Module 02_ Explosive Atmospheres September 2007

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    ExplosiveAtmospheres

    Overview

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    Two types of explosions

    Deflagration: Burns with great heat and light.

    Flame front speed 1 m/sec

    Speed of sound 330 m/sec

    Detonation: A violent explosion

    Flame front speed 2000-8000 m/sec

    Speed of sound 330 m/sec

    Deflagration and Detonation

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    Explosion Properties

    Fuel

    Oxygen

    Ignition source

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    Explosion Properties

    All flammable gases, vapours and mists require to be

    mixed with oxygen to make them burn. There is about20-21% of oxygen in the air we breath. Mixtures of aflammable gas and certain percentages of air will burn ifignited.

    Too much or too little oxygen, the mixture will not ignite.The upper and lower concentrations of gas in

    atmospheric air, by volume, are known as theirflammability or explosive limit.

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    Flammable Range All dangerous substances have a flammable

    range

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    Flammable Range

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    Examples of Flammable Range(PD IEC 60079-20)

    774Hydrogen1002.3Acetylene

    362.3Ethylene111.7Propane

    174.4Methane

    UEL (%)LEL (%)Substance

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    Explosion Properties

    For any mixture of a

    combustible gas orvapour with an oxidizer(air) there is a criticalignition energy.

    Release less than thecritical amount ofenergy into the mixture

    and there will not be anexplosion.

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    At a critical concentration called the mosteasily ignited concentration (MEIC), theamount of energy required to cause ignition isminimal.

    The critical energy at the MEIC is calledminimum ignition energy (MIE).

    Explosion Properties

    MEIC

    MIE

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    477

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    Explosion Properties

    The LEL (LFL) and UEL (UFL) are not inherent

    properties of a combustible mixture. Theirvalues depend on the nature of the experimentby which they are determined.

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    Historical Background

    The first hazardous area was discovered in the

    coal mines.

    This area held a double hazard: methane gas

    (firedamp) and coal dust.

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    Historical Background

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    Historical Background

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    In 1815 Sir HumphreyDavy invented theDavy lamp, whichwas a kerosene lamp

    with a fine brassmesh. This was usedto indicate methane

    concentration in themine atmosphere.

    Historical Background

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    Electrical Equipment

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    This method of

    protection lead tothe development ofthe Flameproof

    (FLP) concept ofprotection

    Ex d.

    Historical Background

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    Historical BackgroundHistorical BackgroundMine explosion in South Wales 1912.

    Cause- a spark generated by the signalling system

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    Historical BackgroundHistorical Background

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    Research at the Mines Research Establishment,Buxton, England that these low voltage circuitswere capable of igniting mine gases, it also ledto new circuit designs in which the stored energywas reduced to a non ignition capable level.

    Historical BackgroundHistorical Background

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    This technique was labelled intrinsic safety Ex

    i and it was the beginning of a new era insafety methods for explosive hazardous areas.

    More on the Ex i concept later.

    Historical BackgroundHistorical Background

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    Gas Group 1(I)

    Explosive Atmosphere

    Gas Group 2 (II)

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    Group I is for mining and not covered further in

    this presentation.

    Group II is for surface industries

    Group II gases is further divided into 3 sub-divisions.

    Explosive Atmosphere

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    IIA, for atmospheres containing propane orgases of an equivalent hazard.

    IIB, for atmospheres containing ethylene orgases of an equivalent hazard.

    IIC, for atmospheres containing hydrogen orgases of an equivalent hazard.

    Explosive Atmosphere

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    Examples of Flammable Range(PD IEC 60079-20*)

    77 IIC4Hydrogen

    100 IIC2.3Acetylene

    36 IIB2.3Ethylene11 IIA1.7Propane

    17 IIA4.4Methane

    UEL (%) GGLEL (%)Substance

    * There are 299 substances listed in PD IEC 60079-20 (Flammable Gas Data).

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    Temperature class

    Equipment is identified with a temperature class

    Identified by a T rating (or by a temperature indegrees C).

    The temperature class identifies the hottest

    temperature that the equipment can obtain innormal operation.

    This can be either the inside or the outside of the

    equipment depending on the protection concept.

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    Temperature ClassThe full list of temperature codes are

    85T6

    100T5

    135T4

    200T3

    300T2

    450T1

    Max Temp limit

    (C)

    Temperature

    Class

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    The temperature codes for the substanceslisted previously (temperature

    classification) are shown below:

    T1Hydrogen

    T2Acetylene

    T2Ethylene

    T1Propane

    T1Methane

    Temp ClassSubstance

    Temperature Class

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    T1 IICHydrogen

    T2 IICAcetylene

    T2 IIBEthylene

    T1 IIAPropane

    T1 IIAMethane

    Temp Class Gas GroupSubstance

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    Equipment Marking

    Example

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    Any Questions