Upload
dangtruc
View
215
Download
2
Embed Size (px)
Citation preview
!!H2S!is!more!volatile!than!H2O!because:!H2O!(hydrogen!bonds)!has!stronger!intermolecular!forces!than!H2S!(dipolePdipole!interactions)!!CH3OH!is!more!volatile!than!H2O!because:!H2O!(two!hydrogen!bond!making!dipoles)!has!stronger!intermolecular!forces!than!CH3OH!(one!hydrogen!bond!making!dipoles)!!CH3OH!is!more!volatile!than!CH3CH2OH!because:!each!has!one!hydrogen!bond!making!dipoles,!but!CH3CH2OH!has!more!atoms,!so!it!has!stronger!London!dispersion!forces!(stronger!intermolecular!forces)!!
!!
1. each!has!dipoles!that!can!make!hydrogen!bonds,!but!the!electronegativity!of!O!in!water!!is!higher!H2O!than!the!electronegativity!of!N!in!ammonia!NH3!!
2. water!has!stronger!intermolecular!forces,!therefore,!requires!more!energy!for!vaporization,!therefore,!the!boiling!point!of!water!is!higher!
!
!!!dimethyl!ether!is!nonPpolar,!it's!intermolecular!forces!are!London!dispersion!forces!ethyl!alchohol!is!polar,!its!intermolecular!forces!are!hydrogen!bonds,!which!are!stronger!therefore,!ethyl!alcohol!is!less!volatile!and!dimethyl!ether!is!more!volatile!therefore,!ethyl!alcohol!has!a!higher!boiling!point!and!dimethyl!ether!has!a!lower!boiling!point!!!