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Masters in Analy cal Technology.
Analy�cal Measurements for Process Control
On-line Analyzers Process Liquids � Process Water
| APPLITEK Process Liquids and Process Water | 02
When crical processes depend on crical data, how will you make the right decision? Manufacturing industries are continuously trying to improve performance, efficiency
or safety by means of process control. Suitable analyzer technology is the first step
in order to manage the total package of your assets and can take your process per-
formance to a higher level. High reliability, few installation costs and a reasonable
total cost of ownership are significant savings required by industrial operations.
AppliTek’s analytical technology helps you to achieve these goals and raise
your standards in process control.
| APPLITEK Process Liquids and Process Water | 03
Enhanced Process Control
Power generation
• Cooling water
• Boiler feed water
• Recirculation water
• Cogeneration
• Solar thermal energy
Semiconductor
• Wafer clean process
• Plating baths
• Etching baths
• Developer solutions
Automobile
• Phosphating baths
• Etching baths
• Recirculation water
Food & Beverage
• Water content
• Process water
• Sauces & juices
Mining
• Purification process
• Cyanide leaching
• Zinc leaching
• Process water
Desalination & Demineralization
• Organic fouling
• Demineralization process
• Storage and distribution
AppliTek analy�cal packages: Reliability � Flexibility � Safety � Trustability � Responsibility
The last years AppliTek expanded significantly its portfolio of measurement and monitor-
ing products in order to be able to offer suitable products for nearly every application
with an attractive price-performance ratio. Through continuous innovation and field ex-
perience AppliTek is able to provide you with the latest and most advanced analyzer
equipment designed for 24/7 measurements in your process. Profitable solutions are
available for every production process, sub process and application.
Chemical & Petrochemical
• Vent gas scrubbers
• Liquid soaps
• Acid streams
• Fertilizer production
• Bleach production
• Brine purification
• Sour water strippers
Pulp & Paper
• Pulping liquids
• Treatment baths
Steel & Metal
• Plating baths
• Etching baths
• Scrubber units
• Cokes production
• Process water
Stand-alone and Integrated Analy�cal Solu�ons for Manufacturing and U�lity Industries
| APPLITEK Process Liquids and Process Water | 04
Data exchange - Superv ision tools
Remote screen sharing Plant engineers, maintenance engineers and other authorized
users can remotely take over the analyzer screen (the client)
by means of LAN Ethernet software (such as VNC). Authorized
users can carry out all manual operations and settings from a
remote PC. Conduct trouble-shooting before doing any
physical intervention, grab cross-platform screenshots for
reports or presentations, the possibilities are endless.
System integrated solutions AppliTek manufactures and commissions analyzer shelters
addressing the needs of customers wishing to monitor a
complex set of parameters in a single integrated system. In
that case, data collection is assured inside the shelter and
transmitted through the network or an existing telephone
line. If necessary, a special computer cabinet can be installed
in the control room to protect the main control/visualization
data computer system.
From real-�me visualiza�on to trouble-shoo�ng: Full integra�on and communica�on of AppliTek process analyzers within industrial produc�on sites and corporate networks.
Control Room
HOST
Industrial grade controllers All AppliTek on-line analyzers (process/water) are equipped
with industrial grade controllers optimized for their tasks. The
colour touch screens (size 10.4” or 5.7”, depending on model)
act as human interfaces with an excellent viewing angle and
swift response to touching. Back-up: all data is automatically
retained in case of power failure.
Flexible communication options All AppliTek process analyzers come with industrial 4-20 mA
outputs, the most common analogue transmission standard
available. Ethernet communication by means of the industry-
standard TCP/IP protocol enables easy and reliable integration
into existing corporate networks. MODBUS interfacing is possi-
ble to assure full integration and communication with distrib-
uted control systems (DCS).
| APPLITEK Process Liquids and Process Water | 05
Data exchange - Supervision
Turnkey analysis projects General purpose zone / Ex-proof
Scope of supply: • Analyzers & instrumentation • Sample preconditioning systems • Ventilation/heating/AC • Safeguarding systems • Recovery systems • Data acquisition & control systems • Sample recovery systems • Sample transport lines
• Results, trendings • Logs, alarms • Cal ibration, val idation • Setup (I/O, communication, preconditioning)
CLIENT
PROCESS
TCP / IP LAN
4 - 20 mA industry standard
Screen sharing on remote desktop
System integrated analyzer shelter
• Results, trendings • Logs, alarms • Data graphs • Control & simulation of wet parts • Cal ibration, val idation program s • Setup (I/O, communication, preconditioning)
| APPLITEK Process Liquids and Process Water | 06
Appl iTek Series of UPA/IPA Process Analyzers
Single and mul� parameter on-line analysis for a mul�tude of manufacturing industries. Titration � ISE � Colorimetry
AppliTek’s Universal Process Analyzer is the state of the art
multi parameter analyzer platform enabling operators to
monitor precisely critical process parameters. The unique
on-line analyzer has been designed to run chemical analysis
on most liquid process samples and outclasses other similar
analyzer designs, thanks to an extended set of analytical and
communication features.
UPA® Universal Process Analyzer • 10 ¼” incorporated industrial panel PC with excellent
graphics and running AppliTek controller software
• Digital outputs: up to 24 DO (24 VDC) and 6 DO (220 VAC)
• Digital inputs: up to 8 DI
• Up to 8 analog inputs
• Data logging of 1000 last recorded results
• Complete separation between wet part and electronics
• Data logging of last 30 titration curves (for titrators)
• Multiple streams (up to 8, application depending)
• ATEX configuration in accordance with 94/9/EC directive
| APPLITEK Process Liquids and Process Water | 07
IPA® Industrial Process Analyzer
The IPA® Industrial Process Analyzer is a single parameter wet-
chemical analyzer with a similar hardware and software architecture
as the Universal Process Analyzer. Providing top quality with an
affordable price tag, the system features all relevant smart and auto-
matic functions and proven chemistry methodologies.
• 5 ¾” color touch screen with function buttons
• Digital outputs: up to 12 DO (24 VDC) and 6 DO (220 VAC)
• Digital inputs: up to 2 DI
• Up to 3 analog inputs
• Data logging of 1000 last recorded results
• Up to 3 streams
• Complete separation between wet part and electronics
Industrial process liquids
For a complete overv iew of al l feasible parameters, please see page 8 - 9.
Chemical - Petrochemical 4-tertiary-butylcatechol � Acetic acid � Acidity � Ammonia � Bromine Index Caustic � Chloride � Chlorine � Cyanide � Ethyl acetate � Fluoride � Hardness � Hydroxide � Hypochlorite � Moisture � Phenol � Silica � Sodium � Sodium hydroxide � Sulphate � Sulphide � Sulphuric acid � TMAH � Total Hydrocarbons Semiconductor Acetic acid � Ammonia � Copper � EDTA � Fluoride � Hydrochloric acid � Hydrogen fluoride � Hydrogen peroxide � Total and free acid � Sulphuric acid Pulp & Paper ABC analysis � Acidity � Acrylonitrile � Alkalinity � Bromide � Bromine Index � Calcium � Carbonate � Caustic � Chlorate � Free Chloride � Hydrogen peroxide � Hypochlorite � Lime � pH � Phenol � Sodium hydroxide � Sulphate � Sulphide � Sulphite � Thio cyanate Mining Acidity � Alkalinity � Ammonium � Aluminium � Carbonate � Chloride � Chromic acid � Copper � Cyanide � EDTA � Hydrochloric acid � Iron II � Iron III � Nickel � Silver � Sulphuric acid � Total Cyanide � Zinc
Industries and their typical parameters
Wet chemistry hardware � Standard (all models) Colorimetric configuration: photometer (insensitive to ambient
light) and analysis cuvette with magnetic stirrer
Titrimetric configuration: titration vessel with magnetic stirrer,
precision dispenser, additional electrodes
Ionometric (ion-selective) configuration: analysis vessel with
magnetic stirrer, precision dispenser for standard addition, high
quality ISE electrodes
� Options Smart solutions that reduce unnecessary interventions and
down-times: Leak detection senses any liquid spills in the
wet part of the on-line analyzer and will be recorded and
communicated by the analyzer’s industrial controller.
Sample presence detection can be installed internally or
externally and gives the opportunity to generate alarms to
operators or control centers in case there is no sample.
| APPLITEK Process Liquids and Process Water | 08
Appl iTek Series of UPA/IPA Process Analyzers
Methodology
Parameter
Titration
Colorimtery
Ion-selective
4-tertiary-butylcatechol � ABC analysis � Acetic acid � Acidity � Acid number � Acrylonitrile � Aldehyde � Alkalinity � Aluminium � � Aluminium chloride � Ammonia � � � Ammonia/Nitrate � � Aniline � Anion active surfactants � Benzoic acid � Bicarbonate � Boric acid � Bromine index � Calcium � � � Calcium oxide � Caprolactam � Carbonate � � Carbon oxide � Caustic � Chemical Oxygen Demand � � Chlorate � � Chloride � � � Chlorine � � Chromium III � � Chromium VI � � Copper � � Cyanide � � � Fatty acids � Fluoride � � Formaldehyde � Formic acid � Free Chloride � Free Cyanide � � � Hardness � � Hydrazine � Hydrochloric acid � Hydrogen peroxide � � Hydroquinone � Hydroxide � Hydroxylamine �
Methodology
Parameter (continued)
Titration
Colorimtery
Ion-selective
Hypochlorite � Iron II � � Iron III � � Lime � Magnesium � � Metabisulphite � Moisture � Na/P molar ratio � Nickel � � Nitrate � � Nitric acid � Oleum � Ortho-phosphate � Oxalic acid � P&M number � Peracetic acid � Permanganate � � Peroxide � � Persulphate � pH � Phenol � � Phosphate � � Phosphoric acid � Phthalic acid � Poly vinyl alcohol � Potassium � Potassium hydroxide � Potassium iodate � Potassium iodide � Redox � Silica � Silver � Sodium � Sodium hydroxide � Sodium sulphate � Strontium carbonate � Sulphate � � Sulphide � � � Sulphite � Sulphonic acid � Sulphuric acid � Thio cyanate � � TMAH � Tri ethyl amine � Tri methyl amine � Zinc � �
| APPLITEK Process Liquids and Process Water | 09
List of process parameters
Methodology
TOTAL parameters
Titration
Colorimtery
Ion-selective
Total acid �
Total alkalinity �
Total ammonia �
Total chlorine �
Total cyanide �
Total iron �
Total phosphate �
Total chromium �
Methodology
COMBINED parameters *
Titration
Colorimtery
Ion-selective
Acidity and Chloride �
Acidity and Diphosphorous Pentoxide � �
Alkalinity and Calcium � �
Aluminium and Sulphuric acid �
Aluminium, Zinc and Sulphuric acid �
Ammonia, Iron II and Iron III �
Ammonia and Sulphide �
Ammonia and Hydroxylamine �
Blended acids �
Calcium and Magnesium � �
Carbonate and Chloride �
Copper and Sulphuric acid �
Copper, Nickel and Zinc �
Fluoride and pH � �
Fluoride, free acid and total acid � �
Hydroquinone and Peroxide �
Hydroxide and Carbonate �
Na/P ratio and Phosphate �
Na2O and AZ number �
Sodium hydroxide, sodium sulphide and sodium carbonate “ABC” analysis �
Total and free acid �
Total and free ammonia �
Total iron, Iron II and Iron III �
Total chromium, Cr III and Cr VI �
Total and free chlorine �
Zinc and Sulphuric acid �
* UPA platform only
Mixed acids
| APPLITEK Process Liquids and Process Water | 010
EnviroLyzer® Series o f On-l ine Water Analyzers
Challenges for water management Managing both quantity and quality of water resources is
a challenging task for companies, utility industries and
authorities. The second generation EnviroLyzer® Series of
On-line Water Analyzers, originally introduced in 2009,
harness all the technology of AppliTek’s reference process
analyzers and enable companies to measure and monitor
quickly and effectively all the relevant parameters in the
water source. With an impressive list of water quality
indices, the EnviroLyzer® Series come factory configured
as single parameter, single methodology analyzers.
Single parameter, cost-effec�ve on-line analysis for industrial water applica�ons.
Design - Features • Titration, colorimetry or ion-selective electrode (ISE)
• Single methodology and single parameter
• Straight-forward design, reduced reagent consumption
• High quality sample pump, micropumps, vessel, tubing
• Incorporated industrial panel PC with AppliTek controller
software
• Ethernet TCP/IP based connection
• Reduced down-time by smart features and add-on units
• Data logging of 1000 last recorded results
• Complete wet part - electronics separation
• Available in Ex-proof configuration complying with ATEX or
NEC500 directives
• Boiler feed water monitoring
• Steam cycle analysis
• Drinking water monitoring
• Waste water monitoring
• Cooling water monitoring
• Anaerobic digestion control
| APPLITEK Process Liquids and Process Water | 011
Process water
Methodology
Parameter
Colorimtery
Ion-selective
Titration
Acetic acid � Acidity � Alkalinity � Aluminium � Ammonia � � Bicarbonate � Biocides � Boron � Calcium � Chloride � � Chlorine � � Chlorine dioxyde � Chlorite � Chromium III � Chromium VI � Color � Copper � Cyanide (free) � � Fatty acids � Fluoride � � Formaldehyde � Hardness (total) � Hydrazine � Hydrochloric acid � Hydrogen fluoride � Hydroxide � Iron II � � Iron III � � Magnesium � � Manganese � Nickel � Nitrate � � Nitrite � � Oxalic acid � Permanganate � Phenol � Phosphate � Phosphoric acid � Potassium hydroxide � Silica � Silicium dioxyde � Sodium �
Sulphide � � �
Thio cyanate �
Urea � Zinc �
Sodium hydroxide � Sodium hypochlorite � Sulphate �
Sulphite � Sulphuric acid �
Total hardness �
Enclosures - Configurations The EnviroLyzer® Series of On-line Water Analyzers are
equipped with a new compact dust- and splash-proof
analyzer enclosure consisting of a powder coated steel
back, combined with an ergonomic ABS hinged part.
Purging with instrument air is possible in case of extreme
humidity or risk of accumulation of corrosive gases.
Where site-specific requirements may compromise the
analyzer’s potential, optional enclosures/configurations
are available. If necessary, the analyzer can be integrated
in various protective enclosures such as an IP65 rated
protective cabinet for outdoor use. For hazardous areas,
the analyser is integrated in a protective enclosure with
all necessary connections, special analytics and control
units, a stand-alone system factory tested to fully meet
ATEX or NEC 500 directives.
| APPLITEK Process Liquids and Process Water | 012
Appl iTOC® Series of On-l ine TOC Analyzers
TOC as a measure of organic load
The AppliTOC® Series of On-line TOC Analyzers enable
continuous and reliable monitoring of organic compounds
in water, by means of the low-temperature UV/persulfate
oxidation method. Automatic smart functions such as auto-
cleaning, as well as programmable auto-calibration and
auto-validation are standard features, controlled by the
AppliTek industrial grade controller. Operation is made
easier, reliable data are assured and unnecessary operator
intervention is minimized.
AppliTOC® Series of On-line TOC Analyzers
• True continuous analysis
• High quality sample, transfer and addition pumps for acid and
persulfate, mass flow meter, dual wavelength IR detector
• Compliant with standard methods USEPA 415.2, ISO 8245 and
DIN-EN 1484
• 5 ¾” color touch screen with buttons for immediate access
• Standard auto-cleaning, auto-validation, auto-calibration
• Data logging of 1000 last recorded results
• Complete wet part / electronics separation
• Factory configured, tested and calibrated
Analytical mainframe: configurations
Total Organic Carbon (standard) Measurement of non
purgeable organic carbon (NPOC)
Total Inorganic Carbon (TIC) Measurement of inorganic
carbon compounds (including volatile organic compounds)
Total Carbon (TC) Measurement of all carbon compounds
(with single IR detector)
True Total Organic Carbon Measurement of “true” TOC
(= TC – TIC, with double IR detector)
| APPLITEK Process Liquids and Process Water | 013
VPA® Vol tammetric Process Analyzer
Trace level determination of heavy metals
VPA® Voltammetric Process Analyzer is a fully automatic
on-line analyzer system for the simultaneous determination
of a wide range of hazardous heavy metals in water. The
whole system consists of an industrial controller, a number
analytical units (depending on choice of metals), a com-
plete sample preparation unit and reagent containers, all
built and enclosed in a floorstanding cabinet.
VPA® Voltammetric Process Analyzer • Advanced voltammetric principle allowing for high sensitivity
and low reagent consumption
• Batch operation principle limits loading of the electrode and allows to program at will the analysis sequence
• Up to three (3) sampling points possible
• Built-in sample pretreating digestion unit (optional)
• 5 ¾” color touch screen with buttons for immediate access
• Standard auto-calibration / automatic background correction
• Data logging of 1000 last recorded results
• Complete wet part / electronics separation
• Factory configured, tested and calibrated
Methodology
Parameter
Voltammetry
Colorimetry
Antimony �
Bismuth �
Cadmium �
Chromium III � � Chromium VI � � Copper � � Iron II � � Iron III � � Lead � � Manganese II � � Manganese VII � � Mercury �
Nickel � � Selenium �
Silver �
Thallium �
Tin �
Zinc � �
Measurement of total heavy metal content
Accuracy, precision and stability of results are very critical
when monitoring for heavy metal contents in water sam-
ples by photometric and electrochemical methods. The
VPA® can be equipped with an optional add-on unit to
digest organics, while suspended particles can be dissolved
completely. The new digestion unit is conform with US EPA
Method 200.2 or 200.7 and processes samples with concen-
trated acids and oxidizing agents at high temperature.
| APPLITEK Process Liquids and Process Water | 14
AppliTek R&D Values at a Glance
| APPLITEK Process Liquids and Process Water | 15
R & D Values
Reliability
As a specialist manufacturer of on-line analyzers, we are challenged with
offering our customers the best in industrial grade analytics for on-line
monitoring of liquids, from stand-alone analyzers to complete industrial
monitoring systems. All hardware components are carefully selected, with
industrial computers / human interfaces controlling the operation. Results:
massive amounts of process data are reliably measured, logged and com-
municated in a seamlessly easy way to plant managers or control centers.
Flexibility
The incorporated software flexibility minimizes physical operator interven-
tion. The analyzer screen (the client) can remotely be taken over by means
of LAN Ethernet software (such as VNC software). Authorized users can car-
ry out all necessary manual operations and settings from a remote PC using
a modem, internet or intranet connection.
Safety
Standard general purpose zone, optionally conform ATEX or NEC500.
Industrial needs are to be met by industrial solutions. AppliTek can meet
strict regulations for the construction, including materials as well as design
requirements in hazardous locations. On top of that, all automatic features
that come standard with AppliTek on-line analyzers are also included in the
ex-proof design. Special attention is given to wet parts that come in direct
contact with process streams.
Trustability
Trustability is the currency of exchange between you, the customer, and our
company. A proven track record of 25 years of analytical technology is at
your service. AppliTek’s quality approach is visible in all steps of the delivery
chain, from the initial design up to quality control. Moreover, the best suited
analytical technique in function of your application is implemented as a
part of the total framework approach.
Responsibility
AppliTek supplies you with the ideal formula for all your needs in process
monitoring. From the application and feasibility study to basic engineering
to the final implementation of the analyzer system, AppliTek is and remains
your single partner. AppliTek’s symbiosis between analytical expertise and
system integration guarantees you a complete solution for a measuring
problem, not merely supply of an analyzer.
ENGINEERED & MANUFACTURED BY
APPLITEK n.v. NAZARETH BELGIUM
TEL: (32) 9 3863402 FAX: (32) 9 3867297
E-mail: [email protected]
About the company AppliTek AppliTek is an established manufacturer of on-line analyzers applied to
environmental compliance, water treatment and industrial process
applications.
The incorporated technology benefits from a large experience in wet-
chemical techniques since 1985, combined with powerful interfaces,
high quality components and ergonomic design.
Our company has also evolved to a provider of analytical technology
and on-line monitoring solutions for several industries, including Oil &
Gas, Mining, Chlor-alkali, Pharmaceutical, Food & Beverage, Chemical
and Water Utility industries.
Products & Solu ons
On-line analyzers Accessory equipment: preconditioning | filtration systems Turnkey analyzer projects Feasibility | Application studies
© 2014 – AppliTek NV – Printed in Belgium In accordance with its policy of continued product improvement, AppliTek reserves the right to change specifications without further notice. UPA, IPA, VPA, Envirolyzer and AppliTOC are registered trademarks and property of AppliTek NV. Our company is registered under Reg. Nr.: BE 0427.086.347 RPR Gent
AppliTek NV/SA Industrial Zone « De Prijkels » Venecoweg 19 B-9810 Nazareth Belgium Tel.: +32 9 386 34 02 For USA call: +1-866-417-5887 (toll free) Fax.: +32 9 386 72 97 E-mail: [email protected] Visit us on www.applitek.com Follow us on Facebook
Revision July 2014