SURFACE-WATER-QUALITY ASSESSMENT OF THE YAKIMA RIVER BASIN, WASHINGTON: PESTICIDE AND OTHER TRACE-ORGANIC-COMPOUND DATA FOR WATER, SEDIMENT, SOIL, AND AQUATIC BIOTA, 1987-91By J.F. Rinella, S.W. McKenzie, J.K. Crawford, W.T. Foreman,
P.M. Gates, G.J. Fuhrer, and M.L. Janet
Delmarva Peninsula
U.S. GEOLOGICAL SURVEY Open-File Report 92 644
Portland, Oregon 1992
DEPARTMENT OF THE INTERIOR
MANUEL LUJAN, JR., Secretary
U.S. GEOLOGICAL SURVEY
Dallas L. Peck, Director
For additional information write to: Copies of this report can bepurchased from:
District Chief Bookg and Q File ReportsU.S. Geological Survey Box 25425Water Resources Division U s Geological Survey10615 SE. Cherry Blossom Drive Federal center,Building 810Portland, Oregon 97216 Denver, Colorado 80225
CONTENTS
Page
Abstract ---------------------------------------------------------- 1Introduction ------------------------------------------------------ 1
Background --------------------------------------------------- 2Purpose and scope -------------------------------------------- 2Acknowledgments ---------------------------------------------- 3
Data collection and analysis -------------------------------------- 4Sampling plan ------------------------------------------------ 4Sample collection, processing, and preservation -------------- 4
Whole water --------------------------------------------- 14Filtered water and suspended sediment ------------------- 14Bed sediment and soil ----------------------------------- 15Aquatic biota ------------------------------------------- 15
Laboratory methods ------------------------------------------- 17Quality assurance -------------------------------------------- 17
References -------------------------------------------------------- 19Analytical data --------------------------------------------------- 21
Water-column tables ------------------------------------------22-59Bed-sediment and soils tables --------------------------------60-69Aquatic-biota tables -----------------------------------------70-96
Quality-assurance data -------------------------------------------- 97Water-column tables -----------------------------------------98-116Filtered-water tables --------------------------------------117-125Suspended-sediment tables ----------------------------------126-133Bed-sediment tables ----------------------------------------134-137Aquatic-biota tables ---------------------------------------138-145
Appendix A--Method for analyzing trace-organic compounds infiltered water ------------------------------------------------- 146
Appendix B--Method for analyzing trace-organic compounds insuspended sediment --------------------------------------------- 152
ILL
ILLUSTRATIONSPage
Figure 1. Map showing location of sampling stations for trace- organic compounds in water, suspended sediment, bed sediment, soil, and aquatic biota, Yakima River basin, Washington, 1987-91 -------------------- 10
TABLES
Table 1. Sampling plan for collecting trace-organic-compoundsamples, Yakima River basin, Washington, 1987-91 ----- 5
2. Sampling locations for pesticide and other trace-organic compounds in water, bed sediment, soil, and aquatic biota, Yakima River basin, Washington, 1987-91 ------- 7
3. Common technical name and biological activity of pesticides analyzed in water, sediment, soil, and aquatic biota, Yakima River basin, Washington, 1987-91 ---------------------------------------------- 11
4. Laboratories where whole-water, filtered-water, suspended-sediment, bed-sediment, soil, and aquatic-biota samples were analyzed, Yakima River basin, Washington, 1987-91 -------------------- 18
Analytical Data Water Column
5. Field measurements, suspended sediment, turbidity, organic carbon, and selected nutrient data for surface-water and ground-water sites where water samples were collected, Yakima River basin, Washington, 1988-91 --------------------------------- 22
6. Concentrations of carbamate compounds in whole-watersamples, Yakima River basin, Washington, 1988-91 ---- 27
7. Concentrations of carbamate, thiocarbamate, pyrethoid, and other pesticides in filtered-water samples, Yakima River basin, Washington, June 25-30, 1989 ---- 30
8. Concentrations of chlorophenoxy-acid herbicides, dicamba, and picloram in whole-water samples, Yakima River basin, Washington, 1988-91 ------------- 31
9. Concentrations of chlorophenoxy-acid herbicides, dicamba and picloram in filtered-water samples, Yakima River basin, Washington, June 25-30, 1989 ---- 32
10. Concentrations of organochlorine compounds in whole-water samples, Yakima River basin, Washington, 1988-89 --------------------------------- 33
11. Concentrations of organochlorine compounds in filtered-water samples, Yakima River basin, Washington, June 25-30, 1989 ------------------------ 37
12. Concentrations of organochlorine compounds in filtered-water samples, Yakima River basin, Washington, May-September 1991 ---------------------- 39
13. Concentrations of organochlorine compounds associated with suspended sediment, Yakima River basin, Washington, June 25-30, 1989 ----------------------- 41
iv
TABLES--Continued Analytical Data--Continued Water Column--Continued
Page
14. Concentrations of organochlorine compounds associated with suspended sediment, Yakima River basin, Washington, May-September 1991 ---------------------- 43
15. Concentrations of organophosphorus pesticides in whole-water samples, Yakima River basin, Washington, 1988-89 --------------------------------- 45
16. Concentrations of organophosphorus pesticides in filtered-water samples, Yakima River basin, Washington, June 25-30, 1989 ------------------------ 48
17. Concentrations of organphosphorus pesticides in filtered-water samples, Yakima River basin, Washington, May-September 1991 ---------------------- 50
18. Concentrations of organophosphorus pesticidesassociated with suspended sediment, Yakima Riverbasin, Washington, June 25-30, 1989 ----------------- 51
19. Concentrations of organophosphorus pesticidesassociated with suspended sediment, Yakima Riverbasin, Washington, May-September 1991 --------------- 52
20. Concentrations of phenol and cresol compounds (acid-extractable compounds) in whole-water samples, Yakima River basin, Washington, 1988-89 ---- 53
21. Concentrations of triazine, acetamide,chloroacetanilide, and other pesticidesin whole-water samples, Yakima River basin,Washington, 1988-89 --------------------------------- 54
22. Concentrations of triazine, acetamide,chloroacetanilide, and trifluromethyl compounds in filtered-water samples, Yakima River basin, Washington, June 25-30, 1989 ------------------------ 57
23. Concentrations of volatile organic compounds(halogenated aliphatic and monocyclic aromatichydrocarbons) in whole-water samples, YakimaRiver basin, Washington, 1988-89 -------------------- 58
Bed Sediment and Soils
24. Concentrations of organochlorine compounds, total carbon, and inorganic carbon in bed-sediment and soil samples, Yakima River basin, Washington, 1987-90 -------------------------- 60
25. Concentrations of organophosphorus pesticides in soilsamples, Yakima River basin, Washington, 1989 ------- 63
26. Concentrations of semi-volatile organic compounds (phthalate esters, ethers, phenols, cresols, and monocyclic- and polycyclic-aromatic compounds) in bed-sediment samples, Yakima River basin, Washington, 1987-90 --------------------------------- 63
TABLES- -Continued Analytical Data--Continued
Aquatic BiotaPage
Aquatic Biota
27. Ancillary data, for composite biological samples,collected for analysis of trace-organic compounds, Yakima River basin, Washington, 1989-90 ------------- 70
28. Concentrations of organochlorine compounds inaquatic biota, Yakima River basin, Washington,1989-90 --------------------------------------------- 84
29. Concentrations of semi-volatile organic compounds (polycyclic-aromatic hydrocarbons) in aquatic biota, Yakima River basin, Washington, 1989-90 ------ 94
Quality Assurance Data Water Column
30A-H. Concentrations of carbamate compounds in replicate and (or) spiked whole-water samples from the following locations, Washington:
30A. Cle Elum River above Cle Elum Lake near Roslyn,July 26, 1988, at 1000 hour and 1015 hour ------ 98
SOB. Cherry Creek at Thrall, June 2, 1988, at1400 hour and 1405 hour ------------------------ 98
30C. Wide Hollow Creek near mouth at Union Gap,November 15, 1988, at 1330 hour and 1430hour ------------------------------------------- 98
30D. Moxee Drain at Thorp Road near Union Gap,May 6, 1988, at 0930 hour and 0940 hour -------- 99
30E. Granger Drain at mouth near Granger,July 28, 1988, at 0930 hour and 1015 hour ------ 99
30F. Sulphur Creek Wasteway near Sunnyside,August 31, 1988, at 1530 hour and 1630 hour ---- 99
30G. Buckskin Slough below Gleed Ditch near Gleed,May 22, 1991, at 1100 hour and 1107 hour ------- 100
30H. Buckskin Slough below Gleed Ditch near Gleed,August 7, 1991, at 1000 hour and 1007 hour ----- 100
31A-G. Concentrations of chlorophenoxy-acid herbicides, dicamba, and picloram in replicate and (or) spiked whole-water samples from the following locations, Washington:
31A. Cle Elum River above Cle Elum Lake near Roslyn,July 26, 1988, at 1000 hour and 1015 hour ------ 101
31B. Cherry Creek at Thrall, June 2, 1988, at 1400hour and 1405 hour ----------------------------- 101
31C. Wide Hollow Creek near mouth at Union Gap,November 15, 1988, at 1330 hour and 1430hour ------------------------------------------- 101
31D. Moxee Drain at Thorp Road near Union Gap,May 6, 1988, at 0930 hour and 0940 hour -------- 102
31E. Granger Drain at mouth near Granger,July 28, 1988, at 0930 hour and 1015 hour ------ 102
vi
TABLES - -ContinuedQuality Assurance Data--Continued
Water Column--ContinuedPage
31F. Sulphur Creek Wasteway near Sunnyside,August 31, 1988, at 1530 hour and 1630 hour ---- 103
31G. Buckskin Slough below Gleed Ditch near Gleed,May 22, 1991, at 1100 hour and 1107 hour ------- 103
32A-G. Concentrations of organochlorine and organophosphorus compounds in replicate and (or) spiked whole-water samples from the following locations, Yakima River basin, Washington:
32A. Cle Elum River above Cle Elum Lake near Roslyn,July 26, 1988, at 1000 hour and 1015 hour ------ 104
32B. Cherry Creek at Thrall, June 2, 1988, at 1400 hourand 1405 hour ---------------------------------- 104
32C. Wide Hollow Creek near mouth at Union Gap,November 15, 1988, at 1330 hour and 1430 hour -- 105
32D. Moxee Drain at Thorp Road near Union Gap,May 6, 1988, at 0930 hour and 0940 hour -------- 105
32E. Granger Drain at mouth near Granger,July 28, 1988, at 0930 hour and 1015 hour ------ 106
32F. Sulphur Creek Wasteway near Sunnyside,August 31, 1988, at 1530 hour and 1630 hour ---- 106
32G. Well (station identifier: 12N/19E-09H01)January 20, 1989, at 0730 hour and 0737 hour --- 107
33A-B. Concentrations of phenols and cresols (acid-extractable compounds) in replicate and (or) spiked whole-water samples from the following locations, Yakima River basin, Washington:
33A. Wide Hollow Creek near mouth at Union Gap,November 15, 1988, at 1330 hour and 1430 hour -- 108
33B. Sulphur Creek Wasteway near Sunnyside,August 31, 1988, at 1530 hour and 1630 hour ----- 108
34A-F. Concentrations of triazine, acetamide,chloroacetanilide, and other pesticides in replicate and (or) spiked whole-water samples from the following locations, Yakima River basin, Washington:
34A. Cle Elum River above Cle Elum Lake near Roslyn,July 26, 1988, at 0930 hour and 1000 hour ------ 109
34B. Cherry Creek at Thrall, June 2, 1988, at 1400 hourand 1405 hour ---------------------------------- 109
34C. Wide Hollow Creek near mouth at Union Gap,November 15, 1988, at 1330 hour and 1430 hour -- 110
34D. Moxee Drain at Thorp Road near Union Gap,May 6, 1988, at 0930 hour and 0940 hour -------- 110
34E. Granger Drain at mouth near Granger,July 28, 1988, at 0930 hour and 1015 hour ------ 111
34F. Sulphur Creek Wasteway near Sunnyside,August 31, 1988, at 1530 hour and 1630 hour ---- 111
vii
TABLES --ContinuedQuality Assurance Data--Continued
Water Column--Continued
Page
35A-B. Concentrations of volatile organic compounds in replicate and (or) spiked whole-water samples from the following locations, Yakima River basin, Washington:
35A. Wide Hollow Creek near mouth at Union Gap,November 15, 1988, at 1330 hour and 1430 hour -- 112
35B. Sulphur Creek Wasteway near Sunnyside,August 31, 1988, at 1530 hour and 1630 hour ---- 113
36. Concentrations of pesticides in filtered water (using the Goulden large-sample extractor), associated with suspended sediment (analysis of a large sample of de-watered sediment on a glass-fiber filter), and in whole water (conventional analysis of a 1-liter sample of a sediment-water mixture), Yakima River basin, Washington, June 25-30, 1989 ------------------------ 114
37. Concentrations of organic carbon in replicatesuspended-sediment samples and in spiked filtered- water samples from Chandler Canal at Bunn Road at Prosser, Washington, May 22, 1991, at 1500 hour and 1507 hour --------------------------------------- 117
38. Concentrations of organic carbon, suspended sediment, and turbidity in replicate water samples from Yakima River at Kiona, Washington, August 6, 1991, at 1150 hour and 1151 hour ---------------------------------- 117
Filtered Water
39. Mean analytical recoveries using the Gouldenlarge-sample extractor for extracting surrogate compounds from filtered-water samples, Yakima River basin, Washington, June 25-30, 1989 ----------------- 117
40. Analytical recoveries using the Goulden large-sample extractor for extracting spiked compounds from filtered-water samples, Yakima River basin, Washington, June 25-30, 1989 ------------------------------------ 118
41. Concentrations of pesticides extracted from replicatefiltered-water samples using the Goulden large-sampleextractor, Yakima River at Kiona, Washington,June 26, 1989 --------------------------------------- 122
42. Concentrations of organochlorine and organophosphorus compounds in spiked filtered-water samples from Yakima River at Kiona, Washington, May 21, 1991, at 1200 hour and 1207 hour -------------------------- 123
43. Concentrations of organochlorine and organophosphorus compounds in spiked filtered-water samples from Chandler Canal at Bunn Road at Prosser, Washington, June 13, 1991, at 1240 hour and 1247 hour ----------- 124
viii
TABLES --ContinuedQuality Assurance Data--Continued
Filtered Water--Continued
Page
44. Concentrations of organochlorine and organophosphorus compounds in replicate filtered-water samples from Yakima River at Kiona, Washington, August 6, 1991, at 1150 hour and 1151 hour -------------------------- 125
Suspended Sediment
45. Mean analytical recoveries for extracting surrogate compounds from suspended-sediment samples, Yakima River basin, Washington, June 25-30, 1989 ----------- 126
46. Analytical recoveries of pesticides that were spiked into a blank solvent extract and were analyzed in accordance with other extracts from suspended- sediment samples, Yakima River basin, Washington, June 25-30, 1989 ------------------------------------ 127
47. Concentrations of organochlorine and organophosphorus compounds in replicate suspended-sediment samples from Chandler Canal at Bunn Road at Prosser, Washington, June 13, 1991, at 1240 hour and 1241 hour --------------------------------------- 128
48. Concentrations of organochlorine and organophosphorus compounds in replicate suspended-sediment samples from Yakima River at Kiona, Washington, May 21, 1991, at 1200 hour and 1201 hour -------------------------- 129
49. Concentrations of organochlorine and organophosphorus compounds in replicate suspended-sediment samples from Yakima River at Kiona, Washington, August 6, 1991, at 1150 hour and 1151 hour -------------------------- 130
50. Concentrations of organochlorine and organophosphorus compounds associated with blank glass-fiber filters, Yakima River basin, Washington, July to September 1991 .....................__.............-.-.-.------ 131
51. Concentrations of organochlorine and semi-volatileorganic compounds in replicate bed-sediment samples (sediment finer than 62 micrometers in diameter) from Sulphur Creek Wasteway near Sunnyside, Washington, August 31, 1988 ------------------------------------- 132
Bed Sediment
52. Concentrations of organochlorine and semi-volatileorganic compounds in replicate bed-sediment samples (sediment finer than 2,000 micrometers in diameter) from Sulphur Creek Wasteway near Sunnyside, Washington, August 31, 1988 ------------------------ 134
53. Analytical recovery of organochlorine and semi-volatile organic compounds spiked in bed-sediment samples from Sulphur Creek Wasteway, Washington, August 31, 1988 ------------------------------------------------ 136
IX
TABLES --Continued Quality Assurance Data--Continued
Page
Aquatic Biota
54. Laboratory quality-assurance data for organochlorine compounds analyzed in biological samples collected in 1989 and 1990, Yakima River basin, Washington ---- 138
55. Laboratory quality-assurance data for semi-volatileorganic compounds (polycyclic-aromatic hydrocarbons)analyzed in biological samples collected in 1989and 1990, Yakima River basin, Washington ------------ 140
56. Concentrations of organochlorine compounds in field- replicate and laboratory-split samples of aquatic biota, Yakima River basin, Washington, 1989-90 ------ 141
57. Concentrations of semi-volatile organic compounds (polycyclic-aromatic hydrocarbons) in field- replicate and laboratory-split samples of aquatic biota, Yakima River basin, Washington, 1989-90 ------ 144
CONVERSION FACTORS
[SI - International System of units, a modernized metric system of measurement]
A. Factors for converting SI metric units to inch/pound units
Multiply
centimeter (cm) millimeter (mm) meter (m)
milliliter (mL) liter (L) liter
gram (g)
kilogram (kg)
degree Celsius (°C)
B. Factor for converting
Multiply
By
LENGTH
0.3937 0.03937 3.281 1.094
VOLUME
0.001057 1.057 0.2642
MASS
0.03527
2.205
TEMPERATURE
I/
inch/pound units to
By
To obtain
inch (in) inch foot (foot) yard (yd)
quart (qt) quart gallon (gal)
ounce (oz avoirdupois)
pound (Ib avoirdupois)
degree Fahrenheit
SI metric units
To obtain
VOLUME PER UNIT TIME (FLOW)
cubic foot per second (ft 3 /s) 0.02832 cubic meter per second(m3 /s)
I/ Temp degree F = 1.8 (Temp degree C) +32
XL
CONVERSION FACTORS - -Continued
C. Factors for converting SI metric units to other miscellaneous units
Multiply By To obtain
CONCENTRATION, IN WATER
milligrams per liter (mg/L) 1 parts per million (ppm)nanograms per liter (ng/L) 1 parts per trillion (ppt)nanograms per liter 0.000001 parts per million
CONCENTRATION, IN BED SEDIMENT
micrograms per kilogram (/ig/kg) 1 parts per billion (ppb) micrograms per kilogram (/ig/kg) 0.001 parts per million
CONCENTRATION, IN TISSUE
micrograms per gram (/tg/g) 1 parts per million micrograms per kilogram (/ig/kg) 1 parts per billion
Electrical conductivity is measured as specific electrical conductance, in units of microsiemens per centimeter (/tS/cm) at 25 degrees Celsius.
Any use of trade, product, or firm names in this publication is for descriptive purposes only and does not imply endorsement by U.S. Government.
XL!
SURFACE-WATER-QUALITY ASSESSMENT OF THE YAKIMA RIVER BASIN, WASHINGTON: PESTICIDE AND OTHER TRACE-ORGANIC-COMPOUND DATA FOR WATER, SEDIMENT,
SOIL, AND AQUATIC BIOTA, 1987-91
By J.F. Rinella, S.W. McKenzie, J.K. Crawford, W.T. Foreman, P.M. Gates, G.J. Fuhrer, and M.L. Janet
ABSTRACT
Chemical data are presented from an assessment of pesticides and other trace-organic compounds in stream-water, suspended-sediment, bed- sediment, soil, and aquatic-biota samples from the Yakima River basin in south-central Washington during 1987-91. The assessment is a component of the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) Program. The program is designed to describe the status and trends in the quality of the Nation's ground- and surface-water resources, and to determine factors that affect water quality. This report includes the sampling plan, field-collection techniques, laboratory methods, and a compilation of concentration and quality- assurance data. The data may be used by scientists and water managers to assess: (1) spatial distribution of concentrations of trace-organic compounds, (2) temporal (including seasonal) variability in concentrations, (3) suitability of streams for beneficial uses, and (4) major natural and human factors that affect water quality.
Samples were collected upstream and downstream from human activities throughout the basin. Stream-water samples were collected from 32 stations; in addition, five samples were collected from wells in agricultural areas. Large volumes of stream and well water (up to 224 liters) were sampled, filtered, extracted, and analyzed in order to detect small concentrations of trace-organic compounds. Bed-sediment samples were collected from 58 stations (samples from 26 stations were individually analyzed and samples from the other 32 stations were composited into 7 samples for analysis by crop type). Soil samples were collected from three fields in the Moxee subbasin, an area with large concentrations of pesticides in agricultural runoff. Samples of fish, mollusks, crayfish, and aquatic plants were collected from 32 stations in the basin. Analyses for water, sediment, soils, and biota include chlorophenoxy-acid and triazine herbicides; carbamate, organochlorine, and organophosphorus pesticides; and (or) volatile and semi-volatile trace (polycyclic-aromatic hydrocarbons) organic compounds.
INTRODUCTION
The production and use of organic compounds has increased dramatically over the last 50 years and has resulted in a gradual increase in concentrations of these compounds in our Nation's streams (Smith and others, 1988). Thousands of different organic compounds are used annually in commerce and agriculture; moreover, an unknown number of by-products and degradation products result from the production and use of these compounds. Many organic compounds are directly or indirectly released into streams by way of industrial and domestic point-source discharges (specific discharge outlets, such as effluent from pipes), nonpoint-source runoff (such as runoff from agricultural
fields), ground-water discharges, and atmospheric deposition. Even in small concentrations in streams and streambed sediment, many of these compounds are harmful and even toxic to aquatic organisms. Our ability to accurately monitor organic compounds throughout the environment is essential for assessing their influence on aquatic biota, humans, and wildlife.
Background
The U.S. Geological Survey (USGS) was established in 1879 to provide scientific information on the Nation's water, energy, and mineral resources. A major part of the mission of the USGS is to assess the quantity and quality of the Nation's water resources and to provide information to assist resource managers and policy makers at Federal, State, Tribal, and local levels in making sound management decisions. To a significant extent, these responsibilities are being carried out in the USGS's National Water-Quality Assessment (NAWQA) Program (Leahy and others, 1990), whose goals include providing a sound understanding of the natural and human factors that affect water quality.
A major national concern is the degradation of water quality that results from pesticides and other trace-organic compounds in agricultural, industrial, and urban runoff. Crop yields are improved greatly by applying pesticides, and our lives are enhanced through the usage of organic compounds (including fossil fuels for energy, household cleaners, and many others); however, increased production and use of organic compounds often results in an increase in environmental effects. One of the first surface-water studies in the NAWQA Program to collect data on trace-organic compounds was conducted in the Yakima River basin, Washington, from 1987-91 (project described by McKenzie and Rinella [1987]). The Yakima River basin is one of the most intensively irrigated areas in the United States with Yakima County leading the Nation in the production of apples, mint, and hops (basin characteristics described by Rinella and others, 1992). Pesticide use in the basin is extensive.
Purpose and Scope
The purpose of this report is to document the sampling plan, field- collection techniques, and laboratory methods; and to provide a compilation of concentrations of trace-organic compounds collected during the Yakima NAWQA study (1987-91). The scope of this report includes a presentation of the sampling plan, field-collection techniques, laboratory methods, and a compilation of data including quality-control and quality-assurance data. In this study, water, stream-sediment, aquatic-biota, and a few soil samples were collected and analyzed for a variety of pesticides and other trace-organic compounds that have been, and (or) continue to be, used in the basin. These data may be used by scientists and resource managers to quantitatively describe the:
(1) spatial distribution of pesticides and other trace-organic compounds in surface water, stream sediment, and aquatic biota (fish, mollusks, crayfish, and plants) in the Yakima River basin;
(2) temporal (hourly, daily, and seasonal) variability in concentrations of trace-organic compounds in streams;
(3) suitability of streams for designated beneficial uses including aquatic-life and domestic uses; and,
(4) major natural and human factors that affect the distribution of trace - organic-compound concentrations.
Acknowledgments
The authors wish to acknowledge the aid and advice provided by members of the Yakima NAWQA Liaison Committee. During 1992, this committee included:
David W. Zimmer, U.S. Bureau of ReclamationRichard Albright, U.S. Environmental Protection AgencyBill Garrigues, U.S. Forest ServiceTerry W. Berkompas, U.S. Bureau of Indian AffairsKate Benkert, U.S. Fish and Wildlife ServiceJannine Jennings, Yakima Indian NationBob Barwin, Washington State Department of EcologyPerry Harvester, Washington State Department of FisheriesBrent Renfrew, Washington State Department of WildlifeGlen Patrick, Washington State Department of HealthDr. L. Glint Duncan, Washington Water Research Center,
Central Washington State University Skip Steinmetz, Yakima County Health Department Ronald L. Van Gundy, Yakima River Basin Association of
Irrigation Districts Ray L. Wondercheck, U.S. Soil Conservation Service,
District ConservationistElaine Taylor, Yakima Valley Conference of Governments Mike Tobin, North Yakima Conservation District
Special thanks to: (1) the Yakima Indian Nation for their cooperation in providing staff time and equipment for electrofishing, reviewing reports, and giving USGS permission to collect water-quality and biological samples in the Yakima Indian Nation; (2) U.S. Fish and Wildlife Service, Washington State Department of Fisheries, Washington State Department of Game, and Jean-Pierre Wilson (Heritage College, Toppenish, Washington) for assistance and cooperation in electrofishing; (3) U.S. Bureau of Reclamation and the Prosser Experiment Station (Washington State University and U.S. Department of Agriculture) for providing laboratory facilities in the basin; (4) Gregory D. Foster and Frank A. Rinella (U.S. Geological Survey) for developmental work on the Goulden large-sample extractor used to lower minimum analytical reporting levels; (5) Washington State Department of Wildlife for providing refrigeration and freezer space at the Naches Fish Hatchery; and (6) Shen Xianchen (Institute of Water Conservancy and Hydroelectric Power Research, Chinese Academy of Sciences, Ministry of Water Resources and Electric Power, Beijing, China) for assistance in sampling and developing quality-assurance procedures for spiking bed-sediment samples.
DATA COLLECTION AND ANALYSIS
The focus of the NAWQA study in the Yakima River basin is to assess water-quality conditions at a regional scale which involves water- quality characterizations of persistent conditions in stream reaches that extend 20 or more river miles. A local-scale study, which is beyond the scope of this study, would attempt to describe the water- quality patterns within smaller reaches, of perhaps, several hundreds of yards or less. Although the local scale is not the focus of this assessment, data from this study may reveal several, previously unknown, local-scale concerns to human health and ecosystems.
Sampling Plan
The general sampling plan (sampling purpose and scope) and types of analyses for water, bed-sediment, soil, and aquatic-biota samples from the Yakima River basin are outlined in table 1. Locations of the water, bed-sediment, soil, and aquatic-biota stations are given in table 2 and are shown in figure 1.
Whole-water and most filtered-water samples were analyzed for carbamate, chlorophenoxy-acid, organochlorine, organophosphorus, triazine, and other pesticides (see table 3 for listing of pesticide compounds that were analyzed); in addition, a few samples were analyzed for phenol, cresol, and volatile compounds (see table 2 for listing of chemical families that were analyzed at each station). Bed-sediment samples were analyzed for organochlorine and semi-volatile (phthalate esters, ethers, phenols, cresols, and monocyclic- and polycyclic- aromatic hydrocarbons) organic compounds; most of these compounds are hydrophobic and tend to sorb to organic carbon associated with sediment. Soil samples were analyzed for organochlorine and organophosphorus compounds. Aquatic biota samples (fish, mollusks, crayfish, and plants) were analyzed for organochlorine compounds; in addition, mollusks and plant samples were analyzed for selected semi-volatile organic compounds (polycyclic-aromatic hydrocarbons).
Sample Collection. Processing, and Preservation
The selection of sampling media (whole water, dissolved phase, suspended sediment, bed sediment, soil, or aquatic biota) for analysis was based on physical and chemical characteristics of the trace-organic compounds. For example, hydrophobic compounds that strongly associate with organic matter generally were analyzed in bed-sediment, suspended- sediment, soil, and aquatic-biota samples; hydrophilic compounds that are readily soluble in water were analyzed in filtered-water samples and (or) whole-water samples.
To minimize sample contamination from extraneous sources of trace- organic compounds during collection, processing, and shipment, all samples (water, sediment, soil, and aquatic-biota samples) only came in contact with glass, ceramic, stainless steel, Teflon, bronze, cadmium- plated, or aluminum containers, funnels, sieves, pumps, and (or) sampling equipment; however, fish were caught in nylon nets and were measured on a plexiglass measuring board. Prior to sampling, all sampling equipment and containers were washed with non-phosphate detergent and rinsed with tap water and (or) distilled water. Sample
Table 1. Sampling plan for collecting trace-organic-compound samples, Yakima River basin, Washington, 1987-91
[See table 2 for listing of chemical families analyzed et eech site and see table 3 for listing of compounds in in esch chemical family; DOT * dichlorodiphenyltrichloroethane; DDE * dichlorodiphenyldichloroethylene; DDD = dichlorodiphenyldichloroethane]
Sampling medium Sampling period
Number Chemicalof familysites analyzed Purpose of sampling
Analytical data shown in following tables:
Bed sediment August-November 1987
36
Bed sediment
Bed sediment
August-September 1988
September 1988
Bed sediment 1989-90 16
Soil July 1989
Whole water
Whole water
May, June, July, August, and November 1988, and March 1989
July 1988 18
Filtered and suspended phases (separateanalyses ofeach phase)
June 1989 29
Organochlorines Semi-volatiles
Organochlorines Semi-volatiles
Organochlorines Sami-volatiles
Organochlorines Semi-volatiles
Organochlorines Organophosphorus
OrganochlorinesOrganophosphorusTriazinesCarbamatesChlorophenoxy acidsVolatilesPhenols and cresols
Organochlorines Organophosphorus Triazines Carbemates Chlorophenoxy acids Phenols and cresols
Organochlorines Organophosphorus Triazines Carbamates Chlorophenoxy acids
Two main-stem samples, one urban-runoff 24 and 26sample, and seven composited samples(4 to 5 sites per composite)representing seven different crop typeswere collected to examine land-useeffects on bed-sediment chemistry.
One main-stem site, one pristine site, 24 and 26 one urban site, and five agricultural return flows were sampled to compare trace-organic-compound concentrations in bed sediment and in the water column.
Sites were re-sampled and individually 24 and 26analyzed to examine variability inagricultural-return flows that drainapple orchards. Preliminary resultsfrom the 1987 sampling showed thatdreins from apple orchards (onecomposited sample of five orchards) hadlarger concentrations of trace-organiccompounds in bed sediment than thoseconcentretions in drains from sixother crop types.
Sites were sampled to compare 24 and 26 trace-organic-compound concentrations in bed sediment and aquatic biota.
Soil samples were collected from the 24 and 25A and B horizons at several locations inMoxee subbasin. Moxee subbasin wasselected because relatively largeconcentrations of p,p'-DDT, p,p'-DDE,and p,p'-DDD were observed in MoxeeDrain in 1988. Hop fields were selectedbecause surface-weter drainage from thesefields are ladened with sediment and may betransporting trace-organic compounds thatare sorbed to the sediment. An apple orchardwas selected, because preliminary resultsfrom the 1987 sampling showed thatdreins from apple orchards (one compositedsample of five orchards) had largerconcentrations of trace-organic compoundsin bed sediment than those concentrationsin drains from six other crop types.
One main-stem site, one pristine site, 5, 6, 8, 10, 15, one urban site, and five agricultural- return flows were sampled to examine 20, 21, and 23 seesonal variability in concentrations of trece organic compounds in whole-water samples. Three storm samples also were collected from the main-stem site, Yakima River at Kiona, in December. 1989.
Five main-stem sites, one pristine site, 5, 6, 8, 10, 15,one urban site, the Naches River, andten major agricultural-return flows were 20, and 21sampled synoptically (within a four-dayperiod) during peak irrigation todetermine the spatial distribution ofconcentrations and major sources oftrace organic compounds inwhole-water samples.
The main stem, major tributaries, 5, 7, 9, 11, 13,and major agriculturel-return flowswere sampled synoptically (within a 16, 18, and 225-dey period) to determine transportcharacteristics of trece organiccompounds in the basin during peakirrigation. In addition, two drinking-weter wells were sampled in thevicinity of intense agricultural activityto explore surface- and ground-weter relations.
Table 1. Sampling plan for collecting trace-organic-compound samples, Yakima River basin, Washington, 1987-91 Continued
Sampling medium
Filtered and suspended phases (separate analyses of each phase)
Sampling period
May, June, July, and September 1991
Number Chemical of family sites analyzed
4 Organochlorines Organophosphorus
Purpose of sampling
One mein-stam site and three major agricultur el-return flows were sampled to exemine the variability of dissolved- and suspended-phase transport of trece organic compounds during irrigation season.
Analytical data shown in following tables :
5. 12, 14, 17, and 19
Ground water January 1989
Aquatic biota May 1989
Aquatic biota October-November 1989
Aqustic biota
Aquatic biota
October-November 1990
October-November 1991
Organochlorines Organophosphorus
Organochlorines Polycyclic-aromatic hydrocarbons
19 OrganochlorinesPolycyclic-aromatic hydrocarbons
25 OrganochlorinesPolycyclic-aromatic hydrocarbons
Organochlorines
Three shellow wells were sampled neer the mouth of Moxee Drain to examine surfece- and ground-water relations.
A preliminary field test was conducted to provide estimates of time and resources required for collection and analysis of contaminants in tissues.
Biota from sites where contamination was suspected and from reference sites were sampled to determine the occurrence of contaminants in tissues.
Biota from widely dispersed sites in the basin were sampled to provide a spetial distribution of contaminants in tissues.
Fish from three sites were sampled to examine contaminants in edible portions of fish, variability among fish, and conteminants in whole fish versus fish muscle tissue.
10 and IS
27, 28, and 29
27, 28, and 29
27, 28, and 29
Data not shown in this report and will be available in 1993.
Table 2. Sampling locations for pesticide and other trace-organic compounds in water, bed sediment, soil, and aquatic biota, Yakima River basin, Washington, 1987-91
["WATSTORE" indicates U.S. Geological Survey's National HATer Data STOrage and REtrieval Computer System; see figure 1 for location of sampling sites in basin; Carb - carbamates and other compounds; Chlor - chlorophenoxy acid herbicides; OC = organochlorine compounds; OF - organophosphorus compounds; TR - triazine herbicides; V - volatile organic compounds; PC = phenols and cresols; SV - semi-volatile organic compounds; PAH - polycyclic-aromatic hydrocarbons; abbreviations in site names are as follows: ab - above, abv - above, Blvd - Boulevard, blw - below, Br - Bridge, Campgrnd - Campground, Cr = Creek, E - East, Fk - Fork, M.S. - Middle School, mi - miles, N.F. - North Fork, No - North, nr - near, R - River, Rd = Road, Rds - Roads, RM - River Mile, Rnch - Ranch, S.F. - South Fork, STP - sewage treatment plant, and H - West; latitude and longitude are listed in degrees, minutes, and seconds]
Map refer ence Station number number Station name from WATSTORE Latitude Longitude
Chemical families analyzed at each station
Water samples
234
1113
1415192021
2223242728
3033343536
3738404143
4546474849
5051535558
5961
12478200 Cooper River at Salmon LaSac nr Roslyn12478300 Cle Elum R above Cle Elum Lake nr Roslyn12479500 Yakima River at Cle Elum12484100 Wilson Cr abv. Cherry Creek at Thrall12484480 Cherry Creek at Thrall
12484500 Yakima River at Umtanum12484550 Umtanum Creek nr mouth at Umtanum12496510 Pacific Power & Light Company Wasteway12496511 City of Yakima-Finish Water12496550 Buckskin Slough blw Gleed Ditch nr Gleed
12499000 Naches River nr North Yakima12500420 Moxee Drain at Birchfield road nr Union Gap12500430 Moxee Drain at Thorp Rd nr Union Gap12500445 Wide Hollow Creek near mouth at Union Gap12500450 Yakima R abv Ahtanum Cr at Union Gap
12502500 Ahtanum Creek at Union Gap12505350 E Toppenish Drain at Wilson Rd nr Toppenish12505410 Sub 35 Drain at Parton Road near Granger12505450 Granger Drain at Granger12505460 Granger Drain at mouth nr Granger
12505510 Marion Drain at Indian Church Rd at Granger12507508 Toppenish Cr at Indian Church Rd nr Granger12507585 Yakima River at RM 72 ab Satus Cr nr Sunny side12507594 Sstus Cr abv Wilson-Charley Canyon nr Toppenish12508620 Satus Creek at gage at Satus
12508630 South Drain nr Satus12508850 Sulphur Cr Wasteway nr Sunnyside12509050 Yakima R at Euclid Br at RM 55 nr Grandview12509499 Chandler Canal at Bunn Rd at Prosser12509710 Spring Creek at mouth at Whitstran
12509829 Snipes Creek at mouth at Whitstran12510500 Yakima River at Kiona461720120043201 Well 1, Sunnyside, 09N/22E-04P01462510120323901 Well 2, Harrah, 11N/18E-22R02463233120262101 Well 12N/19E-09H02
463234120261601 Well 12N/19E-09H01463257120260801 Well 12N/19E-10D02
4747474646
4646464646
4646464646
4646464646
4646464646
4646464646
4646464646
4646
2421115555
5151414138
3732323232
3222202020
1918160116
1515131314
1415172532
3232
2919353534
4627444301
4246181904
1004113710
5252110026
3503012700
0213201033
3457
121121120120120
120120120120120
120120120120120
120120120120120
120120120120120
120120119119119
119119120120120
120120
0606563029
2829393934
3126272827
2815131111
1111054008
0701554440
4028043226
2626
1122550151
4446111050
1013191758
2000480938
5453305432
5707000838
3737323921
1608
Carb, Chlor,Carb , Chlor ,Carb , Chlor ,Carb, Chlor,Carb, Chlor,
Carb, Chlor,Carb, Chlor,Carb , Chlor ,Carb , Chlor ,Carb, Chlor,
Carb , Chlor ,OC, OPCarb, Chlor,Carb, Chlor,Carb, Chlor,
Carb, OC, OPCarb, Chlor,Carb, Chlor,OC, OPCarb, Chlor,
Carb , Chlor ,Carb, Chlor,Carb, Chlor,Carb, Chlor,Carb, Chlor,
Carb , Chlor ,Carb, Chlor,Carb, Chlor,Carb, Chlor,Carb, Chlor,
Carb , Chlor ,Carb, Chlor,Carb , Chlor ,Carb, Chlor,OC, OP
OC, OPOC, OP
oc,oc,oc,oc,oc,oc,oc,oc,oc,oc,oc,oc,oc,oc,
, TRoc,oc.oc,oc.oc,oc,oc.oc,oc.oc.oc,oc,oc.oc,oc,oc,oc,
OP,OP,OP,OP,OP,
OP,OP,OP,OP,OP
OP,
OP,OP,OP,
OP,OP,
OP,
OP,OP,OP,OP,OP,
OP,OP,OP,OPOP,
OP,OP,OP,OP,
TRTRTRTRTR
TRTRTR, VTR, V
TR
PC, TR,PC, TR,PC, TR
TRTR
PC, TR,
TRTRTRTRTR
TRPC, TR,TR
TR
TRPC, TR,TRTR
Bed sediment
13567
89
101314
1516171824
12478100 Waptus River at mouth nr Roslyn12478300 Cle Elum R above Cle Elum Lake nr Roslynum12479720 Jungle Creek nr mouth nr Cle Elum12479750 No Fk Te an away R blw bridge at Dickey Creek Campgrnd12480000 Teanaway River below forks near Cle Elum
12481900 Taneum Cr at Taneum Meadow nr Thorp12483190 South Fork Manastash Cr nr Ellensburg12483750 Naneura Cr blw High Cr nr Ellensburg12484480 Cherry Creek at Thrall12484500 Yakima River at Umtanum
12484550 Umtanum Creek nr mouth at Umtanum12487200 Little Naches River at mouth nr Cliffdell12488250 American River at Hells Crossing nr Nile12489100 Rattlesnake Cr abv N.F. Rattlesnake Cr nr Nile12500430 Moxee Drain at Thorp Rd nr Union Gap
4747474747
4746474646
4646464646
2521201714
0658105551
5159584832
1319302148
4718553446
2720043418
121121120120120
120120120120120
120121121121120
0506515151
5248262928
2905150427
1522593036
0132445144
4655450819
SVOC, SVOC, SVOCOC, SV
OCOCOCOC, SVOC, SV
OC, SVOCOC, SVOC, SVOC, SV
Table 2. Sampling locations for pesticide and other trace-organic compounds in weter, bed sediment, soil, and aquatic biota, Yakime River basin, Washington, 1987-91 Continued
Map refer ence Station number number Station name from WATSTORE Latitude Longitude
Chemical families analyzed at eech station
Bed sediment Continued
2527282931
3638424446
4951525462
1250043712500445125004501250090012503640
1250546012507508125085001250862512508850
1250971012510500461652119522000461744119522400463359120281400
Wide Hollow Cr at W Valley M.S. nr AhtanumWide Hollow Cr near mouth at Union GapYakima R abv Ahtanum Cr at Union GapS.F. Ahtanum Cr abv Conrad Rnch nr Tempi coUnnamed drain et Lateral & Riggs Rds nr Wapato
Granger Drain at mouth nr GrangerToppenish Cr at Indian Church Rd nr GrangerSatus Cr below Dry Cr near ToppenishYakima R blw Setus Cr at RM 68 nr SetusSulphur Cr Wastewey nr Sunny side
Spring Creek at mouth at WhitstranYakima River at KioneUnnamed drain et County Line Rd nr GrandviewUnnamed drain to E Turbine Laterel nr GrandviewUnnamed urban runoff at Union Gap
4646464646
4646464646
4646464646
3432322928
2018151515
1415161733
5619043240
1052000603
0013524459
120120120120120
120120120120120
119119119119120
3628275731
1111220501
4028525228
3417582359
3853404507
3837202414
OC,OC,oc.OCOC,
OC,OC,OCOC,OC,
svoc,oc.oc.oc.
svsvsvsvsvsvsvsv
svsvsvsv
63 463501120353300 Wide Hollow Creek at Ahtanum Blvd nr Ahtanum 46 35 01 120 35 33 OC, SV
Composited bed-sediment samples by crop type (stations not shown in figure 1)
Composited samples neer pear orchards ...................................... OC, SV
Wide Hollow Cr at Ahtanum Blvd nr Ahtanum Waste ditch south of Old Naches Road nr Naches Road ditch at Houghton Rd above Roza Canal Waste ditch, 0.2 mi south of Best Zillah Drive
46 35 0146 43 0246 25 3446 24 06
120 35 33120 39 49120 11 33120 13 08
Composited ales near apple orchards ...................................... OC, SV
Wide Hollow Cr at Ahtanum Blvd nr Ahtanum Road ditch north of Old Naches Road nr Gleed Waste ditch at intersection of Lateral Rd and
Riggs RdUnnamed drain to E Turbine Lateral nr Grandview Unnamed drain et County Line Rd nr Grandview
46 35 0146 40 56
46 28 4046 17 4446 16 52
120 35 33120 38 01
120 32 00119 52 24119 52 20
Composited samples near hops fields ......................................... OC, SV
Waste ditch near Faucher Rd near Moxee Drain 46 32 47 Weste ditch near intersection of Fort Rd and Bench Rd 46 22 37 Waste ditch at McDoneld Rd. 0.6 mi north of Hanks Rd 46 16 52 Waste ditch at intersection of Hanks Rd and
Hinzerling Rd Waste ditch northeast of intersection of Bonnieview Rd
and Olmstead Rd
120 22 24120 36 19119 43 24
46 16 23 119 46 03
46 15 41 119 52 53
Composited samples near corn fields ......................................... OC, SV
Waste ditch near intersection of Fort Rd and Island Rd 46 22 32 120 35 00 Waste ditch et Fort Rd, 0.4 mi east of Becker Rd Waste ditch at Cemetary Rd, 0.3 mi north of Gap Rd Waste ditch at Indian Church Rd near Granger Waste ditch at Sorensen Rd, 0.5 mi east of
Denmark Hall
46 22 3246 19 2846 20 01
120 20 49120 04 53120 11 58
46 56 30 120 25 22
Composited samples near asparagus fields .................................... OC, SV
Waste ditch at Yost Rd, 0.5 west of South Wapato Rd 46 20 48 120 25 45 Waste ditch at Cemetary Rd, 0.3 mi north of Gap Rd 46 19 28 120 04 53 Waste ditch at intersection of Factory Rd and
Bethany Rd 46 19 02 119 55 28 Waste ditch at intersection of Lemley Rd and Wilgus Rd 46 15 06 119 49 46 Waste ditch near intersection of Colwesh Rd and
Winnier Rd 46 13 02 120 05 51
Table 2. Sampling locations for pesticide and other trace-organic compounds in water, bed sediment, soil, and aquatic biota, Yakima River basin, Washington. 1987-91 Continued
Map refer ence number
Station number Station n« from WATSTORE Latitude Longitude
Chemicel families analyzed at each station
Composited bed-sediment samples by crop type (stations not shown in figure 1) Continued
Composited samples near poteto fields ....................................... OC, SV
Waste ditch at Orchard Rd, 0.1 mi south of Thrall Rd 46 55 44 120 28 28 Waste ditch at Dodge Rd, 0.4 mi south of Orchard Rd 46 55 03 120 27 15 Waste ditch at Sorensen Rd, 0.4 mi west of
Denmark Hall 46 56 30 120 26 31 Waste ditch near intersection of Hanks Rd and
Missimer Rd 46 16 26 119 48 55 Waste ditch at intersection of Olden Way Rd and
Jensen Rd 46 19 57 120 22 28
Composited samples near grape orchards ..................................... OC, SV
Waste ditch, intersection McCreadie and Griffin Rds 46 Waste ditch, intersection McCreadie and Missimer Rds 46 Waste ditch, intersection Snipes and Hinzerling Rds 46 Waste ditch, intersection Fhipps and Scoon Rds 46
15 15 18 22
33 32 11 38
119 119 119 120
51 48 46 00
02 31 15 51
Soils
565760
463202120223600463232120234900463247120222300
Apple orchard nr Moxee CityHop field near Moxee CityHop field nr Moxee City
464646
323232
023247
120120120
222322
364923
OC,oc,oc,
OPOPOP
Aquatic biota
14567
89
1012 13
1415161718
2224252629
3032363839
4041424346
474951
1247810012479500124797201247975012480000
12481900124831901248375012484440 12484480
1248450012484550124872001248825012489100
1249900012500430125004371250044212500900
1250250012503950125054601250750812507525
1250758512507594125085001250862012508850
125090501250971012510500
Waptus River at mouth nr RoslynYakima River at Cle ElumJungle Creek nr mouth nr Cle ElumNo Fk Teanaway R blw bridge et Dickey Cr CampgrndTeanaway River below forks near Cle Elum
Taneum Cr at Taneum Meadow nr ThorpSouth Fork Manastash Cr nr EllensburgNaneum Cr blw High Cr nr EllensburgCherry Creek abv Wipple Wasteway at Thrall Cherry Creek at Thrall
Yakima River at UmtanumUrn tan urn Creek nr mouth at UmtanumLittle Naches River at mouth nr CliffdellAmerican River at Hells Crossing nr NileRattlesnake Cr abv N.F. Rattlesnake Cr nr Nile
Naches River nr North YakimaMoxee Drain at Thorp Rd nr Union GapWide Hollow Cr at W Valley M.S. nr AhtanumWide Hollow Cr at Old StP at Union GapS.F. Ahtanum Cr ebv Conrad Rnch nr Tampico
Ahtanum Creek at Union GepYakime R at ParkerGranger Drein et mouth nr GrangerToppenish Cr at Indian Church Rd nr GrangerYakima R blw toppenish Cr at RM 79.6 nr Granger
Yakima River at RM 72 eb Satus Cr nr SunnysideSatus Cr abv Wilson-Cherley Canyon nr ToppenishSatus Cr below Dry Cr near ToppenishSatus Creek at gage et SatusSulphur Cr Wasteway nr Sunnyside
Yakime R at Euclid Br at RM 55 nr GrandviewSpring Creek at mouth at WhitstranYakima River at Kiona
4747474747
47464746 46
4646464646
4646464646
4646464646
4646464646
464646
2511201714
06581055 55
5151595848
3732343229
3230201818
1601151615
131415
1335302148
47185544 34
4627200434
4218563532
1022105258
1100002603
010013
121120120120120
120120120120 120
120120121121121
120120120120120
120120120120120
120120120120120
119119119
0556515151
52482629 29
2829051504
3127362857
2827111109
0540220801
554028
1555593036
01324448 51
4446554508
1019342623
2007385313
3054403207
003837
OCococococococococ oc,oc,ococococococ,ococ,ocococ,ococ,ococ,ocococ.ococ,oc,oc,
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAHPAHPAH
YAKIMA BENTON COUNTY 1 COUNTY
LEWISCOUNTY YAKIMA COUNTY
EXPLANATION
Canal
28 Sampling Station0 5 10 15 20 25 MILESI .1 . . I I , I I_____II ' ''I i r I n0 5 10 15 20 25 KILOMETERS
Figure 1. Sampling stations for trace organic compounds in water, suspended sediment, bed sediment, soil, and aquatic biota, Yakima River basin.Washington, 1987-91. Reference numbers are shown on map and listed in Table 2.
10
Table 3. Common technical name and biological activity of pesticides analyzed in water, sediment, soil, and aquatic biota, Yakima River basin, Washington, 1987-91
[ODD dichlorodiphenyldichloroethane; DDE - dichlorodiphenyldichloroethylene; DDT - dichlorodiphenyltrichloroethane; HCB hexachlorobenzene; HCH - hexachloro- cyclohexane; DEF - S,S,S-tributyl phosphorotrithioate; 2,4-D - (2,4-dichloro phenoxy)acetic acid; 2,4-DP - 2-(2,4-dichlorophenoxy)propionic acid; 2,4,5-T - (2,4,5-trichlorophenoxy)acetic acid; EPTC - S-ethyl dipropylthiocarbamate]
Common technical name Biological activity
Organochlorine compounds
Aldrincis-Chlordane trans-Chlordane Chlorothalonil p,p'-DDD and o,p'-DDD
p,p'-DDE and o,p'-DDEp,p'-DDT and o,p'-DDTDacthal1,3-DichloropropeneDieldrin
Dicofol Endosulfan I Endosulfan II Endosulfan sulfate Endrin
Endrin aldehyde Endrin ketone HCBalpha-HCH beta-HCH
delta-HCHHeptachlorHeptachlor epoxideKeponeLindane (gamma-HCH)
o,p'-Methoxychlor andp,p'-Methoxychlor
Mirexcis-Nonachlor trans-Nonachlor
Oxychlordane Perthane Toxaphene
InsecticideInsecticide component of technical chlordaneInsecticide component of technical chlordaneFungicideInsecticide and degradation product of DDT
Degradation products of DDTInsecticidesHerbicideNematicideInsecticide and degradation product of aldrin
AcaricideInsecticide and acaricideInsecticide and acaricideDegradation product of endosulfan I and IIInsecticide
Transformation product of endrinMetabolite of endrinFungicide and industrial intermediateInsecticideInsecticide
InsecticideInsecticide component of technical chlordaneDegradation product of heptachlorInsecticideInsecticide and rodenticide
InsecticidesInsecticide and fire retardantInsecticide component of technical chlordaneInsecticide component of technical chlordane
Degradation product of cis- and trans-chlordaneInsecticideInsecticide, nematicide, herbicide, and fish poison
Organophosphorus compounds
Azinphos-methylChlorpyrifosDEFDemeton-SDiazinon
DimethoateDisulfotonEthionFonofosIsofenphos
Insecticide and acaricide InsecticidePlant-growth regulator Insecticide and acaricide Insecticide and acaricide
Insecticide and acaricide Insecticide and acaricide Acaricide and insecticide Insecticide Insecticide
Malathion Methidathion Methyl-parathion Methyl-trithion (methyl-carbophenothion) Insecticide and acaricide
Insecticide and acaricide Insecticide and acaricide Insecticide and acaricide
MevinphosParatnionFhorateFhosphamidonTerbufos
Trithion(carbophenothion)
Insecticide and acaricide Insecticide and acaricide Insecticide, acaricide, and nematicide Insecticide and acaricide Insecticide and nematicide
Insecticide and acaricide
11
Table 3. Common technical name and biological activity of pesticides analyzed in water, sediment, soil, and aquatic biota, Yakima River basin, Washington, 1987-91 Continued
Common technical name Biological activity
Chlorophenoxy acid herbicides
2,4-D2,4-DP (dichlorprop)Fenoprop (Silvex)2,4,5-T
HerbicideHerbicide and plant-growth regulatorHerbicideHerbicide
Triazine compounds
AmetrynAtrazineCyanazineDeethyl-atrazineDeisopropyl-atrazine
HerbicideHerbicideHerbicideDegradation product of atrazine and propazineDegradation product of atrazine and simazine
Hexazinone Metribuzin Prometon Prometryn Propazine
Simazine Simetryn
Herbicide Herbicide Herbicide Herbicide Herbicide
Herbicide Herbicide
Caxbamate compounds
Aldicarb Aldicarb sulfone
Aldicaxb sulfoxideCarbarylCarbofuran
3-Hydroxyc arbofuran Methiocarb
Methomyl 1-Haphthol
OxamylProphamPropoxur
Insecticide, acaricide, and nematicideHematicide and insecticide; degradation product
of aldicarbDegradation product of aldicaxb Insecticide and plant-growth regulator Insecticide, acaricide, and nematicide
Hydrolysis product of caxbofuran Molluscicide, insecticide, acaricide, and
repellentInsecticide and acaricide Insecticide; hydrolysis product of carbaryl
Insecticide, acaricide, and nematicide Herbicide and plant-growth regulator Insecticide
Thiocarbamate compounds
Butylate Cycloate EPTC (also listed in
carbamate family) Vernolate
Herbicide Herbicide
Herbicide Herbicide
Acetamide compounds
Alachlor (also listed in chloroacetanilide family) Herbicide Diphenamid Herbicide Metolachlor Herbicide
Anilide compounds
Carboxin Fungicide
Benzoic compounds
Dicamba Herbicide
12
Table 3. Common technical name and biological activity of pesticides analyzed in water, sediment, soil, and aquatic biota, Yakima River basin, Washington, 1987-91 Continued
Common technical name Biological activity
Chloroacetanilide compounds (chloroacetamide compounds)
Butachlor Propachlor
Herbicide Herbicide
Conazole compounds
Triadimefon Fungicide
Pyrethoid compounds
FLucythrinate cis-Permethrin trans-Permethrin
Insecticide Insecticide Insecticide
Pyridine compounds
Pic lor am Herbicide
Sulfite compounds
Propargite Acaricide
Trifluoromethyl compounds
Trifluralin Herbicide
Uracil compounds
Bromacil Terbacil
Herbicide Herbicide
Urea compounds
Linuron Herbicide
13
bottles and filters were oven-baked at 300-450°C [degrees Celsius] (preferably 450°C) for 8 or more hours. Lid liners were made of Teflon or oven-baked aluminum-foil inserts. Sampling equipment was rinsed with high-purity methanol or methylene chloride (especially manufactured for pesticide-residue analysis) followed by copious rinsings with stream water from the sampling location.
Whole Water
Water samples for analyses of trace-organic-compounds in whole-water, dissolved, and suspended-sediment phases were collected using the equal-width increment method. This method provides samples with (1) chemical concentrations that are discharge-weighted vertically and laterally, and (2) a sample volume at each sampling point in the transect that is proportional to the water discharge in the sampled zone (Ward and Harr, 1990).
A DH-75H sampler (a 1.5 pound sampler on a hand-held rod; Ward and Harr, 1990) was used for collecting water samples in wadeable streams; a DH-76 sampler (a 22 pound sampler on a hand line; Ward and Harr, 1990) was used for collecting samples from bridges and cableways. These samplers were fitted with Teflon nozzles and gaskets, and were designed to use 1-quart glass bottles.
Whole-water samples were chilled with ice within 30-40 minutes after collection, and were shipped within 2 to 5 days after collection to the USGS National Water-Quality Laboratory (NWQL) in Arvada, Colorado, where the samples were analyzed.
The following ancillary data were collected during most water-column samplings: streamflow, suspended-sediment concentrations and (or) turbidity, particle size of suspended sediment (percent sand), pH, specific conductance, stream temperature, suspended organic carbon, and dissolved organic carbon.
Filtered Water and Suspended Sediment
Selected whole-water samples for trace-organic compounds (up to 224 liters) were filtered through a 293-mL (millimeter) diameter, stainless-steel, filtration unit containing a glass-fiber filter (l-/im [micrometer] nominal pore diameter, binder-free filter). Except for samples collected in June 1989, filtered water was placed into glass bottles (conventional analysis for a chemical family such as, triazines--requires one liter of sample), chilled with ice, and shipped for analysis to the USGS National Water-Quality Laboratory in Arvada, Colorado. To obtain lower minimum reporting levels for the samples collected in June 1989, large volumes of filtered water (4.4 to 112 liters) were extracted at a field laboratory with methylene chloride using the Goulden large-sample extractor [GLSE] (Goulden and Anthony, 1985; Foster and others, 1991). The GLSE extracts were placed in amber-colored glass bottles and sealed with Teflon-lined caps; the iced samples were shipped to the USGS Methods Research and Development Program Laboratory in Arvada, Colorado, for analysis.
The suspended sediment trapped on the filters also was analyzed. Prior to removing a filter for analysis from the filtration unit, excess water was removed by applying a gentle vacuum to the outlet port. The filter, which contained suspended sediment for chemical analysis, was folded in half and then into quarters, wrapped in cleaned, baked aluminum foil, and placed in
14
polyethylene storage bags. The samples were preserved by freezing in dry ice and were shipped frozen to the USGS National Water-Quality Laboratory, except for 13 samples collected in June, 1989, and shipped to the USGS Methods Research and Development Program Laboratory. In this report, concentrations of trace-organic compounds associated with suspended sediment are reported in nanograms per liter (calculated by dividing the mass of the trace-organic compound by the volume of water that passed through the filter).
Bed Sediment and Soil
Most bed-sediment samples were collected in late summer and early fall, near or at the end of irrigation season. Bed-sediment samples were collected to provide (1) a historical integration of water-quality conditions, (2) the amount and distribution of trace-organic compounds that are sorbed onto sediment particles, and (3) additional evidence concerning the occurrence of trace-organic compounds in the aquatic environment.
Bed-sediment samples were collected and processed using Teflon, stainless-steel, or glass sampling equipment, sieves, trays, and containers. Hand-held scoops were used for sampling shallow wadeable streams, and a Teflon-lined Ekman grab sampler was used for sampling deep streams. During sample collection, samples were isolated from the stream current in order to minimize loss of fine-grained sediment. The surficial layer (upper 0.5 inch) of bed sediment was sampled and analyzed to provide an estimate of concentrations of trace-organic compounds that were sorbed to the most recently deposited sediment. When possible, the samples were stream-width integrated by collecting and compositing a minimum of 5 samples in a transect; .however, most samples were collected in low velocity zones in the reach (usually near the shoreline) in order to obtain fine-grained sediment. The bed-sediment samples were separated into size classes using stainless-steel sieves with 2-mm, 180 /jm, and 62-/jm openings. Samples were wet sieved using stream water from the sampling location. Immediately after sieving, size classes of samples were chilled with ice.
Soil samples were collected from the A- and B-soil horizons (as designated by the U.S. Soil Conservation Service) using a stainless-steel scoop. The soil samples were not sieved, and were placed in glass containers and chilled to less than 4°C. Bed-sediment and soil samples were packed in ice and shipped to the USGS National Water-Quality Laboratory, generally within 2 to 5 days after sample collection.
Aquatic Biota
Four different types of biological organisms were collected for analysis of organic compounds: mollusks, fish, crayfish, and aquatic plants. Using an underwater viewer to locate organisms, mollusks were collected from the stream bottom by hand or by using a kick net. The kick-net-collection method involved placing a net downstream from an area likely to contain mollusks. The target area then was disturbed by kicking or raking the stream bottom, so that mollusks would drift downstream into the net. Fish were collected by electrofishing, using both backpack and boat-mounted electrofishers. Electrofishing involves stunning the fish using an electrical current and then netting the immobilized fish. Crayfish were collected using kick nets. Vascular aquatic plants were collected by hand, and samples were stored in native water until they were processed. Processing occurred as quickly as could be accomplished following sampling, and always within 6 hours of collection.
15
All biological samples collected in 1989 and 1990 were composites of multiple organisms. Typically, samples were composited by species, and each composite consisted of about 20 mollusks, 10 fish, or 20 crayfish. At least 20 grams (wet weight) of plant material were collected for each sample of rooted aquatic plants. At some sampling sites, the number of organisms needed for a composite sample could not be collected; therefore, composite samples from these sites contained fewer than the desired number of individuals.
During 1991, additional samples were collected to assess contaminants in edible portions of fish, to compare the sensitivity of using whole fish versus fish muscle for detecting selected trace-organic compounds, and to compare the variability of concentrations of selected trace-organic compounds in whole fish and fish muscle. For this comparison, the study required sampling and analyzing several individual fish, not composited.
Sample-processing procedures varied, depending on the organism collected. For mollusks, organisms were washed in native water using a brush to remove attached sediment, algae, bacteria, and other debris. Mollusks were then placed in deionized water and held at 10°C for 3 days. Holding water was changed every 24 hours. The holding period allows an organism to purge ingested materials from its gut. Sediment and food in the gut is not part of the tissue of the organism and including this material would bias the analytical results. Following the gut-purging period, the maximum length of each individual in the composite sample was measured to the nearest millimeter. The shell was opened by cutting the adductor muscle with a stainless-steel scalpel, and the soft tissue was scraped into a precleaned, tared glass jar having a Teflon lid liner. The jar containing all the individuals in the composite was sealed, weighed, and labeled. Samples were packed in dry ice and frozen for shipment to the laboratory for analysis.
For fish, two different sample-preparation techniques were used, one for whole fish and another for fish muscle tissue. Sample preparation for whole fish involved rinsing the fish in native water, weighing and measuring each individual, collecting a scale sample to use for aging the fish, and examining each fish for external abnormalities. Each fish was wrapped in aluminum foil and all fish in a composite were placed in a labeled plastic bag and packed in dry ice for shipment to the laboratory for analysis. Small fish, comprising a composite sample, were wrapped together in one aluminum-foil packet.
For fish muscle tissue, sample preparation involved rinsing, weighing, measuring, scale-sample collection, an external examination, and the additional step of opening the body cavity to determine the sex of the fish. Then, a rectangular cut approximately 2 mm wide and 5 mm long was made through the skin of the fish on its left side, between the dorsal fin and the lateral line. This cut was made using a stainless-steel scalpel and forceps; each had been rinsed in methanol. This skin was peeled away exposing the muscle tissue underneath. Using a second set of pre-cleaned dissecting instruments, a rectangular block of muscle tissue was extracted, weighed, and placed in aluminum foil or in a precleaned glass jar. These samples were packed in dry ice for shipment to the laboratory for analysis.
Crayfish were triple rinsed using native water, then rinsed in deionized water, placed in a precleaned glass jar, weighed, and frozen. Frozen samples were shipped to the laboratory.
16
Only the apical 5 cm (centimeters) of rooted aquatic plants were collected. These plants were placed in a stainless-steel beaker and rinsed copiously using native water followed by distilled water. The sample was allowed to soak in distilled water for two hours, with a change of water after 1 hour. The soaking water was then drained, and the sample was placed in a precleaned, tared jar, weighed, and frozen.
All biological samples collected prior to 1991 were analyzed by the Mississippi State Chemical Laboratory at Mississippi State University. Fish- tissue samples collected in 1991 were analyzed at the USGS National Water- Quality Laboratory in Arvada, Colorado.
Laboratory Methods
Whole-water, filtered-water, and suspended-sediment samples were analyzed for carbamate, chlorophenoxy-acid (except suspended sediment), organochlorine, organophosphorus, triazine, and other pesticides; in addition, a few samples were analyzed for phenol, cresol, and volatile compounds (see table 2 for listing of chemical families that were analyzed at each station). Bed- sediment samples were analyzed for organochlorine and semi-volatile (phthalate esters, ethers, phenols, cresols, and monocyclic- and polycyclic-aromatic hydrocarbons) organic compounds. Soil samples were analyzed for organochlorine and organophosphorus compounds. Aquatic-biota samples (fish, mollusks, crayfish, and plants) were analyzed for organochlorine compounds; in addition, mollusks and plant samples were analyzed for selected semi-volatile organic compounds, namely polycyclic-aromatic hydrocarbons. The analytical laboratories and the methods of analysis for the water, suspended-sediment, bed-sediment, soils, and aquatic-biota samples are referenced in table 4. Three types of water-column samples were analyzed: whole water (water and suspended-sediment mixture), filtered water (water passing through a l-/zm- pore-size glass-fiber filter), and suspended sediment (direct analysis of sediment retained on a l-/zm-pore-size glass-fiber filter). Several different size classes of bed sediment were analyzed to provide data for examining associations among sediment particle size, concentrations of trace-organic compounds, and organic carbon.
Quality Assurance
Quality-assurance data for replicates, spikes, and blanks are shown in tables 30 through 55 at back of this report. The accuracy of water, sediment, and aquatic-biota analyses may be assessed by analyzing blanks (water, filters, and biological tissue) and by spiking the samples with (1) one or more of the target compounds (referred to as a spiked sample in this report-- also known as a matrix spike), and [or] (2) surrogate compounds. A surrogate compound is similar in physical and chemical properties to the compounds of interest; however, they usually do not occur in natural or polluted water (Wershaw and others, 1987). Surrogate-spike recoveries may be used to estimate sample-processing errors and may be related to matrix effects; however, spike recoveries may not reflect the performance for analyzing other organic compounds in the matrix. Matrix spikes provide an estimate of method performance for extracting compounds from the water matrix; however, the analytical recoveries do not necessarily reflect extraction efficiencies of compounds from sediment/water mixtures (whole-water samples), bed-sediment, and biological samples.
17
Table 4. Laboratories where whole-water, filtered-water, suspended-sediment, bed-sediment, soil, and aquatic-biota samples wereanalyzed, Yakima River basin, Washington, 1987-91
[USGS * U.S. Geological Survey; EPA - U.S. Environmental Protection Agency; DDD - dichlorodiphenyldichloroethane]
Sample type Period of sampling Analyzing laboratory or groupTable in this report
Reference for analytical method where data are listed
Whole water 1988-91
Filtered water June 1989(except chlorophenoxy- acid herbicides)
June 1989(chlorophenoxy-acid herbicides)
Suspended sediment
Bed sediment
Bed sediment and soils
Aquatic biota
May-September 1991
June 1989(all samples withdeterminations foro.p'-DDDin table 13)
June 1989(all samples with miss ing determinations for o.p'-DDD in table 13)
May-September 1991
August-November 1987 (organochlorine compounds)
1987(semi-volatilecompounds)1988-90(all compounds)
May 1989October-November 1989 October-November 1990
USGS National Water-Quality Laboratory in Arvada, Colorado
USGS Methods Research and Development Program in Arvada, Colorado
USGS National Water-Quality Laboratory in Arvada, Colorado
USGS National Water-Quality Laboratory in Arvada, Colorado
USGS Methods Research and Development Program in Arvada, Colorado
USGS National Water-Quality Laboratory in Arvada, Colorado
USGS National Water-Quality Laboratory in Arvada, Colorado
Tennessee Valley Authority Laboratory Branch in Chattanooga, Tennessee
USGS National Water-Quality Laboratory in Arvada, Colorado
Mississippi State University-- The Mississippi State Chemical Laboratory
Aquatic biota October-November 1991 USGS National Water-QualityLaboratory in Arvada, Colorado
Wershaw and others (1987); EPA Method 524.2 for volatiles USGS Method 0-3116-86 for
phenols and cresols (written communications, June, 1992, Michael P. Schroeder, USGS, Arvada, Colorado)
Method listed in Appendix A
6, 8, 10, 15, 20, 21, and 23
7, 11, 16, and 22
Wershaw and others (1987) 9
Wershaw and others (1987) 12 and 17
Method listed in Appendix B 13 and 18
Wershaw and others (1987) 13 and 18
Wershaw and others (1987) 14 and 19
EPA Method 8080 for solid waste 24 (U.S. Environmental Protection Agency, 1986)
Wershaw and others (1987); 24, 25, and 26 Wershaw and others (1983) for
semi-volatiles except soxhletextraction with methylene chlorideand methanol was used, and biobeadcleanup was not performed
Cromartie and others (1975) 27, 28, and 29
Data not shown in this report and will be available in 1993
Except for whole-water samples in this study, precision may be assessed by evaluating results of duplicate analyses (samples that were thought to be essentially identical in composition); these results reflect sample-processing and laboratory precision. Duplicate whole-water samples were collected within 60 minutes of one another in this study; consequently, the results also reflect short-term changes in stream quality.
Blank solutions consisted of distilled water that presumably was free of target analytes. These solutions were analyzed concurrently with the filtered-water samples that were extracted using the GLSE. Blank filters (clean, oven-baked filters without suspended sediment) also were analyzed. Except for beta-hexachlorocyclohexane (beta-HCH), which exhibited quantifiable concentrations in most of the blank filters, target compound concentrations generally were below the minimum reporting levels in the blank solutions and blank filters. As a result of contamination from the filter, concentrations of beta-HCH are not reported for the suspended-sediment phase.
18
REFERENCES
Cromartie, Eugene, Reichel, W.L., Locke, L.N., Belisle, A.A., Kaiser, I.E., Lament, T.G., Mulhern, B.M., Prouty, R.M., Swineford, D.M., 1975, Residues of organochlorine pesticides and polychlorinated biphenyls and autopsy data for bald eagles, 1971-72: Pesticides Monitoring Journal, v. 9, p. 11-14.
Foster, G.D., Foreman, W.T., and Gates, P.M., 1991, Performance of the Goulden large-sample extractor in multiclass pesticide isolation and preconcentration from stream water: Journal of Agricultural and Food Chemistry, v. 39, p. 1618-1622.
Goulden, P.D., and Anthony, D.H.J., 1985, Design of a large-scaleextractor for the determination of organics in water: Environment Canada, National Water Research Institute, Report 85-121, Burlington, Ontario, Canada.
Leahy, P.P., Rosenshein, J.S., and Knopman, D.S., 1990, Implementation plan for the National Water-Quality Assessment Program: U.S. Geological Survey Open-File Report 90-174, 10 p.
Lee, M.L., Vassilaros, D.L., White, C.M., and Novotny, M., 1979,Retention Indicies for programmed-temperature capillary-column gas chromatography of polycyclic aromatic hydrocarbons: Analytical Chemistry, v. 51, no. 6, p. 768-773.
McKenzie, S.W., and Rinella, J.F., 1987, Surface-water-quality assessment of the Yakima River basin, Washington: Project description: U.S. Geological Survey Open-File Report 87-238, 35 p.
Miller, J.C., and Miller, J.N., 1986, Statistics for analytical chemistry: John Wiley & Sons, New York, p. 82-118.
Rinella, J.F., McKenzie, S.W., and Fuhrer, G.J., 1992, Surface-water- quality assessment of the Yakima River basin, Washington: Analysis of available water-quality data through 1985 water year: U.S. Geological Survey Open-File Report 91-453, 261 p. (pending publication as a U.S. Geological Survey Water Supply Paper 2354- B).
Smith, J.A., Witkowski, P.J., and Fusillo, T.V., 1988, Manmade organic compounds in surface waters of the United States--A review of current understanding: U.S. Geological Survey Circular 1007, 92 p.
U.S. Environmental Protection Agency, 1986 (November), Test methods for evaluating solid waste (3rd ed.): Washington, B.C., Office of Solid Waste and Emergency Response.
Ward, J.R., and Harr, A., eds., 1990, Methods for collection andprocessing of surface-water and bed-material samples for physical and chemical analyses: U.S. Geological Survey Open-File Report 90- 140, 71 p.
19
REFERENCES - - Continued
Wershaw, R.L., Fishman, M.J., Grabbe, R.R., and Lowe, L.E., eds, 1983, Methods for the determination of organic substances in water and
fluvial sediments: U.S. Geological Survey Open-File Report 82- 1004, 173 p.
_____ 1987, Methods for the determination of organic substances in water and fluvial sediments: U.S. Geological Survey Techniques of Water-Resources Investigations, book 5, chap. A3, 80 p.
20
ANALYTICAL DATA
Data tables have been grouped and presented by sampling media: water-column data are listed in tables 5-23, bed-sediment and soil data in tables 24-26, and aquatic-biota data in tables 27-29. For each sampling medium, data are arranged alphabetically by chemical family. For each chemical family, water-column data are arranged by sampling phase (whole-water, filtered-water, and then suspended- sediment phase).
21
Table 5. Field measurements, suspended sediment, turbidity, organic carbon, and selected nutrient data for surface-water and ground-water sites where water samples were collected, Yakima River basin, Washington, 1988-91
[*C = degress Celsius; /iS/cm = microsiemens per centimeter at 25 degrees Celsius; mg/L = micrograms per liter; NTU = nephelometric turbidity units; C = Carbon; N = Nitrogen; P = Phosphorus; N02 = Nitrite; N03 = Nitrate; "E" = estimated value; "*" = data collected at 0920 hour; "+" = data collected at 0915 hour; "~" = data collected at 1400 hour; " " = not analyzed or measured; "<" = less than; ">" = greater than; see figure 1 for site locations]
Mapreference
number
2
33333
3
44
1111
1313131313
131313
141414
15
19
20
21212222
2323232323
2424242424
2424242424
2424
2727272727
272727
2628
Station number
12478200
1247830012478300124783001247830012478300
12478300
1247950012479500
1248410012484100
1248448012484480124844801248448012484480
124844801248448012484480
124845001248450012484500
12484550
12496510
12496511
12496550124965501249900012499000
1250042012500420125004201250042012500420
1250043012500430125004301250043012500430
1250043012500430125004301250043012500430
1250043012500430
1250044512500445125004451250044512500445
125004451250044512500445
1250045012500450
Station name
Cooper River at Salmon LaSac nr Roslyn
Cle Elum R above Cle Elum Lake nr RoslynCle Elum R above Cle Elum Lake nr RoslynCle Elum R above Cle Elum Lake nr RoslynCle Elum R above Cle Elum Lake nr RoslynCle Elum R above Cle Elum Lake nr Roslyn
Cle Elum R above Cle Elum Lake nr Roslyn
Yakima River at Cle ElumYakima River at Cle Elum
Wilson Creek abv. Cherry Creek at ThrallWilson Creek abv. Cherry Creek at Thrall
Cherry Creek at ThrallCherry Creek at ThrallCherry Creek at ThrallCherry Creek at ThrallCherry Creek at Thrall
Cherry Creek at ThrallCherry Creek at ThrallCherry Creek at Thrall
Yakima River at UmtanumYakima River at UmtanumYakima River at Umtanum
Umtanum Creek nr mouth at Umtanum
Pacific Power & Light Company Wasteway
City of Yakima-Finish Water
Buckskin Slough blw Gleed Ditch nr GleedBuckskin Slough blw Gleed Ditch nr GleedNaches River nr North YakimaNaches River nr North Yakima
Moxee Drain at Birchfield Road nr Union GapMoxee Drain at Birchfield Road nr Union GapMoxee Drain at Birchfield Road nr Union GapMoxee Drain at Birchfield Road nr Union GapMoxee Drain at Birchfield Road nr Union Gap
Moxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union Gap
Moxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union Gap
Moxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union Gap
Wide Hollow Creek near mouth at Union GapWide Hollow Creek near mouth at Union GapWide Hollow Creek near mouth at Union GapWide Hollow Creek near mouth at Union GapWide Hollow Creek near mouth at Union Gap
Wide Hollow Creek near mouth at Union GapWide Hollow Creek near mouth at Union GapWide Hollow Creek near mouth at Union Gap
Yakima R abv Ahtanum Cr at Union GapYakima R abv Ahtanum Cr at Union Gap
Date
06-28-89
05-05-8806-02-8807-26-8808-31-8811-16-88
03-09-89
07-26-8806-29-89
07-26-8806-29-89
05-05-8806-02-8806-02-8807-26-8808-31-88
11-18-8803-09-8906-29-89
07-27-8806-28-8906-28-89
06-28-89
06-25-89
06-25-89
05-22-9106-12-9107-26-8806-27-89
05-23-9106-17-9106-20-9107-10-9109-04-91
05-06-8805-06-8806-01-8807-26-8807-27-88
07-28-8807-29-8808-30-8811-15-8803-10-89
06-28-8906-28-89
05-05-8806-03-8807-27-8808-30-8811-15-88
11-15-8803-10-8906-30-89
07-27-8806-27-89
Time
1900
11000930100010301030
1015
15001200
16151600
15301400140510301630
100014001830
104517001705
1400
1700
1630
1100134513301015
10001100164512401115
09300940160011001310
16050800173010151200
10301035
18450730102514301330
143014001000
16001630
Dis charge , insta-taneous
(ft3 /s)
229
8851,000
607199539
166
3,7803,780
83144
266305
--127225
76250126
3,830*3,630
1.0
501
21
1719
3281,190
6877
1465163
87--
797676
7091772624
65--
4461262223
__8233
2,8903,630
Spe cific
Temper- con- ature duct-water
CC)
11.0
5.55.5
14.515.04.5
2.0
16.510.5
22.015.0
13.012.0
--16.0
7.54.0
16.0
15.5*13.0
16.5
16.5
14.0
14.021.013.0
12.014.014.520.015.0
11.5--
17.0--
23.0
23.017.520.59.57.0
14.5
12.512.518.517.512.0
__7.015.0
21.017.0
ance
(/iS/cm)
24
4737314550
118
4947
213210
262363--
412334
460359245
77*88
205
51
54
--2708267
242247249313300
279
275296309
320266280649606
295
247202322324446
253260
8692
22
Table 5. Field measurements, suspended sediment, turbidity, organic carbon, and selected nutrient data for surface-water and ground-water sites where water samples were collected, Yakima River basin, Washington, 1988-91--Continued
Station number Date
12478200
1247830012478300124783001247830012478300
12478300
1247950012479500
1248410012484100
1248448012484480124844801248448012484480
124844801248448012484480
124845001248450012484500
1248455012496510
12496511
1249655012496550
1249900012499000
1250042012500420125004201250042012500420
1250043012500430125004301250043012500430
1250043012500430125004301250043012500430
1250043012500430
1250044512500445125004451250044512500445
125004451250044512500445
1250045012500450
06-28-89
05-05-8806-02-8807-26-8808-31-8811-16-88
03-09-89
07-26-8806-29-89
07-26-8806-29-89
05-05-8806-02-8806-02-8807-26-8808-31-88
11-18-8803-09-8906-29-89
07-27-8806-28-8906-28-89
06-28-8906-25-89
06-25-89
05-22-9106-12-91
07-26-8806-27-89
05-23-9106-17-9106-20-9107-10-9109-04-91
05-06-8805-06-8806-01-8807-26-8807-27-88
07-28-8807-29-8808-30-8811-15-8803-10-89
06-28-8906-28-89
05-05-8806-03-8807-27-8808-30-8811-15-88
11-15-8803-10-8906-30-89
07-27-8806-27-89
Oxygen,dissolved(mg/L)
10.2
----
~
__11.0
10.4
--
9.2
10.8
9.4
-
__10.5
----
------
------
9.2
------
__--
10.0
10.0
pH (standardunits)
8.2
7.67.77.68.07.7
8.0
7.97.7
8.48.1
8.28.18.18.28.1
8.38.18.1
7.6*8.1
8.17.8
7.0
__--
9.18.1
__------
8.2--
8.37.98.1
8.28.08.18.58.5
6.2
7.97.47.87.88.1
8.17.97.8
8.48.5
Tur bidity(NTU)
--
2.8--
-
1.7--
7.6--
----
37--
--
6.0--
-
__1.5
2.9--
4056
19015042
------
>100
------
__
--
2.8--
----
13
Sedi ment, suspended(mg/L)
2
<13
<112
1
56
1013
9164688245
251,020
121
192525
14
.2
148
36
252373
1,450903337
134143296597443
5656071575847
436432
1728855
5211
8
2224
Carbon, organic sus pended total(mg/Las C)
0.1
.1
.1
.1
.1
.3
.1
.1
.1
.5
.2
2.3.9.8
1.6.8
.4>4.22.1
.5
.3
.3
.1
.2
<.l
.4
.3
.2
.2
1.63.5
E101.42.2
1.01.01.93.43.2
4.9>3.21.51.2
>4.3>4.6
1.0.7.3.2.2
.4>4.1<.l
.6
.7
Carbon, organic dis solved(mg/Las C)
1.1
3.41.61.6.7.8
.8
1.82.8
4.85.1
4.44.9--
5.23.9
2.6129.1
2.65.82.4
2.11.2
.8
1.82.2
2.61.4
2.42.46.63.52.9
3.33.23.34.04.7
3.13.93.26.55.1
2.92.8
2.05.42.61.81.3
228.41.6
3.11.6
Nitro gen, am monia + organic total(mg/Las N)
------
-
.50--
----.70
--
<.20--
-
1.2--
.40
.502.1.90.40
----
1.0.40
.40
.40----
__
--
<.20--
--
<.20
Nitro gen, NO2+N03 dis solved(mg/Las N)
0.036
----
-
.047
.63
.59
----
3.1--
--.87
.15
.46
.016<.010
<.010
--
2.7.045
.81
.862.32.31.1
----
1.21.2
1.2.98----
1.3
--
1.4--
__--
1.3
.16
.16
Phos phorus total(mg/Las P)
--------
-
.16
----.25
----
.04----
-
--
.25--
.23
.15
.70
.43
.37
----.45.39
.28
.15------
__
--.13--
__----
.09--
Phos phorus ortho , dis solved(mg/Las P)
<0.001
--
-
<.001
.10
.08
------.21--
--.11
.017
.04
.082
.015
<.001
----
.13
.005
.08
.10
.26
.09
.10
------.15.15
.17
.18 --
.11--
--.12 --
--.07
.04
.03
23
Table 5. Field measurements, suspended sediment, turbidity, organic carbon, and selected nutrient data for surface-water and ground-water sites where water samples were collected, Yakima River basin, Washington, 1988-91 Continued
Mapreference
number
30
33
34
3535353535
3636363636
36363636
3737
3838383838
3838
40
41
4343
45
4646464646
4646464646
4646464646
4747
4848
4949
5050
i
Station number
12502500
12505350
12505410
1250545012505450125054501250545012505450
1250546012505460125054601250546012505460
12505460125054601250546012505460
1250551012505510
1250750812507508125075081250750812507508
1250750812507508
12507585
12507594
1250862012508620
12508630
1250885012508850125088501250885012508850
1250885012508850125088501250885012508850
1250885012508850125088501250885012508850
1250905012509050
1250949912509499
1250971012509710
1250982912509829
Station name
Ahtanum Creek at Union Gap
E Toppenish Drain at Wilson Rd nr Toppenish
Sub 35 Drain at Parton Road near Granger
Granger Drain at GrangerGranger Drain at GrangerGranger Drain at GrangerGranger Drain at GrangerGranger Drain at Granger
Granger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr Granger
Granger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr Granger
Marion Drain at Indian Church Rd at GrangerMarion Drain at Indian Church Rd at Granger
Toppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr Granger
Toppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr Granger
Yakima River at RM 72 ab Satus Cr nr Sunnyside
Satus Cr abv Wilson-Charley Canyon nr Toppenish
Satus Creek at gage at SatusSatus Creek at gage at Satus
South Drain nr Satus
Sulphur Cr Wasteway n SunnysideSulphur Cr Wasteway n SunnysideSulphur Cr Wasteway n SunnysideSulphur Cr Wasteway n SunnysideSulphur Cr Wasteway n Sunnyside
Sulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr Sunnyside
Sulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr Sunnyside
Yakima R at Euclid Br at RM 55 nr GrandviewYakima R at Euclid Br at RM 55 nr Grandview
Chandler Canal at Bunn Rd at ProsserChandler Canal at Bunn Rd at Prosser
Spring Creek at mouth at WhitstranSpring Creek at mouth at Whitstran
Snipes Creek at mouth at WhitstranSnipes Creek at mouth at Whitstran
Date
06-30-89
06-29-89
06-29-89
05-23-9106-17-9106-20-9107-10-9109-04-91
05-06-8806-01-8807-28-8807-28-8809-02-88
11-15-8803-09-8906-27-8906-27-89
07-28-8806-29-89
05-06-8806-03-8807-28-8809-01-8811-16-88
03-08-8906-26-89
06-30-89
06-26-89
07-29-8806-29-89
06-27-89
05-06-8806-03-8807-28-8807-28-8808-31-88
08-31-8811-17-8803-08-8906-26-8906-26-89
05-24-9106-19-9106-20-9107-11-9109-05-91
07-28-8806-28-89
05-22-9106-13-91
07-29-8806-30-89
07-29-8806-30-89
Time
1230
1700
1500
12301420140015001420
12301300073009301000
1645173017001705
11451130
13451000144509301615
16001445
1030
0940
11451945
1300
16301300120017001530
16300900120020002005
10001145120011551130
10101020
15001240
13001800
15001430
Dis charge, insta-taneous
(ft3 /s)
23
53
56
5155936186
3756494963
293037
--
3971
322105545827
9039
1,070
12
83124
82
302370151144235
2277563
265--
380246800137341
9631,560
1,4801,430
24"
47
3350
Temper aturewater
rc)
17.0
16.0
16.0
15.017.515.522.018.5
13.015.517.017.016.5
12.010.518.5
--
19.516.0
13.013.521.5
--8.5
8.521.5
16.5
12.5
20.017.5
18.0
15.514.018.021.520.0
20.011.09.0
20.0~-
14.015.515.518.517.0
23.0+19.5
15.5
23.019.0
24.018.0
Spe cific con ductance
(/iS/cm)
320
149
241
330358757353326
418357350328304
652689360
257242
217207262267451
402262
194
54
334279
314
264239333381290
290669693259--
224292465317273
267250
141
290192
168167
24
Table 5. Field measurements, suspended sediment, turbidity, organic carbon, and selected nutrient data for surface-water and ground-water sites where water samples were collected, Yakima River basin, Washington, 1988-91 Continued
Station number
12502500
12505350
12505410
1250545012505450125054501250545012505450
1250546012505460125054601250546012505460
12505460125054601250546012505460
1250551012505510
1250750812507508125075081250750812507508
1250750812507508
12507585
12507594
1250862012508620
12508630
1250885012508850125088501250885012508850
1250885012508850125088501250885012508850
1250885012508850125088501250885012508850
1250905012509050
1250949912509499
1250971012509710
1250982912509829
Date
06-30-89
06-29-89
06-29-89
05-23-9106-17-9106-20-9107-10-9109-04-91
05-06-8806-01-8807-28-8807-28-8809-02-88
11-15-8803-09-8906-27-8906-27-89
07-28-8806-29-89
05-06-8806-03-8807-28-8809-01-8811-16-88
03-08-8906-26-89
06-30-89
06-26-89
07-29-8806-29-89
06-27-89
05-06-8806-03-8807-28-8807-28-8808-31-88
08-31-8811-17-8803-08-8906-26-8906-26-89
05-24-9106-19-9106-20-9107-11-9109-05-91
07-28-8806-28-89
05-22-9106-13-91
07-29-8806-30-89
07-29-8806-30-89
Oxygen,dissolved(mg/L)
9.8
8.6
8.3
----
__--
7.9--
._10.7
--
__10.5
8.9
9.6
__8.5
8.5
--------
--
8.5
-- --
8.6
9.0
9.2
pH Tur-(stand- bid-ard ityunits) (NTU)
8.1
7.7
7.8
7587
23018050
8.28.28.0 >1007.8 >1007.7
8.48.58.2--
8.78.2
8.27.98.3 >107.78.6
8.78.5
7.5
7.8
8.0 147.8
8.3
8.88.18.18.18.0
8.28.48.48.1
1833
2504730
8.3+ 248.2
20
8.2 337.8
7.8 >1007.8
Sediment,suspended(mg/L)
9
52
28
557576963
1,020396
205526421432282
6292
643643
729
32
1311
337
3032
44
2
2138
145
702041289983
6719
108245217
130180909272316
2647
38115
140196
5365
Carbon, organic suspendedtotal(mg/Las C)
0.1
.9
.7
2.8E5.4
E10E92.4
2.03.13.01.71.6
1.02.3
>4.7>4.5
.3
.8
.9--.1.3
>5.2
.9
.4
1.4
.2
.6
.8
1.8
1.01.3--
1.41.2
1.11.01.62.32.4
.61.8
EllE3.41.7
.7
.72.1
1.5
.81.3
Carbon, organicdissolved(mg/Las C)
2.3
1.6
1.6
3.6
225.83.5
3.06.74.14.12.8
2.4113.3
35
2.81.8
2.53.02.32.8
27
5.42.1
1.7
1.2
2.72.0
2.7
3.03.63.03.2
60
3.61.93.72.32.3
2.32.7
153.02.4
4.112
2.21.9
2.52.3
2.01.8
Nitro gen, am monia +organictotal(mg/Las N)
-
-
.801.25.71.6.60
1.8.90
2.8----
.50--
-- .50----
-
.40
1.2
----
<.20.60
-- ----
.80
.903.62.2.70
.30
--
.20
<.20
Nitro gen, N02+N03dissolved(mg/Las N)
1.8
2.0
1.61.86.81.91.2
2.02.0--
3.21.9--
2.42.1
----
2.4 --
1.80
.84
.01
2.21.7
-
----.48
3.1--
--
1.8--
1.22.04.62.01.8
1.21.1
----
1.1.64
.38
.39
Phosphorustotal(mg/Las F)
-
-
.42
.491.6.34.49
.71.32
.67----
.08--
--.11--
-
-
.13--
.11
.03.26--
------
.16
.16
.871.2.31
.13--
----
.13
.09--
Phos phorus ortho,dissolved(mg/Las F)
0.13
.05
.28
.33
.80
.22
.09
.16.16
.34.19
.08
.07
.08
.07
.05
.006
.08
.08
--.10.14
-- .09
.04
.07
.32
.22
.05
.09
.06
.06
.06
.03
.03
25
Table 5. Field measurements, suspended sediment, turbidity, organic carbon, and selected nutrient data for surface-water and ground-water sites where water samples were collected, Yakima River basin, Washington, 1988-91--Continued
Mapreferenc
number
5151515151
5151515151
5151515151
51
53
55
58
5959
61
;e
Station number
1251050012510500125105001251050012510500
1251050012510500125105001251050012510500
1251050012510500125105001251050012510500
12510500
461720120043201
462510120323901
463233120262101
463234120261601463234120261601
463257120260801
Station name
Yakima River at KionaYakima River at KionaYakima River at KionaYakima River at KionaYakima River at Kiona
Yakima River at KionaYakima River at KionaYakima River at KionaYakima River at KionaYakima River at Kiona
Yakima River at KionaYakima River at KionaYakima River at KionaYakima River at KionaYakima River at Kiona
Yakima River at Kiona
Well 1, Sunnyside, 09N/22E-04P01
Well 2, Harrah, 11N/18E-22R02
Well 12N/19E-09H02
Well 12N/19E-09H01Well 12N/19E-09H01
Well 12N/19E-10D02
Date
05-07-8806-01-8807-29-8808-31-8811-17-88
03-08-8906-26-8906-26-8912-06-8912-06-89
12-07-8905-21-9107-09-9108-06-9108-06-91
09-25-91
06-27-89
06-29-89
01-20-89
01-20-8901-20-89
01-20-89
Time
08000900103010001400
09001430143516152357
18521200115511501151
1120
1900
0915
0750
07300737
0715
Dis charge, insta-taneous
(ft3 /s)
1,9601,870
8541,6102,410
2,3701,500
--5,2005,210
4,7803,8501,8501,480
--
1,590
-
-
--
--
Spe cific
Temper- con- ature duct-water
CO
14.014.524.020.08.0
7.025.0
--6.56.0
5.515.522.525.0--
17.0
14.5
14.0
--~-
--
ance
(MS/C.)
242222306320251
277267
251185
152184227279
--
292
380
329
582
872864
921
Table 5. Field measurements, suspended sediment, turbidity, organic carbon, and selected nutrient data for surface-water and ground-water sites where water samples were collected, Yakima River basin, Washington, 1988-91--Continued
Station number
1251050012510500125105001251050012510500
1251050012510500125105001251050012510500
1251050012510500125105001251050012510500
12510500
461720120043201
462510120323901
463233120262101
463234120261601463234120261601
Date
05-07-8806-01-8807-29-8808-31-8811-17-88
03-08-8906-26-8906-26-8912-06-8912-06-89
12-07-8905-21-9107-09-9108-06-9108-06-91
09-25-91
06-27-89
06-29-89
01-20-89
01-20-8901-20-89
Oxygen,dissolved(mg/L)
__------
10.5
----
10.010.7
--
-
2.4
7.1
-
--
pH(standardunits)
8.48.18.57.68.4
8.38.6--
8.08.0
7.98.08.4--
8.5
7.6
7.6
-
__
Turbidity(NTU)
__--
19--
----
1214
14144.5
1010
.20
-
-
-
Sediment,suspended(mg/L)
2835223510
10330307171
5751183230
7
-
-
-
__--
Carbon, organic suspendedtotal(mg/Las C)
.8
.2
.71.3.4
1.81.01.21.82.3
2.0.7.6
1.11.2
.5
<.l
<.l
-
__
Carbon , organicdissolved(mg/Las C)
2.72.85.87.31.1
2.12.12.21.61.8
2.72.42.42.72.9
2.1
1.4
1.2
-
Nitro gen, am monia +organictotal(mg/Las N)
_--.40
----.65.61
.59
.60
.30
.30
.40
-
-
Nitro gen, N02+N03dissolved(mg/Las N)
__--
1.1--
1.1--
1.2.76
.62
.68
.861.2--
1.2
1.0
4.9
3.0
9.08.9
Phosphorustotal(mg/Las P)
__--.14----
----.20.10
.16
.13
.08
.12
.09
-
-
-
--
Phos phorus ortho ,dissolved(mg/Las P)
__--.08--
__.05--.08.04
.05
.02
.04
.10
.07
.14
.078
-
463257120260801 01-20-89 6.0
26
Table 6. Concentrations of carbamate compounds in whole-water samples, Yakima River basin, Washington, 1988-91
[Concentrations in nanograms per liter; "--" = not analyzed; "<" = less than; see figure 1 for site locations]
Map reference number
33333
33
4
11
1313131313
1313
1414
212121
22
2424242424
2424242424
24
2727272727
2727
28
3636363636
36363636
37
3838383838
38
43
4646464646
Station number
1247830012478300124783001247830012478300
1247830012478300
12479500
12484100
1248448012484480124844801248448012484480
1248448012484480
1248450012484500
124965501249655012496550
12499000
1250043012500430125004301250043012500430
1250043012500430125004301250043012500430
12500430
1250044512500445125004451250044512500445
1250044512500445
12500450
1250546012505460125054601250546012505460
12505460125054601250546012505460
12505510
1250750812507508125075081250750812507508
12507508
12508620
1250885012508850125088501250885012508850
Station name
Cle Elura R above Cle Elura Lake nr RoslynCle Elura R above Cle Elura Lake nr RoslynCle Elura R above Cle Elura Lake nr RoslynCle Elura R above Cle Elura Lake nr RoslynCle Elura R above Cle Elura Lake nr Roslyn
Cle Elura R above Cle Elura Lake nr RoslynCle Elura R above Cle Elura Lake nr Roslyn
Yakima River at Cle Elura
Wilson Creek abv. Cherry Creek at Thrall
Cherry Creek at ThrallCherry Creek at ThrallCherry Creek at ThrallCherry Creek at ThrallCherry Creek at Thrall
Cherry Creek at ThrallCherry Creek at Thrall
Yakima River at UmtanumYakima River at Umtanum
Buckskin Slough blw Gleed Ditch nr GleedBuckskin Slough blw Gleed Ditch nr GleedBuckskin Slough blw Gleed Ditch nr Gleed
Naches River nr North Yakima
Moxe Drain at Thorp Rd nr Union GapMoxe Drain at Thorp Rd nr Union GapMoxe Drain at Thorp Rd nr Union GapMoxe Drain at Thorp Rd nr Union GapMoxe Drain at Thorp Rd nr Union Gap
Moxe Drain at Thorp Rd nr Union GapMoxe Drain at Thorp Rd nr Union GapMoxe Drain at Thorp Rd nr Union GapMoxe Drain at Thorp Rd nr Union GapMoxe Drain at Thorp Rd nr Union Gap
Moxee Drain at Thorp Rd nr Union Gap
Wide Hollow Creek near mouth at Union GapWide Hollow Creek near mouth at Union GapWide Hollow Creek near mouth at Union GapWide Hollow Creek near mouth at Union GapWide Hollow Creek near mouth at Union Gap
Wide Hollow Creek near mouth at Union GapWide Hollow Creek near mouth at Union Gap
Yakima R abv Ahtanura Cr at Union Gap
Granger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr Granger
Granger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr Granger
Marion Drain et Indian Church Rd at Granger
Toppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr Granger
Toppenish Cr at Indian Church Rd nr Granger
Satus Creek st gage at Satus
Sulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr Sunnyside
Date
05-05-8806-02-8807-26-8807-26-8808-31-88
11-16-8803-09-89
07-26-88
07-26-88
05-05-8806-02-8806-02-8807-26-8808-31-88
11-18-8803-09-89
07-27-8806-28-89
05-22-9106-12-9108-07-91
07-26-88
05-06-8805-06-8806-01-8807-26-8807-27-88
07-28-8807-29-8808-30-8811-15-8803-10-89
06-28-89
05-05-8806-03-8807-27-8808-30-8811-15-88
11-15-8803-10-89
07-27-88
05-06-8806-01-8807-28-8807-28-8807-28-88
09-02-8811-15-8803-09-8906-27-89
07-28-88
05-06-8806-03-8807-28-8809-01-8811-16-88
03-08-89
07-29-88
05-06-8806-03-8807-28-8807-28-8808-31-88
Time
11000930100010151030
10301015
1500
1615
15301400140510301630
10001400
10451705
110013451000
1330
09300940160011001310
16050800173010151200
1035
184507301025143*11330
14301400
1600
12301300073009301015
1000164517301705
1145
13451000144509301615
1600
1145
16301300120017001530
Aldi- carb
<500<500<500<500<500
<500<500
<500
<500
<500<500<500<500<500
<500<500
<500<500
<500<500
<500
<500<500<500<500<500
<500<500<500<500<500
<500
<500<500<500<500<500
<500<500
<500
<500<500<500<500<500
<500<500<500<500
<500
<500<500<500<500<500
<500
<500
<500<500<500<500<500
Aldi- carb sulfone
<500<500<500<500<500
<500<500
<500
<500
<500<500<500<500<500
<500<500
<500<500
<500<500<500
<500
<500<500<500<500<500
<500<500<500<500<500
<500
<500<500<500<500<500
<500<500
<500
<500<500<500<500<500
<500<500<500<500
<500
<500<500<500<500<500
<500
<500
<500<500<500<500<500
Aldi- carb sulf- oxide
<500<500<500<500<500
<500<500
<500
<500
<500<500<500<500<500
<500<500
<500<500
<500<500<500
<500
<500<500<500<500<500
<500<500<500<500<500
<500
<500<500<500<500<500
<500<500
<500
<500<500<500<500<500
<500<500<500<500
<500
<500<500<500<500<500
<500
<500
<500<500<500<500<500
27
Table 6. Concentrations of carbamate compounds in whole-water samples, Yakima River basin, Washington, 1988-91 Continued
Station number
12478300 12478300 12478300 12478300 12478300
12478300 12478300
12479500
12484100
12484480 12484480 12484480 12484480 12484480
12484480 12484480
12484500 12484500
12496550 12496550 12496550
12499000
12500430 12500430 12500430 12500430 12500430
12500430 12500430 12500430 12500430 12500430
12500430
12500445 12500445 12500445 12500445 12500445
12500445 12500445
12500450
12505460 12505460 12505460 12505460 12505460
12505460 12505460 12505460 12505460
12505510
12507508 12507508 12507508 12507508 12507508
12507508
12508620
12508850 12508850 12508850 12508850 12508850
Date
05-05-88 06-02-88 07-26-88 07-26-88 08-31-88
11-16-88 03-09-89
07-26-88
07-26-88
05-05-88 06-02-88 06-02-88 07-26-88 08-31-88
11-18-88 03-09-89
07-27-88 06-28-89
05-22-91 06-12-91 08-07-91
07-26-88
05-06-88 05-06-88 06-01-88 07-26-88 07-27-88
07-28-88 07-29-88 08-30-88 11-15-88 03-10-89
06-28-89
05-05-88 06-03-88 07-27-88 08-30-88 11-15-88
11-15-88 03-10-89
07-27-88
05-06-88 06-01-88 07-28-88 07-28-88 07-28-88
09-02-86 11-15-68 03-09-89 06-27-89
07-28-88
05-06-88 06-03-88 07-28-88 09-01-88 11-16-88
03-08-89
07-29-88
05-06-68 06-03-88 07-28-88 07-28-88 08-31-88
Carbaryl
<500 <500 <500 <500 <500
<500 <500
<500
<500
<500 <500 <500 <500
14
<500 <500
<500 <500
<500 <500 <500
<500
<500 <500 <500 <500 <500
<500 <500 <500 <500 <500
2
<500 <500 <500 <500 <500
<500 <500
<500
<500 <500 <500 <500 <500
4 <500 <500 <500
<500
<500 <500 <500 <500 <500
<500
<500
<500 <500 <500 <500 <500
Carbo- furan
<500 <500 <500 <500 <500
<500 <500
<500
<500
<500 <500 <500 <500 <500
<500 <500
<500 <500
<500 <500 <500
<500
<500 <500 <500 <500 <500
<500 <500 <500 <500 <500
<500
<500 <500 <500 <500 <500
<500 <500
<500
<500 <500 <500 <500 <500
<500 <500 <500 <500
<500
<500 <500 <500 <500 <500
<500
<500
<500 <500 <500 <500 <500
3- Hydroxy- carbo- furan
<500 <500 <500 <500 <500
<500 <500
<500
<500
<500 <500 <500 <500 <500
<500 <500
<500 <500
<500 <500 <500
<500
<500 <500 <500 <500 <500
<500 <500 <500 <500 <500
<500
<500 <500 <500 <500 <500
<500 <500
<500
<500 <500 <500 <500 <500
<500 <500 <500 <500
<500
<500 <500 <500 <500 <500
<500
<500
<500 <500 <500 <500 <500
Methio- carb
<500 <500 <500 <500
<500 <500
<500
<500
<500 <500 <500 <500
<500 <500
<500 <500
<500 <500 <500
<500
<500 <500 <500
<500 <500 <500 <500 <500
<500
<500 <500 <500 <500
<500 <500
<500
<500 <500 <500 <500
<500 <500 <500 <500
<500
<500 <500 <500 <500
<500
<500
<500 <500 <500 <500
Metho- myl
<500 <500 <500 <500 <500
<500 <500
<500
<500
<500 <500 <500 <500 <500
<500 <500
<500 <500
<500 <500 <500
<500
<500 <500 <500 <500 <500
<500 <500 <500 <500 <500
<500
<500 <500 <500 <500 <500
<500 <500
<500
<500 <500 <500 <500 <500
<500 <500 <500 <500
140
<500 <500
51 <500 <500
<500
110
<500 <500 <500 <500 <500
1- Naph- thol
<500 <500 <500 <500 <500
<500 <500
<500
<500
<500 <500 <500 <500 <500
<500 <500
<500 <500
<500 <500 <500
<500
<500 <500 <500 <500 <500
<500 <500 <500 <500 <500
<500
<500 <500 <500 <500 <500
<500 <500
<500
<500 <500 <500 <500 <500
<500 <500 <500 <500
<500
<500 <500 <500 <500 <500
<500
<500
<500 <500 <500 <500 <500
Oxamyl
<500 <500 <500 <500 <500
<500 <500
<500
<500
<500 <500 <500 <500 <500
<500 <500
<500 <500
<500 <500 <500
<500
<500 <500 <500 <500 <500
<500 <500 <500 <500 <500
<500
<500 <500 <500 <500 <500
<500 <500
<500
<500 <500 <500 <500 <500
<500 <500 <500 <500
<500
<500 <500 <500 <500 <500
<500
<500
<500 <500 <500 <500 <500
Propham
<500 <500 <500 <500 <500
<500 <500
<500
<500
<500 <500 <500 <500 <500
<500 <500
<500 <500
<500
<500
<500
<500 <500 <500 <500 <500
<500 <500 <500 <500 <500
<500
<500 <500 <500 <500 <500
<500 <500
<500
<500 <500 <500 <500 <500
<500 <500 <500 <500
<500
<500 <500 <500 <500 <500
<500
<500
<500 <500 <500 <500 <500
Propoxur
<500 <500 <500 <500
<500 <500
<500
<500
<500 <500 <500 <500
<500 <500
<500 <500
<500 <500 <500
<500
<500 <500 <500
<500 <500 <500 <500 <500
<500
<500 <500 <500 <500
<500 <500
<500
<500 <500 <500 <500
<500 <500 <500 <500
<500
<500 <500 <500 <500
<500
<500
<500 <500 <500 <500
28
Table 6. Concentrations of carbamate compounds in whole-water samples, Yakima River basin, Washington, 1988-91
Map reference number
46 46 46 46
47
48 48
49
50
51 51 51 51 51
51 51
Station number
12508850 12508850 12508850 12508850
12509050
12509499 12509499
12509710
12509829
12510500 12510500 12510500 12510500 12510500
12510500 12510500
Station name
Sulphur Cr Wasteway nr Sunny side Sulphur Cr Wasteway nr Sunny side Sulphur Cr Wasteway nr Sunnyside Sulphur Cr Wasteway nr Sunnyside
Yakima R at Euclid Br at RM 55 nr Grand view
Chandler Canal at Bunn Rd nr Frosser Chandler Canal at Bunn Rd nr Frosser
Spring Creek at mouth at Whitstran
Snipes Creek at mouth at Whitstran
Yakima River at Kiona Yakima River at Kiona Yakima River at Kiona Yakima River at Kiona Yakima River at Kiona
Yakima River at Kiona Yakima River at Kiona
Date
08-31-88 11-17-88 03-08-89 06-26-89
07-28-88
05-22-91 06-13-91
07-29-88
07-29-88
05-07-88 06-01-88 07-29-88 08-31-88 11-17-88
03-08-89 06-26-89
Time
1630 0900 1200 2005
1010
1500 1240
1300
1500
0800 0900 1030 1000 1400
0900 1435
Aldi- carb
<500 <500 <500 <500
<500
<500
<500
<500
<500 <500 <500 <500 <500
<500 <500
Aldi- carb sulfone
<500 <500 <500 <500
<500
<500 <500
<500
<500
<500 <500 <500 <500 <500
<500 <500
Aldi- carb sulf- oxide
<500 <500 <500 <500
<500
<500 <500
<500
<500
<500 <500 <500 <500 <500
<500 <500
Station number
12508850 12508850 12508850 12508850
12509050
12509499 12509499
12509710
12509829
12510500 12510500 12510500 12510500 12510500
12510500 12510500
Date
08-31-88 11-17-88 03-08-89 06-26-89
07-28-88
05-22-91 06-13-91
07-29-88
07-29-88
05-07-88 06-01-88 07-29-88 08-31-88 11-17-88
03-08-89 06-26-89
Carbaryl
<500 <500 <500
6
<500
<500 <500
<500
<500
<500 <500 <500 <500 <500
<500 <500
Carbo- furan
<500 <500 <500 <500
<500
<500 <500
<500
<500
A A A A A UIUIUIUIUI ooooo ooooo
<500 <500
3- Hydroxy- carbo- furan
<500 <500 <500 <500
<500
<500 <500
<500
<500
<500 <500 <500 <500 <500
<500 <500
Methio- carb
<500 <500 <500 <500
<500
<500 <500
<soa<500
<500 <500 <500 <500
<500 <500
Metho- myl
<500 <500 <500 <500
<500
<500 <500
<500
<500
<500 <500 <500
30 <500
<500 <500
1- Naph- thol
<500 <500 <500 <500
<500
<500 <500
<500
<500
A A A A A UIUIUIUIUI OOOOO ooooo
<500 <500
Oxamyl
<500 <500 <500 <500
<500
<500 <500
<500
<500
A A A A A UIUIUIUIUIooooo ooooo
<500 <500
Fropham
<500 <500 <500 <500
<500
<500
<500
<500
A A A A A Ui UIUIUIUI ooooo ooooo
<500 <500
Fropoxur
<500 <500 <500 <500
<500
<500 <500
<500
<500
<500 <500 <500 <500
<500 <500
29
Table 7. Concentrations of carbamate, thiocarbamate, pyrethoid, and other pesticides in filtered-water samples, Yakima River basin, Washington, June 25-30, 1989
[Concentrations in nanograms per liter; "<" = less than; "T" = present, but below quantifiable concentration; " " = not analyzed; EPIC = S-ethyl dipropylthiocarbamate; butylate was not detected; trace concentrations of flucythrinate were detected below quantifiable concentrations in Yakima River at Cle Elum and Yakima River at Umtanum; linuron was analyzed in 3 samples 1.9 ng/L in the Yakima River at Kions and not detected at Cherry Creek and Yakima River at RM 72; see figure 1 for site locations]
Map refer ence numb 8]
24
111314
1519
202224
2728303334
3655
373840
41
53
434546
47495051
Station : number
1247820012479500124841001248448012484500
1248455012496510
124965111249900012500430
1250044512500450125025001250535012505410
12505460462510-120323901125055101250750812507585
12507594
461720-120043201125086201250863012508850
12509050125097101250982912510500
Station name 1
Cooper River at Salmon LaSacYakima River at Cle ElumWilson Cr abv. Cherry CreekCherry Creek at ThrallYakima River at Umtanum
Umtanum Creek nr mouthPacific Power & Light CompanyWastewayCity of Yakima-Finish WaterNaches River nr North YakimaMoxee Drain at Thorp Rd
Wide Hollow Creek near mouthYakima R abv Ahtanum CrAhtanum Creek at Union GapE Toppenish Drain at Wilson RdSub 35 Drain at Parton Road
Granger Drain at mouth
Well 2, Harrah, 11N/18E-22R02Marion Drain, Indian Church RdToppenish Cr, Indian Church RdYakima River at RM 72
Satus Cr abv Wilson-CharleyCanyon nr Toppenish
Well 1, Sunnyside, 09/22E-04P01Satus Cr at gage at SatusSouth Drain nr SatusSulphur Creek Wasteway
Yakima R at Euclid Br at RM 55Spring Creek at mouthSnipes Creek at mouthYakima River at Kiona
Bromacil
<1.4<!83
T<3.0
<o cZ . D
T<.97
<.80<.94
T<.45<4.6
T<2.9T<2.4<1 527T<2.9
13
<.94<2.9<1.4<1.5
<.46
<.93<2.9T<4.7
T<24
1.7<2.9T<2.9<2.6
Carbary!
<1.6<!so
T<3.4T<1.0
<.72
<.49<1.0
--
T<3.2<1.5
13T<3.2
<1.0T<3.2
1.5
<1.0T<3.2
T<26
T<3.3T<3.2<1.6
Carbo- L furan
<0.56<.26
T<1.2<.83T<.80
<.54
<.25<.36<. 18
<1.9
<1.1T<!76<.61
<1 13.7
<1.7
<.36<1. 1<]581.5
<.19
<.36<1. 1<1. 9<9.1
.96T<1. 1<1. 1<!so
EPIC
<0.31<.351.6
371.6
<.22
<.34<.20<.26
T<2.7
<.601.1<.871.86.3
3.1
1.03.22.87.3
<.27
<.202.93.4
T<5.0
3.83.31.53.3
cis-Per- methrin
T<1.2<.76<2.5<4.4
<.79
<.74<.78<.48<4.9
<2.4<2.2<1.6<2.4<2.4
<4.4
<.78<2.4T<1.5<4.4
<.49
<.77<2.4<5.0
<20
<1.6<2.4<2.4<2.4
trans- Per- methrin
T<1.3T<.85<2.8<5.5
<.79
<.83<.87<.54
<5.6
<2.6T<2.5<1.8<2.7<2.6
<5.0
<.87<2.6<1.7<5.5
<.56
<.86<2.7<5.6
<22
<1.8<2.7<2.6<2.7
Propar- gite
<1.8T<!ea<3.8T<4.6T<2.1
<.66<1.2
.57210
<3.63.0
<2.11911
40
<1.2302717
<.64
<1.214
160260
443.0
457.2
Triadi- mefon
<0.66<.30
<1.4
<. 92
<.29<.43<.28
<2.8
T<1.3<.88<.91
<1.3T<1.3
<2.6
<.43<1. 3<.87<.61
<.28
T<.42<1. 3<2.9
T<11
<.92<1.3T<1.3
<.92
Verno- late
<0.33K.41<.69
T<1 ^^* J. . «?
<.25
<.40<.21<.34
<3.5
<.65<1.2<1. 1<.66.94
T<3.1
<.21<.65
<1.1<1.3
<.35
<.21<.65
T<3.5<5.4
T<1.1T<!67T<.65<1.3
30
Table 8. Concentrations of chlorophenoxy-acid herbicides, dicamba, and picloram in whole-water samples,Yakima River basin, Washington, 1988-91
[Concentrations in nanograms per liter; "<" - less than; 2,4-D - (2,4-dichlorophenoxy)acetic acid; 2,4-DP 2,4,5-T = (2,4,5-trichlorophenoxy)acetic acid; see figure 1 for site locations]
dichlorprop;
Maprefer ence number
33333
33
4
11
1313131313
1313
1414
2121
22
2424242424
2424242424
24
2727272727
2727
28
3636363636
36363636
37
383838383838
Station number
1247830012478300124783001247830012478300
1247830012478300
12479500
12484100
1248448012484480124844801248448012484480
1248448012484480
1248450012484500
1249655012496550
12499000
1250043012500430125004301250043012500430
1250043012500430125004301250043012500430
12500430
1250044512500445125004451250044512500445
1250044512500445
12500450
1250546012505460125054601250546012505460
12505460125054601250546012505460
12505510
125075081250750812507508125075081250750812507508
Station name
Cle Elum R above Cle Elum Lake nr RoslynCle Elum R above Cle Elum Lake nr RoslynCle Elum R above Cle Elum Lake nr RoslynCle Elum R above Cle Elum Lake nr RoslynCle Elum R above Cle Elum Lake nr Roslyn
Cle Elum R above Cle Elum Lake nr RoslynCle Elum R above Cle Elum Lake nr Roslyn
Yakima River at Cle Elum
Wilson Creek abv. Cherry Creek at Thrall
Cherry Creek at ThrallCherry Creek at ThrallCherry Creek at ThrallCherry Creek at ThrallCherry Creek at Thrall
Cherry Creek at ThrallCherry Creek at Thrall
Yakima River at UmtanumYakima River at Umtanum
Buckskin Slough blw Gleed Ditch nr GleedBuckskin Slough blw Gleed Ditch nr Gleed
Naches River nr North Yakima
Moxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union Gap
Moxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union Gap
Moxee Drain at Thorp Rd nr Union Gap
Wide Hollow Creek near mouth at Union GapWide Hollow Creek near mouth at Union GapWide Hollow Creek near mouth at Union GapWide Hollow Creek near mouth at Union GapWide Hollow Creek near mouth at Union Gap
Wide Hollow Creek near mouth at Union GapWide Hollow Creek near mouth at Union Gap
Yakima R abv Ahtanum Cr at Union Gap
Granger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr Granger
Granger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr Granger
Marion Drain at Indian Church Rd at Granger
Toppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr Granger
Date
05-05-8806-02-8807-26-8807-26-8808-31-88
11-16-8803-09-89
07-26-88
07-26-88
05-05-8806-02-8806-02-8807-26-8808-31-88
11-18-8803-09-89
07-27-8806-28-89
05-22-9106-12-91
07-26-88
05-06-8805-06-8806-01-8807-26-8807-27-88
07-28-8807-29-8808-30-8811-15-8803-10-89
06-28-89
05-05-8806-03-8807-27-8808-30-8811-15-88
11-15-8803-10-89
07-27-88
05-06-8806-01-8807-28-8807-28-8807-28-88
09-02-8811-15-8803-09-8906-27-89
07-28-88
05-06-8806-03-8807-28-8809-01-8811-16-8803-08-89
Time
11000930100010151030
10301015
1500
1615
15301400140510301630
10001400
10451705
11001345
1330
09300940160011001310
16050800173010151200
1035
18450730102514301330
14301400
1600
12301300073009301015
1000164517301705
1145
134510001445093016151600
Dicamba
<10<10<io<10<10
<10<10
<io70
2,60014014052050
<10240
20<10
<10<10
<10
3030102020
101010
<10<10
10
<1020
<10<10<10
<1010
20
<10130404040
<10<102070
50
10701010
<10<10
2,4-D 2,4-DP Fenoprop Picloram 2,4,5-T
<10 <10 <10 <10 <10<10 <10 <10 <10 <10<10 <10 <10 <10 ^10<10 <10 <10 <10 <10<10 <10 <10 <10 <10
220 110 <10 <10 <10<10 <10 <10 70 <10
<10 <10 <10 <10 <10
80 <10 <10 <10 <10
7,500 <10 <10 <10 <10'l50 <10 <10 10 <10140 <10 <10 <10 <10480 <10 <10 <10 <1060 <10 <10 <10 <10
<10 <10 <10 <10 <10200 140 <10 <10 <10
20 <10 <10 <10 <10<10 <10 <10 <10 <10
<10 <10 <10 <10 <10<10 <10 <10 <10 <10
<10 <10 <10 <10 <10
20 <10 <10 10 <10120 <10 <10 <10 <10150 <10 <10 10 <10200 <10 <10 <10 <10290 <10 <10 <10 <10
1,900 <10 <10 <10 <10260 <10 <10 <10 <1050 <10 <10 <10 <10
<10 <10 <10 <10 <10270 <10 <10 <10 <10
<10 <10 <10 <10 <10
<10 <10 <10 <10 <10250 <10 <10 <10 <1020 <10 <10 10 <10
<10 ^10 <10 <10 <10<10 <10 <10 ^10 <10
<10 <10 <10 <10 <10<10 200 <10 <10 <10
40 <10 <10 <10 <10
<10 <10 <10 10 <10430 <10 <10 <10 <10330 <10 <10 <10 <10390 <10 <10 <10 <10410 <10 <10 <10 <10
<10 <10 <10 <10 <10<10 <10 <10 <10 <10<10 ^10 <10 <10 ^10<10 <10 <10 ^10 ^10
<10 ^10 ^10 ^10 ^10
<10 ^10 ^10 ^10 ^10160 <10 <10 <10 <1030 <10 <10 <10 <1040 <10 <10 <10 <1040 <10 <10 <10 <10
<10 <10 <10 <10 <10
43 12508620 Satus Creek at gage at Satus 07-29-88 1145 30 70
31
Table 8. Concentrations of chlorophenoxy-acid herbicides, dicamba, and picloram in whole-water samples, Yakima River basin, Washington, 1988-91 Continued
Map refer encenumber
46 46 46 46 46
46 46 46 46
47
48
Station number
12508850 12508850 12508850 12508850 12508850
12508850 12508850 12508850 12508850
12509050
12509499
Sulphu Sulphu Sulphu Sulphu Sulphu
Sulphu Sulphu Sulphu Sulphu
Yakima
Station
Cr Wasteway nr Cr Wasteway nr Cr Wasteway nr Cr Wasteway nr Cr Wasteway nr
Cr Wasteway nr Cr Wasteway nr Cr Wasteway nr Cr Wasteway nr
R at Euclid Br
Chandler Canal at BunnChandler Canal at Bunn
49
50
5151515151
5151
12509710
12509829
1251050012510500125105001251050012510500
1251050012510500
Spring
Snipes
YakimaYakimaYakimaYakimaYakima
YakimaYakima
Creek at mouth
Creek at mouth
River at KionaRiver at KionaRiver at KionaRiver at KionaRiver at Kiona
River at KionaRiver at Kiona
name
Sunnyside Sunnyside Sunnyside Sunnyside Sunnyside
Sunnyside Sunnyside Sunnyside Sunnyside
at RM 55 nr Grandview
Rd at ProsserRd at Prosser
at Whitstran
at Whitstran
Date
05-06-88 06-03-88 07-28-88 07-28-88 08-31-88
08-31-88 11-17-88 03-08-89 06-26-89
07-28-88
05-22-9106-13-9107-29-88
07-29-88
05-07-8806-01-8807-29-8808-31-8811-17-88
03-08-8906-26-89
Time
1630 1300 1200 1700 1530
1630 0900 1200 2005
1010
150012401300
1500
08000900103010001400
09001435
Dicamba
20 10 20
10
10
20
10
<102010
10
10101020
<10
<1020
2,4-D 2,4-DP Fenoprop Picloram 2,4,5-T
10 <10 <10 10 <10 100 <10 <10 <10 <10 90 <10 <10 <10 <10
50 <10 <10 <10 <10
60 <10 <10 <10 <10 100 <10 <10 <10 <10
60 <10 <10 <10 <10
30 <10 <10 <10 <1070 <10 <10 <10 <1050 <10 <10 <10 <10
60 <10 <10 <10 <10
10 <10 <10 10 <10110 <10 <10 <10 <1070 <10 <10 <10 <1040 <10 <10 <10 <10
<10 <10 <10 <10 <10
<10 <10 <10 <10 <1070 <10 <10 <10 <10
Table 9. Concentrations of chlorophenoxy-acid herbicides, dicamba, and picloram in filtered-water samples,Yakima River basin, Washington, June 25-30, 1989
[Concentrations in nanograms per liter; "<" - less than; 2,4-D = (2,4-dichlorophenoxy)acetic acid; 2,4-DP = dichlorprop; 2,4,5-T - (2,4,5-trichlorophenoxy)acetic acid; see figure 1 for site locations]
Maprefer ence number
24
111314
1519202224
2728333436
3738404143
4546474950
5153
55
Station number
1247820012479500124841001248448012484500
1248455012496510124965111249900012500430
1250044512500450125053501250541012505460
1250551012507508125075851250759412508620
1250863012508850125090501250971012509829
12510500461720-120043201462510-120323901
Station name
Cooper River at Salmon LaSac nr RoslynYakima River at Cle ElumWilson Creek abv. Cherry Creek at ThrallCherry Creek at ThrallYakima River at Umtanum
Umtanum Creek nr mouth at UmtanumPacific Power & Light Company WastewayCity of Yakima-Finish WaterNaches River nr North YakimaMoxee Drain at Thorp Rd nr Union Gap
Wide Hollow Creek near mouth at Union GapYakima R abv Ahtanum Cr at Union GapE Toppenish Drain at Wilson Rd nr ToppenishSub 35 Drain at Parton Road near GrangerGranger Drain at mouth nr Granger
Marion Drain at Indian Church Rd at GrangerToppenish Cr at Indian Church Rd nr GrangerYakima River at RM 72 ab Satus CrSatus Cr abv Wilson -Char ley CanyonSatus Creek at gage at Satus
South Drain nr SatusSulphur Cr Wasteway nr SunnysideYakima R at Euclid Br at RM 55 nr GrandviewSpring Creek at mouth at WhitstranSnipes Creek at mouth at Whitstran
Yakima River at Kiona
Well 1, Sunnyside, 09N/22E-04P01
Well 2, Harrah, 11N/18E-22R02
Date
06-28-8906-29-8906-29-8906-29-8906-28-89
06-28-8906-25-8906-25-8906-27-8906-28-89
06-30-8906-27-8906-29-8906-29-8906-27-89
06-29-8906-26-8906-30-8906-26-8906-29-89
06-27-8906-26-8906-28-8906-30-8906-30-89
06-26-89
06-27-89
06-29-89
Time Dicamba
1900 <101200 <101600 501830 1001700 10
1400 <101700 <101630 <101015 <101030 <10
1000 <101630 <101700 <101500 <101700 50
1130 <101445 <101030 <100940 <101945 <10
1300 <102000 101020 <101800 101430 10
1430 <10
1900 <10
0915 <10
2,4-D 2,4-DP Fenoprop Picloram 2,4,5-T
<10 <10 <10 <10 <10<10 <10 <10 <10 <10<10 <10 <10 <10 <10290 <10 <10 <10 <10<10 <10 <10 <10 <10
<10 <10 <10 <10 <10<10 <10 <10 30 <10<10 <10 <10 <10 <10<10 <10 <10 <10 <10120 <10 <10 <10 <10
<10 <10 <10 <10 <1070 <10 <10 <10 <10
<10 <10 <10 <10 <1030 <10 <10 <10 <10
140 <10 <10 <10 <10
140 <10 <10 <10 <10<10 <10 <10 <10 <10<10 <10 <10 <10 <10<10 <10 <10 <10 <1010 <10 <10 <10 <10
20 <10 <10 <10 <1080 <10 <10 <10 <1070 <10 <10 <10 <1060 <10 <10 <10 <10
<10 <10 <10 <10 <10
90 <10 <10 <10 <10
<10 <10 <10 <10 <10
<10 <10 <10 <10 <10
32
Table 10. Concentrations of organochlorine compounds in whole-water samples, Yakima River basin, Washington, 1988-89
[Concentrations in nanograms per liter; "<" - less than; ODD = dichlorodiphenyldichloroethane; DDE = dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyltrichloroethane; PCB = gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes; see figure 1 for site locations]
Map reference number
33333
33
4
11
1313131313
1313
1414
22
2424242424
2424242424
24
2727272727
2727
28
3636363636
363636
37
3838383838
38
43
4646464646
Station number
1247830012478300124783001247830012478300
1247830012478300
12479500
12484100
1248448012484480124844801248448012484480
1248448012484480
1248450012484500
12499000
1250043012500430125004301250043012500430
1250043012500430125004301250043012500430
12500430
1250044512500445125004451250044512500445
1250044512500445
12500450
1250546012505460125054601250546012505460
125054601250546012505460
12505510
1250750812507508125075081250750812507508
12507508
12508620
1250885012508850125088501250885012508850
Station name
Cle Elum R above Cle Elum Lake nr RoslynCle Elum R above Cle Elum Lake nr RoslynCle Elum R above Cle Elum Lake nr RoslynCle Elum R above Cle Elum Lake nr RoslynCle Elum R above Cle Elum Lake nr Roslyn
Cle Elum R above Cle Elum Lake nr RoslynCle Elum R above Cle Elum Lake nr Roslyn
Yakima River at Cle Elum
Wilson Creek abv. Cherry Creek at Thrall
Cherry Creek at ThrallCherry Creek at ThrallCherry Creek at ThrallCherry Creek at ThrallCherry Creek at Thrall
Cherry Creek at ThrallCherry Creek at Thrall
Yakima River at UmtanumYakima River at Umtanum
Naches River nr North Yakima
Moxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union Gap
Moxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union Gap
Moxee Drain at Thorp Rd nr Union Gap
Wide Hollow Creek nea mouth at Union GapWide Hollow Creek nea mouth at Union GapWide Hollow Creek nea mouth at Union GapWide Hollow Creek nea mouth at Union GapWide Hollow Creek nea mouth at Union Gap
Wide Hollow Creek nea mouth at Union GapHide Hollow Creek nea mouth at Union Gap
Yakima R abv Ah tan urn Cr at Union Gap
Granger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr Granger
Granger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr Granger
Marion Drain at Indian Church Rd at Granger
Toppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr Granger
Toppenish Cr at Indian Church Rd nr Granger
Satus Creek at gege at Satus
Sulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr Sunnyside
Date
05-05-8806-02-8807-26-8807-26-8808-31-88
11-16-8803-09-89
07-26-88
07-26-88
05-05-8806-02-8808-02-8807-26-8808-31-88
11-18-8803-09-89
07-27-8806-28-89
07-26-88
05-06-8805-06-8806-01-8807-26-8807-27-88
07-28-8807-29-8808-30-8811-15-8803-10-89
06-28-89
05-05-8806-03-8807-27-8808-30-8811-15-88
11-15-8803-10-89
07-27-88
05-06-8806-01-8807-28-8807-28-8807-28-88
09-02-8811-15-8803-09-8906-27-89
07-28-88
05-06-8806-03-8807-28-8809-01-8811-16-88
03-08-89
07-29-88
05-06-8806-03-8807-28-8807-28-8808-31-88
Time Aldrin
1100 <10930 <11000 <11015 <11030 <1
1030 <11015 <1
1500 <1
1615 <1
1530 <11400 <11405 <11030 <11630 <1
1000 <11400 <1
1045 <11705 <1
1330 <1
0930 <10940 <11600 <11100 <11310 <1
1605 <10800 <11730 <11015 <11200 <1
1035 <1
1845 <10730 <11025 <11430 <11330 <1
1430 <11400 <1
1600 <1
1230 <11300 <10730 <10930 <11015 <1
1000 <11645 <11730 <11705 <1
1145 <1
1345 <11000 <11445 <10930 <11615 <1
1600 <1
1145 <1
1630 <11300 <11200 <11700 <11530 <1
33
Table 10. Concentrations of organochlorine compounds in whole-water samples, Yakima River basin, Washington, 1988-89 Continued
Station number
1247830012478300124783001247830012478300
1247830012478300
12479500
12484100
1248448012484480124844801248448012484480
1248448012484480
1248450012484500
12499000
1250043012500430125004301250043012500430
1250043012500430125004301250043012500430
12500430
1250044512500445125004451250044512500445
1250044512500445
12500450
1250546012505460125054601250546012505460
125054601250546012505460
12505510
1250750812507508125075081250750812507508
12507508
12508620
1250885012508850125088501250885012508850
Date
05-05-8806-02-8807-26-8807-26-8808-31-88
11-16-8803-09-89
07-26-88
07-26-88
05-05-8806-02-8806-02-8807-26-8808-31-88
11-18-8803-09-89
07-27-8806-28-89
07-26-88
05-06-8805-06-8806-01-8807-26-8807-27-88
07-28-8807-29-8808-30-8811-15-8803-10-89
06-28-89
05-05-8806-03-8807-27-8808-30-8811-15-88
11-15-8803-10-89
07-27-88
05-06-8806-01-8807-28-8807-28-8807-28-88
09-02-8811-15-8803-09-8906-27-89
07-28-88
05-06-8806-03-8807-28-8809-01-8811-16-88
03-08-89
07-29-88
05-06-8806-03-8807-28-8807-28-8808-31-88
Gross chlor- dane
<100<100<100<100<100
<100<100
<100
<100
<100<100<100<100<100
<100<100
<100<100
<100
<100<100<100<100<100
<100<100<100<100<100
<100
<100<100<100<100<100
<100<100
<100
<100<100<100<100<100
<100<100<100<100
<100
<100<100<100<100<100
<100
<100
<100<100<100<100<100
p,p'-DDD
<x<1<1<1<1<!*1<1<1<!<1<1<1<1<!*1<!<1<11
<1<1212211
<1
<1
111
<1<1
<!3
<1
72
117
10
<!2
<1<1
<1
<!<1<1<11
<1
<1
11
<131
P.P'- DDE
<;L<1<1<1<1
<!<1
<1
<1
11142
115
<!«=!
<1
44
103116
2940725
21
35221
143
2
2121615347
21122850
1
11213
<1
1
61119157
P,P'- DDT
<1<1<1<1<1
<!<1
<1
<1
1<1<1<12
124
<!*1
<1
44
112814
26346
<1<1
21
<!41
<1<1
<!45
2
1317504339
155
<160
<1
<!<1<1<11
<1
<1
51516176
Di- eldrin
<;L<1<1<1<1
<!<1
<1
1
333
125
141
1«=!
<1
11466
782
<1 =1
<1
223
<12
2 =1
1
69
243017
85
<1<1
1
1731
<1
<1
2
25
15146
Endo- Hepta- sulfan I Endrin chlor
<1 <1 <1<1 <1 <1<1 <1 <1<1 <1 <1<1 <1 <1
<1 <1 <1<1 <1 <1
<1 <1 <1
<1 <1 <1
<1 <1 <1<1 <1 <1<1 <1 <1<1 <1 <12 <1 <1
<1 <1 <1<1 <1 <1
<1 <1 <1<1 <1 <1
<1 <1 <1
16 <1 <130 <1 <118 <1 <131 <1 <124 <1 <1
190 1 <193 <1 <114 <1 <1<1 <1 <1<1 <1 <1
<1 <1 <1
10 <1 <170 <1 <166 <1 <1<1 <1 <111 <1 <1
13 <1 <187 <1 <1
4 <1 <1
<1 <1 <121 <1 <1
100 <1 <176 <1 <183 <1 <1
<1 <1 <1<1 <1 <1<1 <1 <1<1 <1 <1
3 <1 <1
<1 <1 <1<1 <1 <14 <1 <11 <1 <1
<1 <1 <1
<1 <1 <1
8 <1 <1
<1 <1 <117 <1 <117 <1 <126 <1 <111 <1 <1
34
Table 10. Concentrations of organochlorine compounds in whole-water samples, Yakima River basin, Washington, 1988-89 Continued
Station number
12478300 12478300 12478300 12478300 12478300
12478300 12478300
12479500
12484100
12484480 12484480 12484480 12484480 12484480
12484480 12484480
12484500 12484500
12499000
12500430 12500430 12500430 12500430 12500430
12500430 12500430 12500430 12500430 12500430
12500430
12500445 12500445 12500445 12500445 12500445
12500445 12500445
12500450
12505460 12505460 12505460 12505460 12505460
12505460 12505460 12505460
12505510
12507508 12507508 12507508 12507508 12507508
12507508
12508620
12508850 12508850 12508850 12508850 12508850
P.P'- Hepta- Meth- chlor oxy-
Date epoxide Lindane chlor
05-05-88 <1 <1 <10 06-02-88 <1 <1 <10 07-26-88 <1 <1 <10 07-26-88 <1 <1 <10 08-31-88 <1 <1 <10
11-16-88 <1 <1 <10 03-09-89 <1 <1 <10
07-26-88 <1 <1 <10
07-26-88 <1 <1 <10
05-05-88 <1 <1 <10 06-02-88 <1 <1 <10 06-02-88 <1 <1 <10 07-26-88 <1 <1 <10 08-31-88 <1 <1 <10
11-18-88 <1 <1 <10 03-09-89 <1 <1 <10
07-27-88 <1 <1 <10 06-28-89 <1 <1 <10
07-26-88 <1 <1 <10
05-06-88 <1 <1 <10 05-06-88 <1 <1 <10 06-01-88 <1 <1 <10 07-26-88 <1 <1 <10 07-27-88 <1 <1 <10
07-28-88 <1 <1 <10 07-29-88 <1 <1 <10 08-30-88 <1 <1 <10 11-15-88 <1 <1 <10 03-10-89 <1 <1 <10
06-28-89 <1 <1 <10
05-05-88 <1 <1 <10 06-03-88 <1 <1 <10 07-27-88 <1 <1 <10 08-30-88 <1 <1 <10 11-15-88 <1 <1 <10
11-15-88 <1 <1 <10 03-10-89 <1 <1 <10
07-27-88 <1 <1 <10
05-06-88 <1 <1 <10 06-01-88 <1 1 <10 07-28-88 <1 <1 <10 07-28-88 <1 <1 <10 07-28-88 <1 <1 <10
09-02-88 <1 <1 <10 11-15-88 <1 <1 <10 03-09-89 <1 <1 <10 06-27-89 <1 <1 <10
07-28-88 <1 <1 <10
05-06-88 <1 <1 <10 06-03-88 <1 <1 <10 07-28-88 <1 <1 <10 09-01-88 <1 <1 <10 11-16-88 <1 <1 <10
03-08-89 <1 <1 <10
07-29-88 <1 1 <10
05-06-88 <1 <1 <10 06-03-88 <1 1 <10 07-28-88 <1 <1 <10 07-28-88 <1 <1 <10 08-31-88 <1 <1 <10
Mirex PCB
<10 <100 <10 <100 <10 <100 <10 <100 <10 <100
<10 <100 <10 <100
<10 <100
<10 <100
<10 <100 <10 <100 <10 <100 <10 <100 <10 <100
<10 <100 <10 <100
<10 <100 <10 <100
<10 <100
<10 <100 <10 <100 <10 <100 <10 <100 <10 <100
<10 <100 <10 <100 <10 <100 <10 <100 <10 <100
<10 <100
<10 <100 <10 <100 <10 <100 <10 <100 <10 <100
<10 <100 <10 <100
<10 <100
<10 <100 <10 <100 <10 <100 <10 <100 <10 <100
<10 <100 <10 <100 <10 <100 <10 <100
<10 <100
<10 <100 <10 <100 <10 <100 <10 <100 <10 <100
<10 <100
<10 <100
<10 <100 <10 <100 <10 <100 <10 <100 <10 <100
PCS
<100 <100 <100 <100 <100
<100 <100
<100
<100
<100 <100 <100 <100 <100
<100 <100
<100 <100
<100
<100 <100 <100 <100 <100
<100 <100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100 <100
<100
<100 <100 <100 <100 <100
<100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100
<100
<100 <100 <100 <100 <100
Per- thane
<100 <100 <100 <100 <100
<100 <100
<100
<100
<100 <100 <100 <100 <100
<100 <100
<100 <100
<100
<100 <100 <100 <100 <100
<100 <100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100 <100
<100
<100 <100 <100 <100 <100
<100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100
<100
<100 <100 <100 <100 <100
Tox- aphene
<1,000 <1,000 <1,000 <1,000 <1,000
<1,000 <1,000
<1,000
<1,000
<1,000 <1,000 <1,000 <1,000 <1,000
<1,000 <1,000
<1,000 <1,000
<1,000
<1,000 <1,000 <1,000 <1,000 <1,000
<1,000 <1,000 <1,000 <1,000 <1,000
<1,000
<1,000 <1,000 <1,000 <1,000 <1,000
<1,000 <1,000
<1,000
<1,000 <1,000 <1,000 <1,000 <1,000
<1,000 <1,000 <1,000 <1,000
<1,000
<1,000 <1,000 <1,000 <1,000 <1,000
<1,000
<1,000
<1,000 <1,000 <1,000 <1,000 <1,000
35
Table 10. Concentrations of organochlorine compounds in whole-water samples, Yakima River basin, Washington, 1988-89
Map reference number
A6 A6 A6 A6
A7
A9
50
51 51 51 51 51
51 51 51 51 51
58
59 59
61
Station number
12508850 12508850 12508850 12508850
12509050
12509710
12509829
12510500 12510500 12510500 12510500 12510500
12510500 12510500 12510500 12510500 12510500
A63233120282101
A6323A120261601 A6323A120261601
A63257120260801
Station number
12508850 12508850 12508850 12508850
12509050
12509710
12509829
12510500 12510500 12510500 12510500 12510500
12510500 12510500 12510500 12510500 12510500
A63233120262101
A6323A120261601 A6323A120261601
A63257120260801
Station number
12508850 12508850 12508850 12508850
12509050
12509710
12509829
12510500 12510500 12510500 12510500 12510500
12510500 12510500 12510500 12510500 12510500
A63233120262101
A6323A120261601 A6323A120261601
Station name
Sulphur Cr Wasteway nr Sunnyside Sulphur Cr Wasteway nr Sunnyside Sulphur Cr Wasteway nr Sunnyside Sulphur Cr Wasteway nr Sunnyside
Yakime R at Euclid Br at
Spring Creek at mouth at
Snipes Creek at mouth at
Yakima River at Kiona Yakima River at Kiona Yakima River at Kiona Yakima River at Kiona Yakima River at Kiona
Yakima River at Kiona Yakima River at Kiona Yakima River at Kiona Yakima River at Kiona Yakima River at Kiona
Well 12N/19E-09H02
Well 12N/19E-09H01 Well 12N/19E-09H01
Well 12N/19E-10D02
Gross chlor- P.P'"
Date dane DDD
08-31-88 <100 1 11-17-88 <100 1 03-08-89 <100 <1 06-26-89 <100 <1
07-28-88 <100 1
07-29-88 <100 1
07-29-88 <100 1
05-07-88 <100 1 06-01-88 <100 <1 07-29-88 <100 <1 08-31-88 <100 <1 11-17-88 <100 <1
03-08-89 <100 <1 06-26-89 <100 <1 12-06-89 <100 <1 12-06-89 <100 <1 12-07-89 <100 <1
01-20-89 <100 <1
01-20-89 <100 <1 01-20-89 <100 <1
01-20-89 <100 <1
Hepta- chlor
Date epoxide Lindane
08-31-88 <1 <1 11-17-88 <1 1 03-08-89 <1 <1 06-26-89 <1 <1
07-28-88 <1 <1
07-29-88 <1 <1
07-29-88 <1 <1
05-07-88 <1 <1 06-01-88 <1 1 07-29-88 <1 <1 08-31-88 <1 <1 11-17-88 <1 <1
03-08-89 <1 <1 06-26-89 <1 <1 12-06-89 <1 <1 12-06-89 <1 <1 12-07-89 <1 <1
01-20-89 <1 <1
01-20-89 <1 <1 01-20-89 <1 <1
RM 55 nr Grendview
Whitstran
Whitstran
P.P'- P.P'" Di- DDE DOT eldrin
756 7 2 A 6 <1 3
21 30 <1
A <1 5
12 5 7
8 A 5
311 3 <1 2 1 <1 3 2 <1 2 1 <1 <1
5 9 <1
1 <1 <1 1 <1 <1 1 <1 <1
<1 <1 <1
<1 <1 <l
<1 <1 <1
P.P'- Meth- oxy- chlor Mirex PCB
<10 <10 <100 <10 <10 <100 <10 <10 <100 <10 <10 <100
<10 <10 <100
<10 <10 <100
<10 <10 <100
<10 <10 <100 <10 <10 <100 <10 <10 <100 <10 <10 <100 <10 <10 <100
<10 <10 <100 <10 <10 <100 <10 <10 <100 <10 <10 <100 <10 <10 <100
<10 <10 <100
<10 <10 <100 <10 <10 <100
Date
08-31-88 11-17-88 03-08-89 06-26-89
07-28-88
07-29-88
07-29-88
05-07-88 06-01-88 07-29-88 08-31-88 11-17-88
03-08-89 06-26-89 12-06-89 12-06-89 12-07-89
01-20-89
01-20-89 01-20-89
01-20-89
Endo- sulfan I
5
1
13
<1
11 8
l\
<1
a<i
PCN
<100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100 <100 <100 <100
<100
<100 <100
Time
1630 0900 1200 2005
1010
1300
1500
0800 0900 1030 1000 1AOO
0900 1A35 1615 2357 1852
0750
0730 0737
0715
Endrin
a<i2
<1
l\
:\<i:\<i
Per- thane
<100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100 <100 <100 <100
<100
<100 <100
Aldrin
<i
<1
<1
<1
I
1<1
<l
<l
Hepta- chlor
a<i<i<i
|
|<ia<i
Tox- aphene
<1,000 <1,000 <1,000 <1,000
<1,000
<1,000
<1,000
<1,000 <1,000 <1,000 <1,000 <1,000
<1,000 <1,000 <1,000 <1,000 <1,000
<1,000
<1,000 <1,000
A63257120260801 01-20-89 <100 <100 <1,000
36
Table
11.
Conc
entr
atio
ns of or
gano
chlo
rine
compounds in
filtered-water samples, Yakima Ri
ver
basin, Washington,
June
25-30,
1989
[Con
cent
rati
ons
in n
anog
rams
pe
r liter: "T"
= pr
esen
t, but
below
quan
tifi
able
con
cent
rati
on;
"nd"
=
not
dete
cted
and
min
imum
rep
orti
ng
level
not
quantified;
"--"
=
not
anal
yzed
; "<"
= less than;
"*"
= sum
was
estimated
using
a regression a
nalysis
of 12 d
isso
lved
concentrations of
p,
p'-D
DE and
p.p'-DDT pl
us p
,p'-
DDE
-'--
-
------------^
-- ... ..
?._
... ~
.._.
...-
._
J_^_
....-
in Ju
ne,
1989
; OD
D = dichlorodipnenyldicnloroetnane;
" HCB
= he
xach
loro
benz
ene;
HC
H =
nexachlorocyclohexane;
locations]
Map
referenc
number 2 4 11 13 14 15 19 20 22 24 27 28 30 33 34 36 55 37 38 40 41 53 43 45 46 47 49 50 51
:e
Stat
ion
number
12478200
12479500
12484100
12484480
12484500
12484550
12496510
1249
6511
12499000
12500430
12500445
12500450
12502500
12505350
12505410
12505460
4625
10-
120323901
12505510
1250
7508
1250
7585
12507594
4617
20-
120043201
1250
8620
12508630
12508850
12509050
12509710
12509829
12510500
Station
name
/
Coop
er R
iver
at
Salmon L
aSac
Yakima R
iver
at Cl
e El ur
nWi
1 so
n Cr
abv
. Ch
erry
Creek
Cherry C
reek
at Th
rall
Yaki
ma Ri
ver
at Umtanum
Umtanum
Creek
nr mouth
Paci
fic
Powe
r &
Ligh
t Company
Wast
eway
City
of
Yaki
ma-F
inis
h Wa
ter
Nach
es Ri
ver
nr No
rth
Yakima
Moxe
e Drain
at Thorp
Rd
Wide
Hollow C
reek n
ear
mout
hYa
kima
R abv Ahtanum
CrAhtanum
Cree
k at
Un
ion
Gap
E To
ppen
ish
Drai
n at
Wilson R
dSu
b 35
Drain a
t Par to
n Road
Granger
Drai
n at
mo
uth
Well 2, Harrah.
11N/
18E-
22R0
2Marion D
rain
, In
dian
Chu
rch
RdTo
ppen
ish
Cr,
Indian C
hurch
RdYakima R
iver
at RM
72
Satu
s Cr abv
Wils
on-C
harl
eyCanyon n
r Toppenish
Well 1.
Sunnyside, 09
N/22
E-04
P01
Satus
Cr at gage at
Satus
South
Drai
n nr Satus
Sulp
hur
Creek
Wasteway
Yakima R
at
Euclid B
r at
RM 5
5Sp
ring
Creek a
t mo
uth
Snip
es C
reek a
t mo
uth
Yaki
ma Ri
ver
at Ki
ona
Udrin
<0.9
4T<
.22
<2.0 <.84
T<.69
<.74
<.21
< 61
<.34
<3.5
<1 8
<!65
<1 .
1<1
.9
<1.8
<3.2 <.61
T<1.8
T<1
. 1<.
84
<-35
T<.60
T<1.9
<3.5
<15 <1.1
<1 .9
<1 .8
T<.69
cis-
Chlordane
<0.2
5<.
20<.
53
T<!6
3
<.23
<.20
<.16*
<1.8 <.50
<.60
<.58
T<-51
<.50
<1.6 < 16
<.50
<.55
<1.1 <.18
<. 16
<.50
<1 .8
<4.1 <.59
<.51
<.50
<.63
trans-
Chloro
Chlordane
thal
onil
<0.23
<.22
<.48
T<1.
2 T
T<.7
0
<.15
<.22
<.16
<1.6 <.45
<.67
<.53 .31
<.45
<1.5 < 15
<.45
<-50
<1.2
nd
<.16
<.15
<.46
<1 .6
<3.8 <.53
<-46
<.45
<.70
ftl"
<0.16
.14
<.33
T<.7
7T<.41
.13
.39
'.20
5.6 .47
.74
.34
1.2 .61
.96
< 10 .47
.59
1.4 .17
.17
.28
3.7
15 2.4
4.8
2.9
1.2
P.F
PJ
PJ * * * * * * * * * * * * * * * * *
JI-D
DT+
ji-D
DE*
J'-DDD 0.6 .5
<1 0
T<2.
1T<
1.2 .5 1.3
< 4 .7
15 1.4
2.8
1.1
3.2
1.7
2.6
< 4
1.4
1.7
3.7 .6 .5 .9
11 38 6.2
9.0
6.3
4.2
Dieldrin
<0.28
T<.21
T<-58
3.7 .93
<.10
<.20
<!33
T<3.4
1.0 .77
<1
1<!56
1.1
T<3.1
< 18
1.3
T<1.0 .98
<.34
T<.1
81.6
T<3.4
35 5.7
7.2
5.9
3.6
Endosul-
fan
I
<0.2
5T<
.15
<.53 .82
8.0
1.3 .73
11 2.6 .92
2.3
3.5
<.50
T<1.
4
<.16
1.8
1.2
<.16
<. 16
<.50
<1 6
6.8
<.50
< 51
<.50
1.2
Endosul-
fan
II
<0.4
7<.
26<.98
<.81
<.24
2.0
<.30
<.32
5.2
1.0
<.77
<!94
T<.9
2
<3.0
<.30
<.92
<1 .0
1.6
<-33
<.30
<.93
<3.4
<7.6
<1
1<^
95<.
92
Table
11.
Concentrat ions
of or
gano
chlp
rine
co
mpou
nds
in f
iltered-water
samp
les,
Ya
kima
Ri
ver
basi
n, Wa
shin
gton
, Ju
ne 1989--Continued
oo
Stat
ion
number
12478200
1247
9500
12
4841
0012484480
1248
4500
12484550
12496510
12496511
1249
9000
1250
0430
12500445
12500450
12502500
12505350
12505410
12505460
4625
10-
1203
2390
112505510
12507508
12507585
1250
7594
4617
20-
1200
4320
112
5086
2012
5086
3012
5088
50
1250
9050
12509710
12509829
1251
0500
Stat
ion
name
Coop
er R
iver
at
Sa
lmon
LaS
ac
Yakima R
iver
at
Cl
e El ur
n Wilson C
r abv. Ch
erry
Creek
Cherry C
reek
at
Thra
llYakima R
iver
at Umtanum
Umtanum
Cree
k nr
mouth
Paci
fic
Powe
r &
Ligh
t Co
mpan
yWasteway
City o
f Ya
kima
-Fin
ish
Water
Nacn
es R
iver
nr
North
Yakima
Moxee
Drai
n at Thorp
Rd
Wide Hollow C
r near m
outh
Yakima R
ab
v Ahtanum
CrAhtanum
Cree
k at Union
Gap
E Toppenish
Drai
n at Wi
lson
Rd
Sub
35 Dr
ain
at Pa
rton
Roa
d
Gran
ger
Drain
at mouth
Well
2, Ha
rrah
. 11
N/18
E-22
R02
Marion D
rain
, Indian C
hurch
RdToppenish
Cr,
Indian C
hurch
RdYakima R
iver
at RM 72
Satu
s Cr
abv Wilson-Charley
Canyon
Well
1,
Sumy si
de,
09N/
22E-
04P0
1Sa
tus
Cr at
gage a
t Sa
tus
South
Drai
n nr
Satus
Sulp
hur
Cree
k Wa
stew
ay
Yakima R
at
Euclid Br at RM 5
5Sp
ring
Cre
ek a
t mouth
Snip
es C
reek
at
mouth
Yakima R
iver
at
Kiona
Endrin
<4i4
<2.4 1.5
<.50
<.18
<1 .4
T<.66
<6.8
<4.2 2.8
<2.2
<4.3
<4.2
<6.1
<1 4
<4.2
<2
1<2
.4 <.68
<1 .4
<4.2
<6.8
<35 9.
1<4
.3<4
.2 <.56
HCB
T<0.15
T<!5
2<.56
T<.0
7
< . 17
<. 10
<. 11
<1.1
T<.3
0<.
53<.
35T<.30
T<.3
0
T<.99
T<.10
T<.3
0T<.34
T<.5
2
T<.1
1
T<.1
0T<
-30
<1 .
1<2
.4 <.36
T<.3
0<.
30T<.56
alpha-
HCH
T<!6
2 <2
.2T<1.4
<1.9 <.31
<.60
<.70
T<.38
T<3.
9
<2
1T<l!8
<1 .2
<2.2
<2.1
<3.5 <.70
T<2.1
<1 .2
T<1.4
<.39
<.69
<2.1
<3.9
<18 <1 2
<2i2
T<2.
1<1
.9
L i nda
ne
( gam
ma -
HCH)
*<'.
&
<3io
<2.6 <.84
<.81
<.65
<.25
<2.6
<2.0
<2.5 <.82
<2.0
<2.0
T<2.
3
<.65
<2.0 <-78
<3.0 <.26
<.65
<2.0
<2.6
<16 <.
83<2
.0<2
.0<2
.6
Hepta-
chlor-
epoxide
<0 < <1 T<
1 < < < T< <2 <1 <1 < <1 <1 <2 < <1 < T<1 < < <1 <2 <8 < <1 <1 <1
.54
.38
.5 .2 .82
.37
.35
.25
.5 .1 .1 .81
. 1 1 .3 .35
. 1 .77
.5 .25
.35
.1 .6 .9 .82
. 1 . 1 .2
o,p'
- Me
th-
oxy-
chlo
r
<2.5
T<1.5
<5.2
T<.91
<4.8
<1.2
<1 .5
<1 .6
<.98
<10 <4.9
<4.5
<3.2
<5.0
<4.9
<9.0
<1 6
<4.9
<3.0 <.91
<1 .0
<1 .6
<4.9
<10
<41 <3.2
<5.0
<4.9
<4.8
B4?h'-
oxy-
chlo
r
nd
nd
nd<1 2 nd
<1.4 nd nd
<1 .
1<12 nd nd<3
.7 nd nd
<10 nd nd<3
.5<1
.2
<1 .2 nd nd
<12 nd
<3.7 nd nd nd
Mi rex T<!4
5 <2.3
<2.9
T<1.4
<.51
<.44
< 71
<.20
<2.1
<2
1T<l!3
<.66
<2.2
<2.1
<1.9 < 71
<2.2 <.63
<2.9 <.21
<.70
<2.2
<2.
1<1
8 <.67
<2.2
<2.2
<1 .4
Perthane
<!44
<2
.6
<1.4 <.17
<.43
<.81
< 31
<3.2
<2.4
<1 .3
<1 0
<2.5
<2.4
T<2.
8
T<.81
<2.5 <.96
<1.2 <.32
<.80
<2.5
<3.2
<20 <1 0
<2i5
<2.5
<1 .4
Table 12. Concentrations of organochlorine compounds in filtered-water samples, Yakima River basin, Washington, May-September 1991
[Concentretions in nanograms per liter; "<" = less than; DDD = dichlorodiphenyldichloroethane; DDE - dichlorodiphenyldichloroethylene; DOT - dichlorodiphenyltrichloroethane; PCB - gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes; see figure 1 for site locations]
Map reference number
21 21
23 23 23 23 23
35 35 35 3535
4646464646
4848
5151515151
Station number
12496550 12496550
12500420 12500420 12500420 12500420 12500420
12505450 12505450 12505450 1250545012505450
1250885012508850125088501250885012508850
1250949912509499
1251050012510500125105001251050012510500
Station number
1249655012496550
1250042012500420125004201250042012500420
1250545012505450125054501250545012505450
1250885012508850125088501250885012508850
1250949912509499
1251050012510500125105001251050012510500
Station name
Buckskin Slough blw Gleed Ditch nr Gleed Buckskin Slough blw Gleed Ditch nr Gleed
Moxee Drain at Birchfield Road nr Union Gap Moxee Drain at Birchfield Road nr Union Gap Moxee Drain at Birchfield Road nr Union Gap Moxee Drain at Birchfield Road nr Union Gap Moxee Drain at Birchfield Road nr Union Gap
Grenger Drain at Granger Grange Drain at Granger Grange Drain at Granger Grange Drain at GrangerGrange
SulphuSulphuSulphuSulphuSulphu
ChandlChandl
YakimaYakimaYakimaYakimaYakima
Date
05-22-9106-12-91
05-23-9106-17-9106-20-9107-10-9109-04-91
05-23-9106-17-9106-20-9107-10-9109-04-91
05-24-9106-19-9106-20-9107-11-9109-05-91
05-22-9106-13-91
05-21-9107-09-9108-06-9108-06-9109-25-91
Drein at Granger
Cr Wasteway nrCr Wasteway nrCr Wasteway nrCr Wasteway nrCr Wasteway nr
r Canal at Bunnr Canal at Bunn
River at KionaRiver at KioneRiver at KioneRiver at KionaRiver at Kiona
Grosschlor- p,p'dane DDD
<100 <1<100 5
<100 <1<100 1<100 <1<100 <1<100 <1
<100 <1<100 2<100 2<100 1<100 <1
<100 <1<100 1<100 4<100 1<100 <1
<100 <1<100 <1
<100 <1<100 <1<100 <1<100 2<100 <1
SunnysideSunnysideSunnysideSunnysideSunnyside
Rd at FrosserRd at Frosser
P.P'~ P,P'~DDE DOT
5 <16 2
6 <13 22 <15 44 1
9 <112 534 256 58 4
6 <14 20
19 155 34 2
4 <11 <1
4 <11 <14 <12 <12 <1
Di-eldrin
<!4
<!2124
38966
26
1675
11
33
<115
Date
05-22-91 06-12-91
05-23-91 06-17-91 06-20-91 07-10-91 09-04-91
05-23-91 06-17-91 06-20-91 07-10-9109-04-91
05-24-9106-19-9106-20-9107-11-9109-05-91
05-22-9106-13-91
05-21-9107-09-9108-06-9108-06-9109-25-91
Endo-sulfan I
<!3
<!2
<1<1<1
<!2
<1<1 =1
<!<1<1<1<1
<!2
<!<151
<1
Time Aldrin
1100 <1 1345 <1
1000 <1 1100 <1 1645 <1 1240 <1 1115 <1
1230 <1 1420 <1 1400 <1 1500 <11420 <1
1000 <11145 <11200 <11155 <11130 <1
1500 <11240 <1
1200 <11155 <11150 <11151 <11120 <1
Hepta-Endrin chlor
<1 <1<1 <1
<1 <1<1 <1<1 <1<1 <1<1 <1
<1 <1<1 <1<1 <1<1 <i<1 <1
<1 <1<1 <1<1 <1<1 <1<1 <1
<1 <1<1 <1
<1 <1<1 <1<1 <1<1 <1<1 <1
39
Table 12. Concentrations of organochlorine compounds in filtered-water samples, Yakima River basin, Washington, May-September 1991 Continued
Station number
1249655012496550
1250042012500420125004201250042012500420
1250545012505450125054501250545012505450
1250885012508850125088501250885012508850
1250949912509499
1251050012510500125105001251050012510500
P.P'- Hepta- Meth- chlor oxy-
Date epoxide Lindane chlor
05-22-91 <1 <1 <1006-12-91 <1 1 <10
05-23-91 <1 <1 <1006-17-91 <1 <1 <1006-20-91 <1 <1 <1007-10-91 <1 <1 <1009-04-91 1 <1 <10
05-23-91 <1 <1 <1006-17-91 <1 <1 <1006-20-91 <1 4 <1007-10-91 <1 <1 <1009-04-91 <1 <1 <10
05-24-91 <1 <1 <1006-19-91 <1 <1 <1006-20-91 <1 7 <1007-11-91 <1 <1 <1009-05-91 <1 <1 <10
05-22-91 <1 <1 <1006-13-91 <1 <1 <10
05-21-91 <1 <1 <1007-09-91 <1 <1 <1008-06-91 <1 .3 <1008-06-91 <1 <1 <1009-25-91 <1 <1 <10
Mi rex PCB
<10 <100<10 100
<10 <100<10 <100<10 <100<10 <100<10 <100
<10 <100<10 <100<10 <100<10 <100<10 <100
<10 <100<10 <100<10 <100<10 <100<10 <100
<10 <100<10 <100
<10 <100<10 100<10 200<10 100<10 100
PCN
<100<100
<100<100<100<100<100
<100<100<100<100<100
<100<100<100<100<100
<100<100
<100<100<100<100<100
Per- thane
<100<100
<100<100<100<100<100
<100<100<100<100<100
<100<100<100<100<100
<100<100
<100<100<100<100<100
Tox- aphene
<1,000<1,000
<1,000<1,000<1,000<1,000<1,000
<1,000<1,000<1,000<1,000<1,000
<1,000<1,000<1,000<1,000<1,000
<1,000<1,000
<1,000<1,000<1,000<1,000<1,000
40
Table
13.
Concentrations of
or
gano
chlo
rine
compounds associated w
ith
suspended
sedi
ment
, Yakima Ri
ver
basin, Wa
shin
gton
, Ju
ne 2
5-30,
1989
[Concentrations
in n
anog
rams
pe
r liter; al
l de
term
inat
ions
mad
e using
GC/E
CD (g
as ch
roma
togr
aph/
elec
tron
-cap
ture
det
ecto
r) ex
cept
values in
parentheses
are
determinations m
ade
usin
g GC
/MS
(gas
ch
roma
togr
aph/
mass
spectrometer d
etec
tor)
; nd
= co
ncen
trat
ion
is be
low
quantifiable
conc
entr
atio
n us
ing
GC/M
S; "<"
= less th
an;
ODD
= di
chlo
rodi
phen
yldi
chlo
roet
hane
; DD
E =
dich
loro
diph
enyl
dich
loro
ethy
lene
; DD
T =
dich
loro
diph
enyl
tric
hlor
oeth
ane:
HCB
= hexachlorobenzene; HCH
= hexachlorocyclohexane; "T"
= pr
esen
t, but
belo
w quantifiable
concentration; "-
" =
not
anal
yzed
; "*"
= a portion
of sample w
as lo
st d
uring
anal
ysis
, and
reported c
oncentrations
may
be b
iased
low;
n**n
= co
mpou
nd d
etec
ted
and
may
be less th
an reported v
alue
; I
= interference at pe
ak;
g =
gr9s
s ch
lord
ane
(cis-chlordane +
trans-
chlo
rdan
e);
Endo
sulf
an s
ulfa
te,
endrin a
ldeh
yde,
endrin ke
tone
, heptachlor,
delt
a-HC
H, cis- an
d tr
ans-
perm
ethr
in.
pert
hane
, gr
oss
polychlorinated
napt
hale
nes
(PCN
) were n
ot de
tect
ed.
PCB
= polychlorinated
biph
enyl
: PC
B (8
.8 n
g/L) and
toxaphene
(160
ng/L) were d
etected
at Granger
Drai
n; PCB
also w
as d
etected
at 1.2
ng/L
at
Sulphur
Creek.
ChlorthalomI (0
.08
ng/L)
was
dete
cted
at
Sout
h Dr
ain.
trans-Nonachlor
was
detected a
t Gr
ange
r Drain
(0.21
ng/L
), Moxee
Drai
n (trace c
once
ntra
tion
<0.
03 n
g/L)
, and
Sulp
hur
Cree
k (t
race
con
cent
rati
on <
0.3
ng/L
);
see
figure
1 fo
r site lo
cati
ons]
Map
reference
Station
number
number
2 4 11 13 14 15 19 20 22 22 24 27 28 28 30 33 34 36 55 37 38 40 40 41 53 43 45 46 47 47 49 50 51 51
12478200
1247
9500
1248
4100
1248
4480
12484500
12484550
1249
6510
1249
6511
1249
9000
1249
9000
12500430
1250
0445
1250
0450
1250
0450
1250
2500
12505350
12505410
1250
5460
4625
10-
1203
2390
1
1250
5510
1250
7508
1250
7585
1250
7585
1250
7594
4617
20-
1200
4320
112
5086
2012
5086
3012
5088
5012
5090
50
1250
9050
1250
9710
1250
9829
1251
0500
12510500
Station
name
Aldr
in&r
Cooper R
iver
at
Salmon L
aSac
<0
.09
Yaki
ma R
iver
at
Cle
Elum
Wils
on C
r ab
v. Cherry C
reek
Cher
ry C
reek
at
Thra
ll
Yaki
ma R
iver
at Um
tanu
mUmtanum
Cree
k nr
mou
thPacific
Powe
r &
Light
Company
Wasteway
City
of
Yaki
ma- Fi
nish
Water
Naches R
iver
nr
Nort
h Ya
kima
Naches R
iver
nr
Nort
h Yakima
Moxe
e Drain
at Th
orp
RdWi
de Hollow C
reek
near
mouth
Yaki
ma R
abv Ah
tanu
m Cr
Yaki
ma R
abv Ah
tanu
m Cr
Ahtanum
Cree
k at Un
ion
Gap
E To
ppen
ish
Drain
at W
ilso
n Rd
Sub
35 D
rain a
t Parton R
oad
Granger
Drain
at mo
uth
Well
2, Harrah,
11N/
18E-
22R0
2
Mari
on D
rain
, In
dian
Church
RdTo
ppen
ish
Cr,
Indi
an C
hurch
RdYa
kima
Riv
er a
t RM 7
2Ya
kmia
Riv
er a
t RM
72
Satus
Cr a
bv W
ilson- Cha
r ley
Cany
on n
r To
ppen
ish
Well
1
Sunn
ysid
e, 09
N/22
E-04
P01
Satus
Cr a
t gage a
t Sa
tus
South
Drai
n nr
Sat
usSulphur
Cree
k Wasteway
Yaki
ma R
at Euclid B
r at RM 55
Yakima R
at
Euclid B
r at RM
55
Spring C
reek
at
mouth
Snipes C
reek
at
mout
hYa
kima
Riv
er a
t Ki
ona
Yaki
ma R
iver
at
Kion
a
<.09
<.3
<.3
<.6
<.4
<.01
< 2
<.02 nd <.01
< 3
<.02 nd < .3
<.3
< 3 '.09
<.02
< .3 <.3
dnd <.05
<.01
<.3
<.01
< 5
<.07
*
nd <.3
<.3
< 01 nd
<0.0
2
<.04
<.02
< 01
<.02
<.02 nd .23
<.07 nd 1.9
<.02
T<.
1 nd <.02 .03
.34
<.07
*
<.04 nd
for 0.00
1<-
02 .11
.46
.05
<.02
< 01
<.02
<.02
(T) 1.6 .21
T<.2
(T) .0
67.7
4.54
6.4
<.02 .16
.23
.50
nd <-05
<.04 .16
.53
1.7
<.07
*
(1.3
)1.
9 .86
.17
(T)
61"
0.01
<.05 .18
3.3 .12
.25
.36
<.02
(.28
)7.1 .69
.27
(.95)
.24
3.6
1.6
28 <.02
1.1
1.1
2.5
(4.5)
.008
<.02 .60
4.0
6.4
T<.0
7*
(4.6
)19 6.
79.
6 nd
DDT
DDT
Dieldrin
_ _<0
.02
<.2
<. 1
T<.0
1<.
02<.
02 nd 2.4
<.07 nd 5.7
<.02 .22
nd <.02 .31
2.8
<.07
*
.92
nd
<0.09
<.02
< 3
4.2 .26
<.02 .24
<.02 .05
(T) 9.6 .40
.11
(T) < 3
4i5
6.5
38 <.02
1.9
1.3
3.4 nd <.05
<.02 .86
4.0
7.8
T<.2*
20 7.8 .20
(T)
<0.0
9<.
02 .009
.96
.04
<.02
< 01
<.02
<-02
(.44
).8
6.019
T<-2 nd .0
03.0
52.061
3.6
T<.0
2
.06
.055
.12
nd <.05
<.02 .13
.02
2.1
T<.0
7*
.70
.23
.08
nd
Endosul
fan
I
<0.09
<.02
<.3
<-3
<.04
<.02 .04
<.02
<.02 nd .69
< 3
<.07 nd <.3
<.3
< 3
<!02
<.02
<.3
<.3
< 1 nd <.05
<.02
< 3
<.05
<.06
<.07
*
<.3
< 3
<.04 nd
Endosul
fan
II
_ m
<0.0
5 -
<.07
<.05
<.02
<.05
<.04
(T) <.06
< 2 nd
K2.0
<.05 ..
<.1 nd --
<.04
<. 1
< 1
<.2*
<.08 nd
cis-
Chlo
rdan
e
g 0.
15<.
02g<
3.0
g 4.
0
<.04
<.02
< 01
<.02
<.02 nd
T<.0
3g
.76
<.07 nd
g .4
1g
2.3
g .4
5.0
5
<.02
g .3
8g 3.0
<.1 nd
9<-5 <.02
g<3.
0<.
05T<
.3 <.07
*
g 1.4
g -37
<.04 nd
trans-
Chlo
rdan
e
m m
<0.0
2
<.04
<.02
< 01
<.02
<.02 nd
T<.03
<.07 nd .09
<.02
<.1 nd --
<.02
<.05
T <.
3<.
07*
<.04 nd
Table
13
. C
on
cen
tra
tion
s of
org
an
och
lorin
e
com
poun
ds
ass
oci
ate
d w
ith
su
spen
ded
sedim
ent,
Yak
ima
Riv
er
ba
sin
, W
ashi
ngto
n,
June
2
5-3
0,
1989--
Contin
ued
Station
number
1247
8200
12479500
12484100
12484480
1248
4500
12484500
12484550
1249
6510
12496511
12499000
1249
9000
1250
0430
1250
0445
1250
0450
1250
0450
12502500
1250
5350
12505410
12505460
4625
ID-
1203
2390
112
5055
1012
5075
08
1250
7585
1250
7585
12507594
461720-
1200
4320
1
1250
8620
1250
8630
1250
8850
12509050
1250
9710
12509829
1251
0500
12510500
Stat
ion
name
Cooper River
at Salmon L
aSac
Yaki
ma River
at Cle
Elum
Wils
on C
r ab
v. Ch
erry
Cre
ekCherry C
reek at Th
rall
Yakima River
at Um
tanu
mYa
kima
River
at Um
tanu
mUm
tanum
Creek
nr m
outh
Pacifi
c Po
wer
& Li
ght
Comp
any
Wasteway
City
of
Yakima-Finish
Wate
r
Naches River
nr No
rth
Yakima
Naches River
nr No
rth
Yakima
Moxe
e Drain
at Thorp
RdWi
de Hollow C
reek
nea
r mo
uth
Yaki
ma R
abv Ahtanum
CrYakima R
abv Ahtanum
CrAhtanum
Cree
k at
Union
Gap
E Toppenish
Drain
at W
ilson
RdSub
35 Drain
at Parton R
oad
Granger
Drai
n at
mo
uth
Well
2, Harrah.
11N/
18E-
22R0
2Ma
rion
Dra
in,
Indi
an C
hurc
h Rd
Toppenish
Cr,
Indi
an C
hurc
h Rd
Yaki
ma Ri
ver
at RM
72
Yaki
ma River
at RM
72
Satu
s Cr
ab
v Wi
I son- Cha
r ley
Cany
on n
r Toppenish
Well
1,Sunnyside, 09
N/22
E-04
P01
Satu
s Cr
at gage a
t Satus
Sout
h Drain
nr Sa
tus
Sulphur
Creek
Wasteway
Yaki
ma R
at Euclid B
r at RM
55
Spring Creek
at mo
uth
Snipes Creek
at mo
uth
Yaki
ma R
iver
at
Kion
aYa
kima
River
at Ki
ona
Dacthal
<0.0
2
<.04 nd <.02
< ,Q1
<.02
<.02 nd <.03
<.07 nd .23
<.02 .31
nd -- <.02 .. .15
T<.06
<.07
<.04 nd
Endr
in
<0.09
<.02
<.3
<.3
<.04 nd <.02
<.01
<.02
<.02 nd <.03
<.3
<.07 nd <.3
<.3
<.3 .31
<.02
<.3
<.3
< 1 nd <.05
<.02
< 3
<.05
<.06
<.07
<.3
<.3
<.04 nd
HCB
<0.05
<.07 nd <.07
T<.0
1<.
02
< 01 nd <.01
<.02 nd -- .33
<.01
T<.1
(T) <.01 -- <.01 .08
<.03 .. .16
(T)
alph
a-
HCH
<0.0
2
<.04 nd <.02
< .0
1<.
02
<.02 nd
T<.03
<.07 nd .02
<.02
< 1 nd - <.02
<.05
<.06
<.07
<.04 nd
L i ndane
( gam
ma -
HCH) <0.0
9<.
02<.3
<.3
<-04
(4.0)
<.02
<.oi
<.02
<.02 nd <.03
<.3
<.07 nd <.3
<.3
<.3 .06
<.02
<.3
<.3
T<
1 nd <.05
<.02
< 3
<.05
<.06
<.07
<.3
<.3
<.04 nd
Hepta-
chlo
r epoxide
<0.09
<.02
<.3
<.3
<.04 nd <.02
<,01
<.02
<.02 nd
T<.03
<.3
<.07 nd <.3
<.3
<.3 .15
<.02
<.3
<.3
< 1 nd <.05
<.02
< 3
<.05
<.06
<.07
<.3
<.3
<.04 nd
o,p'
- Meth-
oxy-
chlo
r
<0.0
2
<.04 nd <.02
< 01
<.02
<.04
(T)
<.03
<.07
(T) 3.4**
<.02
< 1
(T) - <.02
<.05
<-06
<.07
<.04 nd
E'P.1"
Meth
-ox
y-
chlo
r
<0.0
9<.
02<.3
<.3
<.04 nd <.02
< 01
<.02
<.04 nd <.03
<.3
<.07 nd <.3
<.3
<.3 .32*
*
<.02
<.3
<.3
< 1 nd <.05
<.02
< 3
<!os
<.06
<.07
<.3
<.3
<.04 nd
Mi rex
0.00
8<.09
<.3 .004
< 2 nd <.oi
<.2
<.02 nd <.03
<.3
<.07 nd <.3
<.3
<.3
<.04
<.09
<.3
<.3
< 5 nd <.05
<.02
< 3
<!os
<.06
<.2
<.3
< 3
<.04 nd
Hepta-
chio
r
<0.0
9<.
05<.
3<.3
<-07 nd < 01
<.02
<-02 nd <.01
<.3
<.02 nd <.3
<.3
<.3
<.02
<.01
<.3
<.3
< 1 nd <.05
<.01
<.3
<.01
<.2
<.07
<.3
<.3
< 01 nd
delt
a-
HCH .
.
<0.0
2-- <.04 nd <.02
< 01
<!02
<.02 nd <.03
<.07 nd -- <.04
<.02
< 1 nd - <.02
<.05
<.06
<.07
<.04 nd
Table 14. Concentrations of organochlorine compounds associated with suspended sediment, Yakima River basin, Washington, May-September 1991
[Concentrations in nanograms per liter; "<" » less than; ODD - dichlorodiphenyldichloroethane; DDE = dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyltrichloroethane; PCB = gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes; "T" = compound present, but less than reported value; "nq" = not quantified because of interference; see figure 1 for site locations]
Map reference number
21 21
23 23 23 23 23
35 35 35 35 35
46 46 46 46 46
484848
5151515151
Station number
12496550 12496550
12500420 12500420 12500420 12500420 12500420
12505450 12505450 12505450 12505450 12505450
12508850 12508850 12508850 12508850 12508850
125094991250949912509499
1251050012510500125105001251050012510500
Station name
Buckskin Slough blw Gleed Ditch nr Gleed Buckskin Slough blw Gleed Ditch nr Gleed
Moxee Drain at Birchfield Road nr Union Gap Moxee Drain at Birchfield Road nr Union Gap Moxee Drain at Birchfield Road nr Union Gap Moxee Drain at Birchfield Road nr Union Gap Moxee Drain at Birchfield Road nr Union Gap
Granger Drain at Granger Granger Drain at Granger Granger Drain at Granger Granger Drain at Granger Granger Drain at Granger
Sulphur Cr Wasteway nr Sunnyside Sulphur Cr Wasteway nr Sunnyside Sulphur Cr Wasteway nr Sunnyside Sulphur Cr Wasteway nr Sunnyside Sulphur Cr Wasteway nr Sunnyside
Chandler Canal at Bunn Rd at FrosserChandler Canal at Bunn Rd at FrosserChandler Canal at Bunn Rd at Frosser
Yakima River at KionaYakima River at KionaYakima River at KionaYakima River at KionaYakima River at Kiona
Date
05-22-91 06-12-91
05-23-91 06-17-91 06-20-91 07-10-91 09-04-91
05-23-91 06-17-91 06-20-91 07-10-91 09-04-91
05-24-91 06-19-91 06-20-91 07-11-91 09-05-91
05-22-9106-13-9106-13-91
05-21-9105-21-9107-09-9108-06-9108-06-91
Time Aldrin
1100 <1 1345 <1
1000 <1 1100 <1 1645 <1 1240 <1 1115 <1
1230 <1 1420 <1 1400 <1 1500 <1 1420 <1
1000 <1 1145 <1 1200 <1 1155 <1 1130 <1
1500 <11240 <11241 <1
1200 <11201 <11155 <11150 <11151 <1
51 12510500 Yakima River at Kiona 09-25-91 1120 <1
Station number
1249655012496550
1250042012500420125004201250042012500420
1250545012505450125054501250545012505450
1250885012508850125088501250885012508850
125094991250949912509499
1251050012510500125105001251050012510500
12510500
Date
05-22-9106-12-91
05-23-9106-17-9106-20-9107-10-9109-04-91
05-23-9106-17-9106-20-9107-10-9109-04-91
05-24-9106-19-9106-20-9107-11-9109-05-91
05-22-9106-13-9106-13-91
05-21-9105-21-9107-09-9108-06-9108-06-91
09-25-91
Gross chlor- dane
<100<100
<100<100<100<100<100
<1001
<100<100<100
<100<100<100<100<100
<100<100<100
<100<100<100<100<100
<100
p,p'-DDD
1<1<11.1
<1113314
21.3
22
<!<1<1
<1<1<1<11
T<1
P,P'- DDE
22
36121
516182919
103
<19
15
112
11111
1
P,P'- DDT
11
35121
413183715
772
1012
<!<1<1
11.2
<1*1
<1
Di- eldrin
<x*1
<11.2.1
1
<!2251
11222
<!<1*1
1<1
.4<11
1
Endo- Hepta- sulfan I Endrin chlor
1 <1 <1<1 <1 <1
1 <1 <1<1 <1 <1
.8 <1 <1<1 <1 <1<1 <1 <1
1 <1 <1<1 <1 <1<1 <1 <1<1 <1 <1<1 <1 <1
2 <1 <1<1 <1 <1
.1 <1 <1<1 <1 <1<1 <1 <1
1 <1 <1<1 <1 <1<1 <1 <1
1 <1 <11 <1 <11 <1 <1
<1 <1 <1<1 <1 <1
<1 <1 <1
43
Table 14. Concentrations of organochlorine compounds associated with suspended sediment, Yakima River basin, Washington, May-September 1991 Continued
Station number
1249655012496550
1250042012500420125004201250042012500420
1250545012505450125054501250545012505450
1250885012508850125088501250885012508850
125094991250949912509499
1251050012510500125105001251050012510500
P-P'- Hepta- Meth- chlor oxy-
Date epoxide Lindane chLor
05-22-91 <1 <1 <1006-12-91 nq <1 <10
05-23-91 <1 <1 <1006-17-91 <1 <1 <1006-20-91 <1 .1 <1007-10-91 <1 <1 <1009-04-91 <1 <1 <10
05-23-91 <1 <1 <1006-17-91 .1 .1 <1006-20-91 <1 .3 <1007-10-91 <1 <1 <1009-04-91 <1 <1 <10
05-24-91 <1 <1 <1006-19-91 <1 <.l <1006-20-91 <1 .5 <1007-11-91 <1 <1 <1009-05-91 <1 <1 <10
05-22-91 <1 <1 <1006-13-91 nq <1 <1006-13-91 nq <1 <10
05-21-91 <1 <1 <1005-21-91 <1 <1 <1007-09-91 <1 <1 <1008-06-91 <1 <1 <1008-06-91 <1 <1 <10
Mirex PCB
<10 <10<10 <100
<10 <10<10 26<10 <100<10 60<10 70
<10 <10<10 <100<10 <100<10 20<10 40
<10 10<10 <100<10 <100<10 <100<10 10
<10 <10<10 <100<10 <100
<10 <10<10 <10<10 10<10 20<10 50
PCN
<100<100
<100<100<100<100<100
<100<100<100<100<100
<100<100<100<100<100
<100<100<100
<100<100<100<100<100
Per- thane
<100<100
<100<100<100<100<100
<100<100<100<100<100
<100<100<100<100<100
<100<100<100
<100<100<100<100<100
Toxa- aphene
<1,000<1,000
<1,000<1,000<1,000<1,000<1,000
<1,000<1,000<1,000<1,000<1,000
<1,000<1,000<1,000<1,000<1,000
<1,000<1,000<1,000
<1,000<1,000<1,000<1,000<1,000
12510500 09-25-91 <1 <1 <10 <10 20 <100 <100 <1,000
44
Table 15. Concentrations of organophosphorus pesticides in whole-water samples, Yakima River basin, Washington, 1988-89
[Concentrations in nanograms per liter; " " = not analyzed; "<" ~ less than; see figure 1 for site locations]
Map reference number
3 3 3 3 3
3 3
4
11
13 13 13 13 13
13 13
1414
22
24 24 24 24 24
24 24 24 24 24
24
27 27 27 27 27
27 27
28
36 36 36 36 36
36 36 36 36
37
38 38 38 38 38
38
43
46 46 46 46 46
Station number
12478300 12478300 12478300 12478300 12478300
12478300 12478300
12479500
12484100
12484480 12484480 12484480 12484480 12484480
12484480 12484480
1248450012484500
12499000
12500430 12500430 12500430 12500430 12500430
12500430 12500430 12500430 12500430 12500430
12500430
12500445 12500445 12500445 12500445 12500445
12500445 12500445
12500450
12505460 12505460 12505460 12505460 12505460
12505460 12505460 12505460 12505460
12505510
12507508 12507508 12507508 12507508 12507508
12507508
12508620
12508850 12508850 12508850 12508850 12508850
Station name
Cle Elum R above Cle Elum Lake nr Roslyn Cle Elum R above Cle Elum Lake nr Roslyn Cle Elum R above Cle Elum Lake nr Roslyn Cle Elum R above Cle Elum Lake nr Roslyn Cle Elum R above Cle Elum Lake nr Roslyn
Cle Elum R above Cle Elum Lake nr Roslyn Cle Elum R above Cle Elum Lake nr Roslyn
Yakima River at Cle Elum
Wilson Creek abv. Cherry Creek at Thrall
Cherry Creek at Thrall Cherry Creek at Thrall Cherry Creek at Thrall Cherry Creek at Thrall Cherry Creek at Thrall
Cherry Creek at Thrall Cherry Creek at Thrall
Yakima River at UmtanumYakima River at Umtanum
Naches River nr North Yakima
Moxee Drain at Thorp Rd nr Union Gap Moxee Drain at Thorp Rd nr Union Gap Moxee Drain at Thorp Rd nr Union Gap Moxee Drain at Thorp Rd nr Union Gap Moxee Drain at Thorp Rd nr Union Gap
Moxee Drain at Thorp Rd nr Union Gap Moxee Drain at Thorp Rd nr Union Gap Moxee Drain at Thorp Rd nr Union Gap Moxee Drain at Thorp Rd nr Union Gap Moxee Drain at Thorp Rd nr Union Gap
Moxee Drain at Thorp Rd nr Union Gap
Wide Hollow Creek near mouth at Union Gap Wide Hollow Creek near mouth at Union Gap Wide Hollow Creek near mouth at Union Gap Wide Hollow Creek near mouth at Union Gap Wide Hollow Creek near mouth at Union Gap
Wide Hollow Creek near mouth at Union Gap Wide Hollow Creek near mouth at Union Gap
Yakima R abv Ah tan urn Cr at Union Gap
Granger Drain at mouth nr Granger Granger Drain at mouth nr Granger Granger Drain at mouth nr Granger Granger Drain at mouth nr Granger Granger Drain at mouth nr Granger
Granger Drain at mouth nr Granger Granger Drain at mouth nr Granger Granger Drain at mouth nr Granger Granger Drain at mouth nr Granger
Marion Drain at Indian Church Rd at Granger
Toppenish Cr at Indian Church Rd nr Granger Toppenish Cr at Indian Church Rd nr Granger Toppenish Cr at Indian Church Rd nr Granger Toppenish Cr at Indian Church Rd nr Granger Toppenish Cr at Indian Church Rd nr Granger
Toppenish Cr at Indian Church Rd nr Granger
Satus Creek at gage at Satus
Sulphu Cr Wasteway nr Sunnyside Sulphu Cr Wasteway nr Sunnyside Sulphu Cr Wasteway nr Sunnyside Sulphu Cr Wasteway nr Sunnyside Sulphu Cr Wasteway nr Sunnyside
Date
05-05-88 06-02-88 07-26-88 07-26-88 08-31-88
11-16-88 03-09-89
07-26-88
07-26-88
05-05-88 06-02-88 06-02-88 07-26-88 08-31-88
11-18-88 03-09-89
07-27-8806-28-89
07-26-88
05-06-88 05-06-88 06-01-88 07-26-88 07-27-88
07-28-88 07-29-88 08-30-88 11-15-88 03-10-89
06-28-89
05-05-88 06-03-88 07-27-88 08-30-88 11-15-88
11-15-88 03-10-89
07-27-88
05-06-88 06-01-88 07-28-88 07-28-88 07-28-88
09-02-88 11-15-88 03-09-89 06-27-89
07-28-88
05-06-88 06-03-88 07-28-88 09-01-88 11-16-88
03-08-89
07-29-88
05-06-88 06-03-88 07-28-88 07-28-88 08-31-88
Time
1100 0930 1000 1015 1030
1030 1015
1500
1615
1530 1400 1405 1030 1630
1000 1400
10451705
1330
0930 0940 1600 1100 1310
1605 0800 1730 1015 1200
1035
1845 0730 1025 1430 1330
1430 1400
1600
1230 1300 0730 0930 1015
1000 1645 1730 1705
1145
1345 1000 1445 0930 1615
1600
1145
1630 1300 1200 1700 1530
Chlor- pyrifos
-
-
-
----
-
10 10
-
--
--
-
-
--
Diaz- inon
1
<iS<10
<10
11So<10<10
<10
10 360 630
130 530 30
370
120 10
<10
20
30 2010
10
10
230
150 10
<10
50
20 10 10
Table 15. Concentrations of organophosphorus pesticides in whole-water samples, Yakima River basin, Washington, 1988-1989 Continued
Station number
12478300 12478300 12478300 12478300 12478300
12478300 12478300
12479500
12484100
12484480 12484480 12484480 12484480 12484480
12484480 12484480
12484500 12484500
12499000
12500430 12500430 12500430 12500430 12500430
12500430 12500430 12500430 12500430 12500430
12500430
12500445 12500445 12500445 12500445 12500445
12500445 12500445
12500450
12505460 12505460 12505460 12505460 12505460
12505460 12505460 12505460 12505460
12505510
12507508 12507508 12507508 12507508 12507508
12507508
12508620
12508850 12508850 12508850 12508850 12508850
Date
05-05-88 06-02-88 07-26-88 07-26-88 08-31-88
11-16-88 03-09-89
07-26-88
07-26-88
05-05-88 06-02-88 06-02-88 07-26-88 08-31-88
11-18-88 03-09-89
07-27-88 06-28-89
07-26-88
05-06-88 05-06-88 06-01-88 07-26-88 07-27-88
07-28-88 07-29-88 08-30-88 11-15-88 03-10-89
06-28-89
05-05-88 06-03-88 07-27-88 08-30-88 11-15-88
11-15-88 03-10-89
07-27-88
05-06-88 06-01-88 07-28-88 07-28-88 07-28-88
09-02-88 11-15-88 03-09-89 06-27-89
07-28-88
05-06-88 06-03-88 07-28-88 09-01-88 11-16-88
03-08-89
07-29-88
05-06-88 06-03-88 07-28-88 07-28-88 08-31-88
Methyl Methyl Disulfo- Mala- para- tri- Para- ton Ethion thion thion thion thion Phorate
:: SS <JS SS <jo SS ::
-- SS <l°o SS <!°o So "<10 <10 <10 <10 <10
<10 <10 <10 <10 <10
:: | | | | | ::
-- <10 <10 <10 <10 <10 --
~ So So So So So --<10 <10 <10 <10 <10
-- <10 <10 <10 <10 ^lO 20 410 <10 <10 <10 80 240 140 <10 <10 <10 10 100
50 <10 <10 <10 100 140 40 <10 <10 <10 10 90
-- 100 <10 <10 <10 <10 10
<10 <10 <10 <10 <10 90
-- <10 <10 <10 < 10 <10 -- <10 60 <10 <10 10 --
:: SS SS SS SS SS "<10 <10 <10 <10 <10
-- <10 10 <10 <10 <10
ij | | ! | | ii-- <10 <10 <10 <10 20 --
-- <10 <10 <10 <10 ^lO -- <10 10 <10 <10 <10 <10 <10 ^lO <10 20
<10 <10 <10 <10 <10
<10 <10 <10 <10 10
-- <10 <10 <10 <10 10 -- 70 <10 <10 <10 <10 <10 10 60 <10 <10 <10 < 10 <10 10 -- <10 <10 <10 <10 <10 --
Tri- thion
1
So<10
<10
1So
So<10
SS
SS<10
i<io<10
I<10
<10
SS
<io<10
o o o o oi-» i-» i-» r-l r-»V V V V V
46
Table 15. Concentrations of organophosphorus pesticides in whole-water samples, Yakima River basin, Washington, 1988-1989 Continued
Mapreferencenumber
46464646
47
49
50
5151515151
5151515151
58
5959
61
Station number
12508850125088501250885012508850
12509050
12509710
12509829
1251050012510500125105001251050012510500
1251050012510500125105001251050012510500
463233120262101
463234120261601463234120261601
463257120260801
Station name
Sulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr Sunnyside
Yakima R at Euclid Br at RM 55 nr Grandview
Spring Creek at mouth at Whitstran
Snipes Creek at mouth st Whitstran
Yakima River at KionaYakima River at KionaYakima River at KionaYakima River at KionaYakima River at Kiona
Yakima River at KionaYakima River at KionaYakima River at KionaYakima River at KionaYakima River at Kiona
Well 12N/19E-09H02
Well 12N/19E-09H01Well 12N/19E-09H01
Well 12N/19E-10D02
Date
08-31-8811-17-8803-08-8906-26-89
07-28-88
07-29-88
07-29-88
05-07-8806-01-8807-29-8808-31-8811-17-88
03-08-8906-26-8912-06-8912-06-8912-07-89
01-20-89
01-20-8901-20-89
01-20-89
Time
1630090012002005
1010
1300
1500
08000900103010001400
09001435161523571852
0750
07300737
0715
Chlor-pyrifos
__------
-
__----
----
__--------
-
--
--
Diaz-inon
<10<10<1020
70
70
10
<10<102501010
<1030
<10<10<10
<10
<10<10
<10
Station number
12508850125088501250885012508850
12509050
12509710
12509829
1251050012510500125105001251050012510500
1251050012510500125105001251050012510500
Disulfo- Mala-Date ton Ethion thion
08-31-88 -- <10 <1011-17-88 <10 <1003-08-89 <10 <1006-26-89 <10 10
07-28-88 <10 <10
07-29-88 <10 10
07-29-88 -- <10 <10
05-07-88 -- <10 <1006-01-88 <10 <1007-29-88 -- <10 <1008-31-88 -- <10 <1011-17-88 -- <10 <10
03-08-89 <10 <1006-26-89 -- <10 <1012-06-89 <10 <10 <1012-06-89 <10 <10 <1012-07-89 <10 <10 <10
Methyl Methylpara- tri-thion thion
<10 <10<10 <10<10 <10<10 <10
<10 <10
<10 <10
<10 <10
<10 <10<10 <10<10 < 10<10 <10<10 <10
<10 <10<10 <10<10 <10<10 <10<10 <10
Para-thion
<10<10<10<10
30
10
<10
<10<1060
<10<10
<1010
<10<10<10
Phorate
__----
10
--
--
--------
--
<10<10<10
Tri-thion
<10<10<10<10
<10
<10
<10
<10<10<10<10<10
<10<10<10<10<10
463233120262101 01-20-89
463234120261601 01-20-89 463234120261601 01-20-89
463257120260801 01-20-89
47
Tabl
e 16.
Conc
entr
atio
ns of
organophosphorus pesticides in fiItered-water samples, Yakima Ri
ver
basin, Washington,
June
25-30, 19
89
[Concentrations
in n
anograms per
liter: "D"
= detected an
d not
quantified;
nd =
not
detected a
nd m
inim
um re
port
ing
leve
l not
quantified;
H..H
=
not;
anal
yzed
; "T"
= pr
esen
t, but
belo
w quantifiable c
once
ntra
tion
; "<"
= less th
an;
DEF
= (S
,S.S
-tri
buty
l ph
osph
orot
rith
ioat
e),
methamidophos, an
d terbufos w
ere
not
dete
cted
; for
qual
ity
assu
ranc
e, three
addi
tion
al re
plic
ate
samp
les
from t
he Y
akima
Rive
r at
Ki
ona
were analyzed for
azinphos-methyl, an
d the concentrations we
re 6
.5,
6.7, an
d 9.
0 ng
/L;
see
figu
re
1 for
site
locations]
oo
Map
refe
renc
e Station
number
numb
er
2 4 11 13 14 15 19 20 22 24 27 28 30 33 34 36 55 37 38 40 41 53 43 45 46 47 49 50 51
1247
8200
1247
9500
12484100
12484480
12484500
12484550
12496510
1249
6511
1249
9000
1250
0430
12500445
1250
0450
1250
2500
1250
5350
1250
5410
1250
5460
462510-
1203
2390
112
5055
1012507508
12507585
1250
7594
461720-
1200
4320
112
5086
2012
5086
3012508850
12509050
1250
9710
12509829
1251
0500
Azinphos-
Chlo
r-
Stat
ion
name
meth
yl
pyrifos
Coop
er Ri
ver
at Sa
lmon
LaSac
Yakima Ri
ver
at Cl
e El
urn
Wilson C
r abv. Ch
erry
Creek
Cherry C
reek a
t Th
rall
Yakima Ri
ver
at Umtanum
Umtanum
Cree
k nr mo
uth
Pacific
Powe
r &
Ligh
t Company
Wast
eway
City o
f Ya
kima
- Fi
nish
Water
Nacnes Ri
ver
nr No
rth
Yakima
Moxe
e Dr
ain
at Thorp
Rd
Wide Hollow C
reek ne
ar m
outh
Yakima R
abv Ahtanum
CrAh
tanu
m Cr
eek
at Un
ion
Gap
E Toppenish
Drai
n at
Wilson R
dSub
35 D
rain
at
Parton R
oad
Gran
ger
Drain
at mo
uth
Well
2, Harrah.
11N/
18E-
22R0
2Marion D
rain
, Indian C
hurc
h Rd
Toppenish
Cr,
Indian C
hurc
h Rd
Yakima Ri
ver
at RM
72
Satu
s Cr
ab
v Wi
lson
-Cha
rley
Canyon n
r To
ppenish
Well
1,
Su
nnys
ide,
09
N/22
E-04
P01
Satu
s Cr
at
gage at Sa
tus
Sout
h Drain
nr S
atus
Sulp
hur
Cree
k Wasteway
Yaki
ma R
at Euclid B
r at
RM 5
5Spring Cr
eek
at mo
uth
Snipes Cr
eek
at mouth
Yakima Ri
ver
at Kiona
nd
<4.6 nd nd nd D D D D nd D
T<4.6 D nd D nd
<1 6
<\75
<3.3
T<3.
1T<
2.4
1.0
<.73
<1 .0
<.65
T<6.7
<3
1<2
i2T<2.1
3.3
T<3.1
T<6.0
<1 .0
<3.
1T<
2.0
T<3.
1
<.66
<1 0
T<3.1
<6.7
<26
T<2.2
2.8
<3.
19.6
Demeton-S
<2
1<>6
<4.4
<4.0
<2.4
<1.2 <.74
<1 .4
<.77
T<7.
9
<4
1<2
i3T<
2.5
<4.2
<4.1
<7.1
<1 .4
<4.
1<2
.4<4
.0 <.79
<1 .3
<4.2
<8.0
T<34 <2
.6<4
.2<4
.1<2
.4
Diazinon
<1 3 !67
<2.7
T<2.7
T<2.
0
<1.2 <.64
<.83
T<.6
4410 5.
97.
93.
328 25 11 T<
.83
55 31 35 <.65
<.82
22 150 66 120 71 32 39
Dime
tho-
at
e <2.2
<1 .2
<4.7
<3.5
<3.7
<1.1
<1 .
1<1
.4
<1 .3
<13 5.
7<3
.5<4
.2T<
4.5
T<4.4
T<12 <1
.4
4.6
T<4.0
<3.5
<1 .3
T<1.
47.7
<13
330 7.
3<4.6
T<4.
4<3.7
Disu
lfo-
to
n <1 7
<>8
<3.5
<2.2
<2.4
<1.3 <.76
<1
1<.
74<7
.6
<3.3
<2.3
<2.4
<3.4
T<3.
3
T<6.9
<1
1T<
3.3
T<2.
3T<
2.2
<.76
<1
1T<
3.3
T<7.
7T<27 <2
.5T<
3.4
<3.3
<2.4
Ethion
<2.6
T<1.
2<5
.4<2
.6T<3.9
<1.2
<1 .2
<1 .7
<1 .
1T<11 T<5.
1T<3.7
<3.6
<5.2
<10 <1 7
T<5.
1<3
.5<2
.6
<1 .1
<1 .7
<5.
1<12
<42 <3.7
T<5.
2T<5.1
T<3.
9
Fonofos
<1 0
<!66
<2
1<2
.4<2
.0
<1.2 <.64
<.66
<.68
<7.0
<2.0
<2.0
<2.2
<2.0
<2.0
<6.3 <.66
T<2.
0<2
1
T<2.
4
<.70
<.65
<2.0
<7.
1<1
7 <2.3
<2.0
<2.0
<2.0
Isofen-
phos <1 8
<!84
<3.9
<2.6
T<2.
6
<.90
<.82
<1 2
<.80
<8.2
<3.6
T<2.
5<2
.6<3.7
<3.6
<7.4
<1 2
<3.7
<2.5
<2.6 <.82
<1 2
<3.7
<8.3
<30 <2.7
<3.8
<3.7
<2.6
Table
16.
Concentrations of
organophosphorus pe
stic
ides
in
fiItered-water
samp
les,
Yakima R
iver
basin,
Wash
ingt
on,
June
25-30
, 19
89--
Cont
inue
d
Station
number
12478200
1247
9500
1248
4100
1248
4480
1248
4500
12484550
12496510
12496511
1249
9000
12500430
1250
0445
12500450
1250
2500
1250
5350
12505410
1250
5460
4625
ID-
120323901
1250
5510
12507508
12507585
12507594
4617
20-
120043201
12508620
1250
8630
1250
8850
1250
9050
1250
9710
12509829
12510500
Station
name
Mala
thio
n
Cooper Ri
ver
at Salmon La
Sac
Yakima Ri
ver
at Cle
Elum
Wils
on C
r abv. Cherry C
reek
Cher
ry C
reek a
t Th
rall
Yakima Ri
ver
at Um
tanu
m
Umta
num
Creek
nr m
outh
Paci
fic
Powe
r &
Ligh
t Company
Wasteway
City o
f Ya
kima
-Fin
ish
Water
Nacnes Ri
ver
nr No
rth
Yakima
Moxee Dr
ain
at Thorp
Rd
Wide Hollow C
reek
nea
r mouth
Yakima R
abv Ah
tanu
m Cr
Ahtanum
Creek
at U
nion G
apE
Topp
enis
h Drain
at Wi
lson
Rd
Sub
35 D
rain
at
Parton R
oad
Gran
ger
Drain
at m
outh
Well
2, Ha
rrah
. 11
N/18
E-22
R02
Mari
on D
rain
, In
dian
Church
RdTo
ppen
ish
Cr,
Indi
an C
hurch
RdYakima Ri
ver
at RM 7
2
Satu
s Cr
abv W
ilso
n-Ch
arle
yCa
nyon
nr
Topp
enis
h
Well
1, Su
nnys
ide,
09
N/22
E-04
P01
Satu
s Cr at ga
ge a
t Sa
tus
Sout
h Drain
nr Sa
tus
Sulphur
Creek
Wasteway
Yakima R
at Euclid B
r at RM 55
Spring C
reek a
t mo
uth
Snipes C
reek
at
mouth
Yakima Ri
ver
at Ki
ona
T<2.7
1.5
T<5.
7T<
2.7
T<3.9
<1.1 5.6
T<1.8
1.6
T<11 13 25 6.
312 19 T<9.9
2.1
31 12 14 <1.1
T<1.
714
T<11
T<44 8.
648 27 70
Methida-
thio
n
<2.4 <.96
140 <2.6 4.9
<.99
<.93
<1.6
<1.0
<10 <4.8
<2.8
<3.4
<4.9
<4.8
<9.5
<1.6
<4.8
<3.2
<2.6
<1.0
<1.6
T<4.
8<1
1<4
0 <3.4
<4.9
<4.8
<3.0
Meth
yl
parathion
<0.69
<1.3
<1.4
<3.1
T<4.
1
<1.4
<1.3 <.45
T<1.4
<14 <1.4
<3.9
<4.5
<1.4
16 <13 5.
6<1.4
<4.3
T<3.1
<1.4 <.44
<1.4
<14
<11 <4.6
13 <1.4
<4.1
Meth
yl
trithion
<2.4
<1.2
<5.1
<2.5
T<3.8
<1.5
<1.2
<1.6
T<1.2
<12 <4.8
<3.6
<3.9
<4.9
<4.8
<11 <1.6
<4.8
<3.7
<2.5
<1.2
<1.6
<4.8
<12
<40 <4.0
<4.9
<4.8
<3.8
Mevinphos
<2.1
<1.0
<4.4
<3.5
<3.2 <.93
<1.0
<1.3 <.93
<9.5
<4.1
<3.0
<3.0
<4.2
<4.1
T<8.6
<1.3
<4.1
<2.9
<3.5 <.95
<1.3
<4.1
<9.6
<34 <3.1
<4.2
<4.1
<3.2
Parathion
<2.6
<1.0
<5.4
<3.0
T<3.
2
T<1.
0<1
.7T<
1.3
<14 <5.1
T<3.
1<4.4
10 <5.1
<12 <1.7 7.4
16 11 <1.4
<1.7
180 23 <42 30 12
T<5.1
T<3.2
Phorate
<2.4 <.88
<5.1 5.2
<2.8 <.92
<.86
<1.6 <.87
130 <4.8 3.6
<2.8
10 <4.8
<8.0
<1.6
19 <2.7
T<3.4
<.89
<1.6
<4.8
<9.0
T<40 T<2.9
<4.9
<4.8
T<2.
8
Phos
pham
- id
on <2.2
T<2.1
T<4.
7<2.4
T<6.
5
<.86
<2.0
<1.5
T<1.0
43 8.1
T<6.1
5.3
52 16 56 T<1.
510 <3.2
T<2.4
<1.0
T<1.
4<4
.5<1
1T<
37 22 6.7
28 5.3
Trithion
<2.6
<1.1
<5.3
<2.5
<3.6 <.99
<1.1
<1.6 <.92
<9.4
<5.0
<3.4
<3.0
<5.1
<5.0
<8.5
<1.6
<5.0
<2.9
<2.5 <.94
<1.6
<5.1
<9.5
<42 <3.1
T<5.
2<5.0
<3.6
Table 17. Concentrations of organophosphorus pesticides in filtered-water samples, Yakima River basin, Washington, May-September 1991
[Concentrations in nanograms per liter; "<" - less than; DEF - S,S,S-tributyl phosphorotrithioate;see figure 1 for site locations]
Mapreference number
21 21
23 23 23 23 23
35 35 35 35 35
46 46 46 46 46
48 48
51 51 51 51 51
Station number
12496550 12496550
12500420 12500420 12500420 12500420 12500420
12505450 12505450 12505450 12505450 12505450
12508850 12508850 12508850 12508850 12508850
12509499 12509499
12510500 12510500 12510500 12510500 12510500
Station number
12496550 12496550
12500420 12500420 12500420 12500420 12500420
12505450 12505450 12505450 12505450 12505450
12508850 12508850 12508850 12508850 12508850
12509499 12509499
12510500 12510500 12510500 12510500 12510500
Station name
Buckskin Slough blw Gleed Ditch nr Gleed Buckskin Slough blw Gleed Ditch nr Gleed
Moxee Drain at Birchfield Road nr Union Gap Moxee Drain at Birchfield Road nr Union Gap Moxee Drain at Birchfield Road nr Union Gap Moxee Drain at Birchfield Road nr Union Gap Moxee Drain at Birchfield Road nr Union Gap
Granger Drain at Granger Granger Drain at Granger Granger Drain at Granger Granger Drain at Granger Granger Drain at Granger
Sulphur Cr Wasteway nr Sunnyside Sulphur Cr Wasteway nr Sunnyside Sulphur Cr Wasteway nr Sunnyside Sulphur Cr Wasteway nr Sunnyside Sulphur Cr Wasteway nr Sunnyside
Chandler Canal at Bunn Rd at Prosser Chandler Canal at Bunn Rd at Prosser
Yakima River at Kiona Yakima River at Kiona Yakima River at Kiona Yakima River at Kiona Yakima River at Kiona
Disulfo- Mala- Date ton Ethion Fonofos thion
05-22-91 <10 <10 <10 <10 06-12-91 <10 <10 <10 <10
05-23-91 <10 <10 <10 <10 06-17-91 <10 <10 <10 10 06-20-91 <10 <10 <10 10 07-10-91 <10 20 <10 <10 09-04-91 <10 20 <10 <10
05-23-91 <10 <10 <10 <10 06-17-91 <10 <10 <10 20 06-20-91 <10 <10 10 20 07-10-91 <10 <10 <10 <10 09-04-91 <10 <10 <10 <10
05-24-91 <10 <10 <10 <10 06-19-91 <10 <10 <10 20 06-20-91 <10 <10 <10 50 07-11-91 <10 <10 <10 50 09-05-91 <10 <10 <10 <10
05-22-91 <10 <10 <10 <10 06-13-91 <10 <10 <10 30
05-21-91 <10 <10 <10 <10 07-09-91 <10 <10 <10 290 08-06-91 <10 <10 <10 <10 08-06-91 <10 <10 <10 <10 09-25-91 <10 <10 <10 <10
Date
05-22-91 06-12-91
05-23-91 06-17-91 06-20-91 07-10-91 09-04-91
05-23-91 06-17-91 06-20-91 07-10-91 09-04-91
05-24-91 06-19-91 06-20-91 07-11-91 09-05-91
05-22-91 06-13-91
05-21-91 07-09-91 08-06-91 08-06-91 09-25-91
Methyl Methyl para- tri- thion thion
:i°Q SS60 <10 20 <10
10 <10 30 <10
10 <10 40 <10
So1 S5So So
Chlor- Time pyrifos DEF
1100 <10 <10 1345 <10 <10
1000 10 <10 1100 10 <10 1645 10 <10 1240 <10 <10 1115 <10 <10
1230 <10 <10 1420 <10 <10 1400 <10 <10 1500 <10 <10 1420 <10 <10
1000 <10 <10 1145 <10 <10 1200 10 <10 1155 <10 <10 1130 <10 <10
1500 <10 <10 1240 <10 <10
1200 <10 <10 1155 <10 <10 1150 <10 <10 1151 <10 <10 1120 <10 <10
Para- Tri- thion Phorate thion
<Jo So So<10 10 <10
<10 10 <10
10 <10 <10 10 <10 <10
<10 10 <10
20 10 <10 10 <10 <10
S5 SS So10 <10 <10
10 <10 <10
Diaz- inon
S!340
1,300 30 10
10 30
20 50 20
So
10 10 10
50
Table 18. Concentrations of organophosphorus pesticides associated with suspended sediment, Yakima River basin, Washington, June 25-30, 1989
[Concentrations in nanograms per liter; " " « not analyzed; "T" - present, but below quantifiable concentration; "<" - less than; DEF - S,S,S-tributy1 phosphorotrithioate; see figure 1 for site locations]
Map reference Station number number
24
111314
1519
202224
2728303334
3655
373840
41
53
434546
47495051
1247820012479500124841001248448012484500
1248455012496510
124965111249900012500430
1250044512500450125025001250535012505410
12505460462510-120323901125055101250750812507585
12507594
461720-120042301125086201250863012508850
12509050125097101250982912510500
Chlor- Station name pyrifos
Cooper River at Sslmon LaSacYakima River at Cle ElumWilson Cr abv. Cherry CreekCherry Creek at ThrallYakima River at Umtanum
Umtanum Creek nr mouthPacific Power & Light CompanyWastewayCity of Yakima-Finish WaterNaches River nr North YakimaMoxee Drain at Thorp Rd
Wide Hollow Creek near mouthYakima R abv Ahtanum CrAhtanum Creek at Union GapE Toppenish Drain at Wilson RdSub 35 Drain at Parton Road
Granger Drain at mouth
Well 2, Harrah, 11N/18E-22R02Marion Drain, Indian Church RdToppenish Cr, Indian Church RdYakima River at RM 72
Satus Cr abv Wilson-CharleyCanyon nr Toppenish
Well 1, Sunnyside, 09N/22E-04P01Satus Cr at gage at SatusSouth Drain nr SatusSulphur Creek Wasteway
Yakima R at Euclid Br at RM 55Spring Creek at mouthSnipes Creek at mouthYakima River at Kiona
<0.05<.04<.2.3
<.06
<.04
<.02<.04K.04
.48
<.l<.l<.2.4
<.l
<.08
<.04<.l.1
T<.1
<.03
<.04.2
K.09.16
<.l.2.2
T<.06
DEF
__<.04----
<.06
<.04
<.02<.04<.04<.05
<.l------
<.08
<.04----
<.l
--
<.04--
<.09<.l
<.l----
<.06
Diazinon
<0.05<.04<.2<.l<.06
<.04
<.02.06
<.043.3
<.lT<.1<.2.3.3
1.9
<.04.3.2.16
<.03
<.04.2.29.18
T<.1.9.3.07
Disulfo- ton
<0.05<.04<.2.6
<.06
<.04
<.02<.04<.04<.05
<.l<.l<.2<.l<.l
<.08
<.04<.l<.l<.l
<.03
<.04<.l<.09<.l
<.l<.l<.l<.06
Ethion
<0.05<.04<.2<.l<.06
<.04
<.02<.04
T<.04.52
<.l<.l<.2<.l<.l
T<.08
<.04<.l<.l
T<.1
<.03
<.04<.l<.09T<.1
<.l.5
<.l<.06
Fonofos
__<0.04
----
<.06
<.04
<.02<.04<.04<.05
--<.l------
<.08
<.04----
<.l
--
<.04--
<.09<.l
<.l----
<.06
Isofen- phos
<0.04
----
<.06
<.04
<.02<.04<.04<.05
--<. 1 ----
<.08
<.04--
* !
--
<.04--
<.09< - 1
T<.1 --
<.06
Station Number
1247820012479500124841001248448012484500
1248455012496510
124965111249900012500430
1250044512500450125025001250535012505410
12505460462510-120323901125055101250750812507585
12507594
461720-120043201125086201250863012508850
12509050125097101250982912510500
Station name
Cooper River at Salmon LaSacYakima River at Cle ElumWilson Cr abv. Cherry CreekCherry Creek at ThrallYakima River at Umtanum
Umtanum Creek nr mouthPacific Power & Light CompanyWastewayCity of Yakima-Finish WaterNaches River nr North YakimaMoxee Drain at Thorp Rd
Wide Hollow Creek near mouthYakima R abv Ahtanum CrAhtanum Creek at Union GapE Toppenish Drain at Wilson RdSub 35 Drain at Parton Road
Granger Drain at mouth
Well 2, Harrah, 11N/18E-22R02Marion Drain, Indian Church RdToppenish Cr, Indian Church RdYakima River at RM 72
Satus Cr abv Wilson-CharleyCanyon nr Toppenish
Well 1, Sunnyside, 09N/22E-04P01Satus Cr at gage at SatusSouth Drain nr SatusSulphur Creek Wasteway
Yakima R at Euclid Br at RM 55Spring Creek at mouthSnipes Creek at mouthYakima River at Kiona
Malathion
<0.05<.04< .2< . i<.06
<.04
<.02<.04<.04<.05
<_!<. i<.2< . 1* !
<.08
<.04<. 1<. 1-M
<.03
<.04<. 1<.09< - 1
<.!<. 1<. 1<.06
Methyl parathion
<0.05<.04<.2<.l<.06
<.04
T<.02<.04<.04<.05
<.l<.l<.2<.l<.l
<.08
<.04<.l<.l<.l
<.03
<.04.6
<.09<.l
<.l<.l.3
<.06
Methyl trithion
<0.05<.04<.2<.l<.06
<.04
<.02<.04<.04<.05
<.l<.l<.2<.l<.l
<.08
<.04<.l<.l<.l
<.03
<.04<.l<.09<.l
<.l<.l<.l<.06
Parathion
<0.05<.04<.2<.l<.06
<.04
<.02<.04<.04.14
<.l<.l<.2.5
<.l
<.08
<.04<.l.1.10
<.03
<.04.3.17.10
<.l.5.2
T<.06
Phorate
<0.05<.04<.2.3
<.06
<.04
<.02<.04<.041.4
<.l<.l<.2<.l<.l
<.08
<.04<.l<.l<.l
<.03
<.04<.l<.09
T<.1
<.l<.l<.l<.06
Trithion
<0.05<.04<.2< . 1<.06
<.04
<.02<.04<.04<.05
<_!<. 1<.2< . 1 = 1
<.08
<.04<. 1<. 1< 1
<.03
.04
.1
.09
.1
.1
.1
.1
.06
51
Table 19. Concentrations of organophosphorus pesticides associated with suspended sediment, Yakima River basin, Washington, May-September 1991
[Concentrations in nanograms per liter; "<" = less than; DBF = S,S,S-tributyl phosphorotrithioate;see figure 1 for site locations]
Map referencenumber
2121
2323232323
3535353535
4646464646
484848
5151515151
51
Station number
1249655012496550
1250042012500420125004201250042012500420
1250545012505450125054501250545012505450
1250885012508850125088501250885012508850
125094991250949912509499
1251050012510500125105001251050012510500
12510500
Station name
Buckskin Slough blw Gleed Ditch nr GleedBuckskin Slough blw Gleed Ditch nr Gleed
Moxee Drain at Birchfield Road nr Union GapMoxee Drain at Birchfield Road nr Union GapMoxee Drain at Birchfield Road nr Union GapMoxee Drain at Birchfield Road nr Union GapMoxee Drain at Birchfield Road nr Union Gap
Grange Drain at GrangerGrange Drain at GrangerGrange Drain at GrangerGrange Drain at GrangerGrange Drain at Granger
Sulphu Cr Wasteway nr SunnysideSulphu Cr Wasteway nr SunnysideSulphu Cr Wasteway nr SunnysideSulphu Cr Wasteway nr SunnysideSulphu Cr Wasteway nr Sunnyside
Chandler Canal at Bunn Rd at ProsserChandler Canal at Bunn Rd at ProsserChandler Canal at Bunn Rd at Prosser
Yakima River at KionaYakima River at KionaYakima River at KionaYakima River at KionaYakima River at Kiona
Yakima River at Kiona
Date
05-22-9106-12-91
05-23-9106-17-9106-20-9107-10-9109-04-91
05-23-9106-17-9106-20-9107-10-9109-04-91
05-24-9106-19-9106-20-9107-11-9109-05-91
05-22-9106-13-9106-13-91
05-21-9105-21-9107-09-9108-06-9108-06-91
09-25-91
Time
11001345
10001100164512401115
12301420140015001420
10001145120011551130
150012401241
12001201115511501151
1120
Chlor-pyrifos
<0*
<<
<*
<<<<*
<<<<*
<<*
<<<
<10<10
<
53
45864
35754
46744
766
444
5
Diaz-DEF inon
<0.5 <0.5<.3 <.3
<.4 <.4<'.5 1<.4 30<.6 1<.4 <.4
<.3 <.3< . 5 <. 5<.7 1< . 5 < . 5<.4 <.4
<.4 <.4<.6 <.6<.7 1<. 4 <.4<.4 <.4
< 7 < 7<. 6 <. 6<.6 <.6
<.4 <.4<. 4 <. 4<. 4 <. 4
<10 <10<10 <10
<.5 <.5
Methyl Methyl
Station number
1249655012496550
1250042012500420125004201250042012500420
1250545012505450125054501250545012505450
1250885012508850125088501250885012508850
125094991250949912509499
1251050012510500125105001251050012510500
Disulf- Mala-Date oton Ethion Fonofos thion
05-22-91 <0.5 <0.5 <0.5 <0.506-12-91 <.3 <.3 <.3 <.3
05-23-91 <.« <.4 <.4 <.406-17-91 <.5 <.5 <.5 <.506-20-91 <.4 <.4 <.4 <.407-10-91 <.6 1 <.6 <.609-04-91 <.4 1 <.4 <.4
05-23-91 <.3 <.3 <.3 <.306-17-91 <.5 <.5 <.5 <.506-20-91 <.7 <.7 <.7 <.707-10-91 <.5 <.5 <.5 <.509-04-91 <.4 <.4 <.4 <.4
05-24-91 <.4 <.4 <.4 <.406-19-91 <.6 <.6 <.6 <.606-20-91 <.7 <.7 <.7 <.707-11-91 <.4 <.4 <.4 <.409-05-91 <.4 <.4 <.4 <.4
05-22-91 <.7 <.7 <.7 <.706-13-91 <.6 <.6 <.6 <.606-13-91 <.6 <.6 <.6 <.6
05-21-91 <.4 <.4 <.4 <.405-21-91 <.4 <.4 <.4 <.407-09-91 <.4 <.4 <.4 .408-06-91 <10 <10 <10 <1008-06-91 <10 <10 <10 <10
para- tri-thion thion
<0.5 <0.5<.3 <.3
<.4 <.4<. 5 <.54 <.41 <.6.5 <.4
<.3 <.31 < . 52 <.71 <. 5.6 <.4
< 4 <.43' <!e7 <.71 < . 4.4 <.4
< 7 <_ 7<.6 <.6<.6 <.6
<.4 <.4<.4 <. 4<.4 <. 4
<10 <10<10 <10
Para-thion
<0.5<.3
<.4<.5<.4<.6<.4
<.3<.5<.7<.5<.4
<.4<.61<.4<.4
<.7<-6<.6
<.4<.4<.4
<10<10
Tri-Phorate thion
<0<
<<<
<
<<<<<
<<<<<
<<*
<<<
<10<10
5 <0.53 <.3
4 <.45 <.54 <.46 <.64 <.4
3 <.35 <.57 <.75 <.54 <.4
4 <.46 <.67 <.74 <.44 <.4
7 <.76 <.66 <.6
4 <.44 <.44 <.4
<10<10
12510500 09-25-91
52
Table 20. Concentrations of phenol and cresoL compounds (acid-extractable compounds) in whole-water samples,Yakima River basin, Washington, 1988-89
[Concentrations in nanograms per liter; "<" « less than; see figure 1 for site locations]
Map reference number Station number
24 12500430
27 12500445 27 12500445 27 12500445 27 12500445 27 12500445 27 12500445
28 12500450
36 12505460
46 12508850 46 12508850 46 12508850 46 12508850
51 12510500
Station name
Moxee Drain at Thorp Rd nr Union Gap
Wide RoLLow Creek near mouth at Union Gap Wide RoLLow Creek near mouth at Union Gap Wide RoLLow Creek near mouth at Union Gap Wide RoLLow Creek near mouth at Union Gap Wide RoLLow Creek near mouth at Union Gap Wide RoLLow Creek near mouth at Union Gap
Yakima R abv Ahtanum Cr at Union Gap
Granger Drain at mouth nr Granger
SuLphur Cr Wasteway nr Sunnyside SuLphur Cr Wasteway nr Sunnyside SuLphur Cr Wasteway nr Sunnyside SuLphur Cr Wasteway nr Sunnyside
Yakima River at Kiona
Station number Date
12500430
125004451250044512500445125004451250044512500445
12500450
12505460
12508850125088501250885012508850
08-30-88
05-05-8807-27-8808-30-8811-15-8811-15-8803-10-89
07-27-88
09-02-88
07-28-8807-28-8808-31-8808-31-88
2,4-Di-methyL- phenoL
<5,000
<5,000<5,000<5,000<5,000<5,000<5.000
<5,000
<5,000
<5,000<5,000<5,000<5,000
4.6-2,4,- Di-
Dinitro- nitro- o-cresoL phenoL
<30,000
<30,000<30,000<30,000<30,000<30,000<30,000
<30,000
<30,000
<30,000<30,000<30,000<30,000
<20,000
<20,000<20,000<20,000<20,000<20,000<20,000
<20,000
<20,000
<20,000<20,000<20,000<20,000
2-Nitro- phenoL
<5,000
<5,000<5,000<5,000<5,000<5,000<5,000
<5,000
<5,000
<5,000<5,000<5,000<5,000
4-
Date
08-30-88
05-05-88 07-27-88 08-30-88 11-15-88 11-15-88 03-10-89
07-27-88
09-02-88
07-28-88 07-28-88 08-31-88 08-31-88
08-31-88
Nitro- phenoL
<30,
<30,<30,<30,<30,<30,<30,
<30,
<30,
<30,<30,<30,<30,
000
000000000000000000
000
000
000000000000
P-
Time
1730
1845 1025 1430 1330 1430 1400
1600
1000
1200 1700 1530 1630
1000
Penta-chLoro- chLoro- m-cresoL phenoL
<30,000
<30,000<30,000<30,000<30,000<30,000<30,000
<30,000
<30,000
<30,000<30,000<30,000<30,000
<30,000
<30,000<30,000<30,000<30,000<30,000<30.000
<30,000
<30,000
<30,000<30,000<30,000<30,000
2-Chloro- phenoL
<5,000
<5,000 <5,000 <5,000 <5,000 <5,000 <5,000
<5,000
<5,000
<5,000 <5,000 <5,000 <5,000
<5,000
PhenoL
<5,000
<5,000<5,000<5,000<5,000<5,000<5,000
<5,000
<5,000
<5,000<5,000<5,000<5,000
2,4-Di- chLoro- phenoL
<5,000
<5,000 <5,000 <5,000 <5,000 <5,000 <5,000
<5,000
<5,000
<5,000 <5,000 <5,000 <5,000
<5,000
2,4.6- Tri-chLoro- phenol
<20,000
<20,000<20,000<20,000<20,000<20,000<20,000
<20,000
<20,000
<20,000<20,000<20,000<20,000
12510500 08-31-88 <5,000 <30,000 <20,000 <5,000 <30,000 <30,000 <30,000 <5,000 <20,000
53
Table 21. Concentrations of triazine, acetamlde, chloroacetanilide, and other pesticides in whole-water samples,Yakima River basin, Washington, 1988-89
[Concentrations in nanograms per liter; "<" - less than; see figure 1 for site locations]
Map reference number
33333
3
4
11
1313131313
1313
1414
22
2424242424
2424242424
24
2727272727
2727
28
3636363636
363636
37
3838383838
38
43
4646464646
46464646
47
49
50
5151515151
5151
Station number
1247830012478300124783001247830012478300
12478300
12479500
12484100
1248448012484480124844801248448012484480
1248448012484480
1248450012484500
12499000
1250043012500430125004301250043012500430
1250043012500430125004301250043012500430
12500430
1250044512500445125004451250044512500445
1250044512500445
12500450
1250546012505460125054601250546012505460
125054601250546012505460
12505510
1250750812507508125075081250750812507508
12507508
12508620
1250885012508850125088501250885012508850
12508850125088501250885012508850
12509050
12509710
12509829
1251050012510500125105001251050012510500
1251050012510500
Station name
Cle Elum R above Cle Elum Lake nr RoslynCle Elum R above Cle Elum Lake nr RoslynCle Elum R above Cle Elum Lake nr RoslynCle Elum R above Cle Elum Lake nr RoslynCle Elum R above Cle Elum Lake nr Roslyn
Cle Elum R above Cle Elum Lake nr Roslyn
Yakima River at Cle Elum
Wilson Creek abv. Cherry Creek at Thrall
Cherry Creek at ThrallCherry Creek at ThrallCherry Creek at ThrallCherry Creek at ThrallCherry Creek at Thrall
Cherry Creek at ThrallCherry Creek at Thrall
Yakima River at UmtanumYakima River at Umtanum
Naches River nr North Yakima
Moxee Drain at Thorp Rd n Un,ion GapMoxee Drain at Thorp Rd n Union GapMoxee Drain at Thorp Rd n Union GapMoxee Drain at Thorp Rd n Union GapMoxee Drain at Thorp Rd n Union Gap
Moxee Drain at Thorp Rd n Union GapMoxee Drain at Thorp Rd n Union GapMoxee Drain at Thorp Rd n Union GapMoxee Drain at Thorp Rd n Union GapMoxee Drain at Thorp Rd n Union Gap
Moxee Drain at Thorp Rd nr Union Gap
Wide Hollow Creek nea mouth at Union GapWide Hollow Creek nea mouth at Union GapWide Hollow Creek nea mouth at Union GapWide Hollow Creek nea mouth at Union GapWide Hollow Creek nea mouth at Union Gap
Wide Hollow Creek nea mouth at Union GapWide Hollow Creek nea mouth at Union Gap
Yakima R abv Ahtanum Cr at Union Gap
Granger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr Granger
Granger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr Granger
Marion Drain at Indian Church Rd at Granger
Toppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr Granger
Toppenish Cr at Indian Church Rd nr Granger
Satus Creek at gage at Satus
Sulphu Cr Wasteway nr SunnysideSulphu Cr Wasteway nr SunnysideSulphu Cr Wasteway nr SunnysideSulphu Cr Wasteway nr SunnysideSulphu Cr Wasteway nr Sunnyside
Sulphu Cr Wasteway nr SunnysideSulphu Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr Sunnyside
Yakima R at Euclid Br at RM 55 nr Grandview
Spring Creek at mouth at Whitstran
Snipes Creek at mouth at Whitstran
Yakima River at KionaYakima River at KionaYakima River at KionaYakima River at KionaYakima River at Kiona
Yakima River at KionaYakima River at Kiona
Date
05-05-8806-02-8807-26-8808-31-8811-16-88
03-09-89
07-26-88
07-26-88
05-05-8806-02-8806-02-8807-26-8808-31-88
11-18-8803-09-89
07-27-8806-28-89
07-26-88
05-06-8805-06-8806-01-8807-26-8807-27-88
07-28-8807-29-8808-30-8811-15-8803-10-89
06-28-89
05-05-8806-03-8807-27-8808-30-8811-15-88
11-15-8803-10-89
07-27-88
05-06-8806-01-8807-28-8807-28-8809-02-88
11-15-8803-09-8906-27-89
07-28-88
05-06-8806-03-8807-28-8809-01-8811-16-88
03-08-89
07-29-88
05-06-8806-03-8807-28-8807-28-8808-31-88
08-31-8811-17-8803-08-8906-26-89
07-28-88
07-29-88
07-29-88
05-07-8806-01-8807-29-8808-31-8811-17-88
03-08-8906-26-89
Time
11000930100010301030
1015
1500
1615
15301400140510301630
10001400
10451705
1330
09300940160011001310
16050800173010151200
1035
18450730102514301330
14301400
1600
12301300073009301000
164517301705
1145
13451000144509301615
1600
1145
16301300120017001530
1630090012002005
1010
1300
1500
08000900103010001400
09001435
Ala- chlor
<100<100<100<100<100
<100
<100
<100
<100<100<100<100<100
<100<100
<100<100
<100
<100<100<100<100<100
<100<100<100<100<100
<100
<100<100<100<100<100
<100<100
<100
<10030
<100<100<100
<100<100<100
<100
<100<100<100<100<100
<100
<100
<100<100<100<100<100
<100<100<100<100
<100
<100
<100
<100<100<100<100<100
<100<100
Ame- tryn
<100<100<100<100<100
<100
<100
<100
<100<100<100<100<100
<100<100
<100<100
<100
<100<100<100<100<100
<100<100<100<100<100
<100
<100<100<100<100<100
<100<100
<100
<100<100<100<100<100
<100<100<100
<100
<100<100<100<100<100
<100
<100
<100<100<100<100<100
<100<100<100<100
<100
<100
<100
<100<100<100<100<100
<100<100
Atra- zine
<100<100<100<100<100
<100
<100
59
7020607861
48600
16<100
<100
30301014
<100
179
16<100<100
10
<10040
<100<100<100
<10011
25
90904047
120
<10028090
120
5060544323
<100
52
6020253134
34<100
4422
48
<100
11
50304930
<100
<100<100
54
Table 21. Concentrations of triazine, acetamide, chloroacetanilide, and other pesticides in whole-water samples, Yakima River basin, Washington, 1988-89 Continued
Station number
12478300 12478300 12478300 12478300 12478300
12478300
12479500
12484100
12484480 12484480 12484480 12484480 12484480
12484480 12484480
12484500 12484500
12499000
12500430 12500430 12500430 12500430
12500430
12500430 12500430 12500430 12500430 12500430
12500430
12500445 12500445 12500445 12500445 12500445
12500445 12500445
12500450
12505460 12505460 12505460 12505460 12505460
12505460 12505460 12505460
12505510
12507508 12507508 12507508 12507508 12507508
12507508
12508620
12508850 12508850 12508850 12508850 12508850
12508850 12508850 12508850 12508850
12509050
12509710
12509829
12510500 12510500 12510500 12510500 12510500
12510500 12510500
Date
05-05-88 06-02-88 07-26-88 08-31-88 11-16-88
03-09-89
07-26-88
07-26-88
05-05-88 06-02-88 06-02-88 07-26-88 08-31-88
11-18-88 03-09-89
07-27-88 06-28-89
07-26-88
05-06-88 05-06-88 06-01-88 07-26-88
07-27-88
07-28-88 07-29-88 08-30-88 11-15-88 03-10-89
06-28-89
05-05-88 06-03-88 07-27-88 08-30-88 11-15-88
11-15-88 03-10-89
07-27-88
05-06-88 06-01-88 07-28-88 07-28-88 09-02-88
11-15-88 03-09-89 06-27-89
07-28-88
05-06-88 06-03-88 07-28-88 09-01-88 11-16-88
03-08-89
07-29-88
05-06-88 06-03-88 07-28-88 07-28-88 08-31-88
08-31-88 11-17-88 03-08-89 06-26-89
07-28-88
07-29-88
07-29-88
05-07-88 06-01-88 07-29-88 08-31-88 11-17-88
03-08-89 06-26-89
Brom- acil
<100 <100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 67
<100 <100
<100
<100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100
<100 200
<100 <100 <100
<100 <100
<100
<100 <100 <100 <100 <100
<100 110
<100
<100
<100 <100 <100 <100 <100
<100
<100
<100 <100 <100 <100 <100
<100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
Buta- chlor
<100 <100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
<100 <100
<100
<100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100 <100
<100
<100 <100 <100 <100 <100
<100 <100 <100
<100
<100 <100 <100 <100 <100
<100
<100
<100 <100 <100 <100 <100
<100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
Butyl- ate
<100 <100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
<100 <100
<100
<100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100 <100
<100
<100 <100 <100 <100 <100
<100 <100 <100
<100
<100 <100 <100 <100 <100
<100
<100
<100 <100 <100 <100 <100
<100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
Car- boxin
<100 <100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
<100 <100
<100
<100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100 <100
<100
<100 <100 <100 <100 <100
<100 <100 <100
<100
<100 <100 <100 <100 <100
<100
<100
<100 <100 <100 <100 <100
<100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
Cyan- azine
<100 <100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
<100 <100
67
<100 <100 <100 <100
<100
<100 <100 <100 <100
14
<100
30 <100 <100 <100 <100
<100 15
<100
<100 60
<100 <100 <100
<100 <100 <100
145
<100 <100 <100 <100 <100
<100
121
<100 <100 <100 <100 <100
<100 <100
12 <100
<100
100
<100
<100 <100
72 <100 <100
<100 <100
Cyclo- ate
<100 <100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
<100 <100
<100
<100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100 <100
<100
<100 <100 <100 <100 <100
<100 <100 <100
<100
<100 <100 <100 <100 <100
<100
<100
<100 <100 <100 <100 <100
<100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
Diphen- amid
<100 <100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
<100 <100
<100
<100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100 <100
<100
<100 <100 <100 <100 <100
<100 <100 <100
<100
<100 <100 <100 <100 <100
<100
<100
<100 <100 <100 <100 <100
<100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
Hexazi- none
<100 <100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 15
<100 <100
<100
<100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100 <100
<100
<100 30
<100 <100 <100
<100 90
<100
<100
<100 <100 <100 <100 <100
<100
<100
<100 <100 <100 <100 <100
<100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
Metola- chlor
<100 <100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
<100 <100
<100
<100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100 <100
<100
<100 <100 <100 <100 <100
<100 <100 <100
<100
<100 <100 <100 <100 <100
<100
<100
<100 <100 <100 <100 <100
<100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
Metri- buzin
<100 <100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
<100 <100
<100
<100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100 <100
<100
<100 <100 <100 <100 <100
<100 <100 <100
<100
<100 <100 <100 <100 <100
<100
<100
<100 <100 <100 <100 <100
<100 <100 <100 <100
42
<100
<100
<100 <100 <100 <100 <100
<100 <100
55
Table 21. Concentrations of triazine, acetamide, chloroacetanilide, and other pesticides in whole-water samples, Yakime River basin, Washington, 1988-89 Continued
Station number
12478300 12478300 12478300 12478300 12478300
12478300
12479500
12484100
12484480 12484480 12484480 12484480 12484480
12484480 12484480
12484500 12484500 12499000
12500430 12500430 12500430 12500430 12500430
12500430 12500430 12500430 12500430 12500430
12500430
12500445 12500445 12500445 12500445 12500445
12500445 12500445
12500450
12505460 12505460 12505460 12505460 12505460
12505460 12505460 12505460
12505510
12507508 12507508 12507508 12507508 12507508
12507508
12508620
12508850 12508850 12508850 12508850 12508850
12508850 12508850 12508850 12508850
12509050
12509710
12509829
12510500 12510500 12510500 12510500 12510500
12510500 12510500
Date
05-05-88 06-02-88 07-26-88 08-31-88 11-16-88
03-09-89
07-26-88
07-26-88
05-05-88 06-02-88 06-02-88 07-26-88 08-31-88
11-18-88 03-09-89
07-27-88 06-28-89 07-26-88
05-06-68 05-06-88 06-01-88 07-26-88 07-27-88
07-28-88 07-29-88 08-30-88 11-15-88 03-10-89
06-28-89
05-05-88 06-03-88 07-27-88 08-30-88 11-15-88
11-15-88 03-10-89
07-27-88
05-06-88 06-01-88 07-28-88 07-28-88 09-02-88
11-15-88 03-09-89 06-27-89
07-28-88
05-06-88 06-03-88 07-28-88 09-01-88 11-16-88
03-08-89
07-29-88
05-06-88 06-03-88 07-28-88 07-28-88 08-31-88
08-31-88 11-17-88 03-08-89 06-26-89
07-28-88
07-29-88
07-29-88
05-07-88 06-01-88 07-29-88 08-31-88 11-17-88
03-08-89 06-26-89
Prome- ton
<100 <100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
<100 <100 <100
<100 <100
30 <100 <100
<100 <100 <100 <100 <100
<100
<100 210 64 58
<100
<100 20
<100
<100 70
<100 <100 <100
<100 <100
50
<100
<100 <100 <100 <100 <100
<100
<100
<100 <100 <100 <100 <100
<100 <100
44 <100
<100
<100
<100
<100 50
<100 <100 <100
<100 <100
Prome- tryn
<100 <100 <100 <100 <100
<100
<100
<100
100 <100 <100 <100 <100
<100 <100
<100 <100 <100
<100 <100 <100 <100 <100
<100 <100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100 <100
<100
A A A A A »- »- -»»- *- o o o o o 00000
<100 <100 <100
<100
<100 <100 <100 <100 <100
<100
<100
<100 <100 <100 <100 <100
<100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
Propa- chlor
<100 <100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
<100 <100 <100
<100 <100 <100 <100 <100
<100 <100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100 <100
<100
<100 <100 <100 <100 <100
<100 <100 <100
<100
<100 <100 <100 <100 <100
<100
<100
<100 <100 <100 <100 <100
<100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
Pro- pazine
<100 <100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
<100 <100 <100
<100 <100 <100 <100 <100
<100 <100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100 <100
<100
<100 <100 <100 <100 <100
<100 <100 <100
<100
<100 <100 <100 <100 <100
<100
<100
<100 <100 <100 <100 <100
<100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
Sitna- zine
<100 <100 <100 <100 <100
<100
<100
41
90 <100
40 220 23
<100 6,600
57 <100
27
20 20 10 15 19
24 <100 <100 <100
18
<100
26 40 33 22
<100
<100 43
38
80 460 91
100 24
<100 100 170
40
<100 40 45 16
<100
11
29
120 60 74 68 29
24 <100
34 77
56
<100
22
40 20 49 17
<100
28
Sime- tryn
<100 <100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
<100 <100 <100
<100 <100 <100 <100 <100
<100 <100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100 <100
<100
<100 <100 <100 <100 <100
<100 <100 <100
<100
<100 <100 <100 <100 <100
<100
<100
<100 <100 <100 <100 <100
<100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
Ter- bacil
<100 <100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
<100 <100 <100
<100 <100 <100 <100 <100
<100 <100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100 <100
<100
<100 <100 <100 <100 <100
<100 <100 <100
<100
<100 <100 <100 <100 <100
<100
<100
<100 <100 <100 <100 <100
<100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
Tri- flura- lin
<100 <100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
<100 <100 <100
<100 <100 <100 <100 <100
<100 19
<100 <100 <100
<100
<100 <100 <100 <100 <100
<100 <100
<100
<100 70 55 42
<100
<100 <100 100
<100
<100 <100 <100 <100 <100
<100
<100
<100 <100 <100 <100 <100
<100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
Ver- nolete
<100 <100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
<100 <100 <100
<100 <100 <100 <100 <100
<100 <100 <100 <100 <100
<100
<100 <100 <100 <100 <100
<100 <100
<100
<100 <100 <100 <100 <100
<100 <100 <100
<100
<100 <100 <100 <100 <100
<100
<100
<100 <100 <100 <100 <100
<100 <100 <100 <100
<100
<100
<100
<100 <100 <100 <100 <100
<100 <100
56
Tabl
e 22.
Conc
entr
atio
ns of triazine,
acet
amid
e, chloroacetanilide, an
d tr
iflu
rome
thyl
comp
ound
s in fiItered-water sa
mple
s,Yakima Ri
ver
basin, Washington,
June
25-30, 19
89
[Con
cent
rati
ons
in n
anog
rams
pe
r liter; "T"
= present, but
below
quan
tifi
able
con
cent
rati
on;
"D"
= de
tect
ed a
nd n
ot qu
anti
fied
; "nd" =
not
dete
cted
and mi
nimu
m reporting
level
not
quan
tifi
ed;
"<"
= less than;
amet
ryn,
propachlor,
simetryn w
ere
not
dete
cted
; de
isop
ropy
latr
azin
e wa
s de
tect
ed a
nd
not
quantified a
t Gr
ange
r Dr
ain
and
Yakima R
iver
at
Ki
ona;
trace
concentrati9ns o
f prometryn
were d
etec
ted
at Sa
tus
Cree
k at
Satus, Sub
35 Dr
ain,
an
d Ma
rion
Drain;
trac
e co
ncen
trat
ions
of
metribuzin w
ere detected a
t Toppenish
and
Sulp
hur
Cree
ks,
and
in th
ree
addi
tion
al replicate
samp
les
coll
ecte
d fr
om Y
akima
Rive
r at
Ki
ona;
for
qual
ity
assu
ranc
e, th
ree
addi
tion
al replicate
samp
les
from
Yakima
cyan
azin
e, and
concentrations were 2
.4,
3.7, an
d 3.7
ng/L
; see
figure
1 for
site locations]
Map
reference
number 2 4 11 13 14 15 19 20 22 24 27 28 30 33 34 36 55 37 38 40 41 53 43 45 46 47 49 50 51
Statio
n number
12478200
1247
9500
1248
4100
12484480
12484500
12484550
12496510
12496511
1249
9000
12500430
12500445
12500450
12502500
12505350
12505410
1250
5460
4625
ID-
120323901
1250
5510
12507508
12507585
1250
7594
461720-
1200
43201
12508620
12508630
1250
8850
1250
9050
12509710
1250
9829
12510500
Stat
ion
name
Cooper Ri
ver
at Salmon L
aSac
Yakima Ri
ver
at Cl
e El ur
nWilson C
r ab
v. Ch
erry
Cre
ekCherry C
reek a
t Th
rall
Yakima Ri
ver
at Umtanum
Umta
num
Creek
nr m
outh
Pacific
Powe
r &
Ligh
t Company
Wasteway
City o
f Ya
kima
- Fi
nish
Wat
erNacnes R
iver nr
North
Yakima
Moxee Drain
at Thorp
Rd
Wide H
ollow
Cree
k ne
ar m
outh
Yakima R
abv Ahtanum
CrAhtanum
Creek
at Un
ion
Gap
E To
ppen
ish
Drain
at Wilson R
dSub
35 D
rain
at
Parton R
oad
Gran
ger
Drai
n at mouth
Well
2, Ha
rrah
. 11
N/18
E-22
R02
Mari
on D
rain
, In
dian
Chu
rch
RdToppenish
Cr,
Indi
an C
hurc
h Rd
Yakima Ri
ver
at RM
72
Satu
s Cr
abv
Wils
on- Ch
ar ley
Canyon n
r Toppenish
Alachlor
<0.99
<.52
<2.
1<1 .2
<1.6 <-42
<.50
<.64
<.39
<4.0
<2.0
<1 .5
<1 3
4.5
98 33 T<.6
420 16 11 <.
40
Well
1,
Sunnyside, 09N/22E-04P01
<.64
Satu
s Cr
at gage a
t Sa
tus
Sout
h Drain
nr Sa
tus
Sulp
hur
Cree
k Wasteway
Yakima R
at Euclid B
r at
RM
55
Spring C
reek
at
mouth
Snipes C
reek
at
mout
hYakima R
iver
at Kiona
13 17 33 19 <2.0
T<2.0
12
Atra
zine
T<1.
4 .27
27 71 10 <.77
<.17
<.88 .26
8.5
6.8
5.6
T<1.8
130 88 48 57 34 54 26 T<.56
18 46 130 49 61 13 12 32
Deet
hyl-
at
razi
ne
nd nd D 4.0
D nd nd nd nd D D D D D D D D D D 1.6
nd D D D D D D D D
Butachlor
<1 4
T<!81
<3.0
<2'.
5
<.89
<.79
<.93
<.69
<7.1
<2.8
T<2.
4<2
.3<2.9
T<2.8
<6.4 <.93
<2.8
<2.2
<1.1 <.71
<.92
<2.9
<7.2
<24 <2.3
<2.9
<2.8
<2.5
Cyanazine
<1 9
<!S5
<4.0
<1 .9
<1.7 <.94
<.54
<1 2
<.36
<3.7
<3.8
<1 2
<3.8
<3.8 8.6
<1 2
<3i8
<1 .
1<1.8 <.37
<1 2
<3.8
<3.7
T<31 T<1.
2<3
.9<3.8
<6.5
Metola-
chlo
r
<0.9
1<.
42<1
.9
< 7
T<1.
3
<.25
<.41
<.59
T<.30
<3.1
<1 8
T<K2
<1 .0
<1 .8
<1.8
T<2.
8
<.59
3.6
2.2 .93
<.31
<.59
4.1
6.0
T<15
1.3
<1 .8
T<1.
81.
9
Rive
r at
Prom
eton
<1 2
<!27
7.8
1.4
1.1
<.58
<.26
< 81
T<.2
63.8
22 1.4
3.0
T<2.
5T<
2.5
32 T<.8
1T<
2.5
2.7
2.4
<-27
<-80
<2.5
T<2.
726 5.
2<2
.5T<
2.5
3.0
Kion
a were
Propazine
<1.1 < 12
<2.3 < 8
T<,3
9
<.56
<.12
<.72
<.35
<3.6
<2.2 <.37
<1
1<2
.2<2
.2
<3.2 <.72
<2.2
T<1
.1<.78
<-36
< 71
<2.2
T<3.6
<18 <1 2
<2.2
<2.2 .4
7
anal
yzed
Simazine
<1 4 !25
4.2
11 2.2
<.67
<.19
<.88 .24
<3.6 7.1
3.9
6.7
14 17 130 6.4
21 43 16 <.36
1.9
27 <3.6
81 33 10 6.4
18
for Tr
iflu
r-
alin <2.0
<1 .2
<4
1T<
3.0
T<3.
8
<1.3
<1 .2
<1 .3
<1 3
T<14 <3
.9T<3.6
<4.4
T<4.
0T<3.9
28 <1 3
7^1
T<4.
23.1
<1.4
<1 3
7.3
T<14
T<32 T<4.
5T<
4.0
T<3.9
T<3.8
Table 23. Concentrations of volatile organic compounds (halogenated aliphatic and monocyclic aromatic hydrocarbons) inwhole-water samples, Yakima River basin, Washington, 1988-89
[Concentrations in nanograms per liter; " " = not analyzed; "<" = less than; see figure 1 for site locations]
Map reference number Station number
19 12496510
20 12496511
24 12500430
27 12500445 27 12500445 27 12500445 27 12500445
36 12505460
46 12508850
51 12510500
Station name
Pacific Power & Light Company Wasteway
City of Yakima-Finish Water
Moxee Drain at Thorp Rd nr Union Gap
Wide Hollow Creek near mouth at Union Gap Wide Hollow Creek near mouth at Union Gap Wide Hollow Creek near mouth at Union Gap Wide Hollow Creek near mouth at Union Gap
Granger Drain at mouth nr Granger
Sulphur Cr Wasteway nr Sunnyside Sulphur Cr Wasteway nr Sunnyside
Yakima River at Kiona
Date
07-01-89
07-01-89
08-30-88
08-30-88 11-15-88 11-15-88 03-10-89
09-02-88
08-31-88 08-31-88
08-31-88
Time
1400
1405
1730
1430 1330 1430 1400
1000
1530 1630
1000
Benzene
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
<200
Bromo- benzene
<200
<200 <200 <200 <200
<200
<200 <200
<200
Station number
12496510
12496511
12500430
12500445 12500445 12500445 12500445
12505460
12508850 12508850
12510500
Date
07-01-89
07-01-89
08-30-88
08-30-88 11-15-88 11-15-88 03-10-89
09-02-88
08-31-88 08-31-88
08-31-88
Broroodi- chloro- methane
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
<200
Bromo- form
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
<200
Bromo- methane
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
<200
Carbon tetra- chlo- ride
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
<200
Chloro- benzene
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
<200
Chloro- ethane
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
<200
2- Chloro- ethyl- vinyl ether
<3,000
<3,000
Chloro form
<3,000
22,000
<200
<200 <200 <200 <200
<200
<200 <200
<200
Chloro- me thane
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
<200
Station number
12496510
12496511
12500430
12500445 12500445 12500445 12500445
12505460
12508850 12508850
Date
07-01-89
07-01-89
08-30-88
08-30-88 11-15-88 11-15-88 03-10-89
09-02-88
08-31-88 08-31-88
1,2- Chloro- toluene
~
<200
<200 <200 <200 <200
<200
<200 <200
1,4- Chloro- toluene
~
<200
<200 <200 <200 <200
<200
<200 <200
cis- 1,3-Di- chloro- propene
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
Dibromo- chloro- me thane
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
1,2- Dibromo- ethane
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
Dibromo- me thane
<200
<200 <200 <200 <200
<200
<200 <200
1,2-Di- chloro- benzene
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
1,3-Di- chloro- benzene
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
1,4-Di- chloro- benzene
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
12510500 08-31-88 <200 <200 <200 <200 <200 <200 <200 <200 <200
58
Table 23. Concentrations of volatile organic compounds (halogenated aliphatic and monocyclic aromatic hydrocarbons) in whole-water samples, Yakima River basin, Washington, 1988-89 Continued
Station number
12496510
12496511
12500430
12500445 12500445 12500445 12500445
12505460
12508850 12508850
12510500
Station number
12496510
12496511
12500430
12500445 12500445 12500445 12500445
12505460
12508850 12508850
12510500
Station number
12496510
12496511
12500430
12500445 12500445 12500445 12500445
12505460
12508850 12508850
Date
07-01-89
07-01-89
08-30-88
08-30-88 11-15-88 11-15-88 03-10-89
09-02-88
08-31-88 08-31-88
08-31-88
Date
07-01-89
07-01-89
08-30-88
08-30-88 11-15-88 11-15-88 03-10-89
09-02-88
08-31-88 08-31-88
08-31-88
Date
07-01-89
07-01-89
08-30-88
08-30-88 11-15-88 11-15-88 03-10-89
09-02-88
08-31-88 08-31-88
Dichloro- difluoro- methane
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
<200
1,3-Di- chloro- propene
<3,000
<3,000
trans- 1,3-Di- chloro- propene
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
1,1-Di- chloro- e thane
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
<200
Ethyl- I benzene
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
<200
1,2,4- Tri- chloro- benzene
<5,000
__
1,2-Di- chloro- ethane
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
<200
tethylene chloride
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
<200
1,1,1- Tri- chloro- ethane
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
1,1-Di- chloro- ethene
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
<200
Styrene
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
<200
1,1,2- Tri- chloro- e thane
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
1,2-Di- chloro- ethene
<200
<200 <200 <200 <200
<200
<200 <200
<200
1,1,1,2-Tetra- chloro- ethane
<200
<200 <200 <200 <200
<200
<200 <200
<200
Tri- chloro- ethene
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
1,2-Di- chloro- propane
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
<200
- 1,1,2,2-Tetra- chloro- e thane
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
<200
Tri- chloro- fluoro- me thane
<3,000
<3,000
<200
<200 <200 <200 <200
<200
900 <200
1,3-Di- chloro- propane
<200
<200 <200 <200 <200
<200
<200 <200
<200
Tetra- chloro- ethene
<3,000
<3,000
<200
200 300 300 200
<200
<200 <200
<200
1,2,3- Tri- chloro- propane
<200
<200 <200 <200 <200
<200
<200 <200
2,2-Di- chloro- propane
<200
<200 <200 <200 <200
<200
<200 <200
<200
Toluene
<3,000
<3,000
<200
<200 <200 <200 <200
<200
<200 <200
<200
Vinyl chloride
<1,000
<1,000
<200
<200 <200 <200 <200
<200
<200 <200
1,1-Di- chloro- propene
<200
<200 <200 <200 <200
<200
<200 <200
<200
1,2-Di- chloro- ethene
<3,000
<3,000
--
Xylene
<3,000
<3,000
<200
A A A A MMM M OO O O OO O O
<200
<200 <200
12510500 08-31-88 <200 <200 <200 <200 <200 <200 <200 <200
59
Table 24. Concentrations of organochlorine compounds, total carbon, and inorganic carbon in bed-sediment and soil ssimples,Yakima River basin, Washington, 1987-90
[gm = gram; kg = kilogram; /on = microgram; "n" = soil sample was not sieved; "--" -= not analyzed; "#" * <62 micrometer data collected during trace element study on a different sample and day; "@" site receives drainage from apple orchard(s); "<" = less than; DDD = dichlorodiphenyldichloroethane; DDE = dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyl- trichloroethane; PCB = gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes; C = Carbon; see figure 1 for site locations]
Map reference number Station number Station name Date Time
Parti cle size finer than, micro meters
Carbon, inor ganic + organic (gm/kg as C)
Carbon, inor ganic , (gm/kg Aldrin as C) (pg/kg)
Bed sediment
35678
910131314
1516171824
2425272728
2931313636
3838424446
4646465151
5252
5454
62
6363
5656
5757
1247830012479720124797501248000012481900
1248319012483750124844801248448012484500
1248455012487200124882501248910012500430
1250043012500437125004451250044512500450
1250090012503640125036401250546012505460
1250750812507508125085001250862512508850
1250885012508850125088501251050012510500
6165211952200061652119522000
6174411952240061744119522400
63359120281400
6350112035330063501120353300
463202120223600463202120223600
463232120234900463232120234900
Cle Elum R above Cle Elum Lake nr RoslynJungle Creek nr mouth nr Cle ElumNo Fk Teanaway R blw bridge at Dickey Cr CampgrndTeanaway River below forks near Cle ElumTaneum Cr at Taneum Meadow nr Thorp
South Fork Manastash Cr nr EllensburgNaneum Cr blw High Cr nr EllensburgCherry Creek at ThrallCherry Creek at ThrallYakima River at Umtanum
Umtanum Creek nr mouth at UmtanumLittle Naches River at mouth nr CliffdellAmerican River at Hells Crossing nr NileRattlesnake Cr abv N.F. Rattlesnake Cr nr NileMoxee Drain at Thorp Rd nr Union Gap
Moxee Drain at Thorp Rd nr Union GapWide Hollow Cr at W. Valley School nr AhtanumWide Hollow Creek near mouth at Union GapWide Hollow Creek near mouth at Union GapYakima R abv Ahtanum Cr at Union Gap
S. F. Ahtanum Cr abv Conrad Rnch nr Tampico@ Unnamed drain at Lateral & Riggs Rds nr WapatoUnnamed drain at Lateral & Riggs Rds nr WapatoGranger Drain at mouth nr GrangerGranger Drain at mouth nr Granger
Toppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerSatus Cr below Dry Cr near ToppenishYakima R blw Satus Cr at RM 68 nr SatusSulphur Cr Wasteway nr Sunnyside
Sulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideYakima River at KionaYakima River at Kiona
@ Unnamed drain at County Line Rd nr GrandviewUnnamed drain at County Line Rd nr Grandview
g Unnamed drain to E Turbine Lateral nr GrandviewUnnamed drain to E Turbine Lateral nr Grandview
Unnamed urban runoff at Union Gap
@ Wide Hollow Cr at Ahtanum Blvd nr AhtanumWide Hollow Cr at Ahtanum Blvd nr Ahtanum
Apple composite from 5 ditchesAsparagus composite from 5 ditchesCorn- -composite from 5 ditchesGrape composite from 4 ditchesHops composite from 5 ditches
Pear composite from 4 ditchesPotato composite from 5 ditches
Apple orchard nr Moxee City, A Horizon, 0-6 in.Apple orchard nr Moxee City, B Horizon, 6-9 in.
Hop field near Moxee City, A Horizon, 0-9 in.Hop field near Moxee City, B Horizon, 9-12 in.
08-31-8805-02-8911-03-9011-06-8911-03-90
11-02-9011-02-9008-31-8808-31-8805-04-89
05-03-8910-30-9011-07-8911-07-8908-30-88
08-30-8805-01-8908-30-8808-30-8809-16-87
11-06-9009-01-8809-01-8809-02-8809-02-88
09-01-8809-01-8811-07-9009-15-8708-31-88
08-31-8808-31-8808-31-8808-31-8808-31-88
09-01-8809-01-88
09-01-8809-01-88
08-28-87
09-01-8809-01-88
08-27-8709-16-8708-27-8711-30-8709-16-87
11-30-8709-18-87
07-01-8907-01-89
07-01-8907-01-89
10301230141509100815
08151330163016351100
09450905120012001730
17351430143014351631
08100800080510001005
09300935092012011530
15351630163510001005
11001105
09000905
1001
10001005
22451600211512001630
13001015
10001005
09000905
2,0002,000
622,000
62
6262
2,00062
2,000
2,00062
2,0002,0002,000
622,0002,000
62180
622,000
622,000
62
2,0006262
1802,000
622,000
622,000
62
2,00062
2,00062
180
2,00062
180180180180180
180180
nn
nn
2.24--
2.6 #4.7 #
3.0 #9.2 #
101016
104.1 #3.8 #3.3 #
12
112427292.1 #
5.2 #9.99.14.98.6
17271.2 #1.6 #9.5
9.35.162.4
18
4.914
1834
-
2222
---- --
--
145.2
166.2
0.4.1--
<.l #<.l #
<.l #<.l #.3.4
<.l
.1<.l #<-l #<-l #.1
.2<.l<.l.1
<.l # <
<.l #1.21.4.8
1.3
<.l<.l<.l #<.l # <1
1.1.8
1.5.1
<.l
< .1.1
<.l<.l
- <
.1
.1
<-- <
<<<
<.l<.l
<.l<.l
<0.1<. 1<. 5<. 1< - 5
<.5<. 5<. 1<. 1< - 1
<.l<. 5<. 1<. 1< - 1
<.l<. 1<. 1.4
10
<.5.4.2
<. 1< - 1
<.l<. 1<.5
10< - 1
<.l<. 1<. 1<. 1< - 1
<.l< - 1
<.l< - 1
10
<.l< - 1
10:10'10:1010
1010
<.l< - 1
<.l<.l
60 463247120222300 Hop field nr Moxee City, A Horizon, 1-10 in. 07-01-89 1100 14
60
Table 24. Concentrations of organochlorine compounds, total carbon, and inorganic carbon in bed-sediment and soil samples, Yakima River basin, Washington, 1987-90 Continued
Station number
Gross chlor- Di- P.P'~ dane eldrin ODD
Date (Mg/kg) (Mg/kg) (Mg/kg)
Hepta- p,p'- P,P'~ Endo- Hepta- chlor DDE DOT sulfan I Endrin chlor epoxide (Mg/kg) (Mg/kg) (Mg/kg) (w/kg) (pg/kg) (Mg/kg)
Bed sediment
1247830012479720124797501248000012481900
1248319012483750124844801248448012484500
1248455012487200124882501248910012500430
1250043012500437125004451250044512500450
1250090012503640125036401250546012505460
1250750812507508125085001250862512508850
1250885012508850125088501251050012510500
461652119522000461652119522000
461744119522400461744119522400
463359120281400
463501120353300463501120353300
Apple composite from 5 ditches
08-31-8805-02-8911-03-9011-06-8911-03-90
11-02-9011-02-9008-31-8808-31-8805-04-89
05-03-8910-30-9011-07-8911-07-8908-30-88
08-30-8805-01-8908-30-8808-30-8809-16-87
11-06-9009-01-8809-01-8809-02-8809-02-88
09-01-8809-01-8811-07-9009-15-8708-31-88
08-31-8808-31-8808-31-8808-31-8808-31-88
09-01-8809-01-88
09-01-8809-01-88
08-28-87
09-01-8809-01-88
08-27-87
<!<1<5<1<5
<5<59
10<1
<!<5<1<1<1
3<10<115
<10
<5<1<1<1<1
1<1<5
<10<1
<!44
<15
<!<1
<!<1
<10
<!<1
<10
<0.1.1.5.1.5
.5
.535391
<.l<.5<.l<.l1.7
1.213.23
<10
<.534471.83.5
.5
.5<.5
<105.6
53.44.4.2
1.3
1531
13.6
<10
2413
<10
<0.1<_ i!i<. i.1.2.2
9.3131
< !\Z.1
<, 123
183828<. 1
<10
.743512316
2.89.5.1
<1013
26101512.7
4880
4.529
<10
48440
130
<0.1<.l.3
<.l.3
.4
.530283
.4
.2
.1
.191
651604416
<10
.54701804760
1623
.815<.l
7433423
10
220160
.94.4
<10
17001400
480
<0.1<.l.1
<.l<.5
<.5.1
15281
<.l.1
<.l<.l15
8.5118.9<.l
<10
.229
160277.6
<.l2.6<.5
<10.8
1389.9.3
<.l
6614
6.110
<10
370180
72
<0
11
7<
213
<10
<<92*
<2<
<10*
711<<
6167
1968
<10
<71
17
11515
55111
1511
41
3
51251
165
1
99911
1
<0.1<.l<.5<.l<.5
<.5<.5.2.2
<.l
<.l<.5<.l<.l.4
.1
.5
.6<.l
<10
<.5<.l<.l<.l<.l
<.l<.l<.5
<10<.l
<.l<.l<.l<.l<.l
.1<.l
5.317
<10
<.l3.5
<10
<0.1<.l.1
<.l.1
.1
.1<.l<.l<.l
<.l.1
<.l<.l<.l
<.l<.l<.l<.l
<10
.1<.l<.l<.l<.l<.l<.l<.5
<10<.l
<.l<.l<.l<.l<.l
<.l<.l
<.l<.l
<10
<.l<.l
<10
<0.1<_ 1<.5<. i<-5
< 5<,5!i.2
< !
<.!<.5<. i<. i.2
.1<. 1<. 1<. 1
<10
<.5i!a2.5<. 1< - 1
<.l<. 1<.5
<10< - 1
<.l<. 1.1
<. 1< - 1
.1< - 1
<.l< - 1
<10
<.l< - 1
<10Asparagus composite from 5 ditches 09-16-87 <10Corn composite from 5 ditches 08-27-87 33Grape composite from 4 ditches 11-30-87 <10Hops composite from 5 ditches 09-16-87 <10
Pear composite from 4 ditches 11-30-87 <10Potato composite from 5 ditches 09-18-87 <10
463202120223600 07-01-89 <1463202120223600 07-01-89 <1
463232120234900 07-01-89 4463232120234900 07-01-89 1
463247120222300 07-01-89 2
38
.1
11
8918
563.5
171.4
25
70
18064
68045
16029
140
65058
14022
310 :.l
:.l :.l
:.l
61
Table 24. Concentrations of organochlorine compounds, total carbon, and inorganic carbon in bed-sediment and soil samples, Yakima River basin, Washington, 1987-90--Continued
Station number Date
p.p'-Meth-oxy- Per- Toxa-
Lindane chlor Mirex PCB PCN thane phene (Mg/kg) (/xg/kg) (fig/kg) (/ig/kg) (/ig/kg) (fig/kg)
12478300 12479720 12479750 12480000 12481900
12483190 12483750 1248448012484480 12484500
12484550 12487200 12488250 12489100 12500430
12500437 12500445 12500445 12500450 12500900
12503640 12503640 12505460 12505460 12507508
12507508 12508500 12508625 12508850 12508850
12508850 12508850 12510500 12510500
461652119522000 461652119522000
461744119522400 461744119522400
463359120281400
463501120353300 463501120353300
Apple composite from 5 ditches Asparagus composite from 5 ditches Corn composite from 5 ditches Grape composite from 4 ditches Hops- -composite from 5 ditches
Pear composite from 4 ditches Potato composite from 5 ditches
463202120223600 463202120223600
463232120234900 463232120234900
Bed sediment
08-31-88 <0.1 <0.1 <0 . 1 05-02-89 <.l <.l <.l 11-03-90 <.5 <.5 <.5 11-06-89 <.l <.l <.l 11-03-90 <.5 <.5 <.5
11-02-90 <.5 <.5 <.5 11-02-90 <.5 <.5 <.5 08-31-88 <.l <.l <.l
05-04-89 <.l <.l <.l
05-03-89 <.l <.l <.l 10-30-90 <.5 <.5 <.5 11-07-89 <.l <1 <.l 11-07-89 <.l <.l <.l 08-30-88 <.l <.l <.l
08-30-88 <.l <.l <.l 05-01-89 <.l <.l <.l 08-30-88 <.l <.l <.l 08-30-88 <.l .6 <.l 09-16-87 <10 <10 <10 11-06-90 <.5 <.5 <.5
09-01-88 <.l <.l <.l 09-01-88 <.l 2.1 <.l 09-02-88 <.l <.l <.l 09-02-88 <.l .8 <.l 09-01-88 <.l <.l <.l
09-01-88 <.l <.l <.l 11-07-90 <.5 <.5 <.5 09-15-87 <10 <10 <10 08-31-88 <.l <.l <.l 08-31-88 <.l <.l <.l
08-31-88 <.l <.l <.l 08-31-88 <.l <.l <.l 08-31-88 <.l <.l <.l 08-31-88 <.l <.l <.l
09-01-88 <.l <.l <. 09-01-88 <.l 3.2 <.
09-01-88 .3 <.l <. 09-01-88 .8 <.l <.
08-27-87 <10 <10 <10
09-01-88 <.l <.l <. 09-01-88 <.l <.l <.
08-27-87 <10 <10 <10 09-16-87 <10 <10 <10 08-27-87 <10 <10 <10 11-30-87 <10 <10 <10 09-16-87 <10 <10 <10
11-30-87 <10 <10 <10 09-18-87 <10 <10 <10
07-01-89 <.l <.l <. 07-01-89 <.l <.l <.
07-01-89 <.l <.l <. 07-01-89 <.l <.l <.
i <5 <5
' <5 <5
<5 <5 <5 <5
<1 <1
<5 <5
<700 <100 <5 <5
1 1
<5 <5<700 <100
a ai a ai a a
<700
i a a<700 <100 <700 <100 <700 <100 <700 <100 <700 <100
<700 <100 <700 <100
i a <J} :} a
<5 <50
<5 <50
<5 <50 <5 <50
3 <io
<5 <50
<1 < 10
2 < 10
<10 <500 <5 <50
3 a?
<5 <50<10 <500
<1 <10
<} <iSa a?
<10 <500
3 a?
<10 <500 <10 <500 <10 <500 <10 <500 <10 <500
<10 <500 <10 <500
3 a?
a <io463247120222300 07-01-89 <1 <1 <1
62
Table 25. Concentrations of organophosphorus pesticides in soil samples, Yakima River basin, Washington, 1989
[Concentrations in micrograms per kilogram; "<" * less than; see figure 1 for site locations]
Map refer ence
Methyl Methyl Diaz- Mala- para- tri- Para- Tri-
number Station number
56 463202120223600
57 463232120234900
60 463247120222300
Stetion name
Apple orchard nr Moxee City, A Horizon, 0-6 inches
Apple orchard nr Moxee City, B Horizon, 6-9 inches
Hop field near Moxee City, A Horizon, 0-9 inches
Hop field near Moxee City, B Horizon, 9-12 inches
Hop field nr Moxee City A Horizon, 1-10 inches
Date
07-01-89
07-01-89
07-01-89
07-01-89
07-01-89
Time inon
1000 1.5
1005 .2
0900 4.1
0905 .2
1100 530
Ethion thion thion
<0.1 <0.1 <0.1
<.l <.l <.l
<.l <.l <.l
<.l <.l <.l
.1 <.l <.l
thion thion thion
<0. 1 2.0 <0. 1
<.l .3 <.l
<.l .4 <.l
<.l <.l <.l
<.l .6 <.l
Table 26. Concentrations of semi-volatile organic compounds (phthalate esters, ethers, phenols, cresols, and monocyclic- and polycyclic-aromatic compounds) in bed-sediment samples, Yakima River basin, Washington, 1987-90
[Concentrations in micrograms per kilogram; "E" « estimated value; "<" = less than; see figure 1 for site locations; the typical minimum reporting level for these compounds is 200, 400, or 600 micrograms per kiliogram however, the analyst is able to quantify smaller concentrations when the background analytical noise is small]
Mapreferencenumber
1357
13
1314141517
1824242527
2728313136
3638384446
4646464951
5151525254
54626363
Particle size finer than,
Station number
1247810012478300124797201248000012484480
1248448012484500124845001248455012488250
1248910012500430125004301250043712500445
1250044512500450125036401250364012505460
1250546012507508125075081250862512508850
1250885012508850125088501250971012510500
1251050012510500
461652119522000461652119522000461744119522400
461744119522400463359120281400463501120353300463501120353300
Station name
Waptus River at mouth nr RoslynCle Elum R above Cle Elum Lake nr RoslynJungle Creek nr mouth nr Cle ElumTeaneway River below forks near Cle ElumCherry Creek et Thrall
Cherry Creek at ThrallYakima River at UmtanumYakima River at UmtanumUmtanum Creek nr mouth at UmtanumAmerican River at Hells Crossing nr Nile
Rattlesnake Cr abv N.F. Rattlesnake Cr nr NileMoxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union GapWide Hollow Cr at W. Valley School nr AhtanumWide Hollow Creek near mouth at Union Gap
Wide Hollow Creek near mouth at Union GapYakima R abv Ahtanum Cr at Union GapUnnamed drain at Lateral & Riggs Rds nr WapatoUnnamed drain at Lateral & Riggs Rds nr WapatoGranger Drain at mouth nr Granger
Granger Drain at mouth nr GrangerToppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerYakima R blw Satus Cr at RM 68 nr SatusSulphur Cr Wasteway nr Sunny side
Sulphur Cr Wasteway nr SunnyaideSulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideSpring Creek at mouth at WhitstranYakima River at Kiona
Yakima River et KionaYakima River at KionaUnnamed drain et County Line Rd nr GrandviewUnnamed drain at County Line Rd nr GrandviewUnnamed drain to E Turbine Laterel nr Grandview
Unnamed drain to E Turbine Lateral nr GrandviewUnnamed urban runoff at Union GapWide Hollow Cr at Ahtanum Blvd nr AhtanumWide Hollow Cr at Ahtanum Blvd nr Ahtanum
Apple composite from 5 ditchesAsparagus composite from 5 ditchesCorn composite from 5 ditchesGrape- -composite from 4 ditchesHops composite from 5 ditches
Pear composite from 4 ditchesPotato composite from 5 ditches
Date
11-06-8908-31-8805-02-8911-06-8908-31-88
08-31-8805-04-8911-05-9005-03-8911-07-89
11-07-8908-30-8808-30-8805-01-8908-30-88
08-30-8809-16-8709-01-8809-01-8809-02-88
09-02-8809-01-8809-01-8809-15-8708-31-88
08-31-8808-31-8808-31-8811-08-9008-31-88
08-31-8811-10-9009-01-8809-01-8809-01-88
09-01-8808-28-8709-01-8809-01-88
08-27-8709-16-8708-27-8711-30-8709-16-87
11-30-8709-18-87
Time
12151030123009101630
16351100133009451200
12001730173514301430
14351630080008051000
10050930093512001530
15351630163513301000
10050940110011050900
0905100010001005
22451600211512001630
13001015
micrometers
2,0002,0002,0002,0002,000
622,000
622,0002,000
2,0002,000
622,0002,000
62180
2,00062
2,000
622,000
62180
2,000
622,000
6262
2,000
6262
2,00062
2,000
62180
2,00062
180180180180180
180180
Iso-phorone
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200110
<200
<200<200<200<200<200
<200<200
2-Chloro-naph-thalene
<400<200<200 .<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200
<200<200<200<200<200
<200<200
63
Table 26. Concentrations of semi-volatile organic compounds (phthalate esters, etheres, phenols, cresols, and monocyclic- and polycyclic-aromatic compounds) in bed-sediment samples, Yakima River basin, Washington, 1987-90 Continued
Station number
1247810012478300124797201248000012484480
1248448012484500124845001248455012488250
1248910012500430125004301250043712500445
1250044512500450125036401250364012505460
1250546012507508125075081250862512508850
1250885012508850125088501250971012510500
1251050012510500
461652119522000461652119522000461744119522400
461744119522400463359120281400463501120353300463501120353300
Apple composite from 5 ditchesAsparagus composite from 5 ditchesCorn composite from 5 ditchesGrape composite from 4 ditchesHops composite from 5 ditches
Pear composite from 4 ditchesPotato composite from 5 ditches
Date
11-06-8908-31-8805-02-8911-06-8908-31-88
08-31-8805-04-8911-05-9005-03-8911-07-89
11-07-8908-30-8808-30-8805-01-8908-30-88
08-30-8809-16-8709-01-8809-01-8809-02-88
09-02-8809-01-8809-01-8809-15-8708-31-88
08-31-8808-31-8808-31-8811-08-9008-31-88
08-31-8811-10-9009-01-8809-01-8809-01-88
09-01-8808-28-8709-01-8809-01-88
08-27-8709-16-8708-27-8711-30-8709-16-87
11-30-8709-18-87
Hexa- chloro- but- adiene
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200
<200<200<200<200<200
<200<200
Hexa- chloro- cyclo- pent- adiene
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200
<200<200<200<200<200
<200<200
Hexa- chloro- ethane
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200
<200<200<200<200<200
<200<200
bis(2- Chloro- ethoxy) methane
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200
<200<200<200<200<200
<200<200
bis(2- Chloro- ethyl) ether
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200160
<200
<200<200<200<200<200
<200<200
bis(2- Chloro- iso- propyl) ether
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200120
<200
<200<200<200<200<200
<200<200
4- Bromo- phenyl phenyl ether
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200
<200<200<200<200<200
<200<200
4- Chloro- phenyl phenyl ether
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200
<200<200<200<200<200
<200<200
1,2-Di- chloro- benzene
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200
<200<200<200<200<200
<200<200
64
Table 26. Concentrations of semi-volatile organic compounds (phthalate esters, ethers, phenols, cresols, and monocyclic- and polycyclic-aromatic compounds) in bed-sediment samples, Yakima River basin, Washington, 1987-90 Continued
Station number
1247810012478300124797201248000012484480
1248448012484500124845001248455012488250
1248910012500430125004301250043712500445
1250044512500450125036401250364012505460
1250750812507508125075081250862512508850
1250885012508850125088501250971012510500
1251050012510500
461652119522000461652119522000461744119522400
461744119522400463359120281400463501120353300463501120353300
Apple composite from 5 ditchesAsparagus composite from 5 ditchesCorn~-composite from 5 ditchesGrape composite from 4 ditchesHops composite from 5 ditches
Pear--composite from 4 ditchesPotato composite from 5 ditches
Date
11-06-8908-31-8805-02-8911-06-8908-31-88
08-31-8805-04-8911-05-9005-03-8911-07-89
11-07-8908-30-8808-30-8805-01-8908-30-88
08-30-8809-16-8709-01-8809-01-8809-02-88
09-02-8809-01-8809-01-8809-15-8708-31-88
08-31-8808-31-8808-31-8811-08-9008-31-88
08-31-8811-10-9009-01-8809-01-8809-01-88
09-01-8808-28-8709-01-8809-01-88
08-27-8709-16-8708-27-8711-30-8709-16-87
11-30-8709-18-87
1,3-Di- chloro- benzene
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200
<200<200<200<200<200
<200<200
1,4-Di- chloro- benzene
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200
<200<200<200<200<200
<200<200
2.4-Di- nitro- toluene
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200
<200<200<200<200<200
<200<200
2,6-Di- nitro- toluene
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200160
<200
<200<200<200<200<200
<200<200
Hexa- chloro- benzene
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200
<200<200<200<200<200
<200<200
Nitro benzene
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200120
<200
<200<200<200<200<200
<200<200
1,2,4- Tri- chloro- benzene
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200
<200<200<200<200<200
<200<200
2- Chloro- phenol
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200
<200<200<200<200<200
<200<200
2,4-Di- chloro- phenol
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200
<200<200<200<200<200
<200<200
65
Table 26. Concentrations of semi-volatile organic compounds (phthalate esters, ethers, phenols, cresols, and monocyclic- and polyeyelie-aromatic compounds) in bed-sediment samples, Yakima River basin, Washington, 1987-90 Continued
Station number
1247810012478300124797201248000012484480
1248448012484500124845001248455012488250
1248910012500430125004301250043712500445
1250044512500450125036401250364012505460
1250546012507508125075081250862512508850
1250885012508850125088501250971012510500
1251050012510500
461652119522000461652119522000461744119522400461744119522400463359120281400
463501120353300463501120353300
Apple composite from 5 ditchesAsparagus composites from 5 ditchesCorn composite from 5 ditchesGrape composite from 4 ditchesHops composite from 5 ditches
Pear composite from 4 ditchesPotato composite from 5 ditches
Date
11-06-8908-31-8805-02-8911-06-8908-31-88
08-31-8805-04-8911-05-9005-03-8911-07-89
11-07-8908-30-8808-30-8805-01-8908-30-88
08-30-8809-16-8709-01-8809-01-8809-02-88
09-02-8809-01-8809-01-8809-15-8708-31-88
08-31-8808-31-8808-31-8811-08-9008-31-88
08-31-8811-10-90
09-01-8809-01-8809-01-8809-01-8808-28-87
09-01-8809-01-88
08-27-8709-16-8708-27-8711-30-8709-16-87
11-30-8709-18-87
2,4-Di- methyl- phenol
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200
<200<200<200<200<200
<200<200
<200<200<200<200<200
<200<200
4,6- Dinitro- ortho- cresol
<1,200<600<600<600<600
<600<600<600<600<600
<600<600<600<600<600
<600<600<600<600<600
<600<600<600<600<600
<600<600<600<600<600
<600<600
<600<600<600<600<600
<600<600
<600<600<600<600<600
<600<600
2,4- Di- nitro- phenol
<1,200<600<600<600<600
<600<600<600<600<600
<600<600<600<600<600
<600<600<600<600<600
<600<600<600<600<600
<600<600<600<600<600
<600<600
<600<600<600<600<600
<600<600
<600<600<600<600<600
<600<600
2- Nitro- phenol
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200
<200<200<200<200<200
<200<200
<200<200<200<200<200
<200<200
4- Nitro- phenol
<1,200<600<600<600<600
<600<600<600<600<600
<600<600<600<600<600
<600<600<600<600<600
<600<600<600<600<600
<600<600<600<600<600
<600<600
<600<600<600<600<600
250<600
<600<600<600<600<600
<600<600
P~ Chloro- m-cresol
<1,200<600<600<600<600
<600<600<600<600<600
<600<600<600<600<600
<600<600<600<600<600
<600<600<600<600<600
<600<600<600<600<600
<600<600
<600<600<600<600<600
<600<600
<600<600<600<600<600
<600<600
Penta- chloro- phenol
<1,200<600<600<600<600
<600<600<600<600<600
<600<600<600<600<600
<600<600<600<600<600
<600<600<600<600<600
<600<600<600<600<600
<600<600
<600<600<600<600<500
<600<600
<600<600<600<600<600
<600<600
Phenol (C6H- 50H)
<400<200<200<200110
110870
<200230
<200
<200110
<200<200<200
<200<200
3<200<200
<200<200<200<200<200
<200110110
<200<200
6335
<200<200110110
<200
130310
120<200170
<200<200
<200<200
2,4,6- Tri- chloro- phenol
<1,200<600<600<600<600
<600<600<600<600<600
<600<600<600<600<600
<600<600<600<600<600
<600<600<600<600<600
<600<600<600<600<600
<600<600
<600<600<600<600<600
<600<600
<600<600<600<600<600
<600<600
66
Table 26. Concentrations of semi-volatile organic compounds (phthalate esters, ethers, phenols, cresols, and monocyclic- and polyeyelie-aromatic compounds) in bed-sediment samples, Yakima River basin, Washington, 1987-90 Continued
Station number
1247810012478300124797201248000012484480
1248448012484500124845001248455012488250
1248910012500430125004301250043712500445
1250044512500450125036401250364012505460
1250750812507508125075081250862512508850
1250885012508850125088501250971012510500
1251050012510500
461652119522000461652119522000461744119522400
461744119522400463359120281400463501120353300463501120353300
Apple composite from 5 ditchesAsparagus composite from 5 ditchesCorn composite from 5 ditchesGrape composite from 4 ditchesHops composite from 5 ditches
Pear composite from 4 ditchesPotato composite from 5 ditches
Date
11-06-8908-31-8805-02-8911-06-8908-31-88
08-31-8805-04-8911-05-9005-03-8911-07-89
11-07-8908-30-8808-30-8805-01-8908-30-88
08-30-8809-16-8709-01-8809-01-8809-02-88
09-02-8809-01-8809-01-8809-15-8708-31-88
08-31-8808-31-8808-31-8811-08-9008-31-88
08-31-8811-10-9009-01-8809-01-8809-01-88
09-01-8808-28-8709-01-8809-01-88
08-27-8709-16-8708-27-8711-30-8709-16-87
11-30-8709-18-87
bis (2- Ethyl- hexyl) phthal ate
E800<200240
<2002500
550310
<2005200<200
<200330180250440
580<200
4<200<200
<200340790
<200<200
350520430
<200<200
610<200<200330260
200<200390520
<200<200<200<200<200
<200<200
Diethyl phthal ate
<400<200<200<200
79
81<200<200<200<200
<20090
<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<2008080
<200<200
<200<200<200<200
81
83<200
88<200
<200<200<200<200<200
<200<200
Di methyl phthal ate
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
99<200<200<200
<200<200<200<200<200
<200<200
Di-n- butyl phthal ate
<400<200<200<200120
120<200<200<200<200
<200160100
<200<200
<200<200
3<200<200
<200<200<200<200<200
<200120120
<200<200
<200<200<200<200110
110<200150
<200
<200<200<200<200<200
<200<200
Di-n- octyl phthal ate
<800<400<400<400190
<400<400<400<400<400
<400150
<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400190
170<400150
<400
<400<400<400<400<400
<400<400
n-Butyl benzyl phthal ate
<400<200<200<200120
<200<200<200<200<200
<200150
<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200150
<200<200<200
<200<200<200<200360
160<200150
<200
<200<200<200<200<200
<200<200
Ace- naph- thene
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200
<200<200<200<200<200
<200<200
Ace- naph- thylene
<400<200<200<200<200
<200<200<200<200<200
<20081
<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200
87<200
<200<200<200<200<200
<200<200
Anthra cene
<400<200<200<200<200
<200<200<200<200<200
<20086
<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<2004099
<200
280<200<200<200<200
<200<200
67
Table 26. Concentrations of semi-volatile organic compounds (phthalate esters, ethers, phenols, cresols, and monocyclic- and polycyclic-aromatic compounds) in bed-sediment samples, Yakima River basin, Washington, 1987-90--Continued
Station number
1247810012478300124797201248000012484480
1248448012484500124845001248455012488250
1248910012500430125004301250043712500445
1250044512500450125036401250364012505460
1250546012507508125075081250862512508850
1250885012508850125088501250971012510500
1251050012510500
461652119522000461652119522000461744119522400461744119522400463359120281400
463501120353300463501120353300
Apple composite from 5 ditchesAsparagus composite from 5 ditchesCorn composite from 5 ditchesGrape composite from 4 ditchesHops--compoosite from 5 ditches
Pear composite from 4 ditchesPotato composite from 5 ditches
Date
11-06-8908-31-8805-02-8911-06-8908-31-88
08-31-8805-04-8911-05-9005-03-8911-07-89
11-07-8908-30-8808-30-8805-01-8908-30-88
08-30-8809-16-8709-01-8809-01-8809-02-88
09-02-8809-01-8809-01-8809-15-8708-31-88
08-31-8808-31-8808-31-8811-08-9008-31-88
08-31-8811-10-9009-01-8809-01-8809-01-8809-01-8808-28-87
09-01-8809-01-88
08-27-8709-16-8708-27-8711-30-8709-16-87
11-30-8709-18-87
Benzo(a) anthra cene
<800<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400<400<400
130<400
<400<400<400<400<400
<400<400
Benzo(a) pyrene
<800<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400<400<400
160<400
<400<400<400<400<400
<400<400
Benzo(b) fluor- anthene
<800<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400 C400<400<400
200<400
<400<400<400<400<400
<400<400
Benzo(k) fluor- anthene
<800<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400<400<400
140<400
<400<400<400<400<400
<400<400
Benzo (ghi) pery- lene
<800<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400<400<400
160<400
<400<400<400<400<400
<400<400
Chry- sene
<800<400<400<400<400
<400<400<400<400<400
<40081
<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400<400<400
160<400
<400<400<400<400<400
<400<400
Dibenzo (a,h) anthra cene
<800<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400<400<400
<400<400
<400<400<400<400<400
<400<400
Fluor- anthene
<400<200<200<200120
<200<200<200<200<200
<200120
<200<200<200
120<200<200<200<200
<200<200<200<200<200
<200<200<200
5<200
<2004
<200<200<200<200
56
200<200
130<200<200<200<200
<200<200
68
Table 26. Concentrations of semi-volatile organic compounds (phthalate esters, ethers, phenols, cresols, and monocyclic- and polycyclic-aromatic compounds) in bed-sediment samples, Yakima River basin, Washington, 1987-90 Continued
Station number
1247810012478300124797201248000012484480
1248448012484500124845001248455012488250
1248910012500430125004301250043712500445
1250044512500450125036401250364012505460
1250546012507508125075081250862512508850
1250885012508850125088501250971012510500
1251050012510500
461652119522000461652119522000461744119522400461744119522400463359120281400
463501120353300463501120353300
Apple composite from 5 ditchesAsparagus composite from 5 ditchesCorn composite from 5 ditchesGrape composite from 4 ditchesHops composite from 5 ditches
Pear composite from 4 ditchesPotato composite from 5 ditches
Date
11-06-8908-31-8805-02-8911-06-8908-31-88
08-31-8805-04-8911-05-9005-03-8911-07-89
11-07-8908-30-8808-30-8805-01-8908-30-88
08-30-8809-16-8709-01-8809-01-8809-02-88
09-02-8809-01-8809-01-8809-15-8708-31-88
08-31-8808-31-8808-31-8811-08-9008-31-88
08-31-8811-10-9009-01-8809-01-8809-01-8809-01-8808-28-87
09-01-8809-01-88
08-27-8709-16-8708-27-8711-30-8709-16-87
11-30-8709-18-87
Fluor- ene
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200<200<200
<200<200
<200<200<200<200<200
<200<200
Indeno (1,2,3- cd) pyrene
<800<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400
<400<400<400<400<400<400<400
<400<400
<400<400<400<400<400
<400<400
Naphth alene
<400<200<200<200<200
95<200<200<200<200
<20096
<200<200
30
20<200<200<200<200
<200<200<200<200<200
<200<200
943
<200
82
<200<200<200<200
25
100<200
<200<200<200<200<200
<200<200
Phenan- threne
<400<200<200<200
96
83<200<200<200<200
<20090
<200<200
90
70<200<200<200<200
<200<200
20<200<200
<200<200
829
<200
<2004
<20038
<200<200
35
14028
240<200<200<200<200
<200<200
Pyrene
<400<200<200<200120
<200<200<200<200<200
<200120
<200<200<200
70<200<200<200<200
<200<200<200<200<200
<200<200110
4<200
<2003
<200<200<200<200
58
190<200
160<200<200<200<200
<200<200
n- Nitro- sodi- methyl- amine
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200<200<200
120<200
<200<200<200<200<200
<200<200
n- Nitro- sodi-n- propyl- amine
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200<200<200
<200<200
<200<200<200<200<200
<200<200
n- Nitro- sodi- phenyl- amine
<400<200<200<200<200
<200<200<200<200<200
<200<200<200<200220
160<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200<200<200
43<200
<200<200<200<200<200
<200<200
69
Table 27. Ancillary data, for composite biological samplas, collected for analysis of trace-organic compounds, Yakima River basin, Washington, 1989-90
[D = did not determine, NA = not applicable; see figure 1 for site locations; age of biological samples are expressed in years as measured from scale samples, for example, 0 = less than 1 year, 1 = greater than 1 year and less than 2 years]
Mapreference Station Samplingnumber number Station name date
Fieldnumber Number
OrganismLength(mm)
Height(grams)
Age(years)
Numberexternalabnormalities
Rainbow Trout
1 12478100 Waptus River at mouth nr Roslyn 11-02-89
5 12479720 Jungle Creek nr mouth nr Cle Elum 05-02-89
7 12480000 Teanaway River blw forks nr Cle Elum 11-06-89
14 12484500 Yakima River at Umtanum 11-07-89
15 12484550 Umtanum Creek nr mouth at Umtanum 05-03-89
16 12487200 Little Naches River at mouth nr Cliffdell 10-30-90
18 12489100 Rattlesnake Cr abv N.F. Rattlesnake Cr nr Nile 11-06-89
41 12507594 Satus Cr abv Wilson-Charley Canyon nr Toppenish 11-09-89
YK0065SF 123
4567
Ave.
YK0005SF 123456789
12Ave.
YK0124SF 123456789
10Ave.
YK0145SF 123456789
10Ave.
YK0011SF 123456789
10Ava.
YK0201SF 123456
Ava.
YK0126SF 123456789
10 Ave.
YK0161SF 1 2345678910Ave.
93122107
112120125120114
10810510674671086979826286
147159166148145171167135154153155
132235131125118198195220200210T7S
137127137122146109113110115_96122
210237157157130133T7T
948870817880828996
If
192 200140135130149170180127115T54
71411
1114161412
17121154
1334538
2533362824424521353633
231332624168370
1108496"67
2923292132161715181021
88115353618193T
8746456576 *
64 70262219274250171355
000
0000
DDDDDDDDDD
1111111111
0111111111
DDDDDDDDDD
221111
DDDDDDDDDD
1 111002211
DDD
DDDD
DDDDDDDDDD
DDDDDDDDDD
DDDDDDDDDD
DDDDDDDDDD
000000
DDDDDDDDDD
D DDDDDDDDD
70
Table 27. Ancillary data, for composite biological samples, collected for analysis of trace-organic compounds,Yakima River besin, Washington, 1989-90--Continued
Map reference Station Sampling Field number number Station name date number Number
OrganismLength (mm)
Weight Age (grams) (years)
Number externalabnor malities
Mountain Whitefish
it 12479500 Yakima River at Cle Elum 11-02-89 YK0067SF 123456789
1° Ave.
4 12479500 Yakima River at Cle Elum 11-05-90 YK0303SF 123456789
10Ave.
M 12484500 Yakima River at Umtanum 11-07-89 YK0143SF 123456789
10Ave.
22 12499000 Naches River nr North Yakima 11-06-90 YK0332SF 123456789
1°Ave.
24 12500430 Moxee Drain at Thorp Rd nr Union Gap 11-08-89 YK0154SF 123456789
1°Ave.
40 12507585 Yakima River at RM 72 ab Satus Cr nr Sunnyside 11-01-89 YK0058SF 123456789
10Ave.
«3 12508620 Satus Creek at gage at Satus 11-03-89 YK0076SF 123456789
10Ave.
313299312299301290313294320
ti295293339313312357287349310291313
399349380356278260245187170184281
406361384319338320290320321292335
132145135149148139159154131m277274187268296269190174183176229
184179184176161187180166172181177
245222208236271205285209304303
268214301296244415224391272217284
512346466393198170138523751
155
658389303289405286238346338223345
162419242520342719
M18918948
16224416855434940
TT9
5149484233505037445546
4232322223
4444454545
5233222100
4545545453
1111111111
DDDDDDDDDD
1110110000
DDDDDDDDDD
0000010000
DDDDDDDDDD
0100200620
DDDDDDDDDD
DDDDDDDDDD
DDDDDDDDDD
71
Table 27. Ancillary data, for composite biological samples, collected for analysis of trace-organic compounds, Yakima River basin, Washington, 1989-90 Continued
Mapreferencenumber
Number
Station Sampling Fieldnumber Station name date number Number
OrganismLength(mm)
externalWeight(grams)
Age(years)
abnormalities
Mountain Whitefish--Continued
51
51
12510500 Yakima River at Kiona 10-31-89 YK0040SF 123456789
10Ave.
12510500 Yakima River at Kiona 11-10-90 YK0404SF 123456789
10Ave.
354425402343357366379359368350375
374388364345334382354371338370312
424626698420433489576446452£25415
496667469367397535462491397378466
D.ODDDDDDDD
5654555534
DDDDDDDDDD
0130111101
Smallmouth Bass
51 12510500 Yakima River at Kiona 10-31-89 YK0039SF 123456789
10Ave.
265202181253289299180233220307543
21910876
20729931176
152116346T5T
DDDDDDDDDD
DDDDDDDDDD
Sculpin
4
5
6
8
Yakima River at Cle Elum 11-05-90 YK0304SF 123456789
i°Ave.
12479720 Jungle Creek nr mouth nr Cle Elum 05-02-89 YK00070F 12345678910Ave.
12479750 No Fk Teanaway R blw bridge at Dickey 11-03-90 YK0268SF 1Creek Campgrnd 2
3456789
10Ave.
12481900 Taneum Cr at Taneum Meadow nr Thorp 11-03-90 YK0265SF 123456789
10Ave.
797642418289578739
6878738076718567686773
1108066
108727678
105548015
12110392
1041159592968593
Toff
56116
103814"3
46565483333
1763
15456
1526~5
241411152112111299
14
DDDDDDDDDD
DDDDDDDDDD
DDDDDDDDDD
DDDDDDDDDD
0000000000
DDDDDDDD0D
0000000000
0000000000
-
72
Table 27. Ancillary data, for composite biological samples, collected for analysis of trace-organic compounds, Yakima River basin, Washington, 1989-90 Continued
Mapreferencenumber
Station Samplingnumber Station name date
Fieldnumber Number
OrganismLength(mm)
Weight(grams)
Age(years)
Numberexternalabnormalities
Sculpin- -Continued
9
10
15
17
18
29
30
41
12483190 South Fork Manastash Cr nr Ellensburg 11-02-90
12483750 Naneum Cr blw High Cr nr Ellensburg 11-02-90
12484550 Umatanum Creek nr mouth at Umtanum 11-05-90
12488250 American River at Hells Crossing nr Nile 11-01-90
12489100 Rattlesnake Cr abv N.F. Rattlesnake Cr nr Nile 11-01-90
12500900 S.F. Ahtanum Cr abv Conrad Rnch 11-06-90nr Tampico
12502500 Ahtanum Creek at Union Gap 11-06-90
12507594 Satus Cr abv Wilson-Charley Canyon 11-07-90nr Toppenish
YK0240SF 123456789
10Ave.
YK0242SF 123456789
10Ave.
YK0297SF 123456789
10Ave.
YK0221SF 123456789
10Ave.
YK0225SF 123456789
10Ave.
YK0337SF 123456789
10Ave.
YK0348SF 123456789
10Ave.
YK0368SF 123456789
.10Ave.
988993
113768682767169~85
12110313578779475807574~SI
7159556782675859617265
8972797482948479807481
11011779
1121039874707576~9T
1091101161081039686
11095
118105
93951261221099299
10296
105104
87908883
1001129492
11890~95
98
1023696554~9
24153858
105755
T2
4224742323~3
75657
126555~6
18195
1710135465
To
1521201416117
14102215
1010282515121416101716
810117
13201111189
12
DDDDDDDDDD
DDDDDDDDDD
DDDDDDDDDD
DDDDDDDDDD
DDDDDDDDDD
DDDDDDDDDD
DDDDDDDDDD
DDDDDDDDDD
0000000000
0000000000
0000000000
0000000000
0000000000
DDDDDDDDDD
0000000000
0000000000
73
Table 27. Ancillary data, for composite biological samples, collected for analysis of trace-organic compounds,Yakima River basin, Washington, 1989-90 Continued
Mapreference Stationnumber number Station name
Samplingdate
Fieldnumber Number
Or Rani smLength(mm)
Weight(grams)
Age(years)
Numberexternalabnormalities
Sculpin Continued
43 12508500 Satus Cr below Dry Cr nr Toppenish
43 12508620 Satus Creek at gage at Satus
11-07-90
11-07-90
YK0355SF
YK0353SF
123456789
10Ave.123456789
10Ave.
7760557279616277645867
10178688473756282718278
63256336424
17759563868
DDDDDDDDDD
DDDDDDDDDD
0000000000
0000000000
Chisalmouth
24 12500430 Moxee Drain at Thorp Rd nr Union Gap
46 12508850 Sulphur Cr Waateway nr Sunny side
49 12509710 Spring Creek at mouth at Whitstran
10-31-90
11-09-90
10-30-89
YK0218SF
YK0401SF
YK0020SF
1234567
Ave.
1234567
Ave.
12345
Ave.
207202178199195192140
142126149129129137141136
19619694
110120109 138
8373586867632462
2521271818222312
80728
131614 34
1212211
1111111
DDDDDD
0000000
0000000
DDDDDD
Largescale Sucker
13 12484480 Cherry Creek at Thrall
14 12484500 Yakima River at Umtanum
11-06-89
11-05-90
YK0122SF
YK0302SF
123456789
10Ave.
123456789
10Ave.
269245229208203187151109176236201
430468576563500528481539455477502
193139131869263291453
143~94
9341,1082,0831,8651,2631,3861,2811,500
9061.2401,357
1111110011
5566665565
DDDDDDDDDD
0000000000
74
Table 27. Ancillary data, for composite biological samples, collected for analysis of trace-organic compounds, Yakima River basin, Washington, 1989-90--Continued
Mapreference Station Sampling Fieldnumber number Station name date number Number
OrganismLength(mm)
Weight(grams)
Age(years)
Numberexternalabnormalities
Largescale Sucker Continued
22 12*99000 Naches River nr North Yakima 11-06-90 YK0331SF
24 12500430 Moxee Drain at Thorp Rd nr Union Gap 11-08-89 YK0157SF
26 12500442 Wide Hollow Cr at Old STP at Union Gap 11-05-90 YK0309SF
32 12503950 Yakima R at Parker 11-07-89 YKOU1SF
32 12503950 Yakima R at Parker 11-06-90 YK0324SF
36 12505460 Granger Drain at mouth at Granger 11-03-89 YK0071SF
38 12507508 Toppenish Cr at Indian Church Rd nr Granger 11-03-89 YK0073SF
123456789
IP. Ave.
12345678
Av'e.
123
_4Ave.
123456789
10Ave.
123456789
10Ave.
123456789
Ave.
123456789
IP.Ave.
347422436341509446449418449497 431
222244226246222169129132199
213219173169194
456420399458454456404451422432435
462529392435427430450426434447443
196196199190187186164163216188
396469424465376441480443453443439
801730762465
1,076840833729923
1.367 853
105150117140106482423~89
108945840~75
912669613761111865479810609741723
9271,097
585790760635904711742781793
64626254515832318856
604891768
1,042525878
1,072944957842~652
5444755657
22221100
111D
2333533444
5635446556
111111111
3465355DDD
0000010010
DDDDDDDD
0000
1000000000
0000040004
DDDDDDDDD
DDDDDDDDDD
75
Table 27. Ancillary data, for composite biological samples, collected for analysis of trace-organic compounds, Yakima River basin, Washington, 1989-90 Continued
Mapreferencenumber
Station Sampling Fieldnumber Station name date number Number
OrganismLength(mm)
Weight(grams)
Age(years)
Numberexternalabnormalities
Largescale Sucker Continued
39
40
46
47
47
51
12507525 Yakima R blw Toppenish Cr at RM 79.6 nr Granger 11-07-90 YK0372SF 123456789
10Ave.
12507585 Yakima River at RM 72 ab Satus Cr nr Sunnyside 11-01-89 YK0055SF 123456789
IP.Ave.
12508850 Sulphur Cr Wasteway nr Sunnyside 11-01-89 YK0052SF 123456789
42Ave.
12509050 Yakima R at Euclid Br at RM 55 nr Grandview 10-31-89 YK0047SF 123456789
10Ave.
12509050 Yakima R at Euclid Br at RM 55 nr Grandview 11-09-90 YK0400SF 123456789
42Ave.
12510500 Yakima River at Kiona 10-31-89 YK0041SF 123456789
10Ave.
397485508445395441445461444423444
429432431375437339430435440434418
473462515484431501203462491465449
475456453451520478461434536491476
513449494424394480440471473422456
396453453475484474400408508436449
708985
1,137958653758858872884749856
762776750537668351787808833773704
9511,0151,238
998817
1,28894
9431,113
895935
1,287888753757
1,421980854826
1,4541.0481^027
1,199870
1,010710623989773940
1,051742891
5971,1301,0111,3331,2931,112
706761
1,292930-155
4555644445
3221413222
3444331344
4433232244
5665545645
DDDDDDDDDD
0000000303
DDDDDDDDDD
DDDDDDDDDD
DDDDDDDDDD
1000201200
0000010000
76
Table 27. Ancillary data, for composite biological samples, collected for analysis of trace-organic compounds, Yakima River basin, Washington, 1989-90 Continued
Maprefer encenumber
Station Samplingnumber Station name date
Fieldnumber Number
OrganismLength(mm)
Weight(grams)
Age(years)
Numberexternal abnormalities
Largescale Sucker Continued
51
51
12510500 Yakima River at Kiona 11-10-90
12510500 Yakima River at Kiona 11-10-90
YK0402SF
YK0403SF
123456789
10Ave.
123456789
10Ave.
471435493531532492556537461500501
471565510495560530460445520560512
1,049908
1,0511,3861,5251,1571,7711,688
9081.2401,268
1,0511,7271,2441,2241,9841,1279501,1131,6091.8141,384
4344648656
5766765455
0000200100
2000002011
Bridgelip Sucker
12
14
25
26
36
12484440 Cherry Creek abv. Wipple Wasteway at Thrall 10-31-90
12484500 Yakima River at Umtanum 05-03-89
12500437 Wide Hollow Cr at W. Valley School nr Ahtanum 05-01-89
12500442 Wide Hollow Creek at Old STP at Union Gap 11-08-89
12505460 Granger Drain at mouth nr Granger 11-08-90
YK0211SF
YK0015SF
YK0001SF
YK0155SF
YK0386SF
123456
Ave.
12345
Ave.
123456789
10Ave.
12345678
_9Ave.
123456789
10Ave.
190174153166130138159
374355392373268
240174186181160155179172168155177
111155108102106119125156141125
227220212223229216198211253201219
72654766263151
595475610550535553
18070
10075604570707050~79
13381111111621342820
1291171181201311066795
19185U6
111121
DDDDD
DDDDDDDDDD
000000000
3223462343
000000
DDDDD
DDDDDDDDDD
DDDDDDDDD
0000000000
Common Carp
40 12507585 Yakima River at RM 72 ab Satus Cr nr Sunnyside 11-01-89 YK0056SF 12345678910 Ave.
552410463510438410393435458447 452
2,126892
1,4862,1601,197
951750
1,0931,3761.241 1,327
DDDDDDDDDD
DDDDDDDDDD
77
Table 27. Ancillary data, for composite biological samples, collected for analysis of trace-organic compounds, Yakima River basin, Washington, 1989-90 Continued
Mapreference Station Samplingnumber number Station name date
Fieldnumber Number
Or «ani smLangth(mm)
Weight(grams)
Age(years)
Numberexternalabnormalities
Asiatic Clam
40 12507585 Yakima River at RM 72 ab Satus Cr nr Sunnyside 11-01-89
40 12507585 Yakima River at RM 72 ab Satus Cr nr Sunnyside 11-01-89
40 12507585 Yakima River at RM 72 ab Satus Cr nr Sunnyside 11-01-89
40 12507585 Yakima River at RM 72 ab Satus Cr nr Sunnyside 11-01-89
YK0100SM 123456789
101112131415161718192021222324252627282930313233343536373839404142434445Ave.
YK0101SM 123456789
1011121314151817181920212223242526272829303132333435363738394041424344
Sve.
YK0102SM 1-?
YK0103SM 1-?
303330311927372530243039252430242825362223233123272624243028282426232928241824253323252324TJ
2420222225183322241830262327222329262326262822292228232232243324242224232528322824232324s--
DDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDD
DDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDD
D
D
DDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDD
DDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDD
D
D
NANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANA
NANANAMANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANA
NA
NA
78
Table 27. Ancillary data, for composite biological samples, collected for anelysis of trace-organic compounds, Yakima River basin, Washington, 1989-90 Continued
Mapreferencenumber
Station Sampling Fieldnumber Station name date number Number
OrganismLength(mm)
Weight(grams)
Age(years)
Numberexternalabnormalities
Asiatic Clam Continued
47
47
12509050 Yakima R at Euclid Br at RM 55 nr Grandview 10-31-89 YK0082SM 123456789
1011121314151617IS192021222324252627262930313233343536373839404142434445Ave.
12509050 Yakima R at Euclid Br at RM 55 nr Grandview 10-31-89 YK0085SM 123456789
1011121314151617IS192021222324252627282930313233343536373839404142434445Ave.
1427201715172020161736283427334030272626212721201926272327262024142422IS1921IS20151416151622
15IS151717151716IS172828332524312935222625272527252321232122211923181823IS18IS17161613151422
DDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDD
DDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDD
DDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDD
DDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDD
NANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANA
NANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANA
79
Table 27. Ancillary data, for composite biological samples, collected for analysis of trace-organic compounds,Yakima River basin, Washington, 1989-90 Continued
Mapreference Station number number
Sampling Field Station name date number Number
OrganismLength (mm)
Weight (grams)
Age (years)
Numberexternalabnor malities
Asiatic Clam Continued
47 12509050
49 12509710
Yakima R at Euclid Br at RM 55 nr Grandview 11-04-90 YK0375SM 123456789
1011121314151617181920212223242526272829303132333435363738394041424344
Xve.
Spring Creek at mouth at Whitstran 10-31-89 YK0080SM 123456789
101112131415161718192021222324252627282930313233343536373839404142434445
2926222521272725252122192321222424232221212021212019252522262022232222212316162018172422
8181717161617161817162622252422262221232122232223222022201820191818181718171916161517131611
DDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDD
D
DDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDD
DDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDD
DDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDD
NANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANA
NANANANANANANANANANANANAHAHAHAHAHAHAHANAHAMAHAHAMANAHAHAMANAHAHAHAHAMAHANANANANANANANANANA
80
Table 27. Ancillary data, for composite biological samples, collected for analysis of trace-organic compounds,Yakima River basin, Washington, 1989-90--Continued
Maprefer ence Stationnumber number
Sampling FieldStation name date number Number
OrganismLength(ran)
Weight(grams)
Age(years)
Numberexternal abnormalities
Asiatic Clam Continued
49 12509710
51 12510500
Spring Creek at mouth at Whitstran 11-08-90 YK0408SM 123456789
1011121314151617181920212223242526272829303132333435363738394041424344454647Ave.
Yakima River at Kiona 10-30-89 YK0115SM 123456789
101112131415161718192021222324252627282930313233343536373839404142434445Ave.
232321212618201817182223211923202130221628262219211819172325121323212019242618202122262321202721
21191716171616222225222019201717191817151720191920241818171619171816161616161816161714141218
DDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDD
DDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDD
DDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDD
DDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDD
HAHAHAHAHAHAHAHAHAHAHAHAHAHAHANAHAHAHAHANAHAHAHAHANAHANAHANANANANAHAHAHANANANAHAHANANAHANANANA
NAHANANANANANANANAHAHANAHANANANANANANANANAHANANANANANANANAHANANAHAHAHAHAHANANANANAHANAHANA
81
Table 27. Ancillary data, for composite biological samples, collected for analysis of trace-organic compounds, Yakima River basin, Washington, 1989-90 Continued
Maprefer ence Stationnumber number Station name
Sampling Fielddate number Number
OrganismLength(mm)
Weight(grams)
Age(years)
Numberexternal abnormalities
Asiatic Clam Continued
51 12510500 Yakima River at Kiona
51 12510500 Yakima River at Kiona
10-30-89 YK0116SM 123456789
101112131415161718192021222324252627282930313233343536373839404142434445Ave.
11-04-90 YK0367SM 123456789
10111213141516171819202122232425262728293031323334353637383940414243444546
161619191620141616192819191717191617162020271819172117231816191918161515152016201818201619Ts
23242419201828222222232022192624212219191918191816182023201919231717181818211818171616171614
DDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDD
DDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDD
DDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDD
DDDDDDDDDD0D0DDDDDDD00000000000000D00DDDDDDDDD
NANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANA
NANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANA _
82
Table 27. Ancillary data, for composite biological samples, collected for analysis of trace-organic compounds,Yakima River basin, Washington, 1989-90 Continued
Map refer ence number
Or nanismStation Sampling number Station name date
Field number Number
Length (mm)
Weight (grams)
Age (years)
Number external abnor malities
Asiatic Clam Continued
47484950515253545556575859 Ave.
15171818171416161615141916 19
DDDDDDDDDDDDD D
DDDDDDDDDDDDD
NANANANANANANANANANANANANA
Western Pearlshell
14
14
12484500 Yakima River at Umtanum 11-01-89
12484500 Yakima River at Umtanum 11-05-90
YK0111SM
YK0393SM
123456789
10Ave.
12345
Ave.
127124111117113111119123118117117
134128125118126126
DDDDDDDDDD
DDDDDD
DDDDDDDDDD
DDDDD
NANANANANANANANANANA
NANANANANA
Crayfish
15
25
49
12484550 Umtanum Creek nr mouth at Umtanum 05-03-89
12500437 Wide Hollow Cr at W. Valley School nr Ahtanum 05-01-89
12509710 Spring Creek at mouth at Whitstran 10-30-89
YK0013SD
YK0003SD
YK0022SD
1-20
1-20
1-?
D
D
D
D
D
D
D
D
D
NA
NA
NA
Coontail
38
51
12507508 Toppenish Creek at Indian Church Rd nr Granger 11-03-89
12510500 Yakima River at Kiona 10-30-89
YK0079SP
YK0034SP
1-?
1-?
D
D
D
D
NA
NA
NA
NA
Curlyleaf Pondweed
13
14
24
26
32
40
43
47
12484480
12484500
12500430
12500442
12503950
12507585
12508620
12509050
Cherry Creak
Yakima River
Moxee Drain
Wide Hollow
Yakima R at
Yakima River
Satus Creek
Yakima River
at
at
at
Thrall
Umtanum
Thorp Rd nr Union Gap
Creek at Old STP at Union Gap
Parker
at
at
at
RM 72 ab Satus Cr nr Sunnyside
gage at Satus
Euclid Br at RM 55 nr Grandview
11-06-89
11-05-89
11-04-89
11-04-89
11-04-89
11-01-89
11-03-89
10-31-89
YK0139SP 1-?
YK0118SP 1-?
YK0093SP 1-?
YK0096SP 1-?
YK0094SP 1-?
YK0060SP 1-?
YK0091SP 1-?
YK0045SP 1-?
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Waterweed
26 12500430 Wide Hollow Creek at Old STP at Union Gap 11-04-89 YK0098SP 1-?
38 12507508 Toppenish Creek at Indian Church Rd nr Granger 11-03-89 YK0088SP 1-?
43 12508620 Satus Creek at gage at Satus 11-03-89 YK0092SP 1-?
49 12509710 Spring Creek at mouth at Whitstran 10-30-89 YK0036SP 1-?
NA
NA
NA
NA
NA
NA
NA
NA
83
Table 28. Concentrations of organochlorine compounds in aquatic biota, Yakima River basin, Washington, 1989-90
[Concentrations in micrograms per kilogram; wet weight; whole fish were analyzed; ODD DDE = dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyltrichloroethane; PCBs " " = not analyzed; see figure 1 for site locations]
dichlorodiphenyldichloroethane; polychlorinated biphenyls;
Map reference Station number number Station name Date
Field number
Moisture, Lipid, in percent in percent
Rainbow Trout
157
1515
161841
1247810012479720124800001248455012484550
124872001248910012507594
Waptus River at mouth nr RoslynJungle Creek nr mouth nr Cle ElumTeanaway River below forks near Cle ElumUmtanum Creek nr mouth at UmtanumUmtanum Creek nr mouth at Umtanum
Little Naches River at mouth nr CliffdellRattlesnake Cr abv N.F. Rattlesnake Cr nr NileSatus Cr abv Wilson-Charley Canyon nr Toppenish
11-02-8905-02-8911-06-8905-03-8911-07-89
10-30-9011-06-8911-09-89
YK0065SFYK0005SFYK0124SFYK0011SFYK0145SF
YK0201SFYK0126SFYK0161SF
76787879,76
767575
.0
.0
.0
.0
.0
.4
.0
.5
31214
443
.48
.80
.22
.68
.10
.56
.58
.68
Mountain White fish
4
142224
40435151
12479500
124845001249900012500430
12507585125086201251050012510500
Yakima River at Cle ElumYakima River at Cle ElumYakima River at UmtanumNaches River nr North YakimaMoxee Drain at Thorp Rd nr Union Gap
Yakima River at RM 72 ab Satus Cr nr SunnysideSatus Creek at gage at SatusYakima River at KionaYakima River at Kiona
11-02-8911-05-9011-07-8911-06-9011-08-89
11-01-8911-03-8910-31-8911-10-90
YK0067SFYK0303SFYK0143SFYK0332SFYK0154SF
YK0058SFYK0076SFYK0040SFYK0404SF
74.72.72.73.73.
71,72.71.70.
,0.2.2.0.0
.5
.4,0.0
65,5,5.6
766.7,
.64
.84
.92
.56
.80
.54
.64
.90
.91
SmalLnouth Bass
51 12510500 Yakima River at Kiona 10-31-89 YK0039SF 76,.0 2,.88
Sculpin
45689
1015171829
30414243
1247950012479720124797501248190012483190
1248375012484550124882501248910012500900
12502500125075941250850012508620
Yakima River at Cle ElumJungle Creek nr mouth nr Cle ElumNo Fk Teanaway R blw bridge at Dickey Creek CampgrndTaneum Cr at Taneum Meadow nr ThorpSouth Fork Manastash Cr nr Ellensburg
Naneum Cr blw High Cr nr EllensburgUmtanum Creek nr mouth at UmtanumAmerican River at Hells Crossing nr NileRattlesnake Cr abv N.F. Rattlesnake Cr nr NileS. F. Ahtanum Cr abv Conrad Rnch nr Tampico
Ahtanum Creek at Union GapSatus Cr abv Wilson-Charley Canyon nr ToppenishSatus Creek below Dry Cr nr ToppenishSatus Creek at gage at Satus
11-05-9005-02-8911-03-9011-03-9011-02-90
11-02-9011-05-9011-01-9011-01-9011-06-90
11-06-9011-07-9011-07-9011-07-90
YK0304SFYK0007SFYK0268SFYK0265SFYK0240SF
YK0242SFYK0297SFYK0221SFYK0225SFYK0337SF
YK0348SFYK0368SFYK0355SFYK0353SF
78.75.81.83.84.
80.76.78.80.80,
80,80,77,78
.2
.5
.8
.4
.8
.4
.6
.0
.2
.8
.8
.0:e.0
21,1.1.1
11,1,1,1
1124
.08
.76
.49
.40
.95
.54
.19
.67
.28
.43
.83
.63
.30
.65
Chiselmouth
244649
125004301250885012509710
Moxee Drain at Thorp Rd nr Union GapSulphur Cr Wasteway nr SunnysideSpring Creek at mouth at Whitstran
10-31-9011-09-9010-30-89
YK0218SFYK0401SFYK0020SF
7276,73
.6
.0
.5
667
.69
.71
.90
Largescale Sucker
1314222426
3232363839
4046474751
5151
1248448012484500124990001250043012500442
1250395012503950125054601250750812507525
1250758512508850125090501250905012510500
1251050012510500
Cherry Creek at ThrallYakima River at UmtanumNaches River nr North YakimaMoxee Drain at Thorp Rd nr Union GapWide Hollow Cr at Old STP at Union Gap
Yakima R at ParkerYakima R at ParkerGranger Drain at mouth nr GrangerToppenish Cr at Indian Church Rd nr GrangerYakima R blw Toppenish Cr at RM 79.6 nr Granger
Yakima River at RM 72 ab Satus Cr nr SunnysideSulphur Cr Wasteway nr SunnysideYakima R at Euclid Br at RM 55 nr GrandviewYakima R at Euclid Br at RM 55 nr GrandviewYakima River at Kiona
Yakima River at KionaYakima River at Kiona
11-06-8911-05-9011-06-9011-08-8911-05-90
11-07-8911-06-9011-03-8911-03-8911-07-90
11-01-8911-01-8910-31-8911-09-901C-31-89
1--10-9011-10-90
YK0122SFYK0302SFYK0331SFYK0157SFYK0309SF
YK0141SFYK0324SFYK0071SFYK0073SFYK0372SF
YK0055SFYK0052SFYK0047SFYK0400SFYK0041SF
YK0402SFYK0403SF
75.72.75.77.76.
75.77.75.76.76.
74.72.73.75.70.
70.67.
5644,8
28002
5,05,0,0
66
5.6.4.3.2.
3.3.3.5.8.
7.8.7.5.
11.
7.11.
,94,64.71,90.79
.60,106606,15
,12,96,56.30.6
,99,6
84
Table 28. Concentrations of organochlorine compounds in aquatic biota, Yakima River basin, Washington, 1989-90--Continued
Map reference number
Station number
Hepta- Field cis- trans- Oxy- chlor number Chlordane Chlordane chlordane epoxide
cis- trans- Nonachlor Nonachlor
Rainbow Trout
1 57
15 15
16 18 41
12478100 12479720 12480000 12484550 12484550
12487200 12489100 12507594
YK0065SF <10 <10 <10 <10 YK0005SF <10 <10 <10 <10 YK0124SF <10 <10 <10 <10 YK0011SF <10 <10 <10 <10 YK0145SF <10 <10 <10 <10
YK0201SF <10 <10 <10 <10 YK0126SF <10 <10 <10 <10 YK0161SF <10 <10 <10 <10
1? is:s %
Mountain Whitefish
4 4
14 22 24
40 43 51 51
12479500 12479500 12484500 12499000 12500430
12507585 12508620 12510500 12510500
YK0067SF <10 <10 <10 <10 YK0303SF 10 <10 <10 <10 YK0143SF <10 <10 <10 <10 YK0332SF <10 <10 10 10 YK0154SF 10 <10 <10 <10
YK0058SF 10 <10 <10 <10 YK0076SF <10 <10 <10 <10 YK0040SF 30 <10 <10 <10 YK0404SF 10 10 10 10
<10 10
<10 10 <10 10
<10 10
<10 20 <10 20
Smallmouth Bass
51 12510500 YK0039SF <10 <10 <10 <10 <10
Sculpin
4 5 6 8 9
10 15 17 18 29
30 41 42 43
12479500 12479720 12479750 12481900 12483190
12483750 12484550 12488250 12489100 12500900
12502500 12507594 12508500 12508620
YK0304SF <10 <10 <10 <10 YK0007SF <10 <10 <10 <10 YK0268SF < 10 <10 <10 <10 YK0265SF <10 <10 <10 <10 YK0240SF <10 <10 <10 <10
YK0242SF <10 <10 <10 <10 YK0297SF <10 <10 <10 <10 YK0221SF <10 <10 <10 <10 YK0225SF <10 <10 <10 <10 YK0337SF <10 <10 <10 <10
YK0348SF <10 <10 <10 <10 YK0368SF <10 <10 <10 <10 YK0355SF <10 <10 <10 <10 YK0353SF <10 <10 <10 10
<10 <10
<10 <10 <10 < 10
<10 <10 <10 <10 <10 <10
Chiselmouth
24 46 49
12500430 12508850 12509710
YK0218SF 20 <10 <10 10 YK0401SF 10 <10 <10 <10 YK0020SF <10 <10 <10 <10
<10 10 <10 10
Largescale Sucker
13 14 22 24
26 32
36 38
39 40 46 47
4751 51 51
12484480 12484500 12499000 12500430
12500442 12503950
12505460 12507508
12507525 12507585 12508850 12509050
12509050 12510500 12510500 12510500
YK0122SF <10 <10 <10 <10 YK0302SF 10 <10 10 10 YK0331SF 10 <10 <10 <10 YK0157SF <10 <10 <10 <10
YK0309SF 10 <10 <10 <10 YK0141SF <10 <10 <10 <10 YK0324SF 10 <10 <10 <10 YK0071SF <10 <10 <10 <10 YK0073SF <10 <10 <10 <10
YK0372SF 10 <10 <10 <10 YK0055SF 10 <10 <10 <10 YK0052SF 40 <10 <10 <10 YK0047SF 20 <10 <10 <10
YK0400SF 20 10 10 10 YK0041SF 20 <10 <10 <10 YK0402SF 20 10 10 10 YK0403SF 30 10 20 20
<10 10
<10 10
<10 10
<10 10 <10 10 <10 30 <10 20
<10 20 <10 20 <10 30 <10 40
85
Table 28. Concentrations of organochlorine compounds in aquatic biota, Yakima River basin, Washington, 1989-90 Continued
Mapreferencenumber
Stationnumber
Fieldnumber
o,p'-DDD
P,P'- o.P'-DDD DDE
P,P'- o,P'~DDE DOT
P,P'DOT
Rainbow Trout
157
1515
161841
1247810012479720124800001248455012484550
124872001248910012507594
YK0065SFYK0005SFYK0124SFYK0011SFYK0145SF
YK0201SFYK0126SFYK0161SF
<10<10<10<10<10
<10<10<10
<10 <10<10 <10<10 <10<10 <10<10 <10
<10 <10<10 <10<10 <10
10 <1010 <1010 <1030 <1050 <10
20 <1010 <1010 <10
<10<10<10<10<10
<10<10<10
Mountain Whitefish
44
142224
40435151
1247950012479500124845001249900012500430
12507585125086201251050012510500
YK0067SFYK0303SFYK0143SFYK0332SFYK0154SF
YK0058SFYK0076SFYK0040SFYK0404SF
<1070
<101020
20<10<1040
10 <1010 <1010 <1060 1070 <10
90 <1010 <10
170 <10230 30
70 <1070 <10
160 <10590 <10830 40
1,000 <1090 <10
1,500 <101,600 <10
30104080
110
11030
<1070
Smallmouth Bass
51 12510500 YK0039SF <10 90 <10 560 <10 <10
Sculpin
45689
1015171829
30414243
1247950012479720124797501248190012483190
1248375012484550124882501248910012500900
12502500125075941250850012508620
YK0304SFYK0007SFYK0268SFYK0265SFYK0240SF
YK0242SFYK0297SFYK0221SFYK0225SFYK0337SF
YK0348SFYK0368SFYK0355SFYK0353SF
<10<10<10<10<10
<10<10<10<10<10
<10<10<10<10
<10 <10<10 <10<10 <10<10 <10<10 <10
<10 <10<10 <10<10 <10<10 <10<10 <10
20 <10<10 <10<10 <1010 <10
<10 <10<10 <10<10 <10<10 <10<10 <10
<10 <1010 <10
<10 <10<10 <10<10 <10
90 <10<10 <1010 <1060 <10
<10<10<10<10<10
<10<10<10<10<10
<10<10<1010
Chiselmouth
244649
125004301250885012509710
YK0218SFYK0401SFYK0020SF
1030
<10
50 20130 20<10 <10
360 <101,200 <10
480 <10
1030
<10
Largescale Sucker
13142224
2632323638
39404647
47515151
12484480124845001249900012500430
1250044212503950125039501250546012507508
12507525125075851250885012509050
12509050125105001251050012510500
YK0122SFYK0302SFYK0331SFYK0157SF
YK0309SFYK0141SFYK0324SFYK0071SFYK0073SF
YK0372SFYK0055SFYK0052SFYK0047SF
YK0400SFYK0041SFYK0402SFYK0403SF
<10<1010
<10
2010103020
20407050
60404050
<10 <1030 1050 <1070 <10
80 1060 <1070 <10
150 <10110 <10
140 20210 <10410 <10290 <10
420 30190 <10300 30390 30
50 <10210 10410 <10530 <10
270 <10420 <10620 <10
1,500 <101,000 <10
1,400 <101,800 <103,400 <102,500 <10
2.500 <101,800 <102,000 <102,200 <10
<105070
160
2080
110260150
210270960370
460240190220
86
Table 28. Concentrations of organochlorine compounds in aquatic biota, Yakima River basin, Washington, 1989-90 Continued
Map reference number
Station number
Field Hexachloro- a-Hexachloro- b-Hexachloro- n umber benzene cyclohexane cyclohexane
g-Hexachloro- cyclohexane d-Hexachloro- ( lindane ) eye lohexane Toxaphene
Rainbow Trout
1 5 7
15 15
16 18 41
12478100 12479720 12480000 12484550 12484550
12487200 12489100 12507594
YK0065SF <10 <10 <10 YK0005SF <10 <10 <10 YK0124SF <10 <10 <10 YK0011SF <10 <10 <10 YK0145SF <10 <10 <10
YK0201SF <10 <10 <10 YK0126SF <10 <10 <10 YK0161SF <10 <10 <10
<10 <10 <50 <10 <10 <50 <10 <10 <50 <10 <10 <50 <10 <10 <50
<10 <10 <50 <10 <10 <50 <10 <10 <50
Mountain Whitefish
4 4
14 22 24
40 43 51 51
12479500 12479500 12484500 12499000 12500430
12507585 12508620 12510500 12510500
YK0067SF <10 <10 <10 YK0303SF <10 <10 <10 YK0143SF <10 <10 <10 YK0332SF <10 <10 <10 YK0154SF <10 <10 <10
YK0058SF <10 <10 <10 YK0076SF <10 <10 <10 YK0040SF <10 <10 <10 YK0404SF <10 <10 <10
<10 <10 <50 <10 <10 <50 <10 <10 <50 <10 <10 <50 <10 <10 <50
<10 <10 <50 <10 <10 <50 <10 <10 <50 <10 <10 360
SmaLlmouth Bass
51 12510500 YK0039SF <10 <10 <10 <10 <10 <50
Sculpin
4 5 6 8 9
10 15 17 18 29
30 41 42 43
12479500 12479720 12479750 12481900 12483190
12483750 12484550 12488250 12489100 12500900
12502500 12507594 12508500 12508620
YK0304SF <10 <10 <10 YK0007SF <10 <10 <10 YK0268SF <10 <10 <10 YK0265SF <10 <10 <10 YK0240SF <10 <10 <10
YK0242SF <10 <10 <10 YK0297SF <10 <10 <10 YK0221SF <10 <10 <10 YK0225SF <10 <10 <10 YK0337SF <10 <10 <10
YK0348SF <10 <10 <10 YK0368SF <10 <10 <10 YK0355SF <10 <10 <10 YK0353SF <10 <10 <10
<10 <10 <50 <10 <10 <50 <10 <10 <50 <10 <10 <50 <10 <10 <50
<10 <10 <50 <10 <10 <50 <10 <10 <50 <10 <10 <50 <10 <10 <50
<10 <10 <50 <10 <10 <50 <10 <10 <50 <10 <10 <50
Chiselmouth
24 46 49
12500430 12508850 12509710
YK0218SF <10 <10 <10 YK0401SF <10 <10 <10 YK0020SF <10 <10 <10
<10 <10 <50 <10 <10 690 <10 <10 <50
Largescale Sucker
13 14 22 24
26 32
36 38
39 40 46 47
47 51 51 51
12484480 12484500 12499000 12500430
12500442 12503950
12505460 12507508
12507525 12507585 12508850 12509050
12509050 12510500 12510500 12510500
YK0122SF , <10 <10 <10 YK0302SF <10 <10 <10 YK0331SF <10 <10 <10 YK0157SF <10 <10 <10
YK0309SF 10 <10 <10 YK0141SF <10 <10 <10 YK0324SF <10 <10 <10 YK0071SF <10 <10 <10 YK0073SF <10 <10 <10
YK0372SF <10 <10 <10 YK0055SF <10 <10 <10 YK0052SF <10 <10 <10 YK0047SF <10 <10 <10
YK0400SF <10 <10 <10 YK0041SF <10 <10 <10 YK0402SF <10 <10 <10 YK0403SF <10 <10 <10
<10 <10 <50 <10 <10 <50 <10 <10 <50 <10 <10 <50
<10 <10 <50 <10 <10 <50 <10 <10 <50 <10 <10 <50 <10 <10 <50
<10 <10 300 <10 <10 350 <10 <10 1,200 <10 <10 520
<10 <10 930 <10 <10 310 <10 <10 710 <10 <10 720
87
Table 28. Concentrations of organochlorine compounds in aquatic biota, Yakima River basin, Washington, 1989-90 Continued
Mapreferencenumber
Stationnumber
Fieldnumber
TotalPCBS Dieldrin Endrin Mirex Kepone
Octochloro-styrene Dicofol
Rainbow Trout
157
1515
161841
1247810012479720124800001248455012484550
124872001248910012507594
YK0065SFYK0005SFYK0124SFYK0011SFYK0145SF
YK0201SFYK0126SFYK0161SF
<50<50<50<50<50
<50<50<50
<10 <10 <10 <10<10 <10 <10 <10<10 <10 <10 <10<10 <10 <10 <1010 <10 <10 <10
<10 <10 <10<10 <10 <10 <10<10 <10 <10 <10
<10 <10<10 <10<10 <10<10 <10<10 <10
<10<10 <10<10 <10
Mountain Whitefish
44
142224
40435151
1247950012479500124845001249900012500430
12507585125086201251050012510500
YK0067SFYK0303SFYK0143SFYK0332SFYK0154SF
YK0058SFYK0076SFYK0040SFYK0404SF
<50<50<50<50<50
<50<50<50620
10 <10 <10 <1010 <10 <10 ~~20 <10 <10 <1010 <10 <10 ~~20 <10 <10 <10
40 <10 <10 <1010 <10 <10 <1060 <10 <10 <1050 <10 <10
<10 <10__
<10 <10
<10 40
<10 40<10 30<10 <10
<10
Smallmouth Bass
51 12510500 YK0039SF <50 <10 <10 <10
Sculpin
45689
1015171829
30414243
1247950012479720124797501248190012483190
1248375012484550124882501248910012500900
12502500125075941250850012508620
YK0304SFYK0007SFYK0268SFYK0265SFYK0240SF
YK0242SFYK0297SFYK0221SFYK0225SFYK0337SF
YK0348SFYK0368SFYK0355SFYK0353SF
<50<50<50<50<50
<50<50<50<50<50
<50<50<50<50
<10 ^10 <10 ~~<10 <10 <10 <10<10 <10 <10 -<10 <10 <10<10 <10 <10
<10 <10 ^10 <10 <10 <10<10 <10 <10<10 <10 <10<10 <10 <10
<10 <10 <10<10 <10 <10<10 <10 <1010 <10 <10
_<10 <10__
<10<10
<10__
<10<10
__<10
--
Chiselmouth
244649
125004301250885012509710
YK0218SFYK0401SFYK0020SF
<50250<50
<10 <10 <1080 <10 <10
100 <10 <10 <10
30060
<10 30
Largescale Sucker
13142224
2632323638
39404647
47515151
12484480124845001249900012500430
1250044212503950125039501250546012507508
12507525125075851250885012509050
12509050125105001251050012510500
YK0122SFYK0302SFYK0331SFYK0157SF
YK0309SFYK0141SFYK0324SFYK0071SFYK0073SF
YK0372SFYK0055SFYK0052SFYK0047SF
YK0400SFYK0041SFYK0402SFYK0403SF
<50<50<50<50
<50<50170<50<50
370100610290
780<50790900
20 <10 <10 <1010 <10 <10
<10 <10 <1010 <10 <10 <10
10 <10 <10 ~~10 <10 <10 <10
<10 <10 <1070 <10 <10 <1020 <10 <10 <10
20 <10 <1040 <10 <10 <10
170 <10 <10 <1080 <10 <10 <10
50 <10 <10100 <10 <10 <1060 <10 <1090 <10 <10
<10 <10 __
<10 30
__<10 <10__
<10 30<10 30
60<10 20<10 60<10 20
50<10 <10
<io<10
88
Table 28. Concentrations of organochlorine compounds in aquatic biota, Yakima River basin. Washington, 1989-90 Continued
Map reference Station number number Station name Date
Field number
Moisture, Lipid, in percent in percent
Bridgelip Sucker
1214252636
1248444012484500125004371250044212505460
Cherry Creek abv. Wipple Westeway at ThrallYakima River at UmtanumWide Hollow Cr at W. Valley School nr AhtanumWide Hollow Cr at Old STF at Union GapGranger Drain at mouth nr Granger
10-31-9005-03-8905-01-8911-08-8911-08-90
YK0211SFYK0015SFYK0001SFYK0155SFYK0386SF
7271737471
.2
.8
.6
.5
.2
77658
.93
.03
.75
.02
.98
Carp
40 12507585 Yakima River at RM 72 ab Satus Cr nr Sunny side 11-01-89 YK0056SF 72 .5 5 .30
Asiatic Clam
4040404047
4747494951
5151
1250758512507585125075851250758512509050
1250905012509050125097101250971012510500
1251050012510500
Yakima River at RM 72 ab Satus Cr nr SunnysideYakima River at RM 72 ab Satus Cr nr SunnysideYakima River at RM 72 ab Satus Cr nr SunnysideYakima River at RM 72 ab Satus Cr nr SunnysideYakima R at Euclid Br at RM 55 nr Grandview
Yakima R at Euclid Br at RM 55 nr GrandviewYakima R at Euclid Br at RM 55 nr GrandviewSpring Creek at mouth at WhitstranSpring Creek at mouth at WhitstranYakima River at Kiona
Yakima River at KionaYakima River at Kiona
11-01-8911-01-8911-01-8911-01-8910-31-89
10-31-8911-04-9010-31-8911-08-9010-30-89
10-30-8911-04-90
YK0100SMYK0101SMYK0102SMYK0103SMYK0085SM
YK0082SMYK0375SMYK0080SMYK0408SMYK0115SM
YK0116SMYK0367SM
7678798282
9582838283
8482
.0
.0
.0
.0
.0
.5
.8
.0
.8
.0
.0
.4
22212
1,121,2
1,2
.40
.32
.62
.96
.20
.64
.74
.00
.98
.20
.95
.04
Western Feerlshell
1414
1248450012484500
Yakima River at UmtanumYakima River at Umtanum
11-01-8911-05-90
YK0111SMYK0393SM
86,90,
.0
.2.92,42
Crayfish
152549
124845501250043712509710
Umtanum Creek nr mouth et UmtanumWide Hollow Cr at W. Valley School nr AhtanumSpring Creek at mouth at Whitstran
05-03-8905-01-8910-30-89
YK0013SDYK0003SDYK0022SD
6776,75,
.5
.5
.0
221,
.64
.16
.10
Coontail
3851
1250750812510500
Toppenish Cr at Indian Church Rd nr GrangerYakima River at Kiona
11-03-8910-30-89
YK0079SPYK0034SP
94.93.
00
0. 1020
Curlyleaf Fondweed
1314242632
404347
1248448012484500125004301250044212503950
125075851250862012509050
Cherry Creek at ThrallYakima River at UmtanumMoxee Drain at Thorp Rd nr Union GapWide Hollow Cr at Old STF at Union GapYakima R at Parker
Yakima River at RM 72 ab Satus Cr nr SunnysideSatus Creek at gage at SatusYakima R at Euclid Br at RM 55 nr Grendview
11-06-8911-05-8911-04-8911-04-8911-04-89
11-01-8911-03-8910-31-89
YK0139SPYK0118SPYK0093SPYK0096SPYK0094SP
YK0060SPYK0091SPYK0045SP
93.99.95.93.94.
93.91.91.
00000
000
2010202&30
303030
Waterweed
26384349
12500442125075081250862012509710
Wide Hollow Cr at Old STF at Union GapToppenish Cr et Indian Church Rd nr GrangerSatus Creek at gage at SatusSpring Creek at mouth at Whitstran
11-04-8911-03-8911-03-8910-30-89
YK0098SPYK0088SPYK0092SPYK0036SP
94.93.94.93.
0000
10203020
89
Table 28. Concentrations of organochlorine compounds in aquatic biota, Yakima River basin, Washington, 1989-90 Continued
Map reference number
Station number
Field cis- trans- Oxy- number Chlordane Chlordane chlordane
Hepta- chlor cis- trans- epoxide Nonachlor Nonachlor
Bridgelip Sucker
12 14 25 26 36
12484440 12484500 12500437 12500442 12505460
YK0211SF 10 10 10 YK0015SF 10 <10 <10 YK0001SF 30 <10 <10 YK0155SF 10 <10 <10 YK0386SF 20 10 10
20 <10 10
<10 <10 10 20 <10 20
Carp
40 12507585 YK0056SF 10 <10 <10 <10 <10 10
Asiatic Clam
40 40 40 40 47
47 47 49 49 51
51 51
12507585 12507585 12507585 12507585 12509050
12509050 12509050 12509710 12509710 12510500
12510500 12510500
YK0100SM <10 <10 <10 YK0101SM <10 <10 <10 YK0102SM <10 <10 <10 YK0103SM <10 <10 <10 YK0085SM <10 <10 <10
YK0082SM <10 <10 <10 YK0375SM <10 <10 <10 YK0080SM <10 <10 <10 YK0408SM 10 <10 <10 YK0115SM <10 <10 <10
YK0116SM <10 <10 <10 YK0367SM 10 <10 <10
<10 <10 <10
<10 <10 <10
<10 <10 10
Western Pearlshell
14 14
12484500 12484500
YK0111SM <10 <10 <10 YK0393SM <10 <10 <10 3! <iS <JS
Crayfish
15 25 49
12484550 12500437 12509710
YK0013SD <10 <10 <10 YK0003SD <10 <10 <10 YK0022SD <10 <10 <10 :a % si
Coontail
38 51
12507508 12510500
YK0079SP <10 <10 <10 YK0034SP <10 <10 <10
<10 <10 <10 <10 <10 ^10
Curlyleaf Pondweed
13 14 24 26 32
40 43 47
12484480 12484500 12500430 12500442 12503950
12507585 12508620 12509050
YK0139SP <10 <10 <10 YK0118SP <10 <10 <10 YK0093SP <10 <10 <10 YK0096SP <10 <10 <10 YK0094SP <10 <10 <10
YK0060SP <10 <10 <10 YK0091SP <10 <10 <10 YK0045SP <10 <10 <10
<10 <10 <10 <10 <10 <10
Waterweed
26 38 43 49
12500442 12507508 12508620 12509710
YK0098SP <10 <10 <10 YK0088SP <10 <10 <10 YK0092SP <10 <10 <10 YK0036SP <10 <10 <10 1 1 1
90
Table 28. Concentrations of organochlorine compounds in aquatic biota, Yakima River basin, Washington, 1989-90 Continued
Mapreferencenumber
Stationnumber
Fieldnumber
o.p'-DDD
p,p'- o,p'-DDD DDE
p,p'- o,p'-DDE DOT
P,P'DOT
Bridgelip Sucker
1214252636
1248444012484500125004371250044212505460
YK0211SFYK0015SFYK0001SFYK0155SFYK0386SF
2010203020
20 1050 <10
150 1080 <10
190 20
60 10220 <10750 10180 20730 <10
3070
11050
200
Carp
40 12507585 YK0056SF 20 140 <10 1,700 <10 40
Asiatic Clam
4040404047
4747494951
5151
1250758512507585125075851250758512509050
1250905012509050125097101250971012510500
1251050012510500
YK0100SMYK0101SMYK0102SMYK0103SMYK0085SM
YK0082SMYK0375SMYK0080SMYK0408SMYK0115SM
YK0116SMYK0367SM
1010101030
2020402020
2010
60 <1050 <1060 <1040 <10
100 10
80 <10100 10180 20120 2080 10
60 <1070 10
310 <10280 <10330 <10230 <10530 <10
390 <10660 <10
1,300 301,300 70
410 <10
360 <10430 <10
8070806060
4070
32038050
3040
Western Pearlshell
1414
1248450012484500
YK0111SMYK0393SM
<10<10
<10 <10<10 <10
<10 <10<10 <10
<10<10
Crayfish
152549
124845501250043712509710
YK0013SDYK0003SDYK0022SD
<10<10<10
<10 <1060 <10
<10 <10
<10 <1050 <1040 <10
<1010
<10
Coontail
3851
1250750812510500
YK0079SPYK0034SP
<10<10
<10 <10<10 <10
<10 <1020 <10
<10<10
Curlyleaf Pondweed
1314242632
404347
1248448012484500125004301250044212503950
125075851250862012509050
YK0139SPYK0118SPYK0093SPYK0096SPYK0094SP
YK0060SPYK0091SPYK0045SP
<10<10<10<10<10
<10<10<10
<10 <10<10 <10<10 <10<10 <10<10 <10
<10 <10<10 <10<10 <10
<10 <10<10 <1020 <1010 <10
<10 <10
10 <1010 <1030 <10
<10<10<10<10<10
<10<10<10
Waterweed
26384349
12500442125075081250862012509710
YK0098SPYK0088SPYK0092SPYK0036SP
<10<10<10<10
<10 <10<10 <10<10 <10<10 <10
10 <10<10 <10<10 <1040 <10
<10<10<10<10
91
Table 28. Concentrations of organochlorine compounds in aquatic biota, Yakima River basin, Washington, 1989-90 Continued
Map reference number
Station number
Field Hexachloro- a-Hexachloro- b-Hexachloro- number benzene cyclohexane cyclohexane
g-Hexachloro- cyclohexane d-Hexachloro- (lindane) cyclohexane Toxaphene
Bridgelip Sucker
12 14 25 26 36
12484440 12484500 12500437 12500442 12505460
YK0211SF <10 <10 <10 YK0015SF <10 <10 <10 YK0001SF <10 <10 <10 YK0155SF <10 <10 <10 YK0386SF <10 <10 <10
<lS <lS<50 <50 <50 <50 410
Carp
40 12507585 YK0056SF <10 <10 <10 <10 220
Asiatic Clam
40 40 40 40 47
47 47 49 49 51
51 51
12507585 12507585 12507585 12507585 12509050
12509050 12509050 12509710 12509710 12510500
12510500 12510500
YK0100SM <10 <10 <10 YK0101SM <10 <10 <10 YK0102SM <10 <10 <10 YK0103SM <10 <10 <10 YK0085SM <10 <10 <10
YK0082SM <10 <10 <10 YK0375SM <10 <10 <10 YK0080SM <10 <10 <10 YK0408SM <10 <10 <10 YK0115SM <10 <10 <10
YK0116SM <10 <10 <10 YK0367SM <10 <10 <10
<10 <10 <10 <10 <10 <10 <10 <10 <10 <10
<10 <10 <10 <10 <10 <10 <10 <10 <10 <10
<10 <10 <10 <10
<50 <50 <50 <50 <50
<50 <50 <50 <50 <50
<50 <50
Western Pearlshell
14 14
12484500 12484500
YK0111SM <10 <10 <10 YK0393SM <10 <10 <10 as as <50
<50
Crayfish
15 2549
12484550 12500437 12509710
YK0013SD <10 <10 <10 YK0003SD <10 <10 <10 YK0022SD <10 <10 <10 as as
<50 <50 <50
Coontail
3851
12507508 12510500
YK0079SP <10 <10 <10 YK0034SP <10 <10 <10 as as <50
<50
Curlyleaf Pondweed
13 14 24 26 32
40 43 47
12484480 12484500 12500430 12500442 12503950
12507585 12508620 12509050
YK0139SP <10 <10 <10 YK0118SP <10 <10 <10 YK0093SP <10 <10 <10 YK0096SP <10 <10 <10 YK0094SP <10 <10 <10
YK0060SP <10 <10 <10 YK0091SP <10 <10 <10 YK0045SP <10 <10 <10
<iS <iS
<50 <50 <50 <50 <50
<50 <50<50
Waterweed
26 38 43 49
12500442 12507508 12508620 12509710
YK0098SP <10 <10 <10 YK0088SP <10 <10 <10 YK0092SP <10 <10 <10 YK0036SP <10 <10 <10
as as <50 <50 <50 <50
92
Table 28. Concentrations of organochlorine compounds in aquatic biota, Yakima River basin, Washington, 1989-90 Continued
Mapreferencenumber
Station number
Field number
Total PCBS Dieldrin Endrin Mirex Kepone
Octochloro- styrene Dicofol
Bridgelip Sucker
1214252636
1248444012484500125004371250044212505460
YK0211SFYK0015SFYK0001SFYK0155SFYK0386SF
<50<50<50<50220
30 <10 <10 -- -- <1010 <10 <10 <10 <10 <1030 <10 <10 <10 <10 <1040 <10 <10 <10 <10 <1080 <10 <10 -- -- <10
Carp
40 12507585 YK0056SF <50 20 20
Asiatic Clam
4040404047
4747494951
5151
1250758512507585125075851250758512509050
1250905012509050125097101250971012510500
1251050012510500
YK0100SMYK0101SMYK0102SMYK0103SMYK0085SM
YK0082SMYK0375SMYK0080SMYK0408SMYK0115SM
YK0116SMYK0367SM
<50<50<50<50<50
<50<50<50<50<50
<50<50
10 <10 <10 <10 <10 <1010 <10 <10 <10 <10 <1010 <10 <10 <10 <10 <1010 <10 <10 <10 <10 <1020 <10 <10 <10 <10 <10
20 <10 <10 <10 <10 <1010 <10 <10 -- -- <1040 <10 <10 <10 <10 <1030 <10 <10 7010 <10 <10 <10 <10 <10
10 <10 <10 <10 <10 <1010 <10 <10 -- -- <10
Western Pearlshell
14 14
12484500 12484500
YK0111SM YK0393SM
<50 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 -- -- <10
Crayfish
15 25 49
12484550 12500437 12509710
YK0013SD YK0003SD YK0022SD
<50 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10
Coontail
38 51
12507508 12510500
YK0079SP YK0034SP
<50 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10
Curly leaf Pondweed
13 14 24 26 32
40 43 47
12484480 12484500 12500430 12500442 12503950
12507585 12508620 12509050
YK0139SP YK0118SP YK0093SP YK0096SP YK0094SP
YK0060SP YK0091SP YK0045SP
<50 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10
<50 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10
Waterweed
26 38 43 49
12500442 12507508 12508620 12509710
YK0098SP YK0088SP YK0092SP YK0036SP
<50 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10
93
Table 29. Concentrations of semi-volatile organic compounds (polycyclic-aromatic hydrocarbons) in aquatic biota,Yakima River basin, Washington, 1989-90
[Concentrations in micrograms per kilogram, wet weight; whole fish were analyzed; see figure 1 for site locations]
Map reference number
Station number Station name Date
Field number
Moisture, in percent
Lipid, in percent
Rainbow Trout
16 12487200 Little Naches River at mouth nr Cliffdell 10-30-90 YK0201SF 76.4 4.56
Asiatic Clam
40 40 40 40 47
47 49 49 51 51
51
12507585 12507585 12507585 12507585 12509050
12509050 12509710 12509710 12510500 12510500
12510500
Yakima River at RM 72 ab Satus Cr nr Sunnyside Yakima River at RM 72 ab Satus Cr nr Sunnyside Yakima River at RM 72 ab Satus Cr nr Sunnyside Yakima River at RM 72 ab Satus Cr nr Sunnyside Yakima R at Euclid Br at RM 55 nr Grandview
Yakima R at Euclid Br at RM 55 nr Grandview Spring Creek at mouth at Whitstran Spring Creek at mouth at Whitstran Yakima River at Kiona Yakima River at Kiona
Yakima River at Kiona
11-01-89 11-01-89 11-01-89 11-01-89 10-31-89
10-31-89 10-31-89 11-08-90 10-30-89 10-30-89
11-04-90
YK0100SM YK0101SM YK0102SM YK0103SM YK0082SM
YK0085SM YK0080SM YK0408SM YK0115SM YK0116SM
YK0367SM
76.0 78.0 79.0 82.0 95.5
82.0 83.0 82.8 83.0 84.0
82.4
2.40 2.32 2.62 1.96 1.64
2.20 2.00 1.98 2.201.95
2.04
Western Fearlshell
14 14
12484500 12484500
Yakima River at Umtanum Yakima River at Umtanum
11-01-89 11-05-90
YK0111SM YK0393SM
86.0 90.2
.92
.42
Crayfish
15 25 49
12484550 12500437 12509710
Umtanum Creek nr mouth at Umtanum Wide Hollow Cr at W. Valley School nr Ahtanum Spring Creek at mouth at Whitstran
05-03-89 05-01-89 10-30-89
YK0013SD YK0003SD YK0022SD
67.5 76.5 75.0
2.64 2.16 1.10
Coontail
3851
12507508 12510500
Toppenish Cr at Indian Church Rd nr Granger Yakima River at Kiona
11-03-89 10-30-89
YK0079SP YK0034SP
94.0 93.0
.10
.20
Curlyleaf Pondweed
13 14 24 26 32
40 43 47
12484480 12484500 12500430 12500442 12503950
12507585 12508620 12509050
Cherry Creek at Thrall Yakima River at Umtanum Moxee Drain at Thorp Rd nr Union Gap Wide Hollow Cr at Old STP at Union Gap Yakima R at Parker
Yakima River at RM 72 ab Satus Cr nr Sunnyside Satus Creek at gage at Satus Yakima R at Euclid Br at RM 55 nr Grandview
11-06-89 11-05-89 11-04-89 11-04-89 11-04-89
11-01-89 11-03-89 10-31-89
YK0139SP YK0118SP YK0093SP YK0096SP YK0094SP
YK0060SP YK0091SP YK0045SP
93.0 99.0 95.0 93.0 94.0
93.0 91.0 91.0
.20
.10
.20
.20
.30
.20
.30
.30
Waterweed
26 38 43 49
12500442 12507508 12508620 12509710
Wide Hollow Cr at Old STP at Union Gap Toppenish Cr at Indian Church Rd nr Granger Satus Creek at gage at Satus Spring Creek at mouth at Whitstran
11-04-89 11-03-89 11-03-89 10-30-89
YK0098SP YK0088SP YK0092SP YK0036SP
94.0 93.0 94.0 93.0
.20
.20
.30
.20
94
Table 29. Concentrations of semi -volatile organic compounds (poly eye lie -aromatic hydrocarbons) in aquatic biota, Yakima River basin, Washington, 1989-90 Continued
Map reference number
Station number
Field number Napthalene
Phenan- Fluorene threne
Anthra cene
Fluor- anthrene Pyrene
1,2-Benz- anthracene
Rainbow Trout
16 12487200 YK0201SF 50 <10 <10 <10 <10 <10 <10
Asiatic Clem
40 40 40 40 47
47 49 49 51 51
51
12507585 12507585 12507585 12507585 12509050
12509050 12509710 12509710 12510500 12510500
12510500
YK0100SM YK0101SM YK0102SM YK0103SM YK0082SM
YK0085SM YK0080SM YK0408SM YK0115SM YK0116SM
YK0367SM
10 <10 <10 10 10
20 10 40
<10 10
40
A A AAA AA AA O OOOOO OOOOO
30 30 30 40 40
30 30 20 90 40
20
o ooooo ooooo
10 10 10 10
<10
10 10
<10 20 50
10
A AAA AAAAA
O OOOOO OOOOO o ooooo ooooo
Western Pearlshell
14 14
12484500 12484500
YK0111SM YK0393SM
<10 10
<10<10
<10 <10
<10 <10
<10 10
<10 <10
<10 <10
Crayfish
15 25 49
12484550 12500437 12509710
YK0013SD YK0003SD YK0022SD
<10 <10 <10
<10 <10 <10
<10 <10 <10
<10 <10 <10
<10 <10 <10
<10 <10 <10
<10 <10 <10
Coontail
38 51
12507508 12510500
YK0079SP YK0034SP
<10 <10
<10 <10
<10 <10
<10 <10
<10 <10
<10 <10
<10 <10
Curlyleaf Pondweed
13 14 24 26 32
40 43 47
12484480 12484500 12500430 12500442 12503950
12507585 12508620 12509050
YK0139SP YK0118SP YK0093SP YK0096SP YK0094SP
YK0060SP YK0091SP YK0045SP
ooo oooooAAA AAAAA
OOO OOOOO
AAA AAAAA OOO OOOOO
AAA AAAAA OOO OOOOO
A A A AAA OOO OOOOO ooo ooooo
AAA AAAAA OOO OOOOO
Waterweed
26 38 43 49
12500442 12507508 12508620 12509710
YK0098SP YK0088SP YK0092SP YK0036SP
<10 <10 <10 20
<10 <10 <10 10
<10<10 <10 40
<10 <10 <10 <10
<10 <10 <10 10
<10 <10 <10 <10
<10 <10 <10 <10
95
Table 29. Concentrations of semi-volatile organic compounds (polycyclic-aromatic hydrocarbons) in aquatic biota,Yakima River basin, Washington, 1989-90--Continued
Mapreferencenumber
Station number
Field number
Benzo(b)- Benzo(k)- Benzo(e)- Benzo(a)- 1,2,5,6-Dibenz- Benz Chrysene fluoranthrene fluoranthrene pyrene pyrene anthracene pery
Rainbow Trout
16 12487200 YK0201SF
51 12510500 YK0367SM
Asiatic Clam
4040404047
4749495151
1250758512507585125075851250758512509050
1250905012509710125097101251050012510500
YK0100SM <10 <10 <10 <10 <10 <10 <10YK0101SM <10 <10 <10 <10 <10 <10 <10YK0102SM <10 <10 <10 <10 <10 <10 <10YK0103SM <10 <10 <10 <10 <10 <10 <10YK0082SM <10 <10 <10 <10 <10 <10 <10
YK0085SM <10 <10 <10 <10 <10 <10 <10YK0080SM <10 <10 <10 <10 <10 <10 <10YK0408SM <10 <10 <10 <10 <10 <10 <10YK0115SM <10 <10 <10 <10 <10 <10 <10YK0116SM <10 <10 <10 <10 <10 <10 <10
Western Pearlshell
1414
1248450012484500
YK0111SM YK0393SM
Crayfish
152549
124845501250043712509710
YK0013SD YK0003SD YK0022SD 10
Coontail
3851
12507508 12510500
YK0079SP <10 <10 YK0034SP <10 <10 as <js as as as
Curlyleaf Pondweed
1314242632
404347
1248448012484500125004301250044212503950
125075851250862012509050
YK0139SP <10 <10YK0118SP <10 <10YK0093SP <10 <10YK0096SP <10 <10YK0094SP <10 <10
YK0060SP <10 <10YK0091SP <10 <10YK0045SP <10 <10
<10 <10 <10 <10 <10<10 <10 <10 <10 <10<10 10 <10 <10 <10<10 10 <10 <10 <10<10 <10 <10 <10 <10
<10 <10 <10 <10 <10<10 <10 <10 <10 <10<10 10 <10 <10 <10
Waterweed
26384349
12500442125075081250862012509710
YK0098SP YK0088SP YK0092SP YK0036SP
10
1010
96
QUALITY-ASSURANCE DATA
Tables showing quality-assurance data have been grouped and presented by sampling media: whole-water data are listed in tables 30-38, filtered-water data in tables 39-44, suspended-sediment data in tables 45-50, bed-sediment data in tables 51-53, and aquatic-biota data in tables 54-57. For whole-water analyses, data are arranged alphabetically by chemical family.
97
Table 30A. Concentrations of carbamate compounds in replicate whole-water samples from Cle Elum River above Cle Elum Lake near Roslyn, Washington, July 26, 1988, at 1000 hour and 1015 hour
[Station number 12478300; map reference number 3 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 15 minutes apart; "<" » less than; less-than values were set equal to zero for calculations]
Concentration, in nanofcrams per literParametercode
39053825878258639750
82615825843028239051
77441826133905230296
Replicate 1 Replicate 2(not spiked) (not spiked) Difference
Constituent
AldicarbAldicarb sulfoneAldicarb sulfoxideCarbaryl
Carbofuran3-HydroxycarbofuranMethiocarbMethomyl
1-NaphtholOxamylFrophamPropoxur
A
<500<500<500<500
<500<500<500<500
<500<500<500<500
B
<500<500<500<500
<500<500<500<500
<500<500<500<500
|A - B|
0000
0000
0000
Table 30B. Concentrations of carbamate compounds in replicate whole-water samples from Cherry Creek at Thrall, Washington, June 2, 1988, at 1400 hour and 1405 hour
[Station number 12484480; map reference number 13 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 5 minutes apart"<" » less than; less-than values were set equal to zero for calculations]
Parametercode
39053825878258639750
82615825843028239051
77441826133905230296
Constituent
AldicarbAldicarb sulfoneAldicarb sulfoxideCarbaryl
Carbofuran3-HydroxycarbofuranMethiocarbMethomyl
1-NaphtholOxamylProphamPropoxur
§oncentrstion,eplicate 1(not spiked)
A
<500<500<500<500
<500<500<500<500
<500<500<500<500
, in nanogramsReplicate 2(not spiked)
B
<500<500<500<500
<500<500<500<500
<500<500<500<500
per liter
Difference|A - B|
0000
0000
0000
Table 30C. Concentrations of carbamate compounds in replicate whole-water samples from Wide Hollow Creek near mouth at Union Gap, Washington, November 15, 1988, at 1330 hour and 1430 hour
[Station number 12500445; map reference number 27 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 1 hour apart; "<" * less than; less-than values were set equal to zero for calculations]
Parametercode
39053825878258639750
82615825843028239051
77441826133905230296
Constituent
AldicarbAldicarb sulfoneAldicarb sulfoxideCarbaryl
Carbofuran3 -Hydr oxy c arbofur anMethiocarbMethomyl
1-NaphtholOxamylProphamPropoxur
Concentration,Replicate 1(not spiked)
A
<500<500<500<500
<500<500<500<500
<500<500<500<500
. in nanogramsReplicate 2(not spiked)
B
<500<500<500<500
<500<500<500<500
<500<500<500<500
per liter
Difference|A - B|
0000
0000
0000
98
Table SOD. Concentrations of carbamate compounds in replicate whole-water samples from Moxee Drain at Thorp Road near Union Gap, Washington, May 6, 1988, at 0930 hour and 0940 hour
[Station number 12500430; map reference number 24 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 10 minutes apart; "<" = less than; less-than valuea were set equal to zero for calculations]
Parametercode
390538258782586
39750826158258439051
774418261339052
Constituent
AldicarbAldicarb sulfoneAldicarb sulfoxide
CarbarylCarbofuran3 -Hydroxyc arbof ur anMethomyl
1-NaphtholOxamylPropham
Concentration,Replicate 1(not spiked)
A
<500<500<500
<500<500<500<500
<500<500<500
, in nanoxramsReplicate 2(not spiked)
B
<500<500<500
<500<500<500<500
<500<500<500
per liter
Difference|A - B|
000
0000
000
Table 30E. Concentrations of carbamate compounds in replicate whole-water samples from Granger Drain at mouth near Granger, Washington, July 28, 1988, at 0930 hour and 1015 hour
[Station number 12505460; map reference number 36 figure 1; in addition to analytical variability, the results include temporal variebility, because the samples were collected 45 minutes apart; "<" = less than; less-than values were set equel to zero for calculations]
Parametercode
39053825878258639750
82615825843028239051
77441826133905230296
Constituent
AldicarbAldicarb sulfoneAldicarb sulfoxideCarbaryl
Carbofuran3 -Hydroxyc arbof ur anMethiocarbMethomyl
1-NaphtholOxamylProphamPropoxur
Concentration,Replicate 1(not spiked)
A
<500<500<500<500
<500<500<500<500
<500<500<500<500
, in nanoKramsReplicate 2(not spiked)
B
<500<500<500<500
<500<500<500<500
<500<500<500<500
per liter
Difference|A - B|
0000
0000
0000
Table 30F. Concentrations of carbamate compounds in replicate and spiked whole-water samples from Sulphur Creek Wasteway near Sunnyside, Washington, August 31, 1988, at 1530 hour and 1630 hour
[Station number 12508850; map reference number 46 figure 1; in addition to analytical variebility, the results include temporal variability, because the samples were collected 1 hour apart; "ns" = not spiked; "<" = less than; less-than values were set equal to zero for calculations]
Concentration, in nanottrams per liter
Laboratory resultsParametercode
39053825878258639750
82615825843028239051
77441826133905230296
Replicate 1
Constituent
AldicarbAldicarb sulfoneAldicarb sulfoxideCarberyl
Carbofuran3 -Hydroxyc arbo fur anMethiocarbMethomyl
1-NaphtholOxamylProphamPropoxur
(not spiked)A
<500<500<500<500
<500<500<500<500
<500<500<500<500
Replicate 2(not spiked)
B
<500<500<500<500
<500<500<500<500
<500<500<500<500
Calculated concentration Analytical
Replicate 3 in replicate 3 recovery,Difference|A - B|
0000
0000
0000
(spiked)C
310nsns350
510nsns400
nsnsnsns
(spiked)D
430nsns470
460nsns510
nsnsnsns
in percentC x 100
72nsns74
110nsns78
nsnsnsns
/ D
99
Table 30G. Concentrations of carbamate compounds in spiked whole-water samples from Buckskin Slough below Gleed Ditch near Gleed, Washington, May 22, 1991, at 1100 hour and 1107 hour
[Station number 12496550; map reference number 21 figure 1; "<" = less than; less-than values were set equal to zero for calculations]
Concentration, in nanoKrams per literLaboratory results
Parametercode
39750826153905182613
Constituent
CarbarylCarbofuranMethomylOxamyl
Replicate 1(not spiked)
A
<500<500<500<500
Replicate 2(spiked)
B
<500<500<500<500
Calculatedconcentrationin replicate 2
C
1,1001,1001,1001,100
Recovery,in percentB x 100 /C
0000
Table 30H. Concentrations of carbamate compounds in spiked whole-water samples from Buckskin Slough below Gleed Ditch near Gleed, Washington, August 7, 1991, at 1000 hour and 1007 hour
[Station number 12496550; map reference number 21 figure 1; "<" = less than; less-than values were set equal to zero for calculations]
Para meter code Constituent
Concentration, in nanograms per liter CalculatedLaboratory results
Replicate (not spiked)
Replicate 2 (spiked)
concentration in replicate 2
Recovery, in perce:int
/ C
39750 Carbaryl82615 Carbofuran39051 Methomyl82613 Oxamyl
<500 <500 <500 <500
9001,000
900600
1,1001,1001,1001,100
82918254
100
Table 31A. Concentrations of chlorophenoxy-acid herbicides, dicamba, and picloram in replicate whole-water samples from Cle Elum River above Cle Elum Lake near Roslyn, Washington, July 26, 1988, at 1000 hour and 1015 hour
[Station number 12478300; map raference number 3 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected IS minutes apart; 2,4-D - (2,4-dichlorophenoxy)acetic acid; 2,4-DP = dichlorprop; 2,4,5-T - (2,4,5-trichlorophenoxy)acetic acid; "<" « less than; less-than values were set equal to zero for calculations]
Parametercode
820523973082183
397603972039740
Constituent
Dicamba2,4-D2,4-DP
FenopropPicloram2,4,5-T
Concentration.Replicate 1(not spiked)
A
<10<10<10
<10<io<10
, in nanoxrams per literReplicate 2(not spiked) Difference
B |A - B|
<io o<10 0<10 0
< 10 0< 10 0< 10 0
Table 31B. Concentrations of chlorophenoxy-acid herbicides, dicamba, and picloram in replicete whole-water samples from Cherry Creek at Thrall, Washington, June 2, 1988, at 1400 hour and 1405 hour
[Station number 12484480; map reference number 13 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 5 minutes apart; 2,4-D - (2,4-dichlorophenoxy)acetic acid; 2,4-DP - dichlorprop; 2,4,5-T - (2,4,5-trichloropheno3ty)acetic acid; "<" - less than; less-than values were set equal to zero for calculations]
Parametercode
820523973082183
397603972039740
Constituent
Dicamba2,4-D2,4-DP
FenopropPicloram2,4,5-T
Concentration,Replicate 1(not spiked)
A
140150<10
<10<10<10
. in nanoKramsReplicate 2(not spiked)
B
140140<10
<10<10<10
per liter
Difference|A - B|
0100
000
Table 31C. Concentrations of chlorophenoxy-acid herbicides, dicamba, and picloram in replicate whole-water samples from Wide Hollow Creek near mouth at Union Gap, Washington, November 15, 1988, at 1330 hour and 1430 hour
[Station number 12500445; map reference number 27 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 1 hour apart; 2,4-D - (2,4-dichlorophenoxy acetic acid; 2,4-DP - dichlorprop; 2,4,5-T = (2,4,5-trichlorophenoxy)acetic acid; "<"» less than; less-than values were set equal to zero for calculations]
Para meter code Constituent
Concentration, in nanograms per liter Replicate 1 (not spiked)
A
Replicate 2(not spiked) Difference
B~^ |A - B|
820523973082183
397603972039740
Dicamba2,4-D2,4-DP
Fenoprop Picloram 2,4,5-T
101
Table 31D. Concentrations of chlorophenoxy-acid herbicides, dicamba, and picloram in replicate whole-water samples from Moxee Drain at Thorp Road near Union Gap, Washington, May 6, 1988, at 0930 hour and 0940 hour
[Station number 12500430; map reference number 24 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 10 minutes apart; 2,4-D = (2,4-dichlorophenoxy)acetic acid; 2,4-DP - dichlorprop; 2,4,5-T = (2,4,5-trichlorophenoxy)acetic acid; "<" = less than; less-than values were set equal to zero for calculations]
Parametercode
820523973082183
397603972039740
Constituent
Dicamba2,4-D2,4-DP
FenopropPicloram2,4,5-T
Concentration,Replicate 1(not spiked)
A
3020
<10
<10<10<10
, in nanogramsReplicate 2(not spiked)
B
30120<10
<10<10<10
per liter
Difference|A - B|
0100
0
000
Table 31E. Concentrations of chlorophenoxy-acid herbicides, dicamba, and picloram in replicate whole-water samples from Granger Drain at mouth near Granger, Washington, July 28, 1988, at 0930 hour and 1015 hour
[Station number 12505460; map reference number 36 figure 1; addition to analytical variability, the results include te
Para- meter code Constituent
Concentration, in nanograms per literRaplicate 1(not spiked)
A
Replicate 2(not spiked) Difference
B |A - B|
820523973082183
397603972039740
Dicamba2,4-D2,4-DP
Fenoprop Picloram 2,4,5-T
40 390 <10
<10 <10 <10
40 410 <10
<10 <10 <10
0200
000
102
Table 31F. Concentrations of chlorophenoxy-acid herbicides, dicamba, and picloram in replicate and spiked whole-water samples from Sulphur Creek Wasteway near Sunnyside, Washington, August 31, 1988, at 1530 hour and 1630 hour
[Station number 12508850; map reference number A6 figure 1; in eddition to analytical variability, the results include temporal variability, beceuse the samples were collected 1 hour apart; "ns" - not spiked; 2,4-D - (2,4-dichlorophenoxy)acetic acid; 2.A-DP - dichlorprop; 2,4,5-T - (2,4,5-trichlorophenoxy)acetic acid; "<" - less than; less-than velues were set equal to zero for calculations]
Concentrstion. in nanograma per literLaboratory results
Parameter code
820523973082183
397603972039740
Constituent
Dicamba2,4-D2,4-DP
FenopropPicloram2,4,5-T
Replicate 1(not spiked)
A
1050
<10
<10<10<10
Replicate 2(not spiked)
B
1060
<10
<10<10«10
Difference|A - B|
0100
000
Replicate 3(spiked)
C
20360<10
280<10220
Calculatedconcentrationin replicate(spiked)
D
ns680ns
510ns450
3 Recovery,in perccC x 100
ns53ns
55ns49
»nt/ D
Table 31G. Concentrations of chlorophenoxy-ecid herbicides, dicambe, and picloram in replicate end spiked whole-water samples from Buckskin Slough below Gleed Ditch near Gleed, Washington, May 22, 1991, et 1100 hour and 1107 hour
[Station number 12496550; map reference number 21 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 7 minutes apart; 2,4-0 - (2,4-dichlorophenoxy)acetic acid; 2,4,5-T - (2,4,5-trichlorophenoxy)acetic acid; "<" - less than; less-than values were set equal to zero for calculations]
Concentretion. in nanograms per liter Calculated
Para meter code Constituent
Laboratory resultsReplicate 1 (not spiked)
Replicate 2 (spiked)
concentretion Recovery, in replicate 2 in percent
x 100 / C
8205239730397603972039740
Dicamba2,4-DFenopropPicloram2,4,5-T
6090606060
110110110110110
5482545454
103
Tabl
e 32A.
Concentrations of Organochlorine and
Organophosphorus
compounds
in replicate whole-water samples
from Cle
Elum River
abov
e Cl
e Elum Lake near Ro
slyn
, Washington,
July 26,
1988
, at
1000 hour an
d 10
15 hour
[Station number 12
4783
00;
map reference number 3 figure 1;
in addition to
analytical variability,
the
results
include
temporal variability, because th
e samples
were co
llec
ted
15
minutes apart; ODD
= dichlorodiphenyldichloroethane; DD
E =
dichlorodiphenyldichloroethylene; DO
T =
dichlorodiphenyl-
tric
hlor
oeth
ane;
HCH = hexachlorocyclohexane; PCB
gross
polychlorinated biphenyls; PCN
= gross
polychlorinated
naphthalenes; "<"
= le
ss than;
less-than values we
re set
equa
l to
ze
ro fo
r ca
lcul
atio
ns]
Para
meter
code
Constituent
Concentration, in
nanograms
Replicate 1
Replicate 2
(not
spiked)
(not sp
iked
)A
B
per
liter
Difference
|A -
B|
Organochlorine compounds
39330
Aldrin
3935
0 gross
Chlordane
3936
0 p,p'-DDD
3936
5 p,p'-DDE
3937
0 p,p'-DDT
3938
0 Dieldrin
39388
Endosulfan I
39390
Endrin
39410
Heptachlor
3942
0 Heptachlor ep
oxid
e
39340
Lindane (gamma-HCH)
39480
p,p' -Methoxychlor
39755
Mirex
3951
6 PC
B39250
PCN
39034
Perthane
39400
Toxaphene
<1
<1<100
<100
<1
<1<1
<1<1
<1
<1
<1<1
<1
<1
<1<1
<1<1
<1
<1
<1<10
<10
<10
<10
<100
<100
<100
<1
00
<100
<1
00<1,000
<1,000
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Organophosphorus comp
ound
s
3957
0 Diazinon
39398
Ethion
39530
Malathion
39600
Methyl parathion
39790
Methyl trithion
39540
Parathion
3978
6 Trithion
<10
<10
<10
<10
<10
<10
<10
<10
<10
<10
<10
<10
<10
<10
0 0 0 0 0 0 0
Table
32B.
Concentrations of
Organochlorine and
Organophosphorus
comp
ound
s in replicate whole-water samples
from Cherry Creek at
Th
rall
, Washington, June 2, 1988,
at 14
00 hour an
d 14
05 hour
[Station number 12
4844
80;
map reference number 13 figure 1;
in addition to
analytical va
riab
ilit
y, th
e results
include
temporal variability, because the
samples
were co
llec
ted
5 minutes ap
art;
ODD
dichlorodiphenyldichloroethane; DD
E =
dichlorodiphenyldichloroethylene; DO
T =
dichlorodiphenyl-
trichloroethane; HCH = hexachlorocyclohexane; PCB
= gross
polychlorinated bi
phen
yls;
PCN
= gross
polychlorinated
naphthalenes; "<
" =
less
than;
less-than values we
re se
t equal
to zero for
calculations]
Para
meter
code
Concentration, in na
nogr
ams
Replicate 1
Replicate 2
(not
spiked)
(not sp
iked
)Constituent
A
B
per
liter
Difference
|A -
B|
Organochlorine co
mpou
nds
39330
3935
039
360
39365
39370
3938
039
388
39390
39410
3942
0
39340
39480
3975
539
516
39250
39034
39400
Aldrin
<1
<1gross
Chlordane
<100
<100
p,p'-DDD
<1
<1p,p'-DDE
1 1
p,p'-DDT
<1
<1
Dieldrin
3 3
Endosulfan I
<1
<1Endrin
<1
<1Heptachlor
<1
<1Heptachlor ep
oxid
e <1
<1
Lindane (gamma-HCH)
<1
<1p,p' -Methoxychlor
<10
<10
Mirex
<10
<10
PCB
<100
<100
PCN
<100
<100
Perthane
<100
<100
Toxaphene
<1,000
<1,000
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Organophosphorus co
mpou
nds
39570
39398
3953
039
600
39790
3954
039
786
Diazinon
<10
<10
Ethion
<10
<10
Malathion
<10
<10
Methyl parathion
<10
<10
Methyl trithion
<10
<10
Parathion
<10
<10
Trithion
<10
<10
0 0 0 0 0 0 0
Table
32C.
Conc
entr
atio
ns of
or
gano
chlo
rine
an
d Organophosphorus
comp
ound
s in
replicate whole-water
samp
les
from
Wide
Hollow Creek
near
mouth
at Union
Gap, Wa
shin
gton
, November 15
, 1988,
at 13
30
hour an
d 1430 ho
ur
[Sta
tion
nu
mber
12
5004
45;
map
reference nu
mber
27 figure 1;
in addition to
analytical variability,
the
resu
lts
incl
ude
temp
oral
variability,
beca
use
the
samp
les
were collected
1 ho
ur apart; ODD
~ dichlorodiphenyldi
chlo
roet
hane
; DD
E -
dich
loro
diph
enyl
dich
loro
ethy
lene
; DOT
di
chlo
rodi
phen
yl-
trichloroethane; HCH
hexachlorocyclohexane; PCB
» gross
polychlorinated
biphenyls; PCN
= gross
polychlorinated
naph
thal
enes
; "<"
- less than;
less
-tha
n values we
re se
t eq
ual
to ze
ro for
calc
ulat
ions
]
Table
32D.
Concentrations of
or
gano
chlo
rine
an
d Or
gano
phos
phor
us
comp
ound
s in replicate wh
ole-
wate
r sa
mple
s from Moxee Dr
ain
at
Thor
p Ro
ad near Union
Gap, Wa
shin
gton
, Ma
y 6,
19
88,
at 0930 ho
ur
and
0940 ho
ur
[Sta
tion
nu
mber
12
5004
30;
map
reference
number 24 figure 1;
in addition to
analytical variability,
the
resu
lts
incl
ude
temp
oral
variability,
beca
use
the
samp
les
were collected
10
minu
tes
apart; OD
D -
dich
loro
diph
enyl
dich
loro
etha
ne;
DDE
- di
chlo
rodi
phen
yldi
chlo
roet
hyle
ne;
DOT
di
chlo
rodi
phen
yl-
tric
hlor
oeth
ane;
HCH
» he
xach
loro
cycl
ohex
ane;
PC
B »
gross
polychlorinated
biphenyls; PCN
» gr
oss
polychlorinated
naphthalenes;
"<"
» less than;
less-than
values we
re set
equal
to ze
ro fo
r ca
lcul
atio
ns]
O
Cn
Concentration, in
nan
ogra
msPara
meter
code
Cons
titu
ent
Repl
icat
e 1
Repl
icat
e 2
(not
sp
iked
) (not sp
iked
) A
B
Orga
noch
lori
ne
39330
39350
39360
3936
5 39370
39380
3938
839
390
3941
0 39420
39340
39480
39755
39516
39250
39034
39400
Aldr
ingross
Chlo
rdan
e p,p'-DDD
p,p'
-DDE
p,p'-DDT
Diel
drin
Endo
sulf
an I
Endr
inHe
ptac
hlor
He
ptac
hlor
ep
oxid
e
Lind
ane
(gamma-HCH)
p,p' -Methoxychlor
Mire
xPCB
PCN
Pert
hane
Toxa
phen
e
<1<1
00 1 2 11 <1 <1 <i
o <i
o<1
00<1
00
<100
<1,000
Organophosphorus
39570
3939
839530
39600
39790
39540
3978
6
Diaz
inon
Ethi
onMalathion
Methyl pa
rath
ion
Methyl trithion
Para
thio
nTrithion
<10
<10
<10 <iS <10
<10
compounds
<1<100
1 2 13 <1 <} <s<100
<100
<100
<1,0
00
comp
ound
s
<10
<10
<10
<10
<io
<io
per
liter
Difference
|A -
B|
0 0 0 0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Para
me
ter
code
Cons
titu
ent
Conc
entr
atio
n ,
Repl
icat
e 1
(not sp
iked
)A
. in
nan
ogra
msReplicate
2(not sp
iked
)B
per
liter
Diff
eren
ce~TS
- B|
Orga
noch
lori
ne co
mpou
nds
39330
39350
39360
39365
3937
0
3938
039
388
39390
39410
3942
0
3934
039
480
39755
3951
639
250
39034
39400
Aldrin
gros
s Ch
lord
ane
p,p'
-DDD
p,p' -DDE
p,p' -DOT
Diel
drin
Endosulfan I
Endr
inHe
ptac
hlor
Hept
achl
or ep
oxid
e
Lind
ane
(gamma-HCH)
p , p ' -Methoxychlor
Mirex
PCB
PCN
Pert
hane
Toxa
phen
e
<1<1
001 4 4 1 16 <1 <1 <1 <1 <10
<10
<100
<100
<100
<1,000
<1<1
00 <14 4 1
30 <1 <1 <1 <1 <10
<10
<100
<100
<100
<1,000
0 0 1 0 0 0 14 0 0 0 0 0 0 0 0 0 0
Organophosphorus co
mpou
nds
38932
39570
3939
839530
39600
39790
3954
039786
Chloryrifos
Diaz
inon
Ethi
onMa
lath
ion
Methyl pa
rath
ion
Methyl trithion
Para
thio
nTr
ithi
on
10<1
0<1
0<1
0<1
0
<10
<10
<10
10<1
0<1
0<1
0<1
0
<10
<10
<10
0 0 0 0 0 0 0 0
Table 32E.
Concentrations of
Organochlorine and
Organophosphorus
compounds
in replicate whole-water samples
from Granger Drain at
mouth near Gr
ange
r, Wa
shin
gton
, Ju
ly 28
, 19
88,
at 09
30 ho
ur and
1015
hour
[Station number 12505460;
map reference number 36 figure 1;
in addition to
analytical variability,
the
resu
lts
include
temporal variability, because th
e samples
were collected 45
minutes ap
art;
DDD
» dichlorodiphenyldichloroethane; DDE "
dichlorodiphenyldichloroethylene; DDT - dichlorodiphenyl-
trichloroethane; HCH * hexachlorocyclohexane; PCB
= gross
polychlorinated biphenyls; PCN
= gr
oss
polychlorinated
naphthalenes; "<"
« le
ss th
an;
less-than values were set
equal
to ze
ro for
calculations]
Para
meter
code
Constituent
Concentration ,
Replicate 1
(not spiked)
X
. in
nan
ogra
msReplicate 2
(not spiked)
5
per
liter
Difference
|A -
B|
Organochlorine co
mpou
nds
39330
39350
39360
39365
3937
0
39380
3938
839390
39410
39420
39340
39480
3975
53951
639250
39034
39400
Aldrin
gross
Chlordane
p,p'-DDD
p.p'-DDE
p.p'-DDT
Dieldrin
Endosulfan I
Endrin
Heptachlor
Heptachlor epoxide
Lindane (gamma-HCH)
p , p ' -Methoxychlor
Mirex
PCS
PCN
Perthane
Toxaphene
<1<1007
53 43 30 76 <1 <1 <1 <1<10
<10
<100
<100
<100
<1,000
<1<100 10 47 39 17 83 <1 <1 <1 <1
<10
<10
<100
<100
<100
<1,000
0 0 3 6 4 13 7 0 0 0 0 0 0 0 0 0 0
Organophosphorus co
mpou
nds
39570
3939
839530
39600
39790
39540
3978
6
Diazinon
Ethion
Malathion
Methyl parathion
Methyl trithion
Parathion
Trithion
20<10
<10
<10
<10
<10
<10
10<10
<10
<10
<10
<10
<10
10 0 0 0 0 0 0
Table
32F.
Concentrations of
Organochlorine an
d Organophosphorus
comp
ound
s in
replicate an
d sp
iked
whole-water samples
from Sulphur
Creek Wasteway near Su
nnys
ide,
Washington,
August 31,
1988
, at 15
30
hour and
1630
hour I/
[Station number 12
5088
50;
map reference number 46 figure 1; in
addition
to analytical variability, th
e results
incl
ude
temporal variability,
because the
samples
were co
llec
ted
1 hour ap
art;
DD
D =
dichloro-
diphenyl- dichloroethane; DD
E =
dichlorodiphenyldichloroethylene;
DDT
= dichlorodiphenyltrichloroethane; HCH = hexachlorocyclohexane;
PCS
= gross
polychlorinated bip
heny
ls;
PCN
= gross
polychlorinated
naphthalenes; "<"
= le
ss th
an;
less-than values were se
t equal
to
zero for
calc
ulat
ions
]
Para
meter
code
Constituent
Concentration
Replicate 1
(not sp
iked
)A
, in
nanograms
Replicate 2
(not
spiked)
B
per
liter
Difference
|A-
B|
Organochlorine co
mpou
nds
39330
39350
39360
3936
5 39370
39380
39388
39390
39410
39420
39340
39480
3975
539
516
39250
3903
439400
Aldrin
gross
Chlordane
p,p'-DDD
p,p'-DDE
p.p'-DDT
Dieldrin
Endosulfan I
Endrin
Heptachlor
Heptachlor epoxide
Lindane (gamma-HCH)
p , p ' -Methoxychlor
Mirex
PCS
PCN
Perthane
Toxaphene
<1<100 1 7 6 6 11
<1 <1
<1 <1
<10
<10
<100
<100
<100
<1,0
00
<1<1
001 7 5 6 5
<1 <1
<1 <1
<10
<10
<100
<100
<100
<1,000
0 0 0 0 1 0 6 0 0 0 0 0 0 0 0 0 0
Organophosphorus co
mpou
nds
3957
039398
39530
39600
39790
39540
3978
6
Diazinon
Ethion
Malathion
Methyl parathion
Methyl trithion
Parathion
Trithion
10<1
0<10
<10
<10
<10
<10
<10
<10
<10
<10
<10
<10
<10
10 0 0 0 0 0 0
I/ A third replicate of this sa
mple
wa
s collected at 16
00 hour,
and
it was
spiked with Organochlorine co
mpou
nds,
including
4,60
0 nanograms pe
r liter
(ng/
L) of
to
xaph
ene.
Th
e laboratory reported
4,000
ng/L.
The
othe
r Organochlorine co
mpou
nds
could
not
be
quantified because of analytical interference,
possibly associated
with th
e relatively la
rge
toxa
phen
e sp
ike
(Fra
nk W. Wi
ebe,
U.S.
Geological Su
rvey
, Ar
vada
, Colorado,
written commun., December 19
91).
Table 32G. Concentrations of organochlorine and organophosphorus confounds in replicate whole-water samples from a well (station identifier: 12N/19E-09H01), Washington, January 20, 1989, at 0730 hour and 0737 hour
[Station number 463234120261601; map reference number 59 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 7 minutes apart; DDD « dichlorodiphenyldichloroethane; DDE - dichlorodiphenyldichloroethylene; DDT « dichlorodiphenyl- trichloroethane; HCH « hexachlorocyclohexane; PCB * gross polychlorinated biphenyls; PCN * gross polychlorinated naphthalenes; "<" = less than; less-than values were set equal to zero for calculations]
Para meter code Constituent
Concentration, in nanoKrams per liter Replicate 1Replicate 2 (not spiked) (not spiked) Difference
A SLfferenci |A - B|
Organochlorine compounds
3933039350393603936539370
Aldringross Chlordanep,p'-DDDp.p'-DDEp,p'-DDT
<1 <1 0<100 <100 0
<1 <1 0<1 <1 0<1 <1 0
39380 Dieldrin39388 Endosulfan I39390 Endrin39410 Heptachlor39420 Heptachlor epoxide
39340 Lindane (ganxna-HCH)39480 p,p'-Methoxychlor39755 Mirex39516 PCB39250 PCN
39034 Perthane39400 Toxaphene
<100 <100
<100 <1,000
<100 <100
<100 <1,000
Organophosphorus compounds
39570 Diazinon39398 Ethion39530 Malathion39600 Methyl parathion39790 Methyl trithion
39540 Parathion39786 Trithion
107
Table 33A. Concentrations of phenols and cresols (acid-extractable compounds) in replicate whole-water samples from Wide Hollow Creek near mouth at Union Gap, Washington, November 15, 1988, at 1330 hour and 1430 hour
[Station number 12500445; map reference number 27 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 1 hour apart; "<" ~ less than; less-than values were set equal to zero for calculations]
Para meter code
34586 34601 34606
34657 34616 34591
34646 34452 39032
34694 34621
Constituent
2-Chlorophenol 2 , 4-Dichlorophenol 2 , 4-Dimethylphenol
4 , 6-Dinitro-o-cresol 2, 4-Dinitrophenol 2-Hitrophenol
4-Hitrophenol P-chloro-m-cresol Pentachlorophenol
Phenol 2,4, 6-Trichlorophenol
ConcentrationReplicate 1 (not spiked)
A
<5,000 <5,000 <5,000
<30,000 <20,000 <5,000
<30,000 <30,000 <30,000
<5,000 <20,000
. in nanogramsReplicate 2 (not spiked)
B
<5,000 <5,000 <5,000
<30,000 <20,000 <5,000
<30,000 <30,000 <30,000
<5,000 <20,000
per liter
Difference|A - B|
0 0 0
0 0 0
0 0 0
0 0
Table 33B. Concentrations of phenols and cresols (acid-extractable compounds) in replicate and spiked whole-water samples from Sulphur Creek Wasteway near Sunnyside, Washington, August 31, 1988, at 1530 hour and 1630 hour
[Station number 12508850; map reference number 46 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 1 hour apart; "<" = less than; less-than values were set equal to zero for calculations]
Concentrations. in nanograms per liter
Laboratory resultsPara meter code
34586 34601 34606
34657 34616 34591
34646 34452 39032
34694 34621
Constituent
2-Chlorophenol 2 , 4-Dichlorophenol 2 , 4-Dimethylphenol
4 , 6-Dinitro-o-cresol 2, 4-Dinitrophenol 2-Nitrophenol
4-Hitrophenol P-chloro-m-cresol Pentachlorophenol
Phenol 2,4, 6-Trichlorophenol
Replicate 1 Replicate 2 (not spiked) (not spiked) Difference
A B |A - B|
<5,000 <5,000 <5,000
<30,000 <20,000 <5,000
<30,000 <30,000 <30,000
<5,000 <20,000
<5,000 <5,000 <5,000
<30,000 <20,000 <5,000
<30,000 <30,000 <30,000
<5,000 <20,000
0 0 0
0 0 0
0 0 0
0 0
Replicate 3 (spiked)
C
21,000 27,000 22,000
230,000 93,000 30,000
73,000 130,000 170,000
<5,000 100,000
Calculated concentration in replicate 3 Recovery, (spiked) in percent
D
29,000 29,000 29,000
144,000 86,000 29,000
144,000 144,000 144,000
29,000 86,000
C x 100 / D
7293 76
160 110 100
51 90
120
<17 120
108
Table 34A. Concentrations of txiazine, acetamide, chloroacetanilide, and other pesticides in spiked whole-water samples from Cle Elum River above Cle Elum Lake near Roslyn, Washington, July 26, 1988, at 0930 hour and 1000 hour
[Station number 12478300; map reference number 3 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 30 minutes apart; "<" - less than; less-than values were set equal to zero for calculations]
Concentrations, in nanograms per literLaboratory results
Parametercode
778253963082612
826113905539030
Constituent
AlachlorAtrazineMetolachlor
MetribuzinSimazineTrifluralin
Replicate 1(not spiked)
A
<100<100<100
<100<100<100
CalculatedReplicate 2 concentration(spiked)
B
520330500
470350430
in replicate 2C
480340420
420350490
Recovery,in percentB x 100
11097
120
11010088
/ c
Table 34B. Concentrations of triazine, acetamide, chloroacetanilide, and other pesticides in replicate whole-water samples from Cherry Creek at Thrall, Washington, June 2, 1988, at 1400 hour and 1405 hour
[Station number 12484480; map reference number 13 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 5 minutes apart; "<" = less than; less-than values were set equal to zero for calculations]
Para meter code
7782582184396303023430235
3023630245817573025430255
3026482612826113905639057
3029539024390553905430311
3903030324
Constituent
AlachlorAmetrynAtrazineBromacilButachlor
ButylateCarboxinCyanazineCycloateDiphenamid
HexazinoneMetolachlorMetribuzinPrometonePrometryn
PropachlorPropazineSimazineSimetrynTerbacil
TrifluralinVernolate
ConcentrationReplicate 1 (not spiked)
A
<100<100
20<100<100
<100<100<100<100<100
<100<100<100<100<100
<100<100<100<100<100
<100<100
, in nanoKramsReplicate 2 (not spiked)
B
<100<100
60<100<100
<100<100<100<100<100
<100<100<100<100<100
<100<100
40<100<100
<100<100
per liter
Difference |A - B|
00
4000
00000
00000
00
4000
00
109
Table SAC. Concentrations of triazine, acetamide, chloroacetanilide, and other pesticides in replicate whole-water samples from Wide Hollow Creek near mouth at Union Gap, Washington, November 15, 1988, at 1330 hour and 1430 hour
[Station number 125004A5; map reference number 27 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 1 hour apart; "<" = less than; less-than values were set equal to zero for calculations]
Para meter code
7782582184396303023A30235
30236302A5817573025A30255
3026482612826113905639057
302953902A390553905A30311
390303032A
Constituent
AlachlorAmetrynAtrazineBromacilButachlor
ButylateCarboxinCyanazineCycloateDiphenamid
HexazinoneMetolachlorMetribuzinPrometonePrometryn
PropachlorPropazineSimazineSimetrynTerbacil
TrifluralinVernolate
ConcentrationReplicate 1 (not spiked)
A
<100<100<100<100<100
<100<100<100<100<100
<100<100<100<100<100
<100<100<100<100<100
<100<100
. in nanogramsReplicate 2 (not spiked)
B
<100<100<100<100<100
<100<100<100<100<100
<100<100<100<100<100
<100<100<100<100<100
<100<100
per liter
Difference|A
00000
00000
00000
00000
00
- B|
Table 34D. Concentrations of triazine, acetamide, chloroacetanilide, and other pesticides in replicate whole-water samples from Moxee Drain at Thorp Road near Union Gap, Washington, May 6, 1988, at 0930 hour and 09AO hour
[Station number 12500A30; map reference number 2A figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 10 minutes apart; "<" = less than; less-than values were set equal to zero for calculations]
Para meter code
778258218A396303023430235
30236302A5817573025A30255
3026A82612826113905639057
3029539024390553905430311
3903030324
Constituent
AlachlorAmetrynAtrazineBromacilButachlor
ButylateCarboxinCyanazineCycloateDiphenamid
HexazinoneMetolachlorMetribuzinPrometonePrometryn
PropachlorPropazineSimazineSimetrynTerbacil
TrifluralinVernolate
ConcentrationReplicate 1 (not spiked)
A
<100<100
30<100<100
<100<100<100<100<100
<100<100<100<100<100
<100<100
20<100<100
<100<100
. in nanogramsReplicate 2 (not spiked)
B
<100<100
30<100<100
<100<100<100<100<100
<100<100<100<100<100
<100<100
20<100<100
<100<100
per liter
Difference |A - B|
00000
00000
00000
00000
00
110
Table 34E. Concentrations of triazine, acetamide, chloroacetanilide, and other pesticides in spiked whole-water samples from Granger Drain at mouth near Granger, Washington, July 28, 1988, at 0930 hour and 1015 hour
[Station number 12505460; map reference number 36 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 45 minutes apart; "<" = less than; less-than values were set equal to zero for calculations]
Concentrations, in nanograms tier literLaboratory results
Para meter code
77825 39630 82612
Constituent
Alachlor Atrazine Metolachlor
Replicate 1 (not spiked)
A
<100 47
<100
Replicate 2 (spiked)
B
570 430 570
Calculated concentration in replicate 2
C
570 410 510
Recovery, in percentB x 100 / C
100 100 110
82611 Metribuzin <10039055 Simazine 10439030 Trifluralin 42
530500510
500420580
11012088
Table 34F. Concentrations of triazine, acetamide, chloroacetanilide, and other pesticides in replicate and spiked whole-water samples from Sulphur Creek Wasteway near Sunnyside, Washington, August 31, 1988, at 1530 hour and 1630 hour
[Station number 12508850; map reference number 46 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 1 hour apart; "ns" = not spiked; "<" = less than; less-than values were set equal to zero for calculations]
Concentrations in nanograms
Laboratory resultsParametercode
7782582184396303023430235
3023630245817573025430255
3026482612826113905639057
3029539024390553905430311
3903030324
Replicate 1 Replicate 2
per literCalculated concentration
Replicate 3 in replicate 3 Recovery,(not spiked) (not spiked) Difference
Constituent
AlachlorAmetrynAtrazineBromacilButachlor
ButylateCarboxinCyanazineCycloateDiphenamid
HexazinoneMetolachlorMetribuzinPrometonePrometryn
PropachlorPropazineSimazineSimetrynTerbacil
TrifluralinVernolate
A
<100<100
34<100<100
<100<100<100<100<100
<100<100<100<100<100
<100<100
29<100<100
<100<100
B
<100<100
34<100<100
<100<100<100<100<100
<100<100<100<100<100
<100<100
24<100<100
<100<100
|A - B|
00000
00000
00000
00500
00
(spiked) (spiked)C
530ns440nsns
nsnsnsnsns
ns530610nsns
nsns310nsns
470ns
D
670ns510nsns
nsnsnsnsns
ns600590nsns
nsns530nsns
690ns
in percentC x 100 / D
79ns86nsns
nsnsnsnsns
ns88
100nsns
nsns58nsns
68ns
111
Table 35A. Concentrations of volatile organic compounds in replicate whole-water samples from Wide Hollow Creek near mouth at Union Gap, Washington, November 15, 1988, at 1330 hour and 1430 hour
[Station number 12500445; map reference number 27 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 1 hour apart; "<" = less than; less-than values were set equal to zero for calculations]
Concentration, in nanograms per literPara meter code
3403081555321013210434413
3210234301343113210634418
7727577277347043210577651
3021734536345663457134668
3449632103345014561734541
7717377170771683437134423
7712877562345163447534010
3454634699345063451139180
34488774433917581551
Replicate 1 Replicate 2 (not spiked) (not spiked) Difference
Constituent
BenzeneBromobenzeneBromodi chlorome thaneBromoformBromome thane
Carbon tetrachlorideChlorobenzeneChloroethaneChloroformChlorome thane
1 , 2-Chlorotoluene1, 4-Chlorotoluenecis-1, 3-DichloropropeneDibromochlorome thane1 , 2-Dibromoethane
D ib r omome th an e1 , 2-Dichlorobenzene1, 3-Dichlorobenzene1, 4-DichlorobenzeneDichlorodifluorome thane
1, 1-Dichloroethane1 , 2-Dichloroethane1, 1-Dichloroethene1 , 2-Dichloroethene1, 2-Dichloropropane
1, 3-Dichloropropane2, 2-Dichloropropane1, 1-DichloropropeneEthylbenzeneMethylene chloride
Styrene1,1,1, 2-Tetrachloroethane1,1,2, 2-TetrachloroethaneTetrachloroetheneToluene
trans-1, 2-Dichloroethenetrans-1, 3-Dichloropropene1,1, 1-Tri chloroethane1,1, 2-TrichloroethaneTrichloroethene
Trichlorofluorome thane1,2,3-TrichloropropaneVinyl chlorideXylene
A
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200
B
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200
|A - B|
00000
00000
00000
00000
00000
00000
00000
00000
0000
112
Table 3SB. Concentrations of volatile organic compounds in replicate and spiked whole-water samples from Sulphur Creek Wasteway near Sunnyside, Washington, August 31, 1988, at 1530 hour and 1630 hour
[Station number 12508850; map reference number 46 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 1 hour apart; "ns" = not spiked; "<" = less than; less-than values were set equal to zero for calculations]
Concentrations, in nanograms per liter
Laboratory resultsPara meter code
3403081555321013210434413
3210234301343113210634418
7727577277347043210577651
3021734536345663457134668
34496321033450145617
3454177173771707716834371
3442377128775623451634475
3401034546346993450634511
3918034488774433917581551
Replicate 1 Replicate 2 (not spiked) (not spiked) Difference
Constituent A B |A - B|
BenzeneBromobenzeneBromodi chlor omethaneBromoformBromomethane
Carbon tetrachlorideChlorobenzeneChloroethaneChloroformChloromethane
1 , 2-Chlorotoluene1 , 4-Chlorotoluenecis-1 , 3-DichloropropeneDibromochloromethane1 , 2-Dibromoethane
Dibromomethane1 , 2-Dichlorobenzene1 , 3-Dichlorobenzene1 , 4-DichlorobenzeneDi chlor odi fluoromethane
1 , 1-Dichloroethane1,2-Di chloroethane1, 1-Dichloroethene1 , 2-Dichloroethene
1, 2-Dichloropropane1, 3-Dichloropropane2, 2-Dichloropropane1, 1-DichloropropeneEthylbenzene
Methylene chlorideStyrene1, 1, 1, 2-Tetrachloroethane1,1,2, 2-TetrachloroethaneTetrachloroethene
Toluenetrans-1, 2-Dichloroethenetrans-1 , 3-Dichloropropene1,1, 1-Tri chloroethane1, 1,2-Tri chloroethane
TrichloroetheneTrichlorofluoromethane1,2,3 -Tr i chlor opropaneVinyl chlorideXylene
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
<200<200<200<200<200
00000
00000
00000
00000
0000
00000
00000
00000
00000
Replicate 3 (spiked)
C
3,200<2002,4002,6001,300
3,6003,4001,4004,9001,100
<200<200<2001,300<200
<200<200<200<200<200
9,2003,9006,700<200
2,400<200<200<200
3, £00
7,300<200<2002,7002,500
2,600<200<2003,6002,700
2,5004,600<2001,300<200
Calculated concentration in replicate (spiked)
D
5,000ns
5,0005,0005,000
5,0005,0005,0005,0005,000
nsnsns
5,000ns
nsnsnsnsns
5,0005,0005,000
ns
5,000nsnsns
5,000
5,000nsns
5,0005,000
5,000nsns
5,0005,000
5,0005,000
ns5,000
ns
3 Recovery, in percentC x 100 / D
64ns485226
7268289822
nsnsns26ns
nsnsnsnsns
18078
130ns
48nsnsns72
150nsns5450
52nsns7254
5092ns26ns
113
Tabl
e 36.
Conc
entr
atio
ns o
f pesticides i
n fi
lter
ed w
ater
(u
sing
the G
oulden la
rge-
samp
le e
xtra
ctor
), as
soci
ated
wit
h su
spen
ded
sediment
(analysis
of a
la
rge
sample o
f de-watered s
edim
ent
on a
glass-fiber f
ilter),
and
in w
hole w
ater
(conventional
anal
ysis
of
a 1- lit
er
sample o
f a
sedi
ment
-wa
ter
mixt
ure)
, Ya
kima
River b
asin,
Washington,
June 2
5-30,
1989
s in
nanograms p
er liter; see
figu
re 1
for
site
locations; "F"
= fi
lter
ed w
ater;
"S"
= su
spen
ded
sedi
ment
; "W
" = whole
wate
r;t,
but
belo
w qu
anti
fiab
le c
oncentration:
'- '
=
not
analyzed:
"nd" =
not
dete
cted
; "D
" = de
tect
ed a
nd n
ot q
uantified;
is o
f cis- plus t
rans-chlordane;
"<"
= less th
an;
ODD
= dichlorodiphenyldichloro
ethane;
DDE
= dichlorodiphenyldichloroethylene;
DOT
= di
chlo
rodi
phen
yltr
ichl
oroe
than
e; HCB
= he
xach
loro
benz
ene;
HCH
= hexachlorocyclohexane:
mi
nimu
m re
port
ing
leve
ls w
ere
smaller
for
filtered a
nd s
uspe
nded
ana
lyse
s, because
analytical sa
mple
vol
umes
wer
e large
rang
ing
from
4.4
to
34.5
liters fo
r di
ssol
ved
samp
les
and
from
[Con
cent
rati
ons
"T"
= pr
esen
t "g
" =
analysis
41.8
to
83.9
li
ters
for
sus
pend
ed s
ampl
es]
Organochlo
rine c
ompo
unds
Map
refe
renc
e St
atio
n nu
mber
number
Stat
ion
name
14 24 36 46 51
1248
4500
Yakima R
iver
at
Umtanum
12500430
Moxe
e Dr
ain
at T
horp
Rd
1250
5460
Gr
ange
r Dr
ain
at m
outh
1250
8850
Su
lphu
r Creek
Uast
eway
1251
0500
Yakima R
iver
at
Kion
a
Samp
le
medi
a Al
drin
F S U F S U F S U F S U F S U
T<0.69
<.6
<1 <3.5 <.01
<1 <3.2 .0
9<1 <15 <.
05<1 T<69 <.
01<1
cis-
trans-
Chlo
rdan
e Ch
lord
ane
p,p'
-DDD
T<0.
63<0.4
g<100 <1 8
T<!03
g<10
0 <1 6 !os
g<100 T<!3
g<10
0 <.63
<.04
g<10
0
T<0.
70<.04
<1 6
T<!0
3
<1 5 !09
<3.8
T<.3 <.
70<.04
T<1.
6 .05
<1 3.0
1.6
<1 T<2.
76.
4<1 9.
41.
7<1
1.4
.17
<1
Endo
sul
p,p'
-DDE
p,
p'-D
DT
Diel
drin
fa
n I
T<0.
41 .12
<1 5.6
7.1
21
.96
28 50 15 6.4
21
1.2
9.6
<1
0.26
<1 6.3
9.6
21 T<8.9
38 60 14 7.8
30
1.6
.2<1
0.93 .04
<1 T<3.4 .86
<1 T<3.1
3.6
<1 35 2.1
<1
3.6
.08
<1
0.82
<.04
<1 11.6
9<1 T<1.
4<.02
6.8
<.06
<1
1.2
<.04
<1
En
dosu
l-
fan
II
<0.81
<.07
5.2
<.06
<3.0
<2.0 -
<7.6 <.1 <.81
<.08 --
Orga
noch
lori
ne c
ompo
unds
Station
numb
er
Stat
ion
name
Samp
le
media
gamma-
Hepta-
alpha-
HCH
chlo
r o.
p'me
th-
p.p'
meth
-En
drin
HCB
HCH
(lindane)
epoxide
oxyc
hlor
oxychlor
Mi rex
Perthane
1248
4500
Yakima
Rive
r at U
mtan
um
F S U
1.5
<.04
<1
<0.56
<.07 --
<1 9
<!04 --
<2.6 <.04
<1
T<1.
2<.
04<1
<4.8 <-04
T<1.4
<1.4
<0.0
4<1
0 <1
< 2
0 <1
00
12500430
Mox
ee D
rain
at
Thorp
Rd
12505460
Gra
nger
Dra
in a
t mouth
1250
8850
Sul
phur
Creek U
asteway
1251
0500
Yakima
Rive
r at K
iona
<6.8
<.03 .31
<35 <.
06
<.56
<.
04
1.1
:.01
T<.99
.33
<2.4
.08
T<.56
.16
<3.9
T<.0
3
<3.5 .0
2
<.06
<.04
<2.6
<.
03
T<2.3 .06
<.06
<2.6 <.04
<2.5
T<.03
<2.3 .1
5
<8.9
<.
06
<.04
<.03
<9.0
3.4
<.06
<4.8
<.04
<.03
10 10
.32
10 <.06
10 <.
04
<.03
<.04
<.06
<.04
<3.2
<100 T<2.8
<100 <20
<100
<100
Tabl
e 36
. Co
ncen
trat
ions
of
pesticides in filtered w
ater
(u
sing
the
Goul
den
larg
e-sa
mple
extractor),
asso
ciat
ed w
ith
suspended
sedi
ment
(a
naly
sis
of a
larg
e sample o
f de-watered
sediment
on a
glass-fiber
filt
er),
an
d in w
hole
wat
er (c
onve
ntio
nal
analysis of a
1-li
ter
sample o
f a
sediment-water m
ixtu
re),
Yakima R
iver
basin, Wa
shin
gton
, Ju
ne 2
5-30
, 1989--Continued
Stat
ion
number
12484500
12500430
1250
5460
12508850
12510500
Station
number
12484500
12500430
1250
5460
1250
8850
12510500
Station
name
Yakima R
iver
at Umtanum
Moxe
e Dr
ain
at Th
orp
Rd
Granger
Drai
n at
mouth
Sulphur
Cree
k Ua
stew
ay
Yakima R
iver
at
Kiona
Station
name
Yakima R
iver
at Umtanum
Moxe
e Drain
at Thorp
Rd
Granger
Drai
n at m
outh
Sulphur
Creek
Uasteway
Yakima R
iver
at Ki
ona
Samt
medi F S U F S U F S U F S U F S U
ne ia
Sample
medi
a
F S U F S U F S U F S U F S U
Azinpnos-
meth
yl
nd D nd ;; nd
cnior-
pyrifos
T<2.
4 <.06
T<6.7 .48
T<6.
0
<26.16
9.6
T<.06
Organophosphorus
Demeton-S
Diazinon
<2.4
T<
2.0
<.06
T<7.9
406 3.
3 370
compounds
Dime
tho-
at
e <3.7
<13..
<7.1
11
T<12
1.9
10
T<34
66 .1
8 20
<2.4
39
.07
30
Disulfo-
ton
<2.4
<.06
<7.6
<.05
T<6.9
<.08
328
T<27
<3.7
<2.4
<.06
Ethion
T<3.
9 <.
06
r<11 .5
2
T<.08
<42
T<3.
9 <.
06
Fonofos
<2.0
<.
06
<7.0
<.
05
<6.3
<
.08
<1<.
1
<2.0
<.
06
Organophosphorus
co
mpou
nds
Meth
ida-
Methyl
Meth
yl
Ma lath ion
thio
n pa
rath ion
trit
nion
T<3.9
<.06
< <.
05
T<9.9
<.08
T<44
10'
70 <-06
4.
<1?. <9.
<40 <3.
9 T<
4.1
T<3.8
<.06
<-06
<.05
<.
05
<.08
<.
08
<10
<10
<11
<40
0 <4.1
<3.8
<-06
<-06
Mevinphos
<3.2
<9.5
T<8.
6
<34 <3.2
Para
thio
n Ph
orat
e
T<3.
2 <.06 .14
<.08
<42 .1
0
T<3.
2 T<
.06
10
<2.8
<.
06
130 1.
4 90 <8
.0
<.08
T<40 T<2.
8 <.
06
Phos
pham
- idon T<6.
5
43 56
T<37 5.
3
Tri thion
<3.6
<.06
<9.4
<.
05
<8.5
<.08
<42 <3.6
<.06
Table
36.
Conc
entr
atio
ns o
f pe
stic
ides
in
filtered
wate
r (using th
e Go
ulde
n large-sample
ext
ract
or),
associated w
ith
susp
ende
d se
dime
nt (analysis
of a
larg
e sa
mple
of
de-w
ater
ed s
edim
ent
on a
glass-fiber f
ilter),
and
in w
hole w
ater
(conventional
analysis o
f a
1-liter
sample o
f a
sedi
ment
-wat
er m
ixtu
re),
Ya
kima
Riv
er b
asin,
Washington,
June
25-
30,
1989
--Co
ntin
ued
Statio
n nu
mber
Stat
ion
name
12484500 Y
akima
River
at U
mtan
um
12500430 M
oxee D
rain A
t Th
orp
Rd
1250
5460 G
rang
er D
rain
at
mouth
1250
8850 S
ulph
ur C
reek
Uas
tewa
y
12510500 Y
akima
River
at K
iona
Sample
medi
a
F U F U F U F U F U
Tria
zine
. acet am
ide, uracil.
chlo
roac
etan
ilid
e. th
iocarbamate. an
d an
ilid
e compo
j Ala-
chlor
<1.6
<1
00 <4.0
<100 33
<100 33
<100 12
<1
00
Atra
- Ametryn
zine
nd
<100 nd
<1
00 nd
<100 nd
<1
00 nd
<100
10
<100 8.
5 10 48
90 49
22 32<1
00
V
unds
Broma-
Buta
- car-
Cyan
a-
cyci
o-
Dipn
en-
cil
chlor
Butylate
bo
x in
zi
ne
ate
amid
nd
<100 nd
<100 13
<1
00 T <100 nd
<100
nd
<100 nd
<1
00 nd
<100 nd
<100 nd
<1
00
nd
<100 nd
<1
00 nd
<100 nd
<1
00 nd
<100
<1.7
<100
<1
00
<100
<3.7
<100
<1
00
<100
8.6
<100
<100
<100
T<31
<100
<100
<1
00
<6.5
<1
00
<100
<100
<100
<100
<100
<100
<100
Statio
n nu
mber
Stat
ion
name
1248
4500 Y
akima
River
at U
mtanum
1250
0430 M
oxee
Dra
in A
t Th
orp
Rd
1250
5460 G
rang
er D
rain a
t mouth
1250
8850 S
ulph
ur C
reek U
aste
way
1251
0500 Y
akima
River
at K
iona
Samp
le
medi
a
F U F U F W F U F U
Tria
zine
. acetamide.
Hexazi
none
<100
<100
<100
<100
<100
- Me
tola
- chlor
T<1.3
<100 <3
.1
<100 T<2.
8 <1
00
T<15
<100 1.
9 <1
00
Metn
- bu
z in
nd
<100 nd
<1
00 nd
<100
<100 T
<100
chlo
roac
etan
ilid
e. ur
acil
. trif luoromethyl.
thiocarbamate
Prome-
ton 1.
1 <100 <3
.1
<100 32 50 26
<100 3.
0 <100
Prome-
tryn nd
<100 nd
<100 nd
<1
00 nd
<100 nd
<1
00
Propa-
chlor
nd
<100 nd
<100 nd
<100 nd
<1
00 nd
<100
Prop
a-
sima-
sime-
zine
zi
ne
tryn
T<0.
39
2.2
nd
<100
<1
00
<100
<3.6
<3
.6
nd<100
<1
00
<100
<3.2
134
nd
<100
17
0 <1
00
<18
81
nd
<100
77
<100
.47
18
nd
<100
44
<100
Terba-
cil
<100
<100
<100
<100
<100
compounds"
Tntl
ur-
verno-
alin
late
T<3.
8 <1
00
T<14
<1
00 28
100
T<32
<100 T<3.8
<100
T <1
00 nd
<100 T
<100 nd
<1
00 nd
<100
I/ Suspended s
ediment
samp
les
were n
ot a
nalyzed.
Table 37. Concentrations of organic carbon in replicate suspended-sediment samples and in spiked filtered-water samples from Chandler Canal at Bunn Road at Prosser, Washington, May 22, 1991, at 1500 hour and 1507 hour
[Station number 12509499; map reference number 48 figure 1]
Concentration, in milligrams per liter
Constituent
Laboratory resultsReplicate 1 Replicate 2 (not spiked) (spiked)
A B
Calculated concentration in replicate 2
C
Recovery, in percentB x 100 / C
Dissolved organic carbon 2.2 3.7 3.1 120
Constituent
Concentration, in milligrams per literLaboratory results
Replicate 1 (not spiked)
A
Replicate 2 (spiked) Difference
|A - B|
Suspended organic carbon 0.7 0.6 0.1
Table 38. Concentration of organic carbon, suspended sediment, and turbidity in replicate water samples from Yakima River at Kiona, Washington, August 6, 1991, at 1150 hour and 1151 hour
[Station number 12510500; map reference number 51 figure 1; NTU = nephelometric turbidity units]
Para meter code
Concentration
Constituent
Replicate 1Replicate 2 (not spiked) (not spiked) Difference
A B | A - B |
00681 Dissolved organic carbon,in milligrams per liter 2.7
00689 Suspended organic carbon,in milligrams per liter 1.1
80154 Suspended sediment,in milligrams per liter 32
70331 Sediment, percent finer than0.062 millimeters 91
00076 Turbidity, in NTU 10
2.9
1.2
30
85
10
Table 39. Mean analytical recoveries using the Goulden large-sample extractor for extracting surrogate compounds from filtered-water samples, Yakima River basin, Washington, June 25-30, 1989
[One standard deviation of the mean is shown in parenthesis and is reported in percent; "$" includes field blanks]
Sample volume Numberextracted, ofin liters samples
______Mean analytical recoveries, in percentgamma-Hexachloro-
Diazinon cyclohexane d-10 d-6 Isodrin
Atrazined-5 Terbuthylazine
5.0 - 7.7$
4.4 - 12
34 - 37
72 - 113
All samples
13
14
17
11
55
81
93
87
69
84
(16)
(14)
(10)
(26)
(18)
59
61
62
65
62
(43)
(26)
(21)
(20)
(28)
18
18
45
27
28
(19)
(16)
(14)
(17)
(20)
84
91
76
47
76
(14)
(18)
(11)
(19)
(22)
84
88
80
63
79
(15)
(23)
(9)
(20)
(19)
117
Table 40. Analytical recoveries using the Goulden large-sample extractor for extracting spiked compounds from filtered-water samples, Yakima River basin, Washington, June 25-30, 1989
[See table 2 for map reference numbers and figure 1 for site locations; natural occurring concentrations of pesticides have been substracted out of reported recoveries; ODD = dichlorodiphenyldichloroethane; DDE = dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyltrichloroethane; HCB = hexachlorobenzene; HCH = hexachlorocyclohexane; DEF = S,S,S~tributyl phosphorotrithioate; EPIC = S-ethyl dipropylthiocarbamate; extracted sample volumes listed in parenthesis; L = liter; " " = not analyzed; "nq" = not quantified, because of analytical problems; "*" = surrogate spike; negative recoveries indicate that concentration detected in native water sample exceeded concentration in spiked sample negative recoveries occurred because actual concentrations in spiked samples were small and because laboratory precision at low concentrations is poor]
Recovery of spiked compound. in percentStation number
12508850 12505460 12508630 12500430 12510500Station name
Compounds
Organochlorine
Aldrincis-Chlordanetrans-Chlordanep,p'-DDDp,p'-DDE
p,p'-DDTp,p'-DDT d-8 *DieldrinEndosulfan IEndosulfan II
EndrinHCBalpha-HCHbeta-HCHdelta-HCH
gamma-HCH (lindane)ganma-HCH d-6 *HeptachlorHeptachlor epoxideIsodrin *
o , p ' -Methoxychlorp , p ' -MethoxychlorMi rexPerthane
Organophosphorus
Azinphos-methylChlorpyrifosDEFDemeton-SDiazinon
Diazinon d-10 *DimethoateDisulfotonEthionFonofos
IsofenphosMalathionMethidathionMethyl parathionMethyl trithion
MevinphosParathionPhoratePhosphamidonTerbufos
SulphurCreekWasteway(11.5 L)
4685793248
013407697
5845605986
575623
10733
14nq1162
1166599
-36
92198378
104
61127171
0149
1227616822116
GrangerDrain(12.3 L)
3060554261
-50
1387647
145235658--
5250136412
12nq1152
7176
10674
7858808197
971121527198
9062
12142095
SouthDrain(11.7 L)
3078735956
33
918767
92326970--
655214
11515
164
1658
92737950
8232697581
7872879285
878487
11068
MoxeeDrain(11.4 L)
4866623844
14
908762
94597175--
67652313545
135
1540
__896987
-32
8126765186
71680
591
8670824379
YakimaReplicate 1
(9.99 L)
2951478452
87
725953
__41766375
5774205115
18101855
6386723688
9735377186
9372758171
918470
10460
River at KionaReplicate 2
(9.51 L)
2243398145
109
655149
31646170
577319597
23141748
5281662972
9128296875
8963687765
7287637750
Replicate 3(10.3 L)
5355518855
109
755652
__35726779
6283207515
23142353
4485692881
9239277081
9364697465
808452
10749
Trithion 82 94 72 52 70 64 65
118
Table 40. Analytical recoveries using the Goulden large-sample extractor for extracting spiked compounds from filtered-water samples, Yakima River basin, Washington, June 25-30, 1989 Continued
Recovery of spiked compound. in percentStation number
12S088SO 12505460 12508630 12500430 12510500Station name
Compounds
Triazine
AmetrynAtrazineAtrazine d~5 *Cyanazine
MetribuzinFrometonPrometrynPropazine
SimazineSimetrynTerbuthylazine
Carbamate
CarbarylCarbofuranEPIC
Thiocarbamate
ButylateVernolate
Acetamide
AlachlorMetolachlor
Chloroacetanilide
ButachlorPropachlor
Conazole
Triadimefon
Pyrethoid
Flucythrinatecis-Permethrintrans-Permethrin
Sulfite
Propargite
Trifluoromethvl
Trifluralin
Uracil
Bromacil
Urea
Linuron
SulphurCreekWasteway(11.5 L)
82338557
92568690
-398276
523085
6284
5584
49110
71
1013335
-439
79
22
GrangerDrain(12.3 L)
64307357
70276572
-1126273
nq3858
3778
6277
6588
78
773537
114
0
11
--
SouthDrain(11.7 L)
8862
10166
7210492
107
2485106
nq3878
6177
8684
80102
92
47343
89
45
33
MoxeeDrain(11.4 L)
8892826
77978892
588785
nq2883
7985
8583
6794
92
392324
-57
76
36
--
YakimaReplicate 1
(9.99 L)
78948373
76808088
567882
472981
5379
7975
89102
84
654940
102
47
35
41
River at KionaReplicate 2
(9.51 L)
73787569
72767680
467174
423057
3860
7169
8286
78
594031
71
48
34
44
Replicate 3(10.3 L)
81988674
77848490
618284
403245
3251
7976
9093
86
624734
93
40
23
44
119
Table 40. Analytical recoveries using the Goulden large-sample extractor for extracting spiked compounds from filtered-water samples, Yakima River basin, Washington, June 25-30, 1989--Continued
Recovery of spiked compound,, in percentStation number
12510500 12484500 12496510 12507594Station name
Compounds
Organochlorine
Aldrincis-Chlordanetrans-Chlordanep,p'-DDDp,p'-DDE
p,p'-DDTp,p'-DDT d-8 *DieldrinEndosulfan IEndosulfan II
EndrinHCBalpha-HCHbeta-HCHdelta-HCH
gamma-HCH (lindane)gamma-HCH d-6 *HeptachlorHeptachlor epoxideIsodrin *
o , p ' -Methoxychlorp , p ' -MethoxychlorMirexPerthane
Organophosphorus
ChlorpyrifosDEFDemeton-SDiazinonDiazinon d-10 *
DimethoateDisulfotonEthionFonophosIsofenphos
MalathionMethidathionMethyl parathionMethyl trithion
MevinphosParathionPhoratePhosphamidonTerbufos
Yakima Riverat Kiona(35.7 L)
901561525157
295
105nq59
14810492
101116
905760
13080
25nq1886
86741027792
2388778766
-96111176116
94nq11914679
Yakima Riverat Umtanum(35.7 L)
49101985359
2944
1059963
196568985
143
9710360
11766
39nq2160
9751
1018892
3480818253
194172257164
6473932681
Pacific Power & LightCompany Wasteway
(113 L)
3083804253
2324778547
160405668116
4074527221
28nq2054
7736756864
1863656543
125113176109
4066551860
Satus Creek aboveWilson-Charley Canyon
(111 L)
4378735161
89
848158
99555356nq
5956287831
199
1657
8675585962
954686163
9476
10380
2779654554
Trithion 75 68 59 69
120
Table 40. Analytical recoveries using the Goulden large-sample extractor for extracting spiked compounds from filtered-water samples, Yakima River basin, Washington, June 25-30, 1989 Continued
Recovery of spiked compound. in percentStation number
12510500 12484500 12496510 12507594Station name
Compounds
Triazine
AmetrynAtrazineAtrazine d-5 *CyanazineMetribuzin
PrometonPrometrynPropazineSimazineSimetryn
Terbuthylazine
Carbamate
CarbarylCarbofuranEPTC
Thiocarbamate
ButylateVernolate
Acetamide
AlachlorMetolachlor
Chloroacetanilide
ButachlorPropachlor
Conazole
Triadimefon
Pyrethoid
Fluey thrinatecis-Permethrintrans-Permethrin
Sulfite
Propargite
Trifluoromethyl
Trifluralin
Uracil
Bromacil
Yakima Riverat Kiona(35.7 L)
1041141047566
1131109877
103
97
7351
126
116115
117103
98118
107
3647
86
108
-25
Yakima Riverat Umtanum(35.7 L)
7768764758
7283832567
91
331581
7178
10392
83114
95
1243741
99
84
148
Pacific Power & LightCompany Was tew ay
(113 L)
5856462641
6063612452
57
401544
4345
7469
5659
119
603436
59
51
9
Satus Creek aboveWilson-Charley Canyon
(111 L)
6456442429
5172671841
62
nq1461
5963
7469
6064
78
643638
82
63
8
121
Table 41. Concentrations of pesticides extracted from replicate filtered-water samples using the Goulden large-sample extractor, Yakima River at Kiona, Washington, June 26, 1989
[Station number 12510500; map reference number 51 figure 1; "T" = trace concentration below minimum reporting level; "nd" = not detected; "ap" = analytical problems; "D" = detected, but not quantified; EPIC = S-ethyl dipropylthiocarbamate; DDD = dichlorodiphenyl- dichloroethane; DDE = dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyl- trichloroethane; HCB = hexachlorobenzene]
Concentration, in nanoRrams per literSample number collected from 0800 to 1330 hour
Compound
Acetamide compounds
AlachlorMetolachlor
Carbamate compounds
EPIC
Organochlorine compounds
Aldrinp,p'-DDD p,p'-DDE p,p'-DDT Dieldrin
Endosulfan IHCB
Organophosphorus compounds
Azinphos-methyl Chloropyrifos DiazinonEthionMalathion
ParathionPhoratePhosphamidon
Pyrethoid compounds
Replicate
9.71.7
4.4
ndT .93
ap 2.9
ndnd
9.0 T
40nd12
TT6.4
1 Replicate 2
9.2T
5.2
ndT T ap T
ndnd
6.5 T
40nd11
TTT
Replicate 3
9.41.5
5.1
ndT .81
ap 2.5
ndnd
6.7 T
40nd11
TT5.9
Sample number 2 collected from 1350 to 1650 hour
121.9
3.3
T1.4 1.2 1.6 3.6
1.2T
nd 9.6
39T
70
TT5.3
c i s-Permethrin
Sulfite compounds
Propargite
Triazine
AtrazineCyanazineDeethylatrazineDeisopropylatrazineMetribuzin
PrometonPropazineSimazine
Trifluoromethyl compounds
Trifluralin
Urea compounds
Linuron
11
372.4T T T
2.1 nd21
11
36 3.7 T T T
3.3 nd 22
11
36 3.7 T T T
3.5 nd 22
nd
7.2
32 nd D D nd
3.0.47
18
1.9
122
Table 42. Concentrations of organochlorine and organophosphorus compounds in spiked filtered-water samples from Yakima River at Kiona, Washington, May 21, 1991, at 1200 hour and 1207 hour
[Station number 12510500; map reference number 51 figure 1; "ns" = not spiked; DDD = dichlorodiphenyldichloroethane; DDE = dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyltrichloroethane; PCB - gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes; DBF = S,S,S-tributyl phosphorotrithioate; "<" = less than; less-than values were set equal to zero for calculations]
Concentration, in nanograms per literLaboratory results Calculated
Para- Replicate 1Replicate 2 concentration Recovery,meter (not spiked) (spiked) in replicate 2 in percentcode Compound A B C B x 100 / C
Organochlorine compounds
39331 Aldrin <1 <1 ns ns39352 Gross chlordane <100 <100 ns ns39361 p,p'-DDD <1 <1 ns ns39366 p,p'-DDE 4 3 ns ns39371 p,p'-DDT <1 <1 ns ns
39381 Dieldrin 3 1 58 282354 Endosulfan I <1 <1 ns ns39391 Endrin <1 <1 ns ns39411 Heptachlor <1 <1 ns ns39421 Heptachlor epoxide <1 <1 ns ns
39341 Lindane (gamna-HCH) <1 <1 56 0p,p'-Methoxychlor <10 <10 ns ns
39756 Mirex <10 <10 ns ns39517 PCB <100 <100 ns ns82360 PCN <100 <100 ns ns
82348 Perthane <100 <100 ns ns39401 Toxaphene <1,000 <1,000 ns ns
Organophosphate compounds
Chlorpyrifos <10 <10 110 0DBF <10 <10 ns ns
39572 Diazinon <10 <10 110 0Disulfoton <10 <10 ns ns
82346 Ethion <10 <10 ns ns
Fonofos <10 <10 ns ns39532 Malathion <10 <10 110 039602 Methyl parathion <10 <10 ns ns
Methyl trithion <10 <10 ns ns39542 Parathion <10 <10 110 0
Phorate <10 <10 ns ns82342 Trithion <10 <10 ns ns
123
Table 43. Concentrations of organochlorine and organophosphorus compounds in spiked filtered-water samples from Chandler Canal at Bunn Road at Prosser, Washington, June 13, 1991, at 1240 hour and 1247 hour
[Station number 12509499; map reference number 48 figure 1; "ns" = not spiked; ODD = dichlorodiphenyldichloroethane; DDE - dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyltrichloroethane; PCB - gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes; DBF - S,S,S-tributyl phosphorotrithioate; less-than values were set equal to zero for calculations]
Para meter code Constituent
Concentration, in nanograms per liter Laboratory results Calculated
concentrationin replicate 2 Recovery.in percent
C
Replicate 1(not spiked)
A
Replicate 2 (spiked)
B B x 100 / C
Organochlorine compounds
39331 Aldrin <1 <139352 gross Chlordane <100 <10039361 p,p'-DDD <1 <139366 p,p'-DDE 1 139371 p,p'-DDT <1 1
39381 Dieldrin 1 4082354 Endosulfan I 2239391 Endrin <1 <139411 Heptachlor <1 <139421 Heptachlor epoxide <1 <1
39341 Lindane (gamma-HCH) <1 40p.p'-Methoxychlor <10 <10
39756 Mirex <10 <1039517 PCB <100 <10082360 PCN <100 <100
82348 Perthane <100 <10039401 Toxaphene <1,000 <1,000
Organophosphate compounds
Chlorpyrifos <10 60DBF <10 <10
39572 Diazinon <10 130Disulfoton <10 <10
82346 Ethion <10 <10
Fonofos <10 <1039532 Malathion 30 16039602 Methyl parathion <10 <10
Methyl trithion <10 <1039542 Parathion <10 160
Phorate <10 <1082342 Trithion <10 <10
ns ns ns ns ns
54 ns ns ns ns
53 ns ns ns ns
ns ns
100 ns100 ns ns
ns140nsns100
ns ns
ns ns ns ns ns
74 ns ns ns ns
75 ns ns ns ns
ns ns
57 ns 120 ns ns
ns120nsns150
ns ns
124
Table 44. Concentrations of organochlorine and organophosphorus compounds in replicate filtered-water samples from Yakima River at Kiona, Washington, August 6, 1991, at 1150 hour and 1151 hour
[Station number 12510500; map reference number 51 figure 1; DDD = dichlorodiphenyldichloroethane; DDE = dichlorodiphenyl- dichloroethylene; DOT = dichlorodiphenyltrichloroethane; HCH = hexachlorocyclohexane; PCB = gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes; DEF - S,S,S-tributyl phosphorotrithioate; "<" = less than; less-than values were set equal to zero for calculations]
Concentration, in nanograms per literPara- Replicate 1Replicate 2meter (not spiked) (not spiked) Differencecode Constituent A B | A - B |
Organochlorine compounds
39331 Aldrin <1 <1 039352 gross Chlordane <100 <100 039361 p,p'-DDD <1 2 239366 p,p'-DDE 42239371 p,p'-DDT <1 <1 0
39381 Dieldrin <1 1 182354 Endosulfan I 51439391 Endrin <1 <1 039411 Heptachlor <1 <1 039421 Heptachlor epoxide <1 <1 0
39341 Lindane (gamma-HCH) .3 <1 .3p,p'-Methoxychlor <10 <10 Q
39756 Mirex <10 <10 039517 PCB 200 100 10082360 PCN <100 <100 0
82348 Perthane <100 <100 039401 Toxaphene <1,000 <1,000 0
Organophosphorus compounds
Chlorpyrifos <10 <10 0DEF <10 <10 0
39572 Diazinon 10 10 0Disulfoton <10 <10 0
82346 Ethion <10 <10 0
Fonofos <10 <10 039532 Malathion <10 <10 039602 Methyl parathion <10 <10 0
Methyl trithion <10 <10 039542 Parathion 10 <10 10
Phorate <10 <10 082342 Trithion <10 <10 0
125
Table 45. Mean analytical recoveries for extracting surrogate compounds from suspended-sediment samples, Yakima River basin, Washington, June 25-30, 1989
["-" = not calculated; HCH = hexachlorocyclohexane; ODD = dichlorodiphenyl- dicloroethane; DDE = dichlorodiphenyldichloroethylene; DOT = dichloro- diphenyltrichloroethane]
Compound
Isodrin
Lindane (gamma-HCH)
p,p'-DDT d-8
p,p'-DDE d-8 I/
p,p'-DDD d-8 I/
(DDT+DDE+DDD) d-8 I/
Diazinon d-10
Isofenphos
Number of samples
1
19
19
6
12
19
19
1
Mean analytical recovery, in percent
45
28
42
5.9
1.0
45
60
110
One standard deviation of the mean, in percent
-
14
23
5.6
.6
23
15
-
If Samples were spiked with p,p'-DDT d-8 surrogate; during sample storage, processing, and (or) analysis, some of the DOT d-8 in several samples was converted to DDE d-8 and ODD d-8.
126
Table 46. Analytical recoveries of pesticides that were spiked into a blank solvent extract and were analyzed in accordance with other extracts from suspended-sediment samples, Yakima River basin, Washington, June 25-30, 1989
[These recoveries do not include losses associated with the extraction and initial solvent-concentration procedures; "ns" = not spiked; "nq" = not quantified; DDD = dichloro- diphenyl dichloroethane; DDE = dichlorodiphenyl- dichloroethylene; DDT = dichlorodiphenyltrichloroethane; HCB = hexachlorobenzene; HCH = hexachlorocyclohexane; DBF = S,S,S- tributyl phosphorotrithioate]
Analytical recoveries,
Compound in percent
Organochlorine compounds
Aldrin 44trans-Chlordane 38cis-Chlordane 39
Chlorthalonil 38p,p'-DDD 53p,p'-DDE 55
p,p'-DDT 48p,p'-DDT d-8 84Dacthal ns
Dieldrin 55Endosulfan I 18Endosulfan II nq
Endosulfan sulfate nsEndrin 52Endrin aldehyde ns
Endrin ketone nsHCB 26alpha-HCH 29
beta-HCH 45delta-HCH 39Heptachlor 40
Heptachlor epoxide 40Isodrin 28 Lindane (ganma-HCH) 34
Lindane d-6 65o,p'-Methoxychlor 70p,p'-Methoxychlor 55
Mirex 38trans-Nonachlor nsToxaphene ns
Organophosphorus compounds
Chlorpyrifos 48DEF 53Diazinon 42
Diazinon d-10 80Disulfoton 10Ethion 47
Fonofos 45Isofenphos 52Malathion 53
Methyl parathion 43Methyl trithion 39
Parathion 50Phorate 17Trithion 49
127
Table 47. Concentrations of organochlorine and organophosphorus compounds in replicate suspended-sediment samples from Chandler Canal at Bunn Road at Prosser, Washington, June 13, 1991, at 17.40 hour and 1241 hour
[Station number 12509499; map reference number 48--figure 1; ODD = dichlorodiphenyldichloroethane; DDE = dichloro- diphenyldichloroethylene; DOT = dichlorodiphenyl- trichloroethane; HCH = hexachlorocyclohexane; PCS = gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes; DBF = S,S,S-tributyl phosphorotrithioate; I = interference at peak; "<" = less than; less-than values were set equal to zero for calculations]
Para meter code Constituent
Concentration, in nanograms per liter Replicate 1Replicate 2 (not spiked) (not spiked) Difference
A B | A - B |
Organochlorine compounds
39332 Aldrin39353 gross Chlordane39362 p.p'-DDD39367 p,p'-DDE39372 p,p'-DDT
39382 Dieldrin82355 Endosulfan I39392 Endrin39412 Heptachlor39422 Heptachlor epoxide
39342 Lindane (gamma-HCH)p,p'-Methoxychlor
39757 Mirex 39518 PCB "7361 PCN
<100 <100
(V.349 Perthane '9402 Toxaphene
ChlorpyrifosDEF
39573 DiazinonDisulfoton
82347 Ethion
Fonofos39533 Malathion 39603 Methyl parathion
Methyl trithion 39543 Parathion
Phorate 82343 Trithion
<100 <100 <100 <100
<100 <100 <1,000 <1,000
Organophosphorus compounds
:.6 :.6 :.6 :.6 :.6
:.6 :.6 :.6 :.6 :.6
:.6 :.6
128
Table 48. Concentrations of organochlorine and organophosphorus compounds in replicate suspended-sediment samples from Yakima River at Kiona, Washington, May 21, 1991, at 1200 hour and 1201 hour
[Station number 12510500; map reference number 51 figure 1; DDD = dichlorodiphenyldichloroethane; DDE = dichlorodiphenyl- dichloroethylene; DDT = dichlorodiphenyltrichloroethane; HCH - hexachlorocyclohexane; PCB = gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes; DEF = S,S,S-tributyl phosphorotrithioate; "<" = less than; less-than values were set equal to zero for calculations]
Concentration, in nanogramsPara meter code
Replicate 1 Replicate 2 (not spiked) (not spiked)
Constituent A B
per liter
Difference 1 A - B |
Organochlorine compounds
3933239353 39362 39367 39372
39382823553939239412 39422
39342
397573951882361
8234939402
39573
82347
3953339603
39543
82343
Aldrin <1gross Chlordane <100 p,p'-DDD <1 p,p'-DDE 1 p,p'-DDT 1
<!<100
1 1
Dieldrin 1 <1Endosulfan I 1Endrin <1Heptachlor <1 Heptachlox epoxide <1
Lindane (gamma -HCH) <1 p , p ' -Methoxychlor <1C Mirex <10PCB <10PCN <100
Perthane <100Toxaphene <1,000
Organophosphorus
Chlorpyrifos DEFDiazinonDisulfotonEthion
FonofosMalathionMethyl parathion Methyl trithion Parathion
PhorateTrithion
1<1
<i<10
<10<100
<100<1,000
compounds
.4
.4
.4
.4
.4
.4
.4
.4
.4
.4
.4
.4
4 4444
444 4 4
44
00 0 0 0
1000 0
0 0 000
00
0 0000
000 0 0
00
129
Table 49. Concentrations of organochlorine and organophosphorus compounds in replicate suspended-sediment samples from Yakima River at Kiona, Washington, August 6, 1991, at 1150, hour and 1151 hour
[Station number 12510500; map reference number 51 figure 1; DDD = dichlorodiphenyldichloroethane; DDE = dichloro- diphenyldichloroethylene; DOT = dichlorodiphenyltrichloroethane; HCH = hexachlorocyclohexane; PCB = gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes; DEF = S,S,S-tributyl phosphorotrithioate; "<" = less than; less-than values were set equal to zero for calculations]
Para meter code Constituent
Concentration, in nanoxrams per liter Replicate 1 Replicate 2 (not spiked) (not spiked) Difference
A B | A - B |
Orxanochlorine compounds
39332 Aldrin39353 gross Chlordane39362 p,p'-DDD39367 p,p'-DDE39372 p,p'-DDT
39382 Dieldrin82355 Endosulfan I39392 Endrin39412 Heptachlor39422 Heptachlor epoxide
39342 Lindane (gamma-HCH)p,p'-Methoxychlor
39757 Mirex 39518 PCB 82361 PCN
8234939402
<100 <100 1 1
Perthane Toxaphene
20 <100
<100 <1,000
50 <100
<100 <1,000
Organophosphorus compounds
ChlorpyrifosDEF
39573 DiazinonDisulfoton
82347 Ethion
Fonofos39533 Malathion 39603 Methyl parathion
Methyl trithion 39543 Parathion
Fhorate 82343 Trithion
00100
10000
000
300
00
130
Table 50. Concentrations of organochlorine and organophosphorus compounds associated with blank glass-fiber filters, Yakima River basin, Washington, July to September 1991
[ <" = less than; DDD - dichlorodiphenyldichloroethane; DDE - dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyltrichloroethane; HCH « hexachloro- cyclohexane; PCB = gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes; DEF = S,S,S- tributyl phosphorotrithioate]
Concentration, in nanograms per liter Glass-fiber filter without
Para- _______suspended sediment__________meter July 1991 Sept. 5. 1991 Sept. 25. 1991code Constituent ABC
Organochlorine compounds
39332 Aldrin <1 <1 <139353 Chlordane <100 <100 <10039362 p,p'-DDD <1 <1 <139367 p,p'-DDE <1 <1 <139372 p,p'-DDT <1 <1 <1
39382 Dieldrin <1 <1 <182355 Endosulfan I <1 <1 <139392 Endrin <1 <1 <139412 Heptachlor <1 <1 <1
39422 Heptachlor epoxide <1 <1 <139342 Lindane (gamma-HCH) <1 <1 <1
p,p'-Methoxychlor <10 <10 <1039757 Mirex <10 <10 <1039518 PCB <100 <100 <100
82361 PCN <100 <100 <10082349 Perthane <100 <100 <10039402 Toxaphene <1,000 <1,000 <1,000
Organophosphorus compounds
Chlorpyrifos <10 <10 <.5DEF <10 <10 <.5
39573 Diazinon <10 <10 <.5Disulfoton <10 <10 <.5
82347 Ethion <10 <10 <.5
Fonofos <10 <10 <.539533 Malathion <10 <10 <.539603 Methyl parathion <10 <10 <.5
Methyl trithion <10 <10 <.539543 Farathion <10 <10 <.5
Phorate <10 <10 <.582343 Trithion <10 <10 <.5
131
Table 51. Concentrations of organochlorine and semi-volatile organic compounds In replicate bed-sediment samples (sediment finer than 62 micrometers in diameter) from Sulphur Creek Wasteway near Sunnyside, Washington, August 31, 1988
[Station number 12508850; map reference number 46 figure 1; DDD = dichlorodiphenyldichloroethane; DDE = dichloro- diphenyldichloroethylene; DOT = dichlorodiphenyltri- chloroethane; HCH = hexachloroeyelohexane; PCB = gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes; "<" = less than; less-than values were set equal to zero for calculations]
Parametercode
Replicate 1 Replicate 2Constituent A B
Difference1 A - B |
Carbon compounds
00693
00686
[concentration,
Carbon, inorganic +organic
Carbon, inorganic
in grams per kilogram]
9.31.1
6.01.5
3.3.4
Organochlorine compounds
3933339351393833936339368
3937339389393933941339423
3934339481397583951939251
8188639403
[concentration, in
Aldringross ChlordaneDieldrinp,p'-DDDp,p'-DDE
p,p'-DDTEndosulfan IEndrinHeptachlorHeptachlor epoxide
Lindane (gamma-HCH)p , p ' -MethoxychlorMirexPCBPCN
PerthaneToxaphene
micrograms per
<.l<15
2674
137.9<.l<.l<.l
<.l<.l<.l
<1<1
<1<10
kilogram]
<.l44.4
1542
9.91.9<.l<.l.1
<.l<.l<.l
<1<1
<1<10
04.6
1132
3.1600.1
00000
00
Semi-volatile compounds
34411345843970534389
34399
34281
34276
34286
34639
34641
34539345693457434614
3462939701
[concentration, in
Isophorone2-ChloronaphthaleneHexachlorobutadieneHexachlorocyclopenta-
dieneHexachloroethane
bis (2-Chloroethoxy)methane
bis (2-Chloroethyl)ether
bis (2-Chloroisopropyl)ether
4-Bromophenyl phenylether
4-Chlorophenyl phenylether
1,2 Dichlorobenzene1,3 Dichlorobenzene1,4 Dichlorobenzene2,4 Dinitrotoluene
2,6 DinitrotolueneHexachlorobenzene
micrograms per
<200<200<200
<200<200
<200
<200
<200
<200
<200<200<200<200<200
<200<200
kilogram]
<200<200<200
<200<200
<200
<200
<200
<200
<200<200<200<200<200
<200<200
000
00
0
0
0
0
00000
00
132
Table 51. Concentrations of organochlorine and semi-volatile organic compounds in replicate bed-sediment samples (sediment finer than 62 micrometers in diameter) from Sulphur Creek Wasteway near Sunnyside, Washington, August 31, 1988 Continued
Parametercode
3445034554345893460434609
3466034619345943464934455
39061346953462439102
34339
3434439112345993429534208
3420334223345293425034233
3424534524343233455934379
3438434406344453446434472
3444134431
34436
Replicate 1Constituent
Semi -volatile[concentration, in
Nitrobenzene1,2,4 Trichlorobenzene2-Chlorophenol2,4 Dichlorophenol2 , 4 -Dimethylphenol
4 , 6-Dinitroortho cresol2, 4-Dinitrophenol2-Nitrophenol4-NitrophenolParachloro meta cresol
PentachlorophenolPhenol2,4,6 Trichlorophenolbis (2-Ethylhexyl)
phthalateDiethyl phthalate
Dimethyl phthalateDi-n-butyl phthalateDi-n-octyl phthalateN-butyl benzl phthalateAcenaphthene
Ac enaphthy leneAnthraceneBenzo (a) anthraceneBenzo (a) pyreneBenzo (b) fluoranthene
Benzo (k) fluorantheneBenzo (g,h,i) peryleneChryseneDibenzo (a,h) anthraceneFluoranthene
FluoreneIndeno (1,2,3-cd) pyreneNaphthalenePhenanthrenePyrene
N-NitrosodimethylamineN-Nitrosodi-n-propyl-
amineN-Nitrosodiphenylamine
AReplicate 2 Difference
JT 1 A - B |
compounds Continuedmicrograms
<200<200<200<200<200
<600<600<200<600<600
<600<200<600
350<200
<200<200<400<200<200
<200<200<400<400<400
<400<400<400<400<200
<200<400<200<200<200
<200
<200<200
per kilogram}
<200<200<200<200<200
<600<600<200<600<600
<600110
<600
43080
<200116
<400<200<200
<200<200<400<400<400
<400<400<400<400<200
<200<400
9482
110
<200
<200<200
00000
00000
0110
0
8080
0116
000
00000
00000
00
9482
110
0
00
133
Table 52. Concentrations of organochlorine and semi-volatile organic compounds in replicate bed-sediment samples (sediment finer than 2,000 micrometers in diameter) from Sulphur Creek Wasteway near Sunnyside, Washington, August 31, 1988
[Station number 12508850; map reference number 46 figure 1; ODD m dichlorodiphenyldichloroethane; DDE m dichlorodiphenyl- dichloroethylene; DOT - dichlorodiphenyltrichloroethane; HCH = hexachlorocyclohexane; PCB = gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes; "<" = less than; less-than values were set equal to zero for calculations]
Para meter code Constituent
Replicate 1 Replicate 2 A B
Difference 1 A - B |
Carbon compounds [concentration, in grams per kilogram]
00693
00686
Carbon, inorganic +organic
Carbon, inorganic9.1.
Organochlorine
3933339351393833936339368
3937339389393933941339423
3934339481397583951939251
8188639403
[concentration, in
Aldringross ChlordaneDieldrinp,p'-DDDp,p'-DDE
p,p'-DDTEndosulfan IEndrinHeptachlorHeptachlor epoxide
Lindane (ganma-HCH)p , p ' -MethoxychlorMirexPCBPCN
PerthaneToxaphene
5 50
compounds
18
4 42
micrograms per kilogram]
<<15.
13< -
.
<1<1
<!<10
Semi -volatile
34411345843970534389
34399
34281
34276
34286
34639
34641
3453934569345743461434629
3970134450345543458934604
3460934660346193459434649
[concentration, in
Isophorone2-CnloronaphthaleneHexachlorobutadieneHexachlorocyclopenta-
dieneHexachloroethane
bis (2-Chloroethoxy)methane
bis (2-Chloroethyl)ether
bis (2-Chloroisopropyl)ether
4-Bromophenyl phenylether
4-Chlorophenyl phenylether
1,2 Dichlorobenzene1,3 Dichlorobenzene1,4 Dichlorobenzene2,4 Dinitrotoluene2,6 Dinitrotoluene
HexachlorobenzeneNitrobenzene1,2,4 Trichlorobenzene2-Chlorophenol2,4 Dichlorophenol
2, 4-Dimethylphenol4,6-Dinitroortho cresol2,4-Dinitrophenol2-Nitrophenol4-Nitrophenol
! <4
6 310
1 33
8 81 1111
111
<1<1
<!<10
compounds
!
4
9111
111
0423
33
71000
00000
00
2
29
micrograms per kilogram]
<200<200<200
<200<200
<200
<200
<200
<200
<200
<200<200<200<200<200
<200<200<200<200<200
<200<600<600<200<600
<200<200<200
<200<200
<200
<200
<200
<200
<200
<200<200<200<200<200
<200<200<200<200<200
<200<600<600<200<600
000
00
0
0
0
0
0
00000
00000
00000
134
Table 52. Concentrations of organochlorine and semi-volatile organic compounds in replicate bed-sediment samples (sediment finer than 2,000 micrometers in diameter) from Sulphur Creek Wasteway near Sunnyside, Washington, August 31, 1988 Continued
Parametercode
3445539061346953462439102
3433934344391123459934295
3420834203342233452934250
3423334245345243432334559
3437934384344063444534464
344723444134431
34436
Replicate 1Constituent
Semi -volatile[concentration, in
Parachloro meta cresolPentachlorophenolPhenol2,4,6 Trichlorophenolbis (2-Ethylhexyl)
phthalate
Diethyl phthalateDimethyl phthalateDi-n-butyl phthalateDi-n-octyl phthalateN-butyl benzl phthalate
AcenaphtheneAcenaphthyleneAnthraceneBenzo (a) anthraceneBenzo (a) pyrene
Benzo (b) fluorantheneBenzo (k ) fluorantheneBenzo (g,h,i) peryleneChryseneDibenzo (a,h) anthracene
FluorantheneFluoreneIndeno (1,2,3-cd) pyreneNaphthalenePhenanthrene
PyreneN-NitrosodimethylamineN-Nitrosodi-n-propyl-
amineN-Nitrosodiphenylamine
AReplicate 2 Difference
B | A - B |
compounds Continuedmicrograms
<600<600<200<600
<200
<200<200<200<400<200
<200<200<200<400<400
<400<400<400<400<400
<200<200<400<200<200
<200<200
<200<200
per kilogram]
<600<600110
<600
520
80<200120
<400150
<200<200<200<400<400
<400<400<400<400<400
<200<200<400<200<200
<200<200
<200<200
00
1100
520
800
1200
150
00000
00000
00000
00
00
135
Table 53. Analytical recovery of organochlorine and semi-volatile organic compounds spiked in bed-sediment samples from Sulphur Creek Wasteway, Washington, August 31, 1988
[Station number 12508850; map reference number 46 figure 1; three replicate sediment samples of each size class (less than 62-micrometer and less than 2,000-micrometer diameter) were analyzed; replicate 1 and replicate 2 in each size class were not spiked to determine precision (results of duplicate analyses shown in tables 51 and 52); replicate 3 in each size class was spiked; percent recoveries from replicate 3 samples are based on the mass of analyte that was spiked plus the mass of the analyte detected in replicates 1 or 2 for each size class; "ns" = not spiked; "-" = one or more of the percent recoveries were reported as "less than" values; "<" = less than; DDD = dichlorodiphenyldichloroethane; DDE = dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyltrichloroethane; HCH = hexachlorocyclohexane; PCB = gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes]
Recovery of spike from Replicate 3.<62 micrometer
Para meter code
in percent<2.000 micrometer
Based on Based on Based on analysis of analysis of analysis of
Constituent Replicate 1 Replicate 2 Replicate 1
Based on analysis of Replicate 2
Mean percent recovery
Percent relative standard deviation
Organochlorine compounds
3933339351 3938339363 39368
39373 393893939339413 39423
39343 39481 397583951939251
8188639403
34411 34584 3970534389
34399
34281
34276
34286
34639
34641
3453934569345743461434629
39701344503455434589 34604
Aldringross Chlordane Dieldrinp,p'-DDD p,p'-DDE
p,p'-DDT Endosulfan IEndrinHeptachlor Heptachlor epoxide
Lindane (gamma-HCH) p , p ' -Methoxy chlor MirexPCBPCN
PerthaneToxaphene
Isophorone 2-Chloronaphthalene HexachlorobutadieneHexachlorocyclopenta- diene
Hexachloroethane
bis (2-Chloroethoxy) methane
bis (2-Chloroethyl) ether
bis (2-chloroisopropyl) ether
4-Bromophenyl phenyl ether
4-Chlorophenyl phenyl ether
1,2 Dichlorobenzene1,3 Dichlorobenzene1,4 Dichlorobenzene2,4 Dinitrotoluene2,6 Dinitrotoluene
HexachlorobenzeneNitrobenzene1,2,4 Trichlorobenzene2-Chlorophenol 2,4 Dichlorophenol
50100 8671 82
90 44
10054 75
58 ns ns<. /
ns
ns<10
39 38
<21<21
64
29
8
200
78
<2i<21<215288
190231
65 110
5071 8676
110
92 49
10054 75
58 ns ns
, < 4ns
ns<10
Semi -volatile
39 38
<21<21
64
29
8
200
78
<21<21<215288
190231
65 110
67230 9889
250
110 10012017 78
61 ns ns<. 5
ns
ns<16
compounds
66 925
<33<33
110
44
<33
300
160
223
1019
300211479
160
6733
10092
131
102 97
12217 78
61 ns ns<. 5
ns
ns<16
66 925
<33<33
110
44
<33
295
160
223
1019
300211479
160
58110 9282
143
98 72
11236 76
60 ns ns<. 4
ns
ns<13
52 65
<27<27
87
36
<20
250
119
<12<12<123154
240228
72 130
1779 8
12 51
9 421060 2
3 ns ns-
ns
ns
30 48
_-
30
24
_
21
40
_--
7874
255
10011 22
136
Table 53. Analytical recovery of organochlorine and semi-volatile organic compounds spiked in bed-sediment samples from Sulphur Creek Wasteway, Washington, August 31, 1988 Continued
<62 micrometerPara meter code Constituent
Based on analysis of Replicate 1
Based on analysis of Replicate 2
<2.000 miBased on analysis of Replicate 1
crometerBased on analysis of Replicate 2
Mean percent recovery
Percent relative standard deviation
Semi-volatile compounds Continued
3460934660346193459434649
3445539061346953462439102
3433934344391123459934295
3420834203342233452934250
3423334245345243432334559
3437934384344063444534464
344723444134431
34436
2, 4-Dimethylphenol4 , 6-Dinitroortho cresol2, 4-Dinitrophenol2-Nitrophenol4-Nitrophenol
Farachloro meta cresolFentachlorophenolPhenol2,4,6 Trichlorophenolbis (2-Ethylhexyl)
phthalate
Di ethyl phthalateDimethyl phthalateDi-n -butyl phthalateDi-n-octyl phthalateN-butyl benzl phthalate
AcenaphtheneAc enaphthy leneAnthraceneBenzo (a) anthraceneBenzo (a) pyrene
Benzo (b) fluorantheneBenzo (k) fluorantheneBenzo (g,h,i) peryleneChryseneDibenz (a,h) anthracene
FluorantheneFluoreneIndeno (1,2,3-cd) pyreneNaphthalenePhenanthrene
PyreneN-NitrosodimethylamineN-Nitrosodi-n-propyl-
amineN-Nitrosodiphenylamine
23
<21647
87<1313097
110
89120629480
523078
120110
12012096120140
8662914
100
120<21
6289
23
<21647
87<1313097
100
82120559480
523078
120110
12012096120140
8662914
96
110<21
6289
21<20<33
42
170<20150110
200
13023034
13040
11073
150190190
210180160180130
12013015016
180
150<33
120210
21<20<33
42
170<20120110
110
1202302913032
11073150190190
210180160180130
12013015016
180
150<33
120210
12<12<27344
130<16130100
130
10017045
11058
7952
120150150
170150130150140
10096
12010
140
140<27
89150
95 -
10064
38-88
36
2235361744
4048432433
313828236
2040306932
15-
3547
137
Table 54. Laboratory quality-assurance data for organochlorine compounds analyzed in biological samples collected in 1989 and 1990, Yakima River basin, Washington
[Concentrations in micrograms per kilogram, wet weight; spike = 100 micrograms per kilogram, except 500 micrograms per kilogram for kepone; ; "<" = less than; ODD = dichlorodiphenyldichloroethane; DDE = dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyltrichloroethane; NS = not spiked; "-" = not applicable; matrix blanks for fish consist of ocean-fish samples with very low to non- detectable concentrations of organochlorine compounds; matrix blanks for vegetation consist of grass samples collected in non-agricultural areas near Mississippi State University]
Compound Reagentanalyzed blank
Matrixblankforfish
Spikeforfish
Percent Reagent Reagentrecovery blank blank
Spikeforfish
Percentrecovery
Reagentblank
May 1989
Hexachlorobenzene <10a-Hexachlorocyc lohexane <10g-Hexachlorocyclohexane <10b-Hexachlorocyclohexane <10d-Hexachlorocyc lohexane <10
Oxychlordane <10Heptachlor epoxide <10trans-Chlordane <10trans-Nonachlor <10Toxaphene <50
Total PCBs <50o,p'-DDE <10cis-Chlordane <10p,p'-DDE <10Dieldrin <10
o,p'-DDD <10Endrin <10cis-Nonchlor <10o,p'-DDT <10p,p'-DDD <10
p.p'-DDT <10Mirex <10Dicofol <10Octochlorstyrene <10Kepone <10
Percent moisturePercent lipid
<10<10<10<10<10
<10<10<10<10<50
<50<10102010
<10<10<10<1010
<10<io<10<10<io
71.08.53
60NS8989NS
8899NS93NS
NS9795
10090
NS1009593
100
100939771
310
70.08.74
60-
8989-
8899-
93-
-9795
10090
-1009593
100
10093977162
October-November 1989
Hexachlorobenzene <10a-Hexachlorocyc lohexane <10g-Hexachlorocyclohexane <10b-Hexachlorocyclohexane <10d-Hexachlorocyc lohexane <10
Oxychlordane <10Heptachlor epoxide <10trans-hlordane <10trans-Nonachlor <10Toxaphene <50
Total PCBs <50o,p'-DDE <10cis-Chlordane <10p.p'-DDE <10Dieldrin <10
o,p'-DDD <10Endrin <10cis-Nonchlor <10o,p'-DDT <10p,p'-DDD <10
p.p'-DDT <10Mirex <10Octochlorstyrene <10Dicofol <10Kepone <10
Percent moisturePercent lipid
<io<io<io<10<10
<10<10<10<10<50
<50<10102010
<10<10<10<1010
<10<10<10<10<10
71.08.53
72NS9498NS
100100NS95NS
NS1109999
100
NS10010099
100
100978591
' 410
70.09.28
72 <10 <10<10 <10
94 <10 <1098 <10 <10
<10 <10
100 <10 <10100 <10 <10
<10 <1095 <10 <10
<50 <50
<50 <50110 <10 <1099 <10 <1099 <10 <10
100 <10 <10
<10 <10100 <10 <10100 <10 <1099 <10 <10
100 <10 <10
100 <10 <1097 <10 <1085 <10 <1091 <10 <1082 <10 <10
_- -
71NS8193NS
8892NS85NS
NS949699
100
NS91979598
94947790
370
70.58.96
71-
8193-
8892-
85-
_949699
100
-91979598
9494779074
_-
<10<io<io<10<10
<10<10<10<10<50
<50<10<10<10<10
<10<10<10<io<10
<io<10<10<10<10
_-
138
Table 54. Laboratory quality-assurance data for organochlorine compounds analyzed in biological samples collected in 1989 and 1990, Yakima River basin, Washington Continued
Matrixblank
Compound Reagent foranalyzed blank fish
Spikeforfish
Percent Reagent Reagentrecovery blank blank
Spikeforfish
Percentrecovery
Reagentblank
October-November 1989
Hexachlorobenzene <10 <10a-Hexachlorocyclohexane <10 <10g-Hexachlorocyclohexane <10 <10b-Hexachlorocyclohexane <10 <10d-Hexachlorocyclohexane <10 <10
Oxychlordane <10 <10Heptachlor epoxide <10 <10trans-Chlordane <10 <10trans-Nonachlor <10 <10Toxaphene <50 <50
Total PCBs <50 <50o.p'-DDE <10 <10cis-Chlordane <10 <10p,p'-DDE <10 <10Dieldrin <10 <10
o,p'-DDD <10 <10Endrin <10 <10cis-Nonchlor <10 <10o.p'-DDT <10 <10p,p'-DDD <10 <10
p,p'-DDT <10 <10Mirex <10 <10Octochlqrstyrene <10 <10Dicofol <10 <10Kepone <10 <10
Percent moisture - 80 . 0Percent lipid
88NS120100NS
100110NS100NS
NS120110110100
NS100110120130
100120100120390
80.0~
88 <10<10
120 <10100 <10
<10
100 <10110 <10
- <10100 <10
<50
<50120 <10110 <10110 <10100 <10
<10100 <10110 <10120 <10130 <10
100 <10120 <10100 <10120 <1078 <10
_
October-November 1990
Hexachlorobenzene <10 <10a-Hexachlorocyclohexane <10 <10g-Hexachlorocyclohexane <10 <10b-Hexachlorocyclohexane <10 <10d-Hexachlorocyclohexane <10 <10
Oxychlordane <10 <10Heptachlor epoxide <10 <10trans-Chlordane <10 <10trans-Nonachlor <10 <10Toxaphene <10 <10
Total PCBs <10 <10o.p'-DDE <10 <10cis-Chlordane <10 <10p,p'~DDE <10 <10Dieldrin <10 <10
o,p'-DDD <10 <10Endrin <10 <10cis-Nonchlor <10 <10o.p'-DDT <10 <10p,p'-DDD <10 <10
p,p'-DDT <10 <10Mirex <10 <10
Percent moisture - 81.4Percent lipid - 1.14
57NS10098NS
91100NS89NS
NS100949393
NS1009196
100
10090
82.21.07
57 <10 <10<10 <10
100 <10 <1098 <10 <10
<10 <10
91 <10 <10100 <10 ^10
<10 <1089 <10 <10
<10 <10
<10 <10100 <10 <1094 <10 <1093 <10 <1093 <10 <10
- <10 ^10100 <10 <1091 <10 <1096 <10 <10
100 <10 <10
100 <10 <1090 <10 <10
_ _- -
57NS10097NS
96100NS91NS
NS100949590
NS1009096
100
9485
83.61.06
57-
10097-
96100
-91-
-100949590
_1009096
100
9485
<io<10<10<10<10
<10<10<10<10<10
<10<10<10<10<10
<10<10<10<io<10
<10<10
_-
139
Table 55. Laboratory quality-assurance data for semi-volatile organic compounds (polycyclic-aromatic hydrocarbons) analyzed in biological samples collected in 1989 and 1990, Yakima River basin, Washington
[Concentrations in micrograms per kilogram, wet weight; spike = 100 micrograms per kilogram; "-" not applicable; matrix blanks for fish consist of ocean-fish samples with very low to non-detectable concentrations of organochlorine compounds; matrix blanks for vegetation consist of grass samples collected in non-agricultural areas near Mississippi State University]
Compound analyzed
Matrix blank Spike
Reagent for for Percent blank fish fish recovery
May 1989
Napthalene <10 <10 Fluorene <10 <10 Phenanthrene <10 <10 Anthracene <10 <10 Fluoranthrene <10 <10
Pyrene <10 <10 1,2-Benzanthracene <10 <10 Chrysene <10 <10 Benzo (b)f luoranthrene <10 <10 Benzo (k)f luoranthrene <10 <10
Benzo (e)pyrene <10 <10 Benzo(a)pyrene <10 <10 1,2,5,6-Dibenzanthracene <10 <10 Benzo (g,h,i)perylene <10 <10
Percent moisture - 81
Compoundanalyzed
Matrixblank
Reagent forblank fish
Spikeforfish
Percent Reagentrecovery blank
75 7595 95 90 90 88 88 80 80
96 96 91 91 94 94 73 93 66 66
84 84 89 89 82 82 71 71
.4 84.5
Reagentblank
Matrixblankfor
vegetation
Spikefor**
vegetationPercent Reagentrecovery blank
October-November 1989
NapthaleneFluorenePhenanthreneAnthraceneFluoranthrene
Pyrene1,2-BenzanthraceneChryseneBenzo (b ) f luoranthreneBenzo (k ) f luoranthrene
Benzo (e)pyreneBenzo(a)pyrene1,2,5, 6-Dibenzanthr aceneBenzo ( g , h , i ) pery lene
Percent moisture
<10 <10<10 <10<10 <10<10 <10<10 <10
<10 <10<10 <10<10 <10<10 <10<10 <10
<10 <10<10 <10<10 <10<10 <10
80.6
Compoundanalyzed
7084947181
7165577564
90716092
78.
70 <1084 <1094 <1071 <1081 <10
71 <1065 <1057 <1075 <1064 <10
90 <1071 <1060 <1092 <10
0 -
Matrixblank
Reagent forblank fish
<10<10<10<10<10
<10<10<10<10<10
<10<10< 10<10
-
Spikeforfish
<10<10<10<10<10
<10<10<10<10<10
<10<io<10<10
80.0
Percent
7094948268
7575979664
70685049
80.0
70 <1094 <1094 <1082 <1068 <10
75 <1075 <1097 <1096 <1064 <10
70 <1068 <1050 <1049 <10
-
recovery
October-November 1990
NapthaleneFluorenePhenanthreneAnthraceneFluoranthrene
Pyrenel,2~Benzanthrac<Chrysene
sne
<10 <10<10 <10<10 <10<10 <10<10 <10
<10 <10<10 <10<10 <10
Benzo(b)fluoranthrene <10 <10Benzo (k)f luoranthrene <10 <10
Benzo(e)pyreneBenzo(a)pyrene
<10 <10< 10 <10
1,2,5,6-Dibenzanthracene <10 <10Benzo(g,h,i)per:/ lene <10 <10
6810095
10083
8785777878
94667967
6810095
10083
8785777878
94667967
Percent moisture 81.4 83.6
140
Table 56. Concentretions of organochlorine compounds in field-replicate and laboratory-split samples of aquatic biota, Yakima River basin, Washington, 1969-90
[Concentrations in micrograms per kilogram; wet weight; whole fish were analyzed; DDD « dichlorodiphenyldichloroethane; DDE = dichlorodiphenyldichloroethylene; DDT - dichlorodiphenyltrichloroethane; PCBa polychlorinated biphenyls; "--" » not analyzed; see figure 1 for site locations; "Replicate" two or more composite samples were collected at a station on the same day and were analyzed individually; "Split" = a single composite sample was homogenized, split into two samples at the lab, and each split was analyzed]
Quality- assurance sample type
Map refer ence Station number number Station name Dete
Field Moisture, Lipid, number in percent in percent
Largescale Sucker
Split Split
Split Split
Split Split Replicate
22 12499000 Naches River nr North Yakima 22 12499000 Naches River nr North Yakima
47 12509050 Yakima R at Euclid Br at RM 55 nr Grandview 47 12509050 Yakima R at Euclid Br at RM 55 nr Grandview
51 12510500 Yakima River at Kiona 51 12510500 Yakima River et Kiona 51 12510500 Yakima River at Kiona
11-06-90 11-06-90
10-31-89 10-31-89
11-10-90 11-10-90 11-10-90
YK0331SF 75.4 4.71 YK0331SF 75.6 4.34
YK0047SF 73.5 7.56 YK0047SF 74.0 7.32
YK0402SF 70.6 7.99 YK0402SF 71.4 7.78 YK0403SF 67.6 11.6
Asiatic Clam
Replicate Replicate Replicate Replicate
Replicate Replicate
Replicate Replicate
40 12507585 Yakima River at RM 72 ab Satus Cr nr Sunnyside 40 12507585 Yakima River at RM 72 ab Satus Cr nr Sunnyside 40 12507585 Yakima River at RM 72 ab Setus Cr nr Sunnyside 40 12507585 Yakima River at RM 72 ab Setus Cr nr Sunnyside
47 12509050 Yakima R at Euclid Br at RM 55 nr Grandview 47 12509050 Yakima R at Euclid Br at RM 55 nr Grandview
51 12510500 Yakima River at Kiona 51 12510500 Yakima River at Kiona
11-01-89 11-01-89 11-01-89 11-01-89
10-31-89 10-31-89
10-30-89 10-30-89
YK0100SM 76.0 2.40 YK0101SM 78.0 2.32 YK0102SM 79.0 2.62 YK0103SM 82.0 1.96
YK0082SM 95.5 1.64 YK0085SM 82.0 2.20
YK0115SM 83.0 2.20 YK0116SM 84.0 1.95
Western Pearlshell
Split Split
14 12484500 Yakima River at Umtanum 14 12484500 Yakima River at Umtanum
11-01-89 11-01-89
YK0111SM 86.0 .92 YK0111SM 84.0 .86
Waterweed
Split Split
26 12500442 Wide Hollow Cr at Old STP at Union Gap 26 12500442 Wide Hollow Cr at Old STP at Union Gap
11-04-89 11-04-89
YK0098SP 94.0 .10 YK0098SP 94.0 .20
Map refer ence number
Hepta- Station Field cis- trans- Oxy- chlor number number Chlordane Chlordane chlordane epoxide
cis- Nonachlor
trans- Nonachlor
Largescale Sucker
22 22
47 47
51 51 51
12499000 YK0331SF 10 <10 <10 <10 12499000 YK0331SF 10 <10 <10 <10
12509050 YK0047SF 20 <10 <10 <10 12509050 YK0047SF 20 <10 <10 <10
12510500 YK0402SF 20 10 10 10 12510500 YK0402SF 20 10 10 10 12510500 YK0403SF 30 10 20 20
<10 <10
<10 <10
<10 <10 <10
<10 <10
20 20
30 40 40
Asiatic Clam
40 40 40 40
47 47
51 51
12507585 YK0100SM <10 <10 <10 <10 12507585 YK0101SM <10 <10 <10 <10 12507585 YK0102SM <10 <10 <10 <10 12507585 YK0103SM <10 <10 <10 <10
12509050 YK0082SM <10 <10 <10 <10 12509050 YK0085SM <10 <10 <10 <10
12510500 YK0115SM <10 <10 <10 <10 12510500 YK0116SM <10 <10 <10 <10
<10 <10 <10 <10
<10<10
<10 <10
<10 <10 <10 <10
<10 <10
<10 <10
Western Pearlshell
14 14
12484500 YK0111SM <10 <10 <10 <10 12484500 YK0111SM <10 <10 <10 <10
<10 <10
<10 <10
Waterweed
26 26
12500442 YK0098SP <10 <10 <10 <10 12500442 YK0098SP <10 <10 <10 <10
<10 <10
<10 <10
141
Table 56. Concentrations of organochlorine compounds in field-replicate and laboratory-split samples of aquatic biota, Yakima River basin, Washington, 1989-90 Continued
Map refer ence number
22 22
47 47
51 51 51
40 40 40 40
47 47
51 51
14 14
26 26
Map refer ence number
Station number
12499000 12499000
12509050 12509050
12510500 12510500 12510500
12507585 12507585 12507585 12507585
12509050 12509050
12510500 12510500
12484500 12484500
12500442 12500442
Station number
Field number
YK0331SF YK0331SF
YK0047SF YK0047SF
YK0402SF YK0402SF YK0403SF
YK0100SM YK0101SM YK0102SM YK0103SM
YK0082SM YK0085SM
YK0115SM YK0116SM
YK0111SM YK0111SM
YK0098SP YK0098SP
Field number
o,p'" P.P 1 - o,p'- P.P'- o,p'~ DDD ODD DDE DDE DOT
Largescale Sucker
10 50 <10 410 <10 10 50 <10 380 <10
50 290 <10 2,500 <10 50 290 <10 2,400 <10
40 300 30 2,000 <10 40 300 30 2,100 <10 50 390 30 2,200 <10
Asiatic Clam
10 60 <10 310 <10 10 50 <10 280 <10 10 60 <10 330 <10 10 40 <10 230 <10
20 80 <10 390 <10 30 100 10 530 <10
20 80 10 410 <10 20 60 <10 360 <10
Western Pearlshell
as <\°0 <i° as <i°0Waterweed
<10 <10 <10 10 <10 <10 <10 <10 10 <10
g-Hexachloro- Hexachloro- a-Hexachloro- b-Hexachloro- cyclohexane benzene cyclohexane cyclohexane (lindane)
p.p'DOT
70 80
370 370
190 190 220
80 70 80 60
40 60
50 30
as
as
d-Hexachloro- cyclohexane Toxaphene
Largescale Sucker
22 22
47 47
51 51 51
12499000 12499000
12509050 12509050
12510500 12510500 12510500
YK0331SF YK0331SF
YK0047SF YK0047SF
YK0402SF YK0402SF YK0403SF
<10 <10 <10 <10
<10 <10 <10 <10 <10 <10 ^10 <10 <10 <10 <10 <10
:ii<50 <50
520 560
710 710 720
Asiatic Clam
40 40 40 40
47 47
51 51
12507585 12507585 12507585 12507585
12509050 12509050
12510500 12510500
YK0100SM YK0101SM YK0102SM YK0103SM
YK0082SM YK0085SM
YK0115SM YK0116SM
<10 <10 <10 < 10 <10 <10 <10 <10 <10 <10 <10 <10
<10 <10 <10 <10
<10 <10 <10 <10 <10 <10 <10 <10
<10
<io
<50 <50 <50 <50
<50 <50
<50 <50
Western Pearlshell
14 14
12484500 12484500
YK0111SM YK0111SM ^ ^ ^ ^ as <50
<50
Waterweed
26 26
12500442 12500442
YK0098SP YK0098SP 35 :i° :% :\° <io <50
<50
142
Table 56. Concentrations of organochlorine compounds in field-replicate and laboratory-split samples of aquatic biota, Yakima River basin, Washington, 1989-90 Continued
Map refer ence number
Station number
Field number
Total PCBs
Octochloro- Dieldrin Endrin Mirex Kepone styrene Dicofol
Largescale Sucker
2222
A7A7
515151
12A9900012A99000
1250905012509050
125105001251050012510500
YK0331SFYK0331SF
YKOOA7SFYKOOA7SF
YKOA02SFYKOA02SFYKOA03SF
<50<50
290300
790790900
<10 <10<10 <10
80 <1070 <10
60 <1060 <1090 <10
<10<10
<10 <10 <10 20<10 <10 <10 20
<10 -- -- <10<10 -- -- <10<10 - - <10
Asiatic Clam
AOAOAOAO
A7A7
5151
12507585125075851250758512507585
1250905012509050
1251050012510500
YK0100SMYK0101SMYK0102SMYK0103SM
YK0082SMYK0085SM
YK0115SMYK0116SM
<50<50<50<50
<50<50
<50<50
10 <10 <10 <10 <10 <1010 <10 <10 <10 <10 <1010 <10 <10 <10 <10 <1010 <10 <10 <10 <10 <10
20 <10 <10 <10 <10 <1020 <10 <10 <10 <10 <10
10 <10 <10 <10 <10 <1010 <10 <10 <10 <10 <10
Western Fearlshell
12A8A500 12A8A500
YK0111SM YK0111SM
<50 <50
Waterweed
2626
12500A42 12500AA2
YK0098SP YK0098SP
<50 <50
143
Table 57. Concentrations of semi-volatile organic compounds (polycyclic-aromatic hydrocarbons) in field-replicate and laboratory-split samples of aquatic biota, Yakima River basin, Washington, 1989-90
[Concentrations in micrograms per kilogram, wet weight; whole fish were analyzed; see figure 1 for site locations; "Replicate" = two or more composite samples were collected at a station on the same day and were analyzed individually; "Split" = a single composite sample was homogenized, split into 2 samples at the lab, and each split was analyzed]
Quality-assurancesampletype
Mapreferencenumber
Stationnumber Station name Date
Fieldnumber
Moisture, Lipid,in percent in percent
Asiatic Clam
ReplicateReplicateReplicateReplicate
ReplicateReplicate
ReplicateReplicate
40404040
4747
5151
12507585125075851250758512507585
1250905012509050
1251050012510500
YakimaYakimaYakimaYakima
YakimaYakima
YakimaYakima
RiverRiverRiverRiver
at RM 72 ab Satus Cr nr Sunnysideat RM 72 ab Satus Cr nr Sunnysideat RM 72 ab Satus Cr nr Sunnysideat RM 72 ab Satus Cr nr Sunnyside
R at Euclid Br at RM 55 nr GrandviewR at Euclid Br at RM 55 nr Grandview
RiverRiver
at Kionaat Kiona
11-01-8911-01-8911-01-8911-01-89
10-31-8910-31-89
10-30-8910-30-89
YK0100SMYK0101SMYK0102SMYK0103SM
YK0082SMYK0085SM
YK0115SMYK0116SM
76.0 2.4078.0 2.3279.0 2.6282.0 1.96
95.5 1.6482.0 2.20
83.0 2.2084.0 1.95
Western Pearlshell
SplitSplit
1414
1248450012484500
YakimaYakima
RiverRiver
at Umtanumat Umtanum
11-01-8911-01-89
YK0111SMYK0111SM
86.0 .9284.0 .86
Waterweed
SplitSplit
2626
1250044212500442
Wide Hollow Cr at Old STP at Union GapWide Hollow Cr at Old STP at Union Gap
11-04-8911-04-89
YK0098SPYK0098SP
94.0 .2094.0 .10
Mapreferencenumber
Stationnumber
Fieldnumber Napthalene
Phenan- Anthra-Fluorene threne cene
Fluor -anthrene Pyrene
1,2-Benz-anthracene
Asiatic Clam
40404040
4747
5151
12507585125075851250758512507585
1250905012509050
1251050012510500
YK0100SMYK0101SMYK0102SMYK0103SM
YK0082SMYK0085SM
YK0115SMYK0116SM
10<10<1010
1020
<1010
<10 30 <10<10 30 <1010 30 <10
<10 40 <10
<10 40 <10<10 30 <10
10 90 <10<10 40 <10
10101010
<1010
2050
<10<10<10<10
<1010
<10<10
<10<1010
<10
<10<10
<10<10
Western Pearlshell
1414
1248450012484500
YK0111SMYK0111SM
<1010
<10 <10 <10<10 10 <10
<10<10
<10<10
<10<10
Waterweed
2626
1250044212500442
YK0098SPYK0098SP
<10<10
<10 <10 <10<10 <10 <10
<10<10
<10<10
<10<10
144
Table 57. Concentrations of semi-volatile organic compounds (polycyclic-aromatic hydrocarbons) in field-replicate and laboratory-split samples of aquatic biota, Yakima River basin, Washington, 1989-90 Continued
Map refer ence number
Station number
Field number Chrysene
Benzo(b)- fluoranthrene
Benzo(k)- fluoranthrene
Benzo(e)- Benzo(a)- 1,2,5,6-Dibenz- Benzo(g,h,i)- pyrene pyrene anthracene perylene
Asiatic Clam
40404040
4747
5151
12507585-125075851250758512507585
1250905012509050
1251050012510500
YK0100SM <10 <10 <10 <10 <10 <10 <10YK0101SM <10 <10 <10 <10 <10 <10 <10YK0102SM <10 <10 <10 <10 <10 <10 <10YK0103SM <10 <10 <10 <10 <10 <10 <10
YK0082SM ^10 ^10 ^10 ^10 ^10 ^10 <10YK0085SM <10 <10 <10 <10 <10 <10 <10
YK0115SM <10 <10 <10 <10 <10 <10 <10YK0116SM <10 <10 <10 <10 <10 <10 <10
Western Fearlshell
1248450012484500
YK0111SM YK0111SM
Waterweed
2626
1250044212500442
YK0098SP YK0098SP
1010
145
APPENDIX A
METHOD FOR ANALYZING TRACE-ORGANIC COMPOUNDS IN FILTERED WATER
Dissolved-Phase Preconcentration
The Goulden Large Sample Extractor (GLSE), a continuous-flow liquid-liquid extractor (Goulden and Anthony, 1985), was used to extract small concentrations of organic compounds from large volumes of water. A schematic representation of the GLSE (Alien Scientific Glassware, Boulder, Colorado) is shown in figure Al. The dimensions of the mixer- settler portion of the GLSE were similar to that initially described by Goulden and Anthony, 1985.
The water sample was pumped at a flow rate of 350 mL/min (milliliters per minute) through Teflon tubing from a tared, stainless - steel, milk can into chamber A of the GLSE using a positive displacement pump [PI] (Model RP-D-2CSC, Fluid Metering Inc.) [fig. Al]. The sample was mixed with the dichloromethane (DCM) extraction solvent using a stirrer blade positioned in chamber A approximately 2 cm (centimeters) from the bottom. The stirrer motor (Fisher Dyna-Mix) was mounted just above the top opening of chamber A. The positioning, blade configuration, and rotation of the stirrer forced the incoming water upward in mixing chamber A and downward in the settling chamber B. This configuration provided efficient mixing, while minimizing the formation of emulsions (Goulden and Anthony, 1985). Column D consisted of a high- density polypropylene Buchner flat-bottom funnel that was packed with 4 mm (millimeters) x 4 mm Teflon Raschig rings. This column was placed over chamber C and was designed to minimize loss of DCM droplets and help break up emulsions (Goulden and Anthony, 1985). A final settling chamber [E] consisted of a Teflon separatory funnel and was positioned downstream of chamber C to collect any remaining DCM droplets. Additional air vents were positioned in the top of the GLSE between chambers A and C, and between C and E.
During the extraction process, a substantial volume of DCM was lost in the effluent water exiting chamber E, because DCM is appreciably soluble in water (about 1.6 percent by volume at 20°C [degrees Celsius]). In addition, some DCM is lost because of volatilization from the open-top design of the GLSE. To counter this loss, DCM was replenished by pumping solvent from a reservoir by another positive displacement pump [P2] (Model RP-SY-1CSC, Fluid Metering Inc.) through an opening at the top of chamber C directly into the packing in column D. Introduction of fresh solvent into column D also helped to extract remaining analytes from the water (Goulden and Anthony, 1985).
It should be noted that large volumes of DCM-saturated waste water, generated by the GLSE system used in this study, present a considerable disposal problem, especially for field applications. In addition, the vapor loss from its open-top design results in a significant vapor exposure potential. A newer version of the GLSE has recently been developed (oral commun., March 1992, D.H.J. Anthony, Environment Canada, National Water Research Institute, Burlington, Ontario) that reduces solvent vapor loss and incorporates a solvent-recovery system, although the latter necessitates much slower flow rates (about 2 L (liters) per hour).
146
DICHLOROMETHANE (DCM)
EXPLANATIONP1 Positive displacement pump 1A Mixing chamber AB Settling chamber BC Settling chamber CD Column D-Designed to minimize loss of solventE Final Settling Chamber EP2 Positive displacement pump 2
F, G, H Stopcocks for draining system
Figure Al. Goulden Large-Sample Extractor.
147
Prior to processing every natural, spike, or blank sample, the GLSE and support hardware were cleaned by pumping 100 mL of acetone and 100 mL of methanol through the Teflon inlet tubing into chamber A using sample pump PI. The extractor also was rinsed thoroughly with acetone and methanol. For the final rinse, the extractor system was filled with 10 L of charcoal-filtered tap water via pump PI, and then drained.
The GLSE was operated by initially adding 250 mL of DCM to the extractor. The sample pump (PI) was started and, when the extractor was half-filled, the stirrer was started. As the sample finished filling the extractor, 50 mL of DCM were used to charge the Raschig rings in column D. The stirrer speed was adjusted so that a homogeneous mixture of sample and DCM was maintained and only a small number of droplets spilled over into chamber C. A solvent level midway between chambers A and C was maintained by continuously introducing fresh DCM at 9 mL/min into the packed column D with pump P2. Once started, a sample was extracted continuously without interruption. Sample volumes processed through the GLSE ranged from 4.4 to 112 L, depending on the expected target-analyte concentrations. After the sample was pumped through the extractor, 500 mL of distilled water was pumped into the extractor by pump PI to ensure that all of the sample had reached the GLSE. The pumps and stirrer were then stopped and the DCM-water mixture was allowed to separate. The DCM fraction was drained through stopcock G into a 500-mL amber-glass bottle that was pre-cleaned by acid rinsing and heating to 450°C for 8 hours. The water in the GLSE was drained through stopcock F until the water level was below column D. Fifty milliliters of DCM were poured through column D, and following settling, the DCM was collected through stopcock G. Water in the extractor was carefully drained through stopcock F to avoid losing any solvent droplets still present. After all the water was removed from the GLSE, the extractor was meticulously rinsed with DCM, which was collected through stopcock G into the amber-glass bottle. Additionally, any DCM droplets in separatory funnel E were collected through stopcock H. Extracts were packed in ice for shipment to the U.S. Geological Survey Laboratory (Methods Research and Development Program in Arvada, Colorado). At the lab, the samples were stored in a refrigerator until volume reduction prior to analysis. During the filtration and extraction process, the solvents and samples only came into contact with Teflon, glass, or stainless steel, except for column D in the Goulden extractor which was made of high-density polypropylene.
GLSE Precleaning and Assembly
Before shipment to the field lab, all GLSE parts that would come in contact with sample or solvent were precleaned with Alconox soap solution, and rinsed with tap and distilled water and acetone. Non- glass components also were rinsed in methanol and DCM prior to being wrapped in clean (baked) aluminum foil. The glass components of the GLSE were then baked for 12 hours in a 450°C oven, and the openings were wrapped in clean aluminum foil. All components were then carefully packed for shipment to the field.
148
At the field lab, the GLSE was attached to a support-rack system contained within a wooden shipping box. The GLSE required electrical power for operation of the sample (PI) and solvent-metering (P2) pumps and the stirrer. The GLSE and filtration pumps were calibrated in the field to verify flows.
Laboratory Preparation of GLSE Extracts
Residual water was removed from extracts using a Teflon separatory funnel and by subsequently passing the extract through anhydrous sodium sulfate. Dried extracts were vacuum-rotary evaporated at 30°C to a volume of approximately 5 mL. Toluene was added as a keeper solvent to the 5-mL extracts, and volume was further reduced by evaporation with ultra-pure nitrogen to a final volume of 0.2 mL.
Ins trumentation
All GLSE extracts were spiked with a perdeuterated-polycyclic- aromatic- hydrocarbon (PAH) internal-injection standard and analyzed by gas chromatography/mass spectrometry (GC/MS) using a Hewlett-Packard (HP) 5890A GC, equipped with a HP 5970 MSD (mass selective detector) and a HP 7673A autosampler. The GC/MSD was fitted with a 30-meters (m) long, 2.5-mm internal diameter, 0.25-micrometers-film-thickness-fused- silica, capillary column (Model DB-1701, J & W Scientific, Inc.). Compound separations were performed using the following temperature program: 80°C initial temperature for 2 minutes; followed by a 20°C per minute gradient to 120°C; followed by a 2.5°C per minute to 285°C with 18.5-minute hold time. The injector and transfer line were set at 250°C and 285°C, respectively. Two-microliter splitless injections were performed by the HP 7673A autosampler. The helium carrier gas had a linear velocity of 32 cm/s (centimeter per second) at 50°C. The split sweep and septum purge were set at 30 and 3 mL/min, respectively. The Grob split time was set at 2 minutes for all injections.
Electron-impact ionization mass spectrometric analysis was conducted at an energy of 70 electronvolts (eV), The ion source temperature was 200°C. The electron multiplier voltage ranged between 1,400 and 2,000 volts (V). Selected ion monitoring for the parent ion and two other characteristic ions was used.
Quantification
All integrations were performed by a HP 59970C 9000 Series Model 216 Chemstation. Response factors relative to perdeuterated PAH's were determined from 0.05, 0.10, 0.25, 0.50, 1.0, and 5.0 ng/^L (nanograms per microliter) standards, for sets of 10 to 16 samples. Modified Lee retention indices (Lee and other, 1979) were calculated using the internal-injection standard as the retention index markers on the DB- 1701 column. Quantification levels were determined using the approach of Miller and Miller (1986). The presence of an analyte required: agreement with the relative retention indices, the presence of the parent peak, and the confirmation of the ion abundances of at least one of the characteristic ions relative to the parent peak. Additionally, concentrations needed to exceed analytical noise in order to be quantifiable.
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Reagents
All solvents were pesticide-residue grade obtained from Burdick and Jackson, Muskegon, Michigan. Pesticide reference standards were obtained from the U.S. Environmental Protection Agency Pesticide Repository, Research Triangle Park, North Carolina. Perdeuterated naphthalene, phenanthrene, fluoranthene, chrysene, and perylene, atrazine ethylamine d-5 (atrazine d-5), gamma-hexachlorocyclohexane d-6 (gamma-HCH d-6), p,p'-DDT d-8, and diazinon diethyl d-10 were obtained from Cambridge Isotopes, Woburn, Massachusetts. Perdeuterated benzo(ghi)perylene was obtained from MSD Isotopes, Montreal, Ontario, Canada. Pesticide stock solutions were formulated from accurately weighed pure standards, at approximately 1,000 ng//*L concentrations in ethyl acetate. All deuterated stock solutions were made in toluene. All pesticides were combined into 50-ng//iL mixed-standard solutions. GC/MS calibration standards were prepared independently from the mixed standard solutions. Instrumental calibration standard solutions were formulated in toluene. A surrogate standard containing atrazine d-5, gamma-HCH d-6, diazinon diethyl d-10, p,p'-DDT d-8, isodrin, and terbuthylazine was formulated at 10 ng//iL in methanol. A separate, 50- ng//*L, mixed standard containing the perdeuterated PAH was prepared. The internal-injection standard solution contained the perdeuterated PAH, naphthalene d-8, phenanthrene d-10, fluoranthene d-10, chrysene d- 12, and benzo(ghi)perylene d-12 diluted to 2.5 ng//iL in toluene.
Quality-Assurance Procedures
Quality-assurance samples represented a large percentage of the total samples processed in the GLSE, because this apparatus was in the evaluation stage. Of the 57 total GLSE extractions performed in the 1989 Yakima study, 32 were stream and well samples (including 4 replicate samples from one site), 12 were spiked samples, and 13 were system and extractor blanks.
Blanks were run for most phases of the procedure. Large volumes of distilled water were prepared in clean glass carboys and transported to the field lab. Field blanks were analyzed to determine extraneous sources of contamination during the filtration and extraction phases of the procedure. GLSE system blanks were prepared by pouring 10 to 20 L of distilled water into a clean milk can and processing it through the filtration unit using a clean glass-fiber filter. The system blank water was then extracted in the GLSE as described above for the stream and well samples.
Extractor blanks were run following every field-matrix spike sample to assess whether the GLSE cleaning procedure was adequate. Extractor blanks were not passed through the filtration apparatus, but were spiked with a surrogate solution and processed through the GLSE as with the system blanks and samples. Because of limitations in the volume of distilled water available to process blanks, extractor- and system-blank water volumes processed through the GLSE ranged from only 5 to 7.7 L for the 1989 trip, whereas stream and well-water sample volumes ranged from 4.4 to 112 L of water. Sampling-equipment blanks were not processed in the field because of an insufficient supply of distilled water. A
150
background site in the Wenatchee National Forest was sampled to assay environmental contributions not directly associated with agricultural pesticide applications in the Yakima River basin.
A surrogate solution was added to all GLSE samples prior to the extraction by spiking the filtered water during the filtration process to provide an estimate of the overall method performance. The surrogates were selected based on their physical and chemical similarity to the various target compound groups. The use of GC/MS also allowed for the selection of deuterated analogs of several target compounds (for example, diazinon d-10, atrazine d-5, gamma-HCH d-6, and p,p'-DDT d-8). However, because of differences in physical and chemical properties (like solubility and DCM-water partition coefficients), surrogate recoveries do not necessarily reflect recoveries for all of the other analytes within a particular pesticide class.
In June 1989, GLSE method performance for all target analytes was monitored by determining recoveries using field-matrix spikes. The spiking solution contained 68 pesticides in methanol and was added to the filtered water. Single-matrix spike samples were added at approximately 50 ng/L for the four 11- to 12- L samples, 25 ng/L for the two 36-L samples, and 11 ng/L for the two 110-L samples (table 40, Quality-assurance Data section). To assess precision, triplicate, 10-L samples from the Yakima River at Kiona were spiked at 50 ng/L (table 40, Quality-assurance Data section). Pesticide spikes were allowed to equilibrate with a sample for at least 30 minutes prior to extraction. Analytical recoveries in spiked samples were corrected for the amount of pesticides present in the duplicate samples of unspiked filtered stream water.
151
APPENDIX B
METHOD FOR ANALYZING TRACE-ORGANIC COMPOUNDS IN SUSPENDED SEDIMENT
Suspended-sediment samples collected in June 1989 were not all analyzed in the same laboratory, because the U.S. Geological Survey Methods and Research Development Laboratory was not prepared to analyze large numbers of suspended-sediment samples (29 stream samples plus quality-assurance samples). The samples were not analyzed using the same method, because procedural problems were recognized during sample- processing steps. The location of the laboratories where the samples were processed is listed in table Bl in this appendix for sample sets 1, 2, and 3. The method of analysis for sample set 3 is listed in Wershaw and others (1987); methods of analysis for sample sets 1 and 2 are described in this appendix.
Procedure for Analyzing Set-1 Samples
All suspended-sediment samples (sediment trapped on filters) were kept frozen until they were analyzed in October and November 1989. Prior to extraction, filters containing suspended sediment were thawed. Wet filters were placed into soxhlet extractors and spiked with a surrogate solution containing diazinon d-10 (10 hydrogens were deuterated), gamma-HCH d-6, p,p'-DDT d-8, and atrazine d-5. The filters were soxhlet extracted (using a solvent mix of 70 percent cyclohexane and 30 percent isopropanol) dried and concentrated to about 5 mL using vacuum-rotary evaporation, and further concentrated to 1 mL using nitrogen blowdown. The samples were then cleaned up and fractionated into two fractions using two rinses of a solvent mix (30 mL of a solvent mix containing 50 percent dichloromethane, 48.5 percent cyclohexane, and 1.5 percent acetonitrile) in a Florisil-sorbent-cartridge cleanup procedure. The first fraction contained most of the organochlorine compounds and some of the organophosphorus compounds. The first- fraction samples were (1) solvent exchanged to toluene and further reduced in volume to about 200 /zL (microliters), (2) transferred to gas chromatograph vials, (3) spiked with a perdeuterated-polycyclic- aromatic-hydrocarbons (PAH), internal-injection-standard solution, and (4) analyzed by GC/MS at the USGS Methods and Research Development laboratory. The second-fraction samples from the Florisil-sorbent cleanup procedure were not analyzed by GC/MS.
To obtain minimum reporting levels, samples were processed further for analyses of (1) organophosphorus compounds using a gas chromatograph with a flame-photometric detector (GC/FPD) and (2) organochlorine compounds using a gas chromatograph with an electron-capture detector (GC/ECD). In preparation for analysis of organophosphorus compounds, Florisil fractions 1 and 2 were recombined, solvent exchanged to toluene, and reduced to a final volume of 500 /zL. For the Yakima River at Euclid Bridge station, only the second-fraction extract was available for GC/FPD and GC/ECD analyses. The analysis was made using dual- column-capillary GC/FPD with DB-5 and DB-1701 columns. In preparation for analyses of organochlorine compounds, the set-1 samples were solvent exchanged to n-octane prior to alumina/silica column fractionation. The glass columns were dry packed with 3 g (grams) of alumina (heated to
152
Table Bl. Analytical laboratories where suspended-sediment samples were processed for analysis of trace-organic compounds, Yakima River basin, Washington, June 1989
[Sample sets were analyzed at U.S. Geological Survey Methods and Research Development Laboratory in Arvada, Colorado. RM River mile, see table 2 of main report for map reference numbers and figure 1 of main report for site locations]
Station number Station name
SAMPLE SET 1
Yakima River at Cle ElumYakima River at UmtanumUmtanum Creek nr mouthPacific Power & Light Company WastewayNaches River nr North YakimaYakima R abv Ahtanum CreekYakima River at RM 72Yakima R at Euclid Br at RM 55Yakima River at Kiona
SAMPLE SET 2
City of Yakima - Finish WaterMoxee Drain at Thorp RdGranger Drain at mouthWell 1, Sunnyside (09N/22E-04P01)Well 2, Harrah (11N/18E-22R02)South Drain nr SatusSulphur Creek Wasteway
SAMPLE SET 3
Cooper River at Salmon LaSacWilson Cr abv. Cherry CreekCherry Creek at ThrallWide Hollow Creek near mouthAhtanum Creek at Union GapE Toppenish Drain at Wilson RdSub 35 Drain at Parton RoadMarion Drain, Indian Church RdToppenish Cr, Indian Church RdSatus Cr abv Wilson-Charley Canyon nr ToppenishSatus Cr at gage at SatusSpring Creek at mouthSnipes Creek at mouth
124795001248450012484550124965101249900012500450125075851250905012510500
124965111250043012505460461720120043246251012032391250863012508850
12478200124841001248448012500445125025001250535012505410125055101250750812507594125086201250971012509829
153
135°C and 1-percent water deactivated) over 6 g silica (heated to 135°C and 5-percent water deactivated). The column was topped with 1 cm (of column height) of sodium sulfate (cleaned by heating overnight at 450°C), and prerinsed with a 35-mL solution of 25-percent ethyl acetate and 75-percent hexane followed by hexane rinses of 35 mL and 25 mL. Samples ranged in volume from 0.5 to 1 mL; they were separately added to the column and eluted with 35 mL of hexane (fraction A), followed by a 25-mL solution of 25-percent ethyl acetate and 75-percent hexane (fraction B). Fractions (A and B) were reduced in volume to 0.5 mL using nitrogen gas and then analyzed by dual-capillary-column GC/ECD using Restek Rtx 5 and 1701 columns.
Procedure for Analyzing Set-2 Samples
Set-2 samples were processed and extracted in January 1990. The procedure was identical to the set-1 procedure up to the Florisil sorbent cleanup step. Set-2 samples were not fractionated on Florisil and were not analyzed by GC/MS. In preparation for organophosphorus (GC/FPD) analyses, set-2 samples were reduced in volume to 500 /zL using cyclohexane as the final solvent. The GC/FPD analytical procedures for the set-2 samples were identical to the procedures used for the set-1 samples. In preparation for organochlorine (GC/ECD) analyses, the set-2 extracts in cyclohexane were cleaned up and fractionated on a combined alumina/silica column. The cleanup, fractionation, and GC/ECD analytical procedures for set-2 samples were identical to procedures used for the set-1 samples.
154