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Hazardous Waste Hazardous Waste ManagementManagement
Environmental Resource CenterEnvironmental Resource Center
Flexible Packaging AssociationFlexible Packaging Association
INTRODUCTIONINTRODUCTION
llBrian KarnofskyBrian Karnofsky
––Environmental Resource CenterEnvironmental Resource Center
llbrianbrian@@ercwebercweb.com.com
ll919919--469469--15851585
llhttp://www.ercweb.comhttp://www.ercweb.com
Material to Be CoveredMaterial to Be Covered
llWhat is Hazardous WasteWhat is Hazardous Waste
llWaste Management OnWaste Management On--sitesite
llPrePre--Transport RequirementsTransport Requirements
llEmergency ResponseEmergency Response
llCommon ProblemsCommon Problems
What IsWhat Is
Hazardous WasteHazardous Waste
Hazardous Waste Hazardous Waste 40 CFR 261
llCharacteristic Characteristic wastewastellListed wasteListed wastellHazardous waste Hazardous waste
mixturesmixturesllTreatment Treatment
residuesresidues
ListedF003
CharacteristicD001
Characteristic WasteCharacteristic Waste
Ignitable Reactive
Corrosive Toxic
Ignitable D001Ignitable D001
ll Liquid with flashpoint less than 140°Liquid with flashpoint less than 140°(except aqueous solutions containing < 24% (except aqueous solutions containing < 24% alcohol)alcohol)
ll NonNon--liquid, capable under standard liquid, capable under standard temperature and pressure, of causing fire temperature and pressure, of causing fire through friction, absorption of moisture or through friction, absorption of moisture or spontaneous chemical change and when spontaneous chemical change and when ignited burns so vigorously and ignited burns so vigorously and persistently it creates a hazardpersistently it creates a hazard
ll Ignitable compressed gases and oxidizers Ignitable compressed gases and oxidizers as defined by DOTas defined by DOT 55--55
IGNITABLE HAZARDOUS WASTE
ENVIRONMENTAL RESOURCE CENTER
COMBUSTIBLE
FLAMMABLE
200° F200° F
60.5°° C (141° F° F)
100° F100° F
140° F140° F
EPAEPA DOTDOT
llAn aqueous material with a An aqueous material with a pH pH << 2 or 2 or >> to 12.5to 12.5
llOr…Or…
Characteristic Hazardous WasteCharacteristic Hazardous Waste
CorrosiveCorrosive D002D002
A liquid that can corrode steel A liquid that can corrode steel at a rate greater than 0.25 at a rate greater than 0.25 inch per year at a inch per year at a temperature of 55temperature of 55°° C (130C (130°° F)F)
Characteristic Hazardous Waste
CorrosiveCorrosive D002D002
Characteristic Hazardous WasteCharacteristic Hazardous Waste
llNormally unstable and reacts Normally unstable and reacts violently without detonatingviolently without detonatingllReacts violently with waterReacts violently with waterllForms an explosive mixture with Forms an explosive mixture with
waterwaterllGenerates toxic gases, vapors, or Generates toxic gases, vapors, or
fumes when mixed with waterfumes when mixed with water
ReactiveReactive D003D003
Characteristic Hazardous WasteCharacteristic Hazardous Waste
ll Contains cyanide or sulfide and generates Contains cyanide or sulfide and generates toxic gases, vapors, or fumes at a pH of toxic gases, vapors, or fumes at a pH of between 2 and 12.5between 2 and 12.5
ll Capable of detonation if heated under Capable of detonation if heated under confinement or subjected to a strong initiating confinement or subjected to a strong initiating sourcesource
ll Capable of detonation at standard Capable of detonation at standard temperature and pressuretemperature and pressure
ll Listed by DOT as 1.1 Listed by DOT as 1.1 –– 1.3 explosive1.3 explosive
ReactiveReactive D003D003
Characteristic Hazardous WastesCharacteristic Hazardous WastesToxicity CharacteristicToxicity Characteristic
EPA HW Regulatory EPA HW RegulatoryNumber Contaminant Level (mg/l) Number Contaminant Level (mg/l)
D004 Arsenic 5.0 D032 Hexachlorobenzene 0.13D005 Barium 100.0 D033 Hexachlorobutadiene 0.5D018 Benzene 0.5 D034 Hexachloroethane 3.0D006 Cadmium 1.0 D008 Lead 5.0D019 Carbon Tetrachloride 0.5 D013 Lindane 0.4D020 Chlordane 0.03 D009 Mercury 0.2D021 Chlorobenzene 100.0 D014 Methoxychlor 10.0D022 Chloroform 6.0 D035 Methyl Ethyl Ketone 200.0D007 Chromium 5.0 D036 Nitrobenzene 2.0D023 o-Cresol 200.0 D037 Pentachlorophenol 100.0D024 m-Cresol 200.0 D038 Pyridine 5.0D025 p-Cresol 200.0 D010 Selenium 1.0D026 Cresol 200.0 D011 Silver 5.0D016 2,4-D 10.0 D039 Tetrachlorethylene 0.7D027 1,4-Dichlorobenzene 7.5 D015 Toxaphene 0.5D028 1,2-Dichloroethane 0.5 D040 Trichloroethylene 0.5D029 1,1-Dichloroethylene 0.7 D041 2,4,5-Trichlorophenol 400.0D030 2,4-Dinitrotolene 0.13 D042 2,4,6-Trichlorophenol 2.0D012 Endrin 0.02 D017 2,4,5-TP (Silvex) 1.0D031 Heptachlor (& its hydroxide) 0.008 D043 Vinyl Chloride 0.2
Listed WasteListed WasteListed Waste
• Spent solvents
• Electroplating
• Wood preserving wastes
• Petroleum refining waste
• Chlorinated aliphatic hydrocarbons
• Dioxin-bearing wastes, pesticide production
•• Spent solventsSpent solvents
•• ElectroplatingElectroplating
•• Wood preserving wastesWood preserving wastes
•• Petroleum refining wastePetroleum refining waste
•• Chlorinated aliphatic Chlorinated aliphatic hydrocarbonshydrocarbons
•• DioxinDioxin--bearing wastes, bearing wastes, pesticide productionpesticide production
Non-Specific Source WastesNonNon--Specific Source WastesSpecific Source Wastes
F List261.30F List
261.30
Degreasing F001Degreasing F001
TetrachloroethyleneTetrachloroethyleneTrichloroethyleneTrichloroethyleneMethyleneMethylene chloridechloride1,1,11,1,1--TrichloroethaneTrichloroethaneCarbon tetrachlorideCarbon tetrachlorideChlorinated fluorocarbonsChlorinated fluorocarbons
Solvents F002Solvents F002
TetrachloroethyleneTetrachloroethyleneMethyleneMethylene chloridechlorideTrichloroethyleneTrichloroethylene1,1,11,1,1--TrichloroethaneTrichloroethaneChlorobenzeneChlorobenzene1,1,21,1,2--TrichloroTrichloro--1,2,21,2,2--trifluoroethanetrifluoroethaneOrthodichlorobenzeneOrthodichlorobenzeneTrichlorofluoromethaneTrichlorofluoromethane1,1,21,1,2--TrichloroethaneTrichloroethane
Solvents F003Solvents F003
XyleneXylene Methyl isobutyl Methyl isobutyl ketoneketoneAcetoneAcetone nn--Butyl alcoholButyl alcoholEthyl acetateEthyl acetate CyclohexanoneCyclohexanoneEthyl benzeneEthyl benzene MethanolMethanolEthyl etherEthyl ether
Solvents F004Solvents F004
CresolsCresolsCresylicCresylic acidacidNitrobenzeneNitrobenzene
Solvents F005Solvents F005
TolueneTolueneMethyl ethyl Methyl ethyl ketoneketoneCarbon disulfideCarbon disulfideIsobutanolIsobutanolPyridinePyridineBenzeneBenzene22--ethoxyethanolethoxyethanol22--nitropropanenitropropane
KK--ListListSpecific Source WastesSpecific Source Wastes
Wood PreservationInorganic PigmentsOrganic ChemicalsInorganic ChemicalsPesticidesExplosivesPetroleum RefiningVeterinary PharmaceuticalsInk Formulation
Wood PreservationInorganic PigmentsOrganic ChemicalsInorganic ChemicalsPesticidesExplosivesPetroleum RefiningVeterinary PharmaceuticalsInk Formulation
Iron and SteelPrimary CopperPrimary LeadPrimary ZincPrimary AluminumFerroalloysSecondary LeadCoking
Iron and SteelPrimary CopperPrimary LeadPrimary ZincPrimary AluminumFerroalloysSecondary LeadCoking
Commercial Chemical Commercial Chemical ProductsProducts
llThe commercial chemical The commercial chemical productproductllOffOff--specification speciesspecification speciesllContainer residueContainer residuellSpill residueSpill residuellWhen used as fuelWhen used as fuelllWhen applied to landWhen applied to land
P LIST
U LIST
PP--LISTLIST
ENVIRONMENTAL RESOURCE CENTER
Haz-ardous waste No.
Chemical abstracts No. Substance
P023 107-20-0 Acetaldehyde, chloroP002 591-08-2 Acetamide, N-aminoP057 640-19-7 Acetamide, 2-fluoroP058 62-74-8 Acetic acid, fluoro-,sodium saltP002 591-08-2 1-Acetyl-2-thioureaP003 107-02-8 AcroleinP070 116-06-03 AldicarbP004 309-00-2 AldrinP005 107-18-6 Allyl alcoholP006 20859-73-6 Alluminum phosphate (R,T)
Regulated Hazardous Waste Regulated Hazardous Waste
llListed wastesListed wastes
llCharacteristic wastesCharacteristic wastes
llWaste mixturesWaste mixtures
llWaste residuesWaste residues
Hazardous Waste MixturesHazardous Waste Mixtures
Listed hazardous waste Listed hazardous waste + “Solid waste” + “Solid waste” = Listed hazardous waste= Listed hazardous waste
Characteristic waste Characteristic waste + “Solid waste” + “Solid waste” = ?= ?
Derived From RuleDerived From Rule
Residue derived from Residue derived from the treatment, storage, the treatment, storage, or disposal of listed or disposal of listed wastewaste
ENVIRONMENTAL RESOURCE CENTER
How to How to Accumulate Accumulate
Hazardous WasteHazardous Waste
ENVIRONMENTAL RESOURCE CENTER
SatelliteSatelliteAccumulationAccumulationPointPoint
AccumulationAccumulationPointPoint
•• Up to 90 DaysUp to 90 Days•• 180 days if SQG180 days if SQG
•• No Volume LimitNo Volume Limit•• No Time LimitNo Time Limit
•• 55 Gallon Limit55 Gallon Limit
Satellite Accumulation PointSatellite Accumulation Point
l An area at or near the point where the waste is initially accumulatedl Under the control of the
operator of the process generating the waste
Satellite Satellite Accumulation PointAccumulation Point
ll 55 gal/1qt of waste in containers55 gal/1qt of waste in containers
llUnlimited timeUnlimited time
Satellite Accumulation PointSatellite Accumulation Point
llIn good conditionIn good conditionllCompatible with the wasteCompatible with the wastellClosedClosedllMarked to identify the contents or Marked to identify the contents or
with the words, “HAZARDOUS with the words, “HAZARDOUS WASTE”WASTE”
Containers Must beContainers Must beContainers Must be
Satellite Accumulation Point Satellite Accumulation Point RequirementsRequirements
llContainers holding Containers holding in in excess of 55 excess of 55 gallonsgallons must be must be marked with the marked with the date the excess date the excess accumulation beganaccumulation began
llRemove excess Remove excess within within three daysthree days
ENVIRONMENTAL RESOURCE CENTER
Satellite Satellite Accumulation PointAccumulation Point
ENVIRONMENTAL RESOURCE CENTER
Accumulation PointAccumulation Point
Accumulation PointAccumulation Point
ll Any volume of waste in tanks Any volume of waste in tanks
or containers or containers
ll Up to 90 days (180 for SQG)Up to 90 days (180 for SQG)
ENVIRONMENTAL RESOURCE CENTER
SatelliteSatellitePointPointAccumulationAccumulation
•• Containers in good Containers in good conditioncondition
•• Compatible w/wasteCompatible w/waste•• Container closedContainer closed•• Mark w/contents or Mark w/contents or ""Hazardous WasteHazardous Waste""
•• No time limitNo time limit•• 55 gallon limit (1 qt 55 gallon limit (1 qt acute)acute)
•• Containers in good Containers in good conditioncondition
•• Compatible w/wasteCompatible w/waste•• Container closedContainer closed••Mark "Hazardous Mark "Hazardous Waste"Waste"
••90 day time limit90 day time limit••Plus...Plus...
Accumulation PointsAccumulation Points
llHandle in a manner to avoid ruptures Handle in a manner to avoid ruptures or releasesor releases
llInspect weeklyInspect weekly
llIgnitable or reactive must be 50 ft. Ignitable or reactive must be 50 ft. inside property boundaryinside property boundary
llSeparate incompatiblesSeparate incompatibles
Regulatory RequirementsRegulatory Requirements
Accumulation PointsAccumulation Points
llDate each containerDate each container
llEmergency equipmentEmergency equipment
llContingency planContingency plan
llTrain personnel exposed to or who Train personnel exposed to or who handle hazardous wastehandle hazardous waste
Regulatory RequirementsRegulatory Requirements
ENVIRONMENTAL RESOURCE CENTER
FIRE
CLAY Absorbent
Accumulation points must be Accumulation points must be equipped withequipped with
llEmergency communication Emergency communication equipmentequipment
ll Fire control equipmentFire control equipment
llSpill control equipmentSpill control equipment
InspectionsInspections
•Inspected by
•Date
•Leaks
•Deterioration
Personnel occupationally Personnel occupationally exposed to or who handle exposed to or who handle
hazardous waste must hazardous waste must receive annual trainingreceive annual training
Hazardous
waste
training
Hazardous
waste
training
llHow to comply with How to comply with regulationsregulations
llHow to implement How to implement emergency response emergency response proceduresprocedures
Training Training RecordsRecords
ll Job titleJob title
ll Job descriptionJob description
ll Training descriptionTraining description
ll Training documentationTraining documentation
PrePre--TransportationTransportation
HazardousWaste
Hazardous Waste Manifest
Placard
MarkingMarking
LabelingLabeling
ENVIRONMENTAL RESOURCE CENTER
Basic DescriptionBasic Description11. US DOT Description
a.
b.
c.
d.
Waste Toxic liquids, n.o.s., 6, UN 2810, PG II (contains 1,1,1-trichloroethane, phenol) ERG 123
(Including Proper Shipping Name, Hazard Class, and ID Number)
Manifest Basic DescriptionManifest Basic DescriptionBlock 11Block 11
llSShipping name (hipping name (colcol 2 of HMT)2 of HMT)
llHHazaz class division or number (class division or number (colcol 3)3)
llIIdentification number (UN/NA: dentification number (UN/NA: colcol 4)4)
llPPacking Group (if any) (acking Group (if any) (colcol 5)5)
–– Example: Waste Acetone, 3, Example: Waste Acetone, 3, UN1090, PGIIUN1090, PGII
ENVIRONMENTAL RESOURCE CENTER
Uniform Hazardous Uniform Hazardous Waste ManifestWaste Manifest
GENERATOR'S CERTIFICATION: I hereby declare that the contents of this consignmentare fully and accurately described above by proper shipping name and are classified,packed, marked, and labeled, and are in all respects in proper condition fortransportation by highway according to applicable international and nationalgovernment regulations.
If I am a large quantity generator, I certify that I have a program in place to reduce thevolume and toxicity of waste generated to the degree I have determined to beeconomically practicable and that I have selected the practicable method of treatment,storage, or disposal currently available to me which minimizes the present and futurethreat to human health and the environment; OR, if I am a small quantity generator, Ihave made a good faith effort to minimize my waste generation and select the best waste management method that is available to me and that I can afford.
16.
Print/Type Name Signature Month Day Year
On or Accompanying ManifestOn or Accompanying Manifest
lEmergency response telephone number
lEmergency response information
ENVIRONMENTAL RESOURCE CENTER
Friday June 1, 1995Friday June 1, 1995
Environmental Protection AgencyEnvironmental Protection Agency
Phase II - Land Disposal Restrictions
Phase II - Land Disposal Restrictions
40 CFR Part 268 et al.40 CFR Part 268 et al.
Land Disposal Land Disposal RestrictionsRestrictions
Emergency RequirementsEmergency Requirements
llContingency planContingency plan–– TSD facilitiesTSD facilities–– Large quantity generatorsLarge quantity generators
llPreparedness and preventionPreparedness and prevention–– TSD facilitiesTSD facilities–– Large quantity generatorsLarge quantity generators–– Small quantity generatorsSmall quantity generators
Preparedness and PreventionPreparedness and Prevention
ll Internal communication Internal communication equipmentequipmentllMeans of summoning Means of summoning
outside assistanceoutside assistancell Emergency response Emergency response
equipmentequipmentll Decontamination equipmentDecontamination equipmentllWater (vol. and pressure) for Water (vol. and pressure) for
above equipmentabove equipment
Mike F
Preparedness and Preparedness and PreventionPrevention
llAccess to emergency equipmentAccess to emergency equipmentllAisle space for emergency Aisle space for emergency
equipmentequipment
•• Make and document Make and document emergency assistance emergency assistance agreementsagreements
ENVIRONMENTAL RESOURCE CENTER
FIRE
CLAY Absorbent
Emergency equipment Emergency equipment must be periodically must be periodically tested and maintained tested and maintained to ensure to ensure proper proper operation in the event operation in the event of an emergencyof an emergency
ENVIRONMENTAL RESOURCE CENTER
Contingency Contingency Plan must listPlan must listlName, lAddress, and lPhone number of
each Emergency Coordinator
Emergency CoordinatorsName Address Phone
1. Jack G Forest Ave. 543-11232. Joe K Lane Dr. 210-12343. Blake M First St. 987-22334. Tracy H Easy St 789-1111
ENVIRONMENTAL RESOURCE CENTER
Describe Describe arrangements arrangements
with with organizations organizations that may be that may be
called upon to called upon to assist in an assist in an emergencyemergency
HOSPITAL
AMBULANCE
ContingencyPlan
GovernmentResponseAgencies
ENVIRONMENTAL RESOURCE CENTER
Emergency Emergency Equipment ListEquipment List
Emergency Equipment
Type of equipmentType of equipment
LocationLocation
DescriptionDescription
CapabilitiesCapabilities
What
Where
Capabilities
Evacuation PlanEvacuation Plan
llEvacuation signalsEvacuation signalsllPrimary evacuation Primary evacuation
routesroutesllAlternate evacuation Alternate evacuation
routesroutes
Emergency ProceduresEmergency Procedures
llHow you will respond to a HW spill, How you will respond to a HW spill, fire or explosionfire or explosionllWho will respond?Who will respond?llWhat procedures will they follow?What procedures will they follow?llWill they respond differently for Will they respond differently for
different wastes or in different different wastes or in different waste accumulation or waste accumulation or management areas?management areas?
Universal WasteUniversal Waste
llBatteriesBatteries
llThermostatsThermostats
llPesticidesPesticides
llLampsLamps
40 CFR 273 Applies to40 CFR 273 Applies to
llGenerators, transporters, Generators, transporters, TSDsTSDs
llDo not count universal wastes Do not count universal wastes in generator statusin generator status
SQHUWsSQHUWs
llSmall quantity handler of Small quantity handler of universal wasteuniversal waste
llUp to 5,000 kg at any timeUp to 5,000 kg at any time
ll§273 Subpart B§273 Subpart B
LQHUWsLQHUWs
llLarge quantity handler of Large quantity handler of universal wasteuniversal waste
ll> 5,000 kg at any time> 5,000 kg at any time
ll§273 Subpart C§273 Subpart C
Destination FacilityDestination Facility
llHW TSD facilityHW TSD facilityllPermit or interim statusPermit or interim status
Handler Requirements Handler Requirements (L and S)(L and S)
llMay not treat or disposeMay not treat or disposellShip toShip to
––S or LQHUWS or LQHUW––TSDTSD––Foreign destinationForeign destination
Handler Requirements Handler Requirements (L and S)(L and S)
ll Label units or containersLabel units or containers–– Universal waste Universal waste -- batteriesbatteries–– Waste batteriesWaste batteries–– Used batteriesUsed batteries
ll Replace “batteries” with Replace “batteries” with –– Thermostats, lampsThermostats, lamps
ll Label pesticidesLabel pesticides–– Original label, DOT label, or Original label, DOT label, or
label approved by pesticide label approved by pesticide collection programcollection program
Handler StorageHandler Storage
llUp to 1 year from Up to 1 year from date it becomes UWdate it becomes UWllProve you store for Prove you store for
less than 1 yearless than 1 year–– LabelLabel–– MarkMark–– Other methodOther method
Handler RequirementsHandler Requirements
llMinimize releases to environmentMinimize releases to environment
llKeep containers Keep containers closedclosed, good , good conditioncondition
llContain releasesContain releases
ll If releases are HW, manage per §260If releases are HW, manage per §260--272272
LQHUW RequirementsLQHUW Requirements
llRegister with EPARegister with EPA
llReceive ID number prior to storing Receive ID number prior to storing 5,000 kg5,000 kg
–– Ensure employees are “thoroughly Ensure employees are “thoroughly familiar with waste handling and familiar with waste handling and emergency procedures relative to emergency procedures relative to their responsibilities during normal their responsibilities during normal facility operations and facility operations and emergencies”emergencies”
SQHUW Training SQHUW Training RequirementRequirement
llInform of waste handling Inform of waste handling and emergency proceduresand emergency procedures
Questions?Questions?
llbrianbrian@@ercwebercweb.com.com
llhttp://www.http://www.ercwebercweb.com.com
ll919919--469469--1585 x 2391585 x 239