50373692 8 Bakey Technology

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    Dr. Li Wenzhao

    Department of Food Science and

    Engineering

    Bakery Technology

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    1 History Bread being one of the earliest

    processed food

    Manufacturing industry from 3,000B.C.E. in Egypt

    $16 billion industry in the US

    Wheat consumption ~100 Kg/person/year

    a central ago, 50 Kg 1960s, 70 Kg 1980s,

    2000 65 Kg

    European as high as 140 Kg/person/year

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    BreadsLeavened

    Flatbread (unleavened)Labeling

    Wheat bread = white flour Whole wheat = whole grain

    Multigrain, cracked wheat, or 7-grain may not be whole grain

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    Leavened Breads

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    Unleavened Breads

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    Oats, barley, and some foodproducts made from cereal grains

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    A wheat field in Dorest, England

    Wheat

    Planting

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    2 Wheat morphology and chemistry

    Section of a grain of wheat

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    a Kernel of Wheat

    83% of kernel isendosperm

    14.5% of kernel is Bran

    2.5% of kernel is Germ

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    1) Bran Layer

    14% of kernel

    Several thin layer Contains aleurone layer

    viable, protected layer,

    surrounds endosperm

    enzyme activity

    Contains: protein, lipid,

    minerals, vitamins, phenolic

    compounds, cellulose

    Graphic: http://www.generalmills.com/wholegrain/101/

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    Source: Hoseney, R.C. Principles of Cereal Science and Technology, 2nd Edition, pg. 17.

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    2) Starchy Endosperm 83% of kernel

    Non-viable, but may haveenzymatic activity

    Contains high levels of starch

    75% of wheat endosperm source of fermentable sugars

    Contains extensible gluten

    proteins Very little mineral, fiber, fat &vitamins

    Graphic: http://www.generalmills.com/wholegrain/101/

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    3) Germ 2-3% of kernel Viable tissue

    Contains embryo all rudimentary growth

    tissues

    Responsible forgermination e.g. during malting of barley

    Contains higher quantitiesof lipid than otherfractions

    Graphic: http://www.generalmills.com/wholegrain/101/

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    3 Milling of Wheat

    Flowchart ofwheat milling

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    Wheat Mill Fractions

    Wheat Flour Germ Bran

    Protein 12.0 11.0 30.0 14.5

    Ash 1.8 .4 4.0 6.0

    Fiber 2.5 - 2.0 10.0Fat 2.9 .88 10.0 3.3

    Source: Hoseney, R.C. Principles of Cereal Science and Technology, 2nd Edition, pg. 137.

    Milling is a process which attempts to cleanly separate the

    anatomical parts of the grain to produce a product (flour), which

    is chemically, compositionally, and functionally very different.

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    FlourFlour

    All-purpose flour

    Cake flour Instant/quick-mixing flour

    Self-rising flour

    Whole wheat flour

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    All-purpose flour

    Milled and sifted blend of different varietiesof wheat.

    Made primarily of endosperm

    Can be bleached or unbleached: nonutritional difference between the two

    General baking and cooking

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    Cake Flour Made from a class of wheat called soft

    wheat.

    Used for making cakes and other bakedproducts with delicate textures.

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    Instant or quick-mixing flour All-purpose flour that has been specially

    treated to blend easily with liquids.

    Used to make gravies and sauces.

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    Self-rising flour Is an all-purpose flour with added

    leavening agents and salt.

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    Whole Wheat Flour

    Made by milling the entire wheat kernelso it contains the bran, germ, and

    endosperm.

    Gives baked products a nutlike flavor and

    coarser texture than does all-purposeflour.

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    4 Wheat protein and starch Flour composition critical for the

    fermentation and physical structure ofthe dough and finished bread

    Refined white flour used mostly in US,from endosperm portion

    Consists mainly protein and starchSmall portion of hemicellulose and lipid

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    Wheat Protein

    8%-15% of wheat flour is protein

    High protein flours from hard wheat

    best for bread, >11% Low-protein flours from soft wheat

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    Wheat Protein

    Gliadin and glutenin the most

    important ones, ~85%

    When hydrated and mixed, form

    gluten, key component of bread

    Remaining globulins and albumins,- and -amylases

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    Gluten Gluten consists of two protein

    -Glutenin and

    -Gliadin

    They interact with each other by thekneading of a wet dough, to form a

    protein complex Gluten is a highly elastic material

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    Gluten

    Protein complex gives bread

    structure and elasticity and essential

    doe the leavening process

    Poorly formed or absent in non-wheat flours

    Most commercial breads containsome wheat

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    Benefits of Vital Gluten Instant protein source

    Aids in water absorption, 1% added

    increases dough absorption by 1.2% Benefits should include volume increases,

    and increased processing tolerance for

    bread and rolls Usage:

    Whole grain breads:2-5%

    High fiber, reduced calorie breads 5-12%

    Pizza dough:0.5-1%

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    Wheat Carbohydrate

    75% of the total weightLargely compose of starch

    Some other carbohydrates

    A small amount of simple sugar,

    cellulose, fiber (~1%)

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    Wheat Starch Native starch granule insoluble

    Amylose and amylopectin withinspherical granules in rigid, semi-

    crystalline network Milling can damage a small

    percentage, increase waterabsorption and enzyme exposure

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    Starch StructureNatural Starch conformation

    Mixture of amylose and amylopectin

    Pure amylose not natural (only 85%)Waxy maize starch - amylopectin

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    Starch CompositionTYPE OF

    STARCH

    AMYLOSE % AMYLOPECTIN

    %

    MAIZE 26 74

    WHEAT 25 75

    RICE 17 83

    POTATO 21 79

    CASSAVA 17 83

    WAXY MAIZE 1 90

    HIGH AMYLOSE 70 30

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    Starch ConfigurationConfiguration = 3D structure

    Not soluble in cold water

    Settles

    No adhesive powerNo binding capacity

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    Starch ConfigurationTo have the previous properties the starch

    slurry must be heated

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    Amylose vs. Amylopectin

    Starch is a food storage polysaccharide used byplants to organize glucose polymers

    Two unique patterns of linear organization:AMYLOPECTIN (75%) AMYLOSE (25%)

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    Amylose vs. Amylopectin Starch linear structural pattern confers

    unique tertiary structure

    AMYLOPECTIN (75%) AMYLOSE (25%)

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    Amylose vs. Amylopectin

    Literature suggests that amylopectin is morereadily digested by -amylase

    Genetically modified maize, rice and barleycontaining 100% amylopectin starch aredigested faster than normal counterparts (Nodaet al. 2002)

    Resistant starches (low GI starches) exhibitslow release of glucose into intestinal lumen,non-resistant starches (high GI starches) exhibit

    rapid release of glucose into lumen (Bird et al.2007)

    Resistant starches high amylose content

    Non-resistant starches high amylopectin content

    St h G l i P t i

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    Starch Granules in Protein

    Matrix

    Source: Hoseney, R.C. Principles of Cereal Science and Technology, 2nd Edition, pg. 9.

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    Starch Granules andGelatinization

    In the storage areas of plant (seeds, roots),molecules of starch are deposited as tiny,organized unit granules

    In cold water, starch granule is insoluble. In warm water, gelatinization

    - swelling of granule as water is absorbed

    - disruption of the granule structure

    - loss birefringence

    Starch Granules &

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    Starch Granules &

    Birefringence

    Bright field microscopy Polarizingmicroscopy

    Gelatinizatio

    n

    (h

    eat+water)

    Source: Hoseney, R.C. Principles of Cereal Science and Technology, 2nd Edition, pg. 53.

    S h G l P l h Di ib i

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    Wheat endosperms consist of three

    distinct starch granules (Raeker et al.,

    1998) A-granules: large, disc shaped

    B-granules: small, spherical shape

    C-granules: not well defined

    Starch Granule Polymorph Distribution

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    Riffkin et al. (1990) and Brosnan et al. (1999)

    Contributary role of starch granule size distribution toethanol yield

    Starch Granule Polymorph Distribution

    A vs. B-granule

    Structural Distinctions Amylose content

    Lipid content

    Size

    Crystallinity

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    Starch GelatinizationGelatinization only occurs with heat and water

    Dry heating = dextrinization

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    Starch Gelatinization5% Corn starch = start of heating only has

    water absorbed onto granule surfacesGranules still clumping

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    Starch GelatinizationAt 40oC more water as absorbed and granules

    start to separate

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    Starch GelatinizationAt 65oC more water as absorbed and granules

    start to rupture

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    Starch GelatinizationAt 70oC further rupture, leakage

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    Starch Gelatinization

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    Starch Gelatinization

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    Factors AffectingGelatinization

    Main determinants of gelatinization:

    Water content

    Starch concentration

    Nature of starch

    Degrading enzymesOther environmental factors

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    Factors AffectingGelatinization

    Main determinants of gelatinization:

    Fat

    Protein

    Temperature

    Hydrogen bonds

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    Staling

    Usually ascribed to :

    Loss of moisture

    Retrogradation

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    Staling Bread and buns become firm (high-moisture,

    yeast-raised products);

    Crusty loaves dry out;

    Crisp baked goods go soft (low-moistureproducts);

    Off-flavours develop.

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    Staling 1 to 5% of baked goods are lost

    Climate plays a role

    Storage conditions

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    StalingMostly ascribed to:

    Retrogradation

    Moisture exclusion (crystallinity)

    Brittle crumb

    Low temperature speeds up the

    process

    Freezing prevents staling

    5 Bread Unit Operations

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    p

    Modern Bread Technology Straight dough process

    Homemade, one-batch-at-a-time, not much by the

    baking industry Sponge and dough process

    Mostly used, using partially concentrated portion

    of dough-sponge to ferment, and then mixing withthe remaining ingredients

    Liquid sponge process

    Continuous bread-making, liquid sponge, savelabor and time, using thin, quality not as good

    Chorleywood Process

    General Manufacturing

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    General Manufacturing

    Principles

    W ei g h an d m i xi ng red i en t s d o u g h F e rmen tedd o u g h

    Por t i onedan d

    shapedb ak e Coo l

    sl i ce p ack

    fermentation

    fermentation

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    Formulation Flour- Usually all purpose flour used forbaking breads. Main function is to give

    structure to the bread. Leavening Agents- Produce gas in

    batters that make baked products rise.

    Steam: high temperatures used in baking heatliquid ingredients enough to form steam.

    Yeast Baking soda and powder

    Formulation

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    Formulation Liquids- Water, milk, and juice are

    common. They serve to hydrate starch to

    absorb water. Fats- Tenderizes the product.

    Eggs- Add color, flavor, and contribute tostructure.

    Salt and sugar- Adds flavor and

    regulates the action of yeast.

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    Typical recipies

    161,200 kg165,700 kg158,200 kgtotal

    2,500 kg4,000 kg1,000 kgImprover

    1,700 kg1,700 kg1,700 kgSalt

    2,500 kg5,000 kg2,500 kgYeast

    55,000 kg55,000 kg53,000 kgWater

    100,000 kg100,000 kg100,000 kgFlour

    BaguettesBread rollPlain white

    bread

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    Typical recipies

    189,700 kgTotal172,700 kgTotal

    15,000 kgImprover

    10,000 kgRaisins1,500 kgImprover

    2,000 kgSugar2,500 kgOlive oil

    1,7000 kgSalt1,700 kgSalt

    8,000 kgYeast1,000 kgYeast

    53,000 kgWater66,000 kgWater

    100,000 kgFlour100,000 kgFlour

    Raisin breadCiabatta

    Mixing

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    Mixing

    Dough Formation

    Doughs are viscoelastic (flows andrecoils)

    Structure largely from proteins calledglutens

    consist of gliadins and glutenins

    30% of amino acid residues arehydrophobic

    water insoluble; can bind water

    Kneading

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    Kneading

    Kneading bread subjects it to shearforces

    promote interactions between gluteninmolecules

    H- bonding, hydrophobic interactions, S-Sbonds

    creates elastic protein networks (films)

    which trap gasviscosity enhanced by gliadins and starch

    molecules

    Kneading is important

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    Kneading is important

    After forming the dough for yeast breads,

    you MUST knead it!!!! Almost all of the gluten forms during the

    kneading stage. It is important to not add

    too much extra flour while kneading. Thiswill make the dough far too stiff.

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    Dough Formation Knead to optimum rheology optimumdough strength

    over-kneading breaks protein structure

    before kneading after optimal kneading

    50 m 1 m

    Temperature control is very

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    important

    Fermentation rate will change in function ofthe temperature : in the same time more (orless) CO2 will produced. If the bread is 10% bigger you need also 10 % more trucks.

    Relationship between humidity and

    temperature : or the dough will get sticky orcrusty in the proofer

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    Dough consistency will change in function of thetemperature i.e. the behaviour on the line will bedifferent

    During lamination the butter or margarine will getcolder or warmer in line with the doughtemperature. To make good puff both should

    have the same consistency

    In 1 hour in 1 kg dough of 28C the yeast will

    metabolise about 10 g of sugar. If the doughhas 29C, the yeast will metabolise 10 % moresugar. Result the bread is less sweet.

    Mixing

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    Mixing

    Temperature control can happen indifferent ways :

    Adding ice to the dough

    Use cold water Cooling the mixing bowl

    Use salt as a saturated solution

    Cool down flour during pneumatic transportwith CO2 (and not injecting CO2 in the dough)

    Bread Fermentation

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    After you knead the dough, what do youdo???

    When you let it rest in a warm place, theyeast acts upon the sugar and the carbondioxide causes the bread to rise. This iscalled FERMENTATION!

    The bread should at least double in sizeduring fermentation

    The fermentation occurs during bread manufacturing

    is different from most other food fermentations Purpose

    Fermentation end products

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    About Yeast Single celled, microscopic plant.

    When you add sugar to yeast, it reacts to thebacteria and creates carbon dioxide. Thisleavens the baked product.

    Water mixed with yeast MUST be between 110and 125 degrees in order to keep the yeast alive.

    Available in three forms:

    Active dry (what we use)- Compressed( very perishable)

    - Fast rising yeast (rises twice as fast)

    Types of Yeast

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    yp Commercially available

    Yeast cream

    Used directly, highly perishable Yeast cake

    Yeast cream through filtration press or vac. filter

    Refrigeration required, shelflife a few week Metabolically active, quick fermentation

    Dry active yeast

    Home bread making, small business operation Last 6 months or longer

    Require hydration, not as active

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    S. cerevisiae, or bakersyeast Properties and characteristics for bread

    making

    Gassing power

    Flavor development

    Stable to drying Stable during storage

    Easy to dispense

    Ethanol

    cryotolerant

    Yeast Cultures

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    Growth medium Molasses or another inexpensive source of sugar and

    various ammonium salts

    Other yeast nutrients Ammonium phosphate Magnesium sulfate Calcium sulfate, trace minerals (zinc, iron)

    Cell mass production required conditions O2 level Temp (30C)

    pH (4.0-5.0) continuous

    Fermentation

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    Fermentation

    Lag phase usually

    Bakersyeast facultative metabolism Aerobic (via TCA cycle)

    Anaerobic glycolytic fermentation pathway

    Glucose inhibit TCA enzymes

    CO2

    Sugar metabolism by bakers yeast

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    g y y

    Carbohydrate sources Starch

    Sugars (glucose and maltose) Transport and utilization

    Sequential use Regulation-glucose represses enzymes involved in

    maltose transportation

    Maltose represses invertase expression

    Mutants available Sugar transport

    Glycolysis

    Fermentation

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    End products

    CO2

    Other compounds Various acids and organic compound by yeasts

    By LAB

    Flavor and rheology of the dough

    Factors affecting growth

    Temp-hold at 25-28 instead of the optimalgrowth temp 36-39 to minimize microbailcontamination, and maintain yeast activity

    Relative humidity 70-80%

    Glucose

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    Glucose 6-phosphate

    Fructose 6-phosphate

    Fructose 1, 6 phosphate

    DGAPDihydroxyacetone

    PGALGlyceraldehyde

    3-phosphate

    PEP

    Phosphenopyruvate

    Pyruvate

    Oxaloacetate

    Respiration Chain

    TCA Cycle

    CO2

    CO2Lactic acid Acetyl CoA

    +36 ATP

    Ethanol

    CO2+2 ATP

    +2 ATP

    Factors affecting fermentation

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    g

    Too much salt inhibits yeast activity, reducing

    the amount of carbon dioxide gas producedand decreasing the volume of the loaf.

    No salt Normal salt Double salt

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    Punching Down! When the dough has risen all

    the way and has doubled insize, you have to punch it

    down to release some of the

    carbon dioxide. Some dough requires a

    second rising period.

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    Avoid Over fermentation

    Gluen streches, becomes weak andcan collapse

    Coarse grain & sour odor due toexcess acid production

    Less color in baked crust

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    Oven spring The quick expansion of dough during the

    first ten minutes of baking, caused byexpanding gases.

    Baking

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    30 C1.CO2-gas expands

    2.increased enzymatic activity3.reduced solubility of CO2 in water

    45 50 C1.yeast dies

    50 60C

    1.intensive enzymatic activity2.starch begins to gelatinise

    Baking

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    Types of ovens

    1. According to heating system directly fired

    indirectly fired (air, oil)

    2. According to product movement static ovens

    continuous belt ovens (tunnel ovens) rotary ovens (horizontal & vertical)

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    Types of ovens

    3. According to type of fuel

    gas

    gasoil

    4. According to heard type

    stone metal (including baking trays)

    Cooling & Freezing

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    Don't touch the bread as long as the crumb hasmore then 80C (semi liquid damage of

    structure staling)

    During cooling and freezing bread looses about

    2 % of its weight (i.e. water loss)

    Freezing : only water freezes. Because of the

    difference in moisture content between the crustand the crumb, the crust can flake off.

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    Cooling & Freezing

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    In the case of frozen dough, special attention hasto be paid to :

    1.Freshness of the yeast, type of yeast (freezetolerant), quantity of the yeast (more but toomuch can be negative weakening ofgluten structure).

    2.Avoid that fermentation starts beforefreezing (unless you make preproofed frozen

    of course)3.Handling in the shop : slow thawing to get

    even temperature distribution in the product

    before proofing and baking (retarder-proofer)

    Cooling & Freezing

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    During storage at - 18C theproduct looses moisture and

    becomes drier and drier(flaking).

    This depends on the storageconditions (air velocity,temperature fluctuations and

    relative humidity in thefreezer) = freeze burn

    Understanding how bread rises

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    When yeast (block or dried) is mixed with waterand sugar it becomes frothy.

    The yeast cells multiply, this process is calledfermentation. Fermentation stops if the

    water/dough is too hot or cold or if there is nosugar.

    Yeast mixture or dried yeast is added to flour,t d th i di t k d d d

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    The loaf tin is put in the oven, the heat killsthe yeast and cooks the dough leavening a'risen' loaf.

    Carbon dioxide gas is produced by the yeastwithin the dough forming pockets whichmakes the dough rise in the warmth. Thisprocess is called proving.

    water and other ingredients, kneaded andplaced in a loaf tin.

    6 Bakery prodcut technology

    l

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    examples

    Sour dough Bread

    Bread product

    Breakfast Foods

    Example1- Sour dough Bread

    Sour dough rye bread

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    Sour dough rye bread Most studied bacterial bread fermentation

    Popular in Europe

    Micro-organisms isolated from sour rye Bacteria: Lb. plantarum, Lb. brevis, Lb. casei, Lb.

    fermenti, Lb. pastorianus, Lb. buchneri, Lb.leichmannii, Lb. acidophilus, Lb. farciminis, Lb.alimentarius, Lb. vrevis var. lindneri, Lb.fermentum, Lb. fructivarans, Pediococcusacidilactici

    LAB with very high amino acid requirementdominant

    Yeasts: Candida krusei, Saccharomycescerevisiae, Pichia saitoi, Torulopsis holmii

    Candida kruseidominant

    Sour Dough Bread

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    The San Francisco sourdough Frenchbread

    Use start culture ormother-sponge Occurred in San Francisco, continuously used

    for over 140 years

    Ecosystem consists of on species of yeastand one species of bacteria

    Occurred in a ratio of 1:100

    Yeast- Candida milleri(or Torulopsis holmii)

    Bacteria- Lb. sanfrancisco

    Formulations for San Francisco Sour Dough

    French Bread

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    French Bread

    Starter-sponge Bread dough

    100 parts of previous sponge 20 parts starter-sponge

    (40% of final mix) (11% of final mix)

    100 parts flour (high-gluten) 100 parts flour (regular patent)

    46-52 parts water 60 parts water

    2 parts salt

    Starting pH 4.4-4.5 Starting pH 5.2-5.3

    Final pH 3.8-3.9 Final pH 3.9-4.0

    Example2 Bread product

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    Flour arrives in tankers at the bakery and isstored in silos. Typically holding 50 tons of

    sifted flour.

    Computer-controlled mixer weighs flour

    and water. Batches of dough are mixedevery few minutes.

    Yeast, salt and other ingredients are addedautomatically.

    Batches of dough are divided into portionsfor 400g or 800 Conical moulders shapedough into balls to produce 8000 loaves

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    dough into balls to produce 8000 loavesper hour. g loaves at a speed of125 loaves per minute.

    Conical moulders shape dough into ballsto produce 8000 loaves per hour.

    First prover allows dough to 'rest' for 6-8minutes.

    Panner moulder shapes dough for final

    product

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    product

    Dough spends 50 minutes in final prover andexpands in controlled humidity and temperature.

    Bread travels through the oven for 20-25 minutes.Lids are added to some tins to produce flat-toppedbread. 6000 large or 8000 small loaves are baked perhour.

    Lids and pans removed before cooling for 2-

    3 hours in the cooler.

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    3 hours in the cooler.

    The bread is sliced and regular samples aretaken away to be inspected to ensure qualityis maintained.

    Bread is packaged, stacked and put ontolorries for distribution.

    Example 3 Break fast FoodsBreak fast Foods

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    Ready-to-eat cereals Quick-cooking/instant cereals

    Raw/old-fashioned cereals

    Prepar ing Cook edPrepar ing Cook ed

    Break fast Cerea lsBreak fast Cereals

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    Break fast Cerea lsBreak fast Cereals Use recommended

    amount of water.

    To prevent lumping,slowly add dry cereal toboiling water or mix first

    with cold water to form apaste.

    Gently stir cereal with a

    fork. Cook cereal until it

    thickens and absorbs allthe water.

    Prepar ing Ric ePrepar ing Ric e

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    Cook over direct heat,

    in a double boiler, or inthe oven.

    Use recommended

    proportions of rice andwater and cook until allliquid is absorbed.

    National Chicken Council

    Prepar ing Past aPrepar ing Past a

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    Add pasta gradually toboiling water.

    Simmer just until tender.

    Drain but do not rinsecooked pasta.

    National Pasta Association