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www.hr.is Utilization of Chloride Bearing High Enthalpy Geothermal Fluid Gudrun SAEVARSDOTTIR, Steindór HJARTARSON, Kristinn INGASON, Bjarni PALSSON, William S. HARVEY Reykjavik University, Mannvit Engineering, Landsvirkjun GEORG Geothermal Workshop, November 2016

B1 Guðrún A. Sævarsdóttir Utilization of the Chloride Bearing, Superheated Steam from IDDP-1

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Page 1: B1 Guðrún A. Sævarsdóttir Utilization of the Chloride Bearing, Superheated Steam from IDDP-1

www.hr.isGEORG Geothermal Workshop, November 2016

Utilization of Chloride Bearing High Enthalpy Geothermal Fluid

Gudrun SAEVARSDOTTIR, Steindór HJARTARSON, Kristinn INGASON, Bjarni PALSSON, William S.

HARVEYReykjavik University, Mannvit Engineering,

Landsvirkjun

Page 2: B1 Guðrún A. Sævarsdóttir Utilization of the Chloride Bearing, Superheated Steam from IDDP-1

www.hr.isGEORG Geothermal Workshop, November 2016

The heat source - Magma

Page 3: B1 Guðrún A. Sævarsdóttir Utilization of the Chloride Bearing, Superheated Steam from IDDP-1

www.hr.isGEORG Geothermal Workshop, November 2016

Fluid from Deep Roots of Geothermal systems

Page 4: B1 Guðrún A. Sævarsdóttir Utilization of the Chloride Bearing, Superheated Steam from IDDP-1

www.hr.isGEORG Geothermal Workshop, November 2016

High enthalpy steam – superheated or SC?

Page 5: B1 Guðrún A. Sævarsdóttir Utilization of the Chloride Bearing, Superheated Steam from IDDP-1

www.hr.isGEORG Geothermal Workshop, November 2016

Iceland Deep Drilling Project (IDDP)• Purpose of IDDP:

– Drill deeper to obtain a higher enthalpy steam, preferably supercritical • T>374 °C• P>220 bar

– For supercritical drill a 5km deep well

• Why:– Higher enthalpy and mass flow gives a more powerful well

• IDDP-1– The first well, IDDP-1, 2.2 km deep

Page 6: B1 Guðrún A. Sævarsdóttir Utilization of the Chloride Bearing, Superheated Steam from IDDP-1

www.hr.isGEORG Geothermal Workshop, November 2016

IDDP1 at Krafla, north Iceland

Page 7: B1 Guðrún A. Sævarsdóttir Utilization of the Chloride Bearing, Superheated Steam from IDDP-1

www.hr.isGEORG Geothermal Workshop, November 2016

The wild well IDDP-1• 12 hours after

opening:– T=410°C,

P=40bar, h=3150kJ/kg

• Chemicals in the steam– HCl, sulphur,

silica fumes Tekið af http://georg.hi.is/files/IDDP%20-%20GOF.pdf þann 16.11.11

Page 8: B1 Guðrún A. Sævarsdóttir Utilization of the Chloride Bearing, Superheated Steam from IDDP-1

www.hr.isGEORG Geothermal Workshop, November 2016

HCl in superheated steam a problem

• HCl dissolves in the first droplets formed

• Potent hydrocloric acid• Corrodes metal!

Must be scrubbed from the steam before it enters sensitive components

Page 9: B1 Guðrún A. Sævarsdóttir Utilization of the Chloride Bearing, Superheated Steam from IDDP-1

www.hr.isGEORG Geothermal Workshop, November 2016

Silica fumes

• Fumes from IDDP condensed as amorphous silica particles

• Formed as pressure dropped below 80 bar

• Similar to industrial microsilica particles

Page 10: B1 Guðrún A. Sævarsdóttir Utilization of the Chloride Bearing, Superheated Steam from IDDP-1

www.hr.isGEORG Geothermal Workshop, November 2016

What can be done?• Dry scrubbing

– Steam lead through a compound which will absorb HCl before it enters the turbine

• Wel schrubbing– NaOH or another base sprayed into the steam to dissolve the HCl

• Binary Cycle– Heat transferred into a binary cycle through a heat exchanger

In any case, the power plant must be designed with regard to the gas treatment configuration.

Page 11: B1 Guðrún A. Sævarsdóttir Utilization of the Chloride Bearing, Superheated Steam from IDDP-1

www.hr.isGEORG Geothermal Workshop, November 2016

Wet scrubbing - 1

Chemicals: NaOH

Page 12: B1 Guðrún A. Sævarsdóttir Utilization of the Chloride Bearing, Superheated Steam from IDDP-1

www.hr.isGEORG Geothermal Workshop, November 2016

Wet scrubbing - 2

Page 13: B1 Guðrún A. Sævarsdóttir Utilization of the Chloride Bearing, Superheated Steam from IDDP-1

www.hr.isGEORG Geothermal Workshop, November 2016

Wet scrubbing - 3

Page 14: B1 Guðrún A. Sævarsdóttir Utilization of the Chloride Bearing, Superheated Steam from IDDP-1

www.hr.isGEORG Geothermal Workshop, November 2016

Dry Scrubbing

Chemicals: K2CO3,Ca(OH)2, NaHCO3, CaCO3

Page 15: B1 Guðrún A. Sævarsdóttir Utilization of the Chloride Bearing, Superheated Steam from IDDP-1

www.hr.isGEORG Geothermal Workshop, November 2016

Binary cycle

Page 16: B1 Guðrún A. Sævarsdóttir Utilization of the Chloride Bearing, Superheated Steam from IDDP-1

www.hr.isGEORG Geothermal Workshop, November 2016

Mass Flow Rate

Page 17: B1 Guðrún A. Sævarsdóttir Utilization of the Chloride Bearing, Superheated Steam from IDDP-1

www.hr.isGEORG Geothermal Workshop, November 2016

Thermodynamic efficiency as a function of well head pressure

Page 18: B1 Guðrún A. Sævarsdóttir Utilization of the Chloride Bearing, Superheated Steam from IDDP-1

www.hr.isGEORG Geothermal Workshop, November 2016

Output as a function of well head pressure

Page 19: B1 Guðrún A. Sævarsdóttir Utilization of the Chloride Bearing, Superheated Steam from IDDP-1

www.hr.isGEORG Geothermal Workshop, November 2016

Wet scrubbing - 2

Page 20: B1 Guðrún A. Sævarsdóttir Utilization of the Chloride Bearing, Superheated Steam from IDDP-1

www.hr.isGEORG Geothermal Workshop, November 2016

Er í lagi að ég komi við hjá þér á morgun í staðinn fyrir í dag?Er í lagi að ég komi við hjá þér á morgun í staðinn fyrir í dag?

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