Phase IngredientNonionic

Emulsifier Pellicer

Oil GLYCERYL STEARATE 1 -

CETETH-20 1 -

SORBETH-40 TETRAOLEATE 0.5 -

CETYL ETHYLHEXANOATE 7 7

BEHENYL ALCOHOL 5 5

ETHYLHEXYL METHOXYCINNAMATE 6 6

BENZOPHENONE-3 2 2

AqueousPellicer LB-10

- 1.0

(Solid 0.1)

2% Carbopol 981 aqueous solution 15 15

WATER The rest The rest

Neutralizer 30w/v% NaOH 0.36 0.36

Nonionic Emulsifier Pellicer

initial 1month@50C

initial 1month@50C

Appearance Good Good Good Good

Particle diameter(um) 8.1 6.8 14.5 15.4

Viscosity (mP・a) 22000 10000 29500 36000

Example for use as emulsifier

Non-tacky water repelling O/W sunscreen formulation

Unique sensory profile and water repellency can be obtained by the use of Pellicer.

Directions for use

1. Low HLB emulsifiers are recommended as co-emulsifier.High HLB emulsifiers reduce waterproof property.

2. Please add Pellicer in water phase.3. Please add oil phase into water phase with homogenizing.4. We recommend the use of homogenizer at least 5000rpm (100g scale).

Pellicer as the primary emulsifier in O/W emulsions results in superior stability and sensory including more slip, shorter playtime, and reduced tack and drag when compared to an traditional emulsifier.

<Formulation example> O/W Sunscreen

2

Example for use as emulsifier and disperser

Non-tacky water repelling O/W foundation (ITT treatment pigment)

Procedure

<Formulation example> Water repelling O/W foundation

Phase No. Ingredient %

Dispersionphase

1 TiO2 *1 7.46

2 IRON OXIDES (Yellow) *1 1.49

3 IRON OXIDES (Red) *1 0.75

4 IRON OXIDES (Black) *1 0.30

5 TALC*1 1.00

6 Pellicer L-30 1.50

7 WATER 37.00

8AMMONIUM ACRYLOYL DIMETHYLTAURATE/ CARBOXYETHYL ACRYLATE CROSSPOLYMER

0.50

Emulsionphase

9 MINERAL OIL 6.67

10 ETHYLHEXYL PALMITATE 6.67

11 CYCLOPENTASILOXANE 6.67

12 XANTHAN GUM (2% aq.) 15.00

13 Pellicer L-30 0.05

14 WATER 14.95

Microscope image ofO/W foundation

Hydrophobic pigments don’t existin oil phase so that wider choiceof oil type and decreasing uselevel of oil are allowed.

Stability: stable at 50C after 1month

*1: ISOPROPYL TITANIUM TRIISOSTEARATE treatment

3

<Step2: Emulsion phase>1. Mix 9,10,11. (B)2. Mix 12,13,14. (C)3. Add B into C with homogenizer 5000rpm*5min

<Step1: Dispersion phase>1. Mix 1,2,3,4,5,8. (A) Please add 8 at this step. It makes easy to wet the pigments at next step.2. Add A to mixture of 6 and 7 slowly with disperser 500rpm.3. Agitate it with disperser 1500rpm*10min.4. Agitate it with homogenizer 8000rpm*20min.

<Step3: Mixing two components>1. Mix two components. Dispersion phase: Emulsion phase = 1:1

Example for use as emulsifier and disperser

Non-tacky water repelling O/W foundation (Silicone treatment pigment)

<Formulation example> Water repelling O/W foundation

*1: HYDROGEN DIMETHICONE treatment

4

Phase No. Ingredient %

Dispersionphase

1 TiO2 *1 9.0

2 IRON OXIDES (Yellow) *1 0.5

3 IRON OXIDES (Red) *1 0.5

4 Pellicer L-30 1.5

5 WATER 37.0

6AMMONIUM ACRYLOYL DIMETHYLTAURATE/ CARBOXYETHYL ACRYLATE CROSSPOLYMER

1.5

Emulsionphase

7 DIMETHICONE 7.5

8 GLYCERYL STEARATE 0.25

9 MYRISTYL ALCOHOL 2.5

10 Pellicer L-30 0.17

11 WATER 39.58

Stability: stable at 40C after 2month

<Step1: Dispersion phase>1. Mix 1,2,3,6. (A) Please add 6 at this step. It makes easy to wet the pigments at next step.2. Add A to mixture of 4 and 5 slowly with disperser 500rpm.3. Agitate it with disperser 1500rpm*10min.4. Agitate it with homogenizer 8000rpm*20min.

Procedure

<Step2: Emulsion phase>1. Mix 10,11, and heat to 80c . (B)2. Mix 7,8,9 at 80c. (C)3. Add C into B with homogenizer 5000rpm*5min.4. Cool down to RT with stirring at 500rpm.

<Step3: Mixing two components>1. Mix two components. Dispersion phase: Emulsion phase = 1:1

Phase IngredientUnstable

O/WWith Pellicer

Oil

GLYCERYL STEARATE 0.1 0.1

CETETH-20 0.1 0.1

SORBETH-40 TETRAOLEATE 0.05 0.05

CETYL ETHYLHEXANOATE 7 7

BEHENYL ALCOHOL 5 5

ETHYLHEXYL METHOXYCINNAMATE 6 6

BENZOPHENONE-3 2 2

Aqueous

Pellicer LB-10 -1.0

(Solid 0.1)

2% Carbopol 981 aqueous solution 15 15

WATER The rest The rest

Neutralizer 30w/v% NaOH 0.36 0.36

Example for use as emulsifier

Unstable emulsion rescue

Pellicer acts as a stabilizing agent in an otherwise unstable O/W emulsion.

Unstable O/W(Nonionic emulsifier: 0.25%) With Pellicer

initial After 1month @50C initial After 1month @50C

Appearance GoodNG

Solid oil precipitatedGood Good

Particle diameter(um) 9.3 9.7 4.6 3.5

Viscosity (mP・a) 34000 28500 18000 20000

With PellicerUnstable O/W

Pellicer has a stabilizing effect on O/W emulsions .

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No.1 (wt%) No.2 (wt%)

Ａ phase

GLYCERYL STEARATE 3 0.75

BEHENYL ALCOHOL 5 1.25

CYCLOPENTASILOXANE 10 10

CETYL DIMETHICONE 3 3

DIMETHICONE,DIMETHICONE/VINYL DIMETHICONE CROSSPOLYMER

3 3

CYCLOPENTASILOXANE, DIMETHICONOL 0.5 0.5

Ｂ phase

Pellicer LB-10(SODIUM DILAURAMIDOGLUTAMIDE LYSINE, BG, WATER)

1 1

GLYCERIN 5 5

BG 5 5

PENTYLENE GLYCOL 1 1

XANTHAN GUM (2% aqueous solution) 10 10

PHENOXYETHANOL 0.5 0.5

ETHYLHEXYLGLYCERIN 0.5 0.5

WATER 52.5 58.5

Viscosity 20,000 10,000

Example for use as emulsifier

High viscosity and non-tacky skin cream containing ‘α-Gel’

• Pellicer forms alpha-crystalline phase (α-gel) with fatty alcohol and water.• α-gel cream with Pellicer provides excellent smooth and non-tacky feeling in spite of high viscosity.• Emulsion viscosity can be controlled easily by changing the use level of Fatty alcohol and Glyceryl

Stearate

Stable at 50C after 1 monthPreparation: 5000rpm 3min at 80C

Ingredients Wt%

GLYCERYL STEARATE 1.5-3.0

Fatty Alcohol 3.0-5.0

Pellicer LB-10(Pellicer L-30)(Solid base)

1.0(0.3)(0.1)

Others The rest

1. Emulsion viscosity can be controlled easily by changingthe use level of Fatty alcohol and Glyceryl Stearate.Recommended combination and use level is as right chart.

2. Any kind of oil can be used.3. Please add Pellicer in water phase.4. We recommend the use of homogenizer at least 5000rpm

(100g scale).

Directions for use

<Formulation example> Silk Touch Skin Cream

6

Pellicer can penetrate into deep portion of hair fiber even with a short treatment time; 1min., and remains in interior portion of hair fiber after water rinsing.

Damaged hairPellicer treatment

(0.1% solid)

After water rinsing

for 3 timesPellicer repairs damage on hair surface and in hair interior portion.

Damaged hair Pellicer treatment (0.1% solid)

As damage repair agent for hair

Pellicer repairs not only surface damage but internal structure.

Break strength recovery

Rel

ativ

est

ren

gth

(%vs

hea

lth

yh

air)

• Hair is treated with a leave-on, aqueous solution of the test articleprior to evaluation.

• Data shows that 0.01% Pellicer 0.01% (0.1% LB-10) is optimal for aleave-n treatment.

As damage repair agent for skin

Pellicer penetrates into stratum corneum and repairs skin damage.

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Trade name PellicerTM L-30 PellicerTM LB-10 PellicerTM LB-30G

INCI name

(Concentration %)

Sodium Dilauramidoglutamide

Lysine (29%),

Water (71%)

Sodium Dilauramidoglutamide

Lysine (10%),

Butylene Glycol (10%),

Water (80%)

Sodium Dilauramidoglutamide

Lysine (27%),

Butylene Glycol (6%),

Water (67%)

Origin Only plants Butylene Glycol is synthetic. Only plants

Packaging 18kg can, 1kg can 18kg can, 1kg can 18kg can

Manufactured by

ASAHI KASEI FINECHEM CO., LTD. Mail : afc_amino@om.asahi-kasei.co.jpWebsite : www.asahi-kasei.co.jp/fsd/en

Regulatory correspondence status

Area Regulation Status as of Oct 28, 2015.

EU REACH Registered. Tonnage band (1-10t/y).

CHINA IECSC Permission on importation granted under “low volume exemption” scheme. Tonnage

band: <1t as solid/y * 3 importers = Less than 3 t/y

CFDA INCI name of Pellicer is listed on “Inventory of Existing Cosmetic Ingredient in China” on June 30,2014.

US TSCA Registered.

CANADA NSNR *New

Substance Notification

Regulation

Listed on NDSL.

Annual tonnage band is not more than 1000kg as solid per 1importer.

AUSTRALIA AICS Not registered.

SWISS ChemG Not registered.

JAPAN JSQI *Japanese

Standards for Quasi-

drug Ingredients

Registered.

Category : “Medicinal cosmetics” , “Perming agent” “Hair-coloring agent”, “Hair

growth tonic” and “medicinal toothpaste”.

Maximum dosage allowed: 0.35% as L-30.

Grade lineup

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