 8a, 10, 13, 19; Concentration/Duration: 0-5% / 0-8hrs, 5-100% / 0-1hr. RMM: Butyl gloves (0.7 mm; EN 374) for immersion protection. Professional PROC: 11; Concentration/Duration: 0-5% / 0-1hr, 5-100% / Not covered. RMM: Butyl gloves (0.7 mm; EN 374) for immersion protection. Professional PROC: 17, 18; Concentration/Duration: 0-1% / 0-8hrs, 1-5% / 0-4hrs, 5-25% / 0-1hr, 25-100% / 0-15min. Operational conditions related to environment Indoor processing and handling.

4.3


Other operational conditions determining exposure Room size > 20 m³ (estimated).

Ventilation rate General ventilation of workplaces. 5 - 15 air changes per hour recommended for general application.

5





cont. GES 11





6.1.1

Inhalation Use indoor.



Air Water

6.2

Soil






Consumer 8.1.2





9 Other information

Risk adequately controlled. Gloves required for immersion protection when handling liquids. Change gloves, if duration of activity exceeds break through time. Then safe handling of high exposure dermal applications (PROC11, 19) is ensured and RCR(dermal) is assumed to be below 0.5. Measured data could be used to confirm exposure levels are within the boundaries of the exposure scenario. Use the exposure assessment tools ECETOC-TRA and EUSES for confirmation that you work inside to boundaries set by the GES (RCR<1 and PEC/PNEC<1)




GES12 Short title 1

Indoor use where opportunity for exposure requires use of gloves and respiratory protection Description of activities/process(es) covered in the Exposure Scenario Industrial or professional activities involving the handling of preparations containing monomers. Includes: IU1: Manufacture and use as intermediate. IU2: Use in production of formulations. IU3: Industrial end use as monomer, intermediate or formulation. IU4: Professional end use in formulations. SU3: Industrial Manufacturing (all). SU2a: Mining, (without offshore industries). SU2b: Offshore industries. SU6a: Manufacture of wood and wood products. SU6b: Manufacture of pulp, paper and paper products. SU8: Manufacture of bulk, large scale chemicals (including petroleum products). SU9: Manufacture of fine chemicals. SU10: Chemical formulation and packaging. SU12: Manufacture of plastic products, including compounding and conversion. SU13: Manufacture of other non-metallic mineral products. SU14: Manufacture of basic metals. SU15: Manufacture of fabricated metal products, except machinery and equipment. SU16: Manufacture of computer, electronic and optical products, electrical equipment. SU17: General manufacturing. SU19: Building and construction work. SU20: Health services. SU23: Recycling. SU22: Public domain. SU21: Consumer uses. PROC4: Use in batch and other process (synthesis) where opportunity for exposure arises. PROC5: Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact). PROC6: Calendaring operations. PROC7: Industrial spraying. PROC8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non dedicated facilities. PROC8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities. PROC9: Transfer of substance or preparation into small containers (dedicated filling line, including weighing). PROC10: Roller application or brushing. PROC11: Non industrial spraying. PROC12: Use of blow agents in manufacture of foam. PROC13: Treatment of articles by dipping and pouring. PROC14: Production of preparations or articles by tabletting, compression, extrusion, pelletisation. PROC17: Lubrication at high energy conditions and in partly open process. PROC18: Greasing at high energy conditions. PROC19: Hand-mixing with intimate contact and only PPE available.

2

ERC1: Manufacture of substances. ERC2: Formulation of preparations. ERC3: Formulation in materials. ERC4: Industrial use of processing aids in processes and products, not becoming part of articles. ERC5: Industrial use resulting in inclusion into or onto a matrix. ERC6a: Industrial use resulting in manufacture of another substance (use of intermediates). ERC6b: Industrial use of reactive processing aids. ERC6c: Industrial use of monomers for polymerisation. ERC6d: Industrial use of auxiliaries for polymerisation processes in production of resins, rubbers, polymers. ERC7: Industrial use of substances in closed systems. ERC8a: Wide dispersive indoor use of processing aids in open systems. ERC8b: Wide dispersive indoor use of reactive substances in open systems. ERC8c: Wide dispersive indoor use resulting in inclusion into or onto a matrix.


Consumer: N/A.


3.1



contained Liquid


≤100%




RMM: Butyl gloves (0.7 mm; EN 374) for immersion protection. RPE protection factor 10 (see section 9). Industrial PROC: 5, 6, 7, 8a, 8b, 9, 10, 13, 14, 17, 18, 19; Professional PROC: 4, 5, 6, 8a, 8b, 9, 10, 12, 13, 14, 17, 18, 19; Concentration/Duration: 0-100% / 0-8hrs.

RMM: Butyl gloves (0.7 mm; EN 374) for immersion protection. RPE protection factor 10 (see section 9). Professional PROC: 11; Concentration/Duration: 0-5% / 0-8hrs, 5-25% / 0-4hrs, 25-100% / 0-1hr. RMM: Butyl gloves (0.7 mm; EN 374) for immersion protection. RPE protection factor 20 (see section 9). Above scenarios plus: Professional PROC: 11; Concentration/Duration: 0-100% / 0-8hrs. Operational conditions related to environment Indoor processing and handling.

4.3


Other operational conditions determining exposure Room size > 20 m³ (estimated).

Ventilation rate General ventilation of workplaces. 5 - 15 air changes per hour recommended for general application.

5





cont. GES12





6.1.1

Inhalation Use indoor. RPE protection factor 20 or 10 dependent upon PROC and duration.



Air Water

6.2

Soil






Consumer 8.1.2





9 Other information

Risk adequately controlled. Gloves required for immersion protection when handling liquids. Change gloves, if duration of activity exceeds break through time. Then safe handling of high exposure dermal applications (PROC11, 19) is ensured and RCR(dermal) is assumed to be below 0.5. All other PROCs indicate a dermal RCR below 0.5 within the assessed boundaries. Ensure duration of wearing respiratory protection comply with the requirements of legislation. Measured data could be used to confirm exposure levels are within the boundaries of the exposure scenario. Use the exposure assessment tools ECETOC-TRA and EUSES for confirmation that you work inside to boundaries set by the GES (RCR<1 and PEC/PNEC<1)

Documents

Safety Data Sheet - Degafloor · Safety Data Sheet in accordance with regulation (EC) 1907/2006 Status: 10.11.2010 Version: 6.3 VISIOMER® MMA Page 3 of 33 SDB Version: 6.3 System: