APPLITEK Process Liquids and Process Water | 06 AppliTek Series of UPA/IPA Process Analyzers ˚ ˘ -line analysis for a ˜ Titration ISE Colorimetry AppliTek’s Universal Process

Masters in Analy cal Technology.

Analy�cal Measurements for Process Control

On-line Analyzers Process Liquids � Process Water

| APPLITEK Process Liquids and Process Water | 02

When crical processes depend on crical data, how will you make the right decision? Manufacturing industries are continuously trying to improve performance, efficiency

or safety by means of process control. Suitable analyzer technology is the first step

in order to manage the total package of your assets and can take your process per-

formance to a higher level. High reliability, few installation costs and a reasonable

total cost of ownership are significant savings required by industrial operations.

AppliTek’s analytical technology helps you to achieve these goals and raise

your standards in process control.


Enhanced Process Control

Power generation

• Cooling water

• Boiler feed water

• Recirculation water

• Cogeneration

• Solar thermal energy

Semiconductor

• Wafer clean process

• Plating baths

• Etching baths

• Developer solutions

Automobile

• Phosphating baths

• Etching baths

• Recirculation water

Food & Beverage

• Water content

• Process water

• Sauces & juices

Mining

• Purification process

• Cyanide leaching

• Zinc leaching

• Process water

Desalination & Demineralization

• Organic fouling

• Demineralization process

• Storage and distribution

AppliTek analy�cal packages: Reliability � Flexibility � Safety � Trustability � Responsibility

The last years AppliTek expanded significantly its portfolio of measurement and monitor-

ing products in order to be able to offer suitable products for nearly every application

with an attractive price-performance ratio. Through continuous innovation and field ex-

perience AppliTek is able to provide you with the latest and most advanced analyzer

equipment designed for 24/7 measurements in your process. Profitable solutions are

available for every production process, sub process and application.

Chemical & Petrochemical

• Vent gas scrubbers

• Liquid soaps

• Acid streams

• Fertilizer production

• Bleach production

• Brine purification

• Sour water strippers

Pulp & Paper

• Pulping liquids

• Treatment baths

Steel & Metal

• Plating baths

• Etching baths

• Scrubber units

• Cokes production

• Process water

Stand-alone and Integrated Analy�cal Solu�ons for Manufacturing and U�lity Industries


Data exchange - Superv ision tools

Remote screen sharing Plant engineers, maintenance engineers and other authorized

users can remotely take over the analyzer screen (the client)

by means of LAN Ethernet software (such as VNC). Authorized

users can carry out all manual operations and settings from a

remote PC. Conduct trouble-shooting before doing any

physical intervention, grab cross-platform screenshots for

reports or presentations, the possibilities are endless.

System integrated solutions AppliTek manufactures and commissions analyzer shelters

addressing the needs of customers wishing to monitor a

complex set of parameters in a single integrated system. In

that case, data collection is assured inside the shelter and

transmitted through the network or an existing telephone

line. If necessary, a special computer cabinet can be installed

in the control room to protect the main control/visualization

data computer system.

From real-�me visualiza�on to trouble-shoo�ng: Full integra�on and communica�on of AppliTek process analyzers within industrial produc�on sites and corporate networks.

Control Room

HOST

Industrial grade controllers All AppliTek on-line analyzers (process/water) are equipped

with industrial grade controllers optimized for their tasks. The

colour touch screens (size 10.4” or 5.7”, depending on model)

act as human interfaces with an excellent viewing angle and

swift response to touching. Back-up: all data is automatically

retained in case of power failure.

Flexible communication options All AppliTek process analyzers come with industrial 4-20 mA

outputs, the most common analogue transmission standard

available. Ethernet communication by means of the industry-

standard TCP/IP protocol enables easy and reliable integration

into existing corporate networks. MODBUS interfacing is possi-

ble to assure full integration and communication with distrib-

uted control systems (DCS).


Data exchange - Supervision

Turnkey analysis projects General purpose zone / Ex-proof

Scope of supply: • Analyzers & instrumentation • Sample preconditioning systems • Ventilation/heating/AC • Safeguarding systems • Recovery systems • Data acquisition & control systems • Sample recovery systems • Sample transport lines

• Results, trendings • Logs, alarms • Cal ibration, val idation • Setup (I/O, communication, preconditioning)

CLIENT

PROCESS

TCP / IP LAN

4 - 20 mA industry standard

Screen sharing on remote desktop

System integrated analyzer shelter

• Results, trendings • Logs, alarms • Data graphs • Control & simulation of wet parts • Cal ibration, val idation program s • Setup (I/O, communication, preconditioning)


Appl iTek Series of UPA/IPA Process Analyzers

Single and mul� parameter on-line analysis for a mul�tude of manufacturing industries. Titration � ISE � Colorimetry

AppliTek’s Universal Process Analyzer is the state of the art

multi parameter analyzer platform enabling operators to

monitor precisely critical process parameters. The unique

on-line analyzer has been designed to run chemical analysis

on most liquid process samples and outclasses other similar

analyzer designs, thanks to an extended set of analytical and

communication features.

UPA® Universal Process Analyzer • 10 ¼” incorporated industrial panel PC with excellent

graphics and running AppliTek controller software

• Digital outputs: up to 24 DO (24 VDC) and 6 DO (220 VAC)

• Digital inputs: up to 8 DI

• Up to 8 analog inputs

• Data logging of 1000 last recorded results

• Complete separation between wet part and electronics

• Data logging of last 30 titration curves (for titrators)

• Multiple streams (up to 8, application depending)

• ATEX configuration in accordance with 94/9/EC directive


IPA® Industrial Process Analyzer

The IPA® Industrial Process Analyzer is a single parameter wet-

chemical analyzer with a similar hardware and software architecture

as the Universal Process Analyzer. Providing top quality with an

affordable price tag, the system features all relevant smart and auto-

matic functions and proven chemistry methodologies.

• 5 ¾” color touch screen with function buttons

• Digital outputs: up to 12 DO (24 VDC) and 6 DO (220 VAC)

• Digital inputs: up to 2 DI

• Up to 3 analog inputs


• Up to 3 streams

• Complete separation between wet part and electronics

Industrial process liquids

For a complete overv iew of al l feasible parameters, please see page 8 - 9.

Chemical - Petrochemical 4-tertiary-butylcatechol � Acetic acid � Acidity � Ammonia � Bromine Index Caustic � Chloride � Chlorine � Cyanide � Ethyl acetate � Fluoride � Hardness � Hydroxide � Hypochlorite � Moisture � Phenol � Silica � Sodium � Sodium hydroxide � Sulphate � Sulphide � Sulphuric acid � TMAH � Total Hydrocarbons Semiconductor Acetic acid � Ammonia � Copper � EDTA � Fluoride � Hydrochloric acid � Hydrogen fluoride � Hydrogen peroxide � Total and free acid � Sulphuric acid Pulp & Paper ABC analysis � Acidity � Acrylonitrile � Alkalinity � Bromide � Bromine Index � Calcium � Carbonate � Caustic � Chlorate � Free Chloride � Hydrogen peroxide � Hypochlorite � Lime � pH � Phenol � Sodium hydroxide � Sulphate � Sulphide � Sulphite � Thio cyanate Mining Acidity � Alkalinity � Ammonium � Aluminium � Carbonate � Chloride � Chromic acid � Copper � Cyanide � EDTA � Hydrochloric acid � Iron II � Iron III � Nickel � Silver � Sulphuric acid � Total Cyanide � Zinc

Industries and their typical parameters

Wet chemistry hardware � Standard (all models) Colorimetric configuration: photometer (insensitive to ambient

light) and analysis cuvette with magnetic stirrer

Titrimetric configuration: titration vessel with magnetic stirrer,

precision dispenser, additional electrodes

Ionometric (ion-selective) configuration: analysis vessel with

magnetic stirrer, precision dispenser for standard addition, high

quality ISE electrodes

� Options Smart solutions that reduce unnecessary interventions and

down-times: Leak detection senses any liquid spills in the

wet part of the on-line analyzer and will be recorded and

communicated by the analyzer’s industrial controller.

Sample presence detection can be installed internally or

externally and gives the opportunity to generate alarms to

operators or control centers in case there is no sample.


Appl iTek Series of UPA/IPA Process Analyzers

Methodology

Parameter

Titration

Colorimtery

Ion-selective

4-tertiary-butylcatechol � ABC analysis � Acetic acid � Acidity � Acid number � Acrylonitrile � Aldehyde � Alkalinity � Aluminium � � Aluminium chloride � Ammonia � � � Ammonia/Nitrate � � Aniline � Anion active surfactants � Benzoic acid � Bicarbonate � Boric acid � Bromine index � Calcium � � � Calcium oxide � Caprolactam � Carbonate � � Carbon oxide � Caustic � Chemical Oxygen Demand � � Chlorate � � Chloride � � � Chlorine � � Chromium III � � Chromium VI � � Copper � � Cyanide � � � Fatty acids � Fluoride � � Formaldehyde � Formic acid � Free Chloride � Free Cyanide � � � Hardness � � Hydrazine � Hydrochloric acid � Hydrogen peroxide � � Hydroquinone � Hydroxide � Hydroxylamine �

Methodology

Parameter (continued)

Titration

Colorimtery

Ion-selective

Hypochlorite � Iron II � � Iron III � � Lime � Magnesium � � Metabisulphite � Moisture � Na/P molar ratio � Nickel � � Nitrate � � Nitric acid � Oleum � Ortho-phosphate � Oxalic acid � P&M number � Peracetic acid � Permanganate � � Peroxide � � Persulphate � pH � Phenol � � Phosphate � � Phosphoric acid � Phthalic acid � Poly vinyl alcohol � Potassium � Potassium hydroxide � Potassium iodate � Potassium iodide � Redox � Silica � Silver � Sodium � Sodium hydroxide � Sodium sulphate � Strontium carbonate � Sulphate � � Sulphide � � � Sulphite � Sulphonic acid � Sulphuric acid � Thio cyanate � � TMAH � Tri ethyl amine � Tri methyl amine � Zinc � �


List of process parameters

Methodology

TOTAL parameters

Titration

Colorimtery

Ion-selective

Total acid �

Total alkalinity �

Total ammonia �

Total chlorine �

Total cyanide �

Total iron �

Total phosphate �

Total chromium �

Methodology

COMBINED parameters *

Titration

Colorimtery

Ion-selective

Acidity and Chloride �

Acidity and Diphosphorous Pentoxide � �

Alkalinity and Calcium � �

Aluminium and Sulphuric acid �

Aluminium, Zinc and Sulphuric acid �

Ammonia, Iron II and Iron III �

Ammonia and Sulphide �

Ammonia and Hydroxylamine �

Blended acids �

Calcium and Magnesium � �

Carbonate and Chloride �

Copper and Sulphuric acid �

Copper, Nickel and Zinc �

Fluoride and pH � �

Fluoride, free acid and total acid � �

Hydroquinone and Peroxide �

Hydroxide and Carbonate �

Na/P ratio and Phosphate �

Na2O and AZ number �

Sodium hydroxide, sodium sulphide and sodium carbonate “ABC” analysis �

Total and free acid �

Total and free ammonia �

Total iron, Iron II and Iron III �

Total chromium, Cr III and Cr VI �

Total and free chlorine �

Zinc and Sulphuric acid �

* UPA platform only

Mixed acids


EnviroLyzer® Series o f On-l ine Water Analyzers

Challenges for water management Managing both quantity and quality of water resources is

a challenging task for companies, utility industries and

authorities. The second generation EnviroLyzer® Series of

On-line Water Analyzers, originally introduced in 2009,

harness all the technology of AppliTek’s reference process

analyzers and enable companies to measure and monitor

quickly and effectively all the relevant parameters in the

water source. With an impressive list of water quality

indices, the EnviroLyzer® Series come factory configured

as single parameter, single methodology analyzers.

Single parameter, cost-effec�ve on-line analysis for industrial water applica�ons.

Design - Features • Titration, colorimetry or ion-selective electrode (ISE)

• Single methodology and single parameter

• Straight-forward design, reduced reagent consumption

• High quality sample pump, micropumps, vessel, tubing

• Incorporated industrial panel PC with AppliTek controller

software

• Ethernet TCP/IP based connection

• Reduced down-time by smart features and add-on units


• Complete wet part - electronics separation

• Available in Ex-proof configuration complying with ATEX or

NEC500 directives

• Boiler feed water monitoring

• Steam cycle analysis

• Drinking water monitoring

• Waste water monitoring

• Cooling water monitoring

• Anaerobic digestion control


Process water

Methodology

Parameter

Colorimtery

Ion-selective

Titration

Acetic acid � Acidity � Alkalinity � Aluminium � Ammonia � � Bicarbonate � Biocides � Boron � Calcium � Chloride � � Chlorine � � Chlorine dioxyde � Chlorite � Chromium III � Chromium VI � Color � Copper � Cyanide (free) � � Fatty acids � Fluoride � � Formaldehyde � Hardness (total) � Hydrazine � Hydrochloric acid � Hydrogen fluoride � Hydroxide � Iron II � � Iron III � � Magnesium � � Manganese � Nickel � Nitrate � � Nitrite � � Oxalic acid � Permanganate � Phenol � Phosphate � Phosphoric acid � Potassium hydroxide � Silica � Silicium dioxyde � Sodium �

Sulphide � � �

Thio cyanate �

Urea � Zinc �

Sodium hydroxide � Sodium hypochlorite � Sulphate �

Sulphite � Sulphuric acid �

Total hardness �

Enclosures - Configurations The EnviroLyzer® Series of On-line Water Analyzers are

equipped with a new compact dust- and splash-proof

analyzer enclosure consisting of a powder coated steel

back, combined with an ergonomic ABS hinged part.

Purging with instrument air is possible in case of extreme

humidity or risk of accumulation of corrosive gases.

Where site-specific requirements may compromise the

analyzer’s potential, optional enclosures/configurations

are available. If necessary, the analyzer can be integrated

in various protective enclosures such as an IP65 rated

protective cabinet for outdoor use. For hazardous areas,

the analyser is integrated in a protective enclosure with

all necessary connections, special analytics and control

units, a stand-alone system factory tested to fully meet

ATEX or NEC 500 directives.


Appl iTOC® Series of On-l ine TOC Analyzers

TOC as a measure of organic load

The AppliTOC® Series of On-line TOC Analyzers enable

continuous and reliable monitoring of organic compounds

in water, by means of the low-temperature UV/persulfate

oxidation method. Automatic smart functions such as auto-

cleaning, as well as programmable auto-calibration and

auto-validation are standard features, controlled by the

AppliTek industrial grade controller. Operation is made

easier, reliable data are assured and unnecessary operator

intervention is minimized.

AppliTOC® Series of On-line TOC Analyzers

• True continuous analysis

• High quality sample, transfer and addition pumps for acid and

persulfate, mass flow meter, dual wavelength IR detector

• Compliant with standard methods USEPA 415.2, ISO 8245 and

DIN-EN 1484

• 5 ¾” color touch screen with buttons for immediate access

• Standard auto-cleaning, auto-validation, auto-calibration


• Complete wet part / electronics separation

• Factory configured, tested and calibrated

Analytical mainframe: configurations

Total Organic Carbon (standard) Measurement of non

purgeable organic carbon (NPOC)

Total Inorganic Carbon (TIC) Measurement of inorganic

carbon compounds (including volatile organic compounds)

Total Carbon (TC) Measurement of all carbon compounds

(with single IR detector)

True Total Organic Carbon Measurement of “true” TOC

(= TC – TIC, with double IR detector)


VPA® Vol tammetric Process Analyzer

Trace level determination of heavy metals

VPA® Voltammetric Process Analyzer is a fully automatic

on-line analyzer system for the simultaneous determination

of a wide range of hazardous heavy metals in water. The

whole system consists of an industrial controller, a number

analytical units (depending on choice of metals), a com-

plete sample preparation unit and reagent containers, all

built and enclosed in a floorstanding cabinet.

VPA® Voltammetric Process Analyzer • Advanced voltammetric principle allowing for high sensitivity

and low reagent consumption

• Batch operation principle limits loading of the electrode and allows to program at will the analysis sequence

• Up to three (3) sampling points possible

• Built-in sample pretreating digestion unit (optional)

• 5 ¾” color touch screen with buttons for immediate access

• Standard auto-calibration / automatic background correction


• Complete wet part / electronics separation

• Factory configured, tested and calibrated

Methodology

Parameter

Voltammetry

Colorimetry

Antimony �

Bismuth �

Cadmium �

Chromium III � � Chromium VI � � Copper � � Iron II � � Iron III � � Lead � � Manganese II � � Manganese VII � � Mercury �

Nickel � � Selenium �

Silver �

Thallium �

Tin �

Zinc � �

Measurement of total heavy metal content

Accuracy, precision and stability of results are very critical

when monitoring for heavy metal contents in water sam-

ples by photometric and electrochemical methods. The

VPA® can be equipped with an optional add-on unit to

digest organics, while suspended particles can be dissolved

completely. The new digestion unit is conform with US EPA

Method 200.2 or 200.7 and processes samples with concen-

trated acids and oxidizing agents at high temperature.


AppliTek R&D Values at a Glance


R & D Values

Reliability

As a specialist manufacturer of on-line analyzers, we are challenged with

offering our customers the best in industrial grade analytics for on-line

monitoring of liquids, from stand-alone analyzers to complete industrial

monitoring systems. All hardware components are carefully selected, with

industrial computers / human interfaces controlling the operation. Results:

massive amounts of process data are reliably measured, logged and com-

municated in a seamlessly easy way to plant managers or control centers.

Flexibility

The incorporated software flexibility minimizes physical operator interven-

tion. The analyzer screen (the client) can remotely be taken over by means

of LAN Ethernet software (such as VNC software). Authorized users can car-

ry out all necessary manual operations and settings from a remote PC using

a modem, internet or intranet connection.

Safety

Standard general purpose zone, optionally conform ATEX or NEC500.

Industrial needs are to be met by industrial solutions. AppliTek can meet

strict regulations for the construction, including materials as well as design

requirements in hazardous locations. On top of that, all automatic features

that come standard with AppliTek on-line analyzers are also included in the

ex-proof design. Special attention is given to wet parts that come in direct

contact with process streams.

Trustability

Trustability is the currency of exchange between you, the customer, and our

company. A proven track record of 25 years of analytical technology is at

your service. AppliTek’s quality approach is visible in all steps of the delivery

chain, from the initial design up to quality control. Moreover, the best suited

analytical technique in function of your application is implemented as a

part of the total framework approach.

Responsibility

AppliTek supplies you with the ideal formula for all your needs in process

monitoring. From the application and feasibility study to basic engineering

to the final implementation of the analyzer system, AppliTek is and remains

your single partner. AppliTek’s symbiosis between analytical expertise and

system integration guarantees you a complete solution for a measuring

problem, not merely supply of an analyzer.

ENGINEERED & MANUFACTURED BY

APPLITEK n.v. NAZARETH BELGIUM

TEL: (32) 9 3863402 FAX: (32) 9 3867297

E-mail: [email protected]

About the company AppliTek AppliTek is an established manufacturer of on-line analyzers applied to

environmental compliance, water treatment and industrial process

applications.

The incorporated technology benefits from a large experience in wet-

chemical techniques since 1985, combined with powerful interfaces,

high quality components and ergonomic design.

Our company has also evolved to a provider of analytical technology

and on-line monitoring solutions for several industries, including Oil &

Gas, Mining, Chlor-alkali, Pharmaceutical, Food & Beverage, Chemical

and Water Utility industries.

Products & Solu ons

On-line analyzers Accessory equipment: preconditioning | filtration systems Turnkey analyzer projects Feasibility | Application studies

© 2014 – AppliTek NV – Printed in Belgium In accordance with its policy of continued product improvement, AppliTek reserves the right to change specifications without further notice. UPA, IPA, VPA, Envirolyzer and AppliTOC are registered trademarks and property of AppliTek NV. Our company is registered under Reg. Nr.: BE 0427.086.347 RPR Gent

AppliTek NV/SA Industrial Zone « De Prijkels » Venecoweg 19 B-9810 Nazareth Belgium Tel.: +32 9 386 34 02 For USA call: +1-866-417-5887 (toll free) Fax.: +32 9 386 72 97 E-mail: [email protected] Visit us on www.applitek.com Follow us on Facebook

Revision July 2014

Documents

APPLITEK Process Liquids and Process Water | 06 AppliTek Series of UPA/IPA Process Analyzers ˚ ˘ -line analysis for a ˜ Titration ISE Colorimetry AppliTek’s Universal Process