Calibration and Reference Samples

Calibration, Reference and Validation Samples for

AC SIMDIS D 2887

Box no. Sample no. Sample name

25950.150 59.50.400 Calibration sample

25650.150 56.40.400 Reference sample

20001.130 00.02.010 SST SD Naphtha

20001.131 00.02.011 SST SD Jet Fuel

For reordering samples use the boxno. mentioned above

AC Analytical Controls BV

Innsbruckweg 35 3047 AG Rotterdam

The Netherlands Phone: +31-(0)10-462 4811

Fax: +31-(0)10-4626330 E-mail: [email protected]

PAC LP 8824 Fallbrook Dr.

Houston, Texas 77064 USA

Phone: +1-281 940 1803 Fax: +1-281 580 0719

E-mail: [email protected]

AC Analytical Controls Asia Pacific Pte Ltd

61, Science Park Road, #03-09/10 The Galen, Singapore Science Park III, Singapore 117525 Phone: +65-6412 0890 Fax. +65-6412 0899 E-mail: [email protected]

Revised, October 2011

mailto:[email protected]



2

3

Index Page

Sample verification 5

Calibration sample SIMDIS D 2887 Box no. 25950.150 6

Reference sample SIMDIS D 2887 Box no. 25650.150 10

Site Specific Sample SIMDIS D 2887 Naphtha

Box no. 20001.130 13

Reference sample SIMDIS D 2887 Jet Fuel Box no. 20001.131 16

Material safety data sheet 19

4

Expiry date samples

Box no. Sample no. Sample name Date prepared

Date expired

25950.150 59.50.400 Lot No. 011

Calibration sample Oct 2011 Oct 2016

25650.150 56.40.400 Lot No. 013

Reference sample May 2011 May 2016

20001.130 00.02.010 Lot No. 004

QC SD Naphtha Aug 2009 Aug 2014

20001.131 00.02.011 Lot No. 005

QC SD Jet Fuel July 2011

July 2016

For reordering samples, use the boxno. of the sample mentioned above

5

Sample verification Each AC standard is carefully manufactured and shipped using our high quality procedures. A sample booklet is included with the standards and contains detailed chromatographic information about the sample. To overcome any wrong interpretation of the results it is necessary to check your actual AC standard run performed on site with the example chromatogram in the booklet. If any discrepancy is found, we advise you to contact AC before continuing analyzing your samples.

Incorporated standard test methods All information in this sample booklet is also applicable for the following standard methods: ASTM 2887 IP 406 DIN 51435 ISO 3924 UOP 621

WARNING - Carbon disulfide (CS2) is highly toxic. Use this chemical only in a fume hood. Avoid inhaling fumes. CS2 is easily absorbed through the skin. Avoid contact with any part of the body. WARNING - Carbon disulfide (CS2) is extremely flammable. The flash point of CS2 is very low: -30 °C. Fumes and vapors are heavier than air and will travel long distances. Do not use CS2 near open flames, sparks or other sources of heat. Do not use open containers or vials of CS2 near hot injectors or detectors on the gas chromatograph. WARNING - Light hydrocarbons are toxic. Avoid inhaling fumes and contact with any Part of the body. WARNING - Light hydrocarbons are extremely flammable. The fumes and vapors from light hydrocarbons are easily ignited. Keep this material away from flames, sparks or other sources of heat. CAUTION - Carbon disulfide (CS2) has a very low boiling temperature: 45 °C. When storing or working with CS2 never expose a container or vial containing CS2 to temperatures above 45 °C. CAUTION - The broken glass ampoule has sharp edges which may cause cuts to the skin. Take care when breaking the top of this ampoule.

6

Calibration sample SIMDIS D 2887 Box no. 25950.150

Sample information

This boiling point calibrant is shipped as a concentrated liquid suspension of normal alkanes with a weight of approximately 0.8 g. Prior to use the suspension requires dilution with carbon disulfide (CS2). Please use the injection volume table on page 7 to determine the correct dilution ratio.

Storage instructions Store the boiling point calibrant at room temperature prior to preparation. Do not heat the concentrated liquid suspension. Store at room temperature.

Sample preparation

NOTE - Carbon disulfide evaporates very quickly. Handle only one vial at a time and seal the vial immediately after preparation.

Take a 2 ml ampoule with the C5-C44 calibration blend.

Pour the contents of the 2 ml ampoule into the 20 ml bottle.

Add the appropriate amount of CS2 to this bottle. See the injection volume table for the recommended sample dilution.

Seal the bottle tightly.

Shake the bottle and heat the solution up to 40 °C to dissolve the n-alkanes.

Put 1.5 ml of this calibration blend into a 2 ml sample vial using a Pasteur pipette.

Place the vial in the desired position of the automatic liquid sampler tray.

7


Injection volume table Mode GC Column

Type Film Diameter

Calibrant Weight

Solvent Weight

Mass%

Injection Volume

Ordering info 7” cage


2887 packed

packed column

0.80 g 15 g 5 % 0.5 µl 40.01.080 n.a.

2887 cap

5 m x 0.53 mm ID

2.65 µm 0.80 g 15 g 5 % 0.1-0.2 µl 24001.070 21074.008

Fast 2887

10m x 0.53 mm ID

0.88 µm 0.80 g 15 g 5 % 0.1-0.2 µl 24001.075 10.74.007

Accel. 2887

10m x 0.53 mm ID

0.88 µm 0.80 g 15 g 5% 0.1-0.2 µl 21073.118 n.a.

Calibrant concentration table Carbon no. Carbon name Weight %

C5 Pentane 10

C6 Hexane 10

C7 Heptane 10

C8 Octane 7.5

C9 Nonane 7.5

C10 Decane 7.5

C11 Undecane 5

C12 Dodecane 5

C14 Tetradecane 5

C15 Pentadecane 5

C16 Hexadecane 5

C17 Heptadecane 5

C18 Octadecane 2.5

C20 Eicosane 2.5

C24 Tetracosane 2.5

C28 Octacosane 2.5

C32 Dotriacontane 2.5

C36 Hexatriacontane 2.5

C40 Tetracontane 1.25

C44 Tetratetracontane 1.25

8


Boiling point table Carbon no. BP ( C) BP ( F) Carbon no. BP (°C) BP (°F)

1 -162 -259 17 302 576 2 -89 -128 18 316 601 3 -42 -44 20 344 651 4 -0.5 32 22 369 696 5 36 97 24 391 736 6 69 156 26 412 774 7 98 209 28 431 808 8 126 259 30 449 840 9 151 303 32 466 871 10 174 345 34 481 898 11 196 385 36 496 925 12 216 421 38 509 948 13 235 455 40 522 972 14 254 489 42 534 993 15 271 520 44 545 1013 16 287 549

9


Version 8,4,1,4

AC8634 AC8634 1

Sample name : Cal

Acquired on : 7/13/2011 5:20:55 PM Vial : 3

Processed on : 7/14/2011 8:18:39 AM Injection : 1

Sample type : Cal 25950.150 Sample (g) : 0.00000

Method name : AC 8634A-6850 Solvent (g) : 0.00000

Operator : AC ISTD (g) : 0.00000

Sequence name : C:\CHEM32\2\SEQUENCE\D110713D.S

Data File : D110713D\003F0101.D\

0 1 2 3 4 5 6 7 8 9

Retention Time (min)

-2000

0

2000

4000

6000

8000

10000

12000

14000

16000

18000

20000

22000

24000

26000

Sig

nal

C5

- 0

.13

41

C6

- 0

.16

07

C7

- 0

.21

18

C8

- 0

.31

14

C9

- 0

.48

25

C1

0 -

0.7

34

5

C1

1 -

1.0

45

5

C1

2 -

1.3

87

3

C1

4 -

2.0

81

5

C1

5 -

2.4

14

9

C1

6 -

2.7

34

1

C1

7 -

3.0

36

4

C1

8 -

3.3

29

2

C2

0 -

3.8

81

0

C2

4 -

4.8

56

1

C2

8 -

5.6

97

1

C3

2 -

6.4

35

3

C3

6 -

7.0

92

9

C4

0 -

7.6

87

4

C4

4 -

8.2

27

2

Signal: Hydrocarbon - FID1 A,

NOTE - The time scale differs for the different SIMDIS modes.

10

Reference sample SIMDIS D 2887 Box no. 25650.150

Sample information The sample can be determined undiluted.

Storage instructions Store the reference sample at room temperature prior to preparation.


Type Film Diameter

Injection Volume



2887 packed packed column 0.5 µl 40.01.080 n.a.

2887 cap 5 m x 0.53 mm ID 2.65 µm 0.1-0.2 µl 24001.070 21074.008

Fast 2887 10m x 0.53 mm ID 0.88 µm 0.1-0.2 µl 24001.075 10.74.007

Accelerated 2887

10m x 0.53 mm ID 0.88 µm 0.1-0.2 µl 21073.118 n.a.

11


Version 8,4,1,4

AC8634 AC8634 2

Sample name : Bottle 1 50

Acquired on : 5/6/2011 5:51:19 PM Vial : 4

Processed on : 5/6/2011 6:00:27 PM Injection : 1

Data File : D110507\004F0501.D

0 1 2 3 4 5 6 7 8 9

Retention Time (min)

0

2000

4000

6000

8000

10000

12000

14000

16000

18000

20000

22000

24000

Sig

na

l

En

d t

ime

8.1

90

0

IBP

11

4

FB

P 3

75

Signal: Hydrocarbon - FID1 A,


12


Boiling point table

Mass% °C °F

IBP 113.9 237

5 157.6 316

10 172.8 343

20 196.3 385

30 216.3 421

40 235.6 456

50 254.7 490

60 272.4 522

70 292.4 558

80 312.3 594

90 336.3 637

95 352.0 666

FBP 374.6 706

13

Validation Sample SIMDIS D 2887 Naphtha

Box no. 20001.130


Storage instructions Store the Validation SIMDIS naphtha sample in a refrigerator prior to preparation.


Type Film Diameter

Injection Volume




2887 cap 5 m x 0.53 mm ID 2.65 µm 0.1-0.2 µl 24001.070 21074.008

Fast 2887 10m x 0.53 mm ID 0.88 µm 0.1-0.2 µl 24001.075 10.74.007

Accelerated 2887

10m x 0.53 mm ID 0.88 µm 0.1-0.2 µl 21073.118 n.a.

14


Box no. 20001.130


15


Box no. 20001.130

Boiling point table Mass% °C °F Mass% °C °F Mass% °C °F

IBP 67.5 154 34 113.5 237 68 132.5 270

1 74.5 166 35 115.0 239 69 133.0 271

2 83.0 181 36 115.5 240 70 133.5 272

3 86.0 187 37 116.0 241 71 133.5 273

4 88.0 191 38 116.5 242 72 134.0 273

5 91.0 196 39 117.0 243 73 134.5 274

6 93.5 200 40 117.5 243 74 135.0 275

7 97.0 206 41 118.0 244 75 135.5 276

8 98.0 208 42 118.0 245 76 136.5 278

9 98.5 209 43 118.5 246 77 137.0 279

10 99.0 210 44 119.0 246 78 138.0 280

11 99.0 211 45 119.0 247 79 138.5 281

12 101.0 214 46 119.5 247 80 139.0 282

13 102.0 216 47 120.0 248 81 139.5 283

14 102.5 216 48 120.0 248 82 140.0 284

15 102.5 217 49 120.5 249 83 140.0 284

16 103.0 217 50 122.0 251 84 140.5 285

17 103.0 218 51 123.0 254 85 140.5 285

18 103.5 218 52 124.0 255 86 141.0 285

19 103.5 219 53 125.5 257 87 141.0 286

20 104.0 219 54 126.0 259 88 141.0 286

21 104.5 220 55 126.5 260 89 141.5 287

22 106.0 223 56 127.0 260 90 142.0 288

23 107.5 225 57 127.0 261 91 143.0 289

24 109.0 228 58 127.5 261 92 144.0 291

25 110.5 231 59 127.5 261 93 144.5 292

26 111.0 232 60 127.5 262 94 145.0 293

27 111.5 232 61 127.5 262 95 145.5 294

28 111.5 233 62 128.0 262 96 146.5 296

29 112.0 233 63 128.0 262 97 149.5 301

30 112.0 234 64 128.0 263 98 151.5 305

31 112.5 234 65 128.5 263 99 153.5 309

32 112.5 235 66 129.0 264 FBP 159.0 318

33 113.0 235 67 131.0 268

16

Validation Sample SIMDIS D 2887 Jet Fuel

Box no. 20001.131


Storage instructions Store the Validation SIMDIS Jet Fuel sample at room temperature prior to preparation.


Type Film Diameter

Injection Volume




2887 cap 5 m x 0.53 mm ID 2.65 µm 0.1-0.2 µl 24001.070 21074.008

Fast 2887 10m x 0.53 mm ID 0.88 µm 0.1-0.2 µl 24001.075 10.74.007

Accelerated 2887

10m x 0.53 mm ID 0.88 µm 0.1-0.2 µl 21073.118 n.a.

17


Box no. 20001.131


18


Box no. 20001.131

Boiling point table Mass% °C °F Mass% °C °F Mass% °C °F

IBP 131.5 269 34 167.0 333 68 196.5 386

1 133.0 271 35 167.5 334 69 197.0 387

2 137.0 279 36 168.5 335 70 197.5 388

3 139.0 282 37 169.0 336 71 197.5 388

4 140.0 284 38 169.5 337 72 198.0 388

5 142.0 288 39 170.0 338 73 199.5 391

6 143.5 290 40 170.5 339 74 201.0 394

7 144.5 292 41 172.0 342 75 202.0 396

8 145.0 293 42 174.0 345 76 203.0 397

9 146.5 296 43 174.5 346 77 204.0 399

10 148.5 299 44 175.0 347 78 205.0 401

11 151.0 304 45 175.5 348 79 206.5 404

12 151.5 305 46 175.5 348 80 208.0 406

13 152.0 306 47 176.0 349 81 209.0 408

14 152.0 306 48 176.0 349 82 210.5 411

15 152.5 307 49 176.5 350 83 211.5 413

16 152.5 307 50 178.0 352 84 213.5 416

17 153.0 307 51 179.0 354 85 215.0 419

18 154.0 309 52 180.0 356 86 216.5 422

19 155.5 312 53 181.0 358 87 217.0 423

20 157.0 315 54 181.5 359 88 217.5 424

21 157.5 316 55 182.5 361 89 218.0 424

22 159.0 318 56 183.0 361 90 219.5 427

23 159.5 319 57 184.0 363 91 221.0 430

24 160.0 320 58 185.0 365 92 223.0 433

25 160.5 321 59 187.0 369 93 225.0 437

26 161.5 323 60 188.0 370 94 227.5 442

27 162.0 324 61 188.5 371 95 229.0 444

28 162.5 325 62 189.5 373 96 231.0 448

29 163.0 325 63 190.5 375 97 235.0 455

30 164.0 327 64 192.0 378 98 236.5 458

31 165.0 329 65 193.5 380 99 245.0 473

32 165.5 330 66 194.5 382 FBP 253.5 488

33 166.5 332 67 196.0 385

19

Material safety data sheet Section 1 - Manufacturer data Chemical Product Identification: Reference Sample (gas oil) AC Analytical Controls Part Number: 25650.150 Chemical Product Identification: Calibration sample (n-Paraffin mix) AC Analytical Controls Part Number: 25950.150 Chemical Product Identification: Validation SIMDIS Naphtha (Gas oil) AC Analytical Controls Part Number: 20001.130 Chemical Product Identification: Validation SIMDIS Jet Fuel (Kerosine) AC Analytical Controls Part Number: 20001.131

Mixbox 20002.007 contains 1 sample 25650.150 and 1 sample 25950.150 Date MSDS prepared: Revised, Feb 2010 Emergency number: 112

AC Analytical Controls BV Innsbruckweg 35

3047 AG Rotterdam The Netherlands

Phone: +31-(0)10-462 4811 Fax: +31-(0)10-4626330 E-mail: [email protected]

PAC LP 8824 Fallbrook Dr.

Houston, Texas 77064 USA

Phone: +1-281 940 1803 Fax: +1-281 580 0719

E-mail: [email protected]

AC Analytical Controls Asia Pacific Pte Ltd

61, Science Park Road, #03-09/10 The Galen, Singapore Science Park III, Singapore 117525 Phone: +65-6412 0890 Fax. +65-6412 0899 E-mail: [email protected]




20

Section 2 - Chemical identity/hazardous ingredients Calibration Sample SIMDIS D 2887 ( 25950.150) OSHA ACGIH % Mass Chemical Name CAS # PEL/TWA TLV/TWA Mass n-Pentane (n-C5) 109-66-0 600ppm 600ppm 5 n-Hexane (n-C6) 110-54-3 50ppm 50ppm 5 n-Heptane (n-C7) 142-82-5 400ppm 400ppm 5 n-Octane (n-C8) 111-65-9 300ppm 300ppm 5 n-Nonane (n-C9) 111-84-2 200ppm 200ppm 5 n-Decane (n-C10) 124-18-5 ND ND 5 n-Undecane (n-C11) 1120-21-4 ND ND 5 n-Dodecane (n-C12) 112-40-3 ND ND 5 n-Tetradecane (n-C14) 629-59-4 ND ND 5 n-Pentadecane (n-C15) 629-62-9 ND ND 5 n-Hexadecane (n-C16) 544-76-3 ND ND 5 n-Heptadecane (n-C17) 629-78-7 ND ND 5 n-Octadecane (n-C18) 593-45-3 ND ND 5 n-Eicosane (n-C20) 112-95-8 ND ND 5 n-Tetracosane (n-C24) 646-31-1 ND ND 5 n-Octacosane (n-C28) 630-02-4 ND ND 5 n-Dotriacontane (n-C32) 544-85-4 ND ND 5 n-Hexatriacontane (n-C36)

630-06-8 ND ND 5

n-Tetracontane (n-C40) 4181-95-7 ND ND 5 n-Tetratetracontane (n-C44)

7098-22-8 ND ND 5

Chemical Families: Aliphatic Hydrocarbons Chemical Synonyms: NA

Reference Sample SIMDIS D 2887 (25650.150) OSHA ACGIH % Mass Chemical Name CAS # PEL/TWA TLV/TWA Mass Reference gas oil mixture 86290-81-

5 300ppm 300ppm 100

Chemical Families: Hydrocarbons - Chemical Synonyms: NA

Validation SIMDIS Naphtha (20001.130) OSHA ACGIH % Mass Chemical Name CAS # PEL/TWA TLV/TWA Mass Gas oil (crude, heavy vac)

64741-57-7

NA NA 100

Chemical Families: Hydrocarbons - Chemical Synonyms: NA

21

Validation SIMDIS Jet fuel (20001.131) OSHA ACGIH % Mass Chemical Name CAS # PEL/TWA TLV/TWA Mass Kerosine (Petroleum) 8008-20-6 NA NA 100 Chemical Families: Hydrocarbons - Chemical Synonyms: NA

Section 3 – Hazards identification This product is extremely flammable! Danger: Flammable liquid. Causes eye, skin and respiratory tract irritation. Harmful if swallowed Can cause lung damage Can cause liver damage Can cause kidney damage Avoid contact with skin, eyes and clothing. Avoid inhalation of mist / vapours Provide local exhaust ventilation to control vapour / mists. Wear safety goggles Wear chemical resistant gloves Wear protective clothing Eye wash fountains and safety showers must be easily accessible. Carcinogenicity: NTP? (NO) IARC Monographs? (NO) OSHA Regulated? (NO) Inhalation: Harmful if inhaled. Vapor or mist is irritating to the mucous membranes and upper respiratory tract. May produce liver and kidney damage. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, vomiting and central nervous system (CNS) depression. Eye Contact: Vapor or mist is irritating to the eyes. Skin Contact: Causes skin irritation. Ingestion: Harmful or fatal if swallowed. Health Hazard Acute/Chronic: This chemical is an eye and mucous membrane irritant, a central nervous system depressant. Acute exposure causes irritation, gastrointestinal tract discomfort and narcosis. Route(s) of Entry: Inhalation? (Yes) Skin? (Yes) Ingestion? (Yes)

22

Section 4 – First aid measures Inhalation: If inhaled, remove to fresh air. If breathing is difficult, give oxygen. Contact Physician. Eye Contact: Contamination of the eyes should be treated by immediate and prolonged irrigation with copious amounts of water by separating the eyelids with the fingers. Contact Physician. Skin Contact: In case of contact, immediately wash the skin with soap and copious amounts of water. Remove and wash contaminated clothing promptly. Ingestion: Do not induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Contact Physician immediately.

Section 5 – Fire fighting measurements

25650.150 and 25950.150: This product is extremely flammable!

Flashpoint °C

LEL UEL

Calibration sample 25950.150 / Reference sample 2560.150

<-50 1 6

Validation SIMDIS Naphtha 20001.130

>100 0.5 5

Validation SIMDIS Jet fuel 20001.131

38 0.6 6

Extinguishing Media: Carbon dioxide, dry chemical powder, foam or water fog. Mixture will float on water and can reignite on surface. Special Fire Fighting Procedures: Wear full protective clothing and self contained positive pressure breathing apparatus certified by NIOSH when fighting chemically related fires. Unusual Fire and Explosion Hazards: Volatile and highly flammable. Vapor may travel a considerable distance to the source of ignition and flash back. Container explosion may occur under fire conditions.

23

Section 6 – Accidental release measures Personal Precaution procedures to be follows in case of leakage or spill: Evacuate area. Shut off all sources of ignition. Use non sparking tools. Procedures of personal precaution(s) Wear self-contained breathing apparatus, chemical safety goggles, rubber boots and heavy rubber gloves. Methods for cleaning up Cover with absorbent material. Place in covered containers using non-sparkling tools and transport outdoors. Ventilate area and wash spill site after material pickup is complete. Do not empty into drains

Section 7 – Handling and storage Handling Directions for safe handling: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure Storage Conditions of Storage: keep container closed. Keep away from heat, sparks and open flame.

Section 8 – Exposure control / Personal protection Max. Exposure: To the best of our knowledge the maximal acceptable allowance for this product has not been established. Ventilation: Adequate ventilation is required to protect personnel from exposure to chemical vapors exceeding PEL and to minimize fire hazards. Respiratory: Use NIOSH approved respirator equipment. Eyes: Safety glasses are considered minimum equipment. Chemical safety goggles or face shield may be necessary depending on quantity of material and conditions of use. Emergency eye wash fountains should be available in the vicinity of any possible exposure. Skin: Chemical-resistant protective gloves and clothing are recommended. The choice of protective gloves or clothing must be based on chemical resistance and other user requirements. Generally, BUNA-N offers acceptable chemical resistance. Individuals who are acutely and specifically sensitive to this chemical may require additional protective clothing.

24

Section 9 - Physical/chemical data Reference and

Calibration sample 25650.150, 25950.150

Validation SIMDIS Naphtha 20001.130

Validation SIMDIS Jet fuel 20001.131

Special Gravity (H2O=1)

0.85 0.90 0.75 - 0.85

Melting Point (°C) NA NA NA Evaporation rate (n-butyl acetate=1)

< 1 Non volatile NA

Boiling Point (°C) 100-550 350 – 620 150 – 300 Vapor Pressure (mm Hg)

NA NA NA

Vapor Density (Air=1)

< 1 >1 4.7

Solubility in Water Insoluble Insoluble Insoluble Appearance and Odor: 25650.150, 25950.150 Clear to dark amber viscous liquid with an oil like odor 20001.130: Dark brown liquid, petroleum hydrocarbon odour 20001.131 Clear liquid, kerosine odour

Section 10 – Stability and reactivity Stability: Stable: ( X ) Unstable: ( ) Conditions to avoid: Heat, sparks, open flames, open containers and poor ventilation. Incompatibility (materials to avoid): Oxidizing agents. Hazardous Decomposition or By-products: Incomplete combustion may generate carbon monoxide and other toxic materials.

Hazardous Polymerization: May Occur: ( ) Will Not Occur: ( X )

25

Section 11 – Toxicological information Signs and symptoms of exposure:

To the best of our knowledge, the chemical, physical and toxicological properties have not been thoroughly investigated.

Route of Exposure

Skin contact: causes skin irritation.

Skin absorption: May be toxic if absorbed through skin.

Eye contact: Causes eye irritation.

Inhalation: May be harmful if inhaled.

Material may be irritating to mucous membrane and upper respiratory tract.

Ingestion: May be toxic if swallowed.

Section 12 – Ecological information No data available

Section 13 – Disposal considerations Substance Disposal:

Do not empty into drains.

Contact a licensed professional waste disposal service to dispose of this material.

Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable.

Observe all federal, state, and local environmental regulations.

Packaging disposal:

Dispose of the vials to hazardous or special waste collection points.

Section 14 – Transport information By air: The samples are transported as excepted quantity. UN code: UN 3316 Proper shipping name: Chemical kit Class: 9 By Road: The samples are transported as Limited Quantity according special provision 251. UN code UN 3316 Proper shipping name: Chemical kit Class: 9

26

Section 15 – Regulatory information Labeling according to EC directives Hazard symbols F Highly flammable Xn Harmful N Dangerous for the environment R-phrases R11 Highly flammable R38 Irritating to skin R48/20 Harmful: danger of serious damage to health by prolonged exposure through

inhalation R62 Possible risk of impaired fertility R65 Harmful: May cause lung damage if swallowed R67 Vapours may cause drowsiness and dizziness. R51/53 Toxic to aquatic organism, may cause long-term adverse effects in the aquatic

environment. S-phrases S9 Keep container in a well ventilated place. S16 Keep away from sources of ignition S29 Do not empty into drains S33 Take precaution measures against static discharge S36/37 Wear suitable protective clothing and gloves S61 Avoid release to the environment S62 If swallowed, do not induce vomiting: seek medical advice immediately and

show this MSDS

27

Section 16 – Other information Unless otherwise noted, the above information pertains only to the solvent and similar types of components in the sample. When no toxicity data is provided, it is prudent to handle this chemical as hazardous. Furthermore, since individual chemical hypersensitivity cannot be predicted, every chemical should be handled with due respect. Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information of this document is based on the present state of our knowledge and is applicable to the product with regard to the appropriate safety precautions. It does not represent any guarantee to the properties of the product. Ac Analytical Controls BV shall not be held liable for any damage resulting from handling or from contact with the above product. For R&D use only, not for drug, household or other uses.

Key to abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS Chemical Abstract Service IARC International Agency for Research on cancer LEL Lower Exposure Limit NA Not Available ND No Data NE Not Established NIOSH National Institute for Occupational Safety and Health NTP National Toxicology Program OSHA Occupational Safety and Health PEL Permissible Exposure Limit TLV Threshold Limit Value TWA Time Weighted Average UEL Upper Exposure Limit

28

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Copyright This document is property of AC Analytical Controls, Rotterdam, the Netherlands. No part of this document may be reproduced, stored in a retrieval system and/or transmitted in any form without prior written permission of the publisher.

ACG 2123A: 00.01.121

Documents

Calibration and Reference Samples