Safety Data Sheet: Absorbent PowderFlammability (solid, gas) Explosion limits of dust clouds not determined Vapor pressure not determined Density not determined Relative density not

MasterBlend • 5285 Fox Street • CO 80216 Denver • United States • Telephone: 303.373.0702 • Telefax 303.373.4968 • e-mail: [email protected] • Website: masterblend.net

Annex - Hazard class and category - Hazard statement code(s)

For full text of H-phrases: see SECTION 16.

SECTION 1: Identification

1.1 Product identifierTrade name Absorbent PowderOther means of identificationProduct code(s): 1862 Formula code: 04-981120

1.2 Relevant identified usesRelevant identified uses General use

1.3 Details of the supplier of the safety data sheet

1.4 Emergency telephone numberChem-Tel 1.800.255.3924 (USA & Canada) 1.813.248.0585 (International)

SECTION 2: Hazard(s) identification

2.1 Classification of the substance or mixtureClassification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)

A.3 serious eye damage/eye irritation Cat. 2B (Eye Irrit. 2B) H320A.8R specific target organ toxicity - single expos-

ure (respiratory tract irritation)Cat. 3 (STOT SE 3) H335

Remarks

Hazards not otherwise classifiedMay be harmful if swallowed (GHS category 5: acutely toxic - oral).Harmful to aquatic life (GHS category 3: aquatic toxicity - acute).

2.2 Label elementsLabelling acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)Signal word WARNINGPictogramsGHS07

Hazard statementsH320 Causes eye irritation.H335 May cause respiratory irritation.

Precautionary statementsPrecautionary statements - preventionAvoid breathing dust/fume/gas/mist/vapors/spray.Wash thoroughly after handling.

Precautionary statements - response

Safety Data Sheet Absorbent PowderRevision date: 06/01/2015

United StatesMB 000201 SDS-01

Page 1 / 10

There is no additional information.

not relevant (mixture)

For full text of abbreviations: see SECTION 16.

Do not leave affected person unattended. Remove victim out of the danger area. Keep affected person warm,still and covered. Take off immediately all contaminated clothing. In all cases of doubt, or when symptoms per-sist, seek medical advice. In case of unconsciousness place person in the recovery position. Never give any-thing by mouth.

If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. In case ofrespiratory tract irritation, consult a physician. Provide fresh air.

Brush off loose particles from skin. - Rinse skin with water/shower.

Remove contact lenses, if present and easy to do. Continue rinsing. Irrigate copiously with clean, fresh waterfor at least 10 minutes, holding the eyelids apart.

Rinse mouth with water (only if the person is conscious). Do NOT induce vomiting.

IF INHALED: Remove person to fresh air and keep comfortable for breathing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing.Call a POISON CENTER/doctor if you feel unwell.

Precautionary statements - storageStore in a well-ventilated place. Keep container tightly closed.

Hazardous ingredients for labelling Zeolite2.3 Other hazards

SECTION 3: Composition/information on ingredients

3.1 Substances

3.2 Mixtures3.2.1

Name of substance Identifier Wt%

Zeolite CAS No12173-10-3

50 - < 75

Calcium carbonate CAS No1317-65-3

25 - < 50

Sodium polyacrylate CAS No9003-04-7

1 - < 5

SECTION 4: First-aid measures

4.1 Description of firs- aid measuresGeneral notes

Following inhalation

Following skin contact

Following eye contact

Following ingestion



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Symptoms and effects are not known to date.

none

water, foam, alcohol resistant foam, ABC-powder

water jet

Deposited combustible dust has considerable explosion potential.

nitrogen oxides (NOx), carbon monoxide (CO), carbon dioxide (CO2)

In case of fire and/or explosion do not breathe fumes. Co-ordinate firefighting measures to the fire surround-ings. Do not allow firefighting water to enter drains or water courses. Collect contaminated firefighting waterseparately. Fight fire with normal precautions from a reasonable distance.

Remove persons to safety.

Wear breathing apparatus if exposed to vapors/dust/aerosols/gases.

Keep away from drains, surface and ground water. Retain contaminated washing water and dispose it.

Covering of drains. - Take up mechanically.

Take up mechanically.

Place in appropriate containers for disposal. Ventilate affected area.

Hazardous combustion products: see section 5. Personal precautions: see section 8. Incompatible materials:see section 10. Disposal considerations: see section 13.

4.2 Most important symptoms and effects, both acute and delayed

4.3 Indication of any immediate medical attention and special treatment needed

SECTION 5: Fire-fighting measures

5.1 Extinguishing mediaSuitable extinguishing media

Unsuitable extinguishing media

5.2 Special hazards arising from the substance or mixture

Hazardous combustion products

5.3 Advice for firefighters

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency proceduresFor non-emergency personnel

For emergency responders

6.2 Environmental precautions

6.3 Methods and material for containment and cleaning upAdvices on how to contain a spill

Advices on how to clean up a spill

Other information relating to spills and releases

6.4 Reference to other sections



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Use local and general ventilation. Take precautionary measures against static discharge. Use only in well-ventilated areas. Ground/bond container and receiving equipment.

Dust deposits may accumulate on all deposition surfaces in a technical room. The product in the delivered formis not dust explosion capable; the enrichment of fine dust however leads to the danger of dust explosion.

Wash hands after use. Do not to eat, drink and smoke in work areas. Remove contaminated clothing and pro-tective equipment before entering eating areas. Never keep food or drink in the vicinity of chemicals. Neverplace chemicals in containers that are normally used for food or drink. Keep away from food, drink and animalfeedingstuffs.

Removal of dust deposits.

Observe compatible storage of chemicals.

Use local and general ventilation.

See section 16 for a general overview.

SECTION 7: Handling and storage

7.1 Precautions for safe handlingRecommendationsMeasures to prevent fire as well as aerosol and dust generation

Warning

Advice on general occupational hygiene

7.2 Conditions for safe storage, including any incompatibilitiesManaging of associated risks• Explosive atmospheres

Incompatible substances or mixtures

Consideration of other adviceVentilation requirements

7.3 Specific end use(s)

SECTION 8: Exposure controls/personal protection

8.1 Control parametersNational limit valuesOccupational exposure limit values (Workplace Exposure Limits)

Coun-try

Name of agent CAS No Identifier TWA[ppm]

TWA[mg/m³]

STEL[ppm]

STEL[mg/m³]

Source

US limestone (calcium carbon-ate)

1317-65-3 PEL 15 29 CFROSHA

US limestone (calcium carbon-ate)

1317-65-3 PEL 5 29 CFROSHA

notationSTEL Short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-minute period

unless otherwise specified.TWA Time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8 hours time-

weighted average.



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No data available.

General ventilation.

Wear eye/face protection.

Wear protective gloves.

Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recom-mended. Wash hands thoroughly after handling.

Particulate filter device (EN 143).

Use appropriate container to avoid environmental contamination. Keep away from drains, surface and groundwater.

Relevant DNELs/DMELs/PNECs and other threshold levels

8.2 Exposure controlsAppropriate engineering controls

Individual protection measures (personal protective equipment)Eye/face protection

Skin protection• hand protection

• other protection measures

Respiratory protection

Environmental exposure controls

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical propertiesAppearancePhysical state solidColor differentOdor freshOther physical and chemical parameterspH (value)Melting point/freezing point not determinedInitial boiling point and boiling range not determinedFlash point not applicableEvaporation rate not determinedFlammability (solid, gas)Explosion limits of dust clouds not determinedVapor pressure not determinedDensity not determinedRelative density not determinedSolubility(ies) not determinedAuto-ignition temperature not determinedViscosity not relevant (solid matter)Explosive properties noneOxidizing properties none



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Concerning incompatibility: see below "Conditions to avoid" and "Incompatible materials".

See below "Conditions to avoid".

No known hazardous reactions.

There are no specific conditions known which have to be avoided.

The product in the delivered form is not dust explosion capable; the enrichment of fine dust however leads tothe danger of dust explosion.

strong shocks


Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill andheating are not known. Hazardous combustion products: see section 5.

Test data are not available for the complete mixture.

The method for classification of the mixture is based on ingredients of the mixture (additivity formula).

Shall not be classified as acutely toxic.

Shall not be classified as corrosive/irritant to skin.

Causes eye irritation.

Shall not be classified as a respiratory or skin sensitizer.

Shall not be classified as germ cell mutagenic, carcinogenic nor as a reproductive toxicant.

May cause respiratory irritation.

SECTION 10: Stability and reactivity

10.1 Reactivity

10.2 Chemical stability

10.3 Possibility of hazardous reactions

10.4 Conditions to avoid

Hints to prevent fire or explosion

Physical stresses which might result in a hazardous situation and have to be avoided

10.5 Incompatible materials

10.6 Hazardous decomposition products

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Classification procedure

Classification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)Acute toxicity

Skin corrosion/irritation

Serious eye damage/eye irritation

Respiratory or skin sensitization

Summary of evaluation of the CMR properties

Carcinogenicity • National Toxicology Program (United States): none of the ingredients are listed • IARC Monographs none of the ingredients are listedSpecific target organ toxicity (STOT)Specific target organ toxicity - single exposure



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Shall not be classified as a specific target organ toxicant (repeated exposure).

Shall not be classified as presenting an aspiration hazard.

Harmful to aquatic life.

The relevant substances of the mixture are readily biodegradable.

Data are not available.





Specific target organ toxicity - repeated exposure

Aspiration hazard

SECTION 12: Ecological information

12.1 Toxicity

Aquatic toxicity (acute)Aquatic toxicity (acute) of components of the mixture

Name of substance CAS No Endpoint Value Species Exposuretime

Zeolite 12173-10-3 ErC50 130 mg/l algae 72 hours

Zeolite 12173-10-3 EC50 44 mg/l algae 72 hours

Aquatic toxicity (chronic)Aquatic toxicity (chronic) of components of the mixture


Zeolite 12173-10-3 EC50 680 mg/l aquatic inverteb-rates

21 d

Biodegradation

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Other adverse effects



Page 7 / 10

Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data sheets.

Completely emptied packages can be recycled. Handle contaminated packages in the same way as the sub-stance itself.

Please consider the relevant national or regional provisions. Waste shall be separated into the categories thatcan be handled separately by the local or national waste management facilities.


The cargo is not intended to be carried in bulk.

Hazardous Materials Identification System (American Coatings Association)

SECTION 13: Disposal considerations

13.1 Waste treatment methodsSewage disposal-relevant information

Waste treatment of containers/packages

Remarks

SECTION 14: Transport information

14.1 UN number (not subject to transport regulations)14.2 UN proper shipping name not relevant14.3 Transport hazard class(es)

Class -

14.4 Packing group not relevant14.5 Environmental hazards none (non-environmentally hazardous acc. to the dangerous

goods regulations)

14.6 Special precautions for user

14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations specific for the product in questionNational regulations (United States)

Industry or sector specific available guidance(s)NPCA-HMIS® III

Category Rating Description

Chronic / None.

Health 2 Temporary or minor injury may occur.

Flammability 1 Material that must be preheated before ignition can occur.

Physical hazard 0 Material that is normally stable, even under fire conditions, and will not react with water,polymerize, decompose, condense, or self-react. Non-explosive.

Personal protectiveequipment

-



Page 8 / 10

National Fire Protection Association: Standard System for the Identification of the Hazards of Materials forEmergency Response (United States)

NFPA® 704

Category Degree ofhazard

Description


Health 2 Material that, under emergency conditions, can cause temporary incapacitation or residualinjury.

Instability 0 Material that is normally stable, even under fire conditions.

Special hazard

Relevant European Union (EU) safety, health and environmental provisionsClassification according to GHS (1272/2008/EC, CLP)Hazard class Category Hazard class and categoryserious eye damage/eye irritation 2 (Eye Irrit. 2)specific target organ toxicity - single exposure (respir-atory tract irritation)

3 (STOT SE 3)

SECTION 16: Other information, including date of preparation or last revision

Abbreviations and acronymsAbbr. Descriptions of used abbreviations

29 CFR OSHA 29 CFR §1910.1001 - Occupational Safety and Health Standards: Toxic and Hazardous Substances (permissible ex-posure limits)

CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)

CLP Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures

CMR Carcinogenic, Mutagenic or toxic for Reproduction

DMEL Derived Minimal Effect Level

DNEL Derived No-Effect Level

GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Nations

HMIS Hazardous Materials Identification System

IARC Mono-graphs

IARC Monographs on the Evaluation of Carcinogenic Risks to Humans

MARPOL International Convention for the Prevention of Pollution from Ships (abbr. of "Marine Pollutant)

NFPA® 704 National Fire Protection Association: Standard System for the Identification of the Hazards of Materials for Emer-gency Response (United States)

NPCA-HMIS®III

National Paint and Coatings Association: Hazardous Materials Identification System - HMIS® III, Third Edition

OSHA Occupational Safety and Health Administration (United States)

PBT Persistent, Bioaccumulative and Toxic

PEL permissible exposure limit

PNEC Predicted No-Effect Concentration

ppm parts per million

STEL short-term exposure limit

TWA time-weighted average

vPvB very Persistent and very Bioaccumulative



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Physical and chemical properties: The classification is based on tested mixture.Health hazards/Environmental hazards: The method for classification of the mixture is based on ingredients ofthe mixture (additivity formula).

This information is based upon the present state of our knowledge. This SDS has been compiled and is solelyintended for this product.

Key literature references and sources for data- OSHA Hazard Communication Standard (HCS), 29 CFR 1910.1200- 49 CFR § 172.101 Hazardous Materials Table (DOT)


List of relevant phrases (code and full text as stated in chapter 2 and 3)Code Text

H320 causes eye irritation

H335 may cause respiratory irritation

Disclaimer



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1.1 Product identifierTrade name MasterGelOther means of identificationProduct code(s): 1822 Formula code: 06-150929






A.2 skin corrosion/irritation Cat. 2 (Skin Irrit. 2) H315A.3 serious eye damage/eye irritation Cat. 1 (Eye Dam. 1) H318Remarks

Hazards not otherwise classifiedMay be harmful if swallowed (GHS category 5: acutely toxic - oral).

2.2 Label elementsLabelling acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)Signal word DANGERPictogramsGHS05

Hazard statementsH315 Causes skin irritation.H318 Causes serious eye damage.

Precautionary statementsPrecautionary statements - preventionWash thoroughly after handling.Wear protective gloves/eye protection/face protection.

Precautionary statements - responseIF ON SKIN: Wash with plenty of water.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing.Immediately call a POISON CENTER/doctor.Specific treatment (see on this label).Take off contaminated clothing and wash it before reuse.

Hazardous ingredients for labelling anionic surfactant

Safety Data Sheet MasterGelRevision date: 06/01/2015


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Special danger of slipping by leaking/spilling product.





Wash with plenty of soap and water.


2.3 Other hazards


3.1 Substances

3.2 Mixtures3.2.1


Deionized Water CAS No7732-18-5

25 - < 50

Aqueous detergent CAS NoTrade Secret

15 - < 25

Soy methyl ester CAS No68919-53-9

15 - < 25

Synthetic hydrocarbon CAS NoTrade Secret

15 - < 25

Anionic surfactant CAS NoTrade Secret

1 - < 5

D-Limonene CAS No94266-47-4

1 - < 5

Sodium (C14-16) olefin sulfonate CAS No68439-57-6

1 - < 5








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none

water spray, alcohol resistant foam, BC-powder, carbon dioxide (CO2)

water jet






Covering of drains.

Wipe up with absorbent material (e.g. cloth, fleece). Collect spillage (sawdust, kieselgur (diatomite), sand,universal binder).

Use of adsorbent materials.



Following ingestion






5.2 Special hazards arising from the substance or mixtureHazardous combustion products








Appropriate containment techniques





Page 3 / 10

Use local and general ventilation. Use only in well-ventilated areas.



frost

Only packagings which are approved (e.g. acc. to DOT) may be used.


No data available.



Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Checkleak-tightness/impermeability prior to use. In the case of wanting to use the gloves again, clean them beforetaking off and air them well. For special purposes, it is recommended to check the resistance to chemicals ofthe protective gloves mentioned above together with the supplier of these gloves.




7.2 Conditions for safe storage, including any incompatibilitiesManaging of associated risksIncompatible substances or mixtures

Control of the effectsProtect against external exposure, such as

Consideration of other advicePackaging compatibilities



8.1 Control parametersNational limit valuesOccupational exposure limit values (Workplace Exposure Limits)Relevant DNELs/DMELs/PNECs and other threshold levels






Page 4 / 10


In case of inadequate ventilation wear respiratory protection.






9.1 Information on basic physical and chemical propertiesAppearancePhysical state liquid (gel)Color differentOdor characteristicOther physical and chemical parameterspH (value) not determinedMelting point/freezing point not determinedInitial boiling point and boiling range 176 °CFlash point >43 °CEvaporation rate not determinedFlammability (solid, gas) not relevant (fluid)Explosive limits• lower explosion limit (LEL) 0.7 vol%• upper explosion limit (UEL) 6.1 vol%Vapor pressure <2 mmHg at 20 °CDensity not determinedRelative density not determinedSolubility(ies) not determinedAuto-ignition temperature 237 °CViscosity not determinedExplosive properties noneOxidizing properties none



Page 5 / 10





strong shocks






Causes skin irritation.

Causes serious eye damage.




10.1 Reactivity











Acute toxicity of components of the mixtureName of substance CAS No Exposure route ATE

aqueous detergent Trade Secret oral 500





Carcinogenicity • National Toxicology Program (United States): none of the ingredients are listed • IARC Monographs none of the ingredients are listed



Page 6 / 10

Shall not be classified as a specific target organ toxicant.


Shall not be classified as hazardous to the aquatic environment.




Specific target organ toxicity (STOT)

Aspiration hazard


12.1 Toxicity



sodium (C14-16) olefinsulfonate

68439-57-6 LC50 4.2 mg/l fish 96 hours


68439-57-6 EC50 4.53 mg/l aquatic inverteb-rates

48 hours


68439-57-6 ErC50 5.2 mg/l algae 72 hours




68439-57-6 EC50 230 mg/l microorganisms 3 h

Biodegradation


Degradability of components of the mixtureName of substance CAS No Process Degradation rate Time


68439-57-6 carbon dioxide genera-tion

80 % 28 d


68439-57-6 DOC removal 96 % 28 d


Bioaccumulative potential of components of the mixtureName of substance CAS No BCF Log KOW BOD5/COD


68439-57-6 70.8 -1.3



Page 7 / 10
















Remarks


14.1 UN number14.2 UN proper shipping name not relevant14.3 Transport hazard class(es)

Class -


goods regulations)







Chronic / None.

Health 3 Major injury likely unless prompt action is taken and medical treatment is given.

Flammability 2 Material that must be moderately heated or exposed to relatively high ambient temperat-ures before ignition can occur.




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-

NFPA® 704


Description


Health 3 Material that, under emergency conditions, can cause serious or permanent injury.


Special hazard

Relevant European Union (EU) safety, health and environmental provisionsClassification according to GHS (1272/2008/EC, CLP)Hazard class Category Hazard class and categoryskin corrosion/irritation 2 (Skin Irrit. 2)serious eye damage/eye irritation 1 (Eye Dam. 1)



ATE Acute Toxicity Estimate

BCF BioConcentration Factor

BOD Biochemical Oxygen Demand




COD chemical oxygen demand



DOT Department of Transportation (USA)



IARC Mono-graphs


log KOW n-octanol/water



NPCA-HMIS®III





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Abbr. Descriptions of used abbreviations







H315 causes skin irritation

H318 causes serious eye damage

Disclaimer



Page 10 / 10




The product is combustible and can be ignited by potential ignition sources.


1.1 Product identifierTrade name MasterSpotterOther means of identificationProduct code(s): 1823 Formula code: 08-150421






B.6 flammable liquid Cat. 3 (Flam. Liq. 3) H226A.3 serious eye damage/eye irritation Cat. 1 (Eye Dam. 1) H318Remarks

The most important adverse physicochemical, human health and environmental effects

2.2 Label elementsLabelling acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)Signal word DANGERPictogramsGHS02, GHS05

Hazard statementsH226 Flammable liquid and vapor.H318 Causes serious eye damage.

Precautionary statementsPrecautionary statements - preventionKeep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Precautionary statements - responseIF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing.In case of fire: Use sand, carbon dioxide or powder extinguisher to extinguish.

Safety Data Sheet MasterSpotterRevision date: 06/01/2015


Page 1 / 12





If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. Providefresh air.


Precautionary statements - storageStore in a well-ventilated place. Keep cool.

Precautionary statements - disposalDispose of contents/container to industrial combustion plant.

Hazardous ingredients for labelling Ethoxylated Alcohols2.3 Other hazards


3.1 Substances

3.2 Mixtures3.2.1


Ethoxylated Alcohols CAS No68439-46-3

5 - < 15


5 - < 15

Dipropylene Glycol Monomethyl Ether CAS No34590-94-8

5 - < 15

Cocamide DIPA CAS No68855-69-6

1 - < 5

Sodium thiosulphate CAS No7772-98-7

1 - < 5

B-Alanine, N-(2-carboxyethyl)-N-[3-(decyloxy)propyl]-, monosodi-um salt

CAS No64972-19-6

< 1







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none


water jet

In case of insufficient ventilation and/or in use, may form flammable/explosive vapor-air mixture. Solvent va-pors are heavier than air and may spread along floors. Places which are not ventilated, e.g. unventilated belowground level areas such as trenches, conduits and shafts, are particularly prone to the presence of flammablesubstances or mixtures.






Covering of drains.



Following ingestion

















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Use local and general ventilation. Avoidance of ignition sources. Keep away from sources of ignition - Nosmoking. Take precautionary measures against static discharge. Use only in well-ventilated areas. Due todanger of explosion, prevent leakage of vapours into cellars, flues and ditches. Ground/bond container and re-ceiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools.

Places which are not ventilated, e.g. unventilated below ground level areas such as trenches, conduits andshafts, are particularly prone to the presence of flammable substances or mixtures. Vapors are heavier thanair, spread along floors and form explosive mixtures with air. Vapors may form explosive mixtures with air.


Keep container tightly closed and in a well-ventilated place. Use local and general ventilation. Keep cool.Protect from sunlight.

Keep away from sources of ignition - No smoking. Keep away from heat, hot surfaces, sparks, open flamesand other ignition sources. No smoking. Take precautionary measures against static discharge. Protect fromsunlight.


Use local and general ventilation. Ground/bond container and receiving equipment.

Only packagings which are approved (e.g. acc. to DOT) may be used.







Warning



• Flammability hazards



Packaging compatibilities




Page 4 / 12

No data available.









Coun-try


TWA[mg/m³]

STEL[ppm]

STEL[mg/m³]

Source

US dipropylene glycol methylether

34590-94-8 PEL 100 600 29 CFROSHA



weighted average.










Page 5 / 12

Concerning incompatibility: see below "Conditions to avoid" and "Incompatible materials". The mixture containsreactive substance(s): risk of ignition

risk of ignition




9.1 Information on basic physical and chemical propertiesAppearancePhysical state liquidColor amberOdor Orange Citrus AromaOther physical and chemical parameterspH (value) 7.5Melting point/freezing point not determinedInitial boiling point and boiling range >100 °CFlash point 52.2 °CEvaporation rate not determinedFlammability (solid, gas) not relevant (fluid)Explosive limits• lower explosion limit (LEL) 0.7 vol%• upper explosion limit (UEL) 14 vol%Vapor pressure <2 mmHg at 20 °CDensity 0.9982 kg/lSolubility(ies) not determinedAuto-ignition temperature 207 °CViscosity not determinedExplosive properties noneOxidizing properties none


10.1 Reactivity

• if heated





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Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionarymeasures against static discharge.

strong shocks







Causes serious eye damage.















Ethoxylated Alcohols 68439-46-3 oral 1,400





Carcinogenicity • National Toxicology Program (United States): none of the ingredients are listed • IARC Monographs none of the ingredients are listedSpecific target organ toxicity (STOT)

Aspiration hazard



Page 7 / 12







12.1 Toxicity



Dipropylene GlycolMonomethyl Ether

34590-94-8 LC50 >1,000 mg/l fish 96 hours


34590-94-8 ErC50 >969 mg/l algae 72 hours


34590-94-8 EC50 >969 mg/l algae 72 hours




34590-94-8 LC50 >1,000 mg/l aquatic inverteb-rates

24 h

Biodegradation




34590-94-8 oxygen depletion 75 % 10 d


34590-94-8 DOC removal 96 % 28 d



76 % 28 d




34590-94-8 0.0043




Page 8 / 12



Solvent reclamation/regeneration.









13.1 Waste treatment methodsWaste treatment-relevant information

Sewage disposal-relevant information


Remarks


14.1 UN number 199314.2 UN proper shipping name FLAMMABLE LIQUID, N.O.S.

Hazardous constituents d-Limonene14.3 Transport hazard class(es)

Class 3 (flammable liquids)

14.4 Packing group III (substance presenting low danger)

14.5 Environmental hazards none (non-environmentally hazardous acc. to the dangerousgoods regulations)



Information for each of the UN Model Regulations• Transport of dangerous goods by road or rail (49 CFR US DOT)Index number 1993Proper shipping name Flammable liquid, n.o.s.Class 3Packing group IIIDanger label(s) 3



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Special provisions (SP) B1, B52, IB3, T4, TP1, TP29ERG No 128• International Maritime Dangerous Goods Code (IMDG)UN number 1993Proper shipping name FLAMMABLE LIQUID, N.O.S.Class 3Packing group IIIDanger label(s) 3

Special provisions (SP) 223, 274, 955Excepted quantities (EQ) E1Limited quantities (LQ) 5 LEmS F-E, S-EStowage category E• International Civil Aviation Organization (ICAO-IATA/DGR)UN number 1993Proper shipping name Flammable liquid, n.o.s.Class 3Packing group IIIDanger label(s) 3

Special provisions (SP) A3, 274Excepted quantities (EQ) E1Limited quantities (LQ) 10 L






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Chronic / None.

Health 3 Major injury likely unless prompt action is taken and medical treatment is given.




-

NFPA® 704


Description


Health 3 Material that, under emergency conditions, can cause serious or permanent injury.


Special hazard

Relevant European Union (EU) safety, health and environmental provisionsClassification according to GHS (1272/2008/EC, CLP)Hazard class Category Hazard class and categoryflammable liquid 3 (Flam. Liq. 3)serious eye damage/eye irritation 1 (Eye Dam. 1)




49 CFR USDOT

49 CFR § 40 U.S. Department of Transportation










DOT Department of Transportation (USA)

EmS Emergency Schedule



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ERG No Emergency Response Guidebook - Number



IARC Mono-graphs


IATA/DGR Dangerous Goods Regulations (DGR) for the air transport (IATA)

ICAO International Civil Aviation Organization

IMDG International Maritime Dangerous Goods Code




NPCA-HMIS®III













H226 flammable liquid and vapor

H318 causes serious eye damage

Disclaimer



Page 12 / 12






1.1 Product identifierTrade name POG - Paint Oil & Grease RemoverOther means of identificationProduct code(s): 1821 Formula code: 04-091110






B.6 flammable liquid Cat. 4 (Flam. Liq. 4) H227A.2 skin corrosion/irritation Cat. 2 (Skin Irrit. 2) H315A.3 serious eye damage/eye irritation Cat. 2B (Eye Irrit. 2B) H320Remarks



Hazard statementsH227 Combustible liquid.H315+H320 Causes skin and eye irritation.

Precautionary statementsPrecautionary statements - preventionKeep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.Wear protective gloves/eye protection/face protection.


Safety Data Sheet POG - Paint Oil & Grease RemoverRevision date: 06/01/2015


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This material is combustible, but will not ignite readily.





IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing.If eye irritation persists: Get medical advice/attention.In case of fire: Use sand, carbon dioxide or powder extinguisher to extinguish.


2.3 Other hazards


3.1 Substances

3.2 Mixtures3.2.1


Soy methyl ester CAS No68919-53-9

50 - < 75

Synthetic hydrocarbon CAS NoTrade Secret

15 - < 25

Cocamide DIPA CAS No68855-69-6

5 - < 15


1 - < 5

Pentyl acetate CAS No628-63-7

1 - < 5

2-methyl butyl acetate CAS No624-41-9

1 - < 5


1 - < 5






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none


water jet







Covering of drains.



Following ingestion
















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Warning








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No data available.










Coun-try


TWA[mg/m³]

STEL[ppm]

STEL[mg/m³]

Source


34590-94-8 PEL 100 600 29 CFROSHA



weighted average.










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risk of ignition




9.1 Information on basic physical and chemical propertiesAppearancePhysical state liquidColor dark amberOdor Citrus AromaOther physical and chemical parameterspH (value) not applicable (non-aqueous)Melting point/freezing point not determinedInitial boiling point and boiling range 176 °CFlash point 62.5 °CEvaporation rate not determinedFlammability (solid, gas) not relevant (fluid)Explosive limits• lower explosion limit (LEL) 0.7 vol%• upper explosion limit (UEL) 14 vol%Vapor pressure <2 mmHg at 20 °CDensity not determinedRelative density not determinedSolubility(ies) not determinedAuto-ignition temperature 207 °CViscosity not determinedExplosive properties noneOxidizing properties none


10.1 Reactivity

• if heated





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strong shocks







Causes eye irritation.


















Carcinogenicity • National Toxicology Program (United States): none of the ingredients are listed • IARC Monographs none of the ingredients are listedSpecific target organ toxicity (STOT)

Aspiration hazard



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12.1 Toxicity




34590-94-8 LC50 >1,000 mg/l fish 96 hours









24 h

Biodegradation






34590-94-8 DOC removal 96 % 28 d



76 % 28 d




34590-94-8 0.0043




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Remarks



Class -


goods regulations)







Chronic / None.






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-

NFPA® 704


Description




Special hazard

Relevant European Union (EU) safety, health and environmental provisionsClassification according to GHS (1272/2008/EC, CLP)Hazard class Category Hazard class and categoryskin corrosion/irritation 2 (Skin Irrit. 2)serious eye damage/eye irritation 2 (Eye Irrit. 2)














IARC Mono-graphs





NPCA-HMIS®III





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H227 combustible liquid


H320 causes eye irritation

Disclaimer



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1.1 Product identifierTrade name Protein SpotterOther means of identificationProduct code(s): 1831 Formula code: 02-960326






A.2 skin corrosion/irritation Cat. 2 (Skin Irrit. 2) H315A.3 serious eye damage/eye irritation Cat. 2 (Eye Irrit. 2) H319Remarks


Hazard statementsH315 Causes skin irritation.H319 Causes serious eye irritation.

Precautionary statementsPrecautionary statements - preventionWash thoroughly after handling.Wear protective gloves/eye protection/face protection.

Precautionary statements - responseIF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing.Specific treatment (see on this label).If skin irritation occurs: Get medical advice/attention.If eye irritation persists: Get medical advice/attention.

Safety Data Sheet Protein SpotterRevision date: 06/01/2015


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2.3 Other hazards


3.1 Substances

3.2 Mixtures3.2.1


Deionized Water CAS No7732-18-5

75 - < 90


5 - < 15

2-butoxyethanol CAS No111-76-2

5 - < 15

2-aminoethanol CAS No141-43-5

1 - < 5

Ammonium lauryl sulfate CAS No2235-54-3

< 1

Ethoxylated Alcohols CAS No68439-46-3

< 1






Following ingestion



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none


water jet






Covering of drains.










5.2 Special hazards arising from the substance or mixtureHazardous combustion products













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Use local and general ventilation. Use only in well-ventilated areas.



frost


No data available.




7.2 Conditions for safe storage, including any incompatibilitiesManaging of associated risksIncompatible substances or mixtures

Control of the effectsProtect against external exposure, such as




Coun-try


TWA[mg/m³]

STEL[ppm]

STEL[mg/m³]

Source

US 2-butoxyethanol 111-76-2 PEL 50 240 29 CFROSHA


34590-94-8 PEL 100 600 29 CFROSHA

US ethanolamine 141-43-5 PEL 3 6 29 CFROSHA



weighted average.




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9.1 Information on basic physical and chemical propertiesAppearancePhysical state liquidColor differentOdor mild sweetOther physical and chemical parameterspH (value) 10Melting point/freezing point not determinedInitial boiling point and boiling range 167 °C at 101 kPaFlash point >96.1 °CEvaporation rate not determinedFlammability (solid, gas) not relevant (fluid)Explosive limits• lower explosion limit (LEL) 1.1 vol%• upper explosion limit (UEL) 14 vol%Vapor pressure 1 hPa at 20 °CDensity not determinedRelative density not determinedSolubility(ies) not determinedAuto-ignition temperature 207 °CViscosity not determined



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strong shocks






Explosive properties noneOxidizing properties none


10.1 Reactivity












2-butoxyethanol 111-76-2 oral 1,414

2-butoxyethanol 111-76-2 dermal 1,100

2-butoxyethanol 111-76-2 inhalation: vapor 11

2-aminoethanol 141-43-5 oral 1,515

2-aminoethanol 141-43-5 dermal 1,100

2-aminoethanol 141-43-5 inhalation: vapor 11

Ammonium lauryl sulfate 2235-54-3 oral 500

Ethoxylated Alcohols 68439-46-3 oral 1,400



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Causes serious eye irritation.










Carcinogenicity • National Toxicology Program (United States): none of the ingredients are listed • IARC Monographs

Name of substance Name acc. to inventory CAS No wt% Classifica-tion

Number

2-butoxyethanol 2-Butoxyethanol 111-76-2 5 3 Volume 88

legend3 Not classifiable as to carcinogenicity in humans.


Aspiration hazard


12.1 Toxicity




34590-94-8 LC50 >1,000 mg/l fish 96 hours





2-butoxyethanol 111-76-2 LC50 1,474 mg/l fish 96 hours

2-butoxyethanol 111-76-2 EC50 1,550 mg/l aquatic inverteb-rates

48 hours

2-butoxyethanol 111-76-2 ErC50 1,840 mg/l algae 72 hours

2-aminoethanol 141-43-5 LC50 >300 mg/l fish 96 hours

2-aminoethanol 141-43-5 EC50 65 mg/l aquatic inverteb-rates

48 hours

2-aminoethanol 141-43-5 ErC50 2.8 mg/l algae 72 hours



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24 h

2-butoxyethanol 111-76-2 EC50 297 mg/l aquatic inverteb-rates

21 d

2-aminoethanol 141-43-5 LC50 525 mg/l fish 10 d

2-aminoethanol 141-43-5 EC50 120 mg/l aquatic inverteb-rates

24 h






34590-94-8 DOC removal 96 % 28 d



76 % 28 d

2-butoxyethanol 111-76-2 carbon dioxide genera-tion

18.3 % 3 d

2-aminoethanol 141-43-5 DOC removal >90 % 21 d




34590-94-8 0.0043

2-butoxyethanol 111-76-2 0.81

2-aminoethanol 141-43-5 0.75 -2.3





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Remarks



Class -


goods regulations)







Chronic / None.





-



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NFPA® 704


Description




Special hazard

Relevant European Union (EU) safety, health and environmental provisionsClassification according to GHS (1272/2008/EC, CLP)Hazard class Category Hazard class and categoryskin corrosion/irritation 2 (Skin Irrit. 2)serious eye damage/eye irritation 2 (Eye Irrit. 2)















IARC Mono-graphs





NPCA-HMIS®III








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H319 causes serious eye irritation

Disclaimer



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1.1 Product identifierTrade name Volatile SolventOther means of identificationProduct code(s): 1811 Formula code: 02-090130






B.6 flammable liquid Cat. 4 (Flam. Liq. 4) H227A.10 aspiration hazard Cat. 1 (Asp. Tox. 1) H304Remarks


2.2 Label elementsLabelling acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)Signal word DANGERPictogramsGHS08

Hazard statementsH227 Combustible liquid.H304 May be fatal if swallowed and enters airways.

Precautionary statementsPrecautionary statements - preventionKeep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.Keep container tightly closed.Wear protective gloves/eye protection/face protection.


Safety Data Sheet Volatile SolventRevision date: 06/01/2015


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This material is combustible, but will not ignite readily.




If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. Providefresh air.





none

IF SWALLOWED: Immediately call a POISON CENTER/doctor/physician.Do NOT induce vomiting.In case of fire: Use sand, carbon dioxide or powder extinguisher to extinguish.


Hazardous ingredients for labelling C12-C14 isoalkanes2.3 Other hazards


3.1 Substances

3.2 Mixtures3.2.1


C12-C14 isoalkanes CAS No68551-19-9

100






Following ingestion





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water jet







Covering of drains.






















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No data available.



Warning








8.1 Control parametersNational limit valuesOccupational exposure limit values (Workplace Exposure Limits)Relevant DNELs/DMELs/PNECs and other threshold levels



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9.1 Information on basic physical and chemical propertiesAppearancePhysical state liquidColor differentOdor characteristicOther physical and chemical parameterspH (value) not determinedMelting point/freezing point <-114 °C at 1 atmInitial boiling point and boiling range 189 °C at 1 atmFlash point 61.1 °C at 1 atmEvaporation rate not determinedFlammability (solid, gas) not relevant (fluid)Explosive limits not determinedVapor pressure not determinedDensity not determinedRelative density not determinedSolubility(ies) not determinedAuto-ignition temperature not determinedViscosity not determinedExplosive properties noneOxidizing properties none



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risk of ignition





strong shocks







Shall not be classified as seriously damaging to the eye or eye irritant.




10.1 Reactivity

• if heated
















Carcinogenicity • National Toxicology Program (United States): none of the ingredients are listed • IARC Monographs none of the ingredients are listed



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May be fatal if swallowed and enters airways.













Aspiration hazard


12.1 Toxicity

Biodegradation










Remarks



Class -


goods regulations)



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Chronic / None.

Health 0 No significant risk to health.




-

NFPA® 704


Description


Health 0 Material that, under emergency conditions, would offer no hazard beyond that of ordinarycombustible material.


Special hazard

Relevant European Union (EU) safety, health and environmental provisionsClassification according to GHS (1272/2008/EC, CLP)Hazard class Category Hazard class and categoryaspiration hazard 1 (Asp. Tox. 1)



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IARC Mono-graphs




NPCA-HMIS®III









H227 combustible liquid

H304 may be fatal if swallowed and enters airways

Disclaimer



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Documents

Safety Data Sheet: Absorbent PowderFlammability (solid, gas) Explosion limits of dust clouds not determined Vapor pressure not determined Density not determined Relative density not