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Weekly course details:
Week/
Duration
Modules Learning Objective Content
Week-1
Transition Elements
(3d series)-1
To : Learn the importance of
transition elements in colour of gemstones and also in Some of the important biological molecules like hemoglobin, vitamin B12 etc.
Differentiate between transition elements and non-transition elements
Write the electronic configuration of first raw transition elements having atomic number 21 to 30.
Write the electronic configuration of transition elements in their different Oxidation state.
Give the reason that why Sc and Zn are not included in the list of transition elements.
General group trends with
specific reference to
electronic configuration
Transition Elements
(3d series)-2
To:
Understand some of the general
physical properties of the first row
transition
metal ion.
Understand the general use of
the all ten first row elements in
the native state
and some of their important
compounds.
Understand the abundance of
the first row elements in the earth
crust.
See the trends in the following
properties%
o Ionization enthalpy
o Atomic & Ionic radii
o Melting point and hardness
o Electronegativity
General physical properties
of transition elements:
-Abundance
-ionization enthalpy
-atomic & ionic radii
-melting point & hardness
-electronegativity
Understand the reactivity of the
elements of first row transition in
general and in
particular with water.
Transition Elements
(3d series)-3
To : Know the alloy formation by
transition elements. Understand the Hume-Rothery
rule Understand the substitutional
and interstitial compounds Know the different variable
oxidation state possess by the first row transition elements
Learn the inter conversion of oxidation states in V, Cr, Mn etc.
General physical properties
of transition elements:
-variable oxidation state
-stability of various oxidation
state
Transition Elements
(3d series)-4
To: Distinguish between
diamagnetic and paramagnetic substances
ferromagnetic and antiferromagnetic substances
and heterogeneous catalysis by transition elements
General physical properties
of transition elements:
-catalysis
-magnetic properties
Week-2
Transition Elements
(3d series)-5
To:
Learn the two important
properties of the transition metal
ion, namely
- Complex formation
- Coordination number and
geometry
Identify the difference between
the complex and chelate andwhy
chelates are more stable than the
complexes.
Learn about the coordination
number and various geometry
associated withthe various
coordination number. i.e.
tetrahedral, octahedral etc.
Learn
General physical properties
of transition elements:
-complex formation
about the type of hybridization involved in ease case
Transition Elements
(3d series)-6
To:
Understand why the transition
metal compounds are coloured.
behind the colour, complimentary
colour i.e. the colour absorbed by
the compound and its
appearance.
-d transition.
compounds in which d-d transition
are not possible
are colourless or white.
transfer phenomena responsible
for the colour in
certain salts like KMnO4.
between the polarization and
colour in certain
transition metal compounds like AgBr or AgI.
General physical properties
of transition elements:
-colour
Transition Elements
(3d series)-7
To understand the latimer
diagrams of Mn, Fe and Cu
Latimer diagrams of Mn, Fe
and Cu
Transition Elements
(3d series)-8
To Know about position of inner
transition elements in periodic
table.
configuration of lanthanide
elements.
properties based on configuration.
states of lanthanides.
most stable +3 oxidation state of
lanthanide.
stable +2 oxidation state of
Lanthanides:
-electronic configuration
-oxidation states
-ionic radii & lanthanide
contraction
-consequences of lanthanide
contraction
lanthanide.
lanthanide and lanthanide
contraction.
of lanthanide contraction.
formed by lanthanides.
learn occurrence of
lanthanides
Week-3
Transition Elements
(3d series)-9
To know about Monazite sand
lanthanides from Monazite
concentration of mineral for
extraction
by sulphuric acid and sodium
hydroxide for
extraction
lanthanides by repeated fractional
crystallization
separation of lanthanide by
solvent extraction
chromatography method of
separation of lanthanide
separation of lanthanide by
complex formation
compounds of lanthanide.
-Extraction & separation of
lanthanides
Transition Elements
(3d series)-10
To:
Know about position of inner
transition elements in periodic
table.
of actinide elements.
Actinides:
-electronic configuration
-variable oxidation state
-actinide contraction
-consequences of actinide
contraction
properties based on configuration.
states of actinides.
stable +3 oxidation state of
actinide.
+2 oxidation state of actinide.
and actinide contraction.
of
actinide contraction.
by actinides.
lanthanides
Transition Elements
(3d series)-11
To know different methods of
separation of actinides.
To discuss precipitation method
for separation of actinide.
To understand solvent
extraction method for separation
of actinide.
To explain ion exchange
method for separation of actinide.
To discuss briefly about
actinium, thorium, protactinium,
uranium and plutonium.
To discuss process of
extraction of thorium.
To know Klaproth process of
extraction of Uranium.
To know preparation of
plutonium.
To explain preparation of
transuranic elements.
To understand common
applications of actinide elements
and briefly discuss about effects
Extraction and separation of
actinides
of actinides on human health.
Coordination
Chemistry -1
To:
Understand IUPAC
nomenclature of complexes
Understand rules for naming
the ligands
Understand rules for naming
the metal center & oxidation state
Understand naming of bridging
groups
Write IUPAC nomenclature of
complexes
-IUPAC nomenclature of
complexes
Week-4
Coordination
Chemistry -2
To:
Write formula of coordination
complexes,
Define Isomerism,
Understand the Types of
isomerism,
Define Structural isomerism,
Define Linkage isomerism,
Define Coordination isomerism,
Define Ionization isomerism,
Define Solvate/hydrate
isomerism,
Define Polymerization
isomerism.
-Isomerism in coordination
compounds
-classification
Coordination
Chemistry -3
To:
Define Stereo Isomerism,
Define Geometrical Isomerism,
Understand Mer-Fac Isomers,
Understand Cis-Trans Isomers.
-sterero & Geometrical
isomerism
Coordination
Chemistry -4
To:
Define Optical activity,
Define Optical isomerism and
Optical isomers,
Understand Plane of symmetry
method and mirror images
method,
-Optical isomerism
Understand Optical isomerism
in complexes with coordination
number 4 and 6
Coordination
Chemistry -5
To:
Understand Valence Bond
Theory
Apply VB Theory to Complex
Ions
Predict geometries of
complexes
Calculate Magnetic moment of
Coordination Compounds
Understand the limitations of
valence bond theory.
-Valance bond theory
& its limitations
Week-5
Crystal Field Theory-1 To:
Understand the limitations of
valence bond theory,
Explain the Crystal Field
Theory (CFT),
Explain the important features
of CFT,
Understand the splitting of d-
orbitals in octahedral complexes,
Understand the splitting of d-
orbitals in tetragonal and
squareplanar complexes.
-CFT
-d orbital splitting in
ocatahedral, tetrahedral and
square planar complexes
Crystal Field Theory -
2
To:
Understand splitting of d-orbitals
in tetrahedral complexes,
Define Spectrochemical series,
Explain the effect of ligand on
splitting energy,
Define Pairing Energy,
Differentiate between High spin
and Low spin complexes,
Distribution of d-electrons in t2g
and eg orbitals in
octahedral complexes.
-spectrochemical series
--High spin & low spin
complexes
Crystal Field Theory -
3
To calculate the Crystal–Field
Stabilisation Energy foroctahedral
complexes,
To understand the splitting of
five d-orbitals in stronger and
weaker tetrahedral field,
To explain high spin and low
spin complexes,
To understand the distribution
of d-electrons in t2g and eg
orbitals in tetrahedral complexes.
-Calculation of CFSE
Crystal Field Theory -
4
To:
Calculate the number of
unpaired electrons - high - spin
and low - spin
complexes
stabilization energy for a
tetrahedral complex
Compare octahedral and
tetrahedral complexes
the magnitude of CFSE
-Factors affecting magnitude
of CFSE
-Limitations of CFT
Week-6
Crystal Field Theory -
5
To understand Jahn-Teller
distortion in metal complexes
- Jahn-Teller distortion
Kinetic Theory of
Gases-1
To:
The properties of gases
The gas laws
The ideal gas equation
The ideal gas constant
- Gas laws
- Ideal gas equation
Kinetic Theory of
Gases-2
To:
Main postulates of kinetic theory
of gases
Derivation of kinetic gas
equation
The ideal gas and real gas
- Postulates of kinetic theory
of gases
- Comparison between ideal
gas and real gas
Comparative study of ideal gas
and real gas
Kinetic Theory of
Gases-3
To understand:
Why real gases deviate from
ideal behaviour
The faulty assumptions in
Kinetic Gas Theory
The Van der Waals equation
The Van Der Waals constant
constants
-Van der waals equation
-Van der waals constant
Week-7
Kinetic Theory of
Gases -4
To understand:
The excluded volume is four
times of the actual volume of the
gas molecule
The validity of Van der Waals
equation
The Boyle’s temperature
Derivation of Boyle’s
temperature
- Boyle’s temperature
Kinetic Theory of
Gases-5
To understand:
The critical constants
The supercritical fluid
Critical constants and the Van
der Waals constants
Applications of critical
constants
The law of corresponding
states
-Critical constants
- Its applications
Kinetic Theory of
Gases-6
To understand:
The Equations of states for real
gases
The Maxwell Boltzmann curve
for distribution of molecular
speeds
The Maxwell Boltzmann
equation for distribution of
molecular speeds
The derivation of Maxwell
-Maxwell Boltzmann equation
Boltzmann equation for
distribution of
molecular speeds
Kinetic Theory of
Gases-7
To understand:
The effect of temperature on
molecular speeds
Types of molecular velocities
Average molecular velocity
The Most probable velocity
The Root mean Square velocity
-Types of molecular velocity
Week-8
Kinetic Theory of
Gases-8
To understand:
What is collision
assumption of collision
theory
-Collision theory
Liquids To:
Understand Surface tension, its
concept and determination,
Know about viscocity of liquid
and determination of coefficient of
viscocity,
Understand effect of
temperature on surface tesion
and viscocity of liquid.
-Surface tension, its concept
and determination
- Viscocity of liquid and
determination of coefficient of
viscocity
- Effect of temperature on
surface tesion and viscocity
of liquid
Solids -1 To:
State different states of matter
and explain their inter-
convertibility,
characteristics,
basis of
the nature of constituent species
and the interaction
between them,
between amorphous and
crystalline solids,
-Introduction to solids
behaviour of crystalline solids,
describe a method to measure
the same,
interfacial angle,
Solids -2 To:
term with the help of suitable examples,
Differentiate between lattice and crystal structure,
motif,
importance,
and and non-primitive unit cells,
two dimensional lattice for NaCl, and identify the unit cell,
and non-Bravias lattices,
to characterise a three dimensional lattice,
faces of a three dimensional unit cell
-Lattice & Unit cell
Week-9 Solids -3 To: Define Bravais lattices and
outline their significance, -
primitive Bravaislattices,
cubic unit cells, -existence of
side centered cubic unit cells,
unit cell for different cubic unit cells,
parameters for a cubic cell,
-Bravias lattices
fraction for simple cubic, body centred cubic and face centred cubic unit cells,
computing density of solid from unit cell dimensions and lattice type
Solids -4 To: Outline the need to study close
packed structures,
structures in two dimension,
and hexagonal close packing in two dimension,
close packing of spheres in two dimensions,
octahedral and tetrahedral voids in close packed structures in three dimensions
and ABCABC.. repeat close packed structures in three dimensions
CCP close packing in three dimensions.
-Packing
-study of close packed
structures
Solids -5 To: State the number of tetrahedral
and octahedral voids in a FCC unit cell and describe their location,
types of tetrahedral voids in FCC unit cell,
Outline the salient features of the CCP close packed structures,
different types of cubic unit cells,
common alloys like brass and steel,
common ionic solids, the unit cell of cesium
chloride.
-FCC & CCP
Solids -6 To: Define symmetry and give
suitable examples,
between symmetry operations and symmetry elements,
operations possible in molecules and state the corresponding symmetry element,
operation and highlight the symmetry element involved,
differentiate between different types of planes of symmetry,
Explain improper rotation operation with the help of examples,
successive symmetry operations on a symmetry element.
- Symmetry operations &
elements
Week-10
Solids -7 To: Define crystal symmetry and
compare it with the molecular symmetry,
difference in the molecular and crystal symmetry,
macroscopic and microscopic symmetry in the context of crystals,
have a five-fold rotation axis,
describe their structure,
representing molecular and crystal symmetry,
that are exclusive to crystals,
in the context of crystal symmetry with the help of an example,
-Crystal symmetry
context of crystal symmetry with the help of an example,
Solids -8 To: Define lattice planes and state
their importance,
planes in two and three dimensions,
and the unit vectors,
designate lattice planes, Describe designation of lattice
planes in terms of Weiss indices and assign Weiss indices to given set of lattice planes,
indices,
Miller indices to lattice planes, ans assign Miller indices to given set of lattice planes,
give an expression for it for cubic crystals,
diffraction of X-rays by crystals,
Bragg’s equation
-Miller indices & Bragg’s law
Solids -9 To: List different experimental
methods for the determination of crystal structure
method for the determination of crystal structure and describe the process involved,
crystal method for the determination of crystal structure and describe the process involved,
-Powder diffraction method
diffraction method for the determination of crystal structure and describe the process involved,
the determination of crystal structure,
diffraction pattern,
determine the nature of unit cell and the edge length of the unit cell
Solids -10 To: Understand Liquid crystal
Know its various applications
-Introduction & Application of
liquid crystals
Week-11 Solids -11 To: Understand the classification of
liquid crystals Understand their
characterization
-Classification of liquid
crystals
Solids -12 To: Understand the various defects
in solids
-Defects in solids
Chemical Kinetics -1 To: Understand the aim and scope
of Chemical Kinetics Explain the meaning of rate of
reaction and its importance Describe the factors affecting
rate of reaction
instantaneous rate and initial rate Relate rate of reaction with
concentration Define rate constant or specific
reaction rate Write the differential form of rate
law Appreciate the importance of
stoichiometry in calculating rate of reaction
-Introduction to Chemical
Kinetics
Chemical Kinetics -2 To: Know the two ways of
classification of the reactions Define order of reaction and
molecularity Derive integrated rate law
expressions of first, second and
-Integrated rate law
zero order reactions Explain characteristics of
reactions following different order Define half-life of a reaction Explain pseudo order reactions
Week-12 Chemical Kinetics -3 To: State and explain radioactive
decay as a first order kinetics,
Determine the half-life period and disintegration constant of any radioactive element,
State various methods of determination of order of the reaction,
Explain and use differential method for determination of order of the reaction,
Describe the method of integration or hit and trial method of determination of order of the reaction,
Elucidate the half-life method of determination of order of the reaction,
Describe the method of isolation for determination of the order of the reaction,
Explain the merits and demerits of each method for determination of order of any reaction.
- Radioactive decay as a first
order kinetics
- Various methods of
determination of order of the
reaction
Chemical Kinetics -4 To: Understand basic requirement
of accurate experimental measurement in reaction kinetics,
Understand the various methods used to study chemical kinetics,
Differentiate between Chemical and Physical methods of analysis of chemical reaction with the help of suitable examples,
State various physical method
-Methods to study kinetics
used for the study of chemical reaction,
Describe the application of conductometry as an analytical tool for the study of chemical reaction,
Explain with the help of suitable example to use potentiometric techniques for studying a chemical reaction,
Discuss the application of polarimeter for the study of chemical reaction involving optically active compounds(reactants and/or products),
Describe the application of spectrophotometer for determination of rate constant and order of a reaction
Chemical Kinetics -5 To:
temperature on chemical kinetics,
Arrhenius equation to explain the effect oftemperature on reaction rate
energy of any chemical reaction,
activation energy of any reaction ,
Arrhenius equation and use of very similar equation i.e., Kooij’s equation to relate rate constant with temperature,
led to the development of theories of reaction rate especially for gaseous phase reaction,
available to explain the reaction rate,
ory of reaction rate- its merits and demerits
collision theory of reaction rate and compare it
-Arrhenius theory
with the Arrhenius equation to obtain the value of pre-exponential factor ‘A’ and Activation energy ‘Eₐ’
Chemical Kinetics -6 To:
Explain the limitations of
collision theory of reaction rate,
bridge the gap between the
chemical
thermodynamics and kinetics,
theory and various assumptions
required to
explain transition state theory,
profile of any reaction including
activated complex
formation
any elementary reaction using
transition state
theory,
the collision and
transition state theory- merits and
demerits.
-Collision theory & transition
state theory
