========================================================================================= MSDSSafety Information

=========================================================================================TOP

FSC:

6810

MSDS Date:

12/08/1992

MSDS Num:

BTXDX

Submitter:

N EN

LIIN:

00N045417

Tech Review:

10/16/1995

Status CD:

C

Product ID:

CUPROUS CHLORIDE

MFN:

01

Article:

N

Kit Part:

N

Responsible Party

Cage:

ZA916

Name:

MALLINCKRODT

Box:

800

City:

PARIS

State:

KY

Zip:

40362

Country:

US

Info Phone Number:

314−539−1600

Emergency PhoneNumber:

314−539−1600

Radioactive Ind:

N

Preparer's Name:

N/P

Proprietary Ind:

N Review Ind:N

Published:Y Special Project CD:N

========================================================================================= ContractorSummary =========================================================================================TOP

Cage:

ZA916

Name:

MALLINCKRODT MEDICAL, INCAddress:

2703 WAGNER PLACE

Box:

MCity:

MARYLANDHEIGHTS

State:

MO

Zip:

63043

Country:

US

Phone:

314−770−7800

Cage: Name:

1

62910 MALLINCKRODT SPECIALTY CHEMICALS COAddress:

222 RED SCHOOL LANECity:

PHILLIPSBURG

State:

NJ

Zip:

08865Country:

US

Phone:

908−859−2151

=========================================================================================Ingredients

=========================================================================================TOP

Cas: 7758−89−6

Code:

M

RTECS #:

GL6990000

Code:

M

Name: COPPER (I) CHLORIDE; (CUPROUS CHLORIDE)

% Text: N/K Environmental Wt:

Other REC Limits:N/KOSHA PEL:

1 MG/M3 (CU) (MFR) Code:M OSHASTEL:

Code:

ACGIH TLV: 1 MG/M3 (CU) (MFR) Code:M ACGIHSTEL:

N/P Code:

EPA Rpt Qty: DOTRpt

Qty:

Ozone Depleting Chemical:

N

Cas:

Code:

X

RTECS #:

9999999ZZ

Code:

M

Name: FIRST AID PROC:PERSISTS. EYE:WASH W/PLENTY OF WATER FOR AT LST 15 MINS, LIFTINGLOWER & UPPER EYELIDS OCCAS. GET (ING 3)

% Text: N/K Environmental Wt:

Other REC Limits:N/KOSHA PEL:

NOT APPLICABLE Code:M OSHASTEL:

Code:

ACGIH TLV: NOT APPLICABLE Code:M ACGIHSTEL:

N/P Code:

EPA Rpt Qty: DOTRpt

Qty:

Ozone Depleting Chemical:

Cas: X 9999999ZZ M

2

Code: RTECS #: Code:

Name: ING 2:MEDICAL ATTENTION IMMEDIATELY.

% Text: N/K Environmental Wt:

Other REC Limits:N/KOSHA PEL:

NOT APPLICABLE Code:M OSHASTEL:

Code:

ACGIH TLV: NOT APPLICABLE Code:M ACGIHSTEL:

N/P Code:

EPA Rpt Qty: DOTRpt

Qty:

Ozone Depleting Chemical:

Cas:

Code:

X

RTECS #:

9999999ZZ

Code:

M

Name: RESP PROT:MAY BE WORN.

% Text: N/K Environmental Wt:

Other REC Limits:N/KOSHA PEL:

NOT APPLICABLE Code:M OSHASTEL:

Code:

ACGIH TLV: NOT APPLICABLE Code:M ACGIHSTEL:

N/P Code:

EPA Rpt Qty: DOTRpt

Qty:

Ozone Depleting Chemical:

Cas:

Code:

X

RTECS #:

9999999ZZ

Code:

M

Name: VENT:PREFERRED BECAUSE IT CAN CONTROL EMISSIONS OF CONTAM AT ITS SOURCE,PREVENTING DISPERSION OF IT INTO GEN (ING 6)

% Text: N/K Environmental Wt:

Other REC Limits:N/KOSHA PEL:

NOT APPLICABLE Code:M OSHASTEL:

Code:

3

ACGIH TLV: NOT APPLICABLE Code:M ACGIHSTEL:

N/P Code:

EPA Rpt Qty: DOTRpt

Qty:

Ozone Depleting Chemical:

Cas:

Code:

X

RTECS #:

9999999ZZ

Code:

M

Name: ING 5:WORK AREA. PLEASE REFER TO ACGIH DOCUMENT, "INDUSTRIAL VENTILATION, AMANUAL OF RECOMMENDED PRACTICES", (ING 7)

% Text: N/K Environmental Wt:

Other REC Limits:N/KOSHA PEL:

NOT APPLICABLE Code:M OSHASTEL:

Code:

ACGIH TLV: NOT APPLICABLE Code:M ACGIHSTEL:

N/P Code:

EPA Rpt Qty: DOTRpt

Qty:

Ozone Depleting Chemical:

Cas:

Code:

X

RTECS #:

9999999ZZ

Code:

M

Name: ING 6:MOST RECENT EDITION, FOR DETAILS.

% Text: N/K Environmental Wt:

Other REC Limits:N/KOSHA PEL:

NOT APPLICABLE Code:M OSHASTEL:

Code:

ACGIH TLV: NOT APPLICABLE Code:M ACGIHSTEL:

N/P Code:

EPA Rpt Qty: DOTRpt

Qty:

Ozone Depleting Chemical:

Cas:

Code:

X

RTECS #:

9999999ZZ

Code:

M

Name: EYE PROT: LENGTH FACESHIELD (FP N).

4

% Text: N/K Environmental Wt:

Other REC Limits:NONE RECOMMENDEDOSHA PEL:

NOT APPLICABLE Code:M OSHASTEL:

Code:

ACGIH TLV: NOT APPLICABLE Code:M ACGIHSTEL:

N/P Code:

EPA Rpt Qty: DOTRpt

Qty:

Ozone Depleting Chemical:

========================================================================================= HealthHazards Data

=========================================================================================TOP

LD50 LC50 Mixture

LD50:(ORAL,RAT) 140 MG/KG.

Route Of Entry Inds − Inhalation:YES Skin:NO Ingestion:YES

Carcinogenicity Inds − NTP:NO IARC:NO OSHA:NO

Health Hazards Acute And Chronic

ACUTE:INHAL:CAUSES IRRIT TO UPPER RESP TRACT, SYMPS MAY INCL COUGH, SORE THROAT &SHORTNESS OF BREATH. MAY ALSO CAUSE SYMPS SIMILAR TO COMMON COLD; INCL CHILLS &STUFFINESS OF HEAD. INGEST:MAY CAUSE B URNING PAIN IN MOUTH, ESOPHAGUS &STOM.HEMORRHAGIC GASTRITIS, NAUS, VOMIT, ABDOM PAIN, METALLIC TASTE,(EFTS OF OVEREXP)

Explanation Of Carcinogenicity

NOT RELEVANT

Signs And Symptions Of Overexposure

HLTH HAZ:& DIARR MAY OCCUR. IF VOMIT DOES NOT OCCUR IMMED, SYSTEMIC COPPER POIS MAYOCCUR. SYMPS MAY INCL CAPILLARY DMG, CENTRAL NERV EXCITATION FOLLOWED BY DEPRESS,JAUNDICE, CONVLS, PARAL & COMA. DE ATH MAY OCCUR FROM SHOCK/RENAL FAILURE.SKIN:CAUSESIRRIT, REDNESS & PAIN. SOME INDIVIDUALS MAY DEVELOP COPPER (SUPDAT)

Medical Cond Aggravated By Exposure

PERSONS W/PRE−EXISTING SKIN DISORDERS OR IMPAIRED LIVER, KIDNEY OR PULMONARY FUNCTION ORPRE−EXISTING WILSON'S DISEASE MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS MATERIAL.

First Aid

5

INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. CALLMD. INGEST:INDUCE VOMIT IMMED BY GIVING 2 GLASSES OF WATER/MILK IF AVAIL & STICKING FINGERDOWN THROAT. CA LL MD IMMED. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERS. SKIN:REMOVEANY CONTAM CLTHG. WIPE OFF EXCESS FROM SKIN. WASH W/SOAP & WATER FOR AT LST 15 MINS. GETMED ATTN IF IRRIT DEVELOPS/ (ING 2)

Spill Release Procedures

VENTILATE AREA OF LEAK/SPILL. CLEAN−UP PERSONNEL REQUIRE PROTECTIVE CLOTHNG & NIOSH/MSHAAPPROVED RESP PROTECTION FROM DUST. PICK UP & PLACE IN SUITABLE CONTAINER FORRECLAMATION/DISPOSAL IN METHOD TH AT DOES NOT GENERATE DUST.

Neutralizing Agent

NONE SPECIFIED BY MANUFACTURER.

Waste Disposal Methods

WHATEVER CANNOT BE SAVED FOR RECLAMATION MAY BE DISPOSED IN A RCRA APPROVED WASTEDISPOSAL FACILITY. DO NOT FLUSH TO SEWER. TOXIC TO FISH. ENSURE COMPLIANCE W/LOCAL, STATE &FEDERAL REGULATIONS.

Handling And Storage Precautions

KEEP IN A TIGHTLY CLOSED CONTAINER, STORED IN A COOL, DRY, VENTILATED AREA. PROTECTAGAINST PHYSICAL DAMAGE. ISOLATE FROM INCOMPATIBLE SUBSTANCES.

Other Precautions

WARNING! HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES & RESPIRATORYTRACT. AVOID BREATHING DUST. KEEP CONTAINER CLOSED. USE W/ADEQUATE VENTILATION. AVOIDCONTACT W/EYES, SKIN & CLO THING. CORROSIVE MATERIAL.

========================================================================================= Fire andExplosion Hazard Information

=========================================================================================TOP

Flash Point Method:

N/P

Flash Point: Flash Point Text:N/K

Autoignition Temp: Autoignition Temp Text:N/A

Lower Limits: N/K Upper Limits:N/K

Extinguishing Media

USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE.

Fire Fighting Procedures

6

USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N).

Unusual Fire/Explosion Hazard

NOT CONSIDERED TO BE A FIRE OR EXPLOSION HAZARD. REACTIONS W/INCOMPATIBILITIES MAY POSE ANEXPLOSION HAZARD.

========================================================================================= ControlMeasures =========================================================================================TOP

Respiratory Protection

IF TLV IS EXCEEDED, NIOSH/MSHA APPRVD DUST/MIST RESP W/CHEM GOGGS MAY BE WORN, IN GEN,UP TO 10 TIMES THE TLV. CONSULT RESP SUPPLIER FOR LIMITATIONS. ALTERNATIVELY,NIOSH/MSHA APPRVD SUPPLIED AIR FULL FACEPIECE RESP/AIRLINED HOOD (ING 4)

Ventilation

SYS OF LOC &/OR GEN EXHST IS REC TO KEEP EMPLOYEE EXPOS BELOW AIRBORNE EXPOS LIMS. LOCEXHST VENT IS GENERALLY (ING 5)

Protective Gloves

IMPERVIOUS GLOVES (FP N).

Eye Protection

ANSI APPVD CHEM WORK GOGG W/FULL (ING 8)

Other Protective Equipment

WEAR CLEAN BODY−CVERING CLOTHING. MAINT ANSI APPVD EYE WASH FOUNT QUICK−DRNCHFACILS IN WORK AREA.

Work Hygienic Practices

WASH THOROUGHLY AFTER HANDLING. CONTACT LENSES SHOULD NOT BE WORN WHEN WORKINGW/THIS MATERIAL.

Supplemental Safety and Health

EFTS OF OVEREXP:ALLERGIES. EYE:CAUSES IRRIT, REDNESS, PAIN, DISCOLORATION & DMG.CHRONIC:PRLNG/RPTD SKIN EXPOS MAY CAUSE DERM. PRLNG/RPTD EXPOS TO DUSTS OF COPPERSALTS MAY CAUSE DISCOLORATION OF SKIN /HAIR, ULCERATION & PERFORATION OF NASALSEPTUM, RUNNY NOSE, METALLIC TASTE & ATROPHIC CHANGES & IRRIT OF MUC MEMBS.

=========================================================================================Physical/Chemical Properties

=========================================================================================TOP

HCC:

T6 NRC/State LIC No:

7

Net Prop WT For Ammo:

Boiling Point: B.P. Text:2491F,1366C

Melt/Freeze Pt: M.P/F.P Text:806F,430C

Decomp Temp: Decomp Text:N/K

Vapor Pres:0.975@546C Vapor Density:N/K

Volatile Org Content %: Spec Gravity:4.14

VOC Pounds/Gallon:

PH: N/K

VOC Grams/Liter: Viscosity: N/P

Evaporation Rate & Reference:N/K

Solubility in Water:0.62 G/100 ML WATER.

Appearance and Odor:WHITE CRYSTALS; ODORLESS.

Percent Volatiles by Volume:N/K Corrosion Rate:N/K

========================================================================================= Reactivity Data========================================================================================= TOP

Stability Indicator:

YES

Stability Condition To Avoid:NONE SPECIFIED BY MANUFACTURER.

Materials To Avoid:POTASSIUM, ACETYLENE, HYDRAZINE NITROMETHANE.

Hazardous Decomposition Products:EMITS TOXIC FUMES OF CHLORINE WHEN HEATED TODECOMPOSITION.

Hazardous Polymerization Indicator:NO

Conditions To Avoid Polymerization

:

NOT RELEVANT

========================================================================================= Toxicological Information========================================================================================= TOP

Toxicological Information:

N/P

========================================================================================= Ecological Information========================================================================================= TOP

Ecological:

8

N/P

========================================================================================= MSDS TransportInformation ========================================================================================= TOP

Transport Information:

N/P

========================================================================================= Regulatory Information========================================================================================= TOP

Sara Title III Information:

N/P

Federal Regulatory Information:N/P

State Regulatory Information:N/P

========================================================================================= Other Information========================================================================================= TOP

Other Information:

N/P

========================================================================================= HMISHAZCOM Label

=========================================================================================TOP

Print Labels

Product ID:

CUPROUS CHLORIDE

Cage:ZA916 Assigned IND:N

Company Name:

MALLINCKRODT MEDICAL, INC

Street:2703 WAGNER PLACE PO Box:M

City:

MARYLAND HEIGHTS State:MO Zipcode:63043

Country: US

Health Emergency Phone:

314−539−1600

Label Required IND:

Y Date Of Label Review:11/17/1993

Status Code:C MFG Label NO:

Label Date:11/17/1993 Year Procured:

Origination Code:

G Chronic Hazard IND:Y

9

Eye Protection IND:YES Skin Protection IND:YES

Signal Word:WARNING Respiratory ProtectionIND:

YES

Health Hazard:

Moderate

Contact Hazard:Moderate

Fire Hazard:

None

Reactivity Hazard:None

Hazard And Precautions

ACUTE:INHAL:CAUSES IRRITATION TO UPPER RESPIRATORY TRACT, SYMPTOMS MAY INCLUDE COUGHING,SORE THROAT & SHORTNESS OF BREATH. MAY ALSO CAUSE SYMPTOMS SIMILAR TO COMMON COLD;INCLUDING CHILLS & STUFFINES S OF HEAD. INGEST:MAY CAUSE BURNING PAIN IN MOUTH, ESOPHAGUS &STOMACH. HEMORRHAGIC GASTRITIS, NAUSEA, VOMITING, ABDOMINAL PAIN, METALLIC TASTE & DIARRHEA.IF VOMITING DOES NOT OCCUR IMMEDIATELY, SYST EMIC COPPER POISONING MAY OCCUR, CAUSINGCAPILLARY DAMAGE, CNS EXCITATION & DEPRESSION, JAUNDICE, CONVULSIONS, PARALYSIS, COMA.SKIN:IRRITATION. EYES:IRRITATION, REDNESS, PAIN, DAMAGE. CHRONIC:SKIN:IR RITATION. INHAL:IRRITATION.==========================================================================================================This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends saidinformation to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of theUnited States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seekcompetent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department ofDefense or other government situation.

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