SURFACE-WATER-QUALITY ASSESSMENT OF THE YAKIMA RIVER … › of › 1992 › 0644 › report.pdf · July 26, 1988, at 1000 hour and 1015 hour ----- 101 31B. Cherry Creek at Thrall,

SURFACE-WATER-QUALITY ASSESSMENT OF THE YAKIMA RIVER BASIN, WASHINGTON: PESTICIDE AND OTHER TRACE-ORGANIC-COMPOUND DATA FOR WATER, SEDIMENT, SOIL, AND AQUATIC BIOTA, 1987-91By J.F. Rinella, S.W. McKenzie, J.K. Crawford, W.T. Foreman,

P.M. Gates, G.J. Fuhrer, and M.L. Janet

Delmarva Peninsula

U.S. GEOLOGICAL SURVEY Open-File Report 92 644

Portland, Oregon 1992

DEPARTMENT OF THE INTERIOR

MANUEL LUJAN, JR., Secretary

U.S. GEOLOGICAL SURVEY

Dallas L. Peck, Director

For additional information write to: Copies of this report can bepurchased from:

District Chief Bookg and Q File ReportsU.S. Geological Survey Box 25425Water Resources Division U s Geological Survey10615 SE. Cherry Blossom Drive Federal center,Building 810Portland, Oregon 97216 Denver, Colorado 80225

CONTENTS

Page

Abstract ---------------------------------------------------------- 1Introduction ------------------------------------------------------ 1

Background --------------------------------------------------- 2Purpose and scope -------------------------------------------- 2Acknowledgments ---------------------------------------------- 3

Data collection and analysis -------------------------------------- 4Sampling plan ------------------------------------------------ 4Sample collection, processing, and preservation -------------- 4

Whole water --------------------------------------------- 14Filtered water and suspended sediment ------------------- 14Bed sediment and soil ----------------------------------- 15Aquatic biota ------------------------------------------- 15

Laboratory methods ------------------------------------------- 17Quality assurance -------------------------------------------- 17

References -------------------------------------------------------- 19Analytical data --------------------------------------------------- 21

Water-column tables ------------------------------------------22-59Bed-sediment and soils tables --------------------------------60-69Aquatic-biota tables -----------------------------------------70-96

Quality-assurance data -------------------------------------------- 97Water-column tables -----------------------------------------98-116Filtered-water tables --------------------------------------117-125Suspended-sediment tables ----------------------------------126-133Bed-sediment tables ----------------------------------------134-137Aquatic-biota tables ---------------------------------------138-145

Appendix A--Method for analyzing trace-organic compounds infiltered water ------------------------------------------------- 146

Appendix B--Method for analyzing trace-organic compounds insuspended sediment --------------------------------------------- 152

ILL

ILLUSTRATIONSPage

Figure 1. Map showing location of sampling stations for trace- organic compounds in water, suspended sediment, bed sediment, soil, and aquatic biota, Yakima River basin, Washington, 1987-91 -------------------- 10

TABLES

Table 1. Sampling plan for collecting trace-organic-compoundsamples, Yakima River basin, Washington, 1987-91 ----- 5

2. Sampling locations for pesticide and other trace-organic compounds in water, bed sediment, soil, and aquatic biota, Yakima River basin, Washington, 1987-91 ------- 7

3. Common technical name and biological activity of pesticides analyzed in water, sediment, soil, and aquatic biota, Yakima River basin, Washington, 1987-91 ---------------------------------------------- 11

4. Laboratories where whole-water, filtered-water, suspended-sediment, bed-sediment, soil, and aquatic-biota samples were analyzed, Yakima River basin, Washington, 1987-91 -------------------- 18

Analytical Data Water Column

5. Field measurements, suspended sediment, turbidity, organic carbon, and selected nutrient data for surface-water and ground-water sites where water samples were collected, Yakima River basin, Washington, 1988-91 --------------------------------- 22

6. Concentrations of carbamate compounds in whole-watersamples, Yakima River basin, Washington, 1988-91 ---- 27

7. Concentrations of carbamate, thiocarbamate, pyrethoid, and other pesticides in filtered-water samples, Yakima River basin, Washington, June 25-30, 1989 ---- 30

8. Concentrations of chlorophenoxy-acid herbicides, dicamba, and picloram in whole-water samples, Yakima River basin, Washington, 1988-91 ------------- 31

9. Concentrations of chlorophenoxy-acid herbicides, dicamba and picloram in filtered-water samples, Yakima River basin, Washington, June 25-30, 1989 ---- 32

10. Concentrations of organochlorine compounds in whole-water samples, Yakima River basin, Washington, 1988-89 --------------------------------- 33

11. Concentrations of organochlorine compounds in filtered-water samples, Yakima River basin, Washington, June 25-30, 1989 ------------------------ 37

12. Concentrations of organochlorine compounds in filtered-water samples, Yakima River basin, Washington, May-September 1991 ---------------------- 39

13. Concentrations of organochlorine compounds associated with suspended sediment, Yakima River basin, Washington, June 25-30, 1989 ----------------------- 41

iv

TABLES--Continued Analytical Data--Continued Water Column--Continued

Page

14. Concentrations of organochlorine compounds associated with suspended sediment, Yakima River basin, Washington, May-September 1991 ---------------------- 43

15. Concentrations of organophosphorus pesticides in whole-water samples, Yakima River basin, Washington, 1988-89 --------------------------------- 45

16. Concentrations of organophosphorus pesticides in filtered-water samples, Yakima River basin, Washington, June 25-30, 1989 ------------------------ 48

17. Concentrations of organphosphorus pesticides in filtered-water samples, Yakima River basin, Washington, May-September 1991 ---------------------- 50

18. Concentrations of organophosphorus pesticidesassociated with suspended sediment, Yakima Riverbasin, Washington, June 25-30, 1989 ----------------- 51

19. Concentrations of organophosphorus pesticidesassociated with suspended sediment, Yakima Riverbasin, Washington, May-September 1991 --------------- 52

20. Concentrations of phenol and cresol compounds (acid-extractable compounds) in whole-water samples, Yakima River basin, Washington, 1988-89 ---- 53

21. Concentrations of triazine, acetamide,chloroacetanilide, and other pesticidesin whole-water samples, Yakima River basin,Washington, 1988-89 --------------------------------- 54

22. Concentrations of triazine, acetamide,chloroacetanilide, and trifluromethyl compounds in filtered-water samples, Yakima River basin, Washington, June 25-30, 1989 ------------------------ 57

23. Concentrations of volatile organic compounds(halogenated aliphatic and monocyclic aromatichydrocarbons) in whole-water samples, YakimaRiver basin, Washington, 1988-89 -------------------- 58

Bed Sediment and Soils

24. Concentrations of organochlorine compounds, total carbon, and inorganic carbon in bed-sediment and soil samples, Yakima River basin, Washington, 1987-90 -------------------------- 60

25. Concentrations of organophosphorus pesticides in soilsamples, Yakima River basin, Washington, 1989 ------- 63

26. Concentrations of semi-volatile organic compounds (phthalate esters, ethers, phenols, cresols, and monocyclic- and polycyclic-aromatic compounds) in bed-sediment samples, Yakima River basin, Washington, 1987-90 --------------------------------- 63

TABLES- -Continued Analytical Data--Continued

Aquatic BiotaPage

Aquatic Biota

27. Ancillary data, for composite biological samples,collected for analysis of trace-organic compounds, Yakima River basin, Washington, 1989-90 ------------- 70

28. Concentrations of organochlorine compounds inaquatic biota, Yakima River basin, Washington,1989-90 --------------------------------------------- 84

29. Concentrations of semi-volatile organic compounds (polycyclic-aromatic hydrocarbons) in aquatic biota, Yakima River basin, Washington, 1989-90 ------ 94

Quality Assurance Data Water Column

30A-H. Concentrations of carbamate compounds in replicate and (or) spiked whole-water samples from the following locations, Washington:

30A. Cle Elum River above Cle Elum Lake near Roslyn,July 26, 1988, at 1000 hour and 1015 hour ------ 98

SOB. Cherry Creek at Thrall, June 2, 1988, at1400 hour and 1405 hour ------------------------ 98

30C. Wide Hollow Creek near mouth at Union Gap,November 15, 1988, at 1330 hour and 1430hour ------------------------------------------- 98

30D. Moxee Drain at Thorp Road near Union Gap,May 6, 1988, at 0930 hour and 0940 hour -------- 99

30E. Granger Drain at mouth near Granger,July 28, 1988, at 0930 hour and 1015 hour ------ 99

30F. Sulphur Creek Wasteway near Sunnyside,August 31, 1988, at 1530 hour and 1630 hour ---- 99

30G. Buckskin Slough below Gleed Ditch near Gleed,May 22, 1991, at 1100 hour and 1107 hour ------- 100

30H. Buckskin Slough below Gleed Ditch near Gleed,August 7, 1991, at 1000 hour and 1007 hour ----- 100

31A-G. Concentrations of chlorophenoxy-acid herbicides, dicamba, and picloram in replicate and (or) spiked whole-water samples from the following locations, Washington:


31B. Cherry Creek at Thrall, June 2, 1988, at 1400hour and 1405 hour ----------------------------- 101

31C. Wide Hollow Creek near mouth at Union Gap,November 15, 1988, at 1330 hour and 1430hour ------------------------------------------- 101



vi

TABLES - -ContinuedQuality Assurance Data--Continued

Water Column--ContinuedPage


31G. Buckskin Slough below Gleed Ditch near Gleed,May 22, 1991, at 1100 hour and 1107 hour ------- 103

32A-G. Concentrations of organochlorine and organophosphorus compounds in replicate and (or) spiked whole-water samples from the following locations, Yakima River basin, Washington:


32B. Cherry Creek at Thrall, June 2, 1988, at 1400 hourand 1405 hour ---------------------------------- 104

32C. Wide Hollow Creek near mouth at Union Gap,November 15, 1988, at 1330 hour and 1430 hour -- 105




32G. Well (station identifier: 12N/19E-09H01)January 20, 1989, at 0730 hour and 0737 hour --- 107

33A-B. Concentrations of phenols and cresols (acid-extractable compounds) in replicate and (or) spiked whole-water samples from the following locations, Yakima River basin, Washington:

33A. Wide Hollow Creek near mouth at Union Gap,November 15, 1988, at 1330 hour and 1430 hour -- 108

33B. Sulphur Creek Wasteway near Sunnyside,August 31, 1988, at 1530 hour and 1630 hour ----- 108

34A-F. Concentrations of triazine, acetamide,chloroacetanilide, and other pesticides in replicate and (or) spiked whole-water samples from the following locations, Yakima River basin, Washington:


34B. Cherry Creek at Thrall, June 2, 1988, at 1400 hourand 1405 hour ---------------------------------- 109

34C. Wide Hollow Creek near mouth at Union Gap,November 15, 1988, at 1330 hour and 1430 hour -- 110




vii

TABLES --ContinuedQuality Assurance Data--Continued

Water Column--Continued

Page

35A-B. Concentrations of volatile organic compounds in replicate and (or) spiked whole-water samples from the following locations, Yakima River basin, Washington:

35A. Wide Hollow Creek near mouth at Union Gap,November 15, 1988, at 1330 hour and 1430 hour -- 112

35B. Sulphur Creek Wasteway near Sunnyside,August 31, 1988, at 1530 hour and 1630 hour ---- 113

36. Concentrations of pesticides in filtered water (using the Goulden large-sample extractor), associated with suspended sediment (analysis of a large sample of de-watered sediment on a glass-fiber filter), and in whole water (conventional analysis of a 1-liter sample of a sediment-water mixture), Yakima River basin, Washington, June 25-30, 1989 ------------------------ 114

37. Concentrations of organic carbon in replicatesuspended-sediment samples and in spiked filtered- water samples from Chandler Canal at Bunn Road at Prosser, Washington, May 22, 1991, at 1500 hour and 1507 hour --------------------------------------- 117

38. Concentrations of organic carbon, suspended sediment, and turbidity in replicate water samples from Yakima River at Kiona, Washington, August 6, 1991, at 1150 hour and 1151 hour ---------------------------------- 117

Filtered Water

39. Mean analytical recoveries using the Gouldenlarge-sample extractor for extracting surrogate compounds from filtered-water samples, Yakima River basin, Washington, June 25-30, 1989 ----------------- 117

40. Analytical recoveries using the Goulden large-sample extractor for extracting spiked compounds from filtered-water samples, Yakima River basin, Washington, June 25-30, 1989 ------------------------------------ 118

41. Concentrations of pesticides extracted from replicatefiltered-water samples using the Goulden large-sampleextractor, Yakima River at Kiona, Washington,June 26, 1989 --------------------------------------- 122

42. Concentrations of organochlorine and organophosphorus compounds in spiked filtered-water samples from Yakima River at Kiona, Washington, May 21, 1991, at 1200 hour and 1207 hour -------------------------- 123

43. Concentrations of organochlorine and organophosphorus compounds in spiked filtered-water samples from Chandler Canal at Bunn Road at Prosser, Washington, June 13, 1991, at 1240 hour and 1247 hour ----------- 124

viii

TABLES --ContinuedQuality Assurance Data--Continued

Filtered Water--Continued

Page

44. Concentrations of organochlorine and organophosphorus compounds in replicate filtered-water samples from Yakima River at Kiona, Washington, August 6, 1991, at 1150 hour and 1151 hour -------------------------- 125

Suspended Sediment

45. Mean analytical recoveries for extracting surrogate compounds from suspended-sediment samples, Yakima River basin, Washington, June 25-30, 1989 ----------- 126

46. Analytical recoveries of pesticides that were spiked into a blank solvent extract and were analyzed in accordance with other extracts from suspended- sediment samples, Yakima River basin, Washington, June 25-30, 1989 ------------------------------------ 127

47. Concentrations of organochlorine and organophosphorus compounds in replicate suspended-sediment samples from Chandler Canal at Bunn Road at Prosser, Washington, June 13, 1991, at 1240 hour and 1241 hour --------------------------------------- 128

48. Concentrations of organochlorine and organophosphorus compounds in replicate suspended-sediment samples from Yakima River at Kiona, Washington, May 21, 1991, at 1200 hour and 1201 hour -------------------------- 129

49. Concentrations of organochlorine and organophosphorus compounds in replicate suspended-sediment samples from Yakima River at Kiona, Washington, August 6, 1991, at 1150 hour and 1151 hour -------------------------- 130

50. Concentrations of organochlorine and organophosphorus compounds associated with blank glass-fiber filters, Yakima River basin, Washington, July to September 1991 .....................__.............-.-.-.------ 131

51. Concentrations of organochlorine and semi-volatileorganic compounds in replicate bed-sediment samples (sediment finer than 62 micrometers in diameter) from Sulphur Creek Wasteway near Sunnyside, Washington, August 31, 1988 ------------------------------------- 132

Bed Sediment

52. Concentrations of organochlorine and semi-volatileorganic compounds in replicate bed-sediment samples (sediment finer than 2,000 micrometers in diameter) from Sulphur Creek Wasteway near Sunnyside, Washington, August 31, 1988 ------------------------ 134

53. Analytical recovery of organochlorine and semi-volatile organic compounds spiked in bed-sediment samples from Sulphur Creek Wasteway, Washington, August 31, 1988 ------------------------------------------------ 136

IX

TABLES --Continued Quality Assurance Data--Continued

Page

Aquatic Biota

54. Laboratory quality-assurance data for organochlorine compounds analyzed in biological samples collected in 1989 and 1990, Yakima River basin, Washington ---- 138

55. Laboratory quality-assurance data for semi-volatileorganic compounds (polycyclic-aromatic hydrocarbons)analyzed in biological samples collected in 1989and 1990, Yakima River basin, Washington ------------ 140

56. Concentrations of organochlorine compounds in field- replicate and laboratory-split samples of aquatic biota, Yakima River basin, Washington, 1989-90 ------ 141

57. Concentrations of semi-volatile organic compounds (polycyclic-aromatic hydrocarbons) in field- replicate and laboratory-split samples of aquatic biota, Yakima River basin, Washington, 1989-90 ------ 144

CONVERSION FACTORS

[SI - International System of units, a modernized metric system of measurement]

A. Factors for converting SI metric units to inch/pound units

Multiply

centimeter (cm) millimeter (mm) meter (m)

milliliter (mL) liter (L) liter

gram (g)

kilogram (kg)

degree Celsius (°C)

B. Factor for converting

Multiply

By

LENGTH

0.3937 0.03937 3.281 1.094

VOLUME

0.001057 1.057 0.2642

MASS

0.03527

2.205

TEMPERATURE

I/

inch/pound units to

By

To obtain

inch (in) inch foot (foot) yard (yd)

quart (qt) quart gallon (gal)

ounce (oz avoirdupois)

pound (Ib avoirdupois)

degree Fahrenheit

SI metric units

To obtain

VOLUME PER UNIT TIME (FLOW)

cubic foot per second (ft 3 /s) 0.02832 cubic meter per second(m3 /s)

I/ Temp degree F = 1.8 (Temp degree C) +32

XL

CONVERSION FACTORS - -Continued

C. Factors for converting SI metric units to other miscellaneous units

Multiply By To obtain

CONCENTRATION, IN WATER

milligrams per liter (mg/L) 1 parts per million (ppm)nanograms per liter (ng/L) 1 parts per trillion (ppt)nanograms per liter 0.000001 parts per million

CONCENTRATION, IN BED SEDIMENT

micrograms per kilogram (/ig/kg) 1 parts per billion (ppb) micrograms per kilogram (/ig/kg) 0.001 parts per million

CONCENTRATION, IN TISSUE

micrograms per gram (/tg/g) 1 parts per million micrograms per kilogram (/ig/kg) 1 parts per billion

Electrical conductivity is measured as specific electrical conductance, in units of microsiemens per centimeter (/tS/cm) at 25 degrees Celsius.

Any use of trade, product, or firm names in this publication is for descriptive purposes only and does not imply endorsement by U.S. Government.

XL!

SURFACE-WATER-QUALITY ASSESSMENT OF THE YAKIMA RIVER BASIN, WASHINGTON: PESTICIDE AND OTHER TRACE-ORGANIC-COMPOUND DATA FOR WATER, SEDIMENT,

SOIL, AND AQUATIC BIOTA, 1987-91

By J.F. Rinella, S.W. McKenzie, J.K. Crawford, W.T. Foreman, P.M. Gates, G.J. Fuhrer, and M.L. Janet

ABSTRACT

Chemical data are presented from an assessment of pesticides and other trace-organic compounds in stream-water, suspended-sediment, bed- sediment, soil, and aquatic-biota samples from the Yakima River basin in south-central Washington during 1987-91. The assessment is a component of the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) Program. The program is designed to describe the status and trends in the quality of the Nation's ground- and surface-water resources, and to determine factors that affect water quality. This report includes the sampling plan, field-collection techniques, laboratory methods, and a compilation of concentration and quality- assurance data. The data may be used by scientists and water managers to assess: (1) spatial distribution of concentrations of trace-organic compounds, (2) temporal (including seasonal) variability in concentrations, (3) suitability of streams for beneficial uses, and (4) major natural and human factors that affect water quality.

Samples were collected upstream and downstream from human activities throughout the basin. Stream-water samples were collected from 32 stations; in addition, five samples were collected from wells in agricultural areas. Large volumes of stream and well water (up to 224 liters) were sampled, filtered, extracted, and analyzed in order to detect small concentrations of trace-organic compounds. Bed-sediment samples were collected from 58 stations (samples from 26 stations were individually analyzed and samples from the other 32 stations were composited into 7 samples for analysis by crop type). Soil samples were collected from three fields in the Moxee subbasin, an area with large concentrations of pesticides in agricultural runoff. Samples of fish, mollusks, crayfish, and aquatic plants were collected from 32 stations in the basin. Analyses for water, sediment, soils, and biota include chlorophenoxy-acid and triazine herbicides; carbamate, organochlorine, and organophosphorus pesticides; and (or) volatile and semi-volatile trace (polycyclic-aromatic hydrocarbons) organic compounds.

INTRODUCTION

The production and use of organic compounds has increased dramatically over the last 50 years and has resulted in a gradual increase in concentrations of these compounds in our Nation's streams (Smith and others, 1988). Thousands of different organic compounds are used annually in commerce and agriculture; moreover, an unknown number of by-products and degradation products result from the production and use of these compounds. Many organic compounds are directly or indirectly released into streams by way of industrial and domestic point-source discharges (specific discharge outlets, such as effluent from pipes), nonpoint-source runoff (such as runoff from agricultural

fields), ground-water discharges, and atmospheric deposition. Even in small concentrations in streams and streambed sediment, many of these compounds are harmful and even toxic to aquatic organisms. Our ability to accurately monitor organic compounds throughout the environment is essential for assessing their influence on aquatic biota, humans, and wildlife.

Background

The U.S. Geological Survey (USGS) was established in 1879 to provide scientific information on the Nation's water, energy, and mineral resources. A major part of the mission of the USGS is to assess the quantity and quality of the Nation's water resources and to provide information to assist resource managers and policy makers at Federal, State, Tribal, and local levels in making sound management decisions. To a significant extent, these responsibilities are being carried out in the USGS's National Water-Quality Assessment (NAWQA) Program (Leahy and others, 1990), whose goals include providing a sound understanding of the natural and human factors that affect water quality.

A major national concern is the degradation of water quality that results from pesticides and other trace-organic compounds in agricultural, industrial, and urban runoff. Crop yields are improved greatly by applying pesticides, and our lives are enhanced through the usage of organic compounds (including fossil fuels for energy, household cleaners, and many others); however, increased production and use of organic compounds often results in an increase in environmental effects. One of the first surface-water studies in the NAWQA Program to collect data on trace-organic compounds was conducted in the Yakima River basin, Washington, from 1987-91 (project described by McKenzie and Rinella [1987]). The Yakima River basin is one of the most intensively irrigated areas in the United States with Yakima County leading the Nation in the production of apples, mint, and hops (basin characteristics described by Rinella and others, 1992). Pesticide use in the basin is extensive.

Purpose and Scope

The purpose of this report is to document the sampling plan, field- collection techniques, and laboratory methods; and to provide a compilation of concentrations of trace-organic compounds collected during the Yakima NAWQA study (1987-91). The scope of this report includes a presentation of the sampling plan, field-collection techniques, laboratory methods, and a compilation of data including quality-control and quality-assurance data. In this study, water, stream-sediment, aquatic-biota, and a few soil samples were collected and analyzed for a variety of pesticides and other trace-organic compounds that have been, and (or) continue to be, used in the basin. These data may be used by scientists and resource managers to quantitatively describe the:

(1) spatial distribution of pesticides and other trace-organic compounds in surface water, stream sediment, and aquatic biota (fish, mollusks, crayfish, and plants) in the Yakima River basin;

(2) temporal (hourly, daily, and seasonal) variability in concentrations of trace-organic compounds in streams;

(3) suitability of streams for designated beneficial uses including aquatic-life and domestic uses; and,

(4) major natural and human factors that affect the distribution of trace - organic-compound concentrations.

Acknowledgments

The authors wish to acknowledge the aid and advice provided by members of the Yakima NAWQA Liaison Committee. During 1992, this committee included:

David W. Zimmer, U.S. Bureau of ReclamationRichard Albright, U.S. Environmental Protection AgencyBill Garrigues, U.S. Forest ServiceTerry W. Berkompas, U.S. Bureau of Indian AffairsKate Benkert, U.S. Fish and Wildlife ServiceJannine Jennings, Yakima Indian NationBob Barwin, Washington State Department of EcologyPerry Harvester, Washington State Department of FisheriesBrent Renfrew, Washington State Department of WildlifeGlen Patrick, Washington State Department of HealthDr. L. Glint Duncan, Washington Water Research Center,

Central Washington State University Skip Steinmetz, Yakima County Health Department Ronald L. Van Gundy, Yakima River Basin Association of

Irrigation Districts Ray L. Wondercheck, U.S. Soil Conservation Service,

District ConservationistElaine Taylor, Yakima Valley Conference of Governments Mike Tobin, North Yakima Conservation District

Special thanks to: (1) the Yakima Indian Nation for their cooperation in providing staff time and equipment for electrofishing, reviewing reports, and giving USGS permission to collect water-quality and biological samples in the Yakima Indian Nation; (2) U.S. Fish and Wildlife Service, Washington State Department of Fisheries, Washington State Department of Game, and Jean-Pierre Wilson (Heritage College, Toppenish, Washington) for assistance and cooperation in electrofishing; (3) U.S. Bureau of Reclamation and the Prosser Experiment Station (Washington State University and U.S. Department of Agriculture) for providing laboratory facilities in the basin; (4) Gregory D. Foster and Frank A. Rinella (U.S. Geological Survey) for developmental work on the Goulden large-sample extractor used to lower minimum analytical reporting levels; (5) Washington State Department of Wildlife for providing refrigeration and freezer space at the Naches Fish Hatchery; and (6) Shen Xianchen (Institute of Water Conservancy and Hydroelectric Power Research, Chinese Academy of Sciences, Ministry of Water Resources and Electric Power, Beijing, China) for assistance in sampling and developing quality-assurance procedures for spiking bed-sediment samples.

DATA COLLECTION AND ANALYSIS

The focus of the NAWQA study in the Yakima River basin is to assess water-quality conditions at a regional scale which involves water- quality characterizations of persistent conditions in stream reaches that extend 20 or more river miles. A local-scale study, which is beyond the scope of this study, would attempt to describe the water- quality patterns within smaller reaches, of perhaps, several hundreds of yards or less. Although the local scale is not the focus of this assessment, data from this study may reveal several, previously unknown, local-scale concerns to human health and ecosystems.

Sampling Plan

The general sampling plan (sampling purpose and scope) and types of analyses for water, bed-sediment, soil, and aquatic-biota samples from the Yakima River basin are outlined in table 1. Locations of the water, bed-sediment, soil, and aquatic-biota stations are given in table 2 and are shown in figure 1.

Whole-water and most filtered-water samples were analyzed for carbamate, chlorophenoxy-acid, organochlorine, organophosphorus, triazine, and other pesticides (see table 3 for listing of pesticide compounds that were analyzed); in addition, a few samples were analyzed for phenol, cresol, and volatile compounds (see table 2 for listing of chemical families that were analyzed at each station). Bed-sediment samples were analyzed for organochlorine and semi-volatile (phthalate esters, ethers, phenols, cresols, and monocyclic- and polycyclic- aromatic hydrocarbons) organic compounds; most of these compounds are hydrophobic and tend to sorb to organic carbon associated with sediment. Soil samples were analyzed for organochlorine and organophosphorus compounds. Aquatic biota samples (fish, mollusks, crayfish, and plants) were analyzed for organochlorine compounds; in addition, mollusks and plant samples were analyzed for selected semi-volatile organic compounds (polycyclic-aromatic hydrocarbons).

Sample Collection. Processing, and Preservation

The selection of sampling media (whole water, dissolved phase, suspended sediment, bed sediment, soil, or aquatic biota) for analysis was based on physical and chemical characteristics of the trace-organic compounds. For example, hydrophobic compounds that strongly associate with organic matter generally were analyzed in bed-sediment, suspended- sediment, soil, and aquatic-biota samples; hydrophilic compounds that are readily soluble in water were analyzed in filtered-water samples and (or) whole-water samples.

To minimize sample contamination from extraneous sources of trace- organic compounds during collection, processing, and shipment, all samples (water, sediment, soil, and aquatic-biota samples) only came in contact with glass, ceramic, stainless steel, Teflon, bronze, cadmium- plated, or aluminum containers, funnels, sieves, pumps, and (or) sampling equipment; however, fish were caught in nylon nets and were measured on a plexiglass measuring board. Prior to sampling, all sampling equipment and containers were washed with non-phosphate detergent and rinsed with tap water and (or) distilled water. Sample

Table 1. Sampling plan for collecting trace-organic-compound samples, Yakima River basin, Washington, 1987-91

[See table 2 for listing of chemical families analyzed et eech site and see table 3 for listing of compounds in in esch chemical family; DOT * dichlorodiphenyltrichloroethane; DDE * dichlorodiphenyldichloroethylene; DDD = dichlorodiphenyldichloroethane]

Sampling medium Sampling period

Number Chemicalof familysites analyzed Purpose of sampling

Analytical data shown in following tables:

Bed sediment August-November 1987

36

Bed sediment

Bed sediment

August-September 1988

September 1988

Bed sediment 1989-90 16

Soil July 1989

Whole water

Whole water

May, June, July, August, and November 1988, and March 1989

July 1988 18

Filtered and suspended phases (separateanalyses ofeach phase)

June 1989 29

Organochlorines Semi-volatiles


Organochlorines Sami-volatiles


Organochlorines Organophosphorus

OrganochlorinesOrganophosphorusTriazinesCarbamatesChlorophenoxy acidsVolatilesPhenols and cresols

Organochlorines Organophosphorus Triazines Carbemates Chlorophenoxy acids Phenols and cresols

Organochlorines Organophosphorus Triazines Carbamates Chlorophenoxy acids

Two main-stem samples, one urban-runoff 24 and 26sample, and seven composited samples(4 to 5 sites per composite)representing seven different crop typeswere collected to examine land-useeffects on bed-sediment chemistry.

One main-stem site, one pristine site, 24 and 26 one urban site, and five agricultural return flows were sampled to compare trace-organic-compound concentrations in bed sediment and in the water column.

Sites were re-sampled and individually 24 and 26analyzed to examine variability inagricultural-return flows that drainapple orchards. Preliminary resultsfrom the 1987 sampling showed thatdreins from apple orchards (onecomposited sample of five orchards) hadlarger concentrations of trace-organiccompounds in bed sediment than thoseconcentretions in drains from sixother crop types.

Sites were sampled to compare 24 and 26 trace-organic-compound concentrations in bed sediment and aquatic biota.

Soil samples were collected from the 24 and 25A and B horizons at several locations inMoxee subbasin. Moxee subbasin wasselected because relatively largeconcentrations of p,p'-DDT, p,p'-DDE,and p,p'-DDD were observed in MoxeeDrain in 1988. Hop fields were selectedbecause surface-weter drainage from thesefields are ladened with sediment and may betransporting trace-organic compounds thatare sorbed to the sediment. An apple orchardwas selected, because preliminary resultsfrom the 1987 sampling showed thatdreins from apple orchards (one compositedsample of five orchards) had largerconcentrations of trace-organic compoundsin bed sediment than those concentrationsin drains from six other crop types.

One main-stem site, one pristine site, 5, 6, 8, 10, 15, one urban site, and five agricultural- return flows were sampled to examine 20, 21, and 23 seesonal variability in concentrations of trece organic compounds in whole-water samples. Three storm samples also were collected from the main-stem site, Yakima River at Kiona, in December. 1989.

Five main-stem sites, one pristine site, 5, 6, 8, 10, 15,one urban site, the Naches River, andten major agricultural-return flows were 20, and 21sampled synoptically (within a four-dayperiod) during peak irrigation todetermine the spatial distribution ofconcentrations and major sources oftrace organic compounds inwhole-water samples.

The main stem, major tributaries, 5, 7, 9, 11, 13,and major agriculturel-return flowswere sampled synoptically (within a 16, 18, and 225-dey period) to determine transportcharacteristics of trece organiccompounds in the basin during peakirrigation. In addition, two drinking-weter wells were sampled in thevicinity of intense agricultural activityto explore surface- and ground-weter relations.

Table 1. Sampling plan for collecting trace-organic-compound samples, Yakima River basin, Washington, 1987-91 Continued

Sampling medium

Filtered and suspended phases (separate analyses of each phase)

Sampling period

May, June, July, and September 1991

Number Chemical of family sites analyzed

4 Organochlorines Organophosphorus

Purpose of sampling

One mein-stam site and three major agricultur el-return flows were sampled to exemine the variability of dissolved- and suspended-phase transport of trece organic compounds during irrigation season.

Analytical data shown in following tables :

5. 12, 14, 17, and 19

Ground water January 1989

Aquatic biota May 1989

Aquatic biota October-November 1989

Aqustic biota

Aquatic biota

October-November 1990


Organochlorines Organophosphorus

Organochlorines Polycyclic-aromatic hydrocarbons

19 OrganochlorinesPolycyclic-aromatic hydrocarbons

25 OrganochlorinesPolycyclic-aromatic hydrocarbons

Organochlorines

Three shellow wells were sampled neer the mouth of Moxee Drain to examine surfece- and ground-water relations.

A preliminary field test was conducted to provide estimates of time and resources required for collection and analysis of contaminants in tissues.

Biota from sites where contamination was suspected and from reference sites were sampled to determine the occurrence of contaminants in tissues.

Biota from widely dispersed sites in the basin were sampled to provide a spetial distribution of contaminants in tissues.

Fish from three sites were sampled to examine contaminants in edible portions of fish, variability among fish, and conteminants in whole fish versus fish muscle tissue.

10 and IS

27, 28, and 29

27, 28, and 29

27, 28, and 29

Data not shown in this report and will be available in 1993.

Table 2. Sampling locations for pesticide and other trace-organic compounds in water, bed sediment, soil, and aquatic biota, Yakima River basin, Washington, 1987-91

["WATSTORE" indicates U.S. Geological Survey's National HATer Data STOrage and REtrieval Computer System; see figure 1 for location of sampling sites in basin; Carb - carbamates and other compounds; Chlor - chlorophenoxy acid herbicides; OC = organochlorine compounds; OF - organophosphorus compounds; TR - triazine herbicides; V - volatile organic compounds; PC = phenols and cresols; SV - semi-volatile organic compounds; PAH - polycyclic-aromatic hydrocarbons; abbreviations in site names are as follows: ab - above, abv - above, Blvd - Boulevard, blw - below, Br - Bridge, Campgrnd - Campground, Cr = Creek, E - East, Fk - Fork, M.S. - Middle School, mi - miles, N.F. - North Fork, No - North, nr - near, R - River, Rd = Road, Rds - Roads, RM - River Mile, Rnch - Ranch, S.F. - South Fork, STP - sewage treatment plant, and H - West; latitude and longitude are listed in degrees, minutes, and seconds]

Map refer ence Station number number Station name from WATSTORE Latitude Longitude

Chemical families analyzed at each station

Water samples

234

1113

1415192021

2223242728

3033343536

3738404143

4546474849

5051535558

5961

12478200 Cooper River at Salmon LaSac nr Roslyn12478300 Cle Elum R above Cle Elum Lake nr Roslyn12479500 Yakima River at Cle Elum12484100 Wilson Cr abv. Cherry Creek at Thrall12484480 Cherry Creek at Thrall

12484500 Yakima River at Umtanum12484550 Umtanum Creek nr mouth at Umtanum12496510 Pacific Power & Light Company Wasteway12496511 City of Yakima-Finish Water12496550 Buckskin Slough blw Gleed Ditch nr Gleed

12499000 Naches River nr North Yakima12500420 Moxee Drain at Birchfield road nr Union Gap12500430 Moxee Drain at Thorp Rd nr Union Gap12500445 Wide Hollow Creek near mouth at Union Gap12500450 Yakima R abv Ahtanum Cr at Union Gap

12502500 Ahtanum Creek at Union Gap12505350 E Toppenish Drain at Wilson Rd nr Toppenish12505410 Sub 35 Drain at Parton Road near Granger12505450 Granger Drain at Granger12505460 Granger Drain at mouth nr Granger

12505510 Marion Drain at Indian Church Rd at Granger12507508 Toppenish Cr at Indian Church Rd nr Granger12507585 Yakima River at RM 72 ab Satus Cr nr Sunny side12507594 Sstus Cr abv Wilson-Charley Canyon nr Toppenish12508620 Satus Creek at gage at Satus

12508630 South Drain nr Satus12508850 Sulphur Cr Wasteway nr Sunnyside12509050 Yakima R at Euclid Br at RM 55 nr Grandview12509499 Chandler Canal at Bunn Rd at Prosser12509710 Spring Creek at mouth at Whitstran

12509829 Snipes Creek at mouth at Whitstran12510500 Yakima River at Kiona461720120043201 Well 1, Sunnyside, 09N/22E-04P01462510120323901 Well 2, Harrah, 11N/18E-22R02463233120262101 Well 12N/19E-09H02

463234120261601 Well 12N/19E-09H01463257120260801 Well 12N/19E-10D02

4747474646

4646464646

4646464646

4646464646

4646464646

4646464646

4646464646

4646

2421115555

5151414138

3732323232

3222202020

1918160116

1515131314

1415172532

3232

2919353534

4627444301

4246181904

1004113710

5252110026

3503012700

0213201033

3457

121121120120120

120120120120120

120120120120120

120120120120120

120120120120120

120120119119119

119119120120120

120120

0606563029

2829393934

3126272827

2815131111

1111054008

0701554440

4028043226

2626

1122550151

4446111050

1013191758

2000480938

5453305432

5707000838

3737323921

1608

Carb, Chlor,Carb , Chlor ,Carb , Chlor ,Carb, Chlor,Carb, Chlor,

Carb, Chlor,Carb, Chlor,Carb , Chlor ,Carb , Chlor ,Carb, Chlor,

Carb , Chlor ,OC, OPCarb, Chlor,Carb, Chlor,Carb, Chlor,

Carb, OC, OPCarb, Chlor,Carb, Chlor,OC, OPCarb, Chlor,

Carb , Chlor ,Carb, Chlor,Carb, Chlor,Carb, Chlor,Carb, Chlor,

Carb , Chlor ,Carb, Chlor,Carb, Chlor,Carb, Chlor,Carb, Chlor,

Carb , Chlor ,Carb, Chlor,Carb , Chlor ,Carb, Chlor,OC, OP

OC, OPOC, OP

oc,oc,oc,oc,oc,oc,oc,oc,oc,oc,oc,oc,oc,oc,

, TRoc,oc.oc,oc.oc,oc,oc.oc,oc.oc.oc,oc,oc.oc,oc,oc,oc,

OP,OP,OP,OP,OP,

OP,OP,OP,OP,OP

OP,

OP,OP,OP,

OP,OP,

OP,

OP,OP,OP,OP,OP,

OP,OP,OP,OPOP,

OP,OP,OP,OP,

TRTRTRTRTR

TRTRTR, VTR, V

TR

PC, TR,PC, TR,PC, TR

TRTR

PC, TR,

TRTRTRTRTR

TRPC, TR,TR

TR

TRPC, TR,TRTR

Bed sediment

13567

89

101314

1516171824

12478100 Waptus River at mouth nr Roslyn12478300 Cle Elum R above Cle Elum Lake nr Roslynum12479720 Jungle Creek nr mouth nr Cle Elum12479750 No Fk Te an away R blw bridge at Dickey Creek Campgrnd12480000 Teanaway River below forks near Cle Elum

12481900 Taneum Cr at Taneum Meadow nr Thorp12483190 South Fork Manastash Cr nr Ellensburg12483750 Naneura Cr blw High Cr nr Ellensburg12484480 Cherry Creek at Thrall12484500 Yakima River at Umtanum

12484550 Umtanum Creek nr mouth at Umtanum12487200 Little Naches River at mouth nr Cliffdell12488250 American River at Hells Crossing nr Nile12489100 Rattlesnake Cr abv N.F. Rattlesnake Cr nr Nile12500430 Moxee Drain at Thorp Rd nr Union Gap

4747474747

4746474646

4646464646

2521201714

0658105551

5159584832

1319302148

4718553446

2720043418

121121120120120

120120120120120

120121121121120

0506515151

5248262928

2905150427

1522593036

0132445144

4655450819

SVOC, SVOC, SVOCOC, SV

OCOCOCOC, SVOC, SV

OC, SVOCOC, SVOC, SVOC, SV

Table 2. Sampling locations for pesticide and other trace-organic compounds in weter, bed sediment, soil, and aquatic biota, Yakime River basin, Washington, 1987-91 Continued

Map refer ence Station number number Station name from WATSTORE Latitude Longitude

Chemical families analyzed at eech station

Bed sediment Continued

2527282931

3638424446

4951525462

1250043712500445125004501250090012503640

1250546012507508125085001250862512508850

1250971012510500461652119522000461744119522400463359120281400

Wide Hollow Cr at W Valley M.S. nr AhtanumWide Hollow Cr near mouth at Union GapYakima R abv Ahtanum Cr at Union GapS.F. Ahtanum Cr abv Conrad Rnch nr Tempi coUnnamed drain et Lateral & Riggs Rds nr Wapato

Granger Drain at mouth nr GrangerToppenish Cr at Indian Church Rd nr GrangerSatus Cr below Dry Cr near ToppenishYakima R blw Setus Cr at RM 68 nr SetusSulphur Cr Wastewey nr Sunny side

Spring Creek at mouth at WhitstranYakima River at KioneUnnamed drain et County Line Rd nr GrandviewUnnamed drain to E Turbine Laterel nr GrandviewUnnamed urban runoff at Union Gap

4646464646

4646464646

4646464646

3432322928

2018151515

1415161733

5619043240

1052000603

0013524459

120120120120120

120120120120120

119119119119120

3628275731

1111220501

4028525228

3417582359

3853404507

3837202414

OC,OC,oc.OCOC,

OC,OC,OCOC,OC,

svoc,oc.oc.oc.

svsvsvsvsvsvsvsv

svsvsvsv

63 463501120353300 Wide Hollow Creek at Ahtanum Blvd nr Ahtanum 46 35 01 120 35 33 OC, SV

Composited bed-sediment samples by crop type (stations not shown in figure 1)

Composited samples neer pear orchards ...................................... OC, SV

Wide Hollow Cr at Ahtanum Blvd nr Ahtanum Waste ditch south of Old Naches Road nr Naches Road ditch at Houghton Rd above Roza Canal Waste ditch, 0.2 mi south of Best Zillah Drive

46 35 0146 43 0246 25 3446 24 06

120 35 33120 39 49120 11 33120 13 08

Composited ales near apple orchards ...................................... OC, SV

Wide Hollow Cr at Ahtanum Blvd nr Ahtanum Road ditch north of Old Naches Road nr Gleed Waste ditch at intersection of Lateral Rd and

Riggs RdUnnamed drain to E Turbine Lateral nr Grandview Unnamed drain et County Line Rd nr Grandview

46 35 0146 40 56

46 28 4046 17 4446 16 52

120 35 33120 38 01

120 32 00119 52 24119 52 20

Composited samples near hops fields ......................................... OC, SV

Waste ditch near Faucher Rd near Moxee Drain 46 32 47 Weste ditch near intersection of Fort Rd and Bench Rd 46 22 37 Waste ditch at McDoneld Rd. 0.6 mi north of Hanks Rd 46 16 52 Waste ditch at intersection of Hanks Rd and

Hinzerling Rd Waste ditch northeast of intersection of Bonnieview Rd

and Olmstead Rd

120 22 24120 36 19119 43 24

46 16 23 119 46 03

46 15 41 119 52 53

Composited samples near corn fields ......................................... OC, SV

Waste ditch near intersection of Fort Rd and Island Rd 46 22 32 120 35 00 Waste ditch et Fort Rd, 0.4 mi east of Becker Rd Waste ditch at Cemetary Rd, 0.3 mi north of Gap Rd Waste ditch at Indian Church Rd near Granger Waste ditch at Sorensen Rd, 0.5 mi east of

Denmark Hall

46 22 3246 19 2846 20 01

120 20 49120 04 53120 11 58

46 56 30 120 25 22

Composited samples near asparagus fields .................................... OC, SV

Waste ditch at Yost Rd, 0.5 west of South Wapato Rd 46 20 48 120 25 45 Waste ditch at Cemetary Rd, 0.3 mi north of Gap Rd 46 19 28 120 04 53 Waste ditch at intersection of Factory Rd and

Bethany Rd 46 19 02 119 55 28 Waste ditch at intersection of Lemley Rd and Wilgus Rd 46 15 06 119 49 46 Waste ditch near intersection of Colwesh Rd and

Winnier Rd 46 13 02 120 05 51

Table 2. Sampling locations for pesticide and other trace-organic compounds in water, bed sediment, soil, and aquatic biota, Yakima River basin, Washington. 1987-91 Continued

Map refer ence number

Station number Station n« from WATSTORE Latitude Longitude

Chemicel families analyzed at each station

Composited bed-sediment samples by crop type (stations not shown in figure 1) Continued

Composited samples near poteto fields ....................................... OC, SV

Waste ditch at Orchard Rd, 0.1 mi south of Thrall Rd 46 55 44 120 28 28 Waste ditch at Dodge Rd, 0.4 mi south of Orchard Rd 46 55 03 120 27 15 Waste ditch at Sorensen Rd, 0.4 mi west of

Denmark Hall 46 56 30 120 26 31 Waste ditch near intersection of Hanks Rd and

Missimer Rd 46 16 26 119 48 55 Waste ditch at intersection of Olden Way Rd and

Jensen Rd 46 19 57 120 22 28

Composited samples near grape orchards ..................................... OC, SV

Waste ditch, intersection McCreadie and Griffin Rds 46 Waste ditch, intersection McCreadie and Missimer Rds 46 Waste ditch, intersection Snipes and Hinzerling Rds 46 Waste ditch, intersection Fhipps and Scoon Rds 46

15 15 18 22

33 32 11 38

119 119 119 120

51 48 46 00

02 31 15 51

Soils

565760

463202120223600463232120234900463247120222300

Apple orchard nr Moxee CityHop field near Moxee CityHop field nr Moxee City

464646

323232

023247

120120120

222322

364923

OC,oc,oc,

OPOPOP

Aquatic biota

14567

89

1012 13

1415161718

2224252629

3032363839

4041424346

474951

1247810012479500124797201247975012480000

12481900124831901248375012484440 12484480

1248450012484550124872001248825012489100

1249900012500430125004371250044212500900

1250250012503950125054601250750812507525

1250758512507594125085001250862012508850

125090501250971012510500

Waptus River at mouth nr RoslynYakima River at Cle ElumJungle Creek nr mouth nr Cle ElumNo Fk Teanaway R blw bridge et Dickey Cr CampgrndTeanaway River below forks near Cle Elum

Taneum Cr at Taneum Meadow nr ThorpSouth Fork Manastash Cr nr EllensburgNaneum Cr blw High Cr nr EllensburgCherry Creek abv Wipple Wasteway at Thrall Cherry Creek at Thrall

Yakima River at UmtanumUrn tan urn Creek nr mouth at UmtanumLittle Naches River at mouth nr CliffdellAmerican River at Hells Crossing nr NileRattlesnake Cr abv N.F. Rattlesnake Cr nr Nile

Naches River nr North YakimaMoxee Drain at Thorp Rd nr Union GapWide Hollow Cr at W Valley M.S. nr AhtanumWide Hollow Cr at Old StP at Union GapS.F. Ahtanum Cr ebv Conrad Rnch nr Tampico

Ahtanum Creek at Union GepYakime R at ParkerGranger Drein et mouth nr GrangerToppenish Cr at Indian Church Rd nr GrangerYakima R blw toppenish Cr at RM 79.6 nr Granger

Yakima River at RM 72 eb Satus Cr nr SunnysideSatus Cr abv Wilson-Cherley Canyon nr ToppenishSatus Cr below Dry Cr near ToppenishSatus Creek at gage et SatusSulphur Cr Wasteway nr Sunnyside

Yakime R at Euclid Br at RM 55 nr GrandviewSpring Creek at mouth at WhitstranYakima River at Kiona

4747474747

47464746 46

4646464646

4646464646

4646464646

4646464646

464646

2511201714

06581055 55

5151595848

3732343229

3230201818

1601151615

131415

1335302148

47185544 34

4627200434

4218563532

1022105258

1100002603

010013

121120120120120

120120120120 120

120120121121121

120120120120120

120120120120120

120120120120120

119119119

0556515151

52482629 29

2829051504

3127362857

2827111109

0540220801

554028

1555593036

01324448 51

4446554508

1019342623

2007385313

3054403207

003837

OCococococococococ oc,oc,ococococococ,ococ,ocococ,ococ,ococ,ocococ.ococ,oc,oc,

PAH

PAH

PAH

PAH

PAH

PAH

PAH

PAH

PAHPAHPAH

YAKIMA BENTON COUNTY 1 COUNTY

LEWISCOUNTY YAKIMA COUNTY

EXPLANATION

Canal

28 Sampling Station0 5 10 15 20 25 MILESI .1 . . I I , I I_____II ' ''I i r I n0 5 10 15 20 25 KILOMETERS

Figure 1. Sampling stations for trace organic compounds in water, suspended sediment, bed sediment, soil, and aquatic biota, Yakima River basin.Washington, 1987-91. Reference numbers are shown on map and listed in Table 2.

10

Table 3. Common technical name and biological activity of pesticides analyzed in water, sediment, soil, and aquatic biota, Yakima River basin, Washington, 1987-91

[ODD dichlorodiphenyldichloroethane; DDE - dichlorodiphenyldichloroethylene; DDT - dichlorodiphenyltrichloroethane; HCB hexachlorobenzene; HCH - hexachlorocyclohexane; DEF - S,S,S-tributyl phosphorotrithioate; 2,4-D - (2,4-dichloro phenoxy)acetic acid; 2,4-DP - 2-(2,4-dichlorophenoxy)propionic acid; 2,4,5-T - (2,4,5-trichlorophenoxy)acetic acid; EPTC - S-ethyl dipropylthiocarbamate]

Common technical name Biological activity

Organochlorine compounds

Aldrincis-Chlordane trans-Chlordane Chlorothalonil p,p'-DDD and o,p'-DDD

p,p'-DDE and o,p'-DDEp,p'-DDT and o,p'-DDTDacthal1,3-DichloropropeneDieldrin

Dicofol Endosulfan I Endosulfan II Endosulfan sulfate Endrin

Endrin aldehyde Endrin ketone HCBalpha-HCH beta-HCH

delta-HCHHeptachlorHeptachlor epoxideKeponeLindane (gamma-HCH)

o,p'-Methoxychlor andp,p'-Methoxychlor

Mirexcis-Nonachlor trans-Nonachlor

Oxychlordane Perthane Toxaphene

InsecticideInsecticide component of technical chlordaneInsecticide component of technical chlordaneFungicideInsecticide and degradation product of DDT

Degradation products of DDTInsecticidesHerbicideNematicideInsecticide and degradation product of aldrin

AcaricideInsecticide and acaricideInsecticide and acaricideDegradation product of endosulfan I and IIInsecticide

Transformation product of endrinMetabolite of endrinFungicide and industrial intermediateInsecticideInsecticide

InsecticideInsecticide component of technical chlordaneDegradation product of heptachlorInsecticideInsecticide and rodenticide

InsecticidesInsecticide and fire retardantInsecticide component of technical chlordaneInsecticide component of technical chlordane

Degradation product of cis- and trans-chlordaneInsecticideInsecticide, nematicide, herbicide, and fish poison

Organophosphorus compounds

Azinphos-methylChlorpyrifosDEFDemeton-SDiazinon

DimethoateDisulfotonEthionFonofosIsofenphos

Insecticide and acaricide InsecticidePlant-growth regulator Insecticide and acaricide Insecticide and acaricide

Insecticide and acaricide Insecticide and acaricide Acaricide and insecticide Insecticide Insecticide

Malathion Methidathion Methyl-parathion Methyl-trithion (methyl-carbophenothion) Insecticide and acaricide

Insecticide and acaricide Insecticide and acaricide Insecticide and acaricide

MevinphosParatnionFhorateFhosphamidonTerbufos

Trithion(carbophenothion)

Insecticide and acaricide Insecticide and acaricide Insecticide, acaricide, and nematicide Insecticide and acaricide Insecticide and nematicide

Insecticide and acaricide

11

Table 3. Common technical name and biological activity of pesticides analyzed in water, sediment, soil, and aquatic biota, Yakima River basin, Washington, 1987-91 Continued


Chlorophenoxy acid herbicides

2,4-D2,4-DP (dichlorprop)Fenoprop (Silvex)2,4,5-T

HerbicideHerbicide and plant-growth regulatorHerbicideHerbicide

Triazine compounds

AmetrynAtrazineCyanazineDeethyl-atrazineDeisopropyl-atrazine

HerbicideHerbicideHerbicideDegradation product of atrazine and propazineDegradation product of atrazine and simazine

Hexazinone Metribuzin Prometon Prometryn Propazine

Simazine Simetryn

Herbicide Herbicide Herbicide Herbicide Herbicide

Herbicide Herbicide

Caxbamate compounds

Aldicarb Aldicarb sulfone

Aldicaxb sulfoxideCarbarylCarbofuran

3-Hydroxyc arbofuran Methiocarb

Methomyl 1-Haphthol

OxamylProphamPropoxur

Insecticide, acaricide, and nematicideHematicide and insecticide; degradation product

of aldicarbDegradation product of aldicaxb Insecticide and plant-growth regulator Insecticide, acaricide, and nematicide

Hydrolysis product of caxbofuran Molluscicide, insecticide, acaricide, and

repellentInsecticide and acaricide Insecticide; hydrolysis product of carbaryl

Insecticide, acaricide, and nematicide Herbicide and plant-growth regulator Insecticide

Thiocarbamate compounds

Butylate Cycloate EPTC (also listed in

carbamate family) Vernolate

Herbicide Herbicide

Herbicide Herbicide

Acetamide compounds

Alachlor (also listed in chloroacetanilide family) Herbicide Diphenamid Herbicide Metolachlor Herbicide

Anilide compounds

Carboxin Fungicide

Benzoic compounds

Dicamba Herbicide

12

Table 3. Common technical name and biological activity of pesticides analyzed in water, sediment, soil, and aquatic biota, Yakima River basin, Washington, 1987-91 Continued


Chloroacetanilide compounds (chloroacetamide compounds)

Butachlor Propachlor

Herbicide Herbicide

Conazole compounds

Triadimefon Fungicide

Pyrethoid compounds

FLucythrinate cis-Permethrin trans-Permethrin

Insecticide Insecticide Insecticide

Pyridine compounds

Pic lor am Herbicide

Sulfite compounds

Propargite Acaricide

Trifluoromethyl compounds

Trifluralin Herbicide

Uracil compounds

Bromacil Terbacil

Herbicide Herbicide

Urea compounds

Linuron Herbicide

13

bottles and filters were oven-baked at 300-450°C [degrees Celsius] (preferably 450°C) for 8 or more hours. Lid liners were made of Teflon or oven-baked aluminum-foil inserts. Sampling equipment was rinsed with high-purity methanol or methylene chloride (especially manufactured for pesticide-residue analysis) followed by copious rinsings with stream water from the sampling location.

Whole Water

Water samples for analyses of trace-organic-compounds in whole-water, dissolved, and suspended-sediment phases were collected using the equal-width increment method. This method provides samples with (1) chemical concentrations that are discharge-weighted vertically and laterally, and (2) a sample volume at each sampling point in the transect that is proportional to the water discharge in the sampled zone (Ward and Harr, 1990).

A DH-75H sampler (a 1.5 pound sampler on a hand-held rod; Ward and Harr, 1990) was used for collecting water samples in wadeable streams; a DH-76 sampler (a 22 pound sampler on a hand line; Ward and Harr, 1990) was used for collecting samples from bridges and cableways. These samplers were fitted with Teflon nozzles and gaskets, and were designed to use 1-quart glass bottles.

Whole-water samples were chilled with ice within 30-40 minutes after collection, and were shipped within 2 to 5 days after collection to the USGS National Water-Quality Laboratory (NWQL) in Arvada, Colorado, where the samples were analyzed.

The following ancillary data were collected during most water-column samplings: streamflow, suspended-sediment concentrations and (or) turbidity, particle size of suspended sediment (percent sand), pH, specific conductance, stream temperature, suspended organic carbon, and dissolved organic carbon.

Filtered Water and Suspended Sediment

Selected whole-water samples for trace-organic compounds (up to 224 liters) were filtered through a 293-mL (millimeter) diameter, stainless-steel, filtration unit containing a glass-fiber filter (l-/im [micrometer] nominal pore diameter, binder-free filter). Except for samples collected in June 1989, filtered water was placed into glass bottles (conventional analysis for a chemical family such as, triazines--requires one liter of sample), chilled with ice, and shipped for analysis to the USGS National Water-Quality Laboratory in Arvada, Colorado. To obtain lower minimum reporting levels for the samples collected in June 1989, large volumes of filtered water (4.4 to 112 liters) were extracted at a field laboratory with methylene chloride using the Goulden large-sample extractor [GLSE] (Goulden and Anthony, 1985; Foster and others, 1991). The GLSE extracts were placed in amber-colored glass bottles and sealed with Teflon-lined caps; the iced samples were shipped to the USGS Methods Research and Development Program Laboratory in Arvada, Colorado, for analysis.

The suspended sediment trapped on the filters also was analyzed. Prior to removing a filter for analysis from the filtration unit, excess water was removed by applying a gentle vacuum to the outlet port. The filter, which contained suspended sediment for chemical analysis, was folded in half and then into quarters, wrapped in cleaned, baked aluminum foil, and placed in

14

polyethylene storage bags. The samples were preserved by freezing in dry ice and were shipped frozen to the USGS National Water-Quality Laboratory, except for 13 samples collected in June, 1989, and shipped to the USGS Methods Research and Development Program Laboratory. In this report, concentrations of trace-organic compounds associated with suspended sediment are reported in nanograms per liter (calculated by dividing the mass of the trace-organic compound by the volume of water that passed through the filter).

Bed Sediment and Soil

Most bed-sediment samples were collected in late summer and early fall, near or at the end of irrigation season. Bed-sediment samples were collected to provide (1) a historical integration of water-quality conditions, (2) the amount and distribution of trace-organic compounds that are sorbed onto sediment particles, and (3) additional evidence concerning the occurrence of trace-organic compounds in the aquatic environment.

Bed-sediment samples were collected and processed using Teflon, stainless-steel, or glass sampling equipment, sieves, trays, and containers. Hand-held scoops were used for sampling shallow wadeable streams, and a Teflon-lined Ekman grab sampler was used for sampling deep streams. During sample collection, samples were isolated from the stream current in order to minimize loss of fine-grained sediment. The surficial layer (upper 0.5 inch) of bed sediment was sampled and analyzed to provide an estimate of concentrations of trace-organic compounds that were sorbed to the most recently deposited sediment. When possible, the samples were stream-width integrated by collecting and compositing a minimum of 5 samples in a transect; .however, most samples were collected in low velocity zones in the reach (usually near the shoreline) in order to obtain fine-grained sediment. The bed-sediment samples were separated into size classes using stainless-steel sieves with 2-mm, 180 /jm, and 62-/jm openings. Samples were wet sieved using stream water from the sampling location. Immediately after sieving, size classes of samples were chilled with ice.

Soil samples were collected from the A- and B-soil horizons (as designated by the U.S. Soil Conservation Service) using a stainless-steel scoop. The soil samples were not sieved, and were placed in glass containers and chilled to less than 4°C. Bed-sediment and soil samples were packed in ice and shipped to the USGS National Water-Quality Laboratory, generally within 2 to 5 days after sample collection.

Aquatic Biota

Four different types of biological organisms were collected for analysis of organic compounds: mollusks, fish, crayfish, and aquatic plants. Using an underwater viewer to locate organisms, mollusks were collected from the stream bottom by hand or by using a kick net. The kick-net-collection method involved placing a net downstream from an area likely to contain mollusks. The target area then was disturbed by kicking or raking the stream bottom, so that mollusks would drift downstream into the net. Fish were collected by electrofishing, using both backpack and boat-mounted electrofishers. Electrofishing involves stunning the fish using an electrical current and then netting the immobilized fish. Crayfish were collected using kick nets. Vascular aquatic plants were collected by hand, and samples were stored in native water until they were processed. Processing occurred as quickly as could be accomplished following sampling, and always within 6 hours of collection.

15

All biological samples collected in 1989 and 1990 were composites of multiple organisms. Typically, samples were composited by species, and each composite consisted of about 20 mollusks, 10 fish, or 20 crayfish. At least 20 grams (wet weight) of plant material were collected for each sample of rooted aquatic plants. At some sampling sites, the number of organisms needed for a composite sample could not be collected; therefore, composite samples from these sites contained fewer than the desired number of individuals.

During 1991, additional samples were collected to assess contaminants in edible portions of fish, to compare the sensitivity of using whole fish versus fish muscle for detecting selected trace-organic compounds, and to compare the variability of concentrations of selected trace-organic compounds in whole fish and fish muscle. For this comparison, the study required sampling and analyzing several individual fish, not composited.

Sample-processing procedures varied, depending on the organism collected. For mollusks, organisms were washed in native water using a brush to remove attached sediment, algae, bacteria, and other debris. Mollusks were then placed in deionized water and held at 10°C for 3 days. Holding water was changed every 24 hours. The holding period allows an organism to purge ingested materials from its gut. Sediment and food in the gut is not part of the tissue of the organism and including this material would bias the analytical results. Following the gut-purging period, the maximum length of each individual in the composite sample was measured to the nearest millimeter. The shell was opened by cutting the adductor muscle with a stainless-steel scalpel, and the soft tissue was scraped into a precleaned, tared glass jar having a Teflon lid liner. The jar containing all the individuals in the composite was sealed, weighed, and labeled. Samples were packed in dry ice and frozen for shipment to the laboratory for analysis.

For fish, two different sample-preparation techniques were used, one for whole fish and another for fish muscle tissue. Sample preparation for whole fish involved rinsing the fish in native water, weighing and measuring each individual, collecting a scale sample to use for aging the fish, and examining each fish for external abnormalities. Each fish was wrapped in aluminum foil and all fish in a composite were placed in a labeled plastic bag and packed in dry ice for shipment to the laboratory for analysis. Small fish, comprising a composite sample, were wrapped together in one aluminum-foil packet.

For fish muscle tissue, sample preparation involved rinsing, weighing, measuring, scale-sample collection, an external examination, and the additional step of opening the body cavity to determine the sex of the fish. Then, a rectangular cut approximately 2 mm wide and 5 mm long was made through the skin of the fish on its left side, between the dorsal fin and the lateral line. This cut was made using a stainless-steel scalpel and forceps; each had been rinsed in methanol. This skin was peeled away exposing the muscle tissue underneath. Using a second set of pre-cleaned dissecting instruments, a rectangular block of muscle tissue was extracted, weighed, and placed in aluminum foil or in a precleaned glass jar. These samples were packed in dry ice for shipment to the laboratory for analysis.

Crayfish were triple rinsed using native water, then rinsed in deionized water, placed in a precleaned glass jar, weighed, and frozen. Frozen samples were shipped to the laboratory.

16

Only the apical 5 cm (centimeters) of rooted aquatic plants were collected. These plants were placed in a stainless-steel beaker and rinsed copiously using native water followed by distilled water. The sample was allowed to soak in distilled water for two hours, with a change of water after 1 hour. The soaking water was then drained, and the sample was placed in a precleaned, tared jar, weighed, and frozen.

All biological samples collected prior to 1991 were analyzed by the Mississippi State Chemical Laboratory at Mississippi State University. Fish- tissue samples collected in 1991 were analyzed at the USGS National Water- Quality Laboratory in Arvada, Colorado.

Laboratory Methods

Whole-water, filtered-water, and suspended-sediment samples were analyzed for carbamate, chlorophenoxy-acid (except suspended sediment), organochlorine, organophosphorus, triazine, and other pesticides; in addition, a few samples were analyzed for phenol, cresol, and volatile compounds (see table 2 for listing of chemical families that were analyzed at each station). Bed- sediment samples were analyzed for organochlorine and semi-volatile (phthalate esters, ethers, phenols, cresols, and monocyclic- and polycyclic-aromatic hydrocarbons) organic compounds. Soil samples were analyzed for organochlorine and organophosphorus compounds. Aquatic-biota samples (fish, mollusks, crayfish, and plants) were analyzed for organochlorine compounds; in addition, mollusks and plant samples were analyzed for selected semi-volatile organic compounds, namely polycyclic-aromatic hydrocarbons. The analytical laboratories and the methods of analysis for the water, suspended-sediment, bed-sediment, soils, and aquatic-biota samples are referenced in table 4. Three types of water-column samples were analyzed: whole water (water and suspended-sediment mixture), filtered water (water passing through a l-/zm- pore-size glass-fiber filter), and suspended sediment (direct analysis of sediment retained on a l-/zm-pore-size glass-fiber filter). Several different size classes of bed sediment were analyzed to provide data for examining associations among sediment particle size, concentrations of trace-organic compounds, and organic carbon.

Quality Assurance

Quality-assurance data for replicates, spikes, and blanks are shown in tables 30 through 55 at back of this report. The accuracy of water, sediment, and aquatic-biota analyses may be assessed by analyzing blanks (water, filters, and biological tissue) and by spiking the samples with (1) one or more of the target compounds (referred to as a spiked sample in this report-- also known as a matrix spike), and [or] (2) surrogate compounds. A surrogate compound is similar in physical and chemical properties to the compounds of interest; however, they usually do not occur in natural or polluted water (Wershaw and others, 1987). Surrogate-spike recoveries may be used to estimate sample-processing errors and may be related to matrix effects; however, spike recoveries may not reflect the performance for analyzing other organic compounds in the matrix. Matrix spikes provide an estimate of method performance for extracting compounds from the water matrix; however, the analytical recoveries do not necessarily reflect extraction efficiencies of compounds from sediment/water mixtures (whole-water samples), bed-sediment, and biological samples.

17

Table 4. Laboratories where whole-water, filtered-water, suspended-sediment, bed-sediment, soil, and aquatic-biota samples wereanalyzed, Yakima River basin, Washington, 1987-91

[USGS * U.S. Geological Survey; EPA - U.S. Environmental Protection Agency; DDD - dichlorodiphenyldichloroethane]

Sample type Period of sampling Analyzing laboratory or groupTable in this report

Reference for analytical method where data are listed

Whole water 1988-91

Filtered water June 1989(except chlorophenoxy- acid herbicides)

June 1989(chlorophenoxy-acid herbicides)

Suspended sediment

Bed sediment

Bed sediment and soils

Aquatic biota

May-September 1991

June 1989(all samples withdeterminations foro.p'-DDDin table 13)

June 1989(all samples with miss ing determinations for o.p'-DDD in table 13)

May-September 1991

August-November 1987 (organochlorine compounds)

1987(semi-volatilecompounds)1988-90(all compounds)

May 1989October-November 1989 October-November 1990

USGS National Water-Quality Laboratory in Arvada, Colorado

USGS Methods Research and Development Program in Arvada, Colorado



USGS Methods Research and Development Program in Arvada, Colorado



Tennessee Valley Authority Laboratory Branch in Chattanooga, Tennessee


Mississippi State University-- The Mississippi State Chemical Laboratory

Aquatic biota October-November 1991 USGS National Water-QualityLaboratory in Arvada, Colorado

Wershaw and others (1987); EPA Method 524.2 for volatiles USGS Method 0-3116-86 for

phenols and cresols (written communications, June, 1992, Michael P. Schroeder, USGS, Arvada, Colorado)

Method listed in Appendix A

6, 8, 10, 15, 20, 21, and 23

7, 11, 16, and 22

Wershaw and others (1987) 9

Wershaw and others (1987) 12 and 17

Method listed in Appendix B 13 and 18



EPA Method 8080 for solid waste 24 (U.S. Environmental Protection Agency, 1986)

Wershaw and others (1987); 24, 25, and 26 Wershaw and others (1983) for

semi-volatiles except soxhletextraction with methylene chlorideand methanol was used, and biobeadcleanup was not performed

Cromartie and others (1975) 27, 28, and 29

Data not shown in this report and will be available in 1993

Except for whole-water samples in this study, precision may be assessed by evaluating results of duplicate analyses (samples that were thought to be essentially identical in composition); these results reflect sample-processing and laboratory precision. Duplicate whole-water samples were collected within 60 minutes of one another in this study; consequently, the results also reflect short-term changes in stream quality.

Blank solutions consisted of distilled water that presumably was free of target analytes. These solutions were analyzed concurrently with the filtered-water samples that were extracted using the GLSE. Blank filters (clean, oven-baked filters without suspended sediment) also were analyzed. Except for beta-hexachlorocyclohexane (beta-HCH), which exhibited quantifiable concentrations in most of the blank filters, target compound concentrations generally were below the minimum reporting levels in the blank solutions and blank filters. As a result of contamination from the filter, concentrations of beta-HCH are not reported for the suspended-sediment phase.

18

REFERENCES

Cromartie, Eugene, Reichel, W.L., Locke, L.N., Belisle, A.A., Kaiser, I.E., Lament, T.G., Mulhern, B.M., Prouty, R.M., Swineford, D.M., 1975, Residues of organochlorine pesticides and polychlorinated biphenyls and autopsy data for bald eagles, 1971-72: Pesticides Monitoring Journal, v. 9, p. 11-14.

Foster, G.D., Foreman, W.T., and Gates, P.M., 1991, Performance of the Goulden large-sample extractor in multiclass pesticide isolation and preconcentration from stream water: Journal of Agricultural and Food Chemistry, v. 39, p. 1618-1622.

Goulden, P.D., and Anthony, D.H.J., 1985, Design of a large-scaleextractor for the determination of organics in water: Environment Canada, National Water Research Institute, Report 85-121, Burlington, Ontario, Canada.

Leahy, P.P., Rosenshein, J.S., and Knopman, D.S., 1990, Implementation plan for the National Water-Quality Assessment Program: U.S. Geological Survey Open-File Report 90-174, 10 p.

Lee, M.L., Vassilaros, D.L., White, C.M., and Novotny, M., 1979,Retention Indicies for programmed-temperature capillary-column gas chromatography of polycyclic aromatic hydrocarbons: Analytical Chemistry, v. 51, no. 6, p. 768-773.

McKenzie, S.W., and Rinella, J.F., 1987, Surface-water-quality assessment of the Yakima River basin, Washington: Project description: U.S. Geological Survey Open-File Report 87-238, 35 p.

Miller, J.C., and Miller, J.N., 1986, Statistics for analytical chemistry: John Wiley & Sons, New York, p. 82-118.

Rinella, J.F., McKenzie, S.W., and Fuhrer, G.J., 1992, Surface-water- quality assessment of the Yakima River basin, Washington: Analysis of available water-quality data through 1985 water year: U.S. Geological Survey Open-File Report 91-453, 261 p. (pending publication as a U.S. Geological Survey Water Supply Paper 2354- B).

Smith, J.A., Witkowski, P.J., and Fusillo, T.V., 1988, Manmade organic compounds in surface waters of the United States--A review of current understanding: U.S. Geological Survey Circular 1007, 92 p.

U.S. Environmental Protection Agency, 1986 (November), Test methods for evaluating solid waste (3rd ed.): Washington, B.C., Office of Solid Waste and Emergency Response.

Ward, J.R., and Harr, A., eds., 1990, Methods for collection andprocessing of surface-water and bed-material samples for physical and chemical analyses: U.S. Geological Survey Open-File Report 90- 140, 71 p.

19

REFERENCES - - Continued

Wershaw, R.L., Fishman, M.J., Grabbe, R.R., and Lowe, L.E., eds, 1983, Methods for the determination of organic substances in water and

fluvial sediments: U.S. Geological Survey Open-File Report 82- 1004, 173 p.

_____ 1987, Methods for the determination of organic substances in water and fluvial sediments: U.S. Geological Survey Techniques of Water-Resources Investigations, book 5, chap. A3, 80 p.

20

ANALYTICAL DATA

Data tables have been grouped and presented by sampling media: water-column data are listed in tables 5-23, bed-sediment and soil data in tables 24-26, and aquatic-biota data in tables 27-29. For each sampling medium, data are arranged alphabetically by chemical family. For each chemical family, water-column data are arranged by sampling phase (whole-water, filtered-water, and then suspended- sediment phase).

21

Table 5. Field measurements, suspended sediment, turbidity, organic carbon, and selected nutrient data for surface-water and ground-water sites where water samples were collected, Yakima River basin, Washington, 1988-91

[*C = degress Celsius; /iS/cm = microsiemens per centimeter at 25 degrees Celsius; mg/L = micrograms per liter; NTU = nephelometric turbidity units; C = Carbon; N = Nitrogen; P = Phosphorus; N02 = Nitrite; N03 = Nitrate; "E" = estimated value; "*" = data collected at 0920 hour; "+" = data collected at 0915 hour; "~" = data collected at 1400 hour; " " = not analyzed or measured; "<" = less than; ">" = greater than; see figure 1 for site locations]

Mapreference

number

2

33333

3

44

1111

1313131313

131313

141414

15

19

20

21212222

2323232323

2424242424

2424242424

2424

2727272727

272727

2628

Station number

12478200

1247830012478300124783001247830012478300

12478300

1247950012479500

1248410012484100

1248448012484480124844801248448012484480

124844801248448012484480

124845001248450012484500

12484550

12496510

12496511

12496550124965501249900012499000

1250042012500420125004201250042012500420

1250043012500430125004301250043012500430

1250043012500430125004301250043012500430

1250043012500430

1250044512500445125004451250044512500445

125004451250044512500445

1250045012500450

Station name

Cooper River at Salmon LaSac nr Roslyn

Cle Elum R above Cle Elum Lake nr RoslynCle Elum R above Cle Elum Lake nr RoslynCle Elum R above Cle Elum Lake nr RoslynCle Elum R above Cle Elum Lake nr RoslynCle Elum R above Cle Elum Lake nr Roslyn

Cle Elum R above Cle Elum Lake nr Roslyn

Yakima River at Cle ElumYakima River at Cle Elum

Wilson Creek abv. Cherry Creek at ThrallWilson Creek abv. Cherry Creek at Thrall

Cherry Creek at ThrallCherry Creek at ThrallCherry Creek at ThrallCherry Creek at ThrallCherry Creek at Thrall

Cherry Creek at ThrallCherry Creek at ThrallCherry Creek at Thrall

Yakima River at UmtanumYakima River at UmtanumYakima River at Umtanum

Umtanum Creek nr mouth at Umtanum

Pacific Power & Light Company Wasteway

City of Yakima-Finish Water

Buckskin Slough blw Gleed Ditch nr GleedBuckskin Slough blw Gleed Ditch nr GleedNaches River nr North YakimaNaches River nr North Yakima

Moxee Drain at Birchfield Road nr Union GapMoxee Drain at Birchfield Road nr Union GapMoxee Drain at Birchfield Road nr Union GapMoxee Drain at Birchfield Road nr Union GapMoxee Drain at Birchfield Road nr Union Gap

Moxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union Gap


Moxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union Gap

Wide Hollow Creek near mouth at Union GapWide Hollow Creek near mouth at Union GapWide Hollow Creek near mouth at Union GapWide Hollow Creek near mouth at Union GapWide Hollow Creek near mouth at Union Gap

Wide Hollow Creek near mouth at Union GapWide Hollow Creek near mouth at Union GapWide Hollow Creek near mouth at Union Gap

Yakima R abv Ahtanum Cr at Union GapYakima R abv Ahtanum Cr at Union Gap

Date

06-28-89

05-05-8806-02-8807-26-8808-31-8811-16-88

03-09-89

07-26-8806-29-89

07-26-8806-29-89

05-05-8806-02-8806-02-8807-26-8808-31-88

11-18-8803-09-8906-29-89

07-27-8806-28-8906-28-89

06-28-89

06-25-89

06-25-89

05-22-9106-12-9107-26-8806-27-89

05-23-9106-17-9106-20-9107-10-9109-04-91

05-06-8805-06-8806-01-8807-26-8807-27-88

07-28-8807-29-8808-30-8811-15-8803-10-89

06-28-8906-28-89

05-05-8806-03-8807-27-8808-30-8811-15-88

11-15-8803-10-8906-30-89

07-27-8806-27-89

Time

1900

11000930100010301030

1015

15001200

16151600

15301400140510301630

100014001830

104517001705

1400

1700

1630

1100134513301015

10001100164512401115

09300940160011001310

16050800173010151200

10301035

18450730102514301330

143014001000

16001630

Dis charge , insta-taneous

(ft3 /s)

229

8851,000

607199539

166

3,7803,780

83144

266305

--127225

76250126

3,830*3,630

1.0

501

21

1719

3281,190

6877

1465163

87--

797676

7091772624

65--

4461262223

__8233

2,8903,630

Spe cific

Temper- con- ature duct-water

CC)

11.0

5.55.5

14.515.04.5

2.0

16.510.5

22.015.0

13.012.0

--16.0

7.54.0

16.0

15.5*13.0

16.5

16.5

14.0

14.021.013.0

12.014.014.520.015.0

11.5--

17.0--

23.0

23.017.520.59.57.0

14.5

12.512.518.517.512.0

__7.015.0

21.017.0

ance

(/iS/cm)

24

4737314550

118

4947

213210

262363--

412334

460359245

77*88

205

51

54

--2708267

242247249313300

279

275296309

320266280649606

295

247202322324446

253260

8692

22

Table 5. Field measurements, suspended sediment, turbidity, organic carbon, and selected nutrient data for surface-water and ground-water sites where water samples were collected, Yakima River basin, Washington, 1988-91--Continued

Station number Date

12478200

1247830012478300124783001247830012478300

12478300

1247950012479500

1248410012484100

1248448012484480124844801248448012484480

124844801248448012484480

124845001248450012484500

1248455012496510

12496511

1249655012496550

1249900012499000

1250042012500420125004201250042012500420

1250043012500430125004301250043012500430

1250043012500430125004301250043012500430

1250043012500430

1250044512500445125004451250044512500445

125004451250044512500445

1250045012500450

06-28-89

05-05-8806-02-8807-26-8808-31-8811-16-88

03-09-89

07-26-8806-29-89

07-26-8806-29-89

05-05-8806-02-8806-02-8807-26-8808-31-88

11-18-8803-09-8906-29-89

07-27-8806-28-8906-28-89

06-28-8906-25-89

06-25-89

05-22-9106-12-91

07-26-8806-27-89

05-23-9106-17-9106-20-9107-10-9109-04-91

05-06-8805-06-8806-01-8807-26-8807-27-88

07-28-8807-29-8808-30-8811-15-8803-10-89

06-28-8906-28-89

05-05-8806-03-8807-27-8808-30-8811-15-88

11-15-8803-10-8906-30-89

07-27-8806-27-89

Oxygen,dissolved(mg/L)

10.2

----

~

__11.0

10.4

--

9.2

10.8

9.4

-

__10.5

----

------

------

9.2

------

__--

10.0

10.0

pH (standardunits)

8.2

7.67.77.68.07.7

8.0

7.97.7

8.48.1

8.28.18.18.28.1

8.38.18.1

7.6*8.1

8.17.8

7.0

__--

9.18.1

__------

8.2--

8.37.98.1

8.28.08.18.58.5

6.2

7.97.47.87.88.1

8.17.97.8

8.48.5

Tur bidity(NTU)

--

2.8--

-

1.7--

7.6--

----

37--

--

6.0--

-

__1.5

2.9--

4056

19015042

------

>100

------

__

--

2.8--

----

13

Sedi ment, suspended(mg/L)

2

<13

<112

1

56

1013

9164688245

251,020

121

192525

14

.2

148

36

252373

1,450903337

134143296597443

5656071575847

436432

1728855

5211

8

2224

Carbon, organic sus pended total(mg/Las C)

0.1

.1

.1

.1

.1

.3

.1

.1

.1

.5

.2

2.3.9.8

1.6.8

.4>4.22.1

.5

.3

.3

.1

.2

<.l

.4

.3

.2

.2

1.63.5

E101.42.2

1.01.01.93.43.2

4.9>3.21.51.2

>4.3>4.6

1.0.7.3.2.2

.4>4.1<.l

.6

.7

Carbon, organic dis solved(mg/Las C)

1.1

3.41.61.6.7.8

.8

1.82.8

4.85.1

4.44.9--

5.23.9

2.6129.1

2.65.82.4

2.11.2

.8

1.82.2

2.61.4

2.42.46.63.52.9

3.33.23.34.04.7

3.13.93.26.55.1

2.92.8

2.05.42.61.81.3

228.41.6

3.11.6

Nitro gen, am monia + organic total(mg/Las N)

------

-

.50--

----.70

--

<.20--

-

1.2--

.40

.502.1.90.40

----

1.0.40

.40

.40----

__

--

<.20--

--

<.20

Nitro gen, NO2+N03 dis solved(mg/Las N)

0.036

----

-

.047

.63

.59

----

3.1--

--.87

.15

.46

.016<.010

<.010

--

2.7.045

.81

.862.32.31.1

----

1.21.2

1.2.98----

1.3

--

1.4--

__--

1.3

.16

.16

Phos phorus total(mg/Las P)

--------

-

.16

----.25

----

.04----

-

--

.25--

.23

.15

.70

.43

.37

----.45.39

.28

.15------

__

--.13--

__----

.09--

Phos phorus ortho , dis solved(mg/Las P)

<0.001

--

-

<.001

.10

.08

------.21--

--.11

.017

.04

.082

.015

<.001

----

.13

.005

.08

.10

.26

.09

.10

------.15.15

.17

.18 --

.11--

--.12 --

--.07

.04

.03

23

Table 5. Field measurements, suspended sediment, turbidity, organic carbon, and selected nutrient data for surface-water and ground-water sites where water samples were collected, Yakima River basin, Washington, 1988-91 Continued

Mapreference

number

30

33

34

3535353535

3636363636

36363636

3737

3838383838

3838

40

41

4343

45

4646464646

4646464646

4646464646

4747

4848

4949

5050

i

Station number

12502500

12505350

12505410

1250545012505450125054501250545012505450

1250546012505460125054601250546012505460

12505460125054601250546012505460

1250551012505510

1250750812507508125075081250750812507508

1250750812507508

12507585

12507594

1250862012508620

12508630

1250885012508850125088501250885012508850

1250885012508850125088501250885012508850

1250885012508850125088501250885012508850

1250905012509050

1250949912509499

1250971012509710

1250982912509829

Station name

Ahtanum Creek at Union Gap

E Toppenish Drain at Wilson Rd nr Toppenish

Sub 35 Drain at Parton Road near Granger

Granger Drain at GrangerGranger Drain at GrangerGranger Drain at GrangerGranger Drain at GrangerGranger Drain at Granger

Granger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr Granger

Granger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr Granger

Marion Drain at Indian Church Rd at GrangerMarion Drain at Indian Church Rd at Granger

Toppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr Granger

Toppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr Granger

Yakima River at RM 72 ab Satus Cr nr Sunnyside

Satus Cr abv Wilson-Charley Canyon nr Toppenish

Satus Creek at gage at SatusSatus Creek at gage at Satus

South Drain nr Satus

Sulphur Cr Wasteway n SunnysideSulphur Cr Wasteway n SunnysideSulphur Cr Wasteway n SunnysideSulphur Cr Wasteway n SunnysideSulphur Cr Wasteway n Sunnyside

Sulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr Sunnyside


Yakima R at Euclid Br at RM 55 nr GrandviewYakima R at Euclid Br at RM 55 nr Grandview

Chandler Canal at Bunn Rd at ProsserChandler Canal at Bunn Rd at Prosser

Spring Creek at mouth at WhitstranSpring Creek at mouth at Whitstran

Snipes Creek at mouth at WhitstranSnipes Creek at mouth at Whitstran

Date

06-30-89

06-29-89

06-29-89

05-23-9106-17-9106-20-9107-10-9109-04-91

05-06-8806-01-8807-28-8807-28-8809-02-88

11-15-8803-09-8906-27-8906-27-89

07-28-8806-29-89

05-06-8806-03-8807-28-8809-01-8811-16-88

03-08-8906-26-89

06-30-89

06-26-89

07-29-8806-29-89

06-27-89

05-06-8806-03-8807-28-8807-28-8808-31-88

08-31-8811-17-8803-08-8906-26-8906-26-89

05-24-9106-19-9106-20-9107-11-9109-05-91

07-28-8806-28-89

05-22-9106-13-91

07-29-8806-30-89

07-29-8806-30-89

Time

1230

1700

1500

12301420140015001420

12301300073009301000

1645173017001705

11451130

13451000144509301615

16001445

1030

0940

11451945

1300

16301300120017001530

16300900120020002005

10001145120011551130

10101020

15001240

13001800

15001430

Dis charge, insta-taneous

(ft3 /s)

23

53

56

5155936186

3756494963

293037

--

3971

322105545827

9039

1,070

12

83124

82

302370151144235

2277563

265--

380246800137341

9631,560

1,4801,430

24"

47

3350

Temper aturewater

rc)

17.0

16.0

16.0

15.017.515.522.018.5

13.015.517.017.016.5

12.010.518.5

--

19.516.0

13.013.521.5

--8.5

8.521.5

16.5

12.5

20.017.5

18.0

15.514.018.021.520.0

20.011.09.0

20.0~-

14.015.515.518.517.0

23.0+19.5

15.5

23.019.0

24.018.0

Spe cific con ductance

(/iS/cm)

320

149

241

330358757353326

418357350328304

652689360

257242

217207262267451

402262

194

54

334279

314

264239333381290

290669693259--

224292465317273

267250

141

290192

168167

24

Table 5. Field measurements, suspended sediment, turbidity, organic carbon, and selected nutrient data for surface-water and ground-water sites where water samples were collected, Yakima River basin, Washington, 1988-91 Continued

Station number

12502500

12505350

12505410

1250545012505450125054501250545012505450

1250546012505460125054601250546012505460

12505460125054601250546012505460

1250551012505510

1250750812507508125075081250750812507508

1250750812507508

12507585

12507594

1250862012508620

12508630

1250885012508850125088501250885012508850

1250885012508850125088501250885012508850

1250885012508850125088501250885012508850

1250905012509050

1250949912509499

1250971012509710

1250982912509829

Date

06-30-89

06-29-89

06-29-89

05-23-9106-17-9106-20-9107-10-9109-04-91

05-06-8806-01-8807-28-8807-28-8809-02-88

11-15-8803-09-8906-27-8906-27-89

07-28-8806-29-89

05-06-8806-03-8807-28-8809-01-8811-16-88

03-08-8906-26-89

06-30-89

06-26-89

07-29-8806-29-89

06-27-89

05-06-8806-03-8807-28-8807-28-8808-31-88

08-31-8811-17-8803-08-8906-26-8906-26-89

05-24-9106-19-9106-20-9107-11-9109-05-91

07-28-8806-28-89

05-22-9106-13-91

07-29-8806-30-89

07-29-8806-30-89


9.8

8.6

8.3

----

__--

7.9--

._10.7

--

__10.5

8.9

9.6

__8.5

8.5

--------

--

8.5

-- --

8.6

9.0

9.2

pH Tur-(stand- bid-ard ityunits) (NTU)

8.1

7.7

7.8

7587

23018050

8.28.28.0 >1007.8 >1007.7

8.48.58.2--

8.78.2

8.27.98.3 >107.78.6

8.78.5

7.5

7.8

8.0 147.8

8.3

8.88.18.18.18.0

8.28.48.48.1

1833

2504730

8.3+ 248.2

20

8.2 337.8

7.8 >1007.8

Sediment,suspended(mg/L)

9

52

28

557576963

1,020396

205526421432282

6292

643643

729

32

1311

337

3032

44

2

2138

145

702041289983

6719

108245217

130180909272316

2647

38115

140196

5365

Carbon, organic suspendedtotal(mg/Las C)

0.1

.9

.7

2.8E5.4

E10E92.4

2.03.13.01.71.6

1.02.3

>4.7>4.5

.3

.8

.9--.1.3

>5.2

.9

.4

1.4

.2

.6

.8

1.8

1.01.3--

1.41.2

1.11.01.62.32.4

.61.8

EllE3.41.7

.7

.72.1

1.5

.81.3

Carbon, organicdissolved(mg/Las C)

2.3

1.6

1.6

3.6

225.83.5

3.06.74.14.12.8

2.4113.3

35

2.81.8

2.53.02.32.8

27

5.42.1

1.7

1.2

2.72.0

2.7

3.03.63.03.2

60

3.61.93.72.32.3

2.32.7

153.02.4

4.112

2.21.9

2.52.3

2.01.8

Nitro gen, am monia +organictotal(mg/Las N)

-

-

.801.25.71.6.60

1.8.90

2.8----

.50--

-- .50----

-

.40

1.2

----

<.20.60

-- ----

.80

.903.62.2.70

.30

--

.20

<.20

Nitro gen, N02+N03dissolved(mg/Las N)

1.8

2.0

1.61.86.81.91.2

2.02.0--

3.21.9--

2.42.1

----

2.4 --

1.80

.84

.01

2.21.7

-

----.48

3.1--

--

1.8--

1.22.04.62.01.8

1.21.1

----

1.1.64

.38

.39

Phosphorustotal(mg/Las F)

-

-

.42

.491.6.34.49

.71.32

.67----

.08--

--.11--

-

-

.13--

.11

.03.26--

------

.16

.16

.871.2.31

.13--

----

.13

.09--

Phos phorus ortho,dissolved(mg/Las F)

0.13

.05

.28

.33

.80

.22

.09

.16.16

.34.19

.08

.07

.08

.07

.05

.006

.08

.08

--.10.14

-- .09

.04

.07

.32

.22

.05

.09

.06

.06

.06

.03

.03

25


Mapreferenc

number

5151515151

5151515151

5151515151

51

53

55

58

5959

61

;e

Station number

1251050012510500125105001251050012510500

1251050012510500125105001251050012510500

1251050012510500125105001251050012510500

12510500

461720120043201

462510120323901

463233120262101

463234120261601463234120261601

463257120260801

Station name

Yakima River at KionaYakima River at KionaYakima River at KionaYakima River at KionaYakima River at Kiona



Yakima River at Kiona

Well 1, Sunnyside, 09N/22E-04P01

Well 2, Harrah, 11N/18E-22R02

Well 12N/19E-09H02

Well 12N/19E-09H01Well 12N/19E-09H01

Well 12N/19E-10D02

Date

05-07-8806-01-8807-29-8808-31-8811-17-88

03-08-8906-26-8906-26-8912-06-8912-06-89

12-07-8905-21-9107-09-9108-06-9108-06-91

09-25-91

06-27-89

06-29-89

01-20-89

01-20-8901-20-89

01-20-89

Time

08000900103010001400

09001430143516152357

18521200115511501151

1120

1900

0915

0750

07300737

0715

Dis charge, insta-taneous

(ft3 /s)

1,9601,870

8541,6102,410

2,3701,500

--5,2005,210

4,7803,8501,8501,480

--

1,590

-

-

--

--

Spe cific

Temper- con- ature duct-water

CO

14.014.524.020.08.0

7.025.0

--6.56.0

5.515.522.525.0--

17.0

14.5

14.0

--~-

--

ance

(MS/C.)

242222306320251

277267

251185

152184227279

--

292

380

329

582

872864

921


Station number

1251050012510500125105001251050012510500

1251050012510500125105001251050012510500

1251050012510500125105001251050012510500

12510500

461720120043201

462510120323901

463233120262101

463234120261601463234120261601

Date

05-07-8806-01-8807-29-8808-31-8811-17-88

03-08-8906-26-8906-26-8912-06-8912-06-89

12-07-8905-21-9107-09-9108-06-9108-06-91

09-25-91

06-27-89

06-29-89

01-20-89

01-20-8901-20-89


__------

10.5

----

10.010.7

--

-

2.4

7.1

-

--

pH(standardunits)

8.48.18.57.68.4

8.38.6--

8.08.0

7.98.08.4--

8.5

7.6

7.6

-

__

Turbidity(NTU)

__--

19--

----

1214

14144.5

1010

.20

-

-

-

Sediment,suspended(mg/L)

2835223510

10330307171

5751183230

7

-

-

-

__--

Carbon, organic suspendedtotal(mg/Las C)

.8

.2

.71.3.4

1.81.01.21.82.3

2.0.7.6

1.11.2

.5

<.l

<.l

-

__

Carbon , organicdissolved(mg/Las C)

2.72.85.87.31.1

2.12.12.21.61.8

2.72.42.42.72.9

2.1

1.4

1.2

-

Nitro gen, am monia +organictotal(mg/Las N)

_--.40

----.65.61

.59

.60

.30

.30

.40

-

-

Nitro gen, N02+N03dissolved(mg/Las N)

__--

1.1--

1.1--

1.2.76

.62

.68

.861.2--

1.2

1.0

4.9

3.0

9.08.9

Phosphorustotal(mg/Las P)

__--.14----

----.20.10

.16

.13

.08

.12

.09

-

-

-

--

Phos phorus ortho ,dissolved(mg/Las P)

__--.08--

__.05--.08.04

.05

.02

.04

.10

.07

.14

.078

-

463257120260801 01-20-89 6.0

26

Table 6. Concentrations of carbamate compounds in whole-water samples, Yakima River basin, Washington, 1988-91

[Concentrations in nanograms per liter; "--" = not analyzed; "<" = less than; see figure 1 for site locations]

Map reference number

33333

33

4

11

1313131313

1313

1414

212121

22

2424242424

2424242424

24

2727272727

2727

28

3636363636

36363636

37

3838383838

38

43

4646464646

Station number

1247830012478300124783001247830012478300

1247830012478300

12479500

12484100

1248448012484480124844801248448012484480

1248448012484480

1248450012484500

124965501249655012496550

12499000

1250043012500430125004301250043012500430

1250043012500430125004301250043012500430

12500430

1250044512500445125004451250044512500445

1250044512500445

12500450

1250546012505460125054601250546012505460

12505460125054601250546012505460

12505510

1250750812507508125075081250750812507508

12507508

12508620

1250885012508850125088501250885012508850

Station name

Cle Elura R above Cle Elura Lake nr RoslynCle Elura R above Cle Elura Lake nr RoslynCle Elura R above Cle Elura Lake nr RoslynCle Elura R above Cle Elura Lake nr RoslynCle Elura R above Cle Elura Lake nr Roslyn

Cle Elura R above Cle Elura Lake nr RoslynCle Elura R above Cle Elura Lake nr Roslyn

Yakima River at Cle Elura

Wilson Creek abv. Cherry Creek at Thrall


Cherry Creek at ThrallCherry Creek at Thrall

Yakima River at UmtanumYakima River at Umtanum

Buckskin Slough blw Gleed Ditch nr GleedBuckskin Slough blw Gleed Ditch nr GleedBuckskin Slough blw Gleed Ditch nr Gleed

Naches River nr North Yakima

Moxe Drain at Thorp Rd nr Union GapMoxe Drain at Thorp Rd nr Union GapMoxe Drain at Thorp Rd nr Union GapMoxe Drain at Thorp Rd nr Union GapMoxe Drain at Thorp Rd nr Union Gap

Moxe Drain at Thorp Rd nr Union GapMoxe Drain at Thorp Rd nr Union GapMoxe Drain at Thorp Rd nr Union GapMoxe Drain at Thorp Rd nr Union GapMoxe Drain at Thorp Rd nr Union Gap

Moxee Drain at Thorp Rd nr Union Gap


Wide Hollow Creek near mouth at Union GapWide Hollow Creek near mouth at Union Gap

Yakima R abv Ahtanura Cr at Union Gap



Marion Drain et Indian Church Rd at Granger


Toppenish Cr at Indian Church Rd nr Granger

Satus Creek st gage at Satus


Date

05-05-8806-02-8807-26-8807-26-8808-31-88

11-16-8803-09-89

07-26-88

07-26-88

05-05-8806-02-8806-02-8807-26-8808-31-88

11-18-8803-09-89

07-27-8806-28-89

05-22-9106-12-9108-07-91

07-26-88

05-06-8805-06-8806-01-8807-26-8807-27-88

07-28-8807-29-8808-30-8811-15-8803-10-89

06-28-89

05-05-8806-03-8807-27-8808-30-8811-15-88

11-15-8803-10-89

07-27-88

05-06-8806-01-8807-28-8807-28-8807-28-88

09-02-8811-15-8803-09-8906-27-89

07-28-88

05-06-8806-03-8807-28-8809-01-8811-16-88

03-08-89

07-29-88

05-06-8806-03-8807-28-8807-28-8808-31-88

Time

11000930100010151030

10301015

1500

1615

15301400140510301630

10001400

10451705

110013451000

1330

09300940160011001310

16050800173010151200

1035

184507301025143*11330

14301400

1600

12301300073009301015

1000164517301705

1145

13451000144509301615

1600

1145

16301300120017001530

Aldi- carb

<500<500<500<500<500

<500<500

<500

<500

<500<500<500<500<500

<500<500

<500<500

<500<500

<500

<500<500<500<500<500

<500<500<500<500<500

<500

<500<500<500<500<500

<500<500

<500

<500<500<500<500<500

<500<500<500<500

<500

<500<500<500<500<500

<500

<500

<500<500<500<500<500

Aldi- carb sulfone

<500<500<500<500<500

<500<500

<500

<500

<500<500<500<500<500

<500<500

<500<500

<500<500<500

<500

<500<500<500<500<500

<500<500<500<500<500

<500

<500<500<500<500<500

<500<500

<500

<500<500<500<500<500

<500<500<500<500

<500

<500<500<500<500<500

<500

<500

<500<500<500<500<500

Aldi- carb sulfoxide

<500<500<500<500<500

<500<500

<500

<500

<500<500<500<500<500

<500<500

<500<500

<500<500<500

<500

<500<500<500<500<500

<500<500<500<500<500

<500

<500<500<500<500<500

<500<500

<500

<500<500<500<500<500

<500<500<500<500

<500

<500<500<500<500<500

<500

<500

<500<500<500<500<500

27

Table 6. Concentrations of carbamate compounds in whole-water samples, Yakima River basin, Washington, 1988-91 Continued

Station number

12478300 12478300 12478300 12478300 12478300

12478300 12478300

12479500

12484100

12484480 12484480 12484480 12484480 12484480

12484480 12484480

12484500 12484500

12496550 12496550 12496550

12499000

12500430 12500430 12500430 12500430 12500430

12500430 12500430 12500430 12500430 12500430

12500430

12500445 12500445 12500445 12500445 12500445

12500445 12500445

12500450

12505460 12505460 12505460 12505460 12505460

12505460 12505460 12505460 12505460

12505510

12507508 12507508 12507508 12507508 12507508

12507508

12508620

12508850 12508850 12508850 12508850 12508850

Date

05-05-88 06-02-88 07-26-88 07-26-88 08-31-88

11-16-88 03-09-89

07-26-88

07-26-88

05-05-88 06-02-88 06-02-88 07-26-88 08-31-88

11-18-88 03-09-89

07-27-88 06-28-89

05-22-91 06-12-91 08-07-91

07-26-88

05-06-88 05-06-88 06-01-88 07-26-88 07-27-88

07-28-88 07-29-88 08-30-88 11-15-88 03-10-89

06-28-89

05-05-88 06-03-88 07-27-88 08-30-88 11-15-88

11-15-88 03-10-89

07-27-88

05-06-88 06-01-88 07-28-88 07-28-88 07-28-88

09-02-86 11-15-68 03-09-89 06-27-89

07-28-88

05-06-88 06-03-88 07-28-88 09-01-88 11-16-88

03-08-89

07-29-88

05-06-68 06-03-88 07-28-88 07-28-88 08-31-88

Carbaryl

<500 <500 <500 <500 <500

<500 <500

<500

<500

<500 <500 <500 <500

14

<500 <500

<500 <500

<500 <500 <500

<500

<500 <500 <500 <500 <500

<500 <500 <500 <500 <500

2

<500 <500 <500 <500 <500

<500 <500

<500

<500 <500 <500 <500 <500

4 <500 <500 <500

<500

<500 <500 <500 <500 <500

<500

<500

<500 <500 <500 <500 <500

Carbo- furan

<500 <500 <500 <500 <500

<500 <500

<500

<500

<500 <500 <500 <500 <500

<500 <500

<500 <500

<500 <500 <500

<500

<500 <500 <500 <500 <500

<500 <500 <500 <500 <500

<500

<500 <500 <500 <500 <500

<500 <500

<500

<500 <500 <500 <500 <500

<500 <500 <500 <500

<500

<500 <500 <500 <500 <500

<500

<500

<500 <500 <500 <500 <500

3- Hydroxy- carbofuran

<500 <500 <500 <500 <500

<500 <500

<500

<500

<500 <500 <500 <500 <500

<500 <500

<500 <500

<500 <500 <500

<500

<500 <500 <500 <500 <500

<500 <500 <500 <500 <500

<500

<500 <500 <500 <500 <500

<500 <500

<500

<500 <500 <500 <500 <500

<500 <500 <500 <500

<500

<500 <500 <500 <500 <500

<500

<500

<500 <500 <500 <500 <500

Methio- carb

<500 <500 <500 <500

<500 <500

<500

<500

<500 <500 <500 <500

<500 <500

<500 <500

<500 <500 <500

<500

<500 <500 <500

<500 <500 <500 <500 <500

<500

<500 <500 <500 <500

<500 <500

<500

<500 <500 <500 <500

<500 <500 <500 <500

<500

<500 <500 <500 <500

<500

<500

<500 <500 <500 <500

Metho- myl

<500 <500 <500 <500 <500

<500 <500

<500

<500

<500 <500 <500 <500 <500

<500 <500

<500 <500

<500 <500 <500

<500

<500 <500 <500 <500 <500

<500 <500 <500 <500 <500

<500

<500 <500 <500 <500 <500

<500 <500

<500

<500 <500 <500 <500 <500

<500 <500 <500 <500

140

<500 <500

51 <500 <500

<500

110

<500 <500 <500 <500 <500

1- Naph- thol

<500 <500 <500 <500 <500

<500 <500

<500

<500

<500 <500 <500 <500 <500

<500 <500

<500 <500

<500 <500 <500

<500

<500 <500 <500 <500 <500

<500 <500 <500 <500 <500

<500

<500 <500 <500 <500 <500

<500 <500

<500

<500 <500 <500 <500 <500

<500 <500 <500 <500

<500

<500 <500 <500 <500 <500

<500

<500

<500 <500 <500 <500 <500

Oxamyl

<500 <500 <500 <500 <500

<500 <500

<500

<500

<500 <500 <500 <500 <500

<500 <500

<500 <500

<500 <500 <500

<500

<500 <500 <500 <500 <500

<500 <500 <500 <500 <500

<500

<500 <500 <500 <500 <500

<500 <500

<500

<500 <500 <500 <500 <500

<500 <500 <500 <500

<500

<500 <500 <500 <500 <500

<500

<500

<500 <500 <500 <500 <500

Propham

<500 <500 <500 <500 <500

<500 <500

<500

<500

<500 <500 <500 <500 <500

<500 <500

<500 <500

<500

<500

<500

<500 <500 <500 <500 <500

<500 <500 <500 <500 <500

<500

<500 <500 <500 <500 <500

<500 <500

<500

<500 <500 <500 <500 <500

<500 <500 <500 <500

<500

<500 <500 <500 <500 <500

<500

<500

<500 <500 <500 <500 <500

Propoxur

<500 <500 <500 <500

<500 <500

<500

<500

<500 <500 <500 <500

<500 <500

<500 <500

<500 <500 <500

<500

<500 <500 <500

<500 <500 <500 <500 <500

<500

<500 <500 <500 <500

<500 <500

<500

<500 <500 <500 <500

<500 <500 <500 <500

<500

<500 <500 <500 <500

<500

<500

<500 <500 <500 <500

28

Table 6. Concentrations of carbamate compounds in whole-water samples, Yakima River basin, Washington, 1988-91


46 46 46 46

47

48 48

49

50

51 51 51 51 51

51 51

Station number

12508850 12508850 12508850 12508850

12509050

12509499 12509499

12509710

12509829

12510500 12510500 12510500 12510500 12510500

12510500 12510500

Station name

Sulphur Cr Wasteway nr Sunny side Sulphur Cr Wasteway nr Sunny side Sulphur Cr Wasteway nr Sunnyside Sulphur Cr Wasteway nr Sunnyside

Yakima R at Euclid Br at RM 55 nr Grand view

Chandler Canal at Bunn Rd nr Frosser Chandler Canal at Bunn Rd nr Frosser

Spring Creek at mouth at Whitstran

Snipes Creek at mouth at Whitstran

Yakima River at Kiona Yakima River at Kiona Yakima River at Kiona Yakima River at Kiona Yakima River at Kiona

Yakima River at Kiona Yakima River at Kiona

Date

08-31-88 11-17-88 03-08-89 06-26-89

07-28-88

05-22-91 06-13-91

07-29-88

07-29-88

05-07-88 06-01-88 07-29-88 08-31-88 11-17-88

03-08-89 06-26-89

Time

1630 0900 1200 2005

1010

1500 1240

1300

1500

0800 0900 1030 1000 1400

0900 1435

Aldi- carb

<500 <500 <500 <500

<500

<500

<500

<500

<500 <500 <500 <500 <500

<500 <500

Aldi- carb sulfone

<500 <500 <500 <500

<500

<500 <500

<500

<500

<500 <500 <500 <500 <500

<500 <500

Aldi- carb sulfoxide

<500 <500 <500 <500

<500

<500 <500

<500

<500

<500 <500 <500 <500 <500

<500 <500

Station number

12508850 12508850 12508850 12508850

12509050

12509499 12509499

12509710

12509829

12510500 12510500 12510500 12510500 12510500

12510500 12510500

Date

08-31-88 11-17-88 03-08-89 06-26-89

07-28-88

05-22-91 06-13-91

07-29-88

07-29-88

05-07-88 06-01-88 07-29-88 08-31-88 11-17-88

03-08-89 06-26-89

Carbaryl

<500 <500 <500

6

<500

<500 <500

<500

<500

<500 <500 <500 <500 <500

<500 <500

Carbo- furan

<500 <500 <500 <500

<500

<500 <500

<500

<500

A A A A A UIUIUIUIUI ooooo ooooo

<500 <500

3- Hydroxy- carbofuran

<500 <500 <500 <500

<500

<500 <500

<500

<500

<500 <500 <500 <500 <500

<500 <500

Methio- carb

<500 <500 <500 <500

<500

<500 <500

<soa<500

<500 <500 <500 <500

<500 <500

Metho- myl

<500 <500 <500 <500

<500

<500 <500

<500

<500

<500 <500 <500

30 <500

<500 <500

1- Naph- thol

<500 <500 <500 <500

<500

<500 <500

<500

<500

A A A A A UIUIUIUIUI OOOOO ooooo

<500 <500

Oxamyl

<500 <500 <500 <500

<500

<500 <500

<500

<500

A A A A A UIUIUIUIUIooooo ooooo

<500 <500

Fropham

<500 <500 <500 <500

<500

<500

<500

<500

A A A A A Ui UIUIUIUI ooooo ooooo

<500 <500

Fropoxur

<500 <500 <500 <500

<500

<500 <500

<500

<500

<500 <500 <500 <500

<500 <500

29

Table 7. Concentrations of carbamate, thiocarbamate, pyrethoid, and other pesticides in filtered-water samples, Yakima River basin, Washington, June 25-30, 1989

[Concentrations in nanograms per liter; "<" = less than; "T" = present, but below quantifiable concentration; " " = not analyzed; EPIC = S-ethyl dipropylthiocarbamate; butylate was not detected; trace concentrations of flucythrinate were detected below quantifiable concentrations in Yakima River at Cle Elum and Yakima River at Umtanum; linuron was analyzed in 3 samples 1.9 ng/L in the Yakima River at Kions and not detected at Cherry Creek and Yakima River at RM 72; see figure 1 for site locations]

Map refer ence numb 8]

24

111314

1519

202224

2728303334

3655

373840

41

53

434546

47495051

Station : number

1247820012479500124841001248448012484500

1248455012496510

124965111249900012500430

1250044512500450125025001250535012505410

12505460462510-120323901125055101250750812507585

12507594

461720-120043201125086201250863012508850

12509050125097101250982912510500

Station name 1

Cooper River at Salmon LaSacYakima River at Cle ElumWilson Cr abv. Cherry CreekCherry Creek at ThrallYakima River at Umtanum

Umtanum Creek nr mouthPacific Power & Light CompanyWastewayCity of Yakima-Finish WaterNaches River nr North YakimaMoxee Drain at Thorp Rd

Wide Hollow Creek near mouthYakima R abv Ahtanum CrAhtanum Creek at Union GapE Toppenish Drain at Wilson RdSub 35 Drain at Parton Road

Granger Drain at mouth

Well 2, Harrah, 11N/18E-22R02Marion Drain, Indian Church RdToppenish Cr, Indian Church RdYakima River at RM 72

Satus Cr abv Wilson-CharleyCanyon nr Toppenish

Well 1, Sunnyside, 09/22E-04P01Satus Cr at gage at SatusSouth Drain nr SatusSulphur Creek Wasteway

Yakima R at Euclid Br at RM 55Spring Creek at mouthSnipes Creek at mouthYakima River at Kiona

Bromacil

<1.4<!83

T<3.0

<o cZ . D

T<.97

<.80<.94

T<.45<4.6

T<2.9T<2.4<1 527T<2.9

13

<.94<2.9<1.4<1.5

<.46

<.93<2.9T<4.7

T<24

1.7<2.9T<2.9<2.6

Carbary!

<1.6<!so

T<3.4T<1.0

<.72

<.49<1.0

--

T<3.2<1.5

13T<3.2

<1.0T<3.2

1.5

<1.0T<3.2

T<26

T<3.3T<3.2<1.6

Carbo- L furan

<0.56<.26

T<1.2<.83T<.80

<.54

<.25<.36<. 18

<1.9

<1.1T<!76<.61

<1 13.7

<1.7

<.36<1. 1<]581.5

<.19

<.36<1. 1<1. 9<9.1

.96T<1. 1<1. 1<!so

EPIC

<0.31<.351.6

371.6

<.22

<.34<.20<.26

T<2.7

<.601.1<.871.86.3

3.1

1.03.22.87.3

<.27

<.202.93.4

T<5.0

3.83.31.53.3

cis-Per- methrin

T<1.2<.76<2.5<4.4

<.79

<.74<.78<.48<4.9

<2.4<2.2<1.6<2.4<2.4

<4.4

<.78<2.4T<1.5<4.4

<.49

<.77<2.4<5.0

<20

<1.6<2.4<2.4<2.4

trans- Per- methrin

T<1.3T<.85<2.8<5.5

<.79

<.83<.87<.54

<5.6

<2.6T<2.5<1.8<2.7<2.6

<5.0

<.87<2.6<1.7<5.5

<.56

<.86<2.7<5.6

<22

<1.8<2.7<2.6<2.7

Propar- gite

<1.8T<!ea<3.8T<4.6T<2.1

<.66<1.2

.57210

<3.63.0

<2.11911

40

<1.2302717

<.64

<1.214

160260

443.0

457.2

Triadi- mefon

<0.66<.30

<1.4

<. 92

<.29<.43<.28

<2.8

T<1.3<.88<.91

<1.3T<1.3

<2.6

<.43<1. 3<.87<.61

<.28

T<.42<1. 3<2.9

T<11

<.92<1.3T<1.3

<.92

Verno- late

<0.33K.41<.69

T<1 ^^* J. . «?

<.25

<.40<.21<.34

<3.5

<.65<1.2<1. 1<.66.94

T<3.1

<.21<.65

<1.1<1.3

<.35

<.21<.65

T<3.5<5.4

T<1.1T<!67T<.65<1.3

30

Table 8. Concentrations of chlorophenoxy-acid herbicides, dicamba, and picloram in whole-water samples,Yakima River basin, Washington, 1988-91

[Concentrations in nanograms per liter; "<" - less than; 2,4-D - (2,4-dichlorophenoxy)acetic acid; 2,4-DP 2,4,5-T = (2,4,5-trichlorophenoxy)acetic acid; see figure 1 for site locations]

dichlorprop;

Maprefer ence number

33333

33

4

11

1313131313

1313

1414

2121

22

2424242424

2424242424

24

2727272727

2727

28

3636363636

36363636

37

383838383838

Station number

1247830012478300124783001247830012478300

1247830012478300

12479500

12484100

1248448012484480124844801248448012484480

1248448012484480

1248450012484500

1249655012496550

12499000

1250043012500430125004301250043012500430

1250043012500430125004301250043012500430

12500430

1250044512500445125004451250044512500445

1250044512500445

12500450

1250546012505460125054601250546012505460

12505460125054601250546012505460

12505510

125075081250750812507508125075081250750812507508

Station name


Cle Elum R above Cle Elum Lake nr RoslynCle Elum R above Cle Elum Lake nr Roslyn

Yakima River at Cle Elum





Buckskin Slough blw Gleed Ditch nr GleedBuckskin Slough blw Gleed Ditch nr Gleed






Wide Hollow Creek near mouth at Union GapWide Hollow Creek near mouth at Union Gap

Yakima R abv Ahtanum Cr at Union Gap



Marion Drain at Indian Church Rd at Granger

Toppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr Granger

Date

05-05-8806-02-8807-26-8807-26-8808-31-88

11-16-8803-09-89

07-26-88

07-26-88

05-05-8806-02-8806-02-8807-26-8808-31-88

11-18-8803-09-89

07-27-8806-28-89

05-22-9106-12-91

07-26-88

05-06-8805-06-8806-01-8807-26-8807-27-88

07-28-8807-29-8808-30-8811-15-8803-10-89

06-28-89

05-05-8806-03-8807-27-8808-30-8811-15-88

11-15-8803-10-89

07-27-88

05-06-8806-01-8807-28-8807-28-8807-28-88

09-02-8811-15-8803-09-8906-27-89

07-28-88

05-06-8806-03-8807-28-8809-01-8811-16-8803-08-89

Time

11000930100010151030

10301015

1500

1615

15301400140510301630

10001400

10451705

11001345

1330

09300940160011001310

16050800173010151200

1035

18450730102514301330

14301400

1600

12301300073009301015

1000164517301705

1145

134510001445093016151600

Dicamba

<10<10<io<10<10

<10<10

<io70

2,60014014052050

<10240

20<10

<10<10

<10

3030102020

101010

<10<10

10

<1020

<10<10<10

<1010

20

<10130404040

<10<102070

50

10701010

<10<10

2,4-D 2,4-DP Fenoprop Picloram 2,4,5-T

<10 <10 <10 <10 <10<10 <10 <10 <10 <10<10 <10 <10 <10 ^10<10 <10 <10 <10 <10<10 <10 <10 <10 <10

220 110 <10 <10 <10<10 <10 <10 70 <10

<10 <10 <10 <10 <10

80 <10 <10 <10 <10

7,500 <10 <10 <10 <10'l50 <10 <10 10 <10140 <10 <10 <10 <10480 <10 <10 <10 <1060 <10 <10 <10 <10

<10 <10 <10 <10 <10200 140 <10 <10 <10

20 <10 <10 <10 <10<10 <10 <10 <10 <10

<10 <10 <10 <10 <10<10 <10 <10 <10 <10

<10 <10 <10 <10 <10

20 <10 <10 10 <10120 <10 <10 <10 <10150 <10 <10 10 <10200 <10 <10 <10 <10290 <10 <10 <10 <10

1,900 <10 <10 <10 <10260 <10 <10 <10 <1050 <10 <10 <10 <10

<10 <10 <10 <10 <10270 <10 <10 <10 <10

<10 <10 <10 <10 <10

<10 <10 <10 <10 <10250 <10 <10 <10 <1020 <10 <10 10 <10

<10 ^10 <10 <10 <10<10 <10 <10 ^10 <10

<10 <10 <10 <10 <10<10 200 <10 <10 <10

40 <10 <10 <10 <10

<10 <10 <10 10 <10430 <10 <10 <10 <10330 <10 <10 <10 <10390 <10 <10 <10 <10410 <10 <10 <10 <10

<10 <10 <10 <10 <10<10 <10 <10 <10 <10<10 ^10 <10 <10 ^10<10 <10 <10 ^10 ^10

<10 ^10 ^10 ^10 ^10

<10 ^10 ^10 ^10 ^10160 <10 <10 <10 <1030 <10 <10 <10 <1040 <10 <10 <10 <1040 <10 <10 <10 <10

<10 <10 <10 <10 <10

43 12508620 Satus Creek at gage at Satus 07-29-88 1145 30 70

31

Table 8. Concentrations of chlorophenoxy-acid herbicides, dicamba, and picloram in whole-water samples, Yakima River basin, Washington, 1988-91 Continued

Map refer encenumber

46 46 46 46 46

46 46 46 46

47

48

Station number

12508850 12508850 12508850 12508850 12508850

12508850 12508850 12508850 12508850

12509050

12509499

Sulphu Sulphu Sulphu Sulphu Sulphu

Sulphu Sulphu Sulphu Sulphu

Yakima

Station

Cr Wasteway nr Cr Wasteway nr Cr Wasteway nr Cr Wasteway nr Cr Wasteway nr

Cr Wasteway nr Cr Wasteway nr Cr Wasteway nr Cr Wasteway nr

R at Euclid Br

Chandler Canal at BunnChandler Canal at Bunn

49

50

5151515151

5151

12509710

12509829

1251050012510500125105001251050012510500

1251050012510500

Spring

Snipes

YakimaYakimaYakimaYakimaYakima

YakimaYakima

Creek at mouth

Creek at mouth

River at KionaRiver at KionaRiver at KionaRiver at KionaRiver at Kiona

River at KionaRiver at Kiona

name

Sunnyside Sunnyside Sunnyside Sunnyside Sunnyside

Sunnyside Sunnyside Sunnyside Sunnyside

at RM 55 nr Grandview

Rd at ProsserRd at Prosser

at Whitstran

at Whitstran

Date

05-06-88 06-03-88 07-28-88 07-28-88 08-31-88

08-31-88 11-17-88 03-08-89 06-26-89

07-28-88

05-22-9106-13-9107-29-88

07-29-88

05-07-8806-01-8807-29-8808-31-8811-17-88

03-08-8906-26-89

Time

1630 1300 1200 1700 1530

1630 0900 1200 2005

1010

150012401300

1500

08000900103010001400

09001435

Dicamba

20 10 20

10

10

20

10

<102010

10

10101020

<10

<1020


10 <10 <10 10 <10 100 <10 <10 <10 <10 90 <10 <10 <10 <10

50 <10 <10 <10 <10

60 <10 <10 <10 <10 100 <10 <10 <10 <10

60 <10 <10 <10 <10

30 <10 <10 <10 <1070 <10 <10 <10 <1050 <10 <10 <10 <10

60 <10 <10 <10 <10

10 <10 <10 10 <10110 <10 <10 <10 <1070 <10 <10 <10 <1040 <10 <10 <10 <10

<10 <10 <10 <10 <10

<10 <10 <10 <10 <1070 <10 <10 <10 <10

Table 9. Concentrations of chlorophenoxy-acid herbicides, dicamba, and picloram in filtered-water samples,Yakima River basin, Washington, June 25-30, 1989

[Concentrations in nanograms per liter; "<" - less than; 2,4-D = (2,4-dichlorophenoxy)acetic acid; 2,4-DP = dichlorprop; 2,4,5-T - (2,4,5-trichlorophenoxy)acetic acid; see figure 1 for site locations]

Maprefer ence number

24

111314

1519202224

2728333436

3738404143

4546474950

5153

55

Station number

1247820012479500124841001248448012484500

1248455012496510124965111249900012500430

1250044512500450125053501250541012505460

1250551012507508125075851250759412508620

1250863012508850125090501250971012509829

12510500461720-120043201462510-120323901

Station name

Cooper River at Salmon LaSac nr RoslynYakima River at Cle ElumWilson Creek abv. Cherry Creek at ThrallCherry Creek at ThrallYakima River at Umtanum

Umtanum Creek nr mouth at UmtanumPacific Power & Light Company WastewayCity of Yakima-Finish WaterNaches River nr North YakimaMoxee Drain at Thorp Rd nr Union Gap

Wide Hollow Creek near mouth at Union GapYakima R abv Ahtanum Cr at Union GapE Toppenish Drain at Wilson Rd nr ToppenishSub 35 Drain at Parton Road near GrangerGranger Drain at mouth nr Granger

Marion Drain at Indian Church Rd at GrangerToppenish Cr at Indian Church Rd nr GrangerYakima River at RM 72 ab Satus CrSatus Cr abv Wilson -Char ley CanyonSatus Creek at gage at Satus

South Drain nr SatusSulphur Cr Wasteway nr SunnysideYakima R at Euclid Br at RM 55 nr GrandviewSpring Creek at mouth at WhitstranSnipes Creek at mouth at Whitstran


Well 1, Sunnyside, 09N/22E-04P01

Well 2, Harrah, 11N/18E-22R02

Date

06-28-8906-29-8906-29-8906-29-8906-28-89

06-28-8906-25-8906-25-8906-27-8906-28-89

06-30-8906-27-8906-29-8906-29-8906-27-89

06-29-8906-26-8906-30-8906-26-8906-29-89

06-27-8906-26-8906-28-8906-30-8906-30-89

06-26-89

06-27-89

06-29-89

Time Dicamba

1900 <101200 <101600 501830 1001700 10

1400 <101700 <101630 <101015 <101030 <10

1000 <101630 <101700 <101500 <101700 50

1130 <101445 <101030 <100940 <101945 <10

1300 <102000 101020 <101800 101430 10

1430 <10

1900 <10

0915 <10


<10 <10 <10 <10 <10<10 <10 <10 <10 <10<10 <10 <10 <10 <10290 <10 <10 <10 <10<10 <10 <10 <10 <10

<10 <10 <10 <10 <10<10 <10 <10 30 <10<10 <10 <10 <10 <10<10 <10 <10 <10 <10120 <10 <10 <10 <10

<10 <10 <10 <10 <1070 <10 <10 <10 <10

<10 <10 <10 <10 <1030 <10 <10 <10 <10

140 <10 <10 <10 <10

140 <10 <10 <10 <10<10 <10 <10 <10 <10<10 <10 <10 <10 <10<10 <10 <10 <10 <1010 <10 <10 <10 <10

20 <10 <10 <10 <1080 <10 <10 <10 <1070 <10 <10 <10 <1060 <10 <10 <10 <10

<10 <10 <10 <10 <10

90 <10 <10 <10 <10

<10 <10 <10 <10 <10

<10 <10 <10 <10 <10

32

Table 10. Concentrations of organochlorine compounds in whole-water samples, Yakima River basin, Washington, 1988-89

[Concentrations in nanograms per liter; "<" - less than; ODD = dichlorodiphenyldichloroethane; DDE = dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyltrichloroethane; PCB = gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes; see figure 1 for site locations]


33333

33

4

11

1313131313

1313

1414

22

2424242424

2424242424

24

2727272727

2727

28

3636363636

363636

37

3838383838

38

43

4646464646

Station number

1247830012478300124783001247830012478300

1247830012478300

12479500

12484100

1248448012484480124844801248448012484480

1248448012484480

1248450012484500

12499000

1250043012500430125004301250043012500430

1250043012500430125004301250043012500430

12500430

1250044512500445125004451250044512500445

1250044512500445

12500450

1250546012505460125054601250546012505460

125054601250546012505460

12505510

1250750812507508125075081250750812507508

12507508

12508620

1250885012508850125088501250885012508850

Station name


Cle Elum R above Cle Elum Lake nr RoslynCle Elum R above Cle Elum Lake nr Roslyn










Wide Hollow Creek nea mouth at Union GapWide Hollow Creek nea mouth at Union GapWide Hollow Creek nea mouth at Union GapWide Hollow Creek nea mouth at Union GapWide Hollow Creek nea mouth at Union Gap

Wide Hollow Creek nea mouth at Union GapHide Hollow Creek nea mouth at Union Gap

Yakima R abv Ah tan urn Cr at Union Gap






Satus Creek at gege at Satus


Date

05-05-8806-02-8807-26-8807-26-8808-31-88

11-16-8803-09-89

07-26-88

07-26-88

05-05-8806-02-8808-02-8807-26-8808-31-88

11-18-8803-09-89

07-27-8806-28-89

07-26-88

05-06-8805-06-8806-01-8807-26-8807-27-88

07-28-8807-29-8808-30-8811-15-8803-10-89

06-28-89

05-05-8806-03-8807-27-8808-30-8811-15-88

11-15-8803-10-89

07-27-88

05-06-8806-01-8807-28-8807-28-8807-28-88

09-02-8811-15-8803-09-8906-27-89

07-28-88

05-06-8806-03-8807-28-8809-01-8811-16-88

03-08-89

07-29-88

05-06-8806-03-8807-28-8807-28-8808-31-88

Time Aldrin

1100 <10930 <11000 <11015 <11030 <1

1030 <11015 <1

1500 <1

1615 <1

1530 <11400 <11405 <11030 <11630 <1

1000 <11400 <1

1045 <11705 <1

1330 <1

0930 <10940 <11600 <11100 <11310 <1

1605 <10800 <11730 <11015 <11200 <1

1035 <1

1845 <10730 <11025 <11430 <11330 <1

1430 <11400 <1

1600 <1

1230 <11300 <10730 <10930 <11015 <1

1000 <11645 <11730 <11705 <1

1145 <1

1345 <11000 <11445 <10930 <11615 <1

1600 <1

1145 <1

1630 <11300 <11200 <11700 <11530 <1

33

Table 10. Concentrations of organochlorine compounds in whole-water samples, Yakima River basin, Washington, 1988-89 Continued

Station number

1247830012478300124783001247830012478300

1247830012478300

12479500

12484100

1248448012484480124844801248448012484480

1248448012484480

1248450012484500

12499000

1250043012500430125004301250043012500430

1250043012500430125004301250043012500430

12500430

1250044512500445125004451250044512500445

1250044512500445

12500450

1250546012505460125054601250546012505460

125054601250546012505460

12505510

1250750812507508125075081250750812507508

12507508

12508620

1250885012508850125088501250885012508850

Date

05-05-8806-02-8807-26-8807-26-8808-31-88

11-16-8803-09-89

07-26-88

07-26-88

05-05-8806-02-8806-02-8807-26-8808-31-88

11-18-8803-09-89

07-27-8806-28-89

07-26-88

05-06-8805-06-8806-01-8807-26-8807-27-88

07-28-8807-29-8808-30-8811-15-8803-10-89

06-28-89

05-05-8806-03-8807-27-8808-30-8811-15-88

11-15-8803-10-89

07-27-88

05-06-8806-01-8807-28-8807-28-8807-28-88

09-02-8811-15-8803-09-8906-27-89

07-28-88

05-06-8806-03-8807-28-8809-01-8811-16-88

03-08-89

07-29-88

05-06-8806-03-8807-28-8807-28-8808-31-88

Gross chlordane

<100<100<100<100<100

<100<100

<100

<100

<100<100<100<100<100

<100<100

<100<100

<100

<100<100<100<100<100

<100<100<100<100<100

<100

<100<100<100<100<100

<100<100

<100

<100<100<100<100<100

<100<100<100<100

<100

<100<100<100<100<100

<100

<100

<100<100<100<100<100

p,p'-DDD

<x<1<1<1<1<!*1<1<1<!<1<1<1<1<!*1<!<1<11

<1<1212211

<1

<1

111

<1<1

<!3

<1

72

117

10

<!2

<1<1

<1

<!<1<1<11

<1

<1

11

<131

P.P'- DDE

<;L<1<1<1<1

<!<1

<1

<1

11142

115

<!«=!

<1

44

103116

2940725

21

35221

143

2

2121615347

21122850

1

11213

<1

1

61119157

P,P'- DDT

<1<1<1<1<1

<!<1

<1

<1

1<1<1<12

124

<!*1

<1

44

112814

26346

<1<1

21

<!41

<1<1

<!45

2

1317504339

155

<160

<1

<!<1<1<11

<1

<1

51516176

Di- eldrin

<;L<1<1<1<1

<!<1

<1

1

333

125

141

1«=!

<1

11466

782

<1 =1

<1

223

<12

2 =1

1

69

243017

85

<1<1

1

1731

<1

<1

2

25

15146

Endo- Hepta- sulfan I Endrin chlor

<1 <1 <1<1 <1 <1<1 <1 <1<1 <1 <1<1 <1 <1

<1 <1 <1<1 <1 <1

<1 <1 <1

<1 <1 <1

<1 <1 <1<1 <1 <1<1 <1 <1<1 <1 <12 <1 <1

<1 <1 <1<1 <1 <1

<1 <1 <1<1 <1 <1

<1 <1 <1

16 <1 <130 <1 <118 <1 <131 <1 <124 <1 <1

190 1 <193 <1 <114 <1 <1<1 <1 <1<1 <1 <1

<1 <1 <1

10 <1 <170 <1 <166 <1 <1<1 <1 <111 <1 <1

13 <1 <187 <1 <1

4 <1 <1

<1 <1 <121 <1 <1

100 <1 <176 <1 <183 <1 <1

<1 <1 <1<1 <1 <1<1 <1 <1<1 <1 <1

3 <1 <1

<1 <1 <1<1 <1 <14 <1 <11 <1 <1

<1 <1 <1

<1 <1 <1

8 <1 <1

<1 <1 <117 <1 <117 <1 <126 <1 <111 <1 <1

34

Table 10. Concentrations of organochlorine compounds in whole-water samples, Yakima River basin, Washington, 1988-89 Continued

Station number

12478300 12478300 12478300 12478300 12478300

12478300 12478300

12479500

12484100

12484480 12484480 12484480 12484480 12484480

12484480 12484480

12484500 12484500

12499000

12500430 12500430 12500430 12500430 12500430

12500430 12500430 12500430 12500430 12500430

12500430

12500445 12500445 12500445 12500445 12500445

12500445 12500445

12500450

12505460 12505460 12505460 12505460 12505460

12505460 12505460 12505460

12505510

12507508 12507508 12507508 12507508 12507508

12507508

12508620

12508850 12508850 12508850 12508850 12508850

P.P'- Hepta- Meth- chlor oxy-

Date epoxide Lindane chlor

05-05-88 <1 <1 <10 06-02-88 <1 <1 <10 07-26-88 <1 <1 <10 07-26-88 <1 <1 <10 08-31-88 <1 <1 <10

11-16-88 <1 <1 <10 03-09-89 <1 <1 <10

07-26-88 <1 <1 <10

07-26-88 <1 <1 <10

05-05-88 <1 <1 <10 06-02-88 <1 <1 <10 06-02-88 <1 <1 <10 07-26-88 <1 <1 <10 08-31-88 <1 <1 <10

11-18-88 <1 <1 <10 03-09-89 <1 <1 <10

07-27-88 <1 <1 <10 06-28-89 <1 <1 <10

07-26-88 <1 <1 <10

05-06-88 <1 <1 <10 05-06-88 <1 <1 <10 06-01-88 <1 <1 <10 07-26-88 <1 <1 <10 07-27-88 <1 <1 <10

07-28-88 <1 <1 <10 07-29-88 <1 <1 <10 08-30-88 <1 <1 <10 11-15-88 <1 <1 <10 03-10-89 <1 <1 <10

06-28-89 <1 <1 <10

05-05-88 <1 <1 <10 06-03-88 <1 <1 <10 07-27-88 <1 <1 <10 08-30-88 <1 <1 <10 11-15-88 <1 <1 <10

11-15-88 <1 <1 <10 03-10-89 <1 <1 <10

07-27-88 <1 <1 <10

05-06-88 <1 <1 <10 06-01-88 <1 1 <10 07-28-88 <1 <1 <10 07-28-88 <1 <1 <10 07-28-88 <1 <1 <10

09-02-88 <1 <1 <10 11-15-88 <1 <1 <10 03-09-89 <1 <1 <10 06-27-89 <1 <1 <10

07-28-88 <1 <1 <10

05-06-88 <1 <1 <10 06-03-88 <1 <1 <10 07-28-88 <1 <1 <10 09-01-88 <1 <1 <10 11-16-88 <1 <1 <10

03-08-89 <1 <1 <10

07-29-88 <1 1 <10

05-06-88 <1 <1 <10 06-03-88 <1 1 <10 07-28-88 <1 <1 <10 07-28-88 <1 <1 <10 08-31-88 <1 <1 <10

Mirex PCB

<10 <100 <10 <100 <10 <100 <10 <100 <10 <100

<10 <100 <10 <100

<10 <100

<10 <100

<10 <100 <10 <100 <10 <100 <10 <100 <10 <100

<10 <100 <10 <100

<10 <100 <10 <100

<10 <100

<10 <100 <10 <100 <10 <100 <10 <100 <10 <100

<10 <100 <10 <100 <10 <100 <10 <100 <10 <100

<10 <100

<10 <100 <10 <100 <10 <100 <10 <100 <10 <100

<10 <100 <10 <100

<10 <100

<10 <100 <10 <100 <10 <100 <10 <100 <10 <100

<10 <100 <10 <100 <10 <100 <10 <100

<10 <100

<10 <100 <10 <100 <10 <100 <10 <100 <10 <100

<10 <100

<10 <100

<10 <100 <10 <100 <10 <100 <10 <100 <10 <100

PCS

<100 <100 <100 <100 <100

<100 <100

<100

<100

<100 <100 <100 <100 <100

<100 <100

<100 <100

<100

<100 <100 <100 <100 <100

<100 <100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100 <100

<100

<100 <100 <100 <100 <100

<100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100

<100

<100 <100 <100 <100 <100

Per- thane

<100 <100 <100 <100 <100

<100 <100

<100

<100

<100 <100 <100 <100 <100

<100 <100

<100 <100

<100

<100 <100 <100 <100 <100

<100 <100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100 <100

<100

<100 <100 <100 <100 <100

<100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100

<100

<100 <100 <100 <100 <100

Tox- aphene

<1,000 <1,000 <1,000 <1,000 <1,000

<1,000 <1,000

<1,000

<1,000

<1,000 <1,000 <1,000 <1,000 <1,000

<1,000 <1,000

<1,000 <1,000

<1,000

<1,000 <1,000 <1,000 <1,000 <1,000

<1,000 <1,000 <1,000 <1,000 <1,000

<1,000

<1,000 <1,000 <1,000 <1,000 <1,000

<1,000 <1,000

<1,000

<1,000 <1,000 <1,000 <1,000 <1,000

<1,000 <1,000 <1,000 <1,000

<1,000

<1,000 <1,000 <1,000 <1,000 <1,000

<1,000

<1,000

<1,000 <1,000 <1,000 <1,000 <1,000

35

Table 10. Concentrations of organochlorine compounds in whole-water samples, Yakima River basin, Washington, 1988-89


A6 A6 A6 A6

A7

A9

50

51 51 51 51 51

51 51 51 51 51

58

59 59

61

Station number

12508850 12508850 12508850 12508850

12509050

12509710

12509829

12510500 12510500 12510500 12510500 12510500

12510500 12510500 12510500 12510500 12510500

A63233120282101

A6323A120261601 A6323A120261601

A63257120260801

Station number

12508850 12508850 12508850 12508850

12509050

12509710

12509829

12510500 12510500 12510500 12510500 12510500

12510500 12510500 12510500 12510500 12510500

A63233120262101

A6323A120261601 A6323A120261601

A63257120260801

Station number

12508850 12508850 12508850 12508850

12509050

12509710

12509829

12510500 12510500 12510500 12510500 12510500

12510500 12510500 12510500 12510500 12510500

A63233120262101

A6323A120261601 A6323A120261601

Station name

Sulphur Cr Wasteway nr Sunnyside Sulphur Cr Wasteway nr Sunnyside Sulphur Cr Wasteway nr Sunnyside Sulphur Cr Wasteway nr Sunnyside

Yakime R at Euclid Br at

Spring Creek at mouth at

Snipes Creek at mouth at



Well 12N/19E-09H02

Well 12N/19E-09H01 Well 12N/19E-09H01

Well 12N/19E-10D02

Gross chlor- P.P'"

Date dane DDD

08-31-88 <100 1 11-17-88 <100 1 03-08-89 <100 <1 06-26-89 <100 <1

07-28-88 <100 1

07-29-88 <100 1

07-29-88 <100 1

05-07-88 <100 1 06-01-88 <100 <1 07-29-88 <100 <1 08-31-88 <100 <1 11-17-88 <100 <1

03-08-89 <100 <1 06-26-89 <100 <1 12-06-89 <100 <1 12-06-89 <100 <1 12-07-89 <100 <1

01-20-89 <100 <1

01-20-89 <100 <1 01-20-89 <100 <1

01-20-89 <100 <1

Hepta- chlor

Date epoxide Lindane

08-31-88 <1 <1 11-17-88 <1 1 03-08-89 <1 <1 06-26-89 <1 <1

07-28-88 <1 <1

07-29-88 <1 <1

07-29-88 <1 <1

05-07-88 <1 <1 06-01-88 <1 1 07-29-88 <1 <1 08-31-88 <1 <1 11-17-88 <1 <1

03-08-89 <1 <1 06-26-89 <1 <1 12-06-89 <1 <1 12-06-89 <1 <1 12-07-89 <1 <1

01-20-89 <1 <1

01-20-89 <1 <1 01-20-89 <1 <1

RM 55 nr Grendview

Whitstran

Whitstran

P.P'- P.P'" Di- DDE DOT eldrin

756 7 2 A 6 <1 3

21 30 <1

A <1 5

12 5 7

8 A 5

311 3 <1 2 1 <1 3 2 <1 2 1 <1 <1

5 9 <1

1 <1 <1 1 <1 <1 1 <1 <1

<1 <1 <1

<1 <1 <l

<1 <1 <1

P.P'- Meth- oxychlor Mirex PCB

<10 <10 <100 <10 <10 <100 <10 <10 <100 <10 <10 <100

<10 <10 <100

<10 <10 <100

<10 <10 <100

<10 <10 <100 <10 <10 <100 <10 <10 <100 <10 <10 <100 <10 <10 <100

<10 <10 <100 <10 <10 <100 <10 <10 <100 <10 <10 <100 <10 <10 <100

<10 <10 <100

<10 <10 <100 <10 <10 <100

Date

08-31-88 11-17-88 03-08-89 06-26-89

07-28-88

07-29-88

07-29-88

05-07-88 06-01-88 07-29-88 08-31-88 11-17-88

03-08-89 06-26-89 12-06-89 12-06-89 12-07-89

01-20-89

01-20-89 01-20-89

01-20-89

Endo- sulfan I

5

1

13

<1

11 8

l\

<1

a<i

PCN

<100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100 <100 <100 <100

<100

<100 <100

Time

1630 0900 1200 2005

1010

1300

1500

0800 0900 1030 1000 1AOO

0900 1A35 1615 2357 1852

0750

0730 0737

0715

Endrin

a<i2

<1

l\

:\<i:\<i

Per- thane

<100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100 <100 <100 <100

<100

<100 <100

Aldrin

<i

<1

<1

<1

I

1<1

<l

<l

Hepta- chlor

a<i<i<i

|

|<ia<i

Tox- aphene

<1,000 <1,000 <1,000 <1,000

<1,000

<1,000

<1,000

<1,000 <1,000 <1,000 <1,000 <1,000

<1,000 <1,000 <1,000 <1,000 <1,000

<1,000

<1,000 <1,000

A63257120260801 01-20-89 <100 <100 <1,000

36

Table

11.

Conc

entr

atio

ns of or

gano

chlo

rine

compounds in

filtered-water samples, Yakima Ri

ver

basin, Washington,

June

25-30,

1989

[Con

cent

rati

ons

in n

anog

rams

pe

r liter: "T"

= pr

esen

t, but

below

quan

tifi

able

con

cent

rati

on;

"nd"

=

not

dete

cted

and

min

imum

rep

orti

ng

level

not

quantified;

"--"

=

not

anal

yzed

; "<"

= less than;

"*"

= sum

was

estimated

using

a regression a

nalysis

of 12 d

isso

lved

concentrations of

p,

p'-D

DE and

p.p'-DDT pl

us p

,p'-

DDE

-'--

-

------------^

-- ... ..

?._

... ~

.._.

...-

._

J_^_

....-

in Ju

ne,

1989

; OD

D = dichlorodipnenyldicnloroetnane;

" HCB

= he

xach

loro

benz

ene;

HC

H =

nexachlorocyclohexane;

locations]

Map

referenc

number 2 4 11 13 14 15 19 20 22 24 27 28 30 33 34 36 55 37 38 40 41 53 43 45 46 47 49 50 51

:e

Stat

ion

number

12478200

12479500

12484100

12484480

12484500

12484550

12496510

1249

6511

12499000

12500430

12500445

12500450

12502500

12505350

12505410

12505460

4625

10-

120323901

12505510

1250

7508

1250

7585

12507594

4617

20-

120043201

1250

8620

12508630

12508850

12509050

12509710

12509829

12510500

Station

name

/

Coop

er R

iver

at

Salmon L

aSac

Yakima R

iver

at Cl

e El ur

nWi

1 so

n Cr

abv

. Ch

erry

Creek

Cherry C

reek

at Th

rall

Yaki

ma Ri

ver

at Umtanum

Umtanum

Creek

nr mouth

Paci

fic

Powe

r &

Ligh

t Company

Wast

eway

City

of

Yaki

ma-F

inis

h Wa

ter

Nach

es Ri

ver

nr No

rth

Yakima

Moxe

e Drain

at Thorp

Rd

Wide

Hollow C

reek n

ear

mout

hYa

kima

R abv Ahtanum

CrAhtanum

Cree

k at

Un

ion

Gap

E To

ppen

ish

Drai

n at

Wilson R

dSu

b 35

Drain a

t Par to

n Road

Granger

Drai

n at

mo

uth

Well 2, Harrah.

11N/

18E-

22R0

2Marion D

rain

, In

dian

Chu

rch

RdTo

ppen

ish

Cr,

Indian C

hurch

RdYakima R

iver

at RM

72

Satu

s Cr abv

Wils

on-C

harl

eyCanyon n

r Toppenish

Well 1.

Sunnyside, 09

N/22

E-04

P01

Satus

Cr at gage at

Satus

South

Drai

n nr Satus

Sulp

hur

Creek

Wasteway

Yakima R

at

Euclid B

r at

RM 5

5Sp

ring

Creek a

t mo

uth

Snip

es C

reek a

t mo

uth

Yaki

ma Ri

ver

at Ki

ona

Udrin

<0.9

4T<

.22

<2.0 <.84

T<.69

<.74

<.21

< 61

<.34

<3.5

<1 8

<!65

<1 .

1<1

.9

<1.8

<3.2 <.61

T<1.8

T<1

. 1<.

84

<-35

T<.60

T<1.9

<3.5

<15 <1.1

<1 .9

<1 .8

T<.69

cis-

Chlordane

<0.2

5<.

20<.

53

T<!6

3

<.23

<.20

<.16*

<1.8 <.50

<.60

<.58

T<-51

<.50

<1.6 < 16

<.50

<.55

<1.1 <.18

<. 16

<.50

<1 .8

<4.1 <.59

<.51

<.50

<.63

trans-

Chloro

Chlordane

thal

onil

<0.23

<.22

<.48

T<1.

2 T

T<.7

0

<.15

<.22

<.16

<1.6 <.45

<.67

<.53 .31

<.45

<1.5 < 15

<.45

<-50

<1.2

nd

<.16

<.15

<.46

<1 .6

<3.8 <.53

<-46

<.45

<.70

ftl"

<0.16

.14

<.33

T<.7

7T<.41

.13

.39

'.20

5.6 .47

.74

.34

1.2 .61

.96

< 10 .47

.59

1.4 .17

.17

.28

3.7

15 2.4

4.8

2.9

1.2

P.F

PJ

PJ * * * * * * * * * * * * * * * * *

JI-D

DT+

ji-D

DE*

J'-DDD 0.6 .5

<1 0

T<2.

1T<

1.2 .5 1.3

< 4 .7

15 1.4

2.8

1.1

3.2

1.7

2.6

< 4

1.4

1.7

3.7 .6 .5 .9

11 38 6.2

9.0

6.3

4.2

Dieldrin

<0.28

T<.21

T<-58

3.7 .93

<.10

<.20

<!33

T<3.4

1.0 .77

<1

1<!56

1.1

T<3.1

< 18

1.3

T<1.0 .98

<.34

T<.1

81.6

T<3.4

35 5.7

7.2

5.9

3.6

Endosul-

fan

I

<0.2

5T<

.15

<.53 .82

8.0

1.3 .73

11 2.6 .92

2.3

3.5

<.50

T<1.

4

<.16

1.8

1.2

<.16

<. 16

<.50

<1 6

6.8

<.50

< 51

<.50

1.2

Endosul-

fan

II

<0.4

7<.

26<.98

<.81

<.24

2.0

<.30

<.32

5.2

1.0

<.77

<!94

T<.9

2

<3.0

<.30

<.92

<1 .0

1.6

<-33

<.30

<.93

<3.4

<7.6

<1

1<^

95<.

92

Table

11.

Concentrat ions

of or

gano

chlp

rine

co

mpou

nds

in f

iltered-water

samp

les,

Ya

kima

Ri

ver

basi

n, Wa

shin

gton

, Ju

ne 1989--Continued

oo

Stat

ion

number

12478200

1247

9500

12

4841

0012484480

1248

4500

12484550

12496510

12496511

1249

9000

1250

0430

12500445

12500450

12502500

12505350

12505410

12505460

4625

10-

1203

2390

112505510

12507508

12507585

1250

7594

4617

20-

1200

4320

112

5086

2012

5086

3012

5088

50

1250

9050

12509710

12509829

1251

0500

Stat

ion

name

Coop

er R

iver

at

Sa

lmon

LaS

ac

Yakima R

iver

at

Cl

e El ur

n Wilson C

r abv. Ch

erry

Creek

Cherry C

reek

at

Thra

llYakima R

iver

at Umtanum

Umtanum

Cree

k nr

mouth

Paci

fic

Powe

r &

Ligh

t Co

mpan

yWasteway

City o

f Ya

kima

-Fin

ish

Water

Nacn

es R

iver

nr

North

Yakima

Moxee

Drai

n at Thorp

Rd

Wide Hollow C

r near m

outh

Yakima R

ab

v Ahtanum

CrAhtanum

Cree

k at Union

Gap

E Toppenish

Drai

n at Wi

lson

Rd

Sub

35 Dr

ain

at Pa

rton

Roa

d

Gran

ger

Drain

at mouth

Well

2, Ha

rrah

. 11

N/18

E-22

R02

Marion D

rain

, Indian C

hurch

RdToppenish

Cr,

Indian C

hurch

RdYakima R

iver

at RM 72

Satu

s Cr

abv Wilson-Charley

Canyon

Well

1,

Sumy si

de,

09N/

22E-

04P0

1Sa

tus

Cr at

gage a

t Sa

tus

South

Drai

n nr

Satus

Sulp

hur

Cree

k Wa

stew

ay

Yakima R

at

Euclid Br at RM 5

5Sp

ring

Cre

ek a

t mouth

Snip

es C

reek

at

mouth

Yakima R

iver

at

Kiona

Endrin

<4i4

<2.4 1.5

<.50

<.18

<1 .4

T<.66

<6.8

<4.2 2.8

<2.2

<4.3

<4.2

<6.1

<1 4

<4.2

<2

1<2

.4 <.68

<1 .4

<4.2

<6.8

<35 9.

1<4

.3<4

.2 <.56

HCB

T<0.15

T<!5

2<.56

T<.0

7

< . 17

<. 10

<. 11

<1.1

T<.3

0<.

53<.

35T<.30

T<.3

0

T<.99

T<.10

T<.3

0T<.34

T<.5

2

T<.1

1

T<.1

0T<

-30

<1 .

1<2

.4 <.36

T<.3

0<.

30T<.56

alpha-

HCH

T<!6

2 <2

.2T<1.4

<1.9 <.31

<.60

<.70

T<.38

T<3.

9

<2

1T<l!8

<1 .2

<2.2

<2.1

<3.5 <.70

T<2.1

<1 .2

T<1.4

<.39

<.69

<2.1

<3.9

<18 <1 2

<2i2

T<2.

1<1

.9

L i nda

ne

( gam

ma -

HCH)

*<'.

&

<3io

<2.6 <.84

<.81

<.65

<.25

<2.6

<2.0

<2.5 <.82

<2.0

<2.0

T<2.

3

<.65

<2.0 <-78

<3.0 <.26

<.65

<2.0

<2.6

<16 <.

83<2

.0<2

.0<2

.6

Hepta-

chlor-

epoxide

<0 < <1 T<

1 < < < T< <2 <1 <1 < <1 <1 <2 < <1 < T<1 < < <1 <2 <8 < <1 <1 <1

.54

.38

.5 .2 .82

.37

.35

.25

.5 .1 .1 .81

. 1 1 .3 .35

. 1 .77

.5 .25

.35

.1 .6 .9 .82

. 1 . 1 .2

o,p'

- Me

th-

oxy-

chlo

r

<2.5

T<1.5

<5.2

T<.91

<4.8

<1.2

<1 .5

<1 .6

<.98

<10 <4.9

<4.5

<3.2

<5.0

<4.9

<9.0

<1 6

<4.9

<3.0 <.91

<1 .0

<1 .6

<4.9

<10

<41 <3.2

<5.0

<4.9

<4.8

B4?h'-

oxy-

chlo

r

nd

nd

nd<1 2 nd

<1.4 nd nd

<1 .

1<12 nd nd<3

.7 nd nd

<10 nd nd<3

.5<1

.2

<1 .2 nd nd

<12 nd

<3.7 nd nd nd

Mi rex T<!4

5 <2.3

<2.9

T<1.4

<.51

<.44

< 71

<.20

<2.1

<2

1T<l!3

<.66

<2.2

<2.1

<1.9 < 71

<2.2 <.63

<2.9 <.21

<.70

<2.2

<2.

1<1

8 <.67

<2.2

<2.2

<1 .4

Perthane

<!44

<2

.6

<1.4 <.17

<.43

<.81

< 31

<3.2

<2.4

<1 .3

<1 0

<2.5

<2.4

T<2.

8

T<.81

<2.5 <.96

<1.2 <.32

<.80

<2.5

<3.2

<20 <1 0

<2i5

<2.5

<1 .4

Table 12. Concentrations of organochlorine compounds in filtered-water samples, Yakima River basin, Washington, May-September 1991

[Concentretions in nanograms per liter; "<" = less than; DDD = dichlorodiphenyldichloroethane; DDE - dichlorodiphenyldichloroethylene; DOT - dichlorodiphenyltrichloroethane; PCB - gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes; see figure 1 for site locations]


21 21

23 23 23 23 23

35 35 35 3535

4646464646

4848

5151515151

Station number

12496550 12496550

12500420 12500420 12500420 12500420 12500420

12505450 12505450 12505450 1250545012505450

1250885012508850125088501250885012508850

1250949912509499

1251050012510500125105001251050012510500

Station number

1249655012496550

1250042012500420125004201250042012500420

1250545012505450125054501250545012505450

1250885012508850125088501250885012508850

1250949912509499

1251050012510500125105001251050012510500

Station name

Buckskin Slough blw Gleed Ditch nr Gleed Buckskin Slough blw Gleed Ditch nr Gleed

Moxee Drain at Birchfield Road nr Union Gap Moxee Drain at Birchfield Road nr Union Gap Moxee Drain at Birchfield Road nr Union Gap Moxee Drain at Birchfield Road nr Union Gap Moxee Drain at Birchfield Road nr Union Gap

Grenger Drain at Granger Grange Drain at Granger Grange Drain at Granger Grange Drain at GrangerGrange

SulphuSulphuSulphuSulphuSulphu

ChandlChandl

YakimaYakimaYakimaYakimaYakima

Date

05-22-9106-12-91

05-23-9106-17-9106-20-9107-10-9109-04-91

05-23-9106-17-9106-20-9107-10-9109-04-91

05-24-9106-19-9106-20-9107-11-9109-05-91

05-22-9106-13-91

05-21-9107-09-9108-06-9108-06-9109-25-91

Drein at Granger

Cr Wasteway nrCr Wasteway nrCr Wasteway nrCr Wasteway nrCr Wasteway nr

r Canal at Bunnr Canal at Bunn

River at KionaRiver at KioneRiver at KioneRiver at KionaRiver at Kiona

Grosschlor- p,p'dane DDD

<100 <1<100 5

<100 <1<100 1<100 <1<100 <1<100 <1

<100 <1<100 2<100 2<100 1<100 <1

<100 <1<100 1<100 4<100 1<100 <1

<100 <1<100 <1

<100 <1<100 <1<100 <1<100 2<100 <1

SunnysideSunnysideSunnysideSunnysideSunnyside

Rd at FrosserRd at Frosser

P.P'~ P,P'~DDE DOT

5 <16 2

6 <13 22 <15 44 1

9 <112 534 256 58 4

6 <14 20

19 155 34 2

4 <11 <1

4 <11 <14 <12 <12 <1

Di-eldrin

<!4

<!2124

38966

26

1675

11

33

<115

Date

05-22-91 06-12-91

05-23-91 06-17-91 06-20-91 07-10-91 09-04-91

05-23-91 06-17-91 06-20-91 07-10-9109-04-91

05-24-9106-19-9106-20-9107-11-9109-05-91

05-22-9106-13-91

05-21-9107-09-9108-06-9108-06-9109-25-91

Endo-sulfan I

<!3

<!2

<1<1<1

<!2

<1<1 =1

<!<1<1<1<1

<!2

<!<151

<1

Time Aldrin

1100 <1 1345 <1

1000 <1 1100 <1 1645 <1 1240 <1 1115 <1

1230 <1 1420 <1 1400 <1 1500 <11420 <1

1000 <11145 <11200 <11155 <11130 <1

1500 <11240 <1

1200 <11155 <11150 <11151 <11120 <1

Hepta-Endrin chlor

<1 <1<1 <1

<1 <1<1 <1<1 <1<1 <1<1 <1

<1 <1<1 <1<1 <1<1 <i<1 <1

<1 <1<1 <1<1 <1<1 <1<1 <1

<1 <1<1 <1

<1 <1<1 <1<1 <1<1 <1<1 <1

39

Table 12. Concentrations of organochlorine compounds in filtered-water samples, Yakima River basin, Washington, May-September 1991 Continued

Station number

1249655012496550

1250042012500420125004201250042012500420

1250545012505450125054501250545012505450

1250885012508850125088501250885012508850

1250949912509499

1251050012510500125105001251050012510500

P.P'- Hepta- Meth- chlor oxy-

Date epoxide Lindane chlor

05-22-91 <1 <1 <1006-12-91 <1 1 <10

05-23-91 <1 <1 <1006-17-91 <1 <1 <1006-20-91 <1 <1 <1007-10-91 <1 <1 <1009-04-91 1 <1 <10

05-23-91 <1 <1 <1006-17-91 <1 <1 <1006-20-91 <1 4 <1007-10-91 <1 <1 <1009-04-91 <1 <1 <10

05-24-91 <1 <1 <1006-19-91 <1 <1 <1006-20-91 <1 7 <1007-11-91 <1 <1 <1009-05-91 <1 <1 <10

05-22-91 <1 <1 <1006-13-91 <1 <1 <10

05-21-91 <1 <1 <1007-09-91 <1 <1 <1008-06-91 <1 .3 <1008-06-91 <1 <1 <1009-25-91 <1 <1 <10

Mi rex PCB

<10 <100<10 100

<10 <100<10 <100<10 <100<10 <100<10 <100

<10 <100<10 <100<10 <100<10 <100<10 <100

<10 <100<10 <100<10 <100<10 <100<10 <100

<10 <100<10 <100

<10 <100<10 100<10 200<10 100<10 100

PCN

<100<100

<100<100<100<100<100

<100<100<100<100<100

<100<100<100<100<100

<100<100

<100<100<100<100<100

Per- thane

<100<100

<100<100<100<100<100

<100<100<100<100<100

<100<100<100<100<100

<100<100

<100<100<100<100<100

Tox- aphene

<1,000<1,000

<1,000<1,000<1,000<1,000<1,000

<1,000<1,000<1,000<1,000<1,000

<1,000<1,000<1,000<1,000<1,000

<1,000<1,000

<1,000<1,000<1,000<1,000<1,000

40

Table

13.

Concentrations of

or

gano

chlo

rine

compounds associated w

ith

suspended

sedi

ment

, Yakima Ri

ver

basin, Wa

shin

gton

, Ju

ne 2

5-30,

1989

[Concentrations

in n

anog

rams

pe

r liter; al

l de

term

inat

ions

mad

e using

GC/E

CD (g

as ch

roma

togr

aph/

elec

tron

-cap

ture

det

ecto

r) ex

cept

values in

parentheses

are

determinations m

ade

usin

g GC

/MS

(gas

ch

roma

togr

aph/

mass

spectrometer d

etec

tor)

; nd

= co

ncen

trat

ion

is be

low

quantifiable

conc

entr

atio

n us

ing

GC/M

S; "<"

= less th

an;

ODD

= di

chlo

rodi

phen

yldi

chlo

roet

hane

; DD

E =

dich

loro

diph

enyl

dich

loro

ethy

lene

; DD

T =

dich

loro

diph

enyl

tric

hlor

oeth

ane:

HCB

= hexachlorobenzene; HCH

= hexachlorocyclohexane; "T"

= pr

esen

t, but

belo

w quantifiable

concentration; "-

" =

not

anal

yzed

; "*"

= a portion

of sample w

as lo

st d

uring

anal

ysis

, and

reported c

oncentrations

may

be b

iased

low;

n**n

= co

mpou

nd d

etec

ted

and

may

be less th

an reported v

alue

; I

= interference at pe

ak;

g =

gr9s

s ch

lord

ane

(cis-chlordane +

trans-

chlo

rdan

e);

Endo

sulf

an s

ulfa

te,

endrin a

ldeh

yde,

endrin ke

tone

, heptachlor,

delt

a-HC

H, cis- an

d tr

ans-

perm

ethr

in.

pert

hane

, gr

oss

polychlorinated

napt

hale

nes

(PCN

) were n

ot de

tect

ed.

PCB

= polychlorinated

biph

enyl

: PC

B (8

.8 n

g/L) and

toxaphene

(160

ng/L) were d

etected

at Granger

Drai

n; PCB

also w

as d

etected

at 1.2

ng/L

at

Sulphur

Creek.

ChlorthalomI (0

.08

ng/L)

was

dete

cted

at

Sout

h Dr

ain.

trans-Nonachlor

was

detected a

t Gr

ange

r Drain

(0.21

ng/L

), Moxee

Drai

n (trace c

once

ntra

tion

<0.

03 n

g/L)

, and

Sulp

hur

Cree

k (t

race

con

cent

rati

on <

0.3

ng/L

);

see

figure

1 fo

r site lo

cati

ons]

Map

reference

Station

number

number

2 4 11 13 14 15 19 20 22 22 24 27 28 28 30 33 34 36 55 37 38 40 40 41 53 43 45 46 47 47 49 50 51 51

12478200

1247

9500

1248

4100

1248

4480

12484500

12484550

1249

6510

1249

6511

1249

9000

1249

9000

12500430

1250

0445

1250

0450

1250

0450

1250

2500

12505350

12505410

1250

5460

4625

10-

1203

2390

1

1250

5510

1250

7508

1250

7585

1250

7585

1250

7594

4617

20-

1200

4320

112

5086

2012

5086

3012

5088

5012

5090

50

1250

9050

1250

9710

1250

9829

1251

0500

12510500

Station

name

Aldr

in&r

Cooper R

iver

at

Salmon L

aSac

<0

.09

Yaki

ma R

iver

at

Cle

Elum

Wils

on C

r ab

v. Cherry C

reek

Cher

ry C

reek

at

Thra

ll

Yaki

ma R

iver

at Um

tanu

mUmtanum

Cree

k nr

mou

thPacific

Powe

r &

Light

Company

Wasteway

City

of

Yaki

ma- Fi

nish

Water

Naches R

iver

nr

Nort

h Ya

kima

Naches R

iver

nr

Nort

h Yakima

Moxe

e Drain

at Th

orp

RdWi

de Hollow C

reek

near

mouth

Yaki

ma R

abv Ah

tanu

m Cr

Yaki

ma R

abv Ah

tanu

m Cr

Ahtanum

Cree

k at Un

ion

Gap

E To

ppen

ish

Drain

at W

ilso

n Rd

Sub

35 D

rain a

t Parton R

oad

Granger

Drain

at mo

uth

Well

2, Harrah,

11N/

18E-

22R0

2

Mari

on D

rain

, In

dian

Church

RdTo

ppen

ish

Cr,

Indi

an C

hurch

RdYa

kima

Riv

er a

t RM 7

2Ya

kmia

Riv

er a

t RM

72

Satus

Cr a

bv W

ilson- Cha

r ley

Cany

on n

r To

ppen

ish

Well

1

Sunn

ysid

e, 09

N/22

E-04

P01

Satus

Cr a

t gage a

t Sa

tus

South

Drai

n nr

Sat

usSulphur

Cree

k Wasteway

Yaki

ma R

at Euclid B

r at RM 55

Yakima R

at

Euclid B

r at RM

55

Spring C

reek

at

mouth

Snipes C

reek

at

mout

hYa

kima

Riv

er a

t Ki

ona

Yaki

ma R

iver

at

Kion

a

<.09

<.3

<.3

<.6

<.4

<.01

< 2

<.02 nd <.01

< 3

<.02 nd < .3

<.3

< 3 '.09

<.02

< .3 <.3

dnd <.05

<.01

<.3

<.01

< 5

<.07

*

nd <.3

<.3

< 01 nd

<0.0

2

<.04

<.02

< 01

<.02

<.02 nd .23

<.07 nd 1.9

<.02

T<.

1 nd <.02 .03

.34

<.07

*

<.04 nd

for 0.00

1<-

02 .11

.46

.05

<.02

< 01

<.02

<.02

(T) 1.6 .21

T<.2

(T) .0

67.7

4.54

6.4

<.02 .16

.23

.50

nd <-05

<.04 .16

.53

1.7

<.07

*

(1.3

)1.

9 .86

.17

(T)

61"

0.01

<.05 .18

3.3 .12

.25

.36

<.02

(.28

)7.1 .69

.27

(.95)

.24

3.6

1.6

28 <.02

1.1

1.1

2.5

(4.5)

.008

<.02 .60

4.0

6.4

T<.0

7*

(4.6

)19 6.

79.

6 nd

DDT

DDT

Dieldrin

_ _<0

.02

<.2

<. 1

T<.0

1<.

02<.

02 nd 2.4

<.07 nd 5.7

<.02 .22

nd <.02 .31

2.8

<.07

*

.92

nd

<0.09

<.02

< 3

4.2 .26

<.02 .24

<.02 .05

(T) 9.6 .40

.11

(T) < 3

4i5

6.5

38 <.02

1.9

1.3

3.4 nd <.05

<.02 .86

4.0

7.8

T<.2*

20 7.8 .20

(T)

<0.0

9<.

02 .009

.96

.04

<.02

< 01

<.02

<-02

(.44

).8

6.019

T<-2 nd .0

03.0

52.061

3.6

T<.0

2

.06

.055

.12

nd <.05

<.02 .13

.02

2.1

T<.0

7*

.70

.23

.08

nd

Endosul

fan

I

<0.09

<.02

<.3

<-3

<.04

<.02 .04

<.02

<.02 nd .69

< 3

<.07 nd <.3

<.3

< 3

<!02

<.02

<.3

<.3

< 1 nd <.05

<.02

< 3

<.05

<.06

<.07

*

<.3

< 3

<.04 nd

Endosul

fan

II

_ m

<0.0

5 -

<.07

<.05

<.02

<.05

<.04

(T) <.06

< 2 nd

K2.0

<.05 ..

<.1 nd --

<.04

<. 1

< 1

<.2*

<.08 nd

cis-

Chlo

rdan

e

g 0.

15<.

02g<

3.0

g 4.

0

<.04

<.02

< 01

<.02

<.02 nd

T<.0

3g

.76

<.07 nd

g .4

1g

2.3

g .4

5.0

5

<.02

g .3

8g 3.0

<.1 nd

9<-5 <.02

g<3.

0<.

05T<

.3 <.07

*

g 1.4

g -37

<.04 nd

trans-

Chlo

rdan

e

m m

<0.0

2

<.04

<.02

< 01

<.02

<.02 nd

T<.03

<.07 nd .09

<.02

<.1 nd --

<.02

<.05

T <.

3<.

07*

<.04 nd

Table

13

. C

on

cen

tra

tion

s of

org

an

och

lorin

e

com

poun

ds

ass

oci

ate

d w

ith

su

spen

ded

sedim

ent,

Yak

ima

Riv

er

ba

sin

, W

ashi

ngto

n,

June

2

5-3

0,

1989--

Contin

ued

Station

number

1247

8200

12479500

12484100

12484480

1248

4500

12484500

12484550

1249

6510

12496511

12499000

1249

9000

1250

0430

1250

0445

1250

0450

1250

0450

12502500

1250

5350

12505410

12505460

4625

ID-

1203

2390

112

5055

1012

5075

08

1250

7585

1250

7585

12507594

461720-

1200

4320

1

1250

8620

1250

8630

1250

8850

12509050

1250

9710

12509829

1251

0500

12510500

Stat

ion

name

Cooper River

at Salmon L

aSac

Yaki

ma River

at Cle

Elum

Wils

on C

r ab

v. Ch

erry

Cre

ekCherry C

reek at Th

rall

Yakima River

at Um

tanu

mYa

kima

River

at Um

tanu

mUm

tanum

Creek

nr m

outh

Pacifi

c Po

wer

& Li

ght

Comp

any

Wasteway

City

of

Yakima-Finish

Wate

r

Naches River

nr No

rth

Yakima

Naches River

nr No

rth

Yakima

Moxe

e Drain

at Thorp

RdWi

de Hollow C

reek

nea

r mo

uth

Yaki

ma R

abv Ahtanum

CrYakima R

abv Ahtanum

CrAhtanum

Cree

k at

Union

Gap

E Toppenish

Drain

at W

ilson

RdSub

35 Drain

at Parton R

oad

Granger

Drai

n at

mo

uth

Well

2, Harrah.

11N/

18E-

22R0

2Ma

rion

Dra

in,

Indi

an C

hurc

h Rd

Toppenish

Cr,

Indi

an C

hurc

h Rd

Yaki

ma Ri

ver

at RM

72

Yaki

ma River

at RM

72

Satu

s Cr

ab

v Wi

I son- Cha

r ley

Cany

on n

r Toppenish

Well

1,Sunnyside, 09

N/22

E-04

P01

Satu

s Cr

at gage a

t Satus

Sout

h Drain

nr Sa

tus

Sulphur

Creek

Wasteway

Yaki

ma R

at Euclid B

r at RM

55

Spring Creek

at mo

uth

Snipes Creek

at mo

uth

Yaki

ma R

iver

at

Kion

aYa

kima

River

at Ki

ona

Dacthal

<0.0

2

<.04 nd <.02

< ,Q1

<.02

<.02 nd <.03

<.07 nd .23

<.02 .31

nd -- <.02 .. .15

T<.06

<.07

<.04 nd

Endr

in

<0.09

<.02

<.3

<.3

<.04 nd <.02

<.01

<.02

<.02 nd <.03

<.3

<.07 nd <.3

<.3

<.3 .31

<.02

<.3

<.3

< 1 nd <.05

<.02

< 3

<.05

<.06

<.07

<.3

<.3

<.04 nd

HCB

<0.05

<.07 nd <.07

T<.0

1<.

02

< 01 nd <.01

<.02 nd -- .33

<.01

T<.1

(T) <.01 -- <.01 .08

<.03 .. .16

(T)

alph

a-

HCH

<0.0

2

<.04 nd <.02

< .0

1<.

02

<.02 nd

T<.03

<.07 nd .02

<.02

< 1 nd - <.02

<.05

<.06

<.07

<.04 nd

L i ndane

( gam

ma -

HCH) <0.0

9<.

02<.3

<.3

<-04

(4.0)

<.02

<.oi

<.02

<.02 nd <.03

<.3

<.07 nd <.3

<.3

<.3 .06

<.02

<.3

<.3

T<

1 nd <.05

<.02

< 3

<.05

<.06

<.07

<.3

<.3

<.04 nd

Hepta-

chlo

r epoxide

<0.09

<.02

<.3

<.3

<.04 nd <.02

<,01

<.02

<.02 nd

T<.03

<.3

<.07 nd <.3

<.3

<.3 .15

<.02

<.3

<.3

< 1 nd <.05

<.02

< 3

<.05

<.06

<.07

<.3

<.3

<.04 nd

o,p'

- Meth-

oxy-

chlo

r

<0.0

2

<.04 nd <.02

< 01

<.02

<.04

(T)

<.03

<.07

(T) 3.4**

<.02

< 1

(T) - <.02

<.05

<-06

<.07

<.04 nd

E'P.1"

Meth

-ox

y-

chlo

r

<0.0

9<.

02<.3

<.3

<.04 nd <.02

< 01

<.02

<.04 nd <.03

<.3

<.07 nd <.3

<.3

<.3 .32*

*

<.02

<.3

<.3

< 1 nd <.05

<.02

< 3

<!os

<.06

<.07

<.3

<.3

<.04 nd

Mi rex

0.00

8<.09

<.3 .004

< 2 nd <.oi

<.2

<.02 nd <.03

<.3

<.07 nd <.3

<.3

<.3

<.04

<.09

<.3

<.3

< 5 nd <.05

<.02

< 3

<!os

<.06

<.2

<.3

< 3

<.04 nd

Hepta-

chio

r

<0.0

9<.

05<.

3<.3

<-07 nd < 01

<.02

<-02 nd <.01

<.3

<.02 nd <.3

<.3

<.3

<.02

<.01

<.3

<.3

< 1 nd <.05

<.01

<.3

<.01

<.2

<.07

<.3

<.3

< 01 nd

delt

a-

HCH .

.

<0.0

2-- <.04 nd <.02

< 01

<!02

<.02 nd <.03

<.07 nd -- <.04

<.02

< 1 nd - <.02

<.05

<.06

<.07

<.04 nd

Table 14. Concentrations of organochlorine compounds associated with suspended sediment, Yakima River basin, Washington, May-September 1991

[Concentrations in nanograms per liter; "<" » less than; ODD - dichlorodiphenyldichloroethane; DDE = dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyltrichloroethane; PCB = gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes; "T" = compound present, but less than reported value; "nq" = not quantified because of interference; see figure 1 for site locations]


21 21

23 23 23 23 23

35 35 35 35 35

46 46 46 46 46

484848

5151515151

Station number

12496550 12496550

12500420 12500420 12500420 12500420 12500420

12505450 12505450 12505450 12505450 12505450

12508850 12508850 12508850 12508850 12508850

125094991250949912509499

1251050012510500125105001251050012510500

Station name



Granger Drain at Granger Granger Drain at Granger Granger Drain at Granger Granger Drain at Granger Granger Drain at Granger

Sulphur Cr Wasteway nr Sunnyside Sulphur Cr Wasteway nr Sunnyside Sulphur Cr Wasteway nr Sunnyside Sulphur Cr Wasteway nr Sunnyside Sulphur Cr Wasteway nr Sunnyside

Chandler Canal at Bunn Rd at FrosserChandler Canal at Bunn Rd at FrosserChandler Canal at Bunn Rd at Frosser


Date

05-22-91 06-12-91

05-23-91 06-17-91 06-20-91 07-10-91 09-04-91

05-23-91 06-17-91 06-20-91 07-10-91 09-04-91

05-24-91 06-19-91 06-20-91 07-11-91 09-05-91

05-22-9106-13-9106-13-91

05-21-9105-21-9107-09-9108-06-9108-06-91

Time Aldrin

1100 <1 1345 <1

1000 <1 1100 <1 1645 <1 1240 <1 1115 <1

1230 <1 1420 <1 1400 <1 1500 <1 1420 <1

1000 <1 1145 <1 1200 <1 1155 <1 1130 <1

1500 <11240 <11241 <1

1200 <11201 <11155 <11150 <11151 <1

51 12510500 Yakima River at Kiona 09-25-91 1120 <1

Station number

1249655012496550

1250042012500420125004201250042012500420

1250545012505450125054501250545012505450

1250885012508850125088501250885012508850

125094991250949912509499

1251050012510500125105001251050012510500

12510500

Date

05-22-9106-12-91

05-23-9106-17-9106-20-9107-10-9109-04-91

05-23-9106-17-9106-20-9107-10-9109-04-91

05-24-9106-19-9106-20-9107-11-9109-05-91

05-22-9106-13-9106-13-91

05-21-9105-21-9107-09-9108-06-9108-06-91

09-25-91

Gross chlordane

<100<100

<100<100<100<100<100

<1001

<100<100<100

<100<100<100<100<100

<100<100<100

<100<100<100<100<100

<100

p,p'-DDD

1<1<11.1

<1113314

21.3

22

<!<1<1

<1<1<1<11

T<1

P,P'- DDE

22

36121

516182919

103

<19

15

112

11111

1

P,P'- DDT

11

35121

413183715

772

1012

<!<1<1

11.2

<1*1

<1

Di- eldrin

<x*1

<11.2.1

1

<!2251

11222

<!<1*1

1<1

.4<11

1

Endo- Hepta- sulfan I Endrin chlor

1 <1 <1<1 <1 <1

1 <1 <1<1 <1 <1

.8 <1 <1<1 <1 <1<1 <1 <1

1 <1 <1<1 <1 <1<1 <1 <1<1 <1 <1<1 <1 <1

2 <1 <1<1 <1 <1

.1 <1 <1<1 <1 <1<1 <1 <1

1 <1 <1<1 <1 <1<1 <1 <1

1 <1 <11 <1 <11 <1 <1

<1 <1 <1<1 <1 <1

<1 <1 <1

43

Table 14. Concentrations of organochlorine compounds associated with suspended sediment, Yakima River basin, Washington, May-September 1991 Continued

Station number

1249655012496550

1250042012500420125004201250042012500420

1250545012505450125054501250545012505450

1250885012508850125088501250885012508850

125094991250949912509499

1251050012510500125105001251050012510500

P-P'- Hepta- Meth- chlor oxy-

Date epoxide Lindane chLor

05-22-91 <1 <1 <1006-12-91 nq <1 <10

05-23-91 <1 <1 <1006-17-91 <1 <1 <1006-20-91 <1 .1 <1007-10-91 <1 <1 <1009-04-91 <1 <1 <10

05-23-91 <1 <1 <1006-17-91 .1 .1 <1006-20-91 <1 .3 <1007-10-91 <1 <1 <1009-04-91 <1 <1 <10

05-24-91 <1 <1 <1006-19-91 <1 <.l <1006-20-91 <1 .5 <1007-11-91 <1 <1 <1009-05-91 <1 <1 <10

05-22-91 <1 <1 <1006-13-91 nq <1 <1006-13-91 nq <1 <10

05-21-91 <1 <1 <1005-21-91 <1 <1 <1007-09-91 <1 <1 <1008-06-91 <1 <1 <1008-06-91 <1 <1 <10

Mirex PCB

<10 <10<10 <100

<10 <10<10 26<10 <100<10 60<10 70

<10 <10<10 <100<10 <100<10 20<10 40

<10 10<10 <100<10 <100<10 <100<10 10

<10 <10<10 <100<10 <100

<10 <10<10 <10<10 10<10 20<10 50

PCN

<100<100

<100<100<100<100<100

<100<100<100<100<100

<100<100<100<100<100

<100<100<100

<100<100<100<100<100

Per- thane

<100<100

<100<100<100<100<100

<100<100<100<100<100

<100<100<100<100<100

<100<100<100

<100<100<100<100<100

Toxa- aphene

<1,000<1,000

<1,000<1,000<1,000<1,000<1,000

<1,000<1,000<1,000<1,000<1,000

<1,000<1,000<1,000<1,000<1,000

<1,000<1,000<1,000

<1,000<1,000<1,000<1,000<1,000

12510500 09-25-91 <1 <1 <10 <10 20 <100 <100 <1,000

44

Table 15. Concentrations of organophosphorus pesticides in whole-water samples, Yakima River basin, Washington, 1988-89

[Concentrations in nanograms per liter; " " = not analyzed; "<" ~ less than; see figure 1 for site locations]


3 3 3 3 3

3 3

4

11

13 13 13 13 13

13 13

1414

22

24 24 24 24 24

24 24 24 24 24

24

27 27 27 27 27

27 27

28

36 36 36 36 36

36 36 36 36

37

38 38 38 38 38

38

43

46 46 46 46 46

Station number

12478300 12478300 12478300 12478300 12478300

12478300 12478300

12479500

12484100

12484480 12484480 12484480 12484480 12484480

12484480 12484480

1248450012484500

12499000

12500430 12500430 12500430 12500430 12500430

12500430 12500430 12500430 12500430 12500430

12500430

12500445 12500445 12500445 12500445 12500445

12500445 12500445

12500450

12505460 12505460 12505460 12505460 12505460

12505460 12505460 12505460 12505460

12505510

12507508 12507508 12507508 12507508 12507508

12507508

12508620

12508850 12508850 12508850 12508850 12508850

Station name

Cle Elum R above Cle Elum Lake nr Roslyn Cle Elum R above Cle Elum Lake nr Roslyn Cle Elum R above Cle Elum Lake nr Roslyn Cle Elum R above Cle Elum Lake nr Roslyn Cle Elum R above Cle Elum Lake nr Roslyn

Cle Elum R above Cle Elum Lake nr Roslyn Cle Elum R above Cle Elum Lake nr Roslyn



Cherry Creek at Thrall Cherry Creek at Thrall Cherry Creek at Thrall Cherry Creek at Thrall Cherry Creek at Thrall

Cherry Creek at Thrall Cherry Creek at Thrall



Moxee Drain at Thorp Rd nr Union Gap Moxee Drain at Thorp Rd nr Union Gap Moxee Drain at Thorp Rd nr Union Gap Moxee Drain at Thorp Rd nr Union Gap Moxee Drain at Thorp Rd nr Union Gap

Moxee Drain at Thorp Rd nr Union Gap Moxee Drain at Thorp Rd nr Union Gap Moxee Drain at Thorp Rd nr Union Gap Moxee Drain at Thorp Rd nr Union Gap Moxee Drain at Thorp Rd nr Union Gap


Wide Hollow Creek near mouth at Union Gap Wide Hollow Creek near mouth at Union Gap Wide Hollow Creek near mouth at Union Gap Wide Hollow Creek near mouth at Union Gap Wide Hollow Creek near mouth at Union Gap

Wide Hollow Creek near mouth at Union Gap Wide Hollow Creek near mouth at Union Gap

Yakima R abv Ah tan urn Cr at Union Gap

Granger Drain at mouth nr Granger Granger Drain at mouth nr Granger Granger Drain at mouth nr Granger Granger Drain at mouth nr Granger Granger Drain at mouth nr Granger

Granger Drain at mouth nr Granger Granger Drain at mouth nr Granger Granger Drain at mouth nr Granger Granger Drain at mouth nr Granger


Toppenish Cr at Indian Church Rd nr Granger Toppenish Cr at Indian Church Rd nr Granger Toppenish Cr at Indian Church Rd nr Granger Toppenish Cr at Indian Church Rd nr Granger Toppenish Cr at Indian Church Rd nr Granger


Satus Creek at gage at Satus

Sulphu Cr Wasteway nr Sunnyside Sulphu Cr Wasteway nr Sunnyside Sulphu Cr Wasteway nr Sunnyside Sulphu Cr Wasteway nr Sunnyside Sulphu Cr Wasteway nr Sunnyside

Date

05-05-88 06-02-88 07-26-88 07-26-88 08-31-88

11-16-88 03-09-89

07-26-88

07-26-88

05-05-88 06-02-88 06-02-88 07-26-88 08-31-88

11-18-88 03-09-89

07-27-8806-28-89

07-26-88

05-06-88 05-06-88 06-01-88 07-26-88 07-27-88

07-28-88 07-29-88 08-30-88 11-15-88 03-10-89

06-28-89

05-05-88 06-03-88 07-27-88 08-30-88 11-15-88

11-15-88 03-10-89

07-27-88

05-06-88 06-01-88 07-28-88 07-28-88 07-28-88

09-02-88 11-15-88 03-09-89 06-27-89

07-28-88

05-06-88 06-03-88 07-28-88 09-01-88 11-16-88

03-08-89

07-29-88

05-06-88 06-03-88 07-28-88 07-28-88 08-31-88

Time

1100 0930 1000 1015 1030

1030 1015

1500

1615

1530 1400 1405 1030 1630

1000 1400

10451705

1330

0930 0940 1600 1100 1310

1605 0800 1730 1015 1200

1035

1845 0730 1025 1430 1330

1430 1400

1600

1230 1300 0730 0930 1015

1000 1645 1730 1705

1145

1345 1000 1445 0930 1615

1600

1145

1630 1300 1200 1700 1530

Chlor- pyrifos

-

-

-

----

-

10 10

-

--

--

-

-

--

Diaz- inon

1

<iS<10

<10

11So<10<10

<10

10 360 630

130 530 30

370

120 10

<10

20

30 2010

10

10

230

150 10

<10

50

20 10 10

Table 15. Concentrations of organophosphorus pesticides in whole-water samples, Yakima River basin, Washington, 1988-1989 Continued

Station number

12478300 12478300 12478300 12478300 12478300

12478300 12478300

12479500

12484100

12484480 12484480 12484480 12484480 12484480

12484480 12484480

12484500 12484500

12499000

12500430 12500430 12500430 12500430 12500430

12500430 12500430 12500430 12500430 12500430

12500430

12500445 12500445 12500445 12500445 12500445

12500445 12500445

12500450

12505460 12505460 12505460 12505460 12505460

12505460 12505460 12505460 12505460

12505510

12507508 12507508 12507508 12507508 12507508

12507508

12508620

12508850 12508850 12508850 12508850 12508850

Date

05-05-88 06-02-88 07-26-88 07-26-88 08-31-88

11-16-88 03-09-89

07-26-88

07-26-88

05-05-88 06-02-88 06-02-88 07-26-88 08-31-88

11-18-88 03-09-89

07-27-88 06-28-89

07-26-88

05-06-88 05-06-88 06-01-88 07-26-88 07-27-88

07-28-88 07-29-88 08-30-88 11-15-88 03-10-89

06-28-89

05-05-88 06-03-88 07-27-88 08-30-88 11-15-88

11-15-88 03-10-89

07-27-88

05-06-88 06-01-88 07-28-88 07-28-88 07-28-88

09-02-88 11-15-88 03-09-89 06-27-89

07-28-88

05-06-88 06-03-88 07-28-88 09-01-88 11-16-88

03-08-89

07-29-88

05-06-88 06-03-88 07-28-88 07-28-88 08-31-88

Methyl Methyl Disulfo- Mala- para- tri- Para- ton Ethion thion thion thion thion Phorate

:: SS <JS SS <jo SS ::

-- SS <l°o SS <!°o So "<10 <10 <10 <10 <10

<10 <10 <10 <10 <10

:: | | | | | ::

-- <10 <10 <10 <10 <10 --

~ So So So So So --<10 <10 <10 <10 <10

-- <10 <10 <10 <10 ^lO 20 410 <10 <10 <10 80 240 140 <10 <10 <10 10 100

50 <10 <10 <10 100 140 40 <10 <10 <10 10 90

-- 100 <10 <10 <10 <10 10

<10 <10 <10 <10 <10 90

-- <10 <10 <10 < 10 <10 -- <10 60 <10 <10 10 --

:: SS SS SS SS SS "<10 <10 <10 <10 <10

-- <10 10 <10 <10 <10

ij | | ! | | ii-- <10 <10 <10 <10 20 --

-- <10 <10 <10 <10 ^lO -- <10 10 <10 <10 <10 <10 <10 ^lO <10 20

<10 <10 <10 <10 <10

<10 <10 <10 <10 10

-- <10 <10 <10 <10 10 -- 70 <10 <10 <10 <10 <10 10 60 <10 <10 <10 < 10 <10 10 -- <10 <10 <10 <10 <10 --

Tri- thion

1

So<10

<10

1So

So<10

SS

SS<10

i<io<10

I<10

<10

SS

<io<10

o o o o oi-» i-» i-» r-l r-»V V V V V

46

Table 15. Concentrations of organophosphorus pesticides in whole-water samples, Yakima River basin, Washington, 1988-1989 Continued

Mapreferencenumber

46464646

47

49

50

5151515151

5151515151

58

5959

61

Station number

12508850125088501250885012508850

12509050

12509710

12509829

1251050012510500125105001251050012510500

1251050012510500125105001251050012510500

463233120262101

463234120261601463234120261601

463257120260801

Station name

Sulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr Sunnyside

Yakima R at Euclid Br at RM 55 nr Grandview


Snipes Creek at mouth st Whitstran



Well 12N/19E-09H02

Well 12N/19E-09H01Well 12N/19E-09H01

Well 12N/19E-10D02

Date

08-31-8811-17-8803-08-8906-26-89

07-28-88

07-29-88

07-29-88

05-07-8806-01-8807-29-8808-31-8811-17-88

03-08-8906-26-8912-06-8912-06-8912-07-89

01-20-89

01-20-8901-20-89

01-20-89

Time

1630090012002005

1010

1300

1500

08000900103010001400

09001435161523571852

0750

07300737

0715

Chlor-pyrifos

__------

-

__----

----

__--------

-

--

--

Diaz-inon

<10<10<1020

70

70

10

<10<102501010

<1030

<10<10<10

<10

<10<10

<10

Station number

12508850125088501250885012508850

12509050

12509710

12509829

1251050012510500125105001251050012510500

1251050012510500125105001251050012510500

Disulfo- Mala-Date ton Ethion thion

08-31-88 -- <10 <1011-17-88 <10 <1003-08-89 <10 <1006-26-89 <10 10

07-28-88 <10 <10

07-29-88 <10 10

07-29-88 -- <10 <10

05-07-88 -- <10 <1006-01-88 <10 <1007-29-88 -- <10 <1008-31-88 -- <10 <1011-17-88 -- <10 <10

03-08-89 <10 <1006-26-89 -- <10 <1012-06-89 <10 <10 <1012-06-89 <10 <10 <1012-07-89 <10 <10 <10

Methyl Methylpara- tri-thion thion

<10 <10<10 <10<10 <10<10 <10

<10 <10

<10 <10

<10 <10

<10 <10<10 <10<10 < 10<10 <10<10 <10

<10 <10<10 <10<10 <10<10 <10<10 <10

Para-thion

<10<10<10<10

30

10

<10

<10<1060

<10<10

<1010

<10<10<10

Phorate

__----

10

--

--

--------

--

<10<10<10

Tri-thion

<10<10<10<10

<10

<10

<10

<10<10<10<10<10

<10<10<10<10<10

463233120262101 01-20-89

463234120261601 01-20-89 463234120261601 01-20-89

463257120260801 01-20-89

47

Tabl

e 16.

Conc

entr

atio

ns of

organophosphorus pesticides in fiItered-water samples, Yakima Ri

ver

basin, Washington,

June

25-30, 19

89

[Concentrations

in n

anograms per

liter: "D"

= detected an

d not

quantified;

nd =

not

detected a

nd m

inim

um re

port

ing

leve

l not

quantified;

H..H

=

not;

anal

yzed

; "T"

= pr

esen

t, but

belo

w quantifiable c

once

ntra

tion

; "<"

= less th

an;

DEF

= (S

,S.S

-tri

buty

l ph

osph

orot

rith

ioat

e),

methamidophos, an

d terbufos w

ere

not

dete

cted

; for

qual

ity

assu

ranc

e, three

addi

tion

al re

plic

ate

samp

les

from t

he Y

akima

Rive

r at

Ki

ona

were analyzed for

azinphos-methyl, an

d the concentrations we

re 6

.5,

6.7, an

d 9.

0 ng

/L;

see

figu

re

1 for

site

locations]

oo

Map

refe

renc

e Station

number

numb

er

2 4 11 13 14 15 19 20 22 24 27 28 30 33 34 36 55 37 38 40 41 53 43 45 46 47 49 50 51

1247

8200

1247

9500

12484100

12484480

12484500

12484550

12496510

1249

6511

1249

9000

1250

0430

12500445

1250

0450

1250

2500

1250

5350

1250

5410

1250

5460

462510-

1203

2390

112

5055

1012507508

12507585

1250

7594

461720-

1200

4320

112

5086

2012

5086

3012508850

12509050

1250

9710

12509829

1251

0500

Azinphos-

Chlo

r-

Stat

ion

name

meth

yl

pyrifos

Coop

er Ri

ver

at Sa

lmon

LaSac

Yakima Ri

ver

at Cl

e El

urn

Wilson C

r abv. Ch

erry

Creek

Cherry C

reek a

t Th

rall

Yakima Ri

ver

at Umtanum

Umtanum

Cree

k nr mo

uth

Pacific

Powe

r &

Ligh

t Company

Wast

eway

City o

f Ya

kima

- Fi

nish

Water

Nacnes Ri

ver

nr No

rth

Yakima

Moxe

e Dr

ain

at Thorp

Rd

Wide Hollow C

reek ne

ar m

outh

Yakima R

abv Ahtanum

CrAh

tanu

m Cr

eek

at Un

ion

Gap

E Toppenish

Drai

n at

Wilson R

dSub

35 D

rain

at

Parton R

oad

Gran

ger

Drain

at mo

uth

Well

2, Harrah.

11N/

18E-

22R0

2Marion D

rain

, Indian C

hurc

h Rd

Toppenish

Cr,

Indian C

hurc

h Rd

Yakima Ri

ver

at RM

72

Satu

s Cr

ab

v Wi

lson

-Cha

rley

Canyon n

r To

ppenish

Well

1,

Su

nnys

ide,

09

N/22

E-04

P01

Satu

s Cr

at

gage at Sa

tus

Sout

h Drain

nr S

atus

Sulp

hur

Cree

k Wasteway

Yaki

ma R

at Euclid B

r at

RM 5

5Spring Cr

eek

at mo

uth

Snipes Cr

eek

at mouth

Yakima Ri

ver

at Kiona

nd

<4.6 nd nd nd D D D D nd D

T<4.6 D nd D nd

<1 6

<\75

<3.3

T<3.

1T<

2.4

1.0

<.73

<1 .0

<.65

T<6.7

<3

1<2

i2T<2.1

3.3

T<3.1

T<6.0

<1 .0

<3.

1T<

2.0

T<3.

1

<.66

<1 0

T<3.1

<6.7

<26

T<2.2

2.8

<3.

19.6

Demeton-S

<2

1<>6

<4.4

<4.0

<2.4

<1.2 <.74

<1 .4

<.77

T<7.

9

<4

1<2

i3T<

2.5

<4.2

<4.1

<7.1

<1 .4

<4.

1<2

.4<4

.0 <.79

<1 .3

<4.2

<8.0

T<34 <2

.6<4

.2<4

.1<2

.4

Diazinon

<1 3 !67

<2.7

T<2.7

T<2.

0

<1.2 <.64

<.83

T<.6

4410 5.

97.

93.

328 25 11 T<

.83

55 31 35 <.65

<.82

22 150 66 120 71 32 39

Dime

tho-

at

e <2.2

<1 .2

<4.7

<3.5

<3.7

<1.1

<1 .

1<1

.4

<1 .3

<13 5.

7<3

.5<4

.2T<

4.5

T<4.4

T<12 <1

.4

4.6

T<4.0

<3.5

<1 .3

T<1.

47.7

<13

330 7.

3<4.6

T<4.

4<3.7

Disu

lfo-

to

n <1 7

<>8

<3.5

<2.2

<2.4

<1.3 <.76

<1

1<.

74<7

.6

<3.3

<2.3

<2.4

<3.4

T<3.

3

T<6.9

<1

1T<

3.3

T<2.

3T<

2.2

<.76

<1

1T<

3.3

T<7.

7T<27 <2

.5T<

3.4

<3.3

<2.4

Ethion

<2.6

T<1.

2<5

.4<2

.6T<3.9

<1.2

<1 .2

<1 .7

<1 .

1T<11 T<5.

1T<3.7

<3.6

<5.2

<10 <1 7

T<5.

1<3

.5<2

.6

<1 .1

<1 .7

<5.

1<12

<42 <3.7

T<5.

2T<5.1

T<3.

9

Fonofos

<1 0

<!66

<2

1<2

.4<2

.0

<1.2 <.64

<.66

<.68

<7.0

<2.0

<2.0

<2.2

<2.0

<2.0

<6.3 <.66

T<2.

0<2

1

T<2.

4

<.70

<.65

<2.0

<7.

1<1

7 <2.3

<2.0

<2.0

<2.0

Isofen-

phos <1 8

<!84

<3.9

<2.6

T<2.

6

<.90

<.82

<1 2

<.80

<8.2

<3.6

T<2.

5<2

.6<3.7

<3.6

<7.4

<1 2

<3.7

<2.5

<2.6 <.82

<1 2

<3.7

<8.3

<30 <2.7

<3.8

<3.7

<2.6

Table

16.

Concentrations of

organophosphorus pe

stic

ides

in

fiItered-water

samp

les,

Yakima R

iver

basin,

Wash

ingt

on,

June

25-30

, 19

89--

Cont

inue

d

Station

number

12478200

1247

9500

1248

4100

1248

4480

1248

4500

12484550

12496510

12496511

1249

9000

12500430

1250

0445

12500450

1250

2500

1250

5350

12505410

1250

5460

4625

ID-

120323901

1250

5510

12507508

12507585

12507594

4617

20-

120043201

12508620

1250

8630

1250

8850

1250

9050

1250

9710

12509829

12510500

Station

name

Mala

thio

n

Cooper Ri

ver

at Salmon La

Sac

Yakima Ri

ver

at Cle

Elum

Wils

on C

r abv. Cherry C

reek

Cher

ry C

reek a

t Th

rall

Yakima Ri

ver

at Um

tanu

m

Umta

num

Creek

nr m

outh

Paci

fic

Powe

r &

Ligh

t Company

Wasteway

City o

f Ya

kima

-Fin

ish

Water

Nacnes Ri

ver

nr No

rth

Yakima

Moxee Dr

ain

at Thorp

Rd

Wide Hollow C

reek

nea

r mouth

Yakima R

abv Ah

tanu

m Cr

Ahtanum

Creek

at U

nion G

apE

Topp

enis

h Drain

at Wi

lson

Rd

Sub

35 D

rain

at

Parton R

oad

Gran

ger

Drain

at m

outh

Well

2, Ha

rrah

. 11

N/18

E-22

R02

Mari

on D

rain

, In

dian

Church

RdTo

ppen

ish

Cr,

Indi

an C

hurch

RdYakima Ri

ver

at RM 7

2

Satu

s Cr

abv W

ilso

n-Ch

arle

yCa

nyon

nr

Topp

enis

h

Well

1, Su

nnys

ide,

09

N/22

E-04

P01

Satu

s Cr at ga

ge a

t Sa

tus

Sout

h Drain

nr Sa

tus

Sulphur

Creek

Wasteway

Yakima R

at Euclid B

r at RM 55

Spring C

reek a

t mo

uth

Snipes C

reek

at

mouth

Yakima Ri

ver

at Ki

ona

T<2.7

1.5

T<5.

7T<

2.7

T<3.9

<1.1 5.6

T<1.8

1.6

T<11 13 25 6.

312 19 T<9.9

2.1

31 12 14 <1.1

T<1.

714

T<11

T<44 8.

648 27 70

Methida-

thio

n

<2.4 <.96

140 <2.6 4.9

<.99

<.93

<1.6

<1.0

<10 <4.8

<2.8

<3.4

<4.9

<4.8

<9.5

<1.6

<4.8

<3.2

<2.6

<1.0

<1.6

T<4.

8<1

1<4

0 <3.4

<4.9

<4.8

<3.0

Meth

yl

parathion

<0.69

<1.3

<1.4

<3.1

T<4.

1

<1.4

<1.3 <.45

T<1.4

<14 <1.4

<3.9

<4.5

<1.4

16 <13 5.

6<1.4

<4.3

T<3.1

<1.4 <.44

<1.4

<14

<11 <4.6

13 <1.4

<4.1

Meth

yl

trithion

<2.4

<1.2

<5.1

<2.5

T<3.8

<1.5

<1.2

<1.6

T<1.2

<12 <4.8

<3.6

<3.9

<4.9

<4.8

<11 <1.6

<4.8

<3.7

<2.5

<1.2

<1.6

<4.8

<12

<40 <4.0

<4.9

<4.8

<3.8

Mevinphos

<2.1

<1.0

<4.4

<3.5

<3.2 <.93

<1.0

<1.3 <.93

<9.5

<4.1

<3.0

<3.0

<4.2

<4.1

T<8.6

<1.3

<4.1

<2.9

<3.5 <.95

<1.3

<4.1

<9.6

<34 <3.1

<4.2

<4.1

<3.2

Parathion

<2.6

<1.0

<5.4

<3.0

T<3.

2

T<1.

0<1

.7T<

1.3

<14 <5.1

T<3.

1<4.4

10 <5.1

<12 <1.7 7.4

16 11 <1.4

<1.7

180 23 <42 30 12

T<5.1

T<3.2

Phorate

<2.4 <.88

<5.1 5.2

<2.8 <.92

<.86

<1.6 <.87

130 <4.8 3.6

<2.8

10 <4.8

<8.0

<1.6

19 <2.7

T<3.4

<.89

<1.6

<4.8

<9.0

T<40 T<2.9

<4.9

<4.8

T<2.

8

Phos

pham

- id

on <2.2

T<2.1

T<4.

7<2.4

T<6.

5

<.86

<2.0

<1.5

T<1.0

43 8.1

T<6.1

5.3

52 16 56 T<1.

510 <3.2

T<2.4

<1.0

T<1.

4<4

.5<1

1T<

37 22 6.7

28 5.3

Trithion

<2.6

<1.1

<5.3

<2.5

<3.6 <.99

<1.1

<1.6 <.92

<9.4

<5.0

<3.4

<3.0

<5.1

<5.0

<8.5

<1.6

<5.0

<2.9

<2.5 <.94

<1.6

<5.1

<9.5

<42 <3.1

T<5.

2<5.0

<3.6

Table 17. Concentrations of organophosphorus pesticides in filtered-water samples, Yakima River basin, Washington, May-September 1991

[Concentrations in nanograms per liter; "<" - less than; DEF - S,S,S-tributyl phosphorotrithioate;see figure 1 for site locations]

Mapreference number

21 21

23 23 23 23 23

35 35 35 35 35

46 46 46 46 46

48 48

51 51 51 51 51

Station number

12496550 12496550

12500420 12500420 12500420 12500420 12500420

12505450 12505450 12505450 12505450 12505450

12508850 12508850 12508850 12508850 12508850

12509499 12509499

12510500 12510500 12510500 12510500 12510500

Station number

12496550 12496550

12500420 12500420 12500420 12500420 12500420

12505450 12505450 12505450 12505450 12505450

12508850 12508850 12508850 12508850 12508850

12509499 12509499

12510500 12510500 12510500 12510500 12510500

Station name



Granger Drain at Granger Granger Drain at Granger Granger Drain at Granger Granger Drain at Granger Granger Drain at Granger

Sulphur Cr Wasteway nr Sunnyside Sulphur Cr Wasteway nr Sunnyside Sulphur Cr Wasteway nr Sunnyside Sulphur Cr Wasteway nr Sunnyside Sulphur Cr Wasteway nr Sunnyside

Chandler Canal at Bunn Rd at Prosser Chandler Canal at Bunn Rd at Prosser


Disulfo- Mala- Date ton Ethion Fonofos thion

05-22-91 <10 <10 <10 <10 06-12-91 <10 <10 <10 <10

05-23-91 <10 <10 <10 <10 06-17-91 <10 <10 <10 10 06-20-91 <10 <10 <10 10 07-10-91 <10 20 <10 <10 09-04-91 <10 20 <10 <10

05-23-91 <10 <10 <10 <10 06-17-91 <10 <10 <10 20 06-20-91 <10 <10 10 20 07-10-91 <10 <10 <10 <10 09-04-91 <10 <10 <10 <10

05-24-91 <10 <10 <10 <10 06-19-91 <10 <10 <10 20 06-20-91 <10 <10 <10 50 07-11-91 <10 <10 <10 50 09-05-91 <10 <10 <10 <10

05-22-91 <10 <10 <10 <10 06-13-91 <10 <10 <10 30

05-21-91 <10 <10 <10 <10 07-09-91 <10 <10 <10 290 08-06-91 <10 <10 <10 <10 08-06-91 <10 <10 <10 <10 09-25-91 <10 <10 <10 <10

Date

05-22-91 06-12-91

05-23-91 06-17-91 06-20-91 07-10-91 09-04-91

05-23-91 06-17-91 06-20-91 07-10-91 09-04-91

05-24-91 06-19-91 06-20-91 07-11-91 09-05-91

05-22-91 06-13-91

05-21-91 07-09-91 08-06-91 08-06-91 09-25-91

Methyl Methyl para- tri- thion thion

:i°Q SS60 <10 20 <10

10 <10 30 <10

10 <10 40 <10

So1 S5So So

Chlor- Time pyrifos DEF

1100 <10 <10 1345 <10 <10

1000 10 <10 1100 10 <10 1645 10 <10 1240 <10 <10 1115 <10 <10

1230 <10 <10 1420 <10 <10 1400 <10 <10 1500 <10 <10 1420 <10 <10

1000 <10 <10 1145 <10 <10 1200 10 <10 1155 <10 <10 1130 <10 <10

1500 <10 <10 1240 <10 <10

1200 <10 <10 1155 <10 <10 1150 <10 <10 1151 <10 <10 1120 <10 <10

Para- Tri- thion Phorate thion

<Jo So So<10 10 <10

<10 10 <10

10 <10 <10 10 <10 <10

<10 10 <10

20 10 <10 10 <10 <10

S5 SS So10 <10 <10

10 <10 <10

Diaz- inon

S!340

1,300 30 10

10 30

20 50 20

So

10 10 10

50

Table 18. Concentrations of organophosphorus pesticides associated with suspended sediment, Yakima River basin, Washington, June 25-30, 1989

[Concentrations in nanograms per liter; " " « not analyzed; "T" - present, but below quantifiable concentration; "<" - less than; DEF - S,S,S-tributy1 phosphorotrithioate; see figure 1 for site locations]

Map reference Station number number

24

111314

1519

202224

2728303334

3655

373840

41

53

434546

47495051

1247820012479500124841001248448012484500

1248455012496510

124965111249900012500430

1250044512500450125025001250535012505410

12505460462510-120323901125055101250750812507585

12507594

461720-120042301125086201250863012508850

12509050125097101250982912510500

Chlor- Station name pyrifos

Cooper River at Sslmon LaSacYakima River at Cle ElumWilson Cr abv. Cherry CreekCherry Creek at ThrallYakima River at Umtanum






Well 1, Sunnyside, 09N/22E-04P01Satus Cr at gage at SatusSouth Drain nr SatusSulphur Creek Wasteway


<0.05<.04<.2.3

<.06

<.04

<.02<.04K.04

.48

<.l<.l<.2.4

<.l

<.08

<.04<.l.1

T<.1

<.03

<.04.2

K.09.16

<.l.2.2

T<.06

DEF

__<.04----

<.06

<.04

<.02<.04<.04<.05

<.l------

<.08

<.04----

<.l

--

<.04--

<.09<.l

<.l----

<.06

Diazinon

<0.05<.04<.2<.l<.06

<.04

<.02.06

<.043.3

<.lT<.1<.2.3.3

1.9

<.04.3.2.16

<.03

<.04.2.29.18

T<.1.9.3.07

Disulfo- ton

<0.05<.04<.2.6

<.06

<.04

<.02<.04<.04<.05

<.l<.l<.2<.l<.l

<.08

<.04<.l<.l<.l

<.03

<.04<.l<.09<.l

<.l<.l<.l<.06

Ethion

<0.05<.04<.2<.l<.06

<.04

<.02<.04

T<.04.52

<.l<.l<.2<.l<.l

T<.08

<.04<.l<.l

T<.1

<.03

<.04<.l<.09T<.1

<.l.5

<.l<.06

Fonofos

__<0.04

----

<.06

<.04

<.02<.04<.04<.05

--<.l------

<.08

<.04----

<.l

--

<.04--

<.09<.l

<.l----

<.06

Isofen- phos

<0.04

----

<.06

<.04

<.02<.04<.04<.05

--<. 1 ----

<.08

<.04--

* !

--

<.04--

<.09< - 1

T<.1 --

<.06

Station Number

1247820012479500124841001248448012484500

1248455012496510

124965111249900012500430

1250044512500450125025001250535012505410

12505460462510-120323901125055101250750812507585

12507594

461720-120043201125086201250863012508850

12509050125097101250982912510500

Station name

Cooper River at Salmon LaSacYakima River at Cle ElumWilson Cr abv. Cherry CreekCherry Creek at ThrallYakima River at Umtanum






Well 1, Sunnyside, 09N/22E-04P01Satus Cr at gage at SatusSouth Drain nr SatusSulphur Creek Wasteway


Malathion

<0.05<.04< .2< . i<.06

<.04

<.02<.04<.04<.05

<_!<. i<.2< . 1* !

<.08

<.04<. 1<. 1-M

<.03

<.04<. 1<.09< - 1

<.!<. 1<. 1<.06

Methyl parathion

<0.05<.04<.2<.l<.06

<.04

T<.02<.04<.04<.05

<.l<.l<.2<.l<.l

<.08

<.04<.l<.l<.l

<.03

<.04.6

<.09<.l

<.l<.l.3

<.06

Methyl trithion

<0.05<.04<.2<.l<.06

<.04

<.02<.04<.04<.05

<.l<.l<.2<.l<.l

<.08

<.04<.l<.l<.l

<.03

<.04<.l<.09<.l

<.l<.l<.l<.06

Parathion

<0.05<.04<.2<.l<.06

<.04

<.02<.04<.04.14

<.l<.l<.2.5

<.l

<.08

<.04<.l.1.10

<.03

<.04.3.17.10

<.l.5.2

T<.06

Phorate

<0.05<.04<.2.3

<.06

<.04

<.02<.04<.041.4

<.l<.l<.2<.l<.l

<.08

<.04<.l<.l<.l

<.03

<.04<.l<.09

T<.1

<.l<.l<.l<.06

Trithion

<0.05<.04<.2< . 1<.06

<.04

<.02<.04<.04<.05

<_!<. 1<.2< . 1 = 1

<.08

<.04<. 1<. 1< 1

<.03

.04

.1

.09

.1

.1

.1

.1

.06

51

Table 19. Concentrations of organophosphorus pesticides associated with suspended sediment, Yakima River basin, Washington, May-September 1991

[Concentrations in nanograms per liter; "<" = less than; DBF = S,S,S-tributyl phosphorotrithioate;see figure 1 for site locations]

Map referencenumber

2121

2323232323

3535353535

4646464646

484848

5151515151

51

Station number

1249655012496550

1250042012500420125004201250042012500420

1250545012505450125054501250545012505450

1250885012508850125088501250885012508850

125094991250949912509499

1251050012510500125105001251050012510500

12510500

Station name

Buckskin Slough blw Gleed Ditch nr GleedBuckskin Slough blw Gleed Ditch nr Gleed

Moxee Drain at Birchfield Road nr Union GapMoxee Drain at Birchfield Road nr Union GapMoxee Drain at Birchfield Road nr Union GapMoxee Drain at Birchfield Road nr Union GapMoxee Drain at Birchfield Road nr Union Gap

Grange Drain at GrangerGrange Drain at GrangerGrange Drain at GrangerGrange Drain at GrangerGrange Drain at Granger

Sulphu Cr Wasteway nr SunnysideSulphu Cr Wasteway nr SunnysideSulphu Cr Wasteway nr SunnysideSulphu Cr Wasteway nr SunnysideSulphu Cr Wasteway nr Sunnyside

Chandler Canal at Bunn Rd at ProsserChandler Canal at Bunn Rd at ProsserChandler Canal at Bunn Rd at Prosser



Date

05-22-9106-12-91

05-23-9106-17-9106-20-9107-10-9109-04-91

05-23-9106-17-9106-20-9107-10-9109-04-91

05-24-9106-19-9106-20-9107-11-9109-05-91

05-22-9106-13-9106-13-91

05-21-9105-21-9107-09-9108-06-9108-06-91

09-25-91

Time

11001345

10001100164512401115

12301420140015001420

10001145120011551130

150012401241

12001201115511501151

1120

Chlor-pyrifos

<0*

<<

<*

<<<<*

<<<<*

<<*

<<<

<10<10

<

53

45864

35754

46744

766

444

5

Diaz-DEF inon

<0.5 <0.5<.3 <.3

<.4 <.4<'.5 1<.4 30<.6 1<.4 <.4

<.3 <.3< . 5 <. 5<.7 1< . 5 < . 5<.4 <.4

<.4 <.4<.6 <.6<.7 1<. 4 <.4<.4 <.4

< 7 < 7<. 6 <. 6<.6 <.6

<.4 <.4<. 4 <. 4<. 4 <. 4

<10 <10<10 <10

<.5 <.5

Methyl Methyl

Station number

1249655012496550

1250042012500420125004201250042012500420

1250545012505450125054501250545012505450

1250885012508850125088501250885012508850

125094991250949912509499

1251050012510500125105001251050012510500

Disulf- Mala-Date oton Ethion Fonofos thion

05-22-91 <0.5 <0.5 <0.5 <0.506-12-91 <.3 <.3 <.3 <.3

05-23-91 <.« <.4 <.4 <.406-17-91 <.5 <.5 <.5 <.506-20-91 <.4 <.4 <.4 <.407-10-91 <.6 1 <.6 <.609-04-91 <.4 1 <.4 <.4

05-23-91 <.3 <.3 <.3 <.306-17-91 <.5 <.5 <.5 <.506-20-91 <.7 <.7 <.7 <.707-10-91 <.5 <.5 <.5 <.509-04-91 <.4 <.4 <.4 <.4

05-24-91 <.4 <.4 <.4 <.406-19-91 <.6 <.6 <.6 <.606-20-91 <.7 <.7 <.7 <.707-11-91 <.4 <.4 <.4 <.409-05-91 <.4 <.4 <.4 <.4

05-22-91 <.7 <.7 <.7 <.706-13-91 <.6 <.6 <.6 <.606-13-91 <.6 <.6 <.6 <.6

05-21-91 <.4 <.4 <.4 <.405-21-91 <.4 <.4 <.4 <.407-09-91 <.4 <.4 <.4 .408-06-91 <10 <10 <10 <1008-06-91 <10 <10 <10 <10

para- tri-thion thion

<0.5 <0.5<.3 <.3

<.4 <.4<. 5 <.54 <.41 <.6.5 <.4

<.3 <.31 < . 52 <.71 <. 5.6 <.4

< 4 <.43' <!e7 <.71 < . 4.4 <.4

< 7 <_ 7<.6 <.6<.6 <.6

<.4 <.4<.4 <. 4<.4 <. 4

<10 <10<10 <10

Para-thion

<0.5<.3

<.4<.5<.4<.6<.4

<.3<.5<.7<.5<.4

<.4<.61<.4<.4

<.7<-6<.6

<.4<.4<.4

<10<10

Tri-Phorate thion

<0<

<<<

<

<<<<<

<<<<<

<<*

<<<

<10<10

5 <0.53 <.3

4 <.45 <.54 <.46 <.64 <.4

3 <.35 <.57 <.75 <.54 <.4

4 <.46 <.67 <.74 <.44 <.4

7 <.76 <.66 <.6

4 <.44 <.44 <.4

<10<10

12510500 09-25-91

52

Table 20. Concentrations of phenol and cresoL compounds (acid-extractable compounds) in whole-water samples,Yakima River basin, Washington, 1988-89

[Concentrations in nanograms per liter; "<" « less than; see figure 1 for site locations]

Map reference number Station number

24 12500430

27 12500445 27 12500445 27 12500445 27 12500445 27 12500445 27 12500445

28 12500450

36 12505460

46 12508850 46 12508850 46 12508850 46 12508850

51 12510500

Station name


Wide RoLLow Creek near mouth at Union Gap Wide RoLLow Creek near mouth at Union Gap Wide RoLLow Creek near mouth at Union Gap Wide RoLLow Creek near mouth at Union Gap Wide RoLLow Creek near mouth at Union Gap Wide RoLLow Creek near mouth at Union Gap


Granger Drain at mouth nr Granger

SuLphur Cr Wasteway nr Sunnyside SuLphur Cr Wasteway nr Sunnyside SuLphur Cr Wasteway nr Sunnyside SuLphur Cr Wasteway nr Sunnyside


Station number Date

12500430

125004451250044512500445125004451250044512500445

12500450

12505460

12508850125088501250885012508850

08-30-88

05-05-8807-27-8808-30-8811-15-8811-15-8803-10-89

07-27-88

09-02-88

07-28-8807-28-8808-31-8808-31-88

2,4-Di-methyL- phenoL

<5,000

<5,000<5,000<5,000<5,000<5,000<5.000

<5,000

<5,000

<5,000<5,000<5,000<5,000

4.6-2,4,- Di-

Dinitro- nitro- o-cresoL phenoL

<30,000

<30,000<30,000<30,000<30,000<30,000<30,000

<30,000

<30,000

<30,000<30,000<30,000<30,000

<20,000

<20,000<20,000<20,000<20,000<20,000<20,000

<20,000

<20,000

<20,000<20,000<20,000<20,000

2-Nitro- phenoL

<5,000

<5,000<5,000<5,000<5,000<5,000<5,000

<5,000

<5,000

<5,000<5,000<5,000<5,000

4-

Date

08-30-88

05-05-88 07-27-88 08-30-88 11-15-88 11-15-88 03-10-89

07-27-88

09-02-88

07-28-88 07-28-88 08-31-88 08-31-88

08-31-88

Nitro- phenoL

<30,

<30,<30,<30,<30,<30,<30,

<30,

<30,

<30,<30,<30,<30,

000

000000000000000000

000

000

000000000000

P-

Time

1730

1845 1025 1430 1330 1430 1400

1600

1000

1200 1700 1530 1630

1000

Penta-chLoro- chLoro- m-cresoL phenoL

<30,000

<30,000<30,000<30,000<30,000<30,000<30,000

<30,000

<30,000

<30,000<30,000<30,000<30,000

<30,000

<30,000<30,000<30,000<30,000<30,000<30.000

<30,000

<30,000

<30,000<30,000<30,000<30,000

2-Chloro- phenoL

<5,000

<5,000 <5,000 <5,000 <5,000 <5,000 <5,000

<5,000

<5,000

<5,000 <5,000 <5,000 <5,000

<5,000

PhenoL

<5,000

<5,000<5,000<5,000<5,000<5,000<5,000

<5,000

<5,000

<5,000<5,000<5,000<5,000

2,4-Di- chLoro- phenoL

<5,000

<5,000 <5,000 <5,000 <5,000 <5,000 <5,000

<5,000

<5,000

<5,000 <5,000 <5,000 <5,000

<5,000

2,4.6- Tri-chLoro- phenol

<20,000

<20,000<20,000<20,000<20,000<20,000<20,000

<20,000

<20,000

<20,000<20,000<20,000<20,000

12510500 08-31-88 <5,000 <30,000 <20,000 <5,000 <30,000 <30,000 <30,000 <5,000 <20,000

53

Table 21. Concentrations of triazine, acetamlde, chloroacetanilide, and other pesticides in whole-water samples,Yakima River basin, Washington, 1988-89

[Concentrations in nanograms per liter; "<" - less than; see figure 1 for site locations]


33333

3

4

11

1313131313

1313

1414

22

2424242424

2424242424

24

2727272727

2727

28

3636363636

363636

37

3838383838

38

43

4646464646

46464646

47

49

50

5151515151

5151

Station number

1247830012478300124783001247830012478300

12478300

12479500

12484100

1248448012484480124844801248448012484480

1248448012484480

1248450012484500

12499000

1250043012500430125004301250043012500430

1250043012500430125004301250043012500430

12500430

1250044512500445125004451250044512500445

1250044512500445

12500450

1250546012505460125054601250546012505460

125054601250546012505460

12505510

1250750812507508125075081250750812507508

12507508

12508620

1250885012508850125088501250885012508850

12508850125088501250885012508850

12509050

12509710

12509829

1251050012510500125105001251050012510500

1251050012510500

Station name


Cle Elum R above Cle Elum Lake nr Roslyn







Moxee Drain at Thorp Rd n Un,ion GapMoxee Drain at Thorp Rd n Union GapMoxee Drain at Thorp Rd n Union GapMoxee Drain at Thorp Rd n Union GapMoxee Drain at Thorp Rd n Union Gap

Moxee Drain at Thorp Rd n Union GapMoxee Drain at Thorp Rd n Union GapMoxee Drain at Thorp Rd n Union GapMoxee Drain at Thorp Rd n Union GapMoxee Drain at Thorp Rd n Union Gap


Wide Hollow Creek nea mouth at Union GapWide Hollow Creek nea mouth at Union GapWide Hollow Creek nea mouth at Union GapWide Hollow Creek nea mouth at Union GapWide Hollow Creek nea mouth at Union Gap

Wide Hollow Creek nea mouth at Union GapWide Hollow Creek nea mouth at Union Gap



Granger Drain at mouth nr GrangerGranger Drain at mouth nr GrangerGranger Drain at mouth nr Granger




Satus Creek at gage at Satus

Sulphu Cr Wasteway nr SunnysideSulphu Cr Wasteway nr SunnysideSulphu Cr Wasteway nr SunnysideSulphu Cr Wasteway nr SunnysideSulphu Cr Wasteway nr Sunnyside

Sulphu Cr Wasteway nr SunnysideSulphu Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr Sunnyside

Yakima R at Euclid Br at RM 55 nr Grandview


Snipes Creek at mouth at Whitstran


Yakima River at KionaYakima River at Kiona

Date

05-05-8806-02-8807-26-8808-31-8811-16-88

03-09-89

07-26-88

07-26-88

05-05-8806-02-8806-02-8807-26-8808-31-88

11-18-8803-09-89

07-27-8806-28-89

07-26-88

05-06-8805-06-8806-01-8807-26-8807-27-88

07-28-8807-29-8808-30-8811-15-8803-10-89

06-28-89

05-05-8806-03-8807-27-8808-30-8811-15-88

11-15-8803-10-89

07-27-88

05-06-8806-01-8807-28-8807-28-8809-02-88

11-15-8803-09-8906-27-89

07-28-88

05-06-8806-03-8807-28-8809-01-8811-16-88

03-08-89

07-29-88

05-06-8806-03-8807-28-8807-28-8808-31-88

08-31-8811-17-8803-08-8906-26-89

07-28-88

07-29-88

07-29-88

05-07-8806-01-8807-29-8808-31-8811-17-88

03-08-8906-26-89

Time

11000930100010301030

1015

1500

1615

15301400140510301630

10001400

10451705

1330

09300940160011001310

16050800173010151200

1035

18450730102514301330

14301400

1600

12301300073009301000

164517301705

1145

13451000144509301615

1600

1145

16301300120017001530

1630090012002005

1010

1300

1500

08000900103010001400

09001435

Ala- chlor

<100<100<100<100<100

<100

<100

<100

<100<100<100<100<100

<100<100

<100<100

<100

<100<100<100<100<100

<100<100<100<100<100

<100

<100<100<100<100<100

<100<100

<100

<10030

<100<100<100

<100<100<100

<100

<100<100<100<100<100

<100

<100

<100<100<100<100<100

<100<100<100<100

<100

<100

<100

<100<100<100<100<100

<100<100

Ame- tryn

<100<100<100<100<100

<100

<100

<100

<100<100<100<100<100

<100<100

<100<100

<100

<100<100<100<100<100

<100<100<100<100<100

<100

<100<100<100<100<100

<100<100

<100

<100<100<100<100<100

<100<100<100

<100

<100<100<100<100<100

<100

<100

<100<100<100<100<100

<100<100<100<100

<100

<100

<100

<100<100<100<100<100

<100<100

Atra- zine

<100<100<100<100<100

<100

<100

59

7020607861

48600

16<100

<100

30301014

<100

179

16<100<100

10

<10040

<100<100<100

<10011

25

90904047

120

<10028090

120

5060544323

<100

52

6020253134

34<100

4422

48

<100

11

50304930

<100

<100<100

54

Table 21. Concentrations of triazine, acetamide, chloroacetanilide, and other pesticides in whole-water samples, Yakima River basin, Washington, 1988-89 Continued

Station number

12478300 12478300 12478300 12478300 12478300

12478300

12479500

12484100

12484480 12484480 12484480 12484480 12484480

12484480 12484480

12484500 12484500

12499000

12500430 12500430 12500430 12500430

12500430

12500430 12500430 12500430 12500430 12500430

12500430

12500445 12500445 12500445 12500445 12500445

12500445 12500445

12500450

12505460 12505460 12505460 12505460 12505460

12505460 12505460 12505460

12505510

12507508 12507508 12507508 12507508 12507508

12507508

12508620

12508850 12508850 12508850 12508850 12508850

12508850 12508850 12508850 12508850

12509050

12509710

12509829

12510500 12510500 12510500 12510500 12510500

12510500 12510500

Date

05-05-88 06-02-88 07-26-88 08-31-88 11-16-88

03-09-89

07-26-88

07-26-88

05-05-88 06-02-88 06-02-88 07-26-88 08-31-88

11-18-88 03-09-89

07-27-88 06-28-89

07-26-88

05-06-88 05-06-88 06-01-88 07-26-88

07-27-88

07-28-88 07-29-88 08-30-88 11-15-88 03-10-89

06-28-89

05-05-88 06-03-88 07-27-88 08-30-88 11-15-88

11-15-88 03-10-89

07-27-88

05-06-88 06-01-88 07-28-88 07-28-88 09-02-88

11-15-88 03-09-89 06-27-89

07-28-88

05-06-88 06-03-88 07-28-88 09-01-88 11-16-88

03-08-89

07-29-88

05-06-88 06-03-88 07-28-88 07-28-88 08-31-88

08-31-88 11-17-88 03-08-89 06-26-89

07-28-88

07-29-88

07-29-88

05-07-88 06-01-88 07-29-88 08-31-88 11-17-88

03-08-89 06-26-89

Brom- acil

<100 <100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 67

<100 <100

<100

<100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100

<100 200

<100 <100 <100

<100 <100

<100

<100 <100 <100 <100 <100

<100 110

<100

<100

<100 <100 <100 <100 <100

<100

<100

<100 <100 <100 <100 <100

<100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

Buta- chlor

<100 <100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

<100 <100

<100

<100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100 <100

<100

<100 <100 <100 <100 <100

<100 <100 <100

<100

<100 <100 <100 <100 <100

<100

<100

<100 <100 <100 <100 <100

<100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

Butyl- ate

<100 <100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

<100 <100

<100

<100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100 <100

<100

<100 <100 <100 <100 <100

<100 <100 <100

<100

<100 <100 <100 <100 <100

<100

<100

<100 <100 <100 <100 <100

<100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

Car- boxin

<100 <100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

<100 <100

<100

<100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100 <100

<100

<100 <100 <100 <100 <100

<100 <100 <100

<100

<100 <100 <100 <100 <100

<100

<100

<100 <100 <100 <100 <100

<100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

Cyan- azine

<100 <100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

<100 <100

67

<100 <100 <100 <100

<100

<100 <100 <100 <100

14

<100

30 <100 <100 <100 <100

<100 15

<100

<100 60

<100 <100 <100

<100 <100 <100

145

<100 <100 <100 <100 <100

<100

121

<100 <100 <100 <100 <100

<100 <100

12 <100

<100

100

<100

<100 <100

72 <100 <100

<100 <100

Cyclo- ate

<100 <100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

<100 <100

<100

<100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100 <100

<100

<100 <100 <100 <100 <100

<100 <100 <100

<100

<100 <100 <100 <100 <100

<100

<100

<100 <100 <100 <100 <100

<100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

Diphen- amid

<100 <100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

<100 <100

<100

<100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100 <100

<100

<100 <100 <100 <100 <100

<100 <100 <100

<100

<100 <100 <100 <100 <100

<100

<100

<100 <100 <100 <100 <100

<100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

Hexazi- none

<100 <100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 15

<100 <100

<100

<100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100 <100

<100

<100 30

<100 <100 <100

<100 90

<100

<100

<100 <100 <100 <100 <100

<100

<100

<100 <100 <100 <100 <100

<100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

Metola- chlor

<100 <100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

<100 <100

<100

<100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100 <100

<100

<100 <100 <100 <100 <100

<100 <100 <100

<100

<100 <100 <100 <100 <100

<100

<100

<100 <100 <100 <100 <100

<100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

Metri- buzin

<100 <100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

<100 <100

<100

<100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100 <100

<100

<100 <100 <100 <100 <100

<100 <100 <100

<100

<100 <100 <100 <100 <100

<100

<100

<100 <100 <100 <100 <100

<100 <100 <100 <100

42

<100

<100

<100 <100 <100 <100 <100

<100 <100

55

Table 21. Concentrations of triazine, acetamide, chloroacetanilide, and other pesticides in whole-water samples, Yakime River basin, Washington, 1988-89 Continued

Station number

12478300 12478300 12478300 12478300 12478300

12478300

12479500

12484100

12484480 12484480 12484480 12484480 12484480

12484480 12484480

12484500 12484500 12499000

12500430 12500430 12500430 12500430 12500430

12500430 12500430 12500430 12500430 12500430

12500430

12500445 12500445 12500445 12500445 12500445

12500445 12500445

12500450

12505460 12505460 12505460 12505460 12505460

12505460 12505460 12505460

12505510

12507508 12507508 12507508 12507508 12507508

12507508

12508620

12508850 12508850 12508850 12508850 12508850

12508850 12508850 12508850 12508850

12509050

12509710

12509829

12510500 12510500 12510500 12510500 12510500

12510500 12510500

Date

05-05-88 06-02-88 07-26-88 08-31-88 11-16-88

03-09-89

07-26-88

07-26-88

05-05-88 06-02-88 06-02-88 07-26-88 08-31-88

11-18-88 03-09-89

07-27-88 06-28-89 07-26-88

05-06-68 05-06-88 06-01-88 07-26-88 07-27-88

07-28-88 07-29-88 08-30-88 11-15-88 03-10-89

06-28-89

05-05-88 06-03-88 07-27-88 08-30-88 11-15-88

11-15-88 03-10-89

07-27-88

05-06-88 06-01-88 07-28-88 07-28-88 09-02-88

11-15-88 03-09-89 06-27-89

07-28-88

05-06-88 06-03-88 07-28-88 09-01-88 11-16-88

03-08-89

07-29-88

05-06-88 06-03-88 07-28-88 07-28-88 08-31-88

08-31-88 11-17-88 03-08-89 06-26-89

07-28-88

07-29-88

07-29-88

05-07-88 06-01-88 07-29-88 08-31-88 11-17-88

03-08-89 06-26-89

Prome- ton

<100 <100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

<100 <100 <100

<100 <100

30 <100 <100

<100 <100 <100 <100 <100

<100

<100 210 64 58

<100

<100 20

<100

<100 70

<100 <100 <100

<100 <100

50

<100

<100 <100 <100 <100 <100

<100

<100

<100 <100 <100 <100 <100

<100 <100

44 <100

<100

<100

<100

<100 50

<100 <100 <100

<100 <100

Prome- tryn

<100 <100 <100 <100 <100

<100

<100

<100

100 <100 <100 <100 <100

<100 <100

<100 <100 <100

<100 <100 <100 <100 <100

<100 <100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100 <100

<100

A A A A A »- »- -»»- *- o o o o o 00000

<100 <100 <100

<100

<100 <100 <100 <100 <100

<100

<100

<100 <100 <100 <100 <100

<100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

Propa- chlor

<100 <100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

<100 <100 <100

<100 <100 <100 <100 <100

<100 <100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100 <100

<100

<100 <100 <100 <100 <100

<100 <100 <100

<100

<100 <100 <100 <100 <100

<100

<100

<100 <100 <100 <100 <100

<100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

Pro- pazine

<100 <100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

<100 <100 <100

<100 <100 <100 <100 <100

<100 <100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100 <100

<100

<100 <100 <100 <100 <100

<100 <100 <100

<100

<100 <100 <100 <100 <100

<100

<100

<100 <100 <100 <100 <100

<100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

Sitna- zine

<100 <100 <100 <100 <100

<100

<100

41

90 <100

40 220 23

<100 6,600

57 <100

27

20 20 10 15 19

24 <100 <100 <100

18

<100

26 40 33 22

<100

<100 43

38

80 460 91

100 24

<100 100 170

40

<100 40 45 16

<100

11

29

120 60 74 68 29

24 <100

34 77

56

<100

22

40 20 49 17

<100

28

Sime- tryn

<100 <100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

<100 <100 <100

<100 <100 <100 <100 <100

<100 <100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100 <100

<100

<100 <100 <100 <100 <100

<100 <100 <100

<100

<100 <100 <100 <100 <100

<100

<100

<100 <100 <100 <100 <100

<100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

Ter- bacil

<100 <100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

<100 <100 <100

<100 <100 <100 <100 <100

<100 <100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100 <100

<100

<100 <100 <100 <100 <100

<100 <100 <100

<100

<100 <100 <100 <100 <100

<100

<100

<100 <100 <100 <100 <100

<100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

Tri- flura- lin

<100 <100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

<100 <100 <100

<100 <100 <100 <100 <100

<100 19

<100 <100 <100

<100

<100 <100 <100 <100 <100

<100 <100

<100

<100 70 55 42

<100

<100 <100 100

<100

<100 <100 <100 <100 <100

<100

<100

<100 <100 <100 <100 <100

<100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

Ver- nolete

<100 <100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

<100 <100 <100

<100 <100 <100 <100 <100

<100 <100 <100 <100 <100

<100

<100 <100 <100 <100 <100

<100 <100

<100

<100 <100 <100 <100 <100

<100 <100 <100

<100

<100 <100 <100 <100 <100

<100

<100

<100 <100 <100 <100 <100

<100 <100 <100 <100

<100

<100

<100

<100 <100 <100 <100 <100

<100 <100

56

Tabl

e 22.

Conc

entr

atio

ns of triazine,

acet

amid

e, chloroacetanilide, an

d tr

iflu

rome

thyl

comp

ound

s in fiItered-water sa

mple

s,Yakima Ri

ver

basin, Washington,

June

25-30, 19

89

[Con

cent

rati

ons

in n

anog

rams

pe

r liter; "T"

= present, but

below

quan

tifi

able

con

cent

rati

on;

"D"

= de

tect

ed a

nd n

ot qu

anti

fied

; "nd" =

not

dete

cted

and mi

nimu

m reporting

level

not

quan

tifi

ed;

"<"

= less than;

amet

ryn,

propachlor,

simetryn w

ere

not

dete

cted

; de

isop

ropy

latr

azin

e wa

s de

tect

ed a

nd

not

quantified a

t Gr

ange

r Dr

ain

and

Yakima R

iver

at

Ki

ona;

trace

concentrati9ns o

f prometryn

were d

etec

ted

at Sa

tus

Cree

k at

Satus, Sub

35 Dr

ain,

an

d Ma

rion

Drain;

trac

e co

ncen

trat

ions

of

metribuzin w

ere detected a

t Toppenish

and

Sulp

hur

Cree

ks,

and

in th

ree

addi

tion

al replicate

samp

les

coll

ecte

d fr

om Y

akima

Rive

r at

Ki

ona;

for

qual

ity

assu

ranc

e, th

ree

addi

tion

al replicate

samp

les

from

Yakima

cyan

azin

e, and

concentrations were 2

.4,

3.7, an

d 3.7

ng/L

; see

figure

1 for

site locations]

Map

reference

number 2 4 11 13 14 15 19 20 22 24 27 28 30 33 34 36 55 37 38 40 41 53 43 45 46 47 49 50 51

Statio

n number

12478200

1247

9500

1248

4100

12484480

12484500

12484550

12496510

12496511

1249

9000

12500430

12500445

12500450

12502500

12505350

12505410

1250

5460

4625

ID-

120323901

1250

5510

12507508

12507585

1250

7594

461720-

1200

43201

12508620

12508630

1250

8850

1250

9050

12509710

1250

9829

12510500

Stat

ion

name

Cooper Ri

ver

at Salmon L

aSac

Yakima Ri

ver

at Cl

e El ur

nWilson C

r ab

v. Ch

erry

Cre

ekCherry C

reek a

t Th

rall

Yakima Ri

ver

at Umtanum

Umta

num

Creek

nr m

outh

Pacific

Powe

r &

Ligh

t Company

Wasteway

City o

f Ya

kima

- Fi

nish

Wat

erNacnes R

iver nr

North

Yakima

Moxee Drain

at Thorp

Rd

Wide H

ollow

Cree

k ne

ar m

outh

Yakima R

abv Ahtanum

CrAhtanum

Creek

at Un

ion

Gap

E To

ppen

ish

Drain

at Wilson R

dSub

35 D

rain

at

Parton R

oad

Gran

ger

Drai

n at mouth

Well

2, Ha

rrah

. 11

N/18

E-22

R02

Mari

on D

rain

, In

dian

Chu

rch

RdToppenish

Cr,

Indi

an C

hurc

h Rd

Yakima Ri

ver

at RM

72

Satu

s Cr

abv

Wils

on- Ch

ar ley

Canyon n

r Toppenish

Alachlor

<0.99

<.52

<2.

1<1 .2

<1.6 <-42

<.50

<.64

<.39

<4.0

<2.0

<1 .5

<1 3

4.5

98 33 T<.6

420 16 11 <.

40

Well

1,

Sunnyside, 09N/22E-04P01

<.64

Satu

s Cr

at gage a

t Sa

tus

Sout

h Drain

nr Sa

tus

Sulp

hur

Cree

k Wasteway

Yakima R

at Euclid B

r at

RM

55

Spring C

reek

at

mouth

Snipes C

reek

at

mout

hYakima R

iver

at Kiona

13 17 33 19 <2.0

T<2.0

12

Atra

zine

T<1.

4 .27

27 71 10 <.77

<.17

<.88 .26

8.5

6.8

5.6

T<1.8

130 88 48 57 34 54 26 T<.56

18 46 130 49 61 13 12 32

Deet

hyl-

at

razi

ne

nd nd D 4.0

D nd nd nd nd D D D D D D D D D D 1.6

nd D D D D D D D D

Butachlor

<1 4

T<!81

<3.0

<2'.

5

<.89

<.79

<.93

<.69

<7.1

<2.8

T<2.

4<2

.3<2.9

T<2.8

<6.4 <.93

<2.8

<2.2

<1.1 <.71

<.92

<2.9

<7.2

<24 <2.3

<2.9

<2.8

<2.5

Cyanazine

<1 9

<!S5

<4.0

<1 .9

<1.7 <.94

<.54

<1 2

<.36

<3.7

<3.8

<1 2

<3.8

<3.8 8.6

<1 2

<3i8

<1 .

1<1.8 <.37

<1 2

<3.8

<3.7

T<31 T<1.

2<3

.9<3.8

<6.5

Metola-

chlo

r

<0.9

1<.

42<1

.9

< 7

T<1.

3

<.25

<.41

<.59

T<.30

<3.1

<1 8

T<K2

<1 .0

<1 .8

<1.8

T<2.

8

<.59

3.6

2.2 .93

<.31

<.59

4.1

6.0

T<15

1.3

<1 .8

T<1.

81.

9

Rive

r at

Prom

eton

<1 2

<!27

7.8

1.4

1.1

<.58

<.26

< 81

T<.2

63.8

22 1.4

3.0

T<2.

5T<

2.5

32 T<.8

1T<

2.5

2.7

2.4

<-27

<-80

<2.5

T<2.

726 5.

2<2

.5T<

2.5

3.0

Kion

a were

Propazine

<1.1 < 12

<2.3 < 8

T<,3

9

<.56

<.12

<.72

<.35

<3.6

<2.2 <.37

<1

1<2

.2<2

.2

<3.2 <.72

<2.2

T<1

.1<.78

<-36

< 71

<2.2

T<3.6

<18 <1 2

<2.2

<2.2 .4

7

anal

yzed

Simazine

<1 4 !25

4.2

11 2.2

<.67

<.19

<.88 .24

<3.6 7.1

3.9

6.7

14 17 130 6.4

21 43 16 <.36

1.9

27 <3.6

81 33 10 6.4

18

for Tr

iflu

r-

alin <2.0

<1 .2

<4

1T<

3.0

T<3.

8

<1.3

<1 .2

<1 .3

<1 3

T<14 <3

.9T<3.6

<4.4

T<4.

0T<3.9

28 <1 3

7^1

T<4.

23.1

<1.4

<1 3

7.3

T<14

T<32 T<4.

5T<

4.0

T<3.9

T<3.8

Table 23. Concentrations of volatile organic compounds (halogenated aliphatic and monocyclic aromatic hydrocarbons) inwhole-water samples, Yakima River basin, Washington, 1988-89

[Concentrations in nanograms per liter; " " = not analyzed; "<" = less than; see figure 1 for site locations]

Map reference number Station number

19 12496510

20 12496511

24 12500430

27 12500445 27 12500445 27 12500445 27 12500445

36 12505460

46 12508850

51 12510500

Station name

Pacific Power & Light Company Wasteway

City of Yakima-Finish Water


Wide Hollow Creek near mouth at Union Gap Wide Hollow Creek near mouth at Union Gap Wide Hollow Creek near mouth at Union Gap Wide Hollow Creek near mouth at Union Gap

Granger Drain at mouth nr Granger

Sulphur Cr Wasteway nr Sunnyside Sulphur Cr Wasteway nr Sunnyside


Date

07-01-89

07-01-89

08-30-88

08-30-88 11-15-88 11-15-88 03-10-89

09-02-88

08-31-88 08-31-88

08-31-88

Time

1400

1405

1730

1430 1330 1430 1400

1000

1530 1630

1000

Benzene

<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200

<200

Bromo- benzene

<200

<200 <200 <200 <200

<200

<200 <200

<200

Station number

12496510

12496511

12500430

12500445 12500445 12500445 12500445

12505460

12508850 12508850

12510500

Date

07-01-89

07-01-89

08-30-88

08-30-88 11-15-88 11-15-88 03-10-89

09-02-88

08-31-88 08-31-88

08-31-88

Broroodi- chloro- methane

<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200

<200

Bromo- form

<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200

<200

Bromo- methane

<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200

<200

Carbon tetra- chlo- ride

<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200

<200

Chloro- benzene

<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200

<200

Chloro- ethane

<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200

<200

2- Chloro- ethyl- vinyl ether

<3,000

<3,000

Chloro form

<3,000

22,000

<200

<200 <200 <200 <200

<200

<200 <200

<200

Chloro- me thane

<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200

<200

Station number

12496510

12496511

12500430

12500445 12500445 12500445 12500445

12505460

12508850 12508850

Date

07-01-89

07-01-89

08-30-88

08-30-88 11-15-88 11-15-88 03-10-89

09-02-88

08-31-88 08-31-88

1,2- Chloro- toluene

~

<200

<200 <200 <200 <200

<200

<200 <200

1,4- Chloro- toluene

~

<200

<200 <200 <200 <200

<200

<200 <200

cis- 1,3-Di- chloro- propene

<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200

Dibromo- chlorome thane

<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200

1,2- Dibromo- ethane

<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200

Dibromo- me thane

<200

<200 <200 <200 <200

<200

<200 <200

1,2-Di- chloro- benzene

<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200


<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200


<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200

12510500 08-31-88 <200 <200 <200 <200 <200 <200 <200 <200 <200

58

Table 23. Concentrations of volatile organic compounds (halogenated aliphatic and monocyclic aromatic hydrocarbons) in whole-water samples, Yakima River basin, Washington, 1988-89 Continued

Station number

12496510

12496511

12500430

12500445 12500445 12500445 12500445

12505460

12508850 12508850

12510500

Station number

12496510

12496511

12500430

12500445 12500445 12500445 12500445

12505460

12508850 12508850

12510500

Station number

12496510

12496511

12500430

12500445 12500445 12500445 12500445

12505460

12508850 12508850

Date

07-01-89

07-01-89

08-30-88

08-30-88 11-15-88 11-15-88 03-10-89

09-02-88

08-31-88 08-31-88

08-31-88

Date

07-01-89

07-01-89

08-30-88

08-30-88 11-15-88 11-15-88 03-10-89

09-02-88

08-31-88 08-31-88

08-31-88

Date

07-01-89

07-01-89

08-30-88

08-30-88 11-15-88 11-15-88 03-10-89

09-02-88

08-31-88 08-31-88

Dichloro- difluoro- methane

<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200

<200

1,3-Di- chloro- propene

<3,000

<3,000

trans- 1,3-Di- chloro- propene

<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200

1,1-Di- chloro- e thane

<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200

<200

Ethyl- I benzene

<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200

<200

1,2,4- Tri- chloro- benzene

<5,000

__

1,2-Di- chloroethane

<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200

<200

tethylene chloride

<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200

<200

1,1,1- Tri- chloroethane

<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200

1,1-Di- chloro- ethene

<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200

<200

Styrene

<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200

<200

1,1,2- Tri- chloro- e thane

<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200


<200

<200 <200 <200 <200

<200

<200 <200

<200

1,1,1,2-Tetra- chloroethane

<200

<200 <200 <200 <200

<200

<200 <200

<200

Tri- chloro- ethene

<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200

1,2-Di- chloro- propane

<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200

<200

- 1,1,2,2-Tetra- chloro- e thane

<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200

<200

Tri- chloro- fluoro- me thane

<3,000

<3,000

<200

<200 <200 <200 <200

<200

900 <200


<200

<200 <200 <200 <200

<200

<200 <200

<200

Tetra- chloro- ethene

<3,000

<3,000

<200

200 300 300 200

<200

<200 <200

<200

1,2,3- Tri- chloro- propane

<200

<200 <200 <200 <200

<200

<200 <200


<200

<200 <200 <200 <200

<200

<200 <200

<200

Toluene

<3,000

<3,000

<200

<200 <200 <200 <200

<200

<200 <200

<200

Vinyl chloride

<1,000

<1,000

<200

<200 <200 <200 <200

<200

<200 <200

1,1-Di- chloro- propene

<200

<200 <200 <200 <200

<200

<200 <200

<200


<3,000

<3,000

--

Xylene

<3,000

<3,000

<200

A A A A MMM M OO O O OO O O

<200

<200 <200

12510500 08-31-88 <200 <200 <200 <200 <200 <200 <200 <200

59

Table 24. Concentrations of organochlorine compounds, total carbon, and inorganic carbon in bed-sediment and soil ssimples,Yakima River basin, Washington, 1987-90

[gm = gram; kg = kilogram; /on = microgram; "n" = soil sample was not sieved; "--" -= not analyzed; "#" * <62 micrometer data collected during trace element study on a different sample and day; "@" site receives drainage from apple orchard(s); "<" = less than; DDD = dichlorodiphenyldichloroethane; DDE = dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyltrichloroethane; PCB = gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes; C = Carbon; see figure 1 for site locations]

Map reference number Station number Station name Date Time

Parti cle size finer than, micro meters

Carbon, inor ganic + organic (gm/kg as C)

Carbon, inor ganic , (gm/kg Aldrin as C) (pg/kg)

Bed sediment

35678

910131314

1516171824

2425272728

2931313636

3838424446

4646465151

5252

5454

62

6363

5656

5757

1247830012479720124797501248000012481900

1248319012483750124844801248448012484500

1248455012487200124882501248910012500430

1250043012500437125004451250044512500450

1250090012503640125036401250546012505460

1250750812507508125085001250862512508850

1250885012508850125088501251050012510500

6165211952200061652119522000

6174411952240061744119522400

63359120281400

6350112035330063501120353300

463202120223600463202120223600

463232120234900463232120234900

Cle Elum R above Cle Elum Lake nr RoslynJungle Creek nr mouth nr Cle ElumNo Fk Teanaway R blw bridge at Dickey Cr CampgrndTeanaway River below forks near Cle ElumTaneum Cr at Taneum Meadow nr Thorp

South Fork Manastash Cr nr EllensburgNaneum Cr blw High Cr nr EllensburgCherry Creek at ThrallCherry Creek at ThrallYakima River at Umtanum

Umtanum Creek nr mouth at UmtanumLittle Naches River at mouth nr CliffdellAmerican River at Hells Crossing nr NileRattlesnake Cr abv N.F. Rattlesnake Cr nr NileMoxee Drain at Thorp Rd nr Union Gap

Moxee Drain at Thorp Rd nr Union GapWide Hollow Cr at W. Valley School nr AhtanumWide Hollow Creek near mouth at Union GapWide Hollow Creek near mouth at Union GapYakima R abv Ahtanum Cr at Union Gap

S. F. Ahtanum Cr abv Conrad Rnch nr Tampico@ Unnamed drain at Lateral & Riggs Rds nr WapatoUnnamed drain at Lateral & Riggs Rds nr WapatoGranger Drain at mouth nr GrangerGranger Drain at mouth nr Granger

Toppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerSatus Cr below Dry Cr near ToppenishYakima R blw Satus Cr at RM 68 nr SatusSulphur Cr Wasteway nr Sunnyside

Sulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideYakima River at KionaYakima River at Kiona

@ Unnamed drain at County Line Rd nr GrandviewUnnamed drain at County Line Rd nr Grandview

g Unnamed drain to E Turbine Lateral nr GrandviewUnnamed drain to E Turbine Lateral nr Grandview

Unnamed urban runoff at Union Gap

@ Wide Hollow Cr at Ahtanum Blvd nr AhtanumWide Hollow Cr at Ahtanum Blvd nr Ahtanum

Apple composite from 5 ditchesAsparagus composite from 5 ditchesCorn- -composite from 5 ditchesGrape composite from 4 ditchesHops composite from 5 ditches

Pear composite from 4 ditchesPotato composite from 5 ditches

Apple orchard nr Moxee City, A Horizon, 0-6 in.Apple orchard nr Moxee City, B Horizon, 6-9 in.

Hop field near Moxee City, A Horizon, 0-9 in.Hop field near Moxee City, B Horizon, 9-12 in.

08-31-8805-02-8911-03-9011-06-8911-03-90

11-02-9011-02-9008-31-8808-31-8805-04-89

05-03-8910-30-9011-07-8911-07-8908-30-88

08-30-8805-01-8908-30-8808-30-8809-16-87

11-06-9009-01-8809-01-8809-02-8809-02-88

09-01-8809-01-8811-07-9009-15-8708-31-88

08-31-8808-31-8808-31-8808-31-8808-31-88

09-01-8809-01-88

09-01-8809-01-88

08-28-87

09-01-8809-01-88

08-27-8709-16-8708-27-8711-30-8709-16-87

11-30-8709-18-87

07-01-8907-01-89

07-01-8907-01-89

10301230141509100815

08151330163016351100

09450905120012001730

17351430143014351631

08100800080510001005

09300935092012011530

15351630163510001005

11001105

09000905

1001

10001005

22451600211512001630

13001015

10001005

09000905

2,0002,000

622,000

62

6262

2,00062

2,000

2,00062

2,0002,0002,000

622,0002,000

62180

622,000

622,000

62

2,0006262

1802,000

622,000

622,000

62

2,00062

2,00062

180

2,00062

180180180180180

180180

nn

nn

2.24--

2.6 #4.7 #

3.0 #9.2 #

101016

104.1 #3.8 #3.3 #

12

112427292.1 #

5.2 #9.99.14.98.6

17271.2 #1.6 #9.5

9.35.162.4

18

4.914

1834

-

2222

---- --

--

145.2

166.2

0.4.1--

<.l #<.l #

<.l #<.l #.3.4

<.l

.1<.l #<-l #<-l #.1

.2<.l<.l.1

<.l # <

<.l #1.21.4.8

1.3

<.l<.l<.l #<.l # <1

1.1.8

1.5.1

<.l

< .1.1

<.l<.l

- <

.1

.1

<-- <

<<<

<.l<.l

<.l<.l

<0.1<. 1<. 5<. 1< - 5

<.5<. 5<. 1<. 1< - 1

<.l<. 5<. 1<. 1< - 1

<.l<. 1<. 1.4

10

<.5.4.2

<. 1< - 1

<.l<. 1<.5

10< - 1

<.l<. 1<. 1<. 1< - 1

<.l< - 1

<.l< - 1

10

<.l< - 1

10:10'10:1010

1010

<.l< - 1

<.l<.l

60 463247120222300 Hop field nr Moxee City, A Horizon, 1-10 in. 07-01-89 1100 14

60

Table 24. Concentrations of organochlorine compounds, total carbon, and inorganic carbon in bed-sediment and soil samples, Yakima River basin, Washington, 1987-90 Continued

Station number

Gross chlor- Di- P.P'~ dane eldrin ODD

Date (Mg/kg) (Mg/kg) (Mg/kg)

Hepta- p,p'- P,P'~ Endo- Hepta- chlor DDE DOT sulfan I Endrin chlor epoxide (Mg/kg) (Mg/kg) (Mg/kg) (w/kg) (pg/kg) (Mg/kg)

Bed sediment

1247830012479720124797501248000012481900

1248319012483750124844801248448012484500

1248455012487200124882501248910012500430

1250043012500437125004451250044512500450

1250090012503640125036401250546012505460

1250750812507508125085001250862512508850

1250885012508850125088501251050012510500

461652119522000461652119522000

461744119522400461744119522400

463359120281400

463501120353300463501120353300

Apple composite from 5 ditches

08-31-8805-02-8911-03-9011-06-8911-03-90

11-02-9011-02-9008-31-8808-31-8805-04-89

05-03-8910-30-9011-07-8911-07-8908-30-88

08-30-8805-01-8908-30-8808-30-8809-16-87

11-06-9009-01-8809-01-8809-02-8809-02-88

09-01-8809-01-8811-07-9009-15-8708-31-88

08-31-8808-31-8808-31-8808-31-8808-31-88

09-01-8809-01-88

09-01-8809-01-88

08-28-87

09-01-8809-01-88

08-27-87

<!<1<5<1<5

<5<59

10<1

<!<5<1<1<1

3<10<115

<10

<5<1<1<1<1

1<1<5

<10<1

<!44

<15

<!<1

<!<1

<10

<!<1

<10

<0.1.1.5.1.5

.5

.535391

<.l<.5<.l<.l1.7

1.213.23

<10

<.534471.83.5

.5

.5<.5

<105.6

53.44.4.2

1.3

1531

13.6

<10

2413

<10

<0.1<_ i!i<. i.1.2.2

9.3131

< !\Z.1

<, 123

183828<. 1

<10

.743512316

2.89.5.1

<1013

26101512.7

4880

4.529

<10

48440

130

<0.1<.l.3

<.l.3

.4

.530283

.4

.2

.1

.191

651604416

<10

.54701804760

1623

.815<.l

7433423

10

220160

.94.4

<10

17001400

480

<0.1<.l.1

<.l<.5

<.5.1

15281

<.l.1

<.l<.l15

8.5118.9<.l

<10

.229

160277.6

<.l2.6<.5

<10.8

1389.9.3

<.l

6614

6.110

<10

370180

72

<0

11

7<

213

<10

<<92*

<2<

<10*

711<<

6167

1968

<10

<71

17

11515

55111

1511

41

3

51251

165

1

99911

1

<0.1<.l<.5<.l<.5

<.5<.5.2.2

<.l

<.l<.5<.l<.l.4

.1

.5

.6<.l

<10

<.5<.l<.l<.l<.l

<.l<.l<.5

<10<.l

<.l<.l<.l<.l<.l

.1<.l

5.317

<10

<.l3.5

<10

<0.1<.l.1

<.l.1

.1

.1<.l<.l<.l

<.l.1

<.l<.l<.l

<.l<.l<.l<.l

<10

.1<.l<.l<.l<.l<.l<.l<.5

<10<.l

<.l<.l<.l<.l<.l

<.l<.l

<.l<.l

<10

<.l<.l

<10

<0.1<_ 1<.5<. i<-5

< 5<,5!i.2

< !

<.!<.5<. i<. i.2

.1<. 1<. 1<. 1

<10

<.5i!a2.5<. 1< - 1

<.l<. 1<.5

<10< - 1

<.l<. 1.1

<. 1< - 1

.1< - 1

<.l< - 1

<10

<.l< - 1

<10Asparagus composite from 5 ditches 09-16-87 <10Corn composite from 5 ditches 08-27-87 33Grape composite from 4 ditches 11-30-87 <10Hops composite from 5 ditches 09-16-87 <10

Pear composite from 4 ditches 11-30-87 <10Potato composite from 5 ditches 09-18-87 <10

463202120223600 07-01-89 <1463202120223600 07-01-89 <1

463232120234900 07-01-89 4463232120234900 07-01-89 1

463247120222300 07-01-89 2

38

.1

11

8918

563.5

171.4

25

70

18064

68045

16029

140

65058

14022

310 :.l

:.l :.l

:.l

61

Table 24. Concentrations of organochlorine compounds, total carbon, and inorganic carbon in bed-sediment and soil samples, Yakima River basin, Washington, 1987-90--Continued

Station number Date

p.p'-Meth-oxy- Per- Toxa-

Lindane chlor Mirex PCB PCN thane phene (Mg/kg) (/xg/kg) (fig/kg) (/ig/kg) (/ig/kg) (fig/kg)

12478300 12479720 12479750 12480000 12481900

12483190 12483750 1248448012484480 12484500

12484550 12487200 12488250 12489100 12500430

12500437 12500445 12500445 12500450 12500900

12503640 12503640 12505460 12505460 12507508

12507508 12508500 12508625 12508850 12508850

12508850 12508850 12510500 12510500

461652119522000 461652119522000

461744119522400 461744119522400

463359120281400

463501120353300 463501120353300

Apple composite from 5 ditches Asparagus composite from 5 ditches Corn composite from 5 ditches Grape composite from 4 ditches Hops- -composite from 5 ditches

Pear composite from 4 ditches Potato composite from 5 ditches

463202120223600 463202120223600

463232120234900 463232120234900

Bed sediment

08-31-88 <0.1 <0.1 <0 . 1 05-02-89 <.l <.l <.l 11-03-90 <.5 <.5 <.5 11-06-89 <.l <.l <.l 11-03-90 <.5 <.5 <.5

11-02-90 <.5 <.5 <.5 11-02-90 <.5 <.5 <.5 08-31-88 <.l <.l <.l

05-04-89 <.l <.l <.l

05-03-89 <.l <.l <.l 10-30-90 <.5 <.5 <.5 11-07-89 <.l <1 <.l 11-07-89 <.l <.l <.l 08-30-88 <.l <.l <.l

08-30-88 <.l <.l <.l 05-01-89 <.l <.l <.l 08-30-88 <.l <.l <.l 08-30-88 <.l .6 <.l 09-16-87 <10 <10 <10 11-06-90 <.5 <.5 <.5

09-01-88 <.l <.l <.l 09-01-88 <.l 2.1 <.l 09-02-88 <.l <.l <.l 09-02-88 <.l .8 <.l 09-01-88 <.l <.l <.l

09-01-88 <.l <.l <.l 11-07-90 <.5 <.5 <.5 09-15-87 <10 <10 <10 08-31-88 <.l <.l <.l 08-31-88 <.l <.l <.l

08-31-88 <.l <.l <.l 08-31-88 <.l <.l <.l 08-31-88 <.l <.l <.l 08-31-88 <.l <.l <.l

09-01-88 <.l <.l <. 09-01-88 <.l 3.2 <.

09-01-88 .3 <.l <. 09-01-88 .8 <.l <.

08-27-87 <10 <10 <10

09-01-88 <.l <.l <. 09-01-88 <.l <.l <.

08-27-87 <10 <10 <10 09-16-87 <10 <10 <10 08-27-87 <10 <10 <10 11-30-87 <10 <10 <10 09-16-87 <10 <10 <10

11-30-87 <10 <10 <10 09-18-87 <10 <10 <10

07-01-89 <.l <.l <. 07-01-89 <.l <.l <.

07-01-89 <.l <.l <. 07-01-89 <.l <.l <.

i <5 <5

' <5 <5

<5 <5 <5 <5

<1 <1

<5 <5

<700 <100 <5 <5

1 1

<5 <5<700 <100

a ai a ai a a

<700

i a a<700 <100 <700 <100 <700 <100 <700 <100 <700 <100

<700 <100 <700 <100

i a <J} :} a

<5 <50

<5 <50

<5 <50 <5 <50

3 <io

<5 <50

<1 < 10

2 < 10

<10 <500 <5 <50

3 a?

<5 <50<10 <500

<1 <10

<} <iSa a?

<10 <500

3 a?

<10 <500 <10 <500 <10 <500 <10 <500 <10 <500

<10 <500 <10 <500

3 a?

a <io463247120222300 07-01-89 <1 <1 <1

62

Table 25. Concentrations of organophosphorus pesticides in soil samples, Yakima River basin, Washington, 1989

[Concentrations in micrograms per kilogram; "<" * less than; see figure 1 for site locations]

Map refer ence

Methyl Methyl Diaz- Mala- para- tri- Para- Tri-

number Station number

56 463202120223600

57 463232120234900

60 463247120222300

Stetion name

Apple orchard nr Moxee City, A Horizon, 0-6 inches

Apple orchard nr Moxee City, B Horizon, 6-9 inches

Hop field near Moxee City, A Horizon, 0-9 inches

Hop field near Moxee City, B Horizon, 9-12 inches

Hop field nr Moxee City A Horizon, 1-10 inches

Date

07-01-89

07-01-89

07-01-89

07-01-89

07-01-89

Time inon

1000 1.5

1005 .2

0900 4.1

0905 .2

1100 530

Ethion thion thion

<0.1 <0.1 <0.1

<.l <.l <.l

<.l <.l <.l

<.l <.l <.l

.1 <.l <.l

thion thion thion

<0. 1 2.0 <0. 1

<.l .3 <.l

<.l .4 <.l

<.l <.l <.l

<.l .6 <.l

Table 26. Concentrations of semi-volatile organic compounds (phthalate esters, ethers, phenols, cresols, and monocyclic- and polycyclic-aromatic compounds) in bed-sediment samples, Yakima River basin, Washington, 1987-90

[Concentrations in micrograms per kilogram; "E" « estimated value; "<" = less than; see figure 1 for site locations; the typical minimum reporting level for these compounds is 200, 400, or 600 micrograms per kiliogram however, the analyst is able to quantify smaller concentrations when the background analytical noise is small]

Mapreferencenumber

1357

13

1314141517

1824242527

2728313136

3638384446

4646464951

5151525254

54626363

Particle size finer than,

Station number

1247810012478300124797201248000012484480

1248448012484500124845001248455012488250

1248910012500430125004301250043712500445

1250044512500450125036401250364012505460

1250546012507508125075081250862512508850

1250885012508850125088501250971012510500

1251050012510500

461652119522000461652119522000461744119522400

461744119522400463359120281400463501120353300463501120353300

Station name

Waptus River at mouth nr RoslynCle Elum R above Cle Elum Lake nr RoslynJungle Creek nr mouth nr Cle ElumTeaneway River below forks near Cle ElumCherry Creek et Thrall

Cherry Creek at ThrallYakima River at UmtanumYakima River at UmtanumUmtanum Creek nr mouth at UmtanumAmerican River at Hells Crossing nr Nile

Rattlesnake Cr abv N.F. Rattlesnake Cr nr NileMoxee Drain at Thorp Rd nr Union GapMoxee Drain at Thorp Rd nr Union GapWide Hollow Cr at W. Valley School nr AhtanumWide Hollow Creek near mouth at Union Gap

Wide Hollow Creek near mouth at Union GapYakima R abv Ahtanum Cr at Union GapUnnamed drain at Lateral & Riggs Rds nr WapatoUnnamed drain at Lateral & Riggs Rds nr WapatoGranger Drain at mouth nr Granger

Granger Drain at mouth nr GrangerToppenish Cr at Indian Church Rd nr GrangerToppenish Cr at Indian Church Rd nr GrangerYakima R blw Satus Cr at RM 68 nr SatusSulphur Cr Wasteway nr Sunny side

Sulphur Cr Wasteway nr SunnyaideSulphur Cr Wasteway nr SunnysideSulphur Cr Wasteway nr SunnysideSpring Creek at mouth at WhitstranYakima River at Kiona

Yakima River et KionaYakima River at KionaUnnamed drain et County Line Rd nr GrandviewUnnamed drain at County Line Rd nr GrandviewUnnamed drain to E Turbine Laterel nr Grandview

Unnamed drain to E Turbine Lateral nr GrandviewUnnamed urban runoff at Union GapWide Hollow Cr at Ahtanum Blvd nr AhtanumWide Hollow Cr at Ahtanum Blvd nr Ahtanum

Apple composite from 5 ditchesAsparagus composite from 5 ditchesCorn composite from 5 ditchesGrape- -composite from 4 ditchesHops composite from 5 ditches


Date

11-06-8908-31-8805-02-8911-06-8908-31-88

08-31-8805-04-8911-05-9005-03-8911-07-89

11-07-8908-30-8808-30-8805-01-8908-30-88

08-30-8809-16-8709-01-8809-01-8809-02-88

09-02-8809-01-8809-01-8809-15-8708-31-88

08-31-8808-31-8808-31-8811-08-9008-31-88

08-31-8811-10-9009-01-8809-01-8809-01-88

09-01-8808-28-8709-01-8809-01-88

08-27-8709-16-8708-27-8711-30-8709-16-87

11-30-8709-18-87

Time

12151030123009101630

16351100133009451200

12001730173514301430

14351630080008051000

10050930093512001530

15351630163513301000

10050940110011050900

0905100010001005

22451600211512001630

13001015

micrometers

2,0002,0002,0002,0002,000

622,000

622,0002,000

2,0002,000

622,0002,000

62180

2,00062

2,000

622,000

62180

2,000

622,000

6262

2,000

6262

2,00062

2,000

62180

2,00062

180180180180180

180180

Iso-phorone

<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200110

<200

<200<200<200<200<200

<200<200

2-Chloro-naph-thalene

<400<200<200 .<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200

<200<200<200<200<200

<200<200

63

Table 26. Concentrations of semi-volatile organic compounds (phthalate esters, etheres, phenols, cresols, and monocyclic- and polycyclic-aromatic compounds) in bed-sediment samples, Yakima River basin, Washington, 1987-90 Continued

Station number

1247810012478300124797201248000012484480

1248448012484500124845001248455012488250

1248910012500430125004301250043712500445

1250044512500450125036401250364012505460

1250546012507508125075081250862512508850

1250885012508850125088501250971012510500

1251050012510500

461652119522000461652119522000461744119522400

461744119522400463359120281400463501120353300463501120353300

Apple composite from 5 ditchesAsparagus composite from 5 ditchesCorn composite from 5 ditchesGrape composite from 4 ditchesHops composite from 5 ditches


Date

11-06-8908-31-8805-02-8911-06-8908-31-88

08-31-8805-04-8911-05-9005-03-8911-07-89

11-07-8908-30-8808-30-8805-01-8908-30-88

08-30-8809-16-8709-01-8809-01-8809-02-88

09-02-8809-01-8809-01-8809-15-8708-31-88

08-31-8808-31-8808-31-8811-08-9008-31-88

08-31-8811-10-9009-01-8809-01-8809-01-88

09-01-8808-28-8709-01-8809-01-88

08-27-8709-16-8708-27-8711-30-8709-16-87

11-30-8709-18-87

Hexa- chloro- but- adiene

<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200

<200<200<200<200<200

<200<200

Hexa- chloro- cyclo- pent- adiene

<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200

<200<200<200<200<200

<200<200

Hexa- chloroethane

<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200

<200<200<200<200<200

<200<200

bis(2- Chloro- ethoxy) methane

<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200

<200<200<200<200<200

<200<200

bis(2- Chloro- ethyl) ether

<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200160

<200

<200<200<200<200<200

<200<200

bis(2- Chloro- iso- propyl) ether

<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200120

<200

<200<200<200<200<200

<200<200

4- Bromo- phenyl phenyl ether

<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200

<200<200<200<200<200

<200<200

4- Chloro- phenyl phenyl ether

<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200

<200<200<200<200<200

<200<200


<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200

<200<200<200<200<200

<200<200

64

Table 26. Concentrations of semi-volatile organic compounds (phthalate esters, ethers, phenols, cresols, and monocyclic- and polycyclic-aromatic compounds) in bed-sediment samples, Yakima River basin, Washington, 1987-90 Continued

Station number

1247810012478300124797201248000012484480

1248448012484500124845001248455012488250

1248910012500430125004301250043712500445

1250044512500450125036401250364012505460

1250750812507508125075081250862512508850

1250885012508850125088501250971012510500

1251050012510500

461652119522000461652119522000461744119522400

461744119522400463359120281400463501120353300463501120353300

Apple composite from 5 ditchesAsparagus composite from 5 ditchesCorn~-composite from 5 ditchesGrape composite from 4 ditchesHops composite from 5 ditches

Pear--composite from 4 ditchesPotato composite from 5 ditches

Date

11-06-8908-31-8805-02-8911-06-8908-31-88

08-31-8805-04-8911-05-9005-03-8911-07-89

11-07-8908-30-8808-30-8805-01-8908-30-88

08-30-8809-16-8709-01-8809-01-8809-02-88

09-02-8809-01-8809-01-8809-15-8708-31-88

08-31-8808-31-8808-31-8811-08-9008-31-88

08-31-8811-10-9009-01-8809-01-8809-01-88

09-01-8808-28-8709-01-8809-01-88

08-27-8709-16-8708-27-8711-30-8709-16-87

11-30-8709-18-87


<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200

<200<200<200<200<200

<200<200


<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200

<200<200<200<200<200

<200<200

2.4-Di- nitro- toluene

<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200

<200<200<200<200<200

<200<200

2,6-Di- nitro- toluene

<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200160

<200

<200<200<200<200<200

<200<200

Hexa- chloro- benzene

<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200

<200<200<200<200<200

<200<200

Nitro benzene

<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200120

<200

<200<200<200<200<200

<200<200

1,2,4- Tri- chloro- benzene

<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200

<200<200<200<200<200

<200<200

2- Chloro- phenol

<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200

<200<200<200<200<200

<200<200

2,4-Di- chlorophenol

<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200

<200<200<200<200<200

<200<200

65

Table 26. Concentrations of semi-volatile organic compounds (phthalate esters, ethers, phenols, cresols, and monocyclic- and polyeyelie-aromatic compounds) in bed-sediment samples, Yakima River basin, Washington, 1987-90 Continued

Station number

1247810012478300124797201248000012484480

1248448012484500124845001248455012488250

1248910012500430125004301250043712500445

1250044512500450125036401250364012505460

1250546012507508125075081250862512508850

1250885012508850125088501250971012510500

1251050012510500

461652119522000461652119522000461744119522400461744119522400463359120281400

463501120353300463501120353300

Apple composite from 5 ditchesAsparagus composites from 5 ditchesCorn composite from 5 ditchesGrape composite from 4 ditchesHops composite from 5 ditches


Date

11-06-8908-31-8805-02-8911-06-8908-31-88

08-31-8805-04-8911-05-9005-03-8911-07-89

11-07-8908-30-8808-30-8805-01-8908-30-88

08-30-8809-16-8709-01-8809-01-8809-02-88

09-02-8809-01-8809-01-8809-15-8708-31-88

08-31-8808-31-8808-31-8811-08-9008-31-88

08-31-8811-10-90

09-01-8809-01-8809-01-8809-01-8808-28-87

09-01-8809-01-88

08-27-8709-16-8708-27-8711-30-8709-16-87

11-30-8709-18-87

2,4-Di- methyl- phenol

<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200

<200<200<200<200<200

<200<200

<200<200<200<200<200

<200<200

4,6- Dinitro- ortho- cresol

<1,200<600<600<600<600

<600<600<600<600<600

<600<600<600<600<600

<600<600<600<600<600

<600<600<600<600<600

<600<600<600<600<600

<600<600

<600<600<600<600<600

<600<600

<600<600<600<600<600

<600<600

2,4- Di- nitrophenol

<1,200<600<600<600<600

<600<600<600<600<600

<600<600<600<600<600

<600<600<600<600<600

<600<600<600<600<600

<600<600<600<600<600

<600<600

<600<600<600<600<600

<600<600

<600<600<600<600<600

<600<600

2- Nitro- phenol

<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200

<200<200<200<200<200

<200<200

<200<200<200<200<200

<200<200

4- Nitro- phenol

<1,200<600<600<600<600

<600<600<600<600<600

<600<600<600<600<600

<600<600<600<600<600

<600<600<600<600<600

<600<600<600<600<600

<600<600

<600<600<600<600<600

250<600

<600<600<600<600<600

<600<600

P~ Chloro- m-cresol

<1,200<600<600<600<600

<600<600<600<600<600

<600<600<600<600<600

<600<600<600<600<600

<600<600<600<600<600

<600<600<600<600<600

<600<600

<600<600<600<600<600

<600<600

<600<600<600<600<600

<600<600

Penta- chlorophenol

<1,200<600<600<600<600

<600<600<600<600<600

<600<600<600<600<600

<600<600<600<600<600

<600<600<600<600<600

<600<600<600<600<600

<600<600

<600<600<600<600<500

<600<600

<600<600<600<600<600

<600<600

Phenol (C6H- 50H)

<400<200<200<200110

110870

<200230

<200

<200110

<200<200<200

<200<200

3<200<200

<200<200<200<200<200

<200110110

<200<200

6335

<200<200110110

<200

130310

120<200170

<200<200

<200<200

2,4,6- Tri- chlorophenol

<1,200<600<600<600<600

<600<600<600<600<600

<600<600<600<600<600

<600<600<600<600<600

<600<600<600<600<600

<600<600<600<600<600

<600<600

<600<600<600<600<600

<600<600

<600<600<600<600<600

<600<600

66

Table 26. Concentrations of semi-volatile organic compounds (phthalate esters, ethers, phenols, cresols, and monocyclic- and polyeyelie-aromatic compounds) in bed-sediment samples, Yakima River basin, Washington, 1987-90 Continued

Station number

1247810012478300124797201248000012484480

1248448012484500124845001248455012488250

1248910012500430125004301250043712500445

1250044512500450125036401250364012505460

1250750812507508125075081250862512508850

1250885012508850125088501250971012510500

1251050012510500

461652119522000461652119522000461744119522400

461744119522400463359120281400463501120353300463501120353300



Date

11-06-8908-31-8805-02-8911-06-8908-31-88

08-31-8805-04-8911-05-9005-03-8911-07-89

11-07-8908-30-8808-30-8805-01-8908-30-88

08-30-8809-16-8709-01-8809-01-8809-02-88

09-02-8809-01-8809-01-8809-15-8708-31-88

08-31-8808-31-8808-31-8811-08-9008-31-88

08-31-8811-10-9009-01-8809-01-8809-01-88

09-01-8808-28-8709-01-8809-01-88

08-27-8709-16-8708-27-8711-30-8709-16-87

11-30-8709-18-87

bis (2- Ethyl- hexyl) phthal ate

E800<200240

<2002500

550310

<2005200<200

<200330180250440

580<200

4<200<200

<200340790

<200<200

350520430

<200<200

610<200<200330260

200<200390520

<200<200<200<200<200

<200<200

Diethyl phthal ate

<400<200<200<200

79

81<200<200<200<200

<20090

<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<2008080

<200<200

<200<200<200<200

81

83<200

88<200

<200<200<200<200<200

<200<200

Di methyl phthal ate

<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

99<200<200<200

<200<200<200<200<200

<200<200

Di-n- butyl phthal ate

<400<200<200<200120

120<200<200<200<200

<200160100

<200<200

<200<200

3<200<200

<200<200<200<200<200

<200120120

<200<200

<200<200<200<200110

110<200150

<200

<200<200<200<200<200

<200<200

Di-n- octyl phthal ate

<800<400<400<400190

<400<400<400<400<400

<400150

<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400190

170<400150

<400

<400<400<400<400<400

<400<400

n-Butyl benzyl phthal ate

<400<200<200<200120

<200<200<200<200<200

<200150

<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200150

<200<200<200

<200<200<200<200360

160<200150

<200

<200<200<200<200<200

<200<200

Ace- naph- thene

<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200

<200<200<200<200<200

<200<200

Ace- naph- thylene

<400<200<200<200<200

<200<200<200<200<200

<20081

<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200

87<200

<200<200<200<200<200

<200<200

Anthra cene

<400<200<200<200<200

<200<200<200<200<200

<20086

<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<2004099

<200

280<200<200<200<200

<200<200

67

Table 26. Concentrations of semi-volatile organic compounds (phthalate esters, ethers, phenols, cresols, and monocyclic- and polycyclic-aromatic compounds) in bed-sediment samples, Yakima River basin, Washington, 1987-90--Continued

Station number

1247810012478300124797201248000012484480

1248448012484500124845001248455012488250

1248910012500430125004301250043712500445

1250044512500450125036401250364012505460

1250546012507508125075081250862512508850

1250885012508850125088501250971012510500

1251050012510500

461652119522000461652119522000461744119522400461744119522400463359120281400

463501120353300463501120353300

Apple composite from 5 ditchesAsparagus composite from 5 ditchesCorn composite from 5 ditchesGrape composite from 4 ditchesHops--compoosite from 5 ditches


Date

11-06-8908-31-8805-02-8911-06-8908-31-88

08-31-8805-04-8911-05-9005-03-8911-07-89

11-07-8908-30-8808-30-8805-01-8908-30-88

08-30-8809-16-8709-01-8809-01-8809-02-88

09-02-8809-01-8809-01-8809-15-8708-31-88

08-31-8808-31-8808-31-8811-08-9008-31-88

08-31-8811-10-9009-01-8809-01-8809-01-8809-01-8808-28-87

09-01-8809-01-88

08-27-8709-16-8708-27-8711-30-8709-16-87

11-30-8709-18-87

Benzo(a) anthra cene

<800<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400<400<400

130<400

<400<400<400<400<400

<400<400

Benzo(a) pyrene

<800<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400<400<400

160<400

<400<400<400<400<400

<400<400

Benzo(b) fluoranthene

<800<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400 C400<400<400

200<400

<400<400<400<400<400

<400<400

Benzo(k) fluoranthene

<800<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400<400<400

140<400

<400<400<400<400<400

<400<400

Benzo (ghi) perylene

<800<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400<400<400

160<400

<400<400<400<400<400

<400<400

Chry- sene

<800<400<400<400<400

<400<400<400<400<400

<40081

<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400<400<400

160<400

<400<400<400<400<400

<400<400

Dibenzo (a,h) anthra cene

<800<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400<400<400

<400<400

<400<400<400<400<400

<400<400

Fluor- anthene

<400<200<200<200120

<200<200<200<200<200

<200120

<200<200<200

120<200<200<200<200

<200<200<200<200<200

<200<200<200

5<200

<2004

<200<200<200<200

56

200<200

130<200<200<200<200

<200<200

68

Table 26. Concentrations of semi-volatile organic compounds (phthalate esters, ethers, phenols, cresols, and monocyclic- and polycyclic-aromatic compounds) in bed-sediment samples, Yakima River basin, Washington, 1987-90 Continued

Station number

1247810012478300124797201248000012484480

1248448012484500124845001248455012488250

1248910012500430125004301250043712500445

1250044512500450125036401250364012505460

1250546012507508125075081250862512508850

1250885012508850125088501250971012510500

1251050012510500

461652119522000461652119522000461744119522400461744119522400463359120281400

463501120353300463501120353300



Date

11-06-8908-31-8805-02-8911-06-8908-31-88

08-31-8805-04-8911-05-9005-03-8911-07-89

11-07-8908-30-8808-30-8805-01-8908-30-88

08-30-8809-16-8709-01-8809-01-8809-02-88

09-02-8809-01-8809-01-8809-15-8708-31-88

08-31-8808-31-8808-31-8811-08-9008-31-88

08-31-8811-10-9009-01-8809-01-8809-01-8809-01-8808-28-87

09-01-8809-01-88

08-27-8709-16-8708-27-8711-30-8709-16-87

11-30-8709-18-87

Fluor- ene

<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200<200<200

<200<200

<200<200<200<200<200

<200<200

Indeno (1,2,3- cd) pyrene

<800<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400

<400<400<400<400<400<400<400

<400<400

<400<400<400<400<400

<400<400

Naphth alene

<400<200<200<200<200

95<200<200<200<200

<20096

<200<200

30

20<200<200<200<200

<200<200<200<200<200

<200<200

943

<200

82

<200<200<200<200

25

100<200

<200<200<200<200<200

<200<200

Phenan- threne

<400<200<200<200

96

83<200<200<200<200

<20090

<200<200

90

70<200<200<200<200

<200<200

20<200<200

<200<200

829

<200

<2004

<20038

<200<200

35

14028

240<200<200<200<200

<200<200

Pyrene

<400<200<200<200120

<200<200<200<200<200

<200120

<200<200<200

70<200<200<200<200

<200<200<200<200<200

<200<200110

4<200

<2003

<200<200<200<200

58

190<200

160<200<200<200<200

<200<200

n- Nitro- sodi- methyl- amine

<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200<200<200

120<200

<200<200<200<200<200

<200<200

n- Nitro- sodi-n- propyl- amine

<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200<200<200

<200<200

<200<200<200<200<200

<200<200

n- Nitro- sodi- phenyl- amine

<400<200<200<200<200

<200<200<200<200<200

<200<200<200<200220

160<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200<200<200

43<200

<200<200<200<200<200

<200<200

69

Table 27. Ancillary data, for composite biological samplas, collected for analysis of trace-organic compounds, Yakima River basin, Washington, 1989-90

[D = did not determine, NA = not applicable; see figure 1 for site locations; age of biological samples are expressed in years as measured from scale samples, for example, 0 = less than 1 year, 1 = greater than 1 year and less than 2 years]

Mapreference Station Samplingnumber number Station name date

Fieldnumber Number

OrganismLength(mm)

Height(grams)

Age(years)

Numberexternalabnormalities

Rainbow Trout

1 12478100 Waptus River at mouth nr Roslyn 11-02-89

5 12479720 Jungle Creek nr mouth nr Cle Elum 05-02-89

7 12480000 Teanaway River blw forks nr Cle Elum 11-06-89

14 12484500 Yakima River at Umtanum 11-07-89

15 12484550 Umtanum Creek nr mouth at Umtanum 05-03-89

16 12487200 Little Naches River at mouth nr Cliffdell 10-30-90

18 12489100 Rattlesnake Cr abv N.F. Rattlesnake Cr nr Nile 11-06-89

41 12507594 Satus Cr abv Wilson-Charley Canyon nr Toppenish 11-09-89

YK0065SF 123

4567

Ave.

YK0005SF 123456789

12Ave.

YK0124SF 123456789

10Ave.

YK0145SF 123456789

10Ave.

YK0011SF 123456789

10Ava.

YK0201SF 123456

Ava.

YK0126SF 123456789

10 Ave.

YK0161SF 1 2345678910Ave.

93122107

112120125120114

10810510674671086979826286

147159166148145171167135154153155

132235131125118198195220200210T7S

137127137122146109113110115_96122

210237157157130133T7T

948870817880828996

If

192 200140135130149170180127115T54

71411

1114161412

17121154

1334538

2533362824424521353633

231332624168370

1108496"67

2923292132161715181021

88115353618193T

8746456576 *

64 70262219274250171355

000

0000

DDDDDDDDDD

1111111111

0111111111

DDDDDDDDDD

221111

DDDDDDDDDD

1 111002211

DDD

DDDD

DDDDDDDDDD

DDDDDDDDDD

DDDDDDDDDD

DDDDDDDDDD

000000

DDDDDDDDDD

D DDDDDDDDD

70

Table 27. Ancillary data, for composite biological samples, collected for analysis of trace-organic compounds,Yakima River besin, Washington, 1989-90--Continued

Map reference Station Sampling Field number number Station name date number Number

OrganismLength (mm)

Weight Age (grams) (years)

Number externalabnor malities

Mountain Whitefish

it 12479500 Yakima River at Cle Elum 11-02-89 YK0067SF 123456789

1° Ave.

4 12479500 Yakima River at Cle Elum 11-05-90 YK0303SF 123456789

10Ave.

M 12484500 Yakima River at Umtanum 11-07-89 YK0143SF 123456789

10Ave.

22 12499000 Naches River nr North Yakima 11-06-90 YK0332SF 123456789

1°Ave.

24 12500430 Moxee Drain at Thorp Rd nr Union Gap 11-08-89 YK0154SF 123456789

1°Ave.

40 12507585 Yakima River at RM 72 ab Satus Cr nr Sunnyside 11-01-89 YK0058SF 123456789

10Ave.

«3 12508620 Satus Creek at gage at Satus 11-03-89 YK0076SF 123456789

10Ave.

313299312299301290313294320

ti295293339313312357287349310291313

399349380356278260245187170184281

406361384319338320290320321292335

132145135149148139159154131m277274187268296269190174183176229

184179184176161187180166172181177

245222208236271205285209304303

268214301296244415224391272217284

512346466393198170138523751

155

658389303289405286238346338223345

162419242520342719

M18918948

16224416855434940

TT9

5149484233505037445546

4232322223

4444454545

5233222100

4545545453

1111111111

DDDDDDDDDD

1110110000

DDDDDDDDDD

0000010000

DDDDDDDDDD

0100200620

DDDDDDDDDD

DDDDDDDDDD

DDDDDDDDDD

71

Table 27. Ancillary data, for composite biological samples, collected for analysis of trace-organic compounds, Yakima River basin, Washington, 1989-90 Continued

Mapreferencenumber

Number

Station Sampling Fieldnumber Station name date number Number

OrganismLength(mm)

externalWeight(grams)

Age(years)

abnormalities

Mountain Whitefish--Continued

51

51

12510500 Yakima River at Kiona 10-31-89 YK0040SF 123456789

10Ave.


10Ave.

354425402343357366379359368350375

374388364345334382354371338370312

424626698420433489576446452£25415

496667469367397535462491397378466

D.ODDDDDDDD

5654555534

DDDDDDDDDD

0130111101

Smallmouth Bass

51 12510500 Yakima River at Kiona 10-31-89 YK0039SF 123456789

10Ave.

265202181253289299180233220307543

21910876

20729931176

152116346T5T

DDDDDDDDDD

DDDDDDDDDD

Sculpin

4

5

6

8

Yakima River at Cle Elum 11-05-90 YK0304SF 123456789

i°Ave.

12479720 Jungle Creek nr mouth nr Cle Elum 05-02-89 YK00070F 12345678910Ave.

12479750 No Fk Teanaway R blw bridge at Dickey 11-03-90 YK0268SF 1Creek Campgrnd 2

3456789

10Ave.

12481900 Taneum Cr at Taneum Meadow nr Thorp 11-03-90 YK0265SF 123456789

10Ave.

797642418289578739

6878738076718567686773

1108066

108727678

105548015

12110392

1041159592968593

Toff

56116

103814"3

46565483333

1763

15456

1526~5

241411152112111299

14

DDDDDDDDDD

DDDDDDDDDD

DDDDDDDDDD

DDDDDDDDDD

0000000000

DDDDDDDD0D

0000000000

0000000000

-

72


Mapreferencenumber

Station Samplingnumber Station name date

Fieldnumber Number

OrganismLength(mm)

Weight(grams)

Age(years)


Sculpin- -Continued

9

10

15

17

18

29

30

41

12483190 South Fork Manastash Cr nr Ellensburg 11-02-90

12483750 Naneum Cr blw High Cr nr Ellensburg 11-02-90

12484550 Umatanum Creek nr mouth at Umtanum 11-05-90

12488250 American River at Hells Crossing nr Nile 11-01-90

12489100 Rattlesnake Cr abv N.F. Rattlesnake Cr nr Nile 11-01-90

12500900 S.F. Ahtanum Cr abv Conrad Rnch 11-06-90nr Tampico

12502500 Ahtanum Creek at Union Gap 11-06-90

12507594 Satus Cr abv Wilson-Charley Canyon 11-07-90nr Toppenish

YK0240SF 123456789

10Ave.

YK0242SF 123456789

10Ave.

YK0297SF 123456789

10Ave.

YK0221SF 123456789

10Ave.

YK0225SF 123456789

10Ave.

YK0337SF 123456789

10Ave.

YK0348SF 123456789

10Ave.

YK0368SF 123456789

.10Ave.

988993

113768682767169~85

12110313578779475807574~SI

7159556782675859617265

8972797482948479807481

11011779

1121039874707576~9T

1091101161081039686

11095

118105

93951261221099299

10296

105104

87908883

1001129492

11890~95

98

1023696554~9

24153858

105755

T2

4224742323~3

75657

126555~6

18195

1710135465

To

1521201416117

14102215

1010282515121416101716

810117

13201111189

12

DDDDDDDDDD

DDDDDDDDDD

DDDDDDDDDD

DDDDDDDDDD

DDDDDDDDDD

DDDDDDDDDD

DDDDDDDDDD

DDDDDDDDDD

0000000000

0000000000

0000000000

0000000000

0000000000

DDDDDDDDDD

0000000000

0000000000

73

Table 27. Ancillary data, for composite biological samples, collected for analysis of trace-organic compounds,Yakima River basin, Washington, 1989-90 Continued

Mapreference Stationnumber number Station name

Samplingdate

Fieldnumber Number

Or Rani smLength(mm)

Weight(grams)

Age(years)


Sculpin Continued

43 12508500 Satus Cr below Dry Cr nr Toppenish

43 12508620 Satus Creek at gage at Satus

11-07-90

11-07-90

YK0355SF

YK0353SF

123456789

10Ave.123456789

10Ave.

7760557279616277645867

10178688473756282718278

63256336424

17759563868

DDDDDDDDDD

DDDDDDDDDD

0000000000

0000000000

Chisalmouth

24 12500430 Moxee Drain at Thorp Rd nr Union Gap

46 12508850 Sulphur Cr Waateway nr Sunny side

49 12509710 Spring Creek at mouth at Whitstran

10-31-90

11-09-90

10-30-89

YK0218SF

YK0401SF

YK0020SF

1234567

Ave.

1234567

Ave.

12345

Ave.

207202178199195192140

142126149129129137141136

19619694

110120109 138

8373586867632462

2521271818222312

80728

131614 34

1212211

1111111

DDDDDD

0000000

0000000

DDDDDD

Largescale Sucker

13 12484480 Cherry Creek at Thrall

14 12484500 Yakima River at Umtanum

11-06-89

11-05-90

YK0122SF

YK0302SF

123456789

10Ave.

123456789

10Ave.

269245229208203187151109176236201

430468576563500528481539455477502

193139131869263291453

143~94

9341,1082,0831,8651,2631,3861,2811,500

9061.2401,357

1111110011

5566665565

DDDDDDDDDD

0000000000

74

Table 27. Ancillary data, for composite biological samples, collected for analysis of trace-organic compounds, Yakima River basin, Washington, 1989-90--Continued

Mapreference Station Sampling Fieldnumber number Station name date number Number

OrganismLength(mm)

Weight(grams)

Age(years)


Largescale Sucker Continued

22 12*99000 Naches River nr North Yakima 11-06-90 YK0331SF

24 12500430 Moxee Drain at Thorp Rd nr Union Gap 11-08-89 YK0157SF

26 12500442 Wide Hollow Cr at Old STP at Union Gap 11-05-90 YK0309SF

32 12503950 Yakima R at Parker 11-07-89 YKOU1SF

32 12503950 Yakima R at Parker 11-06-90 YK0324SF

36 12505460 Granger Drain at mouth at Granger 11-03-89 YK0071SF

38 12507508 Toppenish Cr at Indian Church Rd nr Granger 11-03-89 YK0073SF

123456789

IP. Ave.

12345678

Av'e.

123

_4Ave.

123456789

10Ave.

123456789

10Ave.

123456789

Ave.

123456789

IP.Ave.

347422436341509446449418449497 431

222244226246222169129132199

213219173169194

456420399458454456404451422432435

462529392435427430450426434447443

196196199190187186164163216188

396469424465376441480443453443439

801730762465

1,076840833729923

1.367 853

105150117140106482423~89

108945840~75

912669613761111865479810609741723

9271,097

585790760635904711742781793

64626254515832318856

604891768

1,042525878

1,072944957842~652

5444755657

22221100

111D

2333533444

5635446556

111111111

3465355DDD

0000010010

DDDDDDDD

0000

1000000000

0000040004

DDDDDDDDD

DDDDDDDDDD

75


Mapreferencenumber


OrganismLength(mm)

Weight(grams)

Age(years)



39

40

46

47

47

51

12507525 Yakima R blw Toppenish Cr at RM 79.6 nr Granger 11-07-90 YK0372SF 123456789

10Ave.

12507585 Yakima River at RM 72 ab Satus Cr nr Sunnyside 11-01-89 YK0055SF 123456789

IP.Ave.

12508850 Sulphur Cr Wasteway nr Sunnyside 11-01-89 YK0052SF 123456789

42Ave.

12509050 Yakima R at Euclid Br at RM 55 nr Grandview 10-31-89 YK0047SF 123456789

10Ave.

12509050 Yakima R at Euclid Br at RM 55 nr Grandview 11-09-90 YK0400SF 123456789

42Ave.


10Ave.

397485508445395441445461444423444

429432431375437339430435440434418

473462515484431501203462491465449

475456453451520478461434536491476

513449494424394480440471473422456

396453453475484474400408508436449

708985

1,137958653758858872884749856

762776750537668351787808833773704

9511,0151,238

998817

1,28894

9431,113

895935

1,287888753757

1,421980854826

1,4541.0481^027

1,199870

1,010710623989773940

1,051742891

5971,1301,0111,3331,2931,112

706761

1,292930-155

4555644445

3221413222

3444331344

4433232244

5665545645

DDDDDDDDDD

0000000303

DDDDDDDDDD

DDDDDDDDDD

DDDDDDDDDD

1000201200

0000010000

76


Maprefer encenumber

Station Samplingnumber Station name date

Fieldnumber Number

OrganismLength(mm)

Weight(grams)

Age(years)

Numberexternal abnormalities


51

51

12510500 Yakima River at Kiona 11-10-90


YK0402SF

YK0403SF

123456789

10Ave.

123456789

10Ave.

471435493531532492556537461500501

471565510495560530460445520560512

1,049908

1,0511,3861,5251,1571,7711,688

9081.2401,268

1,0511,7271,2441,2241,9841,1279501,1131,6091.8141,384

4344648656

5766765455

0000200100

2000002011

Bridgelip Sucker

12

14

25

26

36

12484440 Cherry Creek abv. Wipple Wasteway at Thrall 10-31-90

12484500 Yakima River at Umtanum 05-03-89

12500437 Wide Hollow Cr at W. Valley School nr Ahtanum 05-01-89

12500442 Wide Hollow Creek at Old STP at Union Gap 11-08-89

12505460 Granger Drain at mouth nr Granger 11-08-90

YK0211SF

YK0015SF

YK0001SF

YK0155SF

YK0386SF

123456

Ave.

12345

Ave.

123456789

10Ave.

12345678

_9Ave.

123456789

10Ave.

190174153166130138159

374355392373268

240174186181160155179172168155177

111155108102106119125156141125

227220212223229216198211253201219

72654766263151

595475610550535553

18070

10075604570707050~79

13381111111621342820

1291171181201311066795

19185U6

111121

DDDDD

DDDDDDDDDD

000000000

3223462343

000000

DDDDD

DDDDDDDDDD

DDDDDDDDD

0000000000

Common Carp

40 12507585 Yakima River at RM 72 ab Satus Cr nr Sunnyside 11-01-89 YK0056SF 12345678910 Ave.

552410463510438410393435458447 452

2,126892

1,4862,1601,197

951750

1,0931,3761.241 1,327

DDDDDDDDDD

DDDDDDDDDD

77


Mapreference Station Samplingnumber number Station name date

Fieldnumber Number

Or «ani smLangth(mm)

Weight(grams)

Age(years)


Asiatic Clam

40 12507585 Yakima River at RM 72 ab Satus Cr nr Sunnyside 11-01-89




YK0100SM 123456789

101112131415161718192021222324252627282930313233343536373839404142434445Ave.

YK0101SM 123456789

1011121314151817181920212223242526272829303132333435363738394041424344

Sve.

YK0102SM 1-?

YK0103SM 1-?

303330311927372530243039252430242825362223233123272624243028282426232928241824253323252324TJ

2420222225183322241830262327222329262326262822292228232232243324242224232528322824232324s--

DDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDD


D

D



D

D

NANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANA

NANANAMANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANA

NA

NA

78

Table 27. Ancillary data, for composite biological samples, collected for anelysis of trace-organic compounds, Yakima River basin, Washington, 1989-90 Continued

Mapreferencenumber


OrganismLength(mm)

Weight(grams)

Age(years)


Asiatic Clam Continued

47

47

12509050 Yakima R at Euclid Br at RM 55 nr Grandview 10-31-89 YK0082SM 123456789

1011121314151617IS192021222324252627262930313233343536373839404142434445Ave.

12509050 Yakima R at Euclid Br at RM 55 nr Grandview 10-31-89 YK0085SM 123456789

1011121314151617IS192021222324252627282930313233343536373839404142434445Ave.

1427201715172020161736283427334030272626212721201926272327262024142422IS1921IS20151416151622

15IS151717151716IS172828332524312935222625272527252321232122211923181823IS18IS17161613151422







79


Mapreference Station number number

Sampling Field Station name date number Number

OrganismLength (mm)

Weight (grams)

Age (years)

Numberexternalabnor malities


47 12509050

49 12509710

Yakima R at Euclid Br at RM 55 nr Grandview 11-04-90 YK0375SM 123456789

1011121314151617181920212223242526272829303132333435363738394041424344

Xve.

Spring Creek at mouth at Whitstran 10-31-89 YK0080SM 123456789

101112131415161718192021222324252627282930313233343536373839404142434445

2926222521272725252122192321222424232221212021212019252522262022232222212316162018172422

8181717161617161817162622252422262221232122232223222022201820191818181718171916161517131611


D





NANANANANANANANANANANANAHAHAHAHAHAHAHANAHAMAHAHAMANAHAHAMANAHAHAHAHAMAHANANANANANANANANANA

80

Table 27. Ancillary data, for composite biological samples, collected for analysis of trace-organic compounds,Yakima River basin, Washington, 1989-90--Continued

Maprefer ence Stationnumber number

Sampling FieldStation name date number Number

OrganismLength(ran)

Weight(grams)

Age(years)



49 12509710

51 12510500

Spring Creek at mouth at Whitstran 11-08-90 YK0408SM 123456789

1011121314151617181920212223242526272829303132333435363738394041424344454647Ave.

Yakima River at Kiona 10-30-89 YK0115SM 123456789

101112131415161718192021222324252627282930313233343536373839404142434445Ave.

232321212618201817182223211923202130221628262219211819172325121323212019242618202122262321202721

21191716171616222225222019201717191817151720191920241818171619171816161616161816161714141218

DDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDD


DDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDD


HAHAHAHAHAHAHAHAHAHAHAHAHAHAHANAHAHAHAHANAHAHAHAHANAHANAHANANANANAHAHAHANANANAHAHANANAHANANANA

NAHANANANANANANANAHAHANAHANANANANANANANANAHANANANANANANANAHANANAHAHAHAHAHANANANANAHANAHANA

81


Maprefer ence Stationnumber number Station name

Sampling Fielddate number Number

OrganismLength(mm)

Weight(grams)

Age(years)



51 12510500 Yakima River at Kiona

51 12510500 Yakima River at Kiona

10-30-89 YK0116SM 123456789

101112131415161718192021222324252627282930313233343536373839404142434445Ave.

11-04-90 YK0367SM 123456789

10111213141516171819202122232425262728293031323334353637383940414243444546

161619191620141616192819191717191617162020271819172117231816191918161515152016201818201619Ts

23242419201828222222232022192624212219191918191816182023201919231717181818211818171616171614


DDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDD


DDDDDDDDDD0D0DDDDDDD00000000000000D00DDDDDDDDD


NANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANANA _

82



Or nanismStation Sampling number Station name date

Field number Number

Length (mm)

Weight (grams)

Age (years)

Number external abnor malities


47484950515253545556575859 Ave.

15171818171416161615141916 19

DDDDDDDDDDDDD D

DDDDDDDDDDDDD

NANANANANANANANANANANANANA

Western Pearlshell

14

14



YK0111SM

YK0393SM

123456789

10Ave.

12345

Ave.

127124111117113111119123118117117

134128125118126126

DDDDDDDDDD

DDDDDD

DDDDDDDDDD

DDDDD

NANANANANANANANANANA

NANANANANA

Crayfish

15

25

49

12484550 Umtanum Creek nr mouth at Umtanum 05-03-89

12500437 Wide Hollow Cr at W. Valley School nr Ahtanum 05-01-89

12509710 Spring Creek at mouth at Whitstran 10-30-89

YK0013SD

YK0003SD

YK0022SD

1-20

1-20

1-?

D

D

D

D

D

D

D

D

D

NA

NA

NA

Coontail

38

51

12507508 Toppenish Creek at Indian Church Rd nr Granger 11-03-89


YK0079SP

YK0034SP

1-?

1-?

D

D

D

D

NA

NA

NA

NA

Curlyleaf Pondweed

13

14

24

26

32

40

43

47

12484480

12484500

12500430

12500442

12503950

12507585

12508620

12509050

Cherry Creak

Yakima River

Moxee Drain

Wide Hollow

Yakima R at

Yakima River

Satus Creek

Yakima River

at

at

at

Thrall

Umtanum

Thorp Rd nr Union Gap

Creek at Old STP at Union Gap

Parker

at

at

at

RM 72 ab Satus Cr nr Sunnyside

gage at Satus

Euclid Br at RM 55 nr Grandview

11-06-89

11-05-89

11-04-89

11-04-89

11-04-89

11-01-89

11-03-89

10-31-89

YK0139SP 1-?

YK0118SP 1-?

YK0093SP 1-?

YK0096SP 1-?

YK0094SP 1-?

YK0060SP 1-?

YK0091SP 1-?

YK0045SP 1-?

D

D

D

D

D

D

D

D

D

D

D

D

D

D

D

D

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

Waterweed

26 12500430 Wide Hollow Creek at Old STP at Union Gap 11-04-89 YK0098SP 1-?

38 12507508 Toppenish Creek at Indian Church Rd nr Granger 11-03-89 YK0088SP 1-?

43 12508620 Satus Creek at gage at Satus 11-03-89 YK0092SP 1-?

49 12509710 Spring Creek at mouth at Whitstran 10-30-89 YK0036SP 1-?

NA

NA

NA

NA

NA

NA

NA

NA

83

Table 28. Concentrations of organochlorine compounds in aquatic biota, Yakima River basin, Washington, 1989-90

[Concentrations in micrograms per kilogram; wet weight; whole fish were analyzed; ODD DDE = dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyltrichloroethane; PCBs " " = not analyzed; see figure 1 for site locations]

dichlorodiphenyldichloroethane; polychlorinated biphenyls;

Map reference Station number number Station name Date

Field number

Moisture, Lipid, in percent in percent

Rainbow Trout

157

1515

161841

1247810012479720124800001248455012484550

124872001248910012507594

Waptus River at mouth nr RoslynJungle Creek nr mouth nr Cle ElumTeanaway River below forks near Cle ElumUmtanum Creek nr mouth at UmtanumUmtanum Creek nr mouth at Umtanum

Little Naches River at mouth nr CliffdellRattlesnake Cr abv N.F. Rattlesnake Cr nr NileSatus Cr abv Wilson-Charley Canyon nr Toppenish

11-02-8905-02-8911-06-8905-03-8911-07-89

10-30-9011-06-8911-09-89

YK0065SFYK0005SFYK0124SFYK0011SFYK0145SF

YK0201SFYK0126SFYK0161SF

76787879,76

767575

.0

.0

.0

.0

.0

.4

.0

.5

31214

443

.48

.80

.22

.68

.10

.56

.58

.68

Mountain White fish

4

142224

40435151

12479500

124845001249900012500430

12507585125086201251050012510500

Yakima River at Cle ElumYakima River at Cle ElumYakima River at UmtanumNaches River nr North YakimaMoxee Drain at Thorp Rd nr Union Gap

Yakima River at RM 72 ab Satus Cr nr SunnysideSatus Creek at gage at SatusYakima River at KionaYakima River at Kiona

11-02-8911-05-9011-07-8911-06-9011-08-89

11-01-8911-03-8910-31-8911-10-90


YK0058SFYK0076SFYK0040SFYK0404SF

74.72.72.73.73.

71,72.71.70.

,0.2.2.0.0

.5

.4,0.0

65,5,5.6

766.7,

.64

.84

.92

.56

.80

.54

.64

.90

.91

SmalLnouth Bass

51 12510500 Yakima River at Kiona 10-31-89 YK0039SF 76,.0 2,.88

Sculpin

45689

1015171829

30414243

1247950012479720124797501248190012483190

1248375012484550124882501248910012500900

12502500125075941250850012508620

Yakima River at Cle ElumJungle Creek nr mouth nr Cle ElumNo Fk Teanaway R blw bridge at Dickey Creek CampgrndTaneum Cr at Taneum Meadow nr ThorpSouth Fork Manastash Cr nr Ellensburg

Naneum Cr blw High Cr nr EllensburgUmtanum Creek nr mouth at UmtanumAmerican River at Hells Crossing nr NileRattlesnake Cr abv N.F. Rattlesnake Cr nr NileS. F. Ahtanum Cr abv Conrad Rnch nr Tampico

Ahtanum Creek at Union GapSatus Cr abv Wilson-Charley Canyon nr ToppenishSatus Creek below Dry Cr nr ToppenishSatus Creek at gage at Satus

11-05-9005-02-8911-03-9011-03-9011-02-90

11-02-9011-05-9011-01-9011-01-9011-06-90

11-06-9011-07-9011-07-9011-07-90




78.75.81.83.84.

80.76.78.80.80,

80,80,77,78

.2

.5

.8

.4

.8

.4

.6

.0

.2

.8

.8

.0:e.0

21,1.1.1

11,1,1,1

1124

.08

.76

.49

.40

.95

.54

.19

.67

.28

.43

.83

.63

.30

.65

Chiselmouth

244649

125004301250885012509710

Moxee Drain at Thorp Rd nr Union GapSulphur Cr Wasteway nr SunnysideSpring Creek at mouth at Whitstran

10-31-9011-09-9010-30-89


7276,73

.6

.0

.5

667

.69

.71

.90

Largescale Sucker

1314222426

3232363839

4046474751

5151

1248448012484500124990001250043012500442

1250395012503950125054601250750812507525

1250758512508850125090501250905012510500

1251050012510500

Cherry Creek at ThrallYakima River at UmtanumNaches River nr North YakimaMoxee Drain at Thorp Rd nr Union GapWide Hollow Cr at Old STP at Union Gap

Yakima R at ParkerYakima R at ParkerGranger Drain at mouth nr GrangerToppenish Cr at Indian Church Rd nr GrangerYakima R blw Toppenish Cr at RM 79.6 nr Granger

Yakima River at RM 72 ab Satus Cr nr SunnysideSulphur Cr Wasteway nr SunnysideYakima R at Euclid Br at RM 55 nr GrandviewYakima R at Euclid Br at RM 55 nr GrandviewYakima River at Kiona


11-06-8911-05-9011-06-9011-08-8911-05-90

11-07-8911-06-9011-03-8911-03-8911-07-90

11-01-8911-01-8910-31-8911-09-901C-31-89

1--10-9011-10-90




YK0402SFYK0403SF

75.72.75.77.76.

75.77.75.76.76.

74.72.73.75.70.

70.67.

5644,8

28002

5,05,0,0

66

5.6.4.3.2.

3.3.3.5.8.

7.8.7.5.

11.

7.11.

,94,64.71,90.79

.60,106606,15

,12,96,56.30.6

,99,6

84

Table 28. Concentrations of organochlorine compounds in aquatic biota, Yakima River basin, Washington, 1989-90--Continued


Station number

Hepta- Field cis- trans- Oxy- chlor number Chlordane Chlordane chlordane epoxide

cis- trans- Nonachlor Nonachlor

Rainbow Trout

1 57

15 15

16 18 41

12478100 12479720 12480000 12484550 12484550

12487200 12489100 12507594

YK0065SF <10 <10 <10 <10 YK0005SF <10 <10 <10 <10 YK0124SF <10 <10 <10 <10 YK0011SF <10 <10 <10 <10 YK0145SF <10 <10 <10 <10

YK0201SF <10 <10 <10 <10 YK0126SF <10 <10 <10 <10 YK0161SF <10 <10 <10 <10

1? is:s %

Mountain Whitefish

4 4

14 22 24

40 43 51 51

12479500 12479500 12484500 12499000 12500430

12507585 12508620 12510500 12510500

YK0067SF <10 <10 <10 <10 YK0303SF 10 <10 <10 <10 YK0143SF <10 <10 <10 <10 YK0332SF <10 <10 10 10 YK0154SF 10 <10 <10 <10

YK0058SF 10 <10 <10 <10 YK0076SF <10 <10 <10 <10 YK0040SF 30 <10 <10 <10 YK0404SF 10 10 10 10

<10 10

<10 10 <10 10

<10 10

<10 20 <10 20

Smallmouth Bass

51 12510500 YK0039SF <10 <10 <10 <10 <10

Sculpin

4 5 6 8 9

10 15 17 18 29

30 41 42 43

12479500 12479720 12479750 12481900 12483190

12483750 12484550 12488250 12489100 12500900

12502500 12507594 12508500 12508620

YK0304SF <10 <10 <10 <10 YK0007SF <10 <10 <10 <10 YK0268SF < 10 <10 <10 <10 YK0265SF <10 <10 <10 <10 YK0240SF <10 <10 <10 <10

YK0242SF <10 <10 <10 <10 YK0297SF <10 <10 <10 <10 YK0221SF <10 <10 <10 <10 YK0225SF <10 <10 <10 <10 YK0337SF <10 <10 <10 <10

YK0348SF <10 <10 <10 <10 YK0368SF <10 <10 <10 <10 YK0355SF <10 <10 <10 <10 YK0353SF <10 <10 <10 10

<10 <10

<10 <10 <10 < 10

<10 <10 <10 <10 <10 <10

Chiselmouth

24 46 49

12500430 12508850 12509710

YK0218SF 20 <10 <10 10 YK0401SF 10 <10 <10 <10 YK0020SF <10 <10 <10 <10

<10 10 <10 10

Largescale Sucker

13 14 22 24

26 32

36 38

39 40 46 47

4751 51 51

12484480 12484500 12499000 12500430

12500442 12503950

12505460 12507508

12507525 12507585 12508850 12509050

12509050 12510500 12510500 12510500

YK0122SF <10 <10 <10 <10 YK0302SF 10 <10 10 10 YK0331SF 10 <10 <10 <10 YK0157SF <10 <10 <10 <10

YK0309SF 10 <10 <10 <10 YK0141SF <10 <10 <10 <10 YK0324SF 10 <10 <10 <10 YK0071SF <10 <10 <10 <10 YK0073SF <10 <10 <10 <10

YK0372SF 10 <10 <10 <10 YK0055SF 10 <10 <10 <10 YK0052SF 40 <10 <10 <10 YK0047SF 20 <10 <10 <10

YK0400SF 20 10 10 10 YK0041SF 20 <10 <10 <10 YK0402SF 20 10 10 10 YK0403SF 30 10 20 20

<10 10

<10 10

<10 10

<10 10 <10 10 <10 30 <10 20

<10 20 <10 20 <10 30 <10 40

85

Table 28. Concentrations of organochlorine compounds in aquatic biota, Yakima River basin, Washington, 1989-90 Continued

Mapreferencenumber

Stationnumber

Fieldnumber

o,p'-DDD

P,P'- o.P'-DDD DDE

P,P'- o,P'~DDE DOT

P,P'DOT

Rainbow Trout

157

1515

161841

1247810012479720124800001248455012484550

124872001248910012507594



<10<10<10<10<10

<10<10<10

<10 <10<10 <10<10 <10<10 <10<10 <10

<10 <10<10 <10<10 <10

10 <1010 <1010 <1030 <1050 <10

20 <1010 <1010 <10

<10<10<10<10<10

<10<10<10

Mountain Whitefish

44

142224

40435151

1247950012479500124845001249900012500430

12507585125086201251050012510500



<1070

<101020

20<10<1040

10 <1010 <1010 <1060 1070 <10

90 <1010 <10

170 <10230 30

70 <1070 <10

160 <10590 <10830 40

1,000 <1090 <10

1,500 <101,600 <10

30104080

110

11030

<1070

Smallmouth Bass

51 12510500 YK0039SF <10 90 <10 560 <10 <10

Sculpin

45689

1015171829

30414243

1247950012479720124797501248190012483190

1248375012484550124882501248910012500900

12502500125075941250850012508620




<10<10<10<10<10

<10<10<10<10<10

<10<10<10<10

<10 <10<10 <10<10 <10<10 <10<10 <10

<10 <10<10 <10<10 <10<10 <10<10 <10

20 <10<10 <10<10 <1010 <10

<10 <10<10 <10<10 <10<10 <10<10 <10

<10 <1010 <10

<10 <10<10 <10<10 <10

90 <10<10 <1010 <1060 <10

<10<10<10<10<10

<10<10<10<10<10

<10<10<1010

Chiselmouth

244649

125004301250885012509710


1030

<10

50 20130 20<10 <10

360 <101,200 <10

480 <10

1030

<10

Largescale Sucker

13142224

2632323638

39404647

47515151

12484480124845001249900012500430

1250044212503950125039501250546012507508

12507525125075851250885012509050

12509050125105001251050012510500





<10<1010

<10

2010103020

20407050

60404050

<10 <1030 1050 <1070 <10

80 1060 <1070 <10

150 <10110 <10

140 20210 <10410 <10290 <10

420 30190 <10300 30390 30

50 <10210 10410 <10530 <10

270 <10420 <10620 <10

1,500 <101,000 <10

1,400 <101,800 <103,400 <102,500 <10

2.500 <101,800 <102,000 <102,200 <10

<105070

160

2080

110260150

210270960370

460240190220

86



Station number

Field Hexachloro- a-Hexachloro- b-Hexachloro- n umber benzene cyclohexane cyclohexane

g-Hexachloro- cyclohexane d-Hexachloro- ( lindane ) eye lohexane Toxaphene

Rainbow Trout

1 5 7

15 15

16 18 41

12478100 12479720 12480000 12484550 12484550

12487200 12489100 12507594

YK0065SF <10 <10 <10 YK0005SF <10 <10 <10 YK0124SF <10 <10 <10 YK0011SF <10 <10 <10 YK0145SF <10 <10 <10

YK0201SF <10 <10 <10 YK0126SF <10 <10 <10 YK0161SF <10 <10 <10

<10 <10 <50 <10 <10 <50 <10 <10 <50 <10 <10 <50 <10 <10 <50

<10 <10 <50 <10 <10 <50 <10 <10 <50

Mountain Whitefish

4 4

14 22 24

40 43 51 51

12479500 12479500 12484500 12499000 12500430

12507585 12508620 12510500 12510500


YK0058SF <10 <10 <10 YK0076SF <10 <10 <10 YK0040SF <10 <10 <10 YK0404SF <10 <10 <10

<10 <10 <50 <10 <10 <50 <10 <10 <50 <10 <10 <50 <10 <10 <50

<10 <10 <50 <10 <10 <50 <10 <10 <50 <10 <10 360

SmaLlmouth Bass

51 12510500 YK0039SF <10 <10 <10 <10 <10 <50

Sculpin

4 5 6 8 9

10 15 17 18 29

30 41 42 43

12479500 12479720 12479750 12481900 12483190

12483750 12484550 12488250 12489100 12500900

12502500 12507594 12508500 12508620




<10 <10 <50 <10 <10 <50 <10 <10 <50 <10 <10 <50 <10 <10 <50

<10 <10 <50 <10 <10 <50 <10 <10 <50 <10 <10 <50 <10 <10 <50

<10 <10 <50 <10 <10 <50 <10 <10 <50 <10 <10 <50

Chiselmouth

24 46 49

12500430 12508850 12509710

YK0218SF <10 <10 <10 YK0401SF <10 <10 <10 YK0020SF <10 <10 <10

<10 <10 <50 <10 <10 690 <10 <10 <50

Largescale Sucker

13 14 22 24

26 32

36 38

39 40 46 47

47 51 51 51

12484480 12484500 12499000 12500430

12500442 12503950

12505460 12507508

12507525 12507585 12508850 12509050

12509050 12510500 12510500 12510500

YK0122SF , <10 <10 <10 YK0302SF <10 <10 <10 YK0331SF <10 <10 <10 YK0157SF <10 <10 <10

YK0309SF 10 <10 <10 YK0141SF <10 <10 <10 YK0324SF <10 <10 <10 YK0071SF <10 <10 <10 YK0073SF <10 <10 <10



<10 <10 <50 <10 <10 <50 <10 <10 <50 <10 <10 <50

<10 <10 <50 <10 <10 <50 <10 <10 <50 <10 <10 <50 <10 <10 <50

<10 <10 300 <10 <10 350 <10 <10 1,200 <10 <10 520

<10 <10 930 <10 <10 310 <10 <10 710 <10 <10 720

87


Mapreferencenumber

Stationnumber

Fieldnumber

TotalPCBS Dieldrin Endrin Mirex Kepone

Octochloro-styrene Dicofol

Rainbow Trout

157

1515

161841

1247810012479720124800001248455012484550

124872001248910012507594



<50<50<50<50<50

<50<50<50

<10 <10 <10 <10<10 <10 <10 <10<10 <10 <10 <10<10 <10 <10 <1010 <10 <10 <10

<10 <10 <10<10 <10 <10 <10<10 <10 <10 <10

<10 <10<10 <10<10 <10<10 <10<10 <10

<10<10 <10<10 <10

Mountain Whitefish

44

142224

40435151

1247950012479500124845001249900012500430

12507585125086201251050012510500



<50<50<50<50<50

<50<50<50620

10 <10 <10 <1010 <10 <10 ~~20 <10 <10 <1010 <10 <10 ~~20 <10 <10 <10

40 <10 <10 <1010 <10 <10 <1060 <10 <10 <1050 <10 <10

<10 <10__

<10 <10

<10 40

<10 40<10 30<10 <10

<10

Smallmouth Bass

51 12510500 YK0039SF <50 <10 <10 <10

Sculpin

45689

1015171829

30414243

1247950012479720124797501248190012483190

1248375012484550124882501248910012500900

12502500125075941250850012508620




<50<50<50<50<50

<50<50<50<50<50

<50<50<50<50

<10 ^10 <10 ~~<10 <10 <10 <10<10 <10 <10 -<10 <10 <10<10 <10 <10

<10 <10 ^10 <10 <10 <10<10 <10 <10<10 <10 <10<10 <10 <10

<10 <10 <10<10 <10 <10<10 <10 <1010 <10 <10

_<10 <10__

<10<10

<10__

<10<10

__<10

--

Chiselmouth

244649

125004301250885012509710


<50250<50

<10 <10 <1080 <10 <10

100 <10 <10 <10

30060

<10 30

Largescale Sucker

13142224

2632323638

39404647

47515151

12484480124845001249900012500430

1250044212503950125039501250546012507508

12507525125075851250885012509050

12509050125105001251050012510500





<50<50<50<50

<50<50170<50<50

370100610290

780<50790900

20 <10 <10 <1010 <10 <10

<10 <10 <1010 <10 <10 <10

10 <10 <10 ~~10 <10 <10 <10

<10 <10 <1070 <10 <10 <1020 <10 <10 <10

20 <10 <1040 <10 <10 <10

170 <10 <10 <1080 <10 <10 <10

50 <10 <10100 <10 <10 <1060 <10 <1090 <10 <10

<10 <10 __

<10 30

__<10 <10__

<10 30<10 30

60<10 20<10 60<10 20

50<10 <10

<io<10

88

Table 28. Concentrations of organochlorine compounds in aquatic biota, Yakima River basin. Washington, 1989-90 Continued

Map reference Station number number Station name Date

Field number

Moisture, Lipid, in percent in percent

Bridgelip Sucker

1214252636

1248444012484500125004371250044212505460

Cherry Creek abv. Wipple Westeway at ThrallYakima River at UmtanumWide Hollow Cr at W. Valley School nr AhtanumWide Hollow Cr at Old STF at Union GapGranger Drain at mouth nr Granger

10-31-9005-03-8905-01-8911-08-8911-08-90


7271737471

.2

.8

.6

.5

.2

77658

.93

.03

.75

.02

.98

Carp

40 12507585 Yakima River at RM 72 ab Satus Cr nr Sunny side 11-01-89 YK0056SF 72 .5 5 .30

Asiatic Clam

4040404047

4747494951

5151

1250758512507585125075851250758512509050

1250905012509050125097101250971012510500

1251050012510500

Yakima River at RM 72 ab Satus Cr nr SunnysideYakima River at RM 72 ab Satus Cr nr SunnysideYakima River at RM 72 ab Satus Cr nr SunnysideYakima River at RM 72 ab Satus Cr nr SunnysideYakima R at Euclid Br at RM 55 nr Grandview

Yakima R at Euclid Br at RM 55 nr GrandviewYakima R at Euclid Br at RM 55 nr GrandviewSpring Creek at mouth at WhitstranSpring Creek at mouth at WhitstranYakima River at Kiona


11-01-8911-01-8911-01-8911-01-8910-31-89

10-31-8911-04-9010-31-8911-08-9010-30-89

10-30-8911-04-90

YK0100SMYK0101SMYK0102SMYK0103SMYK0085SM


YK0116SMYK0367SM

7678798282

9582838283

8482

.0

.0

.0

.0

.0

.5

.8

.0

.8

.0

.0

.4

22212

1,121,2

1,2

.40

.32

.62

.96

.20

.64

.74

.00

.98

.20

.95

.04

Western Feerlshell

1414

1248450012484500


11-01-8911-05-90

YK0111SMYK0393SM

86,90,

.0

.2.92,42

Crayfish

152549

124845501250043712509710

Umtanum Creek nr mouth et UmtanumWide Hollow Cr at W. Valley School nr AhtanumSpring Creek at mouth at Whitstran

05-03-8905-01-8910-30-89

YK0013SDYK0003SDYK0022SD

6776,75,

.5

.5

.0

221,

.64

.16

.10

Coontail

3851

1250750812510500

Toppenish Cr at Indian Church Rd nr GrangerYakima River at Kiona

11-03-8910-30-89

YK0079SPYK0034SP

94.93.

00

0. 1020

Curlyleaf Fondweed

1314242632

404347

1248448012484500125004301250044212503950

125075851250862012509050

Cherry Creek at ThrallYakima River at UmtanumMoxee Drain at Thorp Rd nr Union GapWide Hollow Cr at Old STF at Union GapYakima R at Parker

Yakima River at RM 72 ab Satus Cr nr SunnysideSatus Creek at gage at SatusYakima R at Euclid Br at RM 55 nr Grendview

11-06-8911-05-8911-04-8911-04-8911-04-89

11-01-8911-03-8910-31-89

YK0139SPYK0118SPYK0093SPYK0096SPYK0094SP

YK0060SPYK0091SPYK0045SP

93.99.95.93.94.

93.91.91.

00000

000

2010202&30

303030

Waterweed

26384349

12500442125075081250862012509710

Wide Hollow Cr at Old STF at Union GapToppenish Cr et Indian Church Rd nr GrangerSatus Creek at gage at SatusSpring Creek at mouth at Whitstran

11-04-8911-03-8911-03-8910-30-89

YK0098SPYK0088SPYK0092SPYK0036SP

94.93.94.93.

0000

10203020

89



Station number

Field cis- trans- Oxy- number Chlordane Chlordane chlordane

Hepta- chlor cis- trans- epoxide Nonachlor Nonachlor

Bridgelip Sucker

12 14 25 26 36

12484440 12484500 12500437 12500442 12505460

YK0211SF 10 10 10 YK0015SF 10 <10 <10 YK0001SF 30 <10 <10 YK0155SF 10 <10 <10 YK0386SF 20 10 10

20 <10 10

<10 <10 10 20 <10 20

Carp

40 12507585 YK0056SF 10 <10 <10 <10 <10 10

Asiatic Clam

40 40 40 40 47

47 47 49 49 51

51 51

12507585 12507585 12507585 12507585 12509050

12509050 12509050 12509710 12509710 12510500

12510500 12510500

YK0100SM <10 <10 <10 YK0101SM <10 <10 <10 YK0102SM <10 <10 <10 YK0103SM <10 <10 <10 YK0085SM <10 <10 <10

YK0082SM <10 <10 <10 YK0375SM <10 <10 <10 YK0080SM <10 <10 <10 YK0408SM 10 <10 <10 YK0115SM <10 <10 <10

YK0116SM <10 <10 <10 YK0367SM 10 <10 <10

<10 <10 <10

<10 <10 <10

<10 <10 10

Western Pearlshell

14 14

12484500 12484500

YK0111SM <10 <10 <10 YK0393SM <10 <10 <10 3! <iS <JS

Crayfish

15 25 49

12484550 12500437 12509710

YK0013SD <10 <10 <10 YK0003SD <10 <10 <10 YK0022SD <10 <10 <10 :a % si

Coontail

38 51

12507508 12510500

YK0079SP <10 <10 <10 YK0034SP <10 <10 <10

<10 <10 <10 <10 <10 ^10

Curlyleaf Pondweed

13 14 24 26 32

40 43 47

12484480 12484500 12500430 12500442 12503950

12507585 12508620 12509050

YK0139SP <10 <10 <10 YK0118SP <10 <10 <10 YK0093SP <10 <10 <10 YK0096SP <10 <10 <10 YK0094SP <10 <10 <10

YK0060SP <10 <10 <10 YK0091SP <10 <10 <10 YK0045SP <10 <10 <10

<10 <10 <10 <10 <10 <10

Waterweed

26 38 43 49

12500442 12507508 12508620 12509710

YK0098SP <10 <10 <10 YK0088SP <10 <10 <10 YK0092SP <10 <10 <10 YK0036SP <10 <10 <10 1 1 1

90


Mapreferencenumber

Stationnumber

Fieldnumber

o.p'-DDD

p,p'- o,p'-DDD DDE

p,p'- o,p'-DDE DOT

P,P'DOT

Bridgelip Sucker

1214252636

1248444012484500125004371250044212505460


2010203020

20 1050 <10

150 1080 <10

190 20

60 10220 <10750 10180 20730 <10

3070

11050

200

Carp

40 12507585 YK0056SF 20 140 <10 1,700 <10 40

Asiatic Clam

4040404047

4747494951

5151

1250758512507585125075851250758512509050

1250905012509050125097101250971012510500

1251050012510500



YK0116SMYK0367SM

1010101030

2020402020

2010

60 <1050 <1060 <1040 <10

100 10

80 <10100 10180 20120 2080 10

60 <1070 10

310 <10280 <10330 <10230 <10530 <10

390 <10660 <10

1,300 301,300 70

410 <10

360 <10430 <10

8070806060

4070

32038050

3040

Western Pearlshell

1414

1248450012484500

YK0111SMYK0393SM

<10<10

<10 <10<10 <10

<10 <10<10 <10

<10<10

Crayfish

152549

124845501250043712509710

YK0013SDYK0003SDYK0022SD

<10<10<10

<10 <1060 <10

<10 <10

<10 <1050 <1040 <10

<1010

<10

Coontail

3851

1250750812510500

YK0079SPYK0034SP

<10<10

<10 <10<10 <10

<10 <1020 <10

<10<10

Curlyleaf Pondweed

1314242632

404347

1248448012484500125004301250044212503950

125075851250862012509050

YK0139SPYK0118SPYK0093SPYK0096SPYK0094SP

YK0060SPYK0091SPYK0045SP

<10<10<10<10<10

<10<10<10

<10 <10<10 <10<10 <10<10 <10<10 <10

<10 <10<10 <10<10 <10

<10 <10<10 <1020 <1010 <10

<10 <10

10 <1010 <1030 <10

<10<10<10<10<10

<10<10<10

Waterweed

26384349

12500442125075081250862012509710

YK0098SPYK0088SPYK0092SPYK0036SP

<10<10<10<10

<10 <10<10 <10<10 <10<10 <10

10 <10<10 <10<10 <1040 <10

<10<10<10<10

91



Station number

Field Hexachloro- a-Hexachloro- b-Hexachloro- number benzene cyclohexane cyclohexane

g-Hexachloro- cyclohexane d-Hexachloro- (lindane) cyclohexane Toxaphene

Bridgelip Sucker

12 14 25 26 36

12484440 12484500 12500437 12500442 12505460


<lS <lS<50 <50 <50 <50 410

Carp

40 12507585 YK0056SF <10 <10 <10 <10 220

Asiatic Clam

40 40 40 40 47

47 47 49 49 51

51 51

12507585 12507585 12507585 12507585 12509050

12509050 12509050 12509710 12509710 12510500

12510500 12510500



YK0116SM <10 <10 <10 YK0367SM <10 <10 <10

<10 <10 <10 <10 <10 <10 <10 <10 <10 <10

<10 <10 <10 <10 <10 <10 <10 <10 <10 <10

<10 <10 <10 <10

<50 <50 <50 <50 <50

<50 <50 <50 <50 <50

<50 <50

Western Pearlshell

14 14

12484500 12484500

YK0111SM <10 <10 <10 YK0393SM <10 <10 <10 as as <50

<50

Crayfish

15 2549

12484550 12500437 12509710

YK0013SD <10 <10 <10 YK0003SD <10 <10 <10 YK0022SD <10 <10 <10 as as

<50 <50 <50

Coontail

3851

12507508 12510500

YK0079SP <10 <10 <10 YK0034SP <10 <10 <10 as as <50

<50

Curlyleaf Pondweed

13 14 24 26 32

40 43 47

12484480 12484500 12500430 12500442 12503950

12507585 12508620 12509050

YK0139SP <10 <10 <10 YK0118SP <10 <10 <10 YK0093SP <10 <10 <10 YK0096SP <10 <10 <10 YK0094SP <10 <10 <10

YK0060SP <10 <10 <10 YK0091SP <10 <10 <10 YK0045SP <10 <10 <10

<iS <iS

<50 <50 <50 <50 <50

<50 <50<50

Waterweed

26 38 43 49

12500442 12507508 12508620 12509710

YK0098SP <10 <10 <10 YK0088SP <10 <10 <10 YK0092SP <10 <10 <10 YK0036SP <10 <10 <10

as as <50 <50 <50 <50

92


Mapreferencenumber

Station number

Field number

Total PCBS Dieldrin Endrin Mirex Kepone

Octochloro- styrene Dicofol

Bridgelip Sucker

1214252636

1248444012484500125004371250044212505460


<50<50<50<50220

30 <10 <10 -- -- <1010 <10 <10 <10 <10 <1030 <10 <10 <10 <10 <1040 <10 <10 <10 <10 <1080 <10 <10 -- -- <10

Carp

40 12507585 YK0056SF <50 20 20

Asiatic Clam

4040404047

4747494951

5151

1250758512507585125075851250758512509050

1250905012509050125097101250971012510500

1251050012510500



YK0116SMYK0367SM

<50<50<50<50<50

<50<50<50<50<50

<50<50

10 <10 <10 <10 <10 <1010 <10 <10 <10 <10 <1010 <10 <10 <10 <10 <1010 <10 <10 <10 <10 <1020 <10 <10 <10 <10 <10

20 <10 <10 <10 <10 <1010 <10 <10 -- -- <1040 <10 <10 <10 <10 <1030 <10 <10 7010 <10 <10 <10 <10 <10

10 <10 <10 <10 <10 <1010 <10 <10 -- -- <10

Western Pearlshell

14 14

12484500 12484500

YK0111SM YK0393SM

<50 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 -- -- <10

Crayfish

15 25 49

12484550 12500437 12509710

YK0013SD YK0003SD YK0022SD

<50 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10

Coontail

38 51

12507508 12510500

YK0079SP YK0034SP

<50 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10

Curly leaf Pondweed

13 14 24 26 32

40 43 47

12484480 12484500 12500430 12500442 12503950

12507585 12508620 12509050

YK0139SP YK0118SP YK0093SP YK0096SP YK0094SP

YK0060SP YK0091SP YK0045SP

<50 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10

<50 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10

Waterweed

26 38 43 49

12500442 12507508 12508620 12509710

YK0098SP YK0088SP YK0092SP YK0036SP

<50 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10

93

Table 29. Concentrations of semi-volatile organic compounds (polycyclic-aromatic hydrocarbons) in aquatic biota,Yakima River basin, Washington, 1989-90

[Concentrations in micrograms per kilogram, wet weight; whole fish were analyzed; see figure 1 for site locations]


Station number Station name Date

Field number

Moisture, in percent

Lipid, in percent

Rainbow Trout

16 12487200 Little Naches River at mouth nr Cliffdell 10-30-90 YK0201SF 76.4 4.56

Asiatic Clam

40 40 40 40 47

47 49 49 51 51

51

12507585 12507585 12507585 12507585 12509050

12509050 12509710 12509710 12510500 12510500

12510500

Yakima River at RM 72 ab Satus Cr nr Sunnyside Yakima River at RM 72 ab Satus Cr nr Sunnyside Yakima River at RM 72 ab Satus Cr nr Sunnyside Yakima River at RM 72 ab Satus Cr nr Sunnyside Yakima R at Euclid Br at RM 55 nr Grandview

Yakima R at Euclid Br at RM 55 nr Grandview Spring Creek at mouth at Whitstran Spring Creek at mouth at Whitstran Yakima River at Kiona Yakima River at Kiona


11-01-89 11-01-89 11-01-89 11-01-89 10-31-89

10-31-89 10-31-89 11-08-90 10-30-89 10-30-89

11-04-90

YK0100SM YK0101SM YK0102SM YK0103SM YK0082SM


YK0367SM

76.0 78.0 79.0 82.0 95.5

82.0 83.0 82.8 83.0 84.0

82.4

2.40 2.32 2.62 1.96 1.64

2.20 2.00 1.98 2.201.95

2.04

Western Fearlshell

14 14

12484500 12484500

Yakima River at Umtanum Yakima River at Umtanum

11-01-89 11-05-90

YK0111SM YK0393SM

86.0 90.2

.92

.42

Crayfish

15 25 49

12484550 12500437 12509710

Umtanum Creek nr mouth at Umtanum Wide Hollow Cr at W. Valley School nr Ahtanum Spring Creek at mouth at Whitstran

05-03-89 05-01-89 10-30-89


67.5 76.5 75.0

2.64 2.16 1.10

Coontail

3851

12507508 12510500

Toppenish Cr at Indian Church Rd nr Granger Yakima River at Kiona

11-03-89 10-30-89

YK0079SP YK0034SP

94.0 93.0

.10

.20

Curlyleaf Pondweed

13 14 24 26 32

40 43 47

12484480 12484500 12500430 12500442 12503950

12507585 12508620 12509050

Cherry Creek at Thrall Yakima River at Umtanum Moxee Drain at Thorp Rd nr Union Gap Wide Hollow Cr at Old STP at Union Gap Yakima R at Parker

Yakima River at RM 72 ab Satus Cr nr Sunnyside Satus Creek at gage at Satus Yakima R at Euclid Br at RM 55 nr Grandview

11-06-89 11-05-89 11-04-89 11-04-89 11-04-89

11-01-89 11-03-89 10-31-89



93.0 99.0 95.0 93.0 94.0

93.0 91.0 91.0

.20

.10

.20

.20

.30

.20

.30

.30

Waterweed

26 38 43 49

12500442 12507508 12508620 12509710

Wide Hollow Cr at Old STP at Union Gap Toppenish Cr at Indian Church Rd nr Granger Satus Creek at gage at Satus Spring Creek at mouth at Whitstran

11-04-89 11-03-89 11-03-89 10-30-89


94.0 93.0 94.0 93.0

.20

.20

.30

.20

94

Table 29. Concentrations of semi -volatile organic compounds (poly eye lie -aromatic hydrocarbons) in aquatic biota, Yakima River basin, Washington, 1989-90 Continued


Station number

Field number Napthalene

Phenan- Fluorene threne

Anthra cene

Fluor- anthrene Pyrene

1,2-Benz- anthracene

Rainbow Trout

16 12487200 YK0201SF 50 <10 <10 <10 <10 <10 <10

Asiatic Clem

40 40 40 40 47

47 49 49 51 51

51

12507585 12507585 12507585 12507585 12509050

12509050 12509710 12509710 12510500 12510500

12510500



YK0367SM

10 <10 <10 10 10

20 10 40

<10 10

40

A A AAA AA AA O OOOOO OOOOO

30 30 30 40 40

30 30 20 90 40

20

o ooooo ooooo

10 10 10 10

<10

10 10

<10 20 50

10

A AAA AAAAA

O OOOOO OOOOO o ooooo ooooo

Western Pearlshell

14 14

12484500 12484500

YK0111SM YK0393SM

<10 10

<10<10

<10 <10

<10 <10

<10 10

<10 <10

<10 <10

Crayfish

15 25 49

12484550 12500437 12509710


<10 <10 <10

<10 <10 <10

<10 <10 <10

<10 <10 <10

<10 <10 <10

<10 <10 <10

<10 <10 <10

Coontail

38 51

12507508 12510500

YK0079SP YK0034SP

<10 <10

<10 <10

<10 <10

<10 <10

<10 <10

<10 <10

<10 <10

Curlyleaf Pondweed

13 14 24 26 32

40 43 47

12484480 12484500 12500430 12500442 12503950

12507585 12508620 12509050



ooo oooooAAA AAAAA

OOO OOOOO

AAA AAAAA OOO OOOOO

AAA AAAAA OOO OOOOO

A A A AAA OOO OOOOO ooo ooooo

AAA AAAAA OOO OOOOO

Waterweed

26 38 43 49

12500442 12507508 12508620 12509710


<10 <10 <10 20

<10 <10 <10 10

<10<10 <10 40

<10 <10 <10 <10

<10 <10 <10 10

<10 <10 <10 <10

<10 <10 <10 <10

95

Table 29. Concentrations of semi-volatile organic compounds (polycyclic-aromatic hydrocarbons) in aquatic biota,Yakima River basin, Washington, 1989-90--Continued

Mapreferencenumber

Station number

Field number

Benzo(b)- Benzo(k)- Benzo(e)- Benzo(a)- 1,2,5,6-Dibenz- Benz Chrysene fluoranthrene fluoranthrene pyrene pyrene anthracene pery

Rainbow Trout

16 12487200 YK0201SF

51 12510500 YK0367SM

Asiatic Clam

4040404047

4749495151

1250758512507585125075851250758512509050

1250905012509710125097101251050012510500

YK0100SM <10 <10 <10 <10 <10 <10 <10YK0101SM <10 <10 <10 <10 <10 <10 <10YK0102SM <10 <10 <10 <10 <10 <10 <10YK0103SM <10 <10 <10 <10 <10 <10 <10YK0082SM <10 <10 <10 <10 <10 <10 <10

YK0085SM <10 <10 <10 <10 <10 <10 <10YK0080SM <10 <10 <10 <10 <10 <10 <10YK0408SM <10 <10 <10 <10 <10 <10 <10YK0115SM <10 <10 <10 <10 <10 <10 <10YK0116SM <10 <10 <10 <10 <10 <10 <10

Western Pearlshell

1414

1248450012484500

YK0111SM YK0393SM

Crayfish

152549

124845501250043712509710

YK0013SD YK0003SD YK0022SD 10

Coontail

3851

12507508 12510500

YK0079SP <10 <10 YK0034SP <10 <10 as <js as as as

Curlyleaf Pondweed

1314242632

404347

1248448012484500125004301250044212503950

125075851250862012509050

YK0139SP <10 <10YK0118SP <10 <10YK0093SP <10 <10YK0096SP <10 <10YK0094SP <10 <10

YK0060SP <10 <10YK0091SP <10 <10YK0045SP <10 <10

<10 <10 <10 <10 <10<10 <10 <10 <10 <10<10 10 <10 <10 <10<10 10 <10 <10 <10<10 <10 <10 <10 <10

<10 <10 <10 <10 <10<10 <10 <10 <10 <10<10 10 <10 <10 <10

Waterweed

26384349

12500442125075081250862012509710


10

1010

96

QUALITY-ASSURANCE DATA

Tables showing quality-assurance data have been grouped and presented by sampling media: whole-water data are listed in tables 30-38, filtered-water data in tables 39-44, suspended-sediment data in tables 45-50, bed-sediment data in tables 51-53, and aquatic-biota data in tables 54-57. For whole-water analyses, data are arranged alphabetically by chemical family.

97

Table 30A. Concentrations of carbamate compounds in replicate whole-water samples from Cle Elum River above Cle Elum Lake near Roslyn, Washington, July 26, 1988, at 1000 hour and 1015 hour

[Station number 12478300; map reference number 3 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 15 minutes apart; "<" » less than; less-than values were set equal to zero for calculations]

Concentration, in nanofcrams per literParametercode

39053825878258639750

82615825843028239051

77441826133905230296

Replicate 1 Replicate 2(not spiked) (not spiked) Difference

Constituent

AldicarbAldicarb sulfoneAldicarb sulfoxideCarbaryl

Carbofuran3-HydroxycarbofuranMethiocarbMethomyl

1-NaphtholOxamylFrophamPropoxur

A

<500<500<500<500

<500<500<500<500

<500<500<500<500

B

<500<500<500<500

<500<500<500<500

<500<500<500<500

|A - B|

0000

0000

0000

Table 30B. Concentrations of carbamate compounds in replicate whole-water samples from Cherry Creek at Thrall, Washington, June 2, 1988, at 1400 hour and 1405 hour

[Station number 12484480; map reference number 13 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 5 minutes apart"<" » less than; less-than values were set equal to zero for calculations]

Parametercode

39053825878258639750

82615825843028239051

77441826133905230296

Constituent


Carbofuran3-HydroxycarbofuranMethiocarbMethomyl

1-NaphtholOxamylProphamPropoxur

§oncentrstion,eplicate 1(not spiked)

A

<500<500<500<500

<500<500<500<500

<500<500<500<500

, in nanogramsReplicate 2(not spiked)

B

<500<500<500<500

<500<500<500<500

<500<500<500<500

per liter

Difference|A - B|

0000

0000

0000

Table 30C. Concentrations of carbamate compounds in replicate whole-water samples from Wide Hollow Creek near mouth at Union Gap, Washington, November 15, 1988, at 1330 hour and 1430 hour

[Station number 12500445; map reference number 27 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 1 hour apart; "<" * less than; less-than values were set equal to zero for calculations]

Parametercode

39053825878258639750

82615825843028239051

77441826133905230296

Constituent


Carbofuran3 -Hydr oxy c arbofur anMethiocarbMethomyl


Concentration,Replicate 1(not spiked)

A

<500<500<500<500

<500<500<500<500

<500<500<500<500

. in nanogramsReplicate 2(not spiked)

B

<500<500<500<500

<500<500<500<500

<500<500<500<500

per liter

Difference|A - B|

0000

0000

0000

98

Table SOD. Concentrations of carbamate compounds in replicate whole-water samples from Moxee Drain at Thorp Road near Union Gap, Washington, May 6, 1988, at 0930 hour and 0940 hour

[Station number 12500430; map reference number 24 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 10 minutes apart; "<" = less than; less-than valuea were set equal to zero for calculations]

Parametercode

390538258782586

39750826158258439051

774418261339052

Constituent

AldicarbAldicarb sulfoneAldicarb sulfoxide

CarbarylCarbofuran3 -Hydroxyc arbof ur anMethomyl

1-NaphtholOxamylPropham


A

<500<500<500

<500<500<500<500

<500<500<500

, in nanoxramsReplicate 2(not spiked)

B

<500<500<500

<500<500<500<500

<500<500<500

per liter

Difference|A - B|

000

0000

000

Table 30E. Concentrations of carbamate compounds in replicate whole-water samples from Granger Drain at mouth near Granger, Washington, July 28, 1988, at 0930 hour and 1015 hour

[Station number 12505460; map reference number 36 figure 1; in addition to analytical variability, the results include temporal variebility, because the samples were collected 45 minutes apart; "<" = less than; less-than values were set equel to zero for calculations]

Parametercode

39053825878258639750

82615825843028239051

77441826133905230296

Constituent


Carbofuran3 -Hydroxyc arbof ur anMethiocarbMethomyl



A

<500<500<500<500

<500<500<500<500

<500<500<500<500

, in nanoKramsReplicate 2(not spiked)

B

<500<500<500<500

<500<500<500<500

<500<500<500<500

per liter

Difference|A - B|

0000

0000

0000

Table 30F. Concentrations of carbamate compounds in replicate and spiked whole-water samples from Sulphur Creek Wasteway near Sunnyside, Washington, August 31, 1988, at 1530 hour and 1630 hour

[Station number 12508850; map reference number 46 figure 1; in addition to analytical variebility, the results include temporal variability, because the samples were collected 1 hour apart; "ns" = not spiked; "<" = less than; less-than values were set equal to zero for calculations]

Concentration, in nanottrams per liter

Laboratory resultsParametercode

39053825878258639750

82615825843028239051

77441826133905230296

Replicate 1

Constituent

AldicarbAldicarb sulfoneAldicarb sulfoxideCarberyl

Carbofuran3 -Hydroxyc arbo fur anMethiocarbMethomyl


(not spiked)A

<500<500<500<500

<500<500<500<500

<500<500<500<500

Replicate 2(not spiked)

B

<500<500<500<500

<500<500<500<500

<500<500<500<500

Calculated concentration Analytical

Replicate 3 in replicate 3 recovery,Difference|A - B|

0000

0000

0000

(spiked)C

310nsns350

510nsns400

nsnsnsns

(spiked)D

430nsns470

460nsns510

nsnsnsns

in percentC x 100

72nsns74

110nsns78

nsnsnsns

/ D

99

Table 30G. Concentrations of carbamate compounds in spiked whole-water samples from Buckskin Slough below Gleed Ditch near Gleed, Washington, May 22, 1991, at 1100 hour and 1107 hour

[Station number 12496550; map reference number 21 figure 1; "<" = less than; less-than values were set equal to zero for calculations]

Concentration, in nanoKrams per literLaboratory results

Parametercode

39750826153905182613

Constituent

CarbarylCarbofuranMethomylOxamyl


A

<500<500<500<500

Replicate 2(spiked)

B

<500<500<500<500

Calculatedconcentrationin replicate 2

C

1,1001,1001,1001,100

Recovery,in percentB x 100 /C

0000

Table 30H. Concentrations of carbamate compounds in spiked whole-water samples from Buckskin Slough below Gleed Ditch near Gleed, Washington, August 7, 1991, at 1000 hour and 1007 hour

[Station number 12496550; map reference number 21 figure 1; "<" = less than; less-than values were set equal to zero for calculations]

Para meter code Constituent

Concentration, in nanograms per liter CalculatedLaboratory results

Replicate (not spiked)

Replicate 2 (spiked)

concentration in replicate 2

Recovery, in perce:int

/ C

39750 Carbaryl82615 Carbofuran39051 Methomyl82613 Oxamyl

<500 <500 <500 <500

9001,000

900600

1,1001,1001,1001,100

82918254

100

Table 31A. Concentrations of chlorophenoxy-acid herbicides, dicamba, and picloram in replicate whole-water samples from Cle Elum River above Cle Elum Lake near Roslyn, Washington, July 26, 1988, at 1000 hour and 1015 hour

[Station number 12478300; map raference number 3 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected IS minutes apart; 2,4-D - (2,4-dichlorophenoxy)acetic acid; 2,4-DP = dichlorprop; 2,4,5-T - (2,4,5-trichlorophenoxy)acetic acid; "<" « less than; less-than values were set equal to zero for calculations]

Parametercode

820523973082183

397603972039740

Constituent

Dicamba2,4-D2,4-DP

FenopropPicloram2,4,5-T

Concentration.Replicate 1(not spiked)

A

<10<10<10

<10<io<10

, in nanoxrams per literReplicate 2(not spiked) Difference

B |A - B|

<io o<10 0<10 0

< 10 0< 10 0< 10 0

Table 31B. Concentrations of chlorophenoxy-acid herbicides, dicamba, and picloram in replicete whole-water samples from Cherry Creek at Thrall, Washington, June 2, 1988, at 1400 hour and 1405 hour

[Station number 12484480; map reference number 13 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 5 minutes apart; 2,4-D - (2,4-dichlorophenoxy)acetic acid; 2,4-DP - dichlorprop; 2,4,5-T - (2,4,5-trichloropheno3ty)acetic acid; "<" - less than; less-than values were set equal to zero for calculations]

Parametercode

820523973082183

397603972039740

Constituent

Dicamba2,4-D2,4-DP



A

140150<10

<10<10<10

. in nanoKramsReplicate 2(not spiked)

B

140140<10

<10<10<10

per liter

Difference|A - B|

0100

000

Table 31C. Concentrations of chlorophenoxy-acid herbicides, dicamba, and picloram in replicate whole-water samples from Wide Hollow Creek near mouth at Union Gap, Washington, November 15, 1988, at 1330 hour and 1430 hour

[Station number 12500445; map reference number 27 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 1 hour apart; 2,4-D - (2,4-dichlorophenoxy acetic acid; 2,4-DP - dichlorprop; 2,4,5-T = (2,4,5-trichlorophenoxy)acetic acid; "<"» less than; less-than values were set equal to zero for calculations]


Concentration, in nanograms per liter Replicate 1 (not spiked)

A

Replicate 2(not spiked) Difference

B~^ |A - B|

820523973082183

397603972039740

Dicamba2,4-D2,4-DP

Fenoprop Picloram 2,4,5-T

101

Table 31D. Concentrations of chlorophenoxy-acid herbicides, dicamba, and picloram in replicate whole-water samples from Moxee Drain at Thorp Road near Union Gap, Washington, May 6, 1988, at 0930 hour and 0940 hour

[Station number 12500430; map reference number 24 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 10 minutes apart; 2,4-D = (2,4-dichlorophenoxy)acetic acid; 2,4-DP - dichlorprop; 2,4,5-T = (2,4,5-trichlorophenoxy)acetic acid; "<" = less than; less-than values were set equal to zero for calculations]

Parametercode

820523973082183

397603972039740

Constituent

Dicamba2,4-D2,4-DP



A

3020

<10

<10<10<10

, in nanogramsReplicate 2(not spiked)

B

30120<10

<10<10<10

per liter

Difference|A - B|

0100

0

000

Table 31E. Concentrations of chlorophenoxy-acid herbicides, dicamba, and picloram in replicate whole-water samples from Granger Drain at mouth near Granger, Washington, July 28, 1988, at 0930 hour and 1015 hour

[Station number 12505460; map reference number 36 figure 1; addition to analytical variability, the results include te

Para- meter code Constituent

Concentration, in nanograms per literRaplicate 1(not spiked)

A

Replicate 2(not spiked) Difference

B |A - B|

820523973082183

397603972039740

Dicamba2,4-D2,4-DP

Fenoprop Picloram 2,4,5-T

40 390 <10

<10 <10 <10

40 410 <10

<10 <10 <10

0200

000

102

Table 31F. Concentrations of chlorophenoxy-acid herbicides, dicamba, and picloram in replicate and spiked whole-water samples from Sulphur Creek Wasteway near Sunnyside, Washington, August 31, 1988, at 1530 hour and 1630 hour

[Station number 12508850; map reference number A6 figure 1; in eddition to analytical variability, the results include temporal variability, beceuse the samples were collected 1 hour apart; "ns" - not spiked; 2,4-D - (2,4-dichlorophenoxy)acetic acid; 2.A-DP - dichlorprop; 2,4,5-T - (2,4,5-trichlorophenoxy)acetic acid; "<" - less than; less-than velues were set equal to zero for calculations]

Concentrstion. in nanograma per literLaboratory results

Parameter code

820523973082183

397603972039740

Constituent

Dicamba2,4-D2,4-DP



A

1050

<10

<10<10<10


B

1060

<10

<10<10«10

Difference|A - B|

0100

000

Replicate 3(spiked)

C

20360<10

280<10220

Calculatedconcentrationin replicate(spiked)

D

ns680ns

510ns450

3 Recovery,in perccC x 100

ns53ns

55ns49

»nt/ D

Table 31G. Concentrations of chlorophenoxy-ecid herbicides, dicambe, and picloram in replicate end spiked whole-water samples from Buckskin Slough below Gleed Ditch near Gleed, Washington, May 22, 1991, et 1100 hour and 1107 hour

[Station number 12496550; map reference number 21 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 7 minutes apart; 2,4-0 - (2,4-dichlorophenoxy)acetic acid; 2,4,5-T - (2,4,5-trichlorophenoxy)acetic acid; "<" - less than; less-than values were set equal to zero for calculations]

Concentretion. in nanograms per liter Calculated


Laboratory resultsReplicate 1 (not spiked)


concentretion Recovery, in replicate 2 in percent

x 100 / C

8205239730397603972039740

Dicamba2,4-DFenopropPicloram2,4,5-T

6090606060

110110110110110

5482545454

103

Tabl

e 32A.

Concentrations of Organochlorine and

Organophosphorus

compounds

in replicate whole-water samples

from Cle

Elum River

abov

e Cl

e Elum Lake near Ro

slyn

, Washington,

July 26,

1988

, at

1000 hour an

d 10

15 hour

[Station number 12

4783

00;

map reference number 3 figure 1;

in addition to

analytical variability,

the

results

include

temporal variability, because th

e samples

were co

llec

ted

15

minutes apart; ODD

= dichlorodiphenyldichloroethane; DD

E =

dichlorodiphenyldichloroethylene; DO

T =

dichlorodiphenyl-

tric

hlor

oeth

ane;

HCH = hexachlorocyclohexane; PCB

gross

polychlorinated biphenyls; PCN

= gross

polychlorinated

naphthalenes; "<"

= le

ss than;

less-than values we

re set

equa

l to

ze

ro fo

r ca

lcul

atio

ns]

Para

meter

code

Constituent

Concentration, in

nanograms

Replicate 1

Replicate 2

(not

spiked)

(not sp

iked

)A

B

per

liter

Difference

|A -

B|


39330

Aldrin

3935

0 gross

Chlordane

3936

0 p,p'-DDD

3936

5 p,p'-DDE

3937

0 p,p'-DDT

3938

0 Dieldrin

39388

Endosulfan I

39390

Endrin

39410

Heptachlor

3942

0 Heptachlor ep

oxid

e

39340

Lindane (gamma-HCH)

39480

p,p' -Methoxychlor

39755

Mirex

3951

6 PC

B39250

PCN

39034

Perthane

39400

Toxaphene

<1

<1<100

<100

<1

<1<1

<1<1

<1

<1

<1<1

<1

<1

<1<1

<1<1

<1

<1

<1<10

<10

<10

<10

<100

<100

<100

<1

00

<100

<1

00<1,000

<1,000

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

Organophosphorus comp

ound

s

3957

0 Diazinon

39398

Ethion

39530

Malathion

39600

Methyl parathion

39790

Methyl trithion

39540

Parathion

3978

6 Trithion

<10

<10

<10

<10

<10

<10

<10

<10

<10

<10

<10

<10

<10

<10

0 0 0 0 0 0 0

Table

32B.

Concentrations of

Organochlorine and

Organophosphorus

comp

ound

s in replicate whole-water samples

from Cherry Creek at

Th

rall

, Washington, June 2, 1988,

at 14

00 hour an

d 14

05 hour

[Station number 12

4844

80;


in addition to

analytical va

riab

ilit

y, th

e results

include

temporal variability, because the

samples

were co

llec

ted

5 minutes ap

art;

ODD

dichlorodiphenyldichloroethane; DD

E =

dichlorodiphenyldichloroethylene; DO

T =

dichlorodiphenyl-

trichloroethane; HCH = hexachlorocyclohexane; PCB

= gross

polychlorinated bi

phen

yls;

PCN

= gross

polychlorinated

naphthalenes; "<

" =

less

than;

less-than values we

re se

t equal

to zero for

calculations]

Para

meter

code

Concentration, in na

nogr

ams

Replicate 1

Replicate 2

(not

spiked)

(not sp

iked

)Constituent

A

B

per

liter

Difference

|A -

B|

Organochlorine co

mpou

nds

39330

3935

039

360

39365

39370

3938

039

388

39390

39410

3942

0

39340

39480

3975

539

516

39250

39034

39400

Aldrin

<1

<1gross

Chlordane

<100

<100

p,p'-DDD

<1

<1p,p'-DDE

1 1

p,p'-DDT

<1

<1

Dieldrin

3 3

Endosulfan I

<1

<1Endrin

<1

<1Heptachlor

<1

<1Heptachlor ep

oxid

e <1

<1

Lindane (gamma-HCH)

<1

<1p,p' -Methoxychlor

<10

<10

Mirex

<10

<10

PCB

<100

<100

PCN

<100

<100

Perthane

<100

<100

Toxaphene

<1,000

<1,000

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

Organophosphorus co

mpou

nds

39570

39398

3953

039

600

39790

3954

039

786

Diazinon

<10

<10

Ethion

<10

<10

Malathion

<10

<10

Methyl parathion

<10

<10

Methyl trithion

<10

<10

Parathion

<10

<10

Trithion

<10

<10

0 0 0 0 0 0 0

Table

32C.

Conc

entr

atio

ns of

or

gano

chlo

rine

an

d Organophosphorus

comp

ound

s in

replicate whole-water

samp

les

from

Wide

Hollow Creek

near

mouth

at Union

Gap, Wa

shin

gton

, November 15

, 1988,

at 13

30

hour an

d 1430 ho

ur

[Sta

tion

nu

mber

12

5004

45;

map

reference nu

mber

27 figure 1;

in addition to


the

resu

lts

incl

ude

temp

oral

variability,

beca

use

the

samp

les

were collected

1 ho

ur apart; ODD

~ dichlorodiphenyldi

chlo

roet

hane

; DD

E -

dich

loro

diph

enyl

dich

loro

ethy

lene

; DOT

di

chlo

rodi

phen

yl-

trichloroethane; HCH

hexachlorocyclohexane; PCB

» gross

polychlorinated

biphenyls; PCN

= gross

polychlorinated

naph

thal

enes

; "<"

- less than;

less

-tha

n values we

re se

t eq

ual

to ze

ro for

calc

ulat

ions

]

Table

32D.

Concentrations of

or

gano

chlo

rine

an

d Or

gano

phos

phor

us

comp

ound

s in replicate wh

ole-

wate

r sa

mple

s from Moxee Dr

ain

at

Thor

p Ro

ad near Union

Gap, Wa

shin

gton

, Ma

y 6,

19

88,

at 0930 ho

ur

and

0940 ho

ur

[Sta

tion

nu

mber

12

5004

30;

map

reference

number 24 figure 1;

in addition to


the

resu

lts

incl

ude

temp

oral

variability,

beca

use

the

samp

les

were collected

10

minu

tes

apart; OD

D -

dich

loro

diph

enyl

dich

loro

etha

ne;

DDE

- di

chlo

rodi

phen

yldi

chlo

roet

hyle

ne;

DOT

di

chlo

rodi

phen

yl-

tric

hlor

oeth

ane;

HCH

» he

xach

loro

cycl

ohex

ane;

PC

B »

gross

polychlorinated

biphenyls; PCN

» gr

oss

polychlorinated

naphthalenes;

"<"

» less than;

less-than

values we

re set

equal

to ze

ro fo

r ca

lcul

atio

ns]

O

Cn

Concentration, in

nan

ogra

msPara

meter

code

Cons

titu

ent

Repl

icat

e 1

Repl

icat

e 2

(not

sp

iked

) (not sp

iked

) A

B

Orga

noch

lori

ne

39330

39350

39360

3936

5 39370

39380

3938

839

390

3941

0 39420

39340

39480

39755

39516

39250

39034

39400

Aldr

ingross

Chlo

rdan

e p,p'-DDD

p,p'

-DDE

p,p'-DDT

Diel

drin

Endo

sulf

an I

Endr

inHe

ptac

hlor

He

ptac

hlor

ep

oxid

e

Lind

ane

(gamma-HCH)

p,p' -Methoxychlor

Mire

xPCB

PCN

Pert

hane

Toxa

phen

e

<1<1

00 1 2 11 <1 <1 <i

o <i

o<1

00<1

00

<100

<1,000

Organophosphorus

39570

3939

839530

39600

39790

39540

3978

6

Diaz

inon

Ethi

onMalathion

Methyl pa

rath

ion

Methyl trithion

Para

thio

nTrithion

<10

<10

<10 <iS <10

<10

compounds

<1<100

1 2 13 <1 <} <s<100

<100

<100

<1,0

00

comp

ound

s

<10

<10

<10

<10

<io

<io

per

liter

Difference

|A -

B|

0 0 0 0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

Para

me

ter

code

Cons

titu

ent

Conc

entr

atio

n ,

Repl

icat

e 1

(not sp

iked

)A

. in

nan

ogra

msReplicate

2(not sp

iked

)B

per

liter

Diff

eren

ce~TS

- B|

Orga

noch

lori

ne co

mpou

nds

39330

39350

39360

39365

3937

0

3938

039

388

39390

39410

3942

0

3934

039

480

39755

3951

639

250

39034

39400

Aldrin

gros

s Ch

lord

ane

p,p'

-DDD

p,p' -DDE

p,p' -DOT

Diel

drin

Endosulfan I

Endr

inHe

ptac

hlor

Hept

achl

or ep

oxid

e

Lind

ane

(gamma-HCH)

p , p ' -Methoxychlor

Mirex

PCB

PCN

Pert

hane

Toxa

phen

e

<1<1

001 4 4 1 16 <1 <1 <1 <1 <10

<10

<100

<100

<100

<1,000

<1<1

00 <14 4 1

30 <1 <1 <1 <1 <10

<10

<100

<100

<100

<1,000

0 0 1 0 0 0 14 0 0 0 0 0 0 0 0 0 0

Organophosphorus co

mpou

nds

38932

39570

3939

839530

39600

39790

3954

039786

Chloryrifos

Diaz

inon

Ethi

onMa

lath

ion

Methyl pa

rath

ion

Methyl trithion

Para

thio

nTr

ithi

on

10<1

0<1

0<1

0<1

0

<10

<10

<10

10<1

0<1

0<1

0<1

0

<10

<10

<10

0 0 0 0 0 0 0 0

Table 32E.

Concentrations of

Organochlorine and

Organophosphorus

compounds

in replicate whole-water samples

from Granger Drain at

mouth near Gr

ange

r, Wa

shin

gton

, Ju

ly 28

, 19

88,

at 09

30 ho

ur and

1015

hour

[Station number 12505460;


in addition to


the

resu

lts

include

temporal variability, because th

e samples

were collected 45

minutes ap

art;

DDD

» dichlorodiphenyldichloroethane; DDE "

dichlorodiphenyldichloroethylene; DDT - dichlorodiphenyl-

trichloroethane; HCH * hexachlorocyclohexane; PCB

= gross

polychlorinated biphenyls; PCN

= gr

oss

polychlorinated

naphthalenes; "<"

« le

ss th

an;

less-than values were set

equal

to ze

ro for

calculations]

Para

meter

code

Constituent

Concentration ,

Replicate 1

(not spiked)

X

. in

nan

ogra

msReplicate 2

(not spiked)

5

per

liter

Difference

|A -

B|

Organochlorine co

mpou

nds

39330

39350

39360

39365

3937

0

39380

3938

839390

39410

39420

39340

39480

3975

53951

639250

39034

39400

Aldrin

gross

Chlordane

p,p'-DDD

p.p'-DDE

p.p'-DDT

Dieldrin

Endosulfan I

Endrin

Heptachlor

Heptachlor epoxide

Lindane (gamma-HCH)


Mirex

PCS

PCN

Perthane

Toxaphene

<1<1007

53 43 30 76 <1 <1 <1 <1<10

<10

<100

<100

<100

<1,000

<1<100 10 47 39 17 83 <1 <1 <1 <1

<10

<10

<100

<100

<100

<1,000

0 0 3 6 4 13 7 0 0 0 0 0 0 0 0 0 0

Organophosphorus co

mpou

nds

39570

3939

839530

39600

39790

39540

3978

6

Diazinon

Ethion

Malathion

Methyl parathion

Methyl trithion

Parathion

Trithion

20<10

<10

<10

<10

<10

<10

10<10

<10

<10

<10

<10

<10

10 0 0 0 0 0 0

Table

32F.

Concentrations of

Organochlorine an

d Organophosphorus

comp

ound

s in

replicate an

d sp

iked

whole-water samples

from Sulphur

Creek Wasteway near Su

nnys

ide,

Washington,

August 31,

1988

, at 15

30

hour and

1630

hour I/

[Station number 12

5088

50;

map reference number 46 figure 1; in

addition

to analytical variability, th

e results

incl

ude

temporal variability,

because the

samples

were co

llec

ted

1 hour ap

art;

DD

D =

dichloro-

diphenyl- dichloroethane; DD

E =

dichlorodiphenyldichloroethylene;

DDT

= dichlorodiphenyltrichloroethane; HCH = hexachlorocyclohexane;

PCS

= gross

polychlorinated bip

heny

ls;

PCN

= gross

polychlorinated

naphthalenes; "<"

= le

ss th

an;

less-than values were se

t equal

to

zero for

calc

ulat

ions

]

Para

meter

code

Constituent

Concentration

Replicate 1

(not sp

iked

)A

, in

nanograms

Replicate 2

(not

spiked)

B

per

liter

Difference

|A-

B|

Organochlorine co

mpou

nds

39330

39350

39360

3936

5 39370

39380

39388

39390

39410

39420

39340

39480

3975

539

516

39250

3903

439400

Aldrin

gross

Chlordane

p,p'-DDD

p,p'-DDE

p.p'-DDT

Dieldrin

Endosulfan I

Endrin

Heptachlor

Heptachlor epoxide

Lindane (gamma-HCH)


Mirex

PCS

PCN

Perthane

Toxaphene

<1<100 1 7 6 6 11

<1 <1

<1 <1

<10

<10

<100

<100

<100

<1,0

00

<1<1

001 7 5 6 5

<1 <1

<1 <1

<10

<10

<100

<100

<100

<1,000

0 0 0 0 1 0 6 0 0 0 0 0 0 0 0 0 0

Organophosphorus co

mpou

nds

3957

039398

39530

39600

39790

39540

3978

6

Diazinon

Ethion

Malathion

Methyl parathion

Methyl trithion

Parathion

Trithion

10<1

0<10

<10

<10

<10

<10

<10

<10

<10

<10

<10

<10

<10

10 0 0 0 0 0 0

I/ A third replicate of this sa

mple

wa

s collected at 16

00 hour,

and

it was

spiked with Organochlorine co

mpou

nds,

including

4,60

0 nanograms pe

r liter

(ng/

L) of

to

xaph

ene.

Th

e laboratory reported

4,000

ng/L.

The

othe

r Organochlorine co

mpou

nds

could

not

be

quantified because of analytical interference,

possibly associated

with th

e relatively la

rge

toxa

phen

e sp

ike

(Fra

nk W. Wi

ebe,

U.S.

Geological Su

rvey

, Ar

vada

, Colorado,

written commun., December 19

91).

Table 32G. Concentrations of organochlorine and organophosphorus confounds in replicate whole-water samples from a well (station identifier: 12N/19E-09H01), Washington, January 20, 1989, at 0730 hour and 0737 hour

[Station number 463234120261601; map reference number 59 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 7 minutes apart; DDD « dichlorodiphenyldichloroethane; DDE - dichlorodiphenyldichloroethylene; DDT « dichlorodiphenyltrichloroethane; HCH « hexachlorocyclohexane; PCB * gross polychlorinated biphenyls; PCN * gross polychlorinated naphthalenes; "<" = less than; less-than values were set equal to zero for calculations]


Concentration, in nanoKrams per liter Replicate 1Replicate 2 (not spiked) (not spiked) Difference

A SLfferenci |A - B|


3933039350393603936539370

Aldringross Chlordanep,p'-DDDp.p'-DDEp,p'-DDT

<1 <1 0<100 <100 0

<1 <1 0<1 <1 0<1 <1 0

39380 Dieldrin39388 Endosulfan I39390 Endrin39410 Heptachlor39420 Heptachlor epoxide

39340 Lindane (ganxna-HCH)39480 p,p'-Methoxychlor39755 Mirex39516 PCB39250 PCN

39034 Perthane39400 Toxaphene

<100 <100

<100 <1,000

<100 <100

<100 <1,000


39570 Diazinon39398 Ethion39530 Malathion39600 Methyl parathion39790 Methyl trithion

39540 Parathion39786 Trithion

107

Table 33A. Concentrations of phenols and cresols (acid-extractable compounds) in replicate whole-water samples from Wide Hollow Creek near mouth at Union Gap, Washington, November 15, 1988, at 1330 hour and 1430 hour

[Station number 12500445; map reference number 27 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 1 hour apart; "<" ~ less than; less-than values were set equal to zero for calculations]

Para meter code

34586 34601 34606

34657 34616 34591

34646 34452 39032

34694 34621

Constituent

2-Chlorophenol 2 , 4-Dichlorophenol 2 , 4-Dimethylphenol

4 , 6-Dinitro-o-cresol 2, 4-Dinitrophenol 2-Hitrophenol

4-Hitrophenol P-chloro-m-cresol Pentachlorophenol

Phenol 2,4, 6-Trichlorophenol

ConcentrationReplicate 1 (not spiked)

A

<5,000 <5,000 <5,000

<30,000 <20,000 <5,000

<30,000 <30,000 <30,000

<5,000 <20,000

. in nanogramsReplicate 2 (not spiked)

B

<5,000 <5,000 <5,000

<30,000 <20,000 <5,000

<30,000 <30,000 <30,000

<5,000 <20,000

per liter

Difference|A - B|

0 0 0

0 0 0

0 0 0

0 0

Table 33B. Concentrations of phenols and cresols (acid-extractable compounds) in replicate and spiked whole-water samples from Sulphur Creek Wasteway near Sunnyside, Washington, August 31, 1988, at 1530 hour and 1630 hour

[Station number 12508850; map reference number 46 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 1 hour apart; "<" = less than; less-than values were set equal to zero for calculations]

Concentrations. in nanograms per liter

Laboratory resultsPara meter code

34586 34601 34606

34657 34616 34591

34646 34452 39032

34694 34621

Constituent

2-Chlorophenol 2 , 4-Dichlorophenol 2 , 4-Dimethylphenol

4 , 6-Dinitro-o-cresol 2, 4-Dinitrophenol 2-Nitrophenol

4-Hitrophenol P-chloro-m-cresol Pentachlorophenol

Phenol 2,4, 6-Trichlorophenol

Replicate 1 Replicate 2 (not spiked) (not spiked) Difference

A B |A - B|

<5,000 <5,000 <5,000

<30,000 <20,000 <5,000

<30,000 <30,000 <30,000

<5,000 <20,000

<5,000 <5,000 <5,000

<30,000 <20,000 <5,000

<30,000 <30,000 <30,000

<5,000 <20,000

0 0 0

0 0 0

0 0 0

0 0


C

21,000 27,000 22,000

230,000 93,000 30,000

73,000 130,000 170,000

<5,000 100,000

Calculated concentration in replicate 3 Recovery, (spiked) in percent

D

29,000 29,000 29,000

144,000 86,000 29,000

144,000 144,000 144,000

29,000 86,000

C x 100 / D

7293 76

160 110 100

51 90

120

<17 120

108

Table 34A. Concentrations of txiazine, acetamide, chloroacetanilide, and other pesticides in spiked whole-water samples from Cle Elum River above Cle Elum Lake near Roslyn, Washington, July 26, 1988, at 0930 hour and 1000 hour

[Station number 12478300; map reference number 3 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 30 minutes apart; "<" - less than; less-than values were set equal to zero for calculations]

Concentrations, in nanograms per literLaboratory results

Parametercode

778253963082612

826113905539030

Constituent

AlachlorAtrazineMetolachlor

MetribuzinSimazineTrifluralin


A

<100<100<100

<100<100<100

CalculatedReplicate 2 concentration(spiked)

B

520330500

470350430

in replicate 2C

480340420

420350490

Recovery,in percentB x 100

11097

120

11010088

/ c

Table 34B. Concentrations of triazine, acetamide, chloroacetanilide, and other pesticides in replicate whole-water samples from Cherry Creek at Thrall, Washington, June 2, 1988, at 1400 hour and 1405 hour

[Station number 12484480; map reference number 13 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 5 minutes apart; "<" = less than; less-than values were set equal to zero for calculations]

Para meter code

7782582184396303023430235

3023630245817573025430255

3026482612826113905639057

3029539024390553905430311

3903030324

Constituent

AlachlorAmetrynAtrazineBromacilButachlor

ButylateCarboxinCyanazineCycloateDiphenamid

HexazinoneMetolachlorMetribuzinPrometonePrometryn

PropachlorPropazineSimazineSimetrynTerbacil

TrifluralinVernolate


A

<100<100

20<100<100

<100<100<100<100<100

<100<100<100<100<100

<100<100<100<100<100

<100<100

, in nanoKramsReplicate 2 (not spiked)

B

<100<100

60<100<100

<100<100<100<100<100

<100<100<100<100<100

<100<100

40<100<100

<100<100

per liter

Difference |A - B|

00

4000

00000

00000

00

4000

00

109

Table SAC. Concentrations of triazine, acetamide, chloroacetanilide, and other pesticides in replicate whole-water samples from Wide Hollow Creek near mouth at Union Gap, Washington, November 15, 1988, at 1330 hour and 1430 hour

[Station number 125004A5; map reference number 27 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 1 hour apart; "<" = less than; less-than values were set equal to zero for calculations]

Para meter code

7782582184396303023A30235

30236302A5817573025A30255

3026482612826113905639057

302953902A390553905A30311

390303032A

Constituent







A

<100<100<100<100<100

<100<100<100<100<100

<100<100<100<100<100

<100<100<100<100<100

<100<100


B

<100<100<100<100<100

<100<100<100<100<100

<100<100<100<100<100

<100<100<100<100<100

<100<100

per liter

Difference|A

00000

00000

00000

00000

00

- B|

Table 34D. Concentrations of triazine, acetamide, chloroacetanilide, and other pesticides in replicate whole-water samples from Moxee Drain at Thorp Road near Union Gap, Washington, May 6, 1988, at 0930 hour and 09AO hour

[Station number 12500A30; map reference number 2A figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 10 minutes apart; "<" = less than; less-than values were set equal to zero for calculations]

Para meter code

778258218A396303023430235

30236302A5817573025A30255

3026A82612826113905639057

3029539024390553905430311

3903030324

Constituent







A

<100<100

30<100<100

<100<100<100<100<100

<100<100<100<100<100

<100<100

20<100<100

<100<100


B

<100<100

30<100<100

<100<100<100<100<100

<100<100<100<100<100

<100<100

20<100<100

<100<100

per liter

Difference |A - B|

00000

00000

00000

00000

00

110

Table 34E. Concentrations of triazine, acetamide, chloroacetanilide, and other pesticides in spiked whole-water samples from Granger Drain at mouth near Granger, Washington, July 28, 1988, at 0930 hour and 1015 hour

[Station number 12505460; map reference number 36 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 45 minutes apart; "<" = less than; less-than values were set equal to zero for calculations]

Concentrations, in nanograms tier literLaboratory results

Para meter code

77825 39630 82612

Constituent

Alachlor Atrazine Metolachlor

Replicate 1 (not spiked)

A

<100 47

<100


B

570 430 570

Calculated concentration in replicate 2

C

570 410 510

Recovery, in percentB x 100 / C

100 100 110

82611 Metribuzin <10039055 Simazine 10439030 Trifluralin 42

530500510

500420580

11012088

Table 34F. Concentrations of triazine, acetamide, chloroacetanilide, and other pesticides in replicate and spiked whole-water samples from Sulphur Creek Wasteway near Sunnyside, Washington, August 31, 1988, at 1530 hour and 1630 hour

[Station number 12508850; map reference number 46 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 1 hour apart; "ns" = not spiked; "<" = less than; less-than values were set equal to zero for calculations]

Concentrations in nanograms

Laboratory resultsParametercode

7782582184396303023430235

3023630245817573025430255

3026482612826113905639057

3029539024390553905430311

3903030324

Replicate 1 Replicate 2

per literCalculated concentration

Replicate 3 in replicate 3 Recovery,(not spiked) (not spiked) Difference

Constituent






A

<100<100

34<100<100

<100<100<100<100<100

<100<100<100<100<100

<100<100

29<100<100

<100<100

B

<100<100

34<100<100

<100<100<100<100<100

<100<100<100<100<100

<100<100

24<100<100

<100<100

|A - B|

00000

00000

00000

00500

00

(spiked) (spiked)C

530ns440nsns

nsnsnsnsns

ns530610nsns

nsns310nsns

470ns

D

670ns510nsns

nsnsnsnsns

ns600590nsns

nsns530nsns

690ns

in percentC x 100 / D

79ns86nsns

nsnsnsnsns

ns88

100nsns

nsns58nsns

68ns

111

Table 35A. Concentrations of volatile organic compounds in replicate whole-water samples from Wide Hollow Creek near mouth at Union Gap, Washington, November 15, 1988, at 1330 hour and 1430 hour

[Station number 12500445; map reference number 27 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 1 hour apart; "<" = less than; less-than values were set equal to zero for calculations]

Concentration, in nanograms per literPara meter code

3403081555321013210434413

3210234301343113210634418

7727577277347043210577651

3021734536345663457134668

3449632103345014561734541

7717377170771683437134423

7712877562345163447534010

3454634699345063451139180

34488774433917581551


Constituent

BenzeneBromobenzeneBromodi chlorome thaneBromoformBromome thane

Carbon tetrachlorideChlorobenzeneChloroethaneChloroformChlorome thane

1 , 2-Chlorotoluene1, 4-Chlorotoluenecis-1, 3-DichloropropeneDibromochlorome thane1 , 2-Dibromoethane

D ib r omome th an e1 , 2-Dichlorobenzene1, 3-Dichlorobenzene1, 4-DichlorobenzeneDichlorodifluorome thane

1, 1-Dichloroethane1 , 2-Dichloroethane1, 1-Dichloroethene1 , 2-Dichloroethene1, 2-Dichloropropane

1, 3-Dichloropropane2, 2-Dichloropropane1, 1-DichloropropeneEthylbenzeneMethylene chloride

Styrene1,1,1, 2-Tetrachloroethane1,1,2, 2-TetrachloroethaneTetrachloroetheneToluene

trans-1, 2-Dichloroethenetrans-1, 3-Dichloropropene1,1, 1-Tri chloroethane1,1, 2-TrichloroethaneTrichloroethene

Trichlorofluorome thane1,2,3-TrichloropropaneVinyl chlorideXylene

A

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200

B

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200

|A - B|

00000

00000

00000

00000

00000

00000

00000

00000

0000

112

Table 3SB. Concentrations of volatile organic compounds in replicate and spiked whole-water samples from Sulphur Creek Wasteway near Sunnyside, Washington, August 31, 1988, at 1530 hour and 1630 hour

[Station number 12508850; map reference number 46 figure 1; in addition to analytical variability, the results include temporal variability, because the samples were collected 1 hour apart; "ns" = not spiked; "<" = less than; less-than values were set equal to zero for calculations]

Concentrations, in nanograms per liter

Laboratory resultsPara meter code

3403081555321013210434413

3210234301343113210634418

7727577277347043210577651

3021734536345663457134668

34496321033450145617

3454177173771707716834371

3442377128775623451634475

3401034546346993450634511

3918034488774433917581551


Constituent A B |A - B|

BenzeneBromobenzeneBromodi chlor omethaneBromoformBromomethane

Carbon tetrachlorideChlorobenzeneChloroethaneChloroformChloromethane

1 , 2-Chlorotoluene1 , 4-Chlorotoluenecis-1 , 3-DichloropropeneDibromochloromethane1 , 2-Dibromoethane

Dibromomethane1 , 2-Dichlorobenzene1 , 3-Dichlorobenzene1 , 4-DichlorobenzeneDi chlor odi fluoromethane

1 , 1-Dichloroethane1,2-Di chloroethane1, 1-Dichloroethene1 , 2-Dichloroethene

1, 2-Dichloropropane1, 3-Dichloropropane2, 2-Dichloropropane1, 1-DichloropropeneEthylbenzene

Methylene chlorideStyrene1, 1, 1, 2-Tetrachloroethane1,1,2, 2-TetrachloroethaneTetrachloroethene

Toluenetrans-1, 2-Dichloroethenetrans-1 , 3-Dichloropropene1,1, 1-Tri chloroethane1, 1,2-Tri chloroethane

TrichloroetheneTrichlorofluoromethane1,2,3 -Tr i chlor opropaneVinyl chlorideXylene

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

<200<200<200<200<200

00000

00000

00000

00000

0000

00000

00000

00000

00000


C

3,200<2002,4002,6001,300

3,6003,4001,4004,9001,100

<200<200<2001,300<200

<200<200<200<200<200

9,2003,9006,700<200

2,400<200<200<200

3, £00

7,300<200<2002,7002,500

2,600<200<2003,6002,700

2,5004,600<2001,300<200

Calculated concentration in replicate (spiked)

D

5,000ns

5,0005,0005,000

5,0005,0005,0005,0005,000

nsnsns

5,000ns

nsnsnsnsns

5,0005,0005,000

ns

5,000nsnsns

5,000

5,000nsns

5,0005,000

5,000nsns

5,0005,000

5,0005,000

ns5,000

ns

3 Recovery, in percentC x 100 / D

64ns485226

7268289822

nsnsns26ns

nsnsnsnsns

18078

130ns

48nsnsns72

150nsns5450

52nsns7254

5092ns26ns

113

Tabl

e 36.

Conc

entr

atio

ns o

f pesticides i

n fi

lter

ed w

ater

(u

sing

the G

oulden la

rge-

samp

le e

xtra

ctor

), as

soci

ated

wit

h su

spen

ded

sediment

(analysis

of a

la

rge

sample o

f de-watered s

edim

ent

on a

glass-fiber f

ilter),

and

in w

hole w

ater

(conventional

anal

ysis

of

a 1- lit

er

sample o

f a

sedi

ment

-wa

ter

mixt

ure)

, Ya

kima

River b

asin,

Washington,

June 2

5-30,

1989

s in

nanograms p

er liter; see

figu

re 1

for

site

locations; "F"

= fi

lter

ed w

ater;

"S"

= su

spen

ded

sedi

ment

; "W

" = whole

wate

r;t,

but

belo

w qu

anti

fiab

le c

oncentration:

'- '

=

not

analyzed:

"nd" =

not

dete

cted

; "D

" = de

tect

ed a

nd n

ot q

uantified;

is o

f cis- plus t

rans-chlordane;

"<"

= less th

an;

ODD

= dichlorodiphenyldichloro

ethane;

DDE

= dichlorodiphenyldichloroethylene;

DOT

= di

chlo

rodi

phen

yltr

ichl

oroe

than

e; HCB

= he

xach

loro

benz

ene;

HCH

= hexachlorocyclohexane:

mi

nimu

m re

port

ing

leve

ls w

ere

smaller

for

filtered a

nd s

uspe

nded

ana

lyse

s, because

analytical sa

mple

vol

umes

wer

e large

rang

ing

from

4.4

to

34.5

liters fo

r di

ssol

ved

samp

les

and

from

[Con

cent

rati

ons

"T"

= pr

esen

t "g

" =

analysis

41.8

to

83.9

li

ters

for

sus

pend

ed s

ampl

es]

Organochlo

rine c

ompo

unds

Map

refe

renc

e St

atio

n nu

mber

number

Stat

ion

name

14 24 36 46 51

1248

4500

Yakima R

iver

at

Umtanum

12500430

Moxe

e Dr

ain

at T

horp

Rd

1250

5460

Gr

ange

r Dr

ain

at m

outh

1250

8850

Su

lphu

r Creek

Uast

eway

1251

0500

Yakima R

iver

at

Kion

a

Samp

le

medi

a Al

drin

F S U F S U F S U F S U F S U

T<0.69

<.6

<1 <3.5 <.01

<1 <3.2 .0

9<1 <15 <.

05<1 T<69 <.

01<1

cis-

trans-

Chlo

rdan

e Ch

lord

ane

p,p'

-DDD

T<0.

63<0.4

g<100 <1 8

T<!03

g<10

0 <1 6 !os

g<100 T<!3

g<10

0 <.63

<.04

g<10

0

T<0.

70<.04

<1 6

T<!0

3

<1 5 !09

<3.8

T<.3 <.

70<.04

T<1.

6 .05

<1 3.0

1.6

<1 T<2.

76.

4<1 9.

41.

7<1

1.4

.17

<1

Endo

sul

p,p'

-DDE

p,

p'-D

DT

Diel

drin

fa

n I

T<0.

41 .12

<1 5.6

7.1

21

.96

28 50 15 6.4

21

1.2

9.6

<1

0.26

<1 6.3

9.6

21 T<8.9

38 60 14 7.8

30

1.6

.2<1

0.93 .04

<1 T<3.4 .86

<1 T<3.1

3.6

<1 35 2.1

<1

3.6

.08

<1

0.82

<.04

<1 11.6

9<1 T<1.

4<.02

6.8

<.06

<1

1.2

<.04

<1

En

dosu

l-

fan

II

<0.81

<.07

5.2

<.06

<3.0

<2.0 -

<7.6 <.1 <.81

<.08 --

Orga

noch

lori

ne c

ompo

unds

Station

numb

er

Stat

ion

name

Samp

le

media

gamma-

Hepta-

alpha-

HCH

chlo

r o.

p'me

th-

p.p'

meth

-En

drin

HCB

HCH

(lindane)

epoxide

oxyc

hlor

oxychlor

Mi rex

Perthane

1248

4500

Yakima

Rive

r at U

mtan

um

F S U

1.5

<.04

<1

<0.56

<.07 --

<1 9

<!04 --

<2.6 <.04

<1

T<1.

2<.

04<1

<4.8 <-04

T<1.4

<1.4

<0.0

4<1

0 <1

< 2

0 <1

00

12500430

Mox

ee D

rain

at

Thorp

Rd

12505460

Gra

nger

Dra

in a

t mouth

1250

8850

Sul

phur

Creek U

asteway

1251

0500

Yakima

Rive

r at K

iona

<6.8

<.03 .31

<35 <.

06

<.56

<.

04

1.1

:.01

T<.99

.33

<2.4

.08

T<.56

.16

<3.9

T<.0

3

<3.5 .0

2

<.06

<.04

<2.6

<.

03

T<2.3 .06

<.06

<2.6 <.04

<2.5

T<.03

<2.3 .1

5

<8.9

<.

06

<.04

<.03

<9.0

3.4

<.06

<4.8

<.04

<.03

10 10

.32

10 <.06

10 <.

04

<.03

<.04

<.06

<.04

<3.2

<100 T<2.8

<100 <20

<100

<100

Tabl

e 36

. Co

ncen

trat

ions

of

pesticides in filtered w

ater

(u

sing

the

Goul

den

larg

e-sa

mple

extractor),

asso

ciat

ed w

ith

suspended

sedi

ment

(a

naly

sis

of a

larg

e sample o

f de-watered

sediment

on a

glass-fiber

filt

er),

an

d in w

hole

wat

er (c

onve

ntio

nal

analysis of a

1-li

ter

sample o

f a

sediment-water m

ixtu

re),

Yakima R

iver

basin, Wa

shin

gton

, Ju

ne 2

5-30

, 1989--Continued

Stat

ion

number

12484500

12500430

1250

5460

12508850

12510500

Station

number

12484500

12500430

1250

5460

1250

8850

12510500

Station

name

Yakima R

iver

at Umtanum

Moxe

e Dr

ain

at Th

orp

Rd

Granger

Drai

n at

mouth

Sulphur

Cree

k Ua

stew

ay

Yakima R

iver

at

Kiona

Station

name

Yakima R

iver

at Umtanum

Moxe

e Drain

at Thorp

Rd

Granger

Drai

n at m

outh

Sulphur

Creek

Uasteway

Yakima R

iver

at Ki

ona

Samt

medi F S U F S U F S U F S U F S U

ne ia

Sample

medi

a

F S U F S U F S U F S U F S U

Azinpnos-

meth

yl

nd D nd ;; nd

cnior-

pyrifos

T<2.

4 <.06

T<6.7 .48

T<6.

0

<26.16

9.6

T<.06

Organophosphorus

Demeton-S

Diazinon

<2.4

T<

2.0

<.06

T<7.9

406 3.

3 370

compounds

Dime

tho-

at

e <3.7

<13..

<7.1

11

T<12

1.9

10

T<34

66 .1

8 20

<2.4

39

.07

30

Disulfo-

ton

<2.4

<.06

<7.6

<.05

T<6.9

<.08

328

T<27

<3.7

<2.4

<.06

Ethion

T<3.

9 <.

06

r<11 .5

2

T<.08

<42

T<3.

9 <.

06

Fonofos

<2.0

<.

06

<7.0

<.

05

<6.3

<

.08

<1<.

1

<2.0

<.

06

Organophosphorus

co

mpou

nds

Meth

ida-

Methyl

Meth

yl

Ma lath ion

thio

n pa

rath ion

trit

nion

T<3.9

<.06

< <.

05

T<9.9

<.08

T<44

10'

70 <-06

4.

<1?. <9.

<40 <3.

9 T<

4.1

T<3.8

<.06

<-06

<.05

<.

05

<.08

<.

08

<10

<10

<11

<40

0 <4.1

<3.8

<-06

<-06

Mevinphos

<3.2

<9.5

T<8.

6

<34 <3.2

Para

thio

n Ph

orat

e

T<3.

2 <.06 .14

<.08

<42 .1

0

T<3.

2 T<

.06

10

<2.8

<.

06

130 1.

4 90 <8

.0

<.08

T<40 T<2.

8 <.

06

Phos

pham

- idon T<6.

5

43 56

T<37 5.

3

Tri thion

<3.6

<.06

<9.4

<.

05

<8.5

<.08

<42 <3.6

<.06

Table

36.

Conc

entr

atio

ns o

f pe

stic

ides

in

filtered

wate

r (using th

e Go

ulde

n large-sample

ext

ract

or),

associated w

ith

susp

ende

d se

dime

nt (analysis

of a

larg

e sa

mple

of

de-w

ater

ed s

edim

ent

on a

glass-fiber f

ilter),

and

in w

hole w

ater

(conventional

analysis o

f a

1-liter

sample o

f a

sedi

ment

-wat

er m

ixtu

re),

Ya

kima

Riv

er b

asin,

Washington,

June

25-

30,

1989

--Co

ntin

ued

Statio

n nu

mber

Stat

ion

name

12484500 Y

akima

River

at U

mtan

um

12500430 M

oxee D

rain A

t Th

orp

Rd

1250

5460 G

rang

er D

rain

at

mouth

1250

8850 S

ulph

ur C

reek

Uas

tewa

y

12510500 Y

akima

River

at K

iona

Sample

medi

a

F U F U F U F U F U

Tria

zine

. acet am

ide, uracil.

chlo

roac

etan

ilid

e. th

iocarbamate. an

d an

ilid

e compo

j Ala-

chlor

<1.6

<1

00 <4.0

<100 33

<100 33

<100 12

<1

00

Atra

- Ametryn

zine

nd

<100 nd

<1

00 nd

<100 nd

<1

00 nd

<100

10

<100 8.

5 10 48

90 49

22 32<1

00

V

unds

Broma-

Buta

- car-

Cyan

a-

cyci

o-

Dipn

en-

cil

chlor

Butylate

bo

x in

zi

ne

ate

amid

nd

<100 nd

<100 13

<1

00 T <100 nd

<100

nd

<100 nd

<1

00 nd

<100 nd

<100 nd

<1

00

nd

<100 nd

<1

00 nd

<100 nd

<1

00 nd

<100

<1.7

<100

<1

00

<100

<3.7

<100

<1

00

<100

8.6

<100

<100

<100

T<31

<100

<100

<1

00

<6.5

<1

00

<100

<100

<100

<100

<100

<100

<100

Statio

n nu

mber

Stat

ion

name

1248

4500 Y

akima

River

at U

mtanum

1250

0430 M

oxee

Dra

in A

t Th

orp

Rd

1250

5460 G

rang

er D

rain a

t mouth

1250

8850 S

ulph

ur C

reek U

aste

way

1251

0500 Y

akima

River

at K

iona

Samp

le

medi

a

F U F U F W F U F U

Tria

zine

. acetamide.

Hexazi

none

<100

<100

<100

<100

<100

- Me

tola

- chlor

T<1.3

<100 <3

.1

<100 T<2.

8 <1

00

T<15

<100 1.

9 <1

00

Metn

- bu

z in

nd

<100 nd

<1

00 nd

<100

<100 T

<100

chlo

roac

etan

ilid

e. ur

acil

. trif luoromethyl.

thiocarbamate

Prome-

ton 1.

1 <100 <3

.1

<100 32 50 26

<100 3.

0 <100

Prome-

tryn nd

<100 nd

<100 nd

<1

00 nd

<100 nd

<1

00

Propa-

chlor

nd

<100 nd

<100 nd

<100 nd

<1

00 nd

<100

Prop

a-

sima-

sime-

zine

zi

ne

tryn

T<0.

39

2.2

nd

<100

<1

00

<100

<3.6

<3

.6

nd<100

<1

00

<100

<3.2

134

nd

<100

17

0 <1

00

<18

81

nd

<100

77

<100

.47

18

nd

<100

44

<100

Terba-

cil

<100

<100

<100

<100

<100

compounds"

Tntl

ur-

verno-

alin

late

T<3.

8 <1

00

T<14

<1

00 28

100

T<32

<100 T<3.8

<100

T <1

00 nd

<100 T

<100 nd

<1

00 nd

<100

I/ Suspended s

ediment

samp

les

were n

ot a

nalyzed.

Table 37. Concentrations of organic carbon in replicate suspended-sediment samples and in spiked filtered-water samples from Chandler Canal at Bunn Road at Prosser, Washington, May 22, 1991, at 1500 hour and 1507 hour

[Station number 12509499; map reference number 48 figure 1]

Concentration, in milligrams per liter

Constituent

Laboratory resultsReplicate 1 Replicate 2 (not spiked) (spiked)

A B

Calculated concentration in replicate 2

C

Recovery, in percentB x 100 / C

Dissolved organic carbon 2.2 3.7 3.1 120

Constituent

Concentration, in milligrams per literLaboratory results

Replicate 1 (not spiked)

A

Replicate 2 (spiked) Difference

|A - B|

Suspended organic carbon 0.7 0.6 0.1

Table 38. Concentration of organic carbon, suspended sediment, and turbidity in replicate water samples from Yakima River at Kiona, Washington, August 6, 1991, at 1150 hour and 1151 hour

[Station number 12510500; map reference number 51 figure 1; NTU = nephelometric turbidity units]

Para meter code

Concentration

Constituent

Replicate 1Replicate 2 (not spiked) (not spiked) Difference

A B | A - B |

00681 Dissolved organic carbon,in milligrams per liter 2.7

00689 Suspended organic carbon,in milligrams per liter 1.1

80154 Suspended sediment,in milligrams per liter 32

70331 Sediment, percent finer than0.062 millimeters 91

00076 Turbidity, in NTU 10

2.9

1.2

30

85

10

Table 39. Mean analytical recoveries using the Goulden large-sample extractor for extracting surrogate compounds from filtered-water samples, Yakima River basin, Washington, June 25-30, 1989

[One standard deviation of the mean is shown in parenthesis and is reported in percent; "$" includes field blanks]

Sample volume Numberextracted, ofin liters samples

______Mean analytical recoveries, in percentgamma-Hexachloro-

Diazinon cyclohexane d-10 d-6 Isodrin

Atrazined-5 Terbuthylazine

5.0 - 7.7$

4.4 - 12

34 - 37

72 - 113

All samples

13

14

17

11

55

81

93

87

69

84

(16)

(14)

(10)

(26)

(18)

59

61

62

65

62

(43)

(26)

(21)

(20)

(28)

18

18

45

27

28

(19)

(16)

(14)

(17)

(20)

84

91

76

47

76

(14)

(18)

(11)

(19)

(22)

84

88

80

63

79

(15)

(23)

(9)

(20)

(19)

117

Table 40. Analytical recoveries using the Goulden large-sample extractor for extracting spiked compounds from filtered-water samples, Yakima River basin, Washington, June 25-30, 1989

[See table 2 for map reference numbers and figure 1 for site locations; natural occurring concentrations of pesticides have been substracted out of reported recoveries; ODD = dichlorodiphenyldichloroethane; DDE = dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyltrichloroethane; HCB = hexachlorobenzene; HCH = hexachlorocyclohexane; DEF = S,S,S~tributyl phosphorotrithioate; EPIC = S-ethyl dipropylthiocarbamate; extracted sample volumes listed in parenthesis; L = liter; " " = not analyzed; "nq" = not quantified, because of analytical problems; "*" = surrogate spike; negative recoveries indicate that concentration detected in native water sample exceeded concentration in spiked sample negative recoveries occurred because actual concentrations in spiked samples were small and because laboratory precision at low concentrations is poor]

Recovery of spiked compound. in percentStation number

12508850 12505460 12508630 12500430 12510500Station name

Compounds

Organochlorine

Aldrincis-Chlordanetrans-Chlordanep,p'-DDDp,p'-DDE

p,p'-DDTp,p'-DDT d-8 *DieldrinEndosulfan IEndosulfan II

EndrinHCBalpha-HCHbeta-HCHdelta-HCH

gamma-HCH (lindane)ganma-HCH d-6 *HeptachlorHeptachlor epoxideIsodrin *

o , p ' -Methoxychlorp , p ' -MethoxychlorMi rexPerthane

Organophosphorus

Azinphos-methylChlorpyrifosDEFDemeton-SDiazinon

Diazinon d-10 *DimethoateDisulfotonEthionFonofos

IsofenphosMalathionMethidathionMethyl parathionMethyl trithion

MevinphosParathionPhoratePhosphamidonTerbufos

SulphurCreekWasteway(11.5 L)

4685793248

013407697

5845605986

575623

10733

14nq1162

1166599

-36

92198378

104

61127171

0149

1227616822116

GrangerDrain(12.3 L)

3060554261

-50

1387647

145235658--

5250136412

12nq1152

7176

10674

7858808197

971121527198

9062

12142095

SouthDrain(11.7 L)

3078735956

33

918767

92326970--

655214

11515

164

1658

92737950

8232697581

7872879285

878487

11068

MoxeeDrain(11.4 L)

4866623844

14

908762

94597175--

67652313545

135

1540

__896987

-32

8126765186

71680

591

8670824379

YakimaReplicate 1

(9.99 L)

2951478452

87

725953

__41766375

5774205115

18101855

6386723688

9735377186

9372758171

918470

10460

River at KionaReplicate 2

(9.51 L)

2243398145

109

655149

31646170

577319597

23141748

5281662972

9128296875

8963687765

7287637750

Replicate 3(10.3 L)

5355518855

109

755652

__35726779

6283207515

23142353

4485692881

9239277081

9364697465

808452

10749

Trithion 82 94 72 52 70 64 65

118

Table 40. Analytical recoveries using the Goulden large-sample extractor for extracting spiked compounds from filtered-water samples, Yakima River basin, Washington, June 25-30, 1989 Continued


12S088SO 12505460 12508630 12500430 12510500Station name

Compounds

Triazine

AmetrynAtrazineAtrazine d~5 *Cyanazine

MetribuzinFrometonPrometrynPropazine

SimazineSimetrynTerbuthylazine

Carbamate

CarbarylCarbofuranEPIC

Thiocarbamate

ButylateVernolate

Acetamide

AlachlorMetolachlor

Chloroacetanilide

ButachlorPropachlor

Conazole

Triadimefon

Pyrethoid

Flucythrinatecis-Permethrintrans-Permethrin

Sulfite

Propargite

Trifluoromethvl

Trifluralin

Uracil

Bromacil

Urea

Linuron

SulphurCreekWasteway(11.5 L)

82338557

92568690

-398276

523085

6284

5584

49110

71

1013335

-439

79

22

GrangerDrain(12.3 L)

64307357

70276572

-1126273

nq3858

3778

6277

6588

78

773537

114

0

11

--

SouthDrain(11.7 L)

8862

10166

7210492

107

2485106

nq3878

6177

8684

80102

92

47343

89

45

33

MoxeeDrain(11.4 L)

8892826

77978892

588785

nq2883

7985

8583

6794

92

392324

-57

76

36

--

YakimaReplicate 1

(9.99 L)

78948373

76808088

567882

472981

5379

7975

89102

84

654940

102

47

35

41

River at KionaReplicate 2

(9.51 L)

73787569

72767680

467174

423057

3860

7169

8286

78

594031

71

48

34

44

Replicate 3(10.3 L)

81988674

77848490

618284

403245

3251

7976

9093

86

624734

93

40

23

44

119

Table 40. Analytical recoveries using the Goulden large-sample extractor for extracting spiked compounds from filtered-water samples, Yakima River basin, Washington, June 25-30, 1989--Continued

Recovery of spiked compound,, in percentStation number

12510500 12484500 12496510 12507594Station name

Compounds

Organochlorine

Aldrincis-Chlordanetrans-Chlordanep,p'-DDDp,p'-DDE

p,p'-DDTp,p'-DDT d-8 *DieldrinEndosulfan IEndosulfan II

EndrinHCBalpha-HCHbeta-HCHdelta-HCH

gamma-HCH (lindane)gamma-HCH d-6 *HeptachlorHeptachlor epoxideIsodrin *

o , p ' -Methoxychlorp , p ' -MethoxychlorMirexPerthane

Organophosphorus

ChlorpyrifosDEFDemeton-SDiazinonDiazinon d-10 *

DimethoateDisulfotonEthionFonophosIsofenphos

MalathionMethidathionMethyl parathionMethyl trithion

MevinphosParathionPhoratePhosphamidonTerbufos

Yakima Riverat Kiona(35.7 L)

901561525157

295

105nq59

14810492

101116

905760

13080

25nq1886

86741027792

2388778766

-96111176116

94nq11914679

Yakima Riverat Umtanum(35.7 L)

49101985359

2944

1059963

196568985

143

9710360

11766

39nq2160

9751

1018892

3480818253

194172257164

6473932681

Pacific Power & LightCompany Wasteway

(113 L)

3083804253

2324778547

160405668116

4074527221

28nq2054

7736756864

1863656543

125113176109

4066551860

Satus Creek aboveWilson-Charley Canyon

(111 L)

4378735161

89

848158

99555356nq

5956287831

199

1657

8675585962

954686163

9476

10380

2779654554

Trithion 75 68 59 69

120

Table 40. Analytical recoveries using the Goulden large-sample extractor for extracting spiked compounds from filtered-water samples, Yakima River basin, Washington, June 25-30, 1989 Continued


12510500 12484500 12496510 12507594Station name

Compounds

Triazine

AmetrynAtrazineAtrazine d-5 *CyanazineMetribuzin

PrometonPrometrynPropazineSimazineSimetryn

Terbuthylazine

Carbamate

CarbarylCarbofuranEPTC

Thiocarbamate

ButylateVernolate

Acetamide

AlachlorMetolachlor

Chloroacetanilide

ButachlorPropachlor

Conazole

Triadimefon

Pyrethoid

Fluey thrinatecis-Permethrintrans-Permethrin

Sulfite

Propargite

Trifluoromethyl

Trifluralin

Uracil

Bromacil

Yakima Riverat Kiona(35.7 L)

1041141047566

1131109877

103

97

7351

126

116115

117103

98118

107

3647

86

108

-25

Yakima Riverat Umtanum(35.7 L)

7768764758

7283832567

91

331581

7178

10392

83114

95

1243741

99

84

148

Pacific Power & LightCompany Was tew ay

(113 L)

5856462641

6063612452

57

401544

4345

7469

5659

119

603436

59

51

9

Satus Creek aboveWilson-Charley Canyon

(111 L)

6456442429

5172671841

62

nq1461

5963

7469

6064

78

643638

82

63

8

121

Table 41. Concentrations of pesticides extracted from replicate filtered-water samples using the Goulden large-sample extractor, Yakima River at Kiona, Washington, June 26, 1989

[Station number 12510500; map reference number 51 figure 1; "T" = trace concentration below minimum reporting level; "nd" = not detected; "ap" = analytical problems; "D" = detected, but not quantified; EPIC = S-ethyl dipropylthiocarbamate; DDD = dichlorodiphenyldichloroethane; DDE = dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyltrichloroethane; HCB = hexachlorobenzene]

Concentration, in nanoRrams per literSample number collected from 0800 to 1330 hour

Compound

Acetamide compounds

AlachlorMetolachlor

Carbamate compounds

EPIC


Aldrinp,p'-DDD p,p'-DDE p,p'-DDT Dieldrin

Endosulfan IHCB


Azinphos-methyl Chloropyrifos DiazinonEthionMalathion

ParathionPhoratePhosphamidon

Pyrethoid compounds

Replicate

9.71.7

4.4

ndT .93

ap 2.9

ndnd

9.0 T

40nd12

TT6.4

1 Replicate 2

9.2T

5.2

ndT T ap T

ndnd

6.5 T

40nd11

TTT

Replicate 3

9.41.5

5.1

ndT .81

ap 2.5

ndnd

6.7 T

40nd11

TT5.9

Sample number 2 collected from 1350 to 1650 hour

121.9

3.3

T1.4 1.2 1.6 3.6

1.2T

nd 9.6

39T

70

TT5.3

c i s-Permethrin

Sulfite compounds

Propargite

Triazine

AtrazineCyanazineDeethylatrazineDeisopropylatrazineMetribuzin

PrometonPropazineSimazine

Trifluoromethyl compounds

Trifluralin

Urea compounds

Linuron

11

372.4T T T

2.1 nd21

11

36 3.7 T T T

3.3 nd 22

11

36 3.7 T T T

3.5 nd 22

nd

7.2

32 nd D D nd

3.0.47

18

1.9

122

Table 42. Concentrations of organochlorine and organophosphorus compounds in spiked filtered-water samples from Yakima River at Kiona, Washington, May 21, 1991, at 1200 hour and 1207 hour

[Station number 12510500; map reference number 51 figure 1; "ns" = not spiked; DDD = dichlorodiphenyldichloroethane; DDE = dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyltrichloroethane; PCB - gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes; DBF = S,S,S-tributyl phosphorotrithioate; "<" = less than; less-than values were set equal to zero for calculations]

Concentration, in nanograms per literLaboratory results Calculated

Para- Replicate 1Replicate 2 concentration Recovery,meter (not spiked) (spiked) in replicate 2 in percentcode Compound A B C B x 100 / C


39331 Aldrin <1 <1 ns ns39352 Gross chlordane <100 <100 ns ns39361 p,p'-DDD <1 <1 ns ns39366 p,p'-DDE 4 3 ns ns39371 p,p'-DDT <1 <1 ns ns

39381 Dieldrin 3 1 58 282354 Endosulfan I <1 <1 ns ns39391 Endrin <1 <1 ns ns39411 Heptachlor <1 <1 ns ns39421 Heptachlor epoxide <1 <1 ns ns

39341 Lindane (gamna-HCH) <1 <1 56 0p,p'-Methoxychlor <10 <10 ns ns

39756 Mirex <10 <10 ns ns39517 PCB <100 <100 ns ns82360 PCN <100 <100 ns ns

82348 Perthane <100 <100 ns ns39401 Toxaphene <1,000 <1,000 ns ns

Organophosphate compounds

Chlorpyrifos <10 <10 110 0DBF <10 <10 ns ns

39572 Diazinon <10 <10 110 0Disulfoton <10 <10 ns ns

82346 Ethion <10 <10 ns ns

Fonofos <10 <10 ns ns39532 Malathion <10 <10 110 039602 Methyl parathion <10 <10 ns ns

Methyl trithion <10 <10 ns ns39542 Parathion <10 <10 110 0

Phorate <10 <10 ns ns82342 Trithion <10 <10 ns ns

123

Table 43. Concentrations of organochlorine and organophosphorus compounds in spiked filtered-water samples from Chandler Canal at Bunn Road at Prosser, Washington, June 13, 1991, at 1240 hour and 1247 hour

[Station number 12509499; map reference number 48 figure 1; "ns" = not spiked; ODD = dichlorodiphenyldichloroethane; DDE - dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyltrichloroethane; PCB - gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes; DBF - S,S,S-tributyl phosphorotrithioate; less-than values were set equal to zero for calculations]


Concentration, in nanograms per liter Laboratory results Calculated

concentrationin replicate 2 Recovery.in percent

C


A


B B x 100 / C


39331 Aldrin <1 <139352 gross Chlordane <100 <10039361 p,p'-DDD <1 <139366 p,p'-DDE 1 139371 p,p'-DDT <1 1

39381 Dieldrin 1 4082354 Endosulfan I 2239391 Endrin <1 <139411 Heptachlor <1 <139421 Heptachlor epoxide <1 <1

39341 Lindane (gamma-HCH) <1 40p.p'-Methoxychlor <10 <10

39756 Mirex <10 <1039517 PCB <100 <10082360 PCN <100 <100

82348 Perthane <100 <10039401 Toxaphene <1,000 <1,000

Organophosphate compounds

Chlorpyrifos <10 60DBF <10 <10

39572 Diazinon <10 130Disulfoton <10 <10

82346 Ethion <10 <10

Fonofos <10 <1039532 Malathion 30 16039602 Methyl parathion <10 <10

Methyl trithion <10 <1039542 Parathion <10 160

Phorate <10 <1082342 Trithion <10 <10

ns ns ns ns ns

54 ns ns ns ns

53 ns ns ns ns

ns ns

100 ns100 ns ns

ns140nsns100

ns ns

ns ns ns ns ns

74 ns ns ns ns

75 ns ns ns ns

ns ns

57 ns 120 ns ns

ns120nsns150

ns ns

124

Table 44. Concentrations of organochlorine and organophosphorus compounds in replicate filtered-water samples from Yakima River at Kiona, Washington, August 6, 1991, at 1150 hour and 1151 hour

[Station number 12510500; map reference number 51 figure 1; DDD = dichlorodiphenyldichloroethane; DDE = dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyltrichloroethane; HCH = hexachlorocyclohexane; PCB = gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes; DEF - S,S,S-tributyl phosphorotrithioate; "<" = less than; less-than values were set equal to zero for calculations]

Concentration, in nanograms per literPara- Replicate 1Replicate 2meter (not spiked) (not spiked) Differencecode Constituent A B | A - B |


39331 Aldrin <1 <1 039352 gross Chlordane <100 <100 039361 p,p'-DDD <1 2 239366 p,p'-DDE 42239371 p,p'-DDT <1 <1 0

39381 Dieldrin <1 1 182354 Endosulfan I 51439391 Endrin <1 <1 039411 Heptachlor <1 <1 039421 Heptachlor epoxide <1 <1 0

39341 Lindane (gamma-HCH) .3 <1 .3p,p'-Methoxychlor <10 <10 Q

39756 Mirex <10 <10 039517 PCB 200 100 10082360 PCN <100 <100 0

82348 Perthane <100 <100 039401 Toxaphene <1,000 <1,000 0


Chlorpyrifos <10 <10 0DEF <10 <10 0

39572 Diazinon 10 10 0Disulfoton <10 <10 0

82346 Ethion <10 <10 0

Fonofos <10 <10 039532 Malathion <10 <10 039602 Methyl parathion <10 <10 0

Methyl trithion <10 <10 039542 Parathion 10 <10 10

Phorate <10 <10 082342 Trithion <10 <10 0

125

Table 45. Mean analytical recoveries for extracting surrogate compounds from suspended-sediment samples, Yakima River basin, Washington, June 25-30, 1989

["-" = not calculated; HCH = hexachlorocyclohexane; ODD = dichlorodiphenyl- dicloroethane; DDE = dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyltrichloroethane]

Compound

Isodrin

Lindane (gamma-HCH)

p,p'-DDT d-8

p,p'-DDE d-8 I/

p,p'-DDD d-8 I/

(DDT+DDE+DDD) d-8 I/

Diazinon d-10

Isofenphos

Number of samples

1

19

19

6

12

19

19

1

Mean analytical recovery, in percent

45

28

42

5.9

1.0

45

60

110

One standard deviation of the mean, in percent

-

14

23

5.6

.6

23

15

-

If Samples were spiked with p,p'-DDT d-8 surrogate; during sample storage, processing, and (or) analysis, some of the DOT d-8 in several samples was converted to DDE d-8 and ODD d-8.

126

Table 46. Analytical recoveries of pesticides that were spiked into a blank solvent extract and were analyzed in accordance with other extracts from suspended-sediment samples, Yakima River basin, Washington, June 25-30, 1989

[These recoveries do not include losses associated with the extraction and initial solvent-concentration procedures; "ns" = not spiked; "nq" = not quantified; DDD = dichlorodiphenyl dichloroethane; DDE = dichlorodiphenyldichloroethylene; DDT = dichlorodiphenyltrichloroethane; HCB = hexachlorobenzene; HCH = hexachlorocyclohexane; DBF = S,S,S- tributyl phosphorotrithioate]

Analytical recoveries,

Compound in percent


Aldrin 44trans-Chlordane 38cis-Chlordane 39

Chlorthalonil 38p,p'-DDD 53p,p'-DDE 55

p,p'-DDT 48p,p'-DDT d-8 84Dacthal ns

Dieldrin 55Endosulfan I 18Endosulfan II nq

Endosulfan sulfate nsEndrin 52Endrin aldehyde ns

Endrin ketone nsHCB 26alpha-HCH 29

beta-HCH 45delta-HCH 39Heptachlor 40

Heptachlor epoxide 40Isodrin 28 Lindane (ganma-HCH) 34

Lindane d-6 65o,p'-Methoxychlor 70p,p'-Methoxychlor 55

Mirex 38trans-Nonachlor nsToxaphene ns


Chlorpyrifos 48DEF 53Diazinon 42

Diazinon d-10 80Disulfoton 10Ethion 47

Fonofos 45Isofenphos 52Malathion 53

Methyl parathion 43Methyl trithion 39

Parathion 50Phorate 17Trithion 49

127

Table 47. Concentrations of organochlorine and organophosphorus compounds in replicate suspended-sediment samples from Chandler Canal at Bunn Road at Prosser, Washington, June 13, 1991, at 17.40 hour and 1241 hour

[Station number 12509499; map reference number 48--figure 1; ODD = dichlorodiphenyldichloroethane; DDE = dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyltrichloroethane; HCH = hexachlorocyclohexane; PCS = gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes; DBF = S,S,S-tributyl phosphorotrithioate; I = interference at peak; "<" = less than; less-than values were set equal to zero for calculations]


Concentration, in nanograms per liter Replicate 1Replicate 2 (not spiked) (not spiked) Difference

A B | A - B |


39332 Aldrin39353 gross Chlordane39362 p.p'-DDD39367 p,p'-DDE39372 p,p'-DDT


39342 Lindane (gamma-HCH)p,p'-Methoxychlor

39757 Mirex 39518 PCB "7361 PCN

<100 <100

(V.349 Perthane '9402 Toxaphene

ChlorpyrifosDEF

39573 DiazinonDisulfoton

82347 Ethion

Fonofos39533 Malathion 39603 Methyl parathion

Methyl trithion 39543 Parathion

Phorate 82343 Trithion

<100 <100 <100 <100

<100 <100 <1,000 <1,000


:.6 :.6 :.6 :.6 :.6

:.6 :.6 :.6 :.6 :.6

:.6 :.6

128

Table 48. Concentrations of organochlorine and organophosphorus compounds in replicate suspended-sediment samples from Yakima River at Kiona, Washington, May 21, 1991, at 1200 hour and 1201 hour

[Station number 12510500; map reference number 51 figure 1; DDD = dichlorodiphenyldichloroethane; DDE = dichlorodiphenyldichloroethylene; DDT = dichlorodiphenyltrichloroethane; HCH - hexachlorocyclohexane; PCB = gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes; DEF = S,S,S-tributyl phosphorotrithioate; "<" = less than; less-than values were set equal to zero for calculations]

Concentration, in nanogramsPara meter code

Replicate 1 Replicate 2 (not spiked) (not spiked)

Constituent A B

per liter

Difference 1 A - B |


3933239353 39362 39367 39372

39382823553939239412 39422

39342

397573951882361

8234939402

39573

82347

3953339603

39543

82343

Aldrin <1gross Chlordane <100 p,p'-DDD <1 p,p'-DDE 1 p,p'-DDT 1

<!<100

1 1

Dieldrin 1 <1Endosulfan I 1Endrin <1Heptachlor <1 Heptachlox epoxide <1

Lindane (gamma -HCH) <1 p , p ' -Methoxychlor <1C Mirex <10PCB <10PCN <100

Perthane <100Toxaphene <1,000

Organophosphorus

Chlorpyrifos DEFDiazinonDisulfotonEthion

FonofosMalathionMethyl parathion Methyl trithion Parathion

PhorateTrithion

1<1

<i<10

<10<100

<100<1,000

compounds

.4

.4

.4

.4

.4

.4

.4

.4

.4

.4

.4

.4

4 4444

444 4 4

44

00 0 0 0

1000 0

0 0 000

00

0 0000

000 0 0

00

129

Table 49. Concentrations of organochlorine and organophosphorus compounds in replicate suspended-sediment samples from Yakima River at Kiona, Washington, August 6, 1991, at 1150, hour and 1151 hour

[Station number 12510500; map reference number 51 figure 1; DDD = dichlorodiphenyldichloroethane; DDE = dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyltrichloroethane; HCH = hexachlorocyclohexane; PCB = gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes; DEF = S,S,S-tributyl phosphorotrithioate; "<" = less than; less-than values were set equal to zero for calculations]


Concentration, in nanoxrams per liter Replicate 1 Replicate 2 (not spiked) (not spiked) Difference

A B | A - B |

Orxanochlorine compounds

39332 Aldrin39353 gross Chlordane39362 p,p'-DDD39367 p,p'-DDE39372 p,p'-DDT


39342 Lindane (gamma-HCH)p,p'-Methoxychlor

39757 Mirex 39518 PCB 82361 PCN

8234939402

<100 <100 1 1

Perthane Toxaphene

20 <100

<100 <1,000

50 <100

<100 <1,000


ChlorpyrifosDEF

39573 DiazinonDisulfoton

82347 Ethion

Fonofos39533 Malathion 39603 Methyl parathion

Methyl trithion 39543 Parathion

Fhorate 82343 Trithion

00100

10000

000

300

00

130

Table 50. Concentrations of organochlorine and organophosphorus compounds associated with blank glass-fiber filters, Yakima River basin, Washington, July to September 1991

[ <" = less than; DDD - dichlorodiphenyldichloroethane; DDE - dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyltrichloroethane; HCH « hexachlorocyclohexane; PCB = gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes; DEF = S,S,S- tributyl phosphorotrithioate]

Concentration, in nanograms per liter Glass-fiber filter without

Para- _______suspended sediment__________meter July 1991 Sept. 5. 1991 Sept. 25. 1991code Constituent ABC


39332 Aldrin <1 <1 <139353 Chlordane <100 <100 <10039362 p,p'-DDD <1 <1 <139367 p,p'-DDE <1 <1 <139372 p,p'-DDT <1 <1 <1

39382 Dieldrin <1 <1 <182355 Endosulfan I <1 <1 <139392 Endrin <1 <1 <139412 Heptachlor <1 <1 <1

39422 Heptachlor epoxide <1 <1 <139342 Lindane (gamma-HCH) <1 <1 <1

p,p'-Methoxychlor <10 <10 <1039757 Mirex <10 <10 <1039518 PCB <100 <100 <100

82361 PCN <100 <100 <10082349 Perthane <100 <100 <10039402 Toxaphene <1,000 <1,000 <1,000


Chlorpyrifos <10 <10 <.5DEF <10 <10 <.5

39573 Diazinon <10 <10 <.5Disulfoton <10 <10 <.5

82347 Ethion <10 <10 <.5

Fonofos <10 <10 <.539533 Malathion <10 <10 <.539603 Methyl parathion <10 <10 <.5

Methyl trithion <10 <10 <.539543 Farathion <10 <10 <.5

Phorate <10 <10 <.582343 Trithion <10 <10 <.5

131

Table 51. Concentrations of organochlorine and semi-volatile organic compounds In replicate bed-sediment samples (sediment finer than 62 micrometers in diameter) from Sulphur Creek Wasteway near Sunnyside, Washington, August 31, 1988

[Station number 12508850; map reference number 46 figure 1; DDD = dichlorodiphenyldichloroethane; DDE = dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyltrichloroethane; HCH = hexachloroeyelohexane; PCB = gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes; "<" = less than; less-than values were set equal to zero for calculations]

Parametercode

Replicate 1 Replicate 2Constituent A B

Difference1 A - B |

Carbon compounds

00693

00686

[concentration,

Carbon, inorganic +organic

Carbon, inorganic

in grams per kilogram]

9.31.1

6.01.5

3.3.4


3933339351393833936339368

3937339389393933941339423

3934339481397583951939251

8188639403

[concentration, in

Aldringross ChlordaneDieldrinp,p'-DDDp,p'-DDE

p,p'-DDTEndosulfan IEndrinHeptachlorHeptachlor epoxide

Lindane (gamma-HCH)p , p ' -MethoxychlorMirexPCBPCN

PerthaneToxaphene

micrograms per

<.l<15

2674

137.9<.l<.l<.l

<.l<.l<.l

<1<1

<1<10

kilogram]

<.l44.4

1542

9.91.9<.l<.l.1

<.l<.l<.l

<1<1

<1<10

04.6

1132

3.1600.1

00000

00

Semi-volatile compounds

34411345843970534389

34399

34281

34276

34286

34639

34641

34539345693457434614

3462939701

[concentration, in

Isophorone2-ChloronaphthaleneHexachlorobutadieneHexachlorocyclopenta-

dieneHexachloroethane

bis (2-Chloroethoxy)methane

bis (2-Chloroethyl)ether

bis (2-Chloroisopropyl)ether

4-Bromophenyl phenylether

4-Chlorophenyl phenylether

1,2 Dichlorobenzene1,3 Dichlorobenzene1,4 Dichlorobenzene2,4 Dinitrotoluene

2,6 DinitrotolueneHexachlorobenzene

micrograms per

<200<200<200

<200<200

<200

<200

<200

<200

<200<200<200<200<200

<200<200

kilogram]

<200<200<200

<200<200

<200

<200

<200

<200

<200<200<200<200<200

<200<200

000

00

0

0

0

0

00000

00

132

Table 51. Concentrations of organochlorine and semi-volatile organic compounds in replicate bed-sediment samples (sediment finer than 62 micrometers in diameter) from Sulphur Creek Wasteway near Sunnyside, Washington, August 31, 1988 Continued

Parametercode

3445034554345893460434609

3466034619345943464934455

39061346953462439102

34339

3434439112345993429534208

3420334223345293425034233

3424534524343233455934379

3438434406344453446434472

3444134431

34436

Replicate 1Constituent

Semi -volatile[concentration, in

Nitrobenzene1,2,4 Trichlorobenzene2-Chlorophenol2,4 Dichlorophenol2 , 4 -Dimethylphenol

4 , 6-Dinitroortho cresol2, 4-Dinitrophenol2-Nitrophenol4-NitrophenolParachloro meta cresol

PentachlorophenolPhenol2,4,6 Trichlorophenolbis (2-Ethylhexyl)

phthalateDiethyl phthalate

Dimethyl phthalateDi-n-butyl phthalateDi-n-octyl phthalateN-butyl benzl phthalateAcenaphthene

Ac enaphthy leneAnthraceneBenzo (a) anthraceneBenzo (a) pyreneBenzo (b) fluoranthene

Benzo (k) fluorantheneBenzo (g,h,i) peryleneChryseneDibenzo (a,h) anthraceneFluoranthene

FluoreneIndeno (1,2,3-cd) pyreneNaphthalenePhenanthrenePyrene

N-NitrosodimethylamineN-Nitrosodi-n-propyl-

amineN-Nitrosodiphenylamine

AReplicate 2 Difference

JT 1 A - B |

compounds Continuedmicrograms

<200<200<200<200<200

<600<600<200<600<600

<600<200<600

350<200

<200<200<400<200<200

<200<200<400<400<400

<400<400<400<400<200

<200<400<200<200<200

<200

<200<200

per kilogram}

<200<200<200<200<200

<600<600<200<600<600

<600110

<600

43080

<200116

<400<200<200

<200<200<400<400<400

<400<400<400<400<200

<200<400

9482

110

<200

<200<200

00000

00000

0110

0

8080

0116

000

00000

00000

00

9482

110

0

00

133

Table 52. Concentrations of organochlorine and semi-volatile organic compounds in replicate bed-sediment samples (sediment finer than 2,000 micrometers in diameter) from Sulphur Creek Wasteway near Sunnyside, Washington, August 31, 1988

[Station number 12508850; map reference number 46 figure 1; ODD m dichlorodiphenyldichloroethane; DDE m dichlorodiphenyldichloroethylene; DOT - dichlorodiphenyltrichloroethane; HCH = hexachlorocyclohexane; PCB = gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes; "<" = less than; less-than values were set equal to zero for calculations]


Replicate 1 Replicate 2 A B

Difference 1 A - B |

Carbon compounds [concentration, in grams per kilogram]

00693

00686

Carbon, inorganic +organic

Carbon, inorganic9.1.

Organochlorine

3933339351393833936339368

3937339389393933941339423

3934339481397583951939251

8188639403

[concentration, in

Aldringross ChlordaneDieldrinp,p'-DDDp,p'-DDE

p,p'-DDTEndosulfan IEndrinHeptachlorHeptachlor epoxide

Lindane (ganma-HCH)p , p ' -MethoxychlorMirexPCBPCN

PerthaneToxaphene

5 50

compounds

18

4 42

micrograms per kilogram]

<<15.

13< -

.

<1<1

<!<10

Semi -volatile

34411345843970534389

34399

34281

34276

34286

34639

34641

3453934569345743461434629

3970134450345543458934604

3460934660346193459434649

[concentration, in

Isophorone2-CnloronaphthaleneHexachlorobutadieneHexachlorocyclopenta-

dieneHexachloroethane

bis (2-Chloroethoxy)methane

bis (2-Chloroethyl)ether

bis (2-Chloroisopropyl)ether

4-Bromophenyl phenylether

4-Chlorophenyl phenylether

1,2 Dichlorobenzene1,3 Dichlorobenzene1,4 Dichlorobenzene2,4 Dinitrotoluene2,6 Dinitrotoluene

HexachlorobenzeneNitrobenzene1,2,4 Trichlorobenzene2-Chlorophenol2,4 Dichlorophenol

2, 4-Dimethylphenol4,6-Dinitroortho cresol2,4-Dinitrophenol2-Nitrophenol4-Nitrophenol

! <4

6 310

1 33

8 81 1111

111

<1<1

<!<10

compounds

!

4

9111

111

0423

33

71000

00000

00

2

29

micrograms per kilogram]

<200<200<200

<200<200

<200

<200

<200

<200

<200

<200<200<200<200<200

<200<200<200<200<200

<200<600<600<200<600

<200<200<200

<200<200

<200

<200

<200

<200

<200

<200<200<200<200<200

<200<200<200<200<200

<200<600<600<200<600

000

00

0

0

0

0

0

00000

00000

00000

134

Table 52. Concentrations of organochlorine and semi-volatile organic compounds in replicate bed-sediment samples (sediment finer than 2,000 micrometers in diameter) from Sulphur Creek Wasteway near Sunnyside, Washington, August 31, 1988 Continued

Parametercode

3445539061346953462439102

3433934344391123459934295

3420834203342233452934250

3423334245345243432334559

3437934384344063444534464

344723444134431

34436

Replicate 1Constituent

Semi -volatile[concentration, in

Parachloro meta cresolPentachlorophenolPhenol2,4,6 Trichlorophenolbis (2-Ethylhexyl)

phthalate

Diethyl phthalateDimethyl phthalateDi-n-butyl phthalateDi-n-octyl phthalateN-butyl benzl phthalate

AcenaphtheneAcenaphthyleneAnthraceneBenzo (a) anthraceneBenzo (a) pyrene

Benzo (b) fluorantheneBenzo (k ) fluorantheneBenzo (g,h,i) peryleneChryseneDibenzo (a,h) anthracene

FluorantheneFluoreneIndeno (1,2,3-cd) pyreneNaphthalenePhenanthrene

PyreneN-NitrosodimethylamineN-Nitrosodi-n-propyl-


AReplicate 2 Difference

B | A - B |

compounds Continuedmicrograms

<600<600<200<600

<200

<200<200<200<400<200

<200<200<200<400<400

<400<400<400<400<400

<200<200<400<200<200

<200<200

<200<200

per kilogram]

<600<600110

<600

520

80<200120

<400150

<200<200<200<400<400

<400<400<400<400<400

<200<200<400<200<200

<200<200

<200<200

00

1100

520

800

1200

150

00000

00000

00000

00

00

135

Table 53. Analytical recovery of organochlorine and semi-volatile organic compounds spiked in bed-sediment samples from Sulphur Creek Wasteway, Washington, August 31, 1988

[Station number 12508850; map reference number 46 figure 1; three replicate sediment samples of each size class (less than 62-micrometer and less than 2,000-micrometer diameter) were analyzed; replicate 1 and replicate 2 in each size class were not spiked to determine precision (results of duplicate analyses shown in tables 51 and 52); replicate 3 in each size class was spiked; percent recoveries from replicate 3 samples are based on the mass of analyte that was spiked plus the mass of the analyte detected in replicates 1 or 2 for each size class; "ns" = not spiked; "-" = one or more of the percent recoveries were reported as "less than" values; "<" = less than; DDD = dichlorodiphenyldichloroethane; DDE = dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyltrichloroethane; HCH = hexachlorocyclohexane; PCB = gross polychlorinated biphenyls; PCN = gross polychlorinated naphthalenes]

Recovery of spike from Replicate 3.<62 micrometer

Para meter code

in percent<2.000 micrometer

Based on Based on Based on analysis of analysis of analysis of

Constituent Replicate 1 Replicate 2 Replicate 1

Based on analysis of Replicate 2

Mean percent recovery

Percent relative standard deviation


3933339351 3938339363 39368

39373 393893939339413 39423

39343 39481 397583951939251

8188639403

34411 34584 3970534389

34399

34281

34276

34286

34639

34641

3453934569345743461434629

39701344503455434589 34604

Aldringross Chlordane Dieldrinp,p'-DDD p,p'-DDE

p,p'-DDT Endosulfan IEndrinHeptachlor Heptachlor epoxide

Lindane (gamma-HCH) p , p ' -Methoxy chlor MirexPCBPCN

PerthaneToxaphene

Isophorone 2-Chloronaphthalene HexachlorobutadieneHexachlorocyclopenta- diene

Hexachloroethane

bis (2-Chloroethoxy) methane

bis (2-Chloroethyl) ether

bis (2-chloroisopropyl) ether

4-Bromophenyl phenyl ether

4-Chlorophenyl phenyl ether

1,2 Dichlorobenzene1,3 Dichlorobenzene1,4 Dichlorobenzene2,4 Dinitrotoluene2,6 Dinitrotoluene

HexachlorobenzeneNitrobenzene1,2,4 Trichlorobenzene2-Chlorophenol 2,4 Dichlorophenol

50100 8671 82

90 44

10054 75

58 ns ns<. /

ns

ns<10

39 38

<21<21

64

29

8

200

78

<2i<21<215288

190231

65 110

5071 8676

110

92 49

10054 75

58 ns ns

, < 4ns

ns<10

Semi -volatile

39 38

<21<21

64

29

8

200

78

<21<21<215288

190231

65 110

67230 9889

250

110 10012017 78

61 ns ns<. 5

ns

ns<16

compounds

66 925

<33<33

110

44

<33

300

160

223

1019

300211479

160

6733

10092

131

102 97

12217 78

61 ns ns<. 5

ns

ns<16

66 925

<33<33

110

44

<33

295

160

223

1019

300211479

160

58110 9282

143

98 72

11236 76

60 ns ns<. 4

ns

ns<13

52 65

<27<27

87

36

<20

250

119

<12<12<123154

240228

72 130

1779 8

12 51

9 421060 2

3 ns ns-

ns

ns

30 48

_-

30

24

_

21

40

_--

7874

255

10011 22

136

Table 53. Analytical recovery of organochlorine and semi-volatile organic compounds spiked in bed-sediment samples from Sulphur Creek Wasteway, Washington, August 31, 1988 Continued

<62 micrometerPara meter code Constituent



<2.000 miBased on analysis of Replicate 1

crometerBased on analysis of Replicate 2

Mean percent recovery

Percent relative standard deviation

Semi-volatile compounds Continued

3460934660346193459434649

3445539061346953462439102

3433934344391123459934295

3420834203342233452934250

3423334245345243432334559

3437934384344063444534464

344723444134431

34436

2, 4-Dimethylphenol4 , 6-Dinitroortho cresol2, 4-Dinitrophenol2-Nitrophenol4-Nitrophenol

Farachloro meta cresolFentachlorophenolPhenol2,4,6 Trichlorophenolbis (2-Ethylhexyl)

phthalate

Di ethyl phthalateDimethyl phthalateDi-n -butyl phthalateDi-n-octyl phthalateN-butyl benzl phthalate

AcenaphtheneAc enaphthy leneAnthraceneBenzo (a) anthraceneBenzo (a) pyrene

Benzo (b) fluorantheneBenzo (k) fluorantheneBenzo (g,h,i) peryleneChryseneDibenz (a,h) anthracene

FluorantheneFluoreneIndeno (1,2,3-cd) pyreneNaphthalenePhenanthrene

PyreneN-NitrosodimethylamineN-Nitrosodi-n-propyl-


23

<21647

87<1313097

110

89120629480

523078

120110

12012096120140

8662914

100

120<21

6289

23

<21647

87<1313097

100

82120559480

523078

120110

12012096120140

8662914

96

110<21

6289

21<20<33

42

170<20150110

200

13023034

13040

11073

150190190

210180160180130

12013015016

180

150<33

120210

21<20<33

42

170<20120110

110

1202302913032

11073150190190

210180160180130

12013015016

180

150<33

120210

12<12<27344

130<16130100

130

10017045

11058

7952

120150150

170150130150140

10096

12010

140

140<27

89150

95 -

10064

38-88

36

2235361744

4048432433

313828236

2040306932

15-

3547

137

Table 54. Laboratory quality-assurance data for organochlorine compounds analyzed in biological samples collected in 1989 and 1990, Yakima River basin, Washington

[Concentrations in micrograms per kilogram, wet weight; spike = 100 micrograms per kilogram, except 500 micrograms per kilogram for kepone; ; "<" = less than; ODD = dichlorodiphenyldichloroethane; DDE = dichlorodiphenyldichloroethylene; DOT = dichlorodiphenyltrichloroethane; NS = not spiked; "-" = not applicable; matrix blanks for fish consist of ocean-fish samples with very low to non- detectable concentrations of organochlorine compounds; matrix blanks for vegetation consist of grass samples collected in non-agricultural areas near Mississippi State University]

Compound Reagentanalyzed blank

Matrixblankforfish

Spikeforfish

Percent Reagent Reagentrecovery blank blank

Spikeforfish

Percentrecovery

Reagentblank

May 1989

Hexachlorobenzene <10a-Hexachlorocyc lohexane <10g-Hexachlorocyclohexane <10b-Hexachlorocyclohexane <10d-Hexachlorocyc lohexane <10

Oxychlordane <10Heptachlor epoxide <10trans-Chlordane <10trans-Nonachlor <10Toxaphene <50

Total PCBs <50o,p'-DDE <10cis-Chlordane <10p,p'-DDE <10Dieldrin <10

o,p'-DDD <10Endrin <10cis-Nonchlor <10o,p'-DDT <10p,p'-DDD <10

p.p'-DDT <10Mirex <10Dicofol <10Octochlorstyrene <10Kepone <10

Percent moisturePercent lipid

<10<10<10<10<10

<10<10<10<10<50

<50<10102010

<10<10<10<1010

<10<io<10<10<io

71.08.53

60NS8989NS

8899NS93NS

NS9795

10090

NS1009593

100

100939771

310

70.08.74

60-

8989-

8899-

93-

-9795

10090

-1009593

100

10093977162


Hexachlorobenzene <10a-Hexachlorocyc lohexane <10g-Hexachlorocyclohexane <10b-Hexachlorocyclohexane <10d-Hexachlorocyc lohexane <10

Oxychlordane <10Heptachlor epoxide <10trans-hlordane <10trans-Nonachlor <10Toxaphene <50

Total PCBs <50o,p'-DDE <10cis-Chlordane <10p.p'-DDE <10Dieldrin <10

o,p'-DDD <10Endrin <10cis-Nonchlor <10o,p'-DDT <10p,p'-DDD <10

p.p'-DDT <10Mirex <10Octochlorstyrene <10Dicofol <10Kepone <10

Percent moisturePercent lipid

<io<io<io<10<10

<10<10<10<10<50

<50<10102010

<10<10<10<1010

<10<10<10<10<10

71.08.53

72NS9498NS

100100NS95NS

NS1109999

100

NS10010099

100

100978591

' 410

70.09.28

72 <10 <10<10 <10

94 <10 <1098 <10 <10

<10 <10

100 <10 <10100 <10 <10

<10 <1095 <10 <10

<50 <50

<50 <50110 <10 <1099 <10 <1099 <10 <10

100 <10 <10

<10 <10100 <10 <10100 <10 <1099 <10 <10

100 <10 <10

100 <10 <1097 <10 <1085 <10 <1091 <10 <1082 <10 <10

_- -

71NS8193NS

8892NS85NS

NS949699

100

NS91979598

94947790

370

70.58.96

71-

8193-

8892-

85-

_949699

100

-91979598

9494779074

_-

<10<io<io<10<10

<10<10<10<10<50

<50<10<10<10<10

<10<10<10<io<10

<io<10<10<10<10

_-

138

Table 54. Laboratory quality-assurance data for organochlorine compounds analyzed in biological samples collected in 1989 and 1990, Yakima River basin, Washington Continued

Matrixblank

Compound Reagent foranalyzed blank fish

Spikeforfish

Percent Reagent Reagentrecovery blank blank

Spikeforfish

Percentrecovery

Reagentblank


Hexachlorobenzene <10 <10a-Hexachlorocyclohexane <10 <10g-Hexachlorocyclohexane <10 <10b-Hexachlorocyclohexane <10 <10d-Hexachlorocyclohexane <10 <10

Oxychlordane <10 <10Heptachlor epoxide <10 <10trans-Chlordane <10 <10trans-Nonachlor <10 <10Toxaphene <50 <50

Total PCBs <50 <50o.p'-DDE <10 <10cis-Chlordane <10 <10p,p'-DDE <10 <10Dieldrin <10 <10

o,p'-DDD <10 <10Endrin <10 <10cis-Nonchlor <10 <10o.p'-DDT <10 <10p,p'-DDD <10 <10

p,p'-DDT <10 <10Mirex <10 <10Octochlqrstyrene <10 <10Dicofol <10 <10Kepone <10 <10

Percent moisture - 80 . 0Percent lipid

88NS120100NS

100110NS100NS

NS120110110100

NS100110120130

100120100120390

80.0~

88 <10<10

120 <10100 <10

<10

100 <10110 <10

- <10100 <10

<50

<50120 <10110 <10110 <10100 <10

<10100 <10110 <10120 <10130 <10

100 <10120 <10100 <10120 <1078 <10

_


Hexachlorobenzene <10 <10a-Hexachlorocyclohexane <10 <10g-Hexachlorocyclohexane <10 <10b-Hexachlorocyclohexane <10 <10d-Hexachlorocyclohexane <10 <10

Oxychlordane <10 <10Heptachlor epoxide <10 <10trans-Chlordane <10 <10trans-Nonachlor <10 <10Toxaphene <10 <10

Total PCBs <10 <10o.p'-DDE <10 <10cis-Chlordane <10 <10p,p'~DDE <10 <10Dieldrin <10 <10

o,p'-DDD <10 <10Endrin <10 <10cis-Nonchlor <10 <10o.p'-DDT <10 <10p,p'-DDD <10 <10

p,p'-DDT <10 <10Mirex <10 <10

Percent moisture - 81.4Percent lipid - 1.14

57NS10098NS

91100NS89NS

NS100949393

NS1009196

100

10090

82.21.07

57 <10 <10<10 <10

100 <10 <1098 <10 <10

<10 <10

91 <10 <10100 <10 ^10

<10 <1089 <10 <10

<10 <10

<10 <10100 <10 <1094 <10 <1093 <10 <1093 <10 <10

- <10 ^10100 <10 <1091 <10 <1096 <10 <10

100 <10 <10

100 <10 <1090 <10 <10

_ _- -

57NS10097NS

96100NS91NS

NS100949590

NS1009096

100

9485

83.61.06

57-

10097-

96100

-91-

-100949590

_1009096

100

9485

<io<10<10<10<10

<10<10<10<10<10

<10<10<10<10<10

<10<10<10<io<10

<10<10

_-

139

Table 55. Laboratory quality-assurance data for semi-volatile organic compounds (polycyclic-aromatic hydrocarbons) analyzed in biological samples collected in 1989 and 1990, Yakima River basin, Washington

[Concentrations in micrograms per kilogram, wet weight; spike = 100 micrograms per kilogram; "-" not applicable; matrix blanks for fish consist of ocean-fish samples with very low to non-detectable concentrations of organochlorine compounds; matrix blanks for vegetation consist of grass samples collected in non-agricultural areas near Mississippi State University]

Compound analyzed

Matrix blank Spike

Reagent for for Percent blank fish fish recovery

May 1989

Napthalene <10 <10 Fluorene <10 <10 Phenanthrene <10 <10 Anthracene <10 <10 Fluoranthrene <10 <10

Pyrene <10 <10 1,2-Benzanthracene <10 <10 Chrysene <10 <10 Benzo (b)f luoranthrene <10 <10 Benzo (k)f luoranthrene <10 <10

Benzo (e)pyrene <10 <10 Benzo(a)pyrene <10 <10 1,2,5,6-Dibenzanthracene <10 <10 Benzo (g,h,i)perylene <10 <10

Percent moisture - 81

Compoundanalyzed

Matrixblank

Reagent forblank fish

Spikeforfish

Percent Reagentrecovery blank

75 7595 95 90 90 88 88 80 80

96 96 91 91 94 94 73 93 66 66

84 84 89 89 82 82 71 71

.4 84.5

Reagentblank

Matrixblankfor

vegetation

Spikefor**

vegetationPercent Reagentrecovery blank


NapthaleneFluorenePhenanthreneAnthraceneFluoranthrene

Pyrene1,2-BenzanthraceneChryseneBenzo (b ) f luoranthreneBenzo (k ) f luoranthrene

Benzo (e)pyreneBenzo(a)pyrene1,2,5, 6-Dibenzanthr aceneBenzo ( g , h , i ) pery lene

Percent moisture

<10 <10<10 <10<10 <10<10 <10<10 <10

<10 <10<10 <10<10 <10<10 <10<10 <10

<10 <10<10 <10<10 <10<10 <10

80.6

Compoundanalyzed

7084947181

7165577564

90716092

78.

70 <1084 <1094 <1071 <1081 <10

71 <1065 <1057 <1075 <1064 <10

90 <1071 <1060 <1092 <10

0 -

Matrixblank

Reagent forblank fish

<10<10<10<10<10

<10<10<10<10<10

<10<10< 10<10

-

Spikeforfish

<10<10<10<10<10

<10<10<10<10<10

<10<io<10<10

80.0

Percent

7094948268

7575979664

70685049

80.0

70 <1094 <1094 <1082 <1068 <10

75 <1075 <1097 <1096 <1064 <10

70 <1068 <1050 <1049 <10

-

recovery


NapthaleneFluorenePhenanthreneAnthraceneFluoranthrene

Pyrenel,2~Benzanthrac<Chrysene

sne

<10 <10<10 <10<10 <10<10 <10<10 <10

<10 <10<10 <10<10 <10

Benzo(b)fluoranthrene <10 <10Benzo (k)f luoranthrene <10 <10

Benzo(e)pyreneBenzo(a)pyrene

<10 <10< 10 <10

1,2,5,6-Dibenzanthracene <10 <10Benzo(g,h,i)per:/ lene <10 <10

6810095

10083

8785777878

94667967

6810095

10083

8785777878

94667967

Percent moisture 81.4 83.6

140

Table 56. Concentretions of organochlorine compounds in field-replicate and laboratory-split samples of aquatic biota, Yakima River basin, Washington, 1969-90

[Concentrations in micrograms per kilogram; wet weight; whole fish were analyzed; DDD « dichlorodiphenyldichloroethane; DDE = dichlorodiphenyldichloroethylene; DDT - dichlorodiphenyltrichloroethane; PCBa polychlorinated biphenyls; "--" » not analyzed; see figure 1 for site locations; "Replicate" two or more composite samples were collected at a station on the same day and were analyzed individually; "Split" = a single composite sample was homogenized, split into two samples at the lab, and each split was analyzed]

Quality- assurance sample type

Map refer ence Station number number Station name Dete

Field Moisture, Lipid, number in percent in percent

Largescale Sucker

Split Split

Split Split

Split Split Replicate

22 12499000 Naches River nr North Yakima 22 12499000 Naches River nr North Yakima

47 12509050 Yakima R at Euclid Br at RM 55 nr Grandview 47 12509050 Yakima R at Euclid Br at RM 55 nr Grandview

51 12510500 Yakima River at Kiona 51 12510500 Yakima River et Kiona 51 12510500 Yakima River at Kiona

11-06-90 11-06-90

10-31-89 10-31-89

11-10-90 11-10-90 11-10-90

YK0331SF 75.4 4.71 YK0331SF 75.6 4.34

YK0047SF 73.5 7.56 YK0047SF 74.0 7.32

YK0402SF 70.6 7.99 YK0402SF 71.4 7.78 YK0403SF 67.6 11.6

Asiatic Clam

Replicate Replicate Replicate Replicate

Replicate Replicate

Replicate Replicate

40 12507585 Yakima River at RM 72 ab Satus Cr nr Sunnyside 40 12507585 Yakima River at RM 72 ab Satus Cr nr Sunnyside 40 12507585 Yakima River at RM 72 ab Setus Cr nr Sunnyside 40 12507585 Yakima River at RM 72 ab Setus Cr nr Sunnyside

47 12509050 Yakima R at Euclid Br at RM 55 nr Grandview 47 12509050 Yakima R at Euclid Br at RM 55 nr Grandview

51 12510500 Yakima River at Kiona 51 12510500 Yakima River at Kiona

11-01-89 11-01-89 11-01-89 11-01-89

10-31-89 10-31-89

10-30-89 10-30-89

YK0100SM 76.0 2.40 YK0101SM 78.0 2.32 YK0102SM 79.0 2.62 YK0103SM 82.0 1.96

YK0082SM 95.5 1.64 YK0085SM 82.0 2.20

YK0115SM 83.0 2.20 YK0116SM 84.0 1.95

Western Pearlshell

Split Split

14 12484500 Yakima River at Umtanum 14 12484500 Yakima River at Umtanum

11-01-89 11-01-89

YK0111SM 86.0 .92 YK0111SM 84.0 .86

Waterweed

Split Split

26 12500442 Wide Hollow Cr at Old STP at Union Gap 26 12500442 Wide Hollow Cr at Old STP at Union Gap

11-04-89 11-04-89

YK0098SP 94.0 .10 YK0098SP 94.0 .20


Hepta- Station Field cis- trans- Oxy- chlor number number Chlordane Chlordane chlordane epoxide

cis- Nonachlor

trans- Nonachlor

Largescale Sucker

22 22

47 47

51 51 51

12499000 YK0331SF 10 <10 <10 <10 12499000 YK0331SF 10 <10 <10 <10

12509050 YK0047SF 20 <10 <10 <10 12509050 YK0047SF 20 <10 <10 <10

12510500 YK0402SF 20 10 10 10 12510500 YK0402SF 20 10 10 10 12510500 YK0403SF 30 10 20 20

<10 <10

<10 <10

<10 <10 <10

<10 <10

20 20

30 40 40

Asiatic Clam

40 40 40 40

47 47

51 51

12507585 YK0100SM <10 <10 <10 <10 12507585 YK0101SM <10 <10 <10 <10 12507585 YK0102SM <10 <10 <10 <10 12507585 YK0103SM <10 <10 <10 <10

12509050 YK0082SM <10 <10 <10 <10 12509050 YK0085SM <10 <10 <10 <10

12510500 YK0115SM <10 <10 <10 <10 12510500 YK0116SM <10 <10 <10 <10

<10 <10 <10 <10

<10<10

<10 <10

<10 <10 <10 <10

<10 <10

<10 <10

Western Pearlshell

14 14

12484500 YK0111SM <10 <10 <10 <10 12484500 YK0111SM <10 <10 <10 <10

<10 <10

<10 <10

Waterweed

26 26

12500442 YK0098SP <10 <10 <10 <10 12500442 YK0098SP <10 <10 <10 <10

<10 <10

<10 <10

141

Table 56. Concentrations of organochlorine compounds in field-replicate and laboratory-split samples of aquatic biota, Yakima River basin, Washington, 1989-90 Continued


22 22

47 47

51 51 51

40 40 40 40

47 47

51 51

14 14

26 26


Station number

12499000 12499000

12509050 12509050

12510500 12510500 12510500

12507585 12507585 12507585 12507585

12509050 12509050

12510500 12510500

12484500 12484500

12500442 12500442

Station number

Field number

YK0331SF YK0331SF

YK0047SF YK0047SF

YK0402SF YK0402SF YK0403SF

YK0100SM YK0101SM YK0102SM YK0103SM

YK0082SM YK0085SM

YK0115SM YK0116SM

YK0111SM YK0111SM

YK0098SP YK0098SP

Field number

o,p'" P.P 1 - o,p'- P.P'- o,p'~ DDD ODD DDE DDE DOT

Largescale Sucker

10 50 <10 410 <10 10 50 <10 380 <10

50 290 <10 2,500 <10 50 290 <10 2,400 <10

40 300 30 2,000 <10 40 300 30 2,100 <10 50 390 30 2,200 <10

Asiatic Clam

10 60 <10 310 <10 10 50 <10 280 <10 10 60 <10 330 <10 10 40 <10 230 <10

20 80 <10 390 <10 30 100 10 530 <10

20 80 10 410 <10 20 60 <10 360 <10

Western Pearlshell

as <\°0 <i° as <i°0Waterweed

<10 <10 <10 10 <10 <10 <10 <10 10 <10

g-Hexachloro- Hexachloro- a-Hexachloro- b-Hexachloro- cyclohexane benzene cyclohexane cyclohexane (lindane)

p.p'DOT

70 80

370 370

190 190 220

80 70 80 60

40 60

50 30

as

as

d-Hexachloro- cyclohexane Toxaphene

Largescale Sucker

22 22

47 47

51 51 51

12499000 12499000

12509050 12509050

12510500 12510500 12510500

YK0331SF YK0331SF

YK0047SF YK0047SF

YK0402SF YK0402SF YK0403SF

<10 <10 <10 <10

<10 <10 <10 <10 <10 <10 ^10 <10 <10 <10 <10 <10

:ii<50 <50

520 560

710 710 720

Asiatic Clam

40 40 40 40

47 47

51 51

12507585 12507585 12507585 12507585

12509050 12509050

12510500 12510500

YK0100SM YK0101SM YK0102SM YK0103SM

YK0082SM YK0085SM

YK0115SM YK0116SM

<10 <10 <10 < 10 <10 <10 <10 <10 <10 <10 <10 <10

<10 <10 <10 <10

<10 <10 <10 <10 <10 <10 <10 <10

<10

<io

<50 <50 <50 <50

<50 <50

<50 <50

Western Pearlshell

14 14

12484500 12484500

YK0111SM YK0111SM ^ ^ ^ ^ as <50

<50

Waterweed

26 26

12500442 12500442

YK0098SP YK0098SP 35 :i° :% :\° <io <50

<50

142

Table 56. Concentrations of organochlorine compounds in field-replicate and laboratory-split samples of aquatic biota, Yakima River basin, Washington, 1989-90 Continued


Station number

Field number

Total PCBs

Octochloro- Dieldrin Endrin Mirex Kepone styrene Dicofol

Largescale Sucker

2222

A7A7

515151

12A9900012A99000

1250905012509050

125105001251050012510500

YK0331SFYK0331SF

YKOOA7SFYKOOA7SF

YKOA02SFYKOA02SFYKOA03SF

<50<50

290300

790790900

<10 <10<10 <10

80 <1070 <10

60 <1060 <1090 <10

<10<10

<10 <10 <10 20<10 <10 <10 20

<10 -- -- <10<10 -- -- <10<10 - - <10

Asiatic Clam

AOAOAOAO

A7A7

5151

12507585125075851250758512507585

1250905012509050

1251050012510500

YK0100SMYK0101SMYK0102SMYK0103SM

YK0082SMYK0085SM

YK0115SMYK0116SM

<50<50<50<50

<50<50

<50<50

10 <10 <10 <10 <10 <1010 <10 <10 <10 <10 <1010 <10 <10 <10 <10 <1010 <10 <10 <10 <10 <10

20 <10 <10 <10 <10 <1020 <10 <10 <10 <10 <10

10 <10 <10 <10 <10 <1010 <10 <10 <10 <10 <10

Western Fearlshell

12A8A500 12A8A500

YK0111SM YK0111SM

<50 <50

Waterweed

2626

12500A42 12500AA2

YK0098SP YK0098SP

<50 <50

143

Table 57. Concentrations of semi-volatile organic compounds (polycyclic-aromatic hydrocarbons) in field-replicate and laboratory-split samples of aquatic biota, Yakima River basin, Washington, 1989-90

[Concentrations in micrograms per kilogram, wet weight; whole fish were analyzed; see figure 1 for site locations; "Replicate" = two or more composite samples were collected at a station on the same day and were analyzed individually; "Split" = a single composite sample was homogenized, split into 2 samples at the lab, and each split was analyzed]

Quality-assurancesampletype

Mapreferencenumber

Stationnumber Station name Date

Fieldnumber

Moisture, Lipid,in percent in percent

Asiatic Clam

ReplicateReplicateReplicateReplicate

ReplicateReplicate

ReplicateReplicate

40404040

4747

5151

12507585125075851250758512507585

1250905012509050

1251050012510500

YakimaYakimaYakimaYakima

YakimaYakima

YakimaYakima

RiverRiverRiverRiver

at RM 72 ab Satus Cr nr Sunnysideat RM 72 ab Satus Cr nr Sunnysideat RM 72 ab Satus Cr nr Sunnysideat RM 72 ab Satus Cr nr Sunnyside

R at Euclid Br at RM 55 nr GrandviewR at Euclid Br at RM 55 nr Grandview

RiverRiver

at Kionaat Kiona

11-01-8911-01-8911-01-8911-01-89

10-31-8910-31-89

10-30-8910-30-89


YK0082SMYK0085SM

YK0115SMYK0116SM

76.0 2.4078.0 2.3279.0 2.6282.0 1.96

95.5 1.6482.0 2.20

83.0 2.2084.0 1.95

Western Pearlshell

SplitSplit

1414

1248450012484500

YakimaYakima

RiverRiver

at Umtanumat Umtanum

11-01-8911-01-89

YK0111SMYK0111SM

86.0 .9284.0 .86

Waterweed

SplitSplit

2626

1250044212500442

Wide Hollow Cr at Old STP at Union GapWide Hollow Cr at Old STP at Union Gap

11-04-8911-04-89

YK0098SPYK0098SP

94.0 .2094.0 .10

Mapreferencenumber

Stationnumber

Fieldnumber Napthalene

Phenan- Anthra-Fluorene threne cene

Fluor -anthrene Pyrene

1,2-Benz-anthracene

Asiatic Clam

40404040

4747

5151

12507585125075851250758512507585

1250905012509050

1251050012510500


YK0082SMYK0085SM

YK0115SMYK0116SM

10<10<1010

1020

<1010

<10 30 <10<10 30 <1010 30 <10

<10 40 <10

<10 40 <10<10 30 <10

10 90 <10<10 40 <10

10101010

<1010

2050

<10<10<10<10

<1010

<10<10

<10<1010

<10

<10<10

<10<10

Western Pearlshell

1414

1248450012484500

YK0111SMYK0111SM

<1010

<10 <10 <10<10 10 <10

<10<10

<10<10

<10<10

Waterweed

2626

1250044212500442

YK0098SPYK0098SP

<10<10

<10 <10 <10<10 <10 <10

<10<10

<10<10

<10<10

144

Table 57. Concentrations of semi-volatile organic compounds (polycyclic-aromatic hydrocarbons) in field-replicate and laboratory-split samples of aquatic biota, Yakima River basin, Washington, 1989-90 Continued


Station number

Field number Chrysene

Benzo(b)- fluoranthrene

Benzo(k)- fluoranthrene

Benzo(e)- Benzo(a)- 1,2,5,6-Dibenz- Benzo(g,h,i)- pyrene pyrene anthracene perylene

Asiatic Clam

40404040

4747

5151

12507585-125075851250758512507585

1250905012509050

1251050012510500

YK0100SM <10 <10 <10 <10 <10 <10 <10YK0101SM <10 <10 <10 <10 <10 <10 <10YK0102SM <10 <10 <10 <10 <10 <10 <10YK0103SM <10 <10 <10 <10 <10 <10 <10

YK0082SM ^10 ^10 ^10 ^10 ^10 ^10 <10YK0085SM <10 <10 <10 <10 <10 <10 <10

YK0115SM <10 <10 <10 <10 <10 <10 <10YK0116SM <10 <10 <10 <10 <10 <10 <10

Western Fearlshell

1248450012484500

YK0111SM YK0111SM

Waterweed

2626

1250044212500442

YK0098SP YK0098SP

1010

145

APPENDIX A

METHOD FOR ANALYZING TRACE-ORGANIC COMPOUNDS IN FILTERED WATER

Dissolved-Phase Preconcentration

The Goulden Large Sample Extractor (GLSE), a continuous-flow liquid-liquid extractor (Goulden and Anthony, 1985), was used to extract small concentrations of organic compounds from large volumes of water. A schematic representation of the GLSE (Alien Scientific Glassware, Boulder, Colorado) is shown in figure Al. The dimensions of the mixer- settler portion of the GLSE were similar to that initially described by Goulden and Anthony, 1985.

The water sample was pumped at a flow rate of 350 mL/min (milliliters per minute) through Teflon tubing from a tared, stainless - steel, milk can into chamber A of the GLSE using a positive displacement pump [PI] (Model RP-D-2CSC, Fluid Metering Inc.) [fig. Al]. The sample was mixed with the dichloromethane (DCM) extraction solvent using a stirrer blade positioned in chamber A approximately 2 cm (centimeters) from the bottom. The stirrer motor (Fisher Dyna-Mix) was mounted just above the top opening of chamber A. The positioning, blade configuration, and rotation of the stirrer forced the incoming water upward in mixing chamber A and downward in the settling chamber B. This configuration provided efficient mixing, while minimizing the formation of emulsions (Goulden and Anthony, 1985). Column D consisted of a high- density polypropylene Buchner flat-bottom funnel that was packed with 4 mm (millimeters) x 4 mm Teflon Raschig rings. This column was placed over chamber C and was designed to minimize loss of DCM droplets and help break up emulsions (Goulden and Anthony, 1985). A final settling chamber [E] consisted of a Teflon separatory funnel and was positioned downstream of chamber C to collect any remaining DCM droplets. Additional air vents were positioned in the top of the GLSE between chambers A and C, and between C and E.

During the extraction process, a substantial volume of DCM was lost in the effluent water exiting chamber E, because DCM is appreciably soluble in water (about 1.6 percent by volume at 20°C [degrees Celsius]). In addition, some DCM is lost because of volatilization from the open-top design of the GLSE. To counter this loss, DCM was replenished by pumping solvent from a reservoir by another positive displacement pump [P2] (Model RP-SY-1CSC, Fluid Metering Inc.) through an opening at the top of chamber C directly into the packing in column D. Introduction of fresh solvent into column D also helped to extract remaining analytes from the water (Goulden and Anthony, 1985).

It should be noted that large volumes of DCM-saturated waste water, generated by the GLSE system used in this study, present a considerable disposal problem, especially for field applications. In addition, the vapor loss from its open-top design results in a significant vapor exposure potential. A newer version of the GLSE has recently been developed (oral commun., March 1992, D.H.J. Anthony, Environment Canada, National Water Research Institute, Burlington, Ontario) that reduces solvent vapor loss and incorporates a solvent-recovery system, although the latter necessitates much slower flow rates (about 2 L (liters) per hour).

146

DICHLOROMETHANE (DCM)

EXPLANATIONP1 Positive displacement pump 1A Mixing chamber AB Settling chamber BC Settling chamber CD Column D-Designed to minimize loss of solventE Final Settling Chamber EP2 Positive displacement pump 2

F, G, H Stopcocks for draining system

Figure Al. Goulden Large-Sample Extractor.

147

Prior to processing every natural, spike, or blank sample, the GLSE and support hardware were cleaned by pumping 100 mL of acetone and 100 mL of methanol through the Teflon inlet tubing into chamber A using sample pump PI. The extractor also was rinsed thoroughly with acetone and methanol. For the final rinse, the extractor system was filled with 10 L of charcoal-filtered tap water via pump PI, and then drained.

The GLSE was operated by initially adding 250 mL of DCM to the extractor. The sample pump (PI) was started and, when the extractor was half-filled, the stirrer was started. As the sample finished filling the extractor, 50 mL of DCM were used to charge the Raschig rings in column D. The stirrer speed was adjusted so that a homogeneous mixture of sample and DCM was maintained and only a small number of droplets spilled over into chamber C. A solvent level midway between chambers A and C was maintained by continuously introducing fresh DCM at 9 mL/min into the packed column D with pump P2. Once started, a sample was extracted continuously without interruption. Sample volumes processed through the GLSE ranged from 4.4 to 112 L, depending on the expected target-analyte concentrations. After the sample was pumped through the extractor, 500 mL of distilled water was pumped into the extractor by pump PI to ensure that all of the sample had reached the GLSE. The pumps and stirrer were then stopped and the DCM-water mixture was allowed to separate. The DCM fraction was drained through stopcock G into a 500-mL amber-glass bottle that was pre-cleaned by acid rinsing and heating to 450°C for 8 hours. The water in the GLSE was drained through stopcock F until the water level was below column D. Fifty milliliters of DCM were poured through column D, and following settling, the DCM was collected through stopcock G. Water in the extractor was carefully drained through stopcock F to avoid losing any solvent droplets still present. After all the water was removed from the GLSE, the extractor was meticulously rinsed with DCM, which was collected through stopcock G into the amber-glass bottle. Additionally, any DCM droplets in separatory funnel E were collected through stopcock H. Extracts were packed in ice for shipment to the U.S. Geological Survey Laboratory (Methods Research and Development Program in Arvada, Colorado). At the lab, the samples were stored in a refrigerator until volume reduction prior to analysis. During the filtration and extraction process, the solvents and samples only came into contact with Teflon, glass, or stainless steel, except for column D in the Goulden extractor which was made of high-density polypropylene.

GLSE Precleaning and Assembly

Before shipment to the field lab, all GLSE parts that would come in contact with sample or solvent were precleaned with Alconox soap solution, and rinsed with tap and distilled water and acetone. Non- glass components also were rinsed in methanol and DCM prior to being wrapped in clean (baked) aluminum foil. The glass components of the GLSE were then baked for 12 hours in a 450°C oven, and the openings were wrapped in clean aluminum foil. All components were then carefully packed for shipment to the field.

148

At the field lab, the GLSE was attached to a support-rack system contained within a wooden shipping box. The GLSE required electrical power for operation of the sample (PI) and solvent-metering (P2) pumps and the stirrer. The GLSE and filtration pumps were calibrated in the field to verify flows.

Laboratory Preparation of GLSE Extracts

Residual water was removed from extracts using a Teflon separatory funnel and by subsequently passing the extract through anhydrous sodium sulfate. Dried extracts were vacuum-rotary evaporated at 30°C to a volume of approximately 5 mL. Toluene was added as a keeper solvent to the 5-mL extracts, and volume was further reduced by evaporation with ultra-pure nitrogen to a final volume of 0.2 mL.

Ins trumentation

All GLSE extracts were spiked with a perdeuterated-polycyclic- aromatic- hydrocarbon (PAH) internal-injection standard and analyzed by gas chromatography/mass spectrometry (GC/MS) using a Hewlett-Packard (HP) 5890A GC, equipped with a HP 5970 MSD (mass selective detector) and a HP 7673A autosampler. The GC/MSD was fitted with a 30-meters (m) long, 2.5-mm internal diameter, 0.25-micrometers-film-thickness-fused- silica, capillary column (Model DB-1701, J & W Scientific, Inc.). Compound separations were performed using the following temperature program: 80°C initial temperature for 2 minutes; followed by a 20°C per minute gradient to 120°C; followed by a 2.5°C per minute to 285°C with 18.5-minute hold time. The injector and transfer line were set at 250°C and 285°C, respectively. Two-microliter splitless injections were performed by the HP 7673A autosampler. The helium carrier gas had a linear velocity of 32 cm/s (centimeter per second) at 50°C. The split sweep and septum purge were set at 30 and 3 mL/min, respectively. The Grob split time was set at 2 minutes for all injections.

Electron-impact ionization mass spectrometric analysis was conducted at an energy of 70 electronvolts (eV), The ion source temperature was 200°C. The electron multiplier voltage ranged between 1,400 and 2,000 volts (V). Selected ion monitoring for the parent ion and two other characteristic ions was used.

Quantification

All integrations were performed by a HP 59970C 9000 Series Model 216 Chemstation. Response factors relative to perdeuterated PAH's were determined from 0.05, 0.10, 0.25, 0.50, 1.0, and 5.0 ng/^L (nanograms per microliter) standards, for sets of 10 to 16 samples. Modified Lee retention indices (Lee and other, 1979) were calculated using the internal-injection standard as the retention index markers on the DB- 1701 column. Quantification levels were determined using the approach of Miller and Miller (1986). The presence of an analyte required: agreement with the relative retention indices, the presence of the parent peak, and the confirmation of the ion abundances of at least one of the characteristic ions relative to the parent peak. Additionally, concentrations needed to exceed analytical noise in order to be quantifiable.

149

Reagents

All solvents were pesticide-residue grade obtained from Burdick and Jackson, Muskegon, Michigan. Pesticide reference standards were obtained from the U.S. Environmental Protection Agency Pesticide Repository, Research Triangle Park, North Carolina. Perdeuterated naphthalene, phenanthrene, fluoranthene, chrysene, and perylene, atrazine ethylamine d-5 (atrazine d-5), gamma-hexachlorocyclohexane d-6 (gamma-HCH d-6), p,p'-DDT d-8, and diazinon diethyl d-10 were obtained from Cambridge Isotopes, Woburn, Massachusetts. Perdeuterated benzo(ghi)perylene was obtained from MSD Isotopes, Montreal, Ontario, Canada. Pesticide stock solutions were formulated from accurately weighed pure standards, at approximately 1,000 ng//*L concentrations in ethyl acetate. All deuterated stock solutions were made in toluene. All pesticides were combined into 50-ng//iL mixed-standard solutions. GC/MS calibration standards were prepared independently from the mixed standard solutions. Instrumental calibration standard solutions were formulated in toluene. A surrogate standard containing atrazine d-5, gamma-HCH d-6, diazinon diethyl d-10, p,p'-DDT d-8, isodrin, and terbuthylazine was formulated at 10 ng//iL in methanol. A separate, 50- ng//*L, mixed standard containing the perdeuterated PAH was prepared. The internal-injection standard solution contained the perdeuterated PAH, naphthalene d-8, phenanthrene d-10, fluoranthene d-10, chrysene d- 12, and benzo(ghi)perylene d-12 diluted to 2.5 ng//iL in toluene.

Quality-Assurance Procedures

Quality-assurance samples represented a large percentage of the total samples processed in the GLSE, because this apparatus was in the evaluation stage. Of the 57 total GLSE extractions performed in the 1989 Yakima study, 32 were stream and well samples (including 4 replicate samples from one site), 12 were spiked samples, and 13 were system and extractor blanks.

Blanks were run for most phases of the procedure. Large volumes of distilled water were prepared in clean glass carboys and transported to the field lab. Field blanks were analyzed to determine extraneous sources of contamination during the filtration and extraction phases of the procedure. GLSE system blanks were prepared by pouring 10 to 20 L of distilled water into a clean milk can and processing it through the filtration unit using a clean glass-fiber filter. The system blank water was then extracted in the GLSE as described above for the stream and well samples.

Extractor blanks were run following every field-matrix spike sample to assess whether the GLSE cleaning procedure was adequate. Extractor blanks were not passed through the filtration apparatus, but were spiked with a surrogate solution and processed through the GLSE as with the system blanks and samples. Because of limitations in the volume of distilled water available to process blanks, extractor- and system-blank water volumes processed through the GLSE ranged from only 5 to 7.7 L for the 1989 trip, whereas stream and well-water sample volumes ranged from 4.4 to 112 L of water. Sampling-equipment blanks were not processed in the field because of an insufficient supply of distilled water. A

150

background site in the Wenatchee National Forest was sampled to assay environmental contributions not directly associated with agricultural pesticide applications in the Yakima River basin.

A surrogate solution was added to all GLSE samples prior to the extraction by spiking the filtered water during the filtration process to provide an estimate of the overall method performance. The surrogates were selected based on their physical and chemical similarity to the various target compound groups. The use of GC/MS also allowed for the selection of deuterated analogs of several target compounds (for example, diazinon d-10, atrazine d-5, gamma-HCH d-6, and p,p'-DDT d-8). However, because of differences in physical and chemical properties (like solubility and DCM-water partition coefficients), surrogate recoveries do not necessarily reflect recoveries for all of the other analytes within a particular pesticide class.

In June 1989, GLSE method performance for all target analytes was monitored by determining recoveries using field-matrix spikes. The spiking solution contained 68 pesticides in methanol and was added to the filtered water. Single-matrix spike samples were added at approximately 50 ng/L for the four 11- to 12- L samples, 25 ng/L for the two 36-L samples, and 11 ng/L for the two 110-L samples (table 40, Quality-assurance Data section). To assess precision, triplicate, 10-L samples from the Yakima River at Kiona were spiked at 50 ng/L (table 40, Quality-assurance Data section). Pesticide spikes were allowed to equilibrate with a sample for at least 30 minutes prior to extraction. Analytical recoveries in spiked samples were corrected for the amount of pesticides present in the duplicate samples of unspiked filtered stream water.

151

APPENDIX B

METHOD FOR ANALYZING TRACE-ORGANIC COMPOUNDS IN SUSPENDED SEDIMENT

Suspended-sediment samples collected in June 1989 were not all analyzed in the same laboratory, because the U.S. Geological Survey Methods and Research Development Laboratory was not prepared to analyze large numbers of suspended-sediment samples (29 stream samples plus quality-assurance samples). The samples were not analyzed using the same method, because procedural problems were recognized during sample- processing steps. The location of the laboratories where the samples were processed is listed in table Bl in this appendix for sample sets 1, 2, and 3. The method of analysis for sample set 3 is listed in Wershaw and others (1987); methods of analysis for sample sets 1 and 2 are described in this appendix.

Procedure for Analyzing Set-1 Samples

All suspended-sediment samples (sediment trapped on filters) were kept frozen until they were analyzed in October and November 1989. Prior to extraction, filters containing suspended sediment were thawed. Wet filters were placed into soxhlet extractors and spiked with a surrogate solution containing diazinon d-10 (10 hydrogens were deuterated), gamma-HCH d-6, p,p'-DDT d-8, and atrazine d-5. The filters were soxhlet extracted (using a solvent mix of 70 percent cyclohexane and 30 percent isopropanol) dried and concentrated to about 5 mL using vacuum-rotary evaporation, and further concentrated to 1 mL using nitrogen blowdown. The samples were then cleaned up and fractionated into two fractions using two rinses of a solvent mix (30 mL of a solvent mix containing 50 percent dichloromethane, 48.5 percent cyclohexane, and 1.5 percent acetonitrile) in a Florisil-sorbent-cartridge cleanup procedure. The first fraction contained most of the organochlorine compounds and some of the organophosphorus compounds. The first- fraction samples were (1) solvent exchanged to toluene and further reduced in volume to about 200 /zL (microliters), (2) transferred to gas chromatograph vials, (3) spiked with a perdeuterated-polycyclic- aromatic-hydrocarbons (PAH), internal-injection-standard solution, and (4) analyzed by GC/MS at the USGS Methods and Research Development laboratory. The second-fraction samples from the Florisil-sorbent cleanup procedure were not analyzed by GC/MS.

To obtain minimum reporting levels, samples were processed further for analyses of (1) organophosphorus compounds using a gas chromatograph with a flame-photometric detector (GC/FPD) and (2) organochlorine compounds using a gas chromatograph with an electron-capture detector (GC/ECD). In preparation for analysis of organophosphorus compounds, Florisil fractions 1 and 2 were recombined, solvent exchanged to toluene, and reduced to a final volume of 500 /zL. For the Yakima River at Euclid Bridge station, only the second-fraction extract was available for GC/FPD and GC/ECD analyses. The analysis was made using dual- column-capillary GC/FPD with DB-5 and DB-1701 columns. In preparation for analyses of organochlorine compounds, the set-1 samples were solvent exchanged to n-octane prior to alumina/silica column fractionation. The glass columns were dry packed with 3 g (grams) of alumina (heated to

152

Table Bl. Analytical laboratories where suspended-sediment samples were processed for analysis of trace-organic compounds, Yakima River basin, Washington, June 1989

[Sample sets were analyzed at U.S. Geological Survey Methods and Research Development Laboratory in Arvada, Colorado. RM River mile, see table 2 of main report for map reference numbers and figure 1 of main report for site locations]

Station number Station name

SAMPLE SET 1

Yakima River at Cle ElumYakima River at UmtanumUmtanum Creek nr mouthPacific Power & Light Company WastewayNaches River nr North YakimaYakima R abv Ahtanum CreekYakima River at RM 72Yakima R at Euclid Br at RM 55Yakima River at Kiona

SAMPLE SET 2

City of Yakima - Finish WaterMoxee Drain at Thorp RdGranger Drain at mouthWell 1, Sunnyside (09N/22E-04P01)Well 2, Harrah (11N/18E-22R02)South Drain nr SatusSulphur Creek Wasteway

SAMPLE SET 3

Cooper River at Salmon LaSacWilson Cr abv. Cherry CreekCherry Creek at ThrallWide Hollow Creek near mouthAhtanum Creek at Union GapE Toppenish Drain at Wilson RdSub 35 Drain at Parton RoadMarion Drain, Indian Church RdToppenish Cr, Indian Church RdSatus Cr abv Wilson-Charley Canyon nr ToppenishSatus Cr at gage at SatusSpring Creek at mouthSnipes Creek at mouth

124795001248450012484550124965101249900012500450125075851250905012510500

124965111250043012505460461720120043246251012032391250863012508850

12478200124841001248448012500445125025001250535012505410125055101250750812507594125086201250971012509829

153

135°C and 1-percent water deactivated) over 6 g silica (heated to 135°C and 5-percent water deactivated). The column was topped with 1 cm (of column height) of sodium sulfate (cleaned by heating overnight at 450°C), and prerinsed with a 35-mL solution of 25-percent ethyl acetate and 75-percent hexane followed by hexane rinses of 35 mL and 25 mL. Samples ranged in volume from 0.5 to 1 mL; they were separately added to the column and eluted with 35 mL of hexane (fraction A), followed by a 25-mL solution of 25-percent ethyl acetate and 75-percent hexane (fraction B). Fractions (A and B) were reduced in volume to 0.5 mL using nitrogen gas and then analyzed by dual-capillary-column GC/ECD using Restek Rtx 5 and 1701 columns.

Procedure for Analyzing Set-2 Samples

Set-2 samples were processed and extracted in January 1990. The procedure was identical to the set-1 procedure up to the Florisil sorbent cleanup step. Set-2 samples were not fractionated on Florisil and were not analyzed by GC/MS. In preparation for organophosphorus (GC/FPD) analyses, set-2 samples were reduced in volume to 500 /zL using cyclohexane as the final solvent. The GC/FPD analytical procedures for the set-2 samples were identical to the procedures used for the set-1 samples. In preparation for organochlorine (GC/ECD) analyses, the set-2 extracts in cyclohexane were cleaned up and fractionated on a combined alumina/silica column. The cleanup, fractionation, and GC/ECD analytical procedures for set-2 samples were identical to procedures used for the set-1 samples.

154

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SURFACE-WATER-QUALITY ASSESSMENT OF THE YAKIMA RIVER … › of › 1992 › 0644 › report.pdf · July 26, 1988, at 1000 hour and 1015 hour ----- 101 31B. Cherry Creek at Thrall,