Upload
thiru1mech
View
48
Download
1
Embed Size (px)
Citation preview
05/01/2023Dept. of Metallurgical Engineering
1
THERMAL SPRAY COATINGSSubmitted byTHIRUNAVUKARASU.H13MY12Dept. Of Metallurgical Engineering
05/01/2023Dept. of Metallurgical Engineering
2
Need For Surface Hardening
•Produce surfaces that ▫wear only a little,▫resistant to tarnishing and corrosion,
05/01/2023Dept. of Metallurgical Engineering
3
Thermal Spray Coating•A group of coating processes where the coating is
deposited on a prepared substrate by applying a stream of particles, metallic or nonmetallic, which flatten more or less forming platelets, called splats, with several layers of these splats forming the coating
•Any material on almost any substrate
05/01/2023Dept. of Metallurgical Engineering
4
Spray Coatings• Use either axial or radial consumable injection in a high energy
flow resulting from combustion or high-velocity gas streams.
• Coating thickness▫50 μm to a few mm
• Bonding▫Substrate surface
undercuts simple roughening
05/01/2023Dept. of Metallurgical Engineering
5
Components• An energetic gas flow
▫ An appropriate gun Devices for feeding, accelerating, heating, and directing the flow of a thermal
spray material toward the substrate.
• Feedstock▫ Powder, wire, rod, or cord. ▫ Fed at a velocity allowing the spray gun to melt them
• Auxiliary gas feed ▫ To accelerate atomized molten material into the spray gun
• Controlled atmosphere or a soft vacuum▫ In air, coating oxidation occurs, increasing with the temperature
05/01/2023Dept. of Metallurgical Engineering
6
Substrate•Should not be degraded by heat•Substrate should be roughened for good adhesion
▫Abrasive blasting – Aluminium Oxide▫2.5 µm roughness optimum
•Difficult to spray hardened steels•Thin sections prone to distortion during blasting and
heating
05/01/2023Dept. of Metallurgical Engineering
7
Fig: Components of spray coating system
05/01/2023Dept. of Metallurgical Engineering
8
Steps In Spray Coating1. Substrate preparation
2. Generation of the energetic gas flow
3. Particle or wire or rod or cord injection
4. Energetic gas particle or droplet interaction
5. Coating formation
05/01/2023Dept. of Metallurgical Engineering
9
Thermal Spray Hardening•Gas Combustion
▫Oxy fuel process using Wire feed Powder feed Rod feed Jet / powder feed Detonation Gun process
•Arc process▫Plasma arc with powder feed▫Arc spray with wire feed
05/01/2023Dept. of Metallurgical Engineering
10
Wire Processes
•Wire from reel fed to oxyacetylene flame•Metal droplets atomized by air jets•Atomized metal spray coats substrate•Gun to substrate distance
10 – 25mm
•Commonly sprayed materials• Zn, Al for corrosion resistance• Bronzes for wear resistance
05/01/2023Dept. of Metallurgical Engineering
11
•Wear application: 1.25mm•Corrosion resistance: 25µm•Max thickness : 6mm
•Deposition rate: 93m2 per hour per 25µm
•Flame temperature: 27600C
05/01/2023Dept. of Metallurgical Engineering
12
Powder Spray
•Powder feed instead of wire•Oxyacetylene torch modified for powder feed•No high pressure air to assist atomization; low deposition rate•Lower bond strength and higher porosity•Easy method for materials that cannot be made into wire
05/01/2023Dept. of Metallurgical Engineering
13
More sophisticated equipment uses compressed air.Increased atomization.Higher deposition rate and bond strength. Flame temperature: 25000C
CoatingsCarbidesHigh alloy steelsCeramics
05/01/2023Dept. of Metallurgical Engineering
14
Rod Consumable
•Ceramics cannot form flexible wire•Coatings made of powder; too friable•Newly designed ones use solid rod of ceramic•Impact velocity: 2.8m/s
•Rod consumables
• Al2O3
• Cr2O3
• Ceramic mixtures
05/01/2023Dept. of Metallurgical Engineering
15
Detonation Gun (D- Gun)
•Powder fed under small gas pressure•Explosive mixture of O2 and acetylene detonated using spark•Temperature: 38700C•Detonation: 4 to 8 times per sec; 730 m/s•N2 gas for flushing detonated gas•Coating thickness: 75 to 125µm
•Noisy process; done in soundproof room•For• Carbides• Ceramics
•High bond strength and coating density•Good surface finish
05/01/2023Dept. of Metallurgical Engineering
16
Combustion Jet Or High Velocity Oxygen Fuel (HVOF) Process
•Continuous gas combustion jet: heat source and carrier• O2 and fuel gas like propylene, H2
•Consumable sprayed as powder to center of jet stream•Temperature: 29800C and velocity:
1370 m/s
•45kg per hour deposition rate•Consumable: Tungsten carbide, cobalt•High bond strength•High cost and safety issues involved
05/01/2023Dept. of Metallurgical Engineering
17
Electric Arc Spraying
•Uses electric arc as heating source•Uses two consumable wires: higher deposition rate•Wires on motor driven feed rolls and insulated from each other meet at tip of torch•After energizing the torch, wires on
contact produce arc•Arc melts metal and air jet carries it to substrate•Wires as large as 1.5mm•Spraying soft materials for corrosion resistance; Zn, Al
05/01/2023Dept. of Metallurgical Engineering
18
Plasma Arc Deposition
• Consumable powder melted and atomized in plasma▫ Tungsten electrodes and Ar gas▫ Temperature: 28000oC
05/01/2023Dept. of Metallurgical Engineering
19
Fig: Paper machine roll coated by NiCrBSi using two powder flame guns (Courtesy of Castoline)
05/01/2023Dept. of Metallurgical Engineering
20
Fig: (a) PTA-coated tooth of excavator with Ni base coating + WC (25 kg/h) and (b) cross section of the coating (courtesy of Castolin)
05/01/2023Dept. of Metallurgical Engineering
21
ComparisonProperties Electro/ electroless
platingCVD PVD Thermal spray
Equipment cost Low Moderate Moderate to high Moderate to high
Operating cost Low Low to moderate
Moderate to high Low to high
Coating thickness 10 μm–mm 10 μm–mm Very thin tomoderate
50 μm–mm
Adherence Moderate mechanical to good chemical bond
good chemical to excellent diffusion Bond
Moderate mechanicalto good Chemical Bond
Good mechanical bond
Coating materials Metals Metals, ceramics, Polymers
Metals, ceramics,polymers
Metals, cermets,ceramics,polymers
Surface finish Moderately coarseto glossy
Smooth to glossy
Smooth to glossy Coarse toSmooth (0.12 µm to 0.5 µm)
05/01/2023Dept. of Metallurgical Engineering
22
Coating Evaluation• Destructive testing: Tensile shear tests
▫ Ends of two strips of desired substrate are sprayed with desired consumable
▫ Coated ends epoxied together▫ Uncoated ends put to tensile tester and pulled to failure▫ If epoxy fails and the coating is intact
Good coating Bond strength as “greater than X”, X- tensile strength of epoxy 82 to 138 MPa nominal
• Non-destructive testing▫ Visual inspection
Porosities, impurities, cracks▫ UT inspection, Thermal imaging
05/01/2023Dept. of Metallurgical Engineering
23
Comparison Between Spray Processes• Wire gun
▫ Heavy deposits: upto 0.100 inch▫ For steels, brass, bronze
• Powder module▫ Minor shop repairs: upto 0.030
inch▫ For nickel base alloys
• Rod feed▫ Wear resistant coatings: upto
0.020 inch▫ For ceramics
• D-gun
▫ Premier coatings: upto 0.010 inch
▫ Of hardfacing alloys, carbides▫ Densest coating
• Electric arc▫ Rebuilding large areas with
steels: upto 0.100 inch▫ For Al and Zn
• Plasma arc▫ Applying hardfacing alloys,
repairs: upto 0.015 inch▫ For metals and ceramics
05/01/2023Dept. of Metallurgical Engineering
24
Applications of Spray Coating•Wear-resistant coatings against abrasion, erosion•Corrosion-resistant coatings•Heat resistant coatings•Thermal insulation or conduction coatings•Electromagnetic shielding•Medical coatings
05/01/2023Dept. of Metallurgical Engineering
25
Do’s And Don’t’s Of Thermal Spray Coating
•Do’s•Apply coating to
undercuts to avoid end chipping
•Hold gun normal while spraying
•Plug keyways when coating
•Don’t’s•Coat end of parts subject
to chipping•Coat faces subject to
impact•Spray at an angle < 600
•Coat cutting edges
05/01/2023Dept. of Metallurgical Engineering
26
Reference1. Cartier M, Handbook of surface treatments and coatings.
ASME Press, New York, NY, 20032. Davis JR, Handbook of thermal spray technology. ASM
International, Materials Park, OH, 20043. Chattopadhyay R (2001), Surface wear. ASM International,
Materials Park, OH4. Kenneth G. Budinski, Surface Engineering for Wear
Resistance, Prentice Hall Inc., 1988, Pg: 221-240.5. ASM Handbook volume 4, Heat Treatment, 1991.