AppliTek Process Liquids Process Water

Applied Technology. Since 1985.

Analytical Measurements for Process Control

On-line Analyzers Process Liquids � Process Water

| APPLITEK Process Liquids and Process Water | 02

Operational performance

Manufacturing industries are continuously trying to improve performance, efficiency

or safety by means of process control. Suitable analyzer technology is the first step

in order to manage the total package of your assets and can take your process per-

formance to a higher level. High reliability, few installation costs and a reasonable

total cost of ownership are significant savings required by those who run large scale

process operations.

When critical processes depend on critical data, how will you make the right decision?

Operational performance AppliTek analytical packages � Operational performance � AppliTek analytical packages

Push the Boundaries of Critical Parameter Monitoring


Enhanced Process Control

Power generation

• Cooling water

• Boiler feed water

• Recirculation water

• Cogeneration

• Solar thermal energy

Semiconductor

• Wafer clean process

• Plating baths

• Etching baths

• Developer solutions

Automobile

• Phosphating baths

• Etching baths

• Recirculation water

Food & Beverage

• Water content

• Process water

• Sauces & juices

Mining

• Purification process

• Cyanide leaching

• Zinc leaching

• Process water

Desalination & Demineralization

• Organic fouling

• Demineralization process

• Storage and distribution

AppliTek analytical packages: Reliability � Flexibility � Safety � Trustability � Responsibility

The last years AppliTek expanded significantly its portfolio of measurement and monitor-

ing products in order to be able to offer suitable products for nearly every application

with an attractive price-performance ratio. Through continuous innovation and field ex-

perience AppliTek is able to provide you with the latest and most advanced analyzer

equipment designed for 24/7 measurements in your process. Profitable solutions are

available for every production process, sub process and application.

Chemical & Petrochemical

• Vent gas scrubbers

• Liquid soaps

• Acid streams

• Fertilizer production

• Bleach production

• Brine purification

• Sour water strippers

Pulp & Paper

• Pulping liquids

• Treatment baths

Steel & Metal

• Plating baths

• Etching baths

• Scrubber units

• Cokes production

• Process water

Stand-alone and Integrated Analytical Solutions for Manufacturing and Utility Industries


Data exchange - Superv ision tools

Remote screen sharing Plant engineers, maintenance engineers and other authorized

users can remotely take over the analyzer screen (the client)

by means of LAN Ethernet software (such as VNC). Authorized

users can carry out all manual operations and settings from a

remote PC. Conduct trouble-shooting before doing any

physical intervention, grab cross-platform screenshots for

reports or presentations, the possibilities are endless.

System integrated solutions AppliTek manufactures and commissions analyzer shelters

addressing the needs of customers wishing to monitor a

complex set of parameters in a single integrated system. In

that case, data collection is assured inside the shelter and

transmitted through the network or an existing telephone

line. If necessary, a special computer cabinet can be installed

in the control room to protect the main control/visualization

data computer system.

From real-time visualization to trouble-shooting: Full integration and communication of AppliTek process analyzers within industrial production sites and corporate networks.

Control Room

HOST

Industrial grade controllers All AppliTek on-line analyzers (process/water) are equipped

with industrial grade controllers optimized for their tasks. The

colour touch screens (size 10.4” or 5.7”, depending on model)

act as human interfaces with an excellent viewing angle and

swift response to touching. Back-up: all data is automatically

retained in case of power failure.

Flexible communication options All AppliTek process analyzers come with industrial 4-20 mA

outputs, the most common analogue transmission standard

available. Ethernet communication by means of the industry-

standard TCP/IP protocol enables easy and reliable integration

into existing corporate networks. MODBUS interfacing is possi-

ble to assure full integration and communication with distrib-

uted control systems (DCS).


Data exchange - Supervision

Turnkey analysis projects General purpose zone / Ex-proof

Scope of supply: • Analyzers & instrumentation • Sample preconditioning systems • Ventilation/heating/AC • Safeguarding systems • Recovery systems • Data acquisition & control systems • Sample recovery systems • Sample transport lines

• Results, trendings • Logs, alarms • Data graphs • Control & simulation of wet parts • Calibrat ion, val idation programs • Setup (I/O, communication, precondit ioning)

• Results, trendings • Logs, alarms • Calibrat ion, val idation • Setup (I/O, communication, precondit ioning)

CLIENT

PROCESS

TCP / IP LAN

4 - 20 mA industry standard

Screen sharing on remote desktop

System integrated analyzer shelter


Appl iTek Series of xPA Process Analyzers

Single and multi parameter on-line analysis for a multitude of manufacturing industries. Titration � ISE � Colorimetry

AppliTek’s Universal Process Analyzer is the state of the art multi parameter analyzer platform enabling operators

to monitor precisely critical process parameters. The unique

on-line analyzer has been designed to run chemical analysis

on most liquid process samples and outclasses other similar

analyzer designs, thanks to an extended set of analytical and

communication features.

UPA® Universal Process Analyzer

• 10 ¼” color touch screen with excellent graphics for process

follow-up, programming and maintenance

• Digital outputs: up to 24 DO (24 VDC) and 6 DO (220 VAC)

• Digital inputs: up to 8 DI

• Up to 8 analog inputs

• Data logging of 1000 last recorded results

• Complete separation between wet part and electronics

• Data logging of last 30 titration curves (for titrators)

• Multiple streams (up to 8, application depending)

• ATEX configuration in accordance with 94/9/EC directive


IPA® Industrial Process Analyzer

The Industrial Process Analyzer is a single parameter wet-

chemical analyzer with a similar hardware and software architecture

as the Universal Process Analyzer. Providing top quality with an af-

fordable price tag, the system features all relevant smart and auto-

matic functions and proven chemistry methodologies.

• 5 ¾” color touch screen with function buttons

• Digital outputs: up to 12 DO (24 VDC) and 6 DO (220 VAC)

• Digital inputs: up to 2 DI

• Up to 3 analog inputs


• Up to 3 streams

• Complete separation between wet part and electronics

Industrial process liquids

For a complete overview of al l feasible parameters, please see page 8 - 9.

Chemical - Petrochemical 4-tertiary-butylcatechol � Acetic acid � Acidity � Ammonia � Bromine Index Caustic � Chloride � Chlorine � Cyanide � Ethyl acetate � Fluoride � Hardness � Hydroxide � Hypochlorite � Moisture � Phenol � Silica � Sodium � Sodium hydroxide � Sulphate � Sulphide � Sulphuric acid � TMAH � Total Hydrocarbons Semiconductor Acetic acid � Ammonia � Copper � EDTA � Fluoride � Hydrochloric acid � Hydrogen fluoride � Hydrogen peroxide � Total and free acid � Sulphuric acid Pulp & Paper ABC analysis � Acidity � Acrylonitrile � Alkalinity � Bromide � Bromine Index � Calcium � Carbonate � Caustic � Chlorate � Free Chloride � Hydrogen peroxide � Hypochlorite � Lime � pH � Phenol � Sodium hydroxide � Sulphate � Sulphide � Sulphite � Thio cyanate Mining Acidity � Alkalinity � Ammonium � Aluminium � Carbonate � Chloride � Chromic acid � Copper � Cyanide � EDTA � Hydrochloric acid � Iron II � Iron III � Nickel � Silver � Sulphuric acid � Total Cyanide � Zinc

Industries and their typical parameters

Wet chemistry hardware � Standard (all models) Colorimetric configuration: photometer (insensitive to ambient

light) and analysis cuvette with magnetic stirrer

Titrimetric configuration: titration vessel with magnetic stirrer,

precision dispenser, additional electrodes

Ionometric (ion-selective) configuration: analysis vessel with

magnetic stirrer, precision dispenser for standard addition, high

quality ISE electrodes

� Options Smart solutions that reduce unnecessary interventions and

down-times: Leak detection senses any liquid spills in the

wet part of the on-line analyzer and will be recorded and

communicated by the analyzer’s industrial controller.

Sample presence detection can be installed internally or

externally and gives the opportunity to generate alarms to

operators or control centers in case there is no sample.


Appl iTek Series of xPA Process Analyzers

Methodology

Parameter

Titration

Colorimtery

Ion-selective

4-tertiary-butylcatechol � ABC analysis � � Acetic acid � Acidity � Acid number � Acrylonitrile � Active chloride � Aldehyde � Alkalinity � Aluminium � � Aluminium chloride � Ammonia � � Ammonia/Nitrate � � Aniline � Anion active surfactants � Benzoic acid � Bicarbonate � Boric acid � Bromine index � Cadmium � Calcium � � � Calcium oxide � Caprolactam � Carbonate � � Carbon oxide � Caustic � Chemical Oxygen Demand � � Chlorate � � Chloride � � � Chlorine � � Chromium III � � Chromium VI � � Cobalt � Copper � � Cyanide � � � Fatty acids � Fluoride � Formaldehyde � Formic acid � Free Chloride � Free Cyanide � Hardness � Hydrazine � Hydrochloric acid � Hydrogen peroxide � Hydroquinone � Hydroxide � Hydroxylamine �

Methodology

Parameter (continued)

Titration

Colorimtery

Ion-selective

Hypochlorite � Iron II � � Iron III � � Lime � Magnesium � � Metabisulphite � Moisture � Na/P molar ratio � Nickel � � Nitrate � � Nitric acid � Oleum � Ortho-phosphate � Oxalic acid � P&M number � Peracetic acid � Permanganate � Peroxide � Persulphate � pH � Phenol � � Phosphate � � Phosphoric acid � Phthalic acid � Poly vinyl alcohol � Potassium � Potassium hydroxide � Potassium iodate � Potassium iodide � Redox � Silica � Silver � Sodium � Sodium hydroxide � Sodium sulphate � Strontium carbonate � Sulphate � Sulphide � � Sulphite � Sulphonic acid � Sulphuric acid � Thio cyanate � Tin � TMAH � Tri ethyl amine � Tri methyl amine � Uranium � Zinc � �


List of process parameters

Methodology

Total parameters

Titration

Colorimtery

Ion-selective

Total acid �

Total alkalinity �

Total ammonia �

Total chlorine �

Total cyanide �

Total iron �

Total phosphate �

Methodology

Combined parameters *

Titration

Colorimtery

Ion-selective

Acidity and Chloride �

Acidity and Diphosphorous Pentoxide � �

Alkalinity and Calcium � � Aluminium and Sulphuric acid �

Aluminium, Zinc and Sulphuric acid �

Ammonia, Iron II and Iron III �

Ammonia and Sulphide � Ammonia and Hydroxylamine �

Calcium and Magnesium � �

Carbonate and Chloride �

Copper and Sulphuric acid �

Copper, Nickel and Zinc �

Fluoride and pH � � Fluoride, Free acid and Total acid � � Hydroquinone and Peroxide �

Hydroxide and Carbonate �

Na/P ratio and Phosphate �

Na2O and AZ number �

Total and Free acid �

Total and Free ammonia �

Total iron, Iron II and Iron III �

Total chromium, Cr III and Cr VI �

Total and Free chlorine �

Zinc and Sulphuric acid �

* UPA platform only


EnviroLyzer® Series o f On-l ine Water Analyzers

Challenges for water management Managing both quantity and quality of water resources is

a challenging task for companies, utility industries and

authorities. On-line monitoring helps them to measure

quickly and effectively all the relevant parameters in the

water source. AppliTek’s EnviroLyzer® Series of On-line

Water Analyzers are up to these challenges and represent

a multitude of solutions —resulting in an impressive list

of chemical quality indices and equally corresponding

applications.

Single parameter on-line analysis for industrial water applications.

Boiler feed water

On-line analysis is an excellent strategy to obtain chemical control and, in return, optimal efficiency of boiler operation and steam distribution. Typical parameters measured: Chlo-ride, Hydrazine, Phosphate, (low) Sodium, Silica. Microbiological fouling

Microbiological water treatment is frequently applied in refin-eries, power plants, offshore facilities and others. Automatic dosing systems can be controlled by on-line analysis. Other solutions: organics removal can be controlled by means of TOC analysis (see p. 12). Cooling tower make-up water

Proper maintenance and economy of cooling water systems requires a careful balance between water quality parameters and treatment chemicals. Typical parameters are: Alkalinity, Ammonia, Conductivity, Copper, Hardness, Iron. Waste water treatment / recyling

Increased regulations in waste water discharge requires careful management of treatment processes and recycling. Besides basic nutrients (N-P) most chemical parameters can be determined. Other solutions: analysis of organic sum parameters (TOC, BOD, COD).

Applications

Design - Features • Single-parameter, standard single-stream

• Straight-forward design, reduced reagent consumption

• High quality sample pump, micropumps, vessel, tubing

• 5 ¾” color touch screen with function buttons

• Ethernet TCP/IP based connection

• Standard auto-cleaning / auto-validation / auto-calibration


• Complete wet part electronics separation


Process water

Methodology

Parameter

Colorimtery

Ion-selective

Aluminium � Ammonia � � Biocides � Boron � Calcium � Chloride � � Chlorine � � Chlorine dioxyde � Chlorite � Chromium III � Chromium VI � Color � Copper � Cyanide (free) � � Fluoride � Hardness (total) � Hydrazine � Iron II � Iron III � Manganese � Nickel � Nitrate � � Nitrite � Permanganate � Phenol � Phosphate � Silica � Silicium dioxyde � Sodium � Sulphide � � Thio cyanate � Urea � Zinc �

List of water quality indices Our Application department constantly updates the

central database with new applications, making it

one of the most complete available in analytical

chemistry today. In this respect, the EnviroLyzer® Series of On-line Water Analyzers are on top of an

impressive list of chemical quality indices and

equally corresponding applications.

Enclosures & Configurations The EnviroLyzer® Series of on-line Analyzers come standard in a compact dust- and splash-

proof enclosure. Where site-specific requirements

may compromise the analyzer’s potential, optional

enclosures/configurations are available. The “black”

enclosure was designed to protect the analytical

part from harsh environments, high temperature

fluctuations and humidity. For hazardous areas, a

third enclosure in stainless steel is available with all

necessary connections, special analytics and control

units, a stand-alone system factory tested to fully

meet ATEX or NEC 500 directives.


Appl iTOC® Series of On-l ine TOC Analyzers

TOC as a measure of organic load

The AppliTOC® Series of On-line TOC Analyzers enable

continuous and reliable monitoring of organic compounds

in water, by means of the low-temperature UV/persulfate

oxidation method. Automatic smart functions such as auto-

cleaning, as well as programmable auto-calibration and

auto-validation are standard features, controlled by the

AppliTek industrial grade controller. Operation is made

easier, reliable data are assured and unnecessary operator

intervention is minimized.

Application fields • Process effluent monitoring • Water demineralization • Ground water reclamation • Cooling water monitoring

AppliTOC® Series of On-line TOC Analyzers

• True continuous analysis

• High quality sample, transfer and addition pumps for acid and

persulfate, mass flow meter, dual wavelength IR detector

• Compliant with standard methods USEPA 415.2, ISO 8245 and

DIN-EN 1484

• 5 ¾” color touch screen with buttons for immediate access

• Standard auto-cleaning, auto-validation, auto-calibration


• Complete wet part / electronics separation

• Emergency stop


Analytical mainframe: configurations

The AppliTOC® can be delivered with a specific analysis configuration, according to your application. For example: in case of Total Carbon, the acidifying stage is bypassed so the analyzer needs one reagent less. � Total Organic Carbon (standard) Measure-ment of non purgeable organic carbon (NPOC) � Total Inorganic Carbon (TIC) Measurement of inorganic carbon compounds (including volatile organic compounds, VOC) � Total Carbon (TC) Measurement of all carbon compounds (with single IR detector) � True Total Organic Carbon Measurement of TOCTRUE (= TC – TIC, with double IR detector) Several NDIR detectors with excellent linear output are available in order to suit specific water matrices or measuring ranges.

“True” TOC With double NDIR detector

TOC Total Organic Carbon TIC Total Inorganic Carbon TC Total Carbon

Organic Contamination

Performance in a functional package

The on-line analyzer is equipped with precision peristal-

tic pumps, a precision mass flow controller and a user-

friendly industrial computer, packed in an ergonomic

analyzer housing. Purging with instrument air is possible

in case of extreme humidity or risk of accumulation of

corrosive gases The hardened glass door allows instant

visual inspection of the wet-chemical part. For hazard-

ous areas, a third enclosure in stainless steel is available

with all necessary connections, special analytics and con-

trol units, a stand-alone system factory tested to fully

meet ATEX or NEC 500 directives.

Low-temperature oxidation technology

The AppliTOC® delivers more than just automated TOC.

Low levels of detection (LOD) and fast measurements are

evident with AppliTek’s Series of On-line TOC Analyzers,

at a true continuous sampling rate. Comparative tests

with high temperature TOC systems indicate a similar

high oxidation efficiency, which stays constant since no

catalyst is needed. Together with the development of

appropriate sample preconditioning systems, mainly self-

cleaning types, the typical up-time for the on-line deter-

mination of TOC has been increased to more than 98%.


AppliTek R&D Values at a Glance


R & D Values

Reliability

As a specialist manufacturer of on-line analyzers, we are challenged with

offering our customers the best in industrial grade analytics for on-line

monitoring of liquids, from stand-alone analyzers to complete industrial

monitoring systems. All hardware components are carefully selected, with

industrial computers / human interfaces controlling the operation. Results:

massive amounts of process data are reliably measured, logged and com-

municated in a seamlessly easy way to plant managers or control centers.

Flexibility

The incorporated software flexibility minimizes physical operator interven-

tion. The analyzer screen (the client) can remotely be taken over by means

of LAN Ethernet software (such as VNC software). Authorized users can

carry out all necessary manual operations and settings from a remote PC

using a modem, internet or intranet connection.

Safety

Standard general purpose zone, optionally conform ATEX or NEC500.

Industrial needs are to be met by industrial solutions. AppliTek can meet

strict regulations for the construction, including materials as well as design

requirements in hazardous locations. On top of that, all automatic features

that come standard with AppliTek on-line analyzers are also included in the

ex-proof design. Special attention is given to wet parts that come in direct

contact with process streams.

Trustability

Trustability is the currency of exchange between you, the customer, and our

company. A proven track record of 25 years of analytical technology is at

your service. AppliTek’s quality approach is visible in all steps of the delivery

chain, from the initial design up to quality control. Moreover, the best suited

analytical technique in function of your application is implemented as a

part of the total framework approach.

Responsibility

AppliTek supplies you with the ideal formula for all your needs in process

monitoring. From the feasibility over the basic engineering to the final im-

plementation of the analyzer system, AppliTek is and remains your single

partner. The Single Source Responsibility Program is the AppliTek symbiosis

between analytical expertise and system integration, finalized in-house

until the delivery to the plant, including commissioning and maintenance .

ENGINEERED & MANUFACTURED BY

APPLITEK n.v. NAZARETH BELGIUM

TEL: (32) 9 3863402 FAX: (32) 9 3867297

E-mail: [email protected]

About the company AppliTek

AppliTek is an established manufacturer of on-line analyzers

applied to environmental compliance, water treatment and

industrial process applications.

The incorporated technology benefits from a large experience in wet-

chemical techniques since 1985, combined with powerful interfaces,

high quality components and ergonomic design.

Our company has also evolved to a provider of analytical technology

and on-line monitoring solutions for several industries, including Oil &

Gas, Mining, Chlor-alkali, Pharmaceutical, Food & Beverage, Chemical

and Water Utility industries.

Products & Solutions

On-line analyzers Accessory equipment: preconditioning | filtration systems Turnkey analyzer projects Feasibility | Application studies

© 2011 – AppliTek NV – Printed in Belgium In accordance with its policy of continued product improvement, AppliTek reserves the right to change specifications without further notice. UPA® , IPA® , Envirolyzer® and AppliTOC® are registered trademarks and property of AppliTek NV. Our company is registered under Reg. Nr.: BE 0427.086.347 RPR Gent

AppliTek NV/SA Industrial Zone « De Prijkels » Venecoweg 19 B-9810 Nazareth Belgium Tel.: +32 9 386 34 02 For USA call: +1-866-417-5887 (toll free) Fax.: +32 9 386 72 97 E-mail: [email protected] Visit us on www.applitek.com Follow us on Facebook

Documents

AppliTek Process Liquids Process Water