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Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 • Atoms, Molecules, and Life

Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

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Page 1: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

Copyright © 2005 Pearson Prentice Hall, Inc.

Chapter 2

• Atoms, Molecules, and Life

Page 2: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life
Page 3: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

Copyright © 2005 Pearson Prentice Hall, Inc.

2.1 What Are Atoms?

• 2.1.1 Atoms, the Basic Structural Units of Matter, Are Composed of Still Smaller Particles– Figure 2.1 Atomic models (p. 22) – Table 2.1 Common Elements Important in

Living Organisms (p. 22) – Figure E2.1 How positron emission

tomography works (p.23)

Page 4: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

Helium (He)

nn

Hydrogen (H)

electronshell

nucleus

e-

p+ p+

p+

e-

e-

Page 5: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

Hydrogen (H)

electronshell

nucleus

e-

p+

Page 6: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

Helium (He)

nn

e-

p+

p+

e-

Page 7: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life
Page 8: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

Copyright © 2005 Pearson Prentice Hall, Inc.

2.1 What Are Atoms?

– 2.1.1.1 Electrons Orbit the Nucleus at Fixed Distances, Forming Electron Shells That Correspond to Different Energy Levels

• Figure 2.2 Electron shells in atoms (p. 24)

Page 9: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

Carbon (C) Oxygen (O) Phosphorus (P) Calcium (Ca)CaOC P

4e– 6e–

5e–

2e–

8e–

8e–

8e–

2e– 2e–

2e–

2e–

6p+ 8p+ 15p+ 20p+6n 8n 16n 20n

Page 10: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

Copyright © 2005 Pearson Prentice Hall, Inc.

2.2 How Do Atoms Interact to Form Molecules?

• 2.2.1 Atoms Interact with Other Atoms When There Are Vacancies in Their Outermost Electron Shells

• 2.2.2 Charged Atoms Called Ions Interact to Form Ionic Bonds– Figure 2.3 (Hide/Reveal) The formation of

ions and ionic bonds (p. 25)

Page 11: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

Sodium atom (neutral)

Na

17p+11p+11n

11p+

11n

Chlorine atom (neutral)

18n

17p+

18n

Cl

Sodium ion (+) Chloride ion (–)

Cl–

Cl–

Na+

Na+

An ionic compound: NaCl

Page 12: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

Sodium atom (neutral)

Na

17p+11p+11n

Chlorine atom (neutral)

18n

Cl

Page 13: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

11p+11n

17p+18n

Sodium ion (+) Chloride ion (–)

Cl–Na+

Page 14: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

Cl–

Na+

An ionic compound: NaCl

Page 15: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

Copyright © 2005 Pearson Prentice Hall, Inc.

2.2 How Do Atoms Interact to Form Molecules?

• 2.2.3 Uncharged Atoms Can Become Stable by Sharing Electrons, Forming Covalent Bonds– Figure 2.4 Covalent bonds involve shared

electrons (p. 26) – Table 2.2 Chemical Bonds (p. 26)

Page 16: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

Nonpolar covalent bonding Polar covalent bonding

Water (H–O–H or H2O)

Hydrogen (H–H or H2)

Oxygen (O=O or O2)

(slightly negative)

(slightly positive)

8p+8n

8p+8n

8p+8n

Page 17: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life
Page 18: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

Copyright © 2005 Pearson Prentice Hall, Inc.

2.2 How Do Atoms Interact to Form Molecules?

– 2.2.3.1 Most Biological Molecules Utilize Covalent Bonding

• Unnumbered Figure 3 Bonding Patterns of Atoms Commonly Found in Biological Molecules (p. 27)

• Table 2.3 Bonding Patterns of Atoms Commonly Found in Biological Molecules (p. 27)

Page 19: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

Copyright © 2005 Pearson Prentice Hall, Inc.

2.2 How Do Atoms Interact to Form Molecules?

– 2.2.3.2 Electron Sharing Determines Whether a Covalent Bond Is Nonpolar or Polar

– 2.2.3.3 Free Radicals Are Highly Reactive and Can Damage Cells

• 2.2.4 Hydrogen Bonds Are Weaker Electrical Attractions Between or Within Molecules with Polar Covalent Bonds– Figure 2.5 Hydrogen bonds (p. 28)

Page 20: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

O(–)

H(+)

hydrogrenbonds

H(+)

H(+)

H(+)

O(–)

Page 21: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

Copyright © 2005 Pearson Prentice Hall, Inc.

2.3 Why Is Water So Important to Life?

• 2.3.1 Water Interacts with Many Other Molecules– Figure 2.6 Water as a solvent (p. 29) – Figure 2.7 Water dissolves many biological

molecules (p. 29)

Page 22: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

Cl–

Cl–

Na+

Na+

Na+

H

H

H

H

O

O–

Page 23: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

hydrogen bond

hydroxylgroup

glucose

water

Page 24: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

Copyright © 2005 Pearson Prentice Hall, Inc.

2.3 Why Is Water So Important to Life?

• 2.3.2 Water Molecules Tend to Stick Together– Figure 2.8 Cohesion among water

molecules (p. 30) – Unnumbered Figure 1 Ionization of Water

(p. 30)

Page 25: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life
Page 26: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

O O

hydrogen ion(H+)

hydroxide ion(OH–)

water(H2O)

+(+)

(–)

H H H

H

Page 27: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

Copyright © 2005 Pearson Prentice Hall, Inc.

2.3 Why Is Water So Important to Life?

• 2.3.3 Water-Based Solutions Can Be Acidic, Basic, or Neutral– Figure 2.9 The pH scale (p. 31) – Unnumbered Figure 2 Comparison of liquid

and solid phases of water (p. 32)

Page 28: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

1-molar hydrochloricacid (HCI)

stomach acidlime juice

lemon juice

"acid rain" (2.5–5.5)vinegar, cola, orange juice,tomatoes

beer

black coffee, tea

normal rain (5.6)urine (5.7)

pure water (7.0)salivablood, sweat (7.4)

seawater (7.8–8.3)

baking soda

phosphate detergentschlorine bleachmilk of magnesia

household ammoniasome detergents(without phosphates)

washing soda

oven cleaner

1-molar sodiumhydroxide (NaOH)

0

1

2

3

4

5

6

7

8

9

10

11

12

13

14

pHvalueH+ concentration

(moles/liter)100

10–1

10–2

10–3

10–4

10–5

10–6

10–7

–6

–7

–8

–9

–10

–11

–12

–13

–14

10–8

10–9

10–10

10–11

10–12

10–13

10–14

neutral

(H+ = OH–)

incr

easi

ngly

aci

dic

(H+ >

OH

– )in

cre

asi

ng

ly b

asi

c (

H+ <

OH

– )

Page 29: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

1-molar hydrochloricacid (HCI)

stomach acidlime juice

lemon juice

"acid rain" (2.5–5.5)vinegar, cola, orange juice,tomatoes

beer

black coffee, tea

normal rain (5.6)urine (5.7)

0

1

2

3

4

5

6

pHvalue

H+ concentration(moles/liter)

100

10–1

10–2

10–3

10–1

10–5

10–6

incr

easi

ngly

aci

dic

(H

+ >

OH

– )

Page 30: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

incr

easi

ngly

bas

ic (

H+ <

OH

–)

pure water (7.0)alivablood, sweat (7.4)

seawater (7.8–8.3)

baking soda

phosphate detergentschlorine bleachmilk of magnesia

household ammoniasome detergents(without phosphates)

washing soda

oven cleaner

1-molar sodiumhydroxide (NaOH)

7

8

9

10

11

12

13

14

10–7

10–8

10–9

10–10

10–11

10–12

10–13

10–14

neutral(H+ = OH–)

Page 31: Copyright © 2005 Pearson Prentice Hall, Inc. Chapter 2 Atoms, Molecules, and Life

Copyright © 2005 Pearson Prentice Hall, Inc.

2.3 Why Is Water So Important to Life?

– 2.3.3.1 A Buffer Helps Maintain a Solution at a Relatively Constant pH

• 2.3.4 Water Moderates the Effects of Temperature Changes

• 2.3.5 Water Forms an Unusual Solid: Ice– Figure E2.2 Chocolate (p. 33)