W-14 Bridge Plug Remediation Environmental Bridging Document · 2018. 11. 14. · W-14 Bridge Plug Remediation Environmental Bridging Document HSE-E-105 Page 2 of 21 DISTRIBUTION

W-14 Bridge Plug Remediation Environmental Bridging Document

HSE-E-105 Page 2 of 21

DISTRIBUTION

Paper copies

Name Position Company Copy #

Karin Scheepens Information Coordinator AWE Perth Pty Ltd 1

Nina Hagias Petroleum Engineer AWE Perth Pty Ltd 2

Adrian Halliday Well Service Engineer Upstream Production Solutions 3

Michelle McAuley HSEC Coordinator AWE Perth Pty Ltd 4

Electronic Copies (Uncontrolled)

Position Company

Regional Manager WA AWE

Subsurface Manager – Onshore WA AWE

Petroleum Engineer AWE

HSEC Coordinator AWE

PIC UPS

HSE Officer UPS

Contractor Copies (send direct to service companies for distribution) Wireline (TBA)



TABLE OF CONTENTS 1.0 ABBREVIATIONS ............................................................................................................... 5

2.0 CONTACT DETAILS ........................................................................................................... 6

3.0 PURPOSE ........................................................................................................................... 6

4.0 ACTIVITY LOCATION ......................................................................................................... 6

5.0 GENERAL DESCRIPTION OF EXISTING ENVIRONMENT ............................................... 7

5.1 Natural environment ................................................................................................... 7

5.2 Lake Logue Nature Reserve ....................................................................................... 7

5.3 Social environment ..................................................................................................... 8

5.4 Summary of environmental sensitivities ...................................................................... 8

6.0 DESCRIPTION OF THE ACTIVITY ................................................................................... 10

6.1 Background .............................................................................................................. 10

6.2 Summary of activity .................................................................................................. 10

6.3 Site preparation and earthwork ................................................................................. 11

6.4 Products, additives, chemicals and other substances disclosure .............................. 11

6.5 Water disposal .......................................................................................................... 11

6.6 Site rehabilitation ...................................................................................................... 12

6.7 Impacts and risks of activity ...................................................................................... 12 7.0 IMPLEMENTATION STRATEGY ...................................................................................... 13

8.0 REPORTING ..................................................................................................................... 14

9.0 CONSULTATION .............................................................................................................. 16

10.0 REFERENCES .................................................................................................................. 16

11.0 CHEMICAL DISCLOSURE ............................................................................................... 17

LIST OF FIGURES

Figure 1 Woodada-14 well locality map ..................................................................................... 6

LIST OF TABLES

Table 1 Description of receiving environment ............................................................................ 8

Table 2 Summary of reporting requirements ............................................................................ 14

Table 3 Consultation Record ................................................................................................... 16

Table 4 Cementing products, additives, chemicals and other substances ............................... 17

Table 4.A System Details ............................................................................................................ 17

Table 4.B Product List ................................................................................................................. 17

Table 4.C Chemical List .............................................................................................................. 18

Table 5 Intervention Fluid Products, additives, chemicals and other substances ..................... 19

Table 5.A System Details ............................................................................................................ 19

Table 5.B Product List ................................................................................................................... 19

Table 5.C Chemical List ................................................................................................................ 20



LIST OF ATTACHMENTS Attachment 1 Well Schematic

Attachment 2 Safety Data Sheet – Cement Attachment 3 Safety Data Sheet - Fluids



1.0 ABBREVIATIONS

Abbreviation Meaning

ALARP As Low As Reasonably Practicable

AWE AWE Perth Pty Ltd

DPaW Department of Parks and Wildlife

EP Environment Plan

EPBC Act Environment Protection and Biodiversity Conservation Act 1999

EZSV Drillable bridge plug

MDRT Metres Depth Below Rotary Table

SDS Safety Data Sheet

TD Total Depth

WIA Well Intervention Activity

WDW Water Disposal Well



2.0 CONTACT DETAILS

Regulatory and Community Affairs Manager AWE Perth Pty Limited Level 3, 1101 Hay Street WEST PERTH WA 6005 Phone: 08 9480 1300

3.0 PURPOSE

The purpose of this document is to provide an Environmental Bridging Document for the Woodada-14 well intervention activity. Note, this document should be read in conjunction with the Onshore North Perth Basin Well Intervention Activities Environment Plan (EP) [HSE-E-75] Rev E approved 16 December 2013.

4.0 ACTIVITY LOCATION

The proposed well intervention activity (WIA) is located at Woodada-14 well, approximately 12 km south west of the township of Eneabba, with lease access off Coolimba Eneabba Road. (Figure 1).

Surface Location: 29º 50’ 08.74”S 115º 08’ 21.66”E

Figure 1 Woodada-14 well locality map

Source: AWE, June 2016



5.0 GENERAL DESCRIPTION OF EXISTING ENVIRONMENT

5.1 Natural environment

The northern Perth Basin has a Mediterranean-type climate characterised by seasonal patterns of hot, dry summers and mild, wet winters. The area is subject to high wind speeds, dust storms, lightning storms, high summer temperatures and low winter night temperatures.

Annual rainfall averages approximately 465 mm near the coast but tapers off to around 335 mm 100 km inland. Generally 55% of annual rainfall occurs between April and September with the wetter months being June and July.

The soils consist of calcareous and siliceous sand underlain by aeolianite, which is often exposed. The northern Perth Basin is situated entirely within the Geraldton Sandplains Biogeographical Region. Within this region, three broad physiographical units are recognised; the Swan Coastal Plain, the Arrowsmith Region and the Dandaragan Plateau. The areas in which WIA will be undertaken will generally be located entirely within the Swan Coastal Plain unit, which forms an elongated strip approximately 40 km wide running along the coast.

Groundwater and surface water drainage is westward but the Irwin River valley to the north of the region is the only major coordinated drainage indentation. A number of swamps surrounded by dense scrub, frequent limestone outcrops and the occasional laterite outcrop are the other major features in the region. The sub-surface geology of the area consists of the Late Jurassic Yarragadee Formation, which is overlain by Tertiary sediments. Groundwater is present in the Tertiary sediments and the Yarragadee Formation, and the groundwater level is near, or at surface in the aforementioned swamps and low lying areas, following the surface topography, but with lower relief.

The northern Perth Basin is located within the Irwin Botanical District (Northern Sandplains Region), within the Southwest Botanical Province as defined by Beard (1976). Under the Interim Biogeographic Regionalisation for Australia (IBRA) (Environment Australia 2000), the area lies on the Geraldton Sandplain, which is described as ‘mainly proteaceous scrub-heaths, rich in endemics, on the sandy earths of an extensive, undulating, lateritic sandplain mantling Permian to Cretaceous strata’.

5.2 Lake Logue Nature Reserve

The Woodada-14 well site is located within of the Lake Logue Nature Reserve in Production Licence L5 area. Lake Logue is the largest feature of the Lake Logue-Indoon System, which includes a number of shallow seasonal wetlands and intermittent creeks and drainage lines. Lake Logue has a surface area of 425 hectares and fills only occasionally, following heavy rain in the catchment. The lake is fed by fresh surface water and has been known to reach a depth of over two metres. When dry, approximately three quarters of its bed is covered by low grasses and shrubs while the remainder is wooded (DEC 2009).

Dieback is known to occur in permit areas L4 and L5. Phytopthora cinnamomi, the most destructive species, is known to occur over a large area in Eneabba Creek and Lake Logue and at several small sites along the Leeman and Erindoon Roads.



Prior to mobilising any equipment into the Woodada Gas Field or within a nature reserve, dieback hygiene measures will be implemented in accordance with the WIA Biosecurity Procedure (HSE-E-PR-051).

Note: as the field is currently under care and maintenance a hygiene station would not be established on site, instead equipment and vehicles must clean-down off site prior to mobilisation.

5.3 Social environment

The surroundings are populated region with limited settlement, transport or communications infrastructure. The townships of Dongara/Port Denison, Mingenew and Eneabba are the largest population centres in the vicinity of the proposal.

The region is relatively undeveloped, comprising of small coastal settlements that are economically dependent on fishing, agriculture, tourism, mining and natural gas/oil production. Dongara/Port Denison is a rock lobster fishing port.

Land use within the surrounding region is pastoral, consisting of wheat, sheep and cattle farming. The bushland areas of the region support seasonal honey production and commercial wildflower harvesting.

5.4 Summary of environmental sensitivities

A description of the existing natural and socio-economic environment within Production Licence L5 area is included above. Table 1 presents a summary of the receiving environment surrounding the Woodada-14 well location.

Table 1 Description of receiving environment

Aspect Description

Geomorphology Macroscale irregular perched claypan within the Tamala Limestone of the Spearwood Dune System, situated in the sumpland of an inter-dune swale of aeolian sands from broadly undulating, Pleistocene upland karst.

Hydrology Inflow via Eneabba, Erindoon and Bindoon Creeks, and from overflow from Weelawadgi Lake and the chain of wetlands to the north. Catchments extensively cleared. Drainage occurs through percolation into superficial sediments of the karst system. Water is lost rapidly through evaporation.

Water Quality Fresh to increasingly brackish as the lake dries out (subhaline).

Benthic Vegetation Alga species Lamprothamnium papulosum.

Littoral Vegetation Casuarina obesa, Melaleuca strobophylla and M. rhaphiophylla.

Cultural No culturally significant sites within the project area.

Invertebrates A total of 137 species of invertebrate have now been recorded from Lake Logue.

Economic Broad hectare cropping and grazing activities, oil and gas, tourism are the typical commercial activities in the area.



Aspect Description

Distance to sensitive receivers

• Private property buildings: ~7 km east from Woodada-14 well site.

• Towns: Eneabba is located approximately 11 km east of the Woodada-14 well site.

• Water course: Lake Logue is the nearest water body located approximately 0.7 km southwest of the site.

• Lake Logue Nature Reserve: Woodada-14 is located within the Lake Logue Nature Reserve.

Source: DEC (2009)



6.0 DESCRIPTION OF THE ACTIVITY

6.1 Background

Gas wells that are no longer in production are suspended prior to being decommissioned. Suspending a gas well involves performing a series of procedures to ensure that the well poses no risk to the public and environment while it is inactive. Suspended wells are routinely pressure monitored on a six-monthly basis until they are fully decommissioned. If monitoring results are not as expected, then further investigation is undertaken to better understand the results and determine if remedial action is required.

Woodada-14 was drilled in September 1994 to 2,198 m MDRT (side-tracked) and then suspended. The well bore was isolated from the reservoir by placing a cement plug from 2,129.5 – 2,134 m MDRT and a 140 mm (5 1/2”) EZSV Cast Iron Bridge Plug was set at 2,124 m MDRT.

Recently, a change in pressure readings observed during the routine Well Pressure Survey indicated that low pressure gas from the depleted reservoir was slowly entering (20-30 psi) the well bore. Testing also confirmed that the integrity of the well head and well casing is intact and that there is no environmental or safety risk.

The primary objective of this operation is to:

• Remediate the bridge plug by placing 30 m of cement on top; and • Conduct subsequent pressure tests to ensure the additional cement plug is

effective.

6.2 Summary of activity

A truck mounted wireline workover unit and related AWE WIA equipment will be utilised to undertake the following activity, which is planned to occur during July 2016: The work will be conducted during daylight hours over a 2-3 day period.

1. Shoot sonologs

2. Mobilise wireline unit, rig up and pressure test.

3. Drift cased hole and tag current bridge plug

4. Install at least 30 m of cement on top of plug. Wait on Cement.

5. Fill well bore with inhibited brine.

6. Pressure test cement plug.

7. Upon successful pressure test, top up well bore with inhibited brine (if required)

8. Rig down and de-mobilise wireline. Secure site.

The WIA program will be managed in accordance with the commitments outlined in the Onshore North Perth Basin Well Intervention Activities Environment Plan (EP) [HSE-E-075]. For the purposed Woodada-14 WIA; there are no additional risks or impacts above or beyond the accepted EP [HSE-E-75] issued December 16 2013.

Refer to Attachment 1 – Well Schematic.



6.3 Site preparation and earthwork

No clearing is anticipated as part of the site preparation activities. Site preparation and earthworks are required to install a portable bunded chemical storage area with the following specific details.

• A PIG® Lease Liner (polypropylene composite) (Liner thickness: 97 mil = 2.54mm) (maximum infiltration rate: 10-9 m/s) would be in place for Woodada-14 well and used as a means of secondary containment for the returned fluids expected as part of the well suspension activity and chemical storage. The PIG® Lease Liner is four times more puncture resistant than commonly used HDPE liners, and its nonslip surface helps prevent slips and falls. The liner is a three layer polypropylene composite consists of three barrier films sandwiched by double layers of needle punched geotextile with heat fused surfaces.

• Returned fluids (not expected) will be stored within 280 bbl tanks (or similar) to provide sufficient capacity for the fluids. A tanker will remove fluid from the onsite storage to the disposal location as per Section 6.4.

• The WIA fluids will be mixed onsite within a water cart or storage vessel with secondary containment (PIG® Lease Liner) to capture any spillage should it occur. The chemicals will be stored within the portable bunded chemical storage as described above. The process of mixing chemicals on site will be supervised by onsite personnel.

• Liquid chemical products (i.e. lubricants) will be stored within bunded pallets or 20 ft internally bunded Dangerous Goods container designed to contain not less than 110% of the volume of the largest storage vessel.

6.4 Products, additives, chemicals and other substances disclosure

An objective of this Bridging Document is to disclose products, additives, chemicals and other substances required under the Petroleum and Geothermal Energy Resources (Environment) Regulations 2012.

AWE Limited confirms that all chemicals and substances have been accurately disclosed in Table 4 & 5 for its Woodada-14 bridge plug remediation program.

The Safety Data Sheets (SDSs) for the proposed chemicals are located within the well site in possession of the AWE Wellsite supervisor. Chemical and fluid transfer activities will be manned at all times.

6.5 Water disposal

Water disposal is not expected to be required as part of the proposed work. If for an unexpected reason water disposal is required, it will be disposed of either to an approved water disposal well (e.g. Eremia-04/Dongara WDW) or an approved evaporation pond (e.g. Hovea Evaporation Pond). If it is disposed into a well then hoses will be rigged up from the tanker to the well via a pump. It will then be pumped into the well. If water is to be disposed of at an evaporation pond then a hose will rigged up and water unloaded directly into the pond.



Where fluid transfers occur (either between onsite storage tanks or into the evaporation pond/disposal well) a spill tray or secondary containment will be in place to capture any potential spillage during transfer.

6.6 Site rehabilitation

Rehabilitation of the Woodada-14 well site will be covered by a separate rehabilitation plan, developed in consultation with Department of Parks and Wildlife (DPaW), and will be completed after the well has been decommissioned.

6.7 Impacts and risks of activity

The risks and impacts associated with by the activity are assessed within Section 6.0 of the accepted EP [HSE-E-75] Rev E.

The major risks associated with this activity are:

• Introduction of weeds (risk analysis ranked this risk as low)

• Disruption of agricultural activities (risk analysis ranked this risk as medium)

• Fuel, oil or chemical spills (risk analysis ranked this risk as low)

• Disposal of waste (risk analysis ranked this risk as low)

• Groundwater contamination (risk analysis ranked this risk as low).



7.0 IMPLEMENTATION STRATEGY

The implementation strategy outlined in the accepted EP [HSE-E-75] Rev E Section 8.0 is applicable to the proposed activity. The aspects include:

• Systems, practices and procedures

• Roles and responsibilities of personnel

• Training and competencies

• Monitoring, auditing, management of non-conformance and review

• Emergency response (including oil spill contingency plan)

• Record keeping

• Reporting

The WIA program will be managed in accordance with the commitments outlined in the AWE Onshore North Perth Basin Well Intervention Activities Environment Plan (EP) [HSE-E-75] Rev E. For the purposed WIA; there are no additional risks or impacts above or beyond the accepted EP [HSE-E-75] Rev E approved December 16 2013.

The objective of this Environmental Bridging Document is to disclose products, additives, chemicals and other substances (Table 4 & 5 A-C) required under the Petroleum and Geothermal Energy Resources (Environment) Regulations 2012.

The WIA will be managed in accordance with the Perth Basin Oil Spill Contingency Plan for Drilling and WIA [HSE-OP-030] Rev 10 approved by DMP on 05 May 2014. The plan provides adequate spill response measures for the proposed activity.



8.0 REPORTING

The incident and routine reporting requirements as required under the applicable legislation is summarised within Table 2, AWE will adhere to these reporting requirements as they apply to the WIA. The following table is based on the Auditing and Reporting Requirements for Petroleum Activities in Western Australia (October 2012) document compiled by the Department of Mines and Petroleum (DMP).

Table 2 Summary of reporting requirements

Legislation Regulation and Schedules

Incident Reporting Routine Reporting

Petroleum and Geothermal Energy Resources Act 1967

Petroleum and Geothermal Energy Resources (Environment) Regulations 2012

Regulation 28 and 29 Reportable incident reporting: Reportable incidents are required to be reported to DMP within two hours and a written report within three days. Regulation 30 Recordable incident reporting: A record of all recordable incidents that occurred during the calendar month to be submitted to DMP not later than 15 days after the end of that calendar month.

Regulation 16 Requires the operator to report to DMP at least annually to provide evidence of compliance. A close out report is acceptable on completion of an activity if the activity is of short duration. Regulation 34 The operator of an activity must monitor all emissions and discharges to any land, air, marine, seabed, groundwater, sub-surface or inland waters environment and submit a written report of emissions and discharges every three months commencing when the EP for the activity is approved.



Legislation Regulation and Schedules

Incident Reporting Routine Reporting

Schedule of Onshore Petroleum and Production Requirements –1991 (amended 2010)

Clause 290 (1)(a) and (1)(b) Report shall be made forthwith (2 hours) upon the occurrence of:

• Spill of hydrocarbon in inland waters > 80L;

• Spill in hydrocarbon in other areas > 500L;

• Significant quantity of petroleum in gaseous form > 500 m3; and

• Uncontrolled escape or ignition of petroleum or other flammable or combustible material causing a potentially hazardous situation.

Direction issued 22 April 03

Spillage of hydrocarbons or other material* that affects a ground surface area > 100m2. * Other materials include drilling fluids, chemicals, produced formation water or a substance that has the potential to adversely affect surface vegetation, soil or subsurface ground water.

Environment Protection and Biodiversity Conservation Act 1999

Death or injury to individual(s) from a Listed Species during an activity; Unplanned impact caused to a matter of national significance (NES) during an activity (as per the EPBC Act).



9.0 CONSULTATION

Consultation for the WIA is listed in Table 3. AWE commits to ongoing consultation during the WIA.

Table 3 Consultation Record

Stakeholders Issues and resolution

DMP (Petroleum Branch)

Technical documentation planned to be submitted to DMP for assessment.

Advice regarding cement plug placement and requirement for 30m cement plug.

DMP (Environmental Branch)

Submission of W-14 Bridge Plug Remediation Environmental Bridging Document.

Various discussions regarding the W-14 program

DPaW Plan to advise DPaW prior to commencement of operations.

10.0 REFERENCES

DEC (2009). Resource Condition Report for a Significant Western Australian Wetland: Lake Logue. Department of Environment and Conservation, Perth.



11.0 CHEMICAL DISCLOSURE

Table 4 Cementing products, additives, chemicals and other substances

Table 4.A System Details

Operator AWE Perth Pty Ltd

Project/Well Woodada-14

System Cementing

Total Volume of System 10 bbls

* includes >100 % Contingency volume

Table 4.B Product List

Product Name Supplier Purpose Toxicity, Ecotoxicity & Biodegradability data % Product in system

fluid

MSDS Attached

Water Town or Bore Water.

Base Fluid N/A- Natural Product. 55.19% N/A

Export NeoSlurry & NeoSuperSlurry Systems,

Neo Products

Cement Slurry Acute Toxicity: Portland cement as an ingredient (<65%) Fish toxicity LC50 (96h): 41.2 mg/L (Oreochromis niloticus) Source: Adamu et al. 2008 Silica sand as an ingredient (<35%) Fish toxicity 96h LL0: 10,000 mg/L (Branchdanio rerio) Crustacean toxicity 24h EL50: >10,000 mg/L (Daphnia magna) Magnesium oxide as an ingredient (<6.0%) LD50 for oral administration of MgO in mice was reported to be 810 mg/kg (Sigma-Aldrich, 2001b). The LD50 for oral administration in rats was reported to be 3870 mg/kg in males and 3990 mg/kg in females (Clydesdale, 1997). Suspension Agent as an ingredient (<3.0%) This product is composed of a synthetic polymer which has a biodegradation of less than 20%. The polymer is essentially a non-toxic material with a worst case toxicity of no greater than 1,000mg/L to Scophthalmus Maximus. The polymer has a large molecular weight and is not expected to bioaccumulate. Friction Reducer as an ingredient (<0.25%) This product contains a polymer which is of less than 20% biodegradation. This additive is essentially non-toxic with a worst case aquatic toxicity of greater than 1000mg/L to all species. The molecular weight of the polymer is in excess of 600 and thus is not expected to bioaccumulate. Cement Slurry Retarder as an ingredient (<4.0%) LD50 oral rat >4,000 mg/Kg LC50 Rainbow Trouts 7300 ppm/48h Chronic Toxicity: Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms include cough, shortness of breath, wheezing, non-specific chest illness, and reduced pulmonary function. Individuals with silicosis are predisposed to develop tuberculosis. Biodegradation/bioaccumulation: Biodegradation not applicable as cement is intended to remain long term in well and will be inert.

44.81% Yes

TOTAL 100%



Table 4.C Chemical List

Chemicals Name CAS number Mass fraction (%)

Water 7732-18-5 55.19%

Portland cement 65997-15-1 <29.13%

Silica sand 14808-60-6 <15.70%

Magnesium oxide 1309-48-4 <2.69%

Calcium salt (1-Propanesulfonic acid) 103115-52-2 <1.34%

Sodium polynaphthalenesulfonate 9084-06-4 <0.11%

Sodium liginsulfonate 8061-51-6 <0.18%

TOTAL: 100.00%



Table 5 Intervention Fluid Products, additives, chemicals and other substances

Table 5.A System Details

Operator AWE Perth Pty Ltd

Project/Well Woodada-14

System Fluids (brine)

Total Volume of System *400bbl

* Includes >100% Contingency volume.

Table 5.B Product List

Product Name Supplier Purpose Toxicity, Eco toxicity & Biodegradability data % Product in system fluid

SDS Attached

Water Town or bore water Base Fluid N/A- Natural product. 92.769 Yes

Potassium Chloride (KCl)

New Park Drilling Fluids

Weighting Agent Acute Toxicity: LD50 (Ingestion): 1500 mg/kg (mouse) LD50 (Intraperitoneal): 620 mg/kg (mouse) Chronic Toxicity: Not listed as a carcinogen. No data available to indicate product or components present at greater than 1% are chronic health hazards. Biodegradation/bioaccumulation: Low bioaccumulation in water/soil. High mobility.

3.880 Yes

Idcide 20 New Park Drilling Fluids Biocide Acute Toxicity: 75% Tetrakis (hydroxymethyl) Phosphonium Sulphate (55566-30-8): LC50 (Rainbow Trout) = 119 mg/L/96 hr LC50(Bluegill Sunfish) = 93 mg/L/ 96 hr EC50 (Daphnia Magna) = 19 mg/L/48 hr LC50 (Brown Shrimp) = 340 mg/L/96 hr LC50 (Mysid Shrimp ) = 9.5 mg/L/96 hr LC50 (Sheepshead Minnow) = 94 mg/L/96 hr LC50 (Jevenile Plaice) = 86 mg/L/96 hr Waste Water management EC50 (Activated Sludge) = 24mg/L/3 hr. Water: 25% Natural product. Biodegradation/bioaccumulation: No specific studies undertaken to date.

0.090 Yes

Sodium Sulphite New Park Drilling Fluids Oxygen Scavenger Acute Toxicity: Sodium Sulphite an ingredient 0-25% Oral (Mouse) LD50: 820mg/kg Water: >80% Natural product. Biodegradation/bioaccumulation: No specific studies undertaken to date.

0.051 Yes



Product Name Supplier Purpose Toxicity, Eco toxicity & Biodegradability data % Product in system fluid

SDS Attached

Ancor-1 (corrosion inhibitor)

New Park Drilling Fluids Corrosion Inhibitor Acute Toxicity- Triethanolamine (68-72%) LD50 (Ingestion): 2200 mg/kg (rabbit) LD50 (Intraperitoneal): 1450 mg/kg (mouse) LD50 (Skin): > 20 mL/kg (rabbit) TDLo (Ingestion): 16 g/kg/64 weeks (mouse - cancer) LC50 (shrimp) : > 100 ppm. Acute Toxicity - Constituent 2 (remainder) Natural product (water). Biodegradation/bioaccumulation: In soil and water, triethanolamine will biodegrade fairly rapidly following acclamation (half-life in the order of days to weeks). In soil, residual triethanolamine may leach to groundwater.

1.210 Yes

Total: 100.000

Table 5.C Chemical List

Chemicals Name CAS number Mass fraction (%)

Water 7732-18-5 95.419

Potassium Chloride (KCl) 7447-40-7 3.880

THPS (Tetrakis hydroxymethyl phosphonium sulfate) 55566-30-8 0.022

Sodium Sulphite 7757-83-7 <0.04

Sodium Carbonate 497-19-8 <0.001

Sodium Sulphate 7757-82-6 <0.001

Triethanolamine 102-71-6 0.679

TOTAL: 100.000



ATTACHMENTS


HSE-E-105

Attachment 1 Well Schematic


HSE-E-105

Attachment 2 Safety Data Sheet – Cement

Safety Data Sheet Portland Cement - Dry Powder Blend

QUICK IDENTIFIER (See Section 1 Product Name)

SECTION 1- IDENTIFICATION OF PRODUCT AND COMPANY

Product: Export NeoSlurry & NeoSuperSlurry Systems, P/Ns: E0105-350-017, E0105-450-017 & E0105-300-017

Application: 5 gallon batch of cement slurry for dump bailers

Manufacturer’s NeoProducts, LLC

name:

Address: 1201 Dealers Ave. Emergency Telephone #: 504-731-1011

City, State, Zip: Harahan, LA 70123 e-mail: [email protected]

Signature of After hours calls will be answered by answering service.

person

responsible for

preparation Date Prepared: August 2015

(Optional):

SECTION 2- HAZARD IDENTIFICATION

Fire: This preparation is not flammable.

Health: Potentially hazardous during normal handling and use as instructed.

Environment: No known hazards.

Other Hazards: CAUTION! – ACUTE HEALTH HAZZARD This dry powder blend contains crystalline silica and quartz. May cause eye and respiratory irritation.

DANGER! – CHRONIC HEALTH HAZZARD This dry powder blend contains crystalline silica and quartz. Breathing crystalline silica can cause lung disease including silicosis and lung cancer. Crystalline silica has also been associated with scleroderma and kidney disease.

This product contains quartz, cristobalite, and/or tridymite, which may become airborne without a visible cloud. Use only with adequate ventilation to keep exposures below recommended exposure limits. Wear a NIOSH certified, European Standard EN 149 or equivalent respirator when using this product. Review the Material Safety Data Sheet (MSDS) for this product, which has been provided to your employer.

Pictograms:

mailto:[email protected]

SIGNAL WORD:..........................DANGER! GHS HAZARD AND PRECAUTIONARY STATEMENTS: H303 H313 H333: May be harmful if swallowed, in contact with skin or if inhaled

P101+102+103: If medical advice is needed, have product container or label at hand. Keep out of the reach of

children. Read label before use.

P202+270+280+281: Do not handle until all safety precautions have been read and understood. Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required.

SECTION 3- COMPOSITION/INFORMATION ON INGREDIENTS

Component(s) % OPT. Average Average CAS No. [chemical and common name(s)] (inhalable dust) (respirable

dust)

Portland Cement #2104 60.0 – 65.0 wgt % 10.0 mg/m3 4 mg/m3 65997-15-1

Silica Sand #2162 30.0 – 35.0 wgt % 0.3mg/m3 N/A 14808-60-6

Magnesium Oxide #2151 0 – 6.0 wgt % 10.0mg/m3 4mg/m3 1309-48-4

Suspension Agent #2099 0.50 – 3.0 wgt % N/A N/A 103115-52-2

Friction Reducer #2105 0.25 wgt % N/A N/A 9084-06-4

Cement Slurry Retarder #2117 1.0 – 4.0 wgt % N/A N/A 8061-51-6

Symbol(s): Xi, Xn

Risk Phrases: R36, R37, R38, R40

Safety Phrases: S22, S25, S36/37/39, S38

SECTION 4- FIRST AID MEASURES

Inhalation: Remove from area to fresh air.

Ingestion: First aid procedures are not required.

Skin: Wash with soap and water.

Eyes: Flush with plenty of water for at least 15 minutes.

SECTION 5- FIRE FIGHTING MEASURES

Extinguishing media: Product does not burn.

Special fire fighting precautions: None. Product does not burn.

Unusual fire and explosion hazards: No fire hazards.

SECTION 6- ACCIDENTAL RELEASE MEASURES

Personal precautions: Wear dust/mist respirator, work gloves and dust proof goggles.

Environmental: No environmental hazards reported.

Spillage: Use protective equipment, avoid creating or inhaling dust, sweep up and attempt to reuse product if not contaminated. Prevent entry into drains, sewers and watercourses.

SECTION 7- HANDLING AND STORAGE

Avoid contact with skin and eyes. Wear Approved work gloves, dust proof goggles and dust/mist respirator. Avoid creating dust. Store in dry location in original container. Use only as instructed.

SECTION 8- EXPOSURE CONTROLS/ PERSONAL PROTECTION

Engineering controls: Use in well ventilated area.

Respiratory protection: Use approved dust/mist respirator.

Hand protection: Use normal work gloves.

Skin protection: Normal work coveralls.

Eye protection: Use dust proof goggles.

SECTION 9- PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Color: Odor: PH: Reactivity in Water:

Solid Gray Odorless Not Determined N/A

Vapor Density Solubility in Water Vapor Pressure Specific Gravity @ Flammable Limits in

(Air=1): (g/100ml): (mm HG): 20C (H2O=1): Air% by Volume:

Not Determined 0.5 Not Determined 3.15 Not Determined

Flash Point: LEL Lower: LEL Upper: Melting Point: Boiling Point:

Not Determined N/A N/A N/A Not Determined

SECTION 10- STABILITY AND REACTIVITY

Stability Data: Hazardous Conditions to avoid: Incompatibility Hazardous

Polymerization: (Materials to avoid): Decomposition or

Byproducts:

Stable Will not occur Avoid contact with water None known None known

SECTION 11- TOXICOLOGICAL INFORMATION

Principle route of exposure: Eye or Skin contact, Inhalation.

Inhalation: This dry powder blend contains crystalline silica and quartz. Inhaled crystalline silica in

the form of quartz or cristobalite from occupational sources is carcinogenic to humans

(IARC, Group 1). There is sufficient evidence in experimental animals for the

carcinogenicity of tridymite (IARC, Group 2A).

This dry powder blend contains crystalline silica and quartz. Breathing silica dust may

cause irritation of the nose, throat and respiratory passages. Breathing silica may cause

noticeable injury or illness even through permanent lung damage may be occurring.

Inhalation of dust may also have serious chronic health effects (See “Chronic Effects /

Carcinogenicity” subsection below).

Skin Contact: Wet cement can dry skin and cause Alkali burns.

Eye Contact: Dust can irritate eyes.

Ingestion: No harmful affects known.

Medical conditions aggravated by exposure: Dermatitis

Chronic effects/ Carcinogenicity:

Silicosis: Excessive inhalation of respirable crystalline silica dust may

cause a progressive, disabling and sometime-fatal lung disease called

silicosis. Symptoms include cough, shortened of breath, wheezing, non-

specific chest illness, and reduced pulmonary function. This disease is

exacerbated by smoking. Individuals will silicosis are predisposed to

develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC)

has determined that crystalline silica inhaled in the form of quartz or

crystallite from occupational sources can cause lung cancer in humans

(Group 1 – carcinogenic to humans) and has determined that there is

sufficient evidence in experimental animals for the carcinogenicity of

tridymite (Group 2A – possible carcinogen to humans). Refer to IARC

Monograph 68, Silica, Some Silicates and Organic Fibers (June 1997) in

conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as “Known to be a human

carcinogen”. Refer to the 9th Report of Carcinogens (2000). The

American Conference of Governmental Industrial Hygienists (ACGIH)

classifies crystalline silica, quartz, as a suspected human carcinogen

(A2).

There is some evidence that breathing respirable crystalline silica or the

disease silicosis is associated with an increased incidence of significant

endpoints such as acleroderma (an immune system disorder manifested

by scarring of the lungs, skin, and other internal organs) and kidney

disease.

Other Information

This dry powder blend contains quartz, crystalline, silica and quartz. For

further information consult “Adverse Effects of Crystalline Silica

Exposure” published by the American Journal of Respiratory and Critical

Care Medicine, Volume 155, pages 71-768 (1997).

Toxicity Tests/ Carcinogenicity: This dry powder blend contains quartz, crystalline, silica and quartz.

Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibers

(June 1997).

SECTION 12- ECOLOGICAL INFORMATION

Mobility (water/air/soil): Not Determined

Persistence/ Degradability: Not Applicable

Bio-Accumulation: Not Determined

Aquatic Toxicity: Not Determined

SECTION 13- DISPOSAL CONSIDERATIONS

Disposal Method: Consult Federal, State or Local regulations.

Contaminated Packaging: Follow all applicable national or local regulations.

SECTION 14- TRANSPORT INFORMATION

NO SPECIAL PRECAUTIONS NECESSARY

SECTION 15- REGULATORY INFORMATION

Hazardous Ingredients: None

Symbol(s): Xi , Xn

Risk Phrases:

R36 Irritating to eyes.

R37 Irritating to Respiratory System.

R38 Irritating to Skin.

R40 Limited evidence of a carcinogenic effect. (Lab test results on silica sand have shown limited evidence of a carcinogenic effect.)

Safety Phrases:

S22 Do not breathe dust.

S25 Avoid contact with eyes.

S36/37/39 Wear suitable protective clothing, gloves, and eye/face protection.

S38 In case of insufficient ventilation, wear suitable respiratory equipment.

SECTION 16- ADDITIONAL INFORMATION

Please read the Safety Data Sheet before using this or any NeoProducts items. This product is intended for the stated application only. Do not use this product for any other application without first obtaining guidance from an approved

NeoProducts employee beforehand.

If this product is for resale, make sure the purchaser receives a copy of this safety data sheet upon acceptance of this preparation. Make sure the employees of your company are aware of the hazards, both chronic and acute, before allowing them to use this product.

The information contained in this Safety Data Sheet is believed to be correct and reflects our best professional judgment. Because it is impossible to anticipate every condition under which this product will be used, this Safety Data Sheet shall only be used as a guide. It is imperative that each user of this product determines its suitability for his particular application and comply with all environmental and workplace regulations.

HMIS:

HEALTH 1

FLAMMABILITY 0

REACTIVITY 0

PERSONAL PROTECTION B

*HMIS®HAZARD INDEX: 0=Minimal Hazard, 1=Slight Hazard, 2=Moderate Hazard, 3=Serious Hazard,

4=Severe Hazard. HMIS® rating involves data interpretations that may vary from company to company. They

are intended only for rapid, general identification of the magnitude of the specific hazard. To deal adequately

with the safe handling of this material, all the information contained in this SDS and product label must be

considered.

REVISION STATEMENT: Changes have been made throughout this Safety Data Sheet (SDS). Please read the entire

document. Prepared according to the OSHA Hazard Communication Standard (29 CFR 1910.1200) and The Globally

Harmonized System of Classification and Labeling of Chemicals (GHS) by the Company Health and Risk Assessment

Unit.

DISCLAIMER: Although the information and recommendations set forth herein (hereinafter "Information") are presented in good faith and

believed to be correct as of the date hereof, the Company makes no representations as to the completeness or accuracy

thereof. Information is supplied upon the condition that the persons receiving this Safety Data Sheet (SDS) will make their

own determination as to its suitability for their intended purposes prior to use. Since the product is within the exclusive

control of the user, it is the user's obligation to determine the conditions of safe use of this product. Such conditions should

comply with all Federal and State Regulations concerning the Product. It must be recognized that the physical and

chemical properties of any product may not be fully understood and that new, possibly hazardous products may arise from

reactions between chemicals. The information given in this data sheet is based on our present knowledge and shall not

constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. NO

REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY,

FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH

RESPECT TO INFORMATION OR THE PRODUCT TO WHICH INFORMATION REFERS.

***This is the last page of this SDS***


HSE-E-105

Attachment 3 Safety Data Sheet - Fluids

IDCIDE-20Product Name

1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER

Supplier Name RHEOCHEM LTD

Address 11 Alacrity Place, Henderson, WA, AUSTRALIA, 6166

Telephone +61 8 9410 8200

Fax +61 8 9410 8299

Emergency 1800 127 406 (Australia); 011 64 3 3530199 (International)

Web Site http://www.rheochem.com.au/

Synonym(s) IDCIDE 20

Use(s) BIOCIDE · DRILLING FLUID ADDITIVE · WATER TREATMENT

SDS Date 11 October 2012

2. HAZARDS IDENTIFICATION

CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA

R36/38 Irritating to eyes and skin.R43 May cause sensitisation by skin contact.

S23 Do not breathe gas/fumes/vapour/spray (where applicable).S24/25 Avoid contact with skin and eyes.S36 Wear suitable protective clothing.

Hazchem Code

Packing Group

UN Number DG Class

Subsidiary Risk(s)

None Allocated None Allocated


None Allocated

NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE

SAFETY PHRASES

RISK PHRASES

3. COMPOSITION/ INFORMATION ON INGREDIENTSIngredient Identification Classification Content

TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE 18 - 25%Not AvailableCAS: 55566-30-8EC: 259-709-0

WATER RemainderNot AvailableCAS: 7732-18-5EC: 231-791-2

4. FIRST AID MEASURES

Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing untiladvised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes.

Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.

Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with runningwater. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.

Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.

Page 1 of 5

SDS Date: 11 Oct 2012

http://www.rheochem.com.au/


Advice to Doctor Treat symptomatically.

First Aid Facilities Eye wash facilities should be available.

5. FIRE FIGHTING MEASURES

Flammability Non flammable. May evolve toxic gases if strongly heated. May evolve carbon oxides, sulphuroxides and phosphates when heated to decomposition.

Fire and Explosion Treat as per requirements for surrounding fires. Evacuate area and contact emergency services.Remain upwind and notify those downwind of hazard. Wear full protective equipment including SelfContained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containersand nearby storage areas.

Extinguishing Use an extinguishing agent suitable for the surrounding fire.

Hazchem Code None Allocated

6. ACCIDENTAL RELEASE MEASURES

Spillage Contact emergency services where appropriate. Use personal protective equipment. Clear area of allunprotected personnel. Ventilate area where possible. Contain spillage, then cover / absorb spill withnon-combustible absorbent material (vermiculite, sand, or similar), collect and place in suitablecontainers for disposal.

7. STORAGE AND HANDLING

Storage Store in a cool, dry, well ventilated area, removed from oxidising agents, acids and foodstuffs.Ensure containers are adequately labelled, protected from physical damage and sealed when not inuse.

Handling Before use carefully read the product label. Use of safe work practices are recommended to avoideye or skin contact and inhalation. Observe good personal hygiene, including washing hands beforeeating. Prohibit eating, drinking and smoking in contaminated areas.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

No exposure standard(s) allocated.Exposure Standards

No biological limit allocated.Biological Limits

Engineering Controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.

PPE

Eye / Face Wear splash-proof goggles.

Hands Wear PVC or rubber gloves.

Body When using large quantities or where heavy contamination is likely, wear coveralls.

Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator.

9. PHYSICAL AND CHEMICAL PROPERTIES

COLOURLESS TO PALE YELLOW LIQUIDAppearanceSLIGHT ODOUROdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point> 100°CBoiling point< 0°CMelting pointAS FOR WATEREvaporation rate3.0 to 3.5pH

Page 2 of 5



NOT AVAILABLEVapour density1.08Specific gravitySOLUBLESolubility (water)18 mm Hg @ 20°CVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEPartition coefficient> 60 % (Water)% Volatiles

10. STABILITY AND REACTIVITY

Chemical Stability Stable under recommended conditions of storage.

Conditions to Avoid Avoid heat, sparks, open flames and other ignition sources.

Material to Avoid Incompatible with oxidising agents (eg. hypochlorites) and acids (eg. nitric acid).

May evolve carbon oxides, sulphur oxides and phosphates when heated to decomposition.Hazardous DecompositionProducts

Polymerization is not expected to occur.Hazardous Reactions

11. TOXICOLOGICAL INFORMATION

Eye Severe irritant. Contact may result in irritation, lacrimation, pain, redness and blurring or dimness ofvision. Prolonged contact may result in corneal burns and possible permanent damage.

Inhalation Low irritant. Over exposure to vapours may result in irritation of the nose and throat, with coughing.High level exposure may result in dizziness, nausea and headache. Due to the low vapour pressure,an inhalation hazard is not anticipated with normal use.

Skin Irritant. Contact may result in irritation, redness, rash and dermatitis. Prolonged or repeated contactmay result in burns. May be absorbed through skin with harmful effects. May cause sensitisation byskin contact.

Ingestion Low to moderate toxicity. Ingestion may result in gastrointestinal irritation, nausea, vomiting,abdominal pain and diarrhoea.

Low to moderate toxicity - irritant. This product has the potential to cause adverse health effects withover exposure. Upon dilution, the potential for adverse health effects may be reduced.

Health HazardSummary

Toxicity Data TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE (55566-30-8)LD50 (ingestion) 248 mg/kg (rat)TDLo (ingestion) 650 mg/kg/13 weeks - intermittent (rat)

12. ECOLOGICAL INFORMATION

Environment Limited ecotoxicity data was available for this product at the time this report was prepared. Ensureappropriate measures are taken to prevent this product from entering the environment.

Ecotoxicity 75% TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE (55566-30-8):LC50 (Rainbow Trout) = 119 mg/L/96 hrLC50(Bluegill Sunfish) = 93 mg/L/ 96 hrEC50 (Daphnia Magna) = 19 mg/L/48 hrLC50 (Brown Shrimp) = 340 mg/L/96 hrLC50 (Mysid Shrimp ) = 9.5 mg/L/96 hrLC50 (Sheepshead Minnow) = 94 mg/L/96 hrLC50 (Jevenile Plaice) = 86 mg/L/96 hr

Waste Water managementEC50 (Activated Sludge) = 24 mg/L/3 hr

Persistence/Degradability This product is readily biodegradable.

13. DISPOSAL CONSIDERATIONS

Waste Disposal For small amounts, absorb with sand, vermiculite or similar and dispose of to an approved landfillsite. For larger amounts, contact the manufacturer for additional information. Prevent contaminationof drains or waterways as aquatic life may be threatened and environmental damage may result.

Page 3 of 5



Legislation Dispose of in accordance with relevant local legislation.

DG Class/ Division

Subsidiary Risk(s)

Packing Group


None Allocated

None Allocated


None Allocated


None Allocated

None Allocated

None Allocated

None Allocated

None Allocated

None AllocatedNone Allocated

None AllocatedProper Shipping Name

UN Number

LAND TRANSPORT(ADG)

SEA TRANSPORT(IMDG / IMO)

AIR TRANSPORT(IATA / ICAO)


14. TRANSPORT INFORMATION

15. REGULATORY INFORMATION

Inventory Listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.

Poison Schedule A poison schedule number has not been allocated to this product using the criteria in the Standardfor the Uniform Scheduling of Medicines and Poisons (SUSMP)

16. OTHER INFORMATION

EXPOSURE CONTROL: If utilised in a closed system the potential for over exposure is reduced. Ifnot used in a closed system, local exhaust ventilation is recommended to control exposure. Provideeye wash and safety shower in close proximity to points of potential exposure. Where the potentialfor an inhalation risk exists, an approved respirator may be required. Do not eat, store, consumefood, tobacco or drink in areas where product is used.

RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.

PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this ChemAlert report is provided asa guide only. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.

HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.

Additional Information

Page 4 of 5



ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberGHS Globally Harmonized SystemIARC International Agency for Research on CancerLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetrePEL Permissible Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly

alkaline).ppm Parts Per MillionREACH Regulation on Registration, Evaluation, Authorisation and Restriction of ChemicalsSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsTLV Threshold Limit ValueTWA/OEL Time Weighted Average or Occupational Exposure Limit

Abbreviations

DescriptionRevision

Standard SDS Review 1.3



Initial SDS creation 1.0

Revision History

Report Status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier ofthe product and serves as their Safety Data Sheet ('SDS').

It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed torepresent the current state of knowledge as to the appropriate safety and handling precautions forthe product at the time of issue. Further clarification regarding any aspect of the product shouldbe obtained directly from the manufacturer, importer or supplier.

While RMT has taken all due care to include accurate and up-to-date information in this SDS, itdoes not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMTaccepts no liability for any loss, injury or damage (including consequential loss) which may besuffered or incurred by any person as a consequence of their reliance on the informationcontained in this SDS.

Prepared By Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au

SDS Date:

End of SDS

Revision:11 October 20121.3

Page 5 of 5



11 Alacrity Place, Henderson, WA, AUSTRALIA, 6166+61 8 9410 8200

1800 127 406 (Australia); 011 64 3 3530199 (International)+61 8 9410 8299


RHEOCHEM LTD

ANCOR 1

BRINE • DRILLING FLUID ADDITIVE • OIL AND GAS INDUSTRY

CORROSION INHIBITOR

28 Jan 2010

Fax

Supplier Name

Address

Telephone

Emergency

Web Site

Synonym(s)

Use(s)

SDS Date

Product Name



RISK PHRASESR36 Irritating to eyes.

SAFETY PHRASESS36 Wear suitable protective clothing.


None Allocated None Allocated None Allocated


UN No.

Packing Group

DG Class

Hazchem Code

Subsidiary Risk(s)

3. COMPOSITION/ INFORMATION ON INGREDIENTS

Ingredient Formula CAS No. Content

TRIETHANOLAMINE C6-H15-N-O3 102-71-6 68-72%

WATER H2O 7732-18-5 remainder

Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by aPoisons Information Centre, a doctor, or for at least 15 minutes.

Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continueflushing with water until advised to stop by a Poisons Information Centre or a doctor.

Inhalation If inhaled, remove from contaminated area. To protect rescuer, use a Type A (Organic vapour) respirator or an Air-line respirator (in poorly ventilated areas). Apply artificial respiration if not breathing.

Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed,do not induce vomiting.


First Aid Facilities Eye wash facilities and safety shower should be available.


Page 1 of 4

Reviewed: 28 Jan 2011Printed: 28 Jan 2011

RMT

ANCOR 1Product Name

Fire andExplosion

Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwindand notify those downwind of hazard. Wear full protective equipment including Self Contained BreathingApparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.

Extinguishing Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains or waterways.

Flammability Combustible. May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated todecomposition.



Spillage Contact emergency services where appropriate. Use personal protective equipment. Clear area of all unprotectedpersonnel. Ventilate area where possible. Contain spillage, then cover / absorb spill with non-combustibleabsorbant material (vermiculite, sand, or similar), collect and place in suitable containers for disposal. Prevent spillentering drains or waterways.

Handling

Store in a cool, dry, well ventilated area, removed from oxidising agents, acids, nitrites, heat or ignition sourcesand foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when notin use. Check regularly for leaks or spills. Store as a Class C1 Combustible Liquid (AS1940).

Storage

Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skincontact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating,drinking and smoking in contaminated areas.



8. EXPOSURE CONTROLS/ PERSONAL PROTECTION

TWA STELExposure Stds

Ingredient ReferenceTriethanolamine SWA (AUS) -- 5 -- --mg/m3


EngineeringControls

Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation isrecommended. Maintain vapour levels below the recommended exposure standard.

Wear splash-proof goggles, rubber or PVC gloves and coveralls. Where an inhalation risk exists, wear: a Type A(Organic vapour) respirator. If spraying, wear: a Type A-Class P1 (Organic gases/vapours and Particulate)respirator.

PPE

9. PHYSICAL AND CHEMICAL PROPERTIESAppearance COLOURLESS LIQUID Solubility (water) SOLUBLE

Odour SLIGHT ODOUR Specific Gravity 1.1

pH NOT AVAILABLE % Volatiles NOT AVAILABLE

Vapour Pressure NOT AVAILABLE Flammability CLASS C1 COMBUSTIBLE

Vapour Density NOT AVAILABLE Flash Point > 100°C

Boiling Point NOT AVAILABLE Upper Explosion Limit NOT AVAILABLE

Melting Point NOT AVAILABLE Lower Explosion Limit NOT AVAILABLE

Evaporation Rate NOT AVAILABLE

Autoignition Temperature NOT AVAILABLE Decomposition Temperature NOT AVAILABLE

Partition Coefficient NOT AVAILABLE Viscosity NOT AVAILABLE

Page 2 of 4


RMT

ANCOR 1Product Name




Material to Avoid Incompatible with oxidising agents (eg. hypochlorites), acids (eg. nitric acid), nitrites, heat and ignitionsources.

HazardousDecompositionProducts

May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated todecomposition.

Hazardous Reactions Hazardous polymerization is not expected to occur.


Slightly corrosive - irritant. This product has the potential to cause adverse health effects with over exposure. Usesafe work practices to avoid eye or skin contact and inhalation. May cause sensitisation by skin contact. Chronicexposure may result in liver and kidney damage. Upon dilution, the potential for adverse health effects may bereduced.

Eye Corrosive - irritant. Contact may result in irritation, lacrimation, pain, redness, corneal burns and possiblepermanent damage.

Inhalation Slightly corrosive - irritant. Over exposure may result in irritation of the nose and throat, coughing, nausea andinflammation with breathing difficulties. Due to the low vapour pressure, an inhalation hazard is not anticipatedwith normal use.

Skin Slightly corrosive. Contact may result in irritation, redness, pain, rash, dermatitis and possible burns. May causesensitisation by skin contact.

Ingestion Slightly corrosive. Ingestion may result in ulceration and burns to the mouth and throat, nausea, vomiting,abdominal pain and diarrhoea.

Toxicity Data TRIETHANOLAMINE (102-71-6) LD50 (Ingestion): 2200 mg/kg (rabbit) LD50 (Intraperitoneal): 1450 mg/kg (mouse) LD50 (Skin): > 20 mL/kg (rabbit) TDLo (Ingestion): 16 g/kg/64 weeks (mouse - cancer)


Environment In soil and water, triethanolamine will biodegrade fairly rapidly following acclamation (half-life in the order of daysto weeks). In soil, residual triethanolamine may leach to groundwater. LC50 (shrimp): > 100 ppm.


Waste Disposal Reduce with sodium thiosulphate/ bisulphite (not strong reducing agent), acidify with 3M sulphuric acid. Scoop intoa container of water and neutralise with soda ash. Absorb with sand or similar and dispose of to approved landfillsite. Contact the manufacturer for additional information.







Shipping Name

UN No.

Packing Group

DG Class

Hazchem Code

Subsidiary Risk(s)

None Allocated

Poison Schedule Classified as a Schedule 5 (S5) Poison using the criteria in the Standard for the Uniform Scheduling of Drugs andPoisons (SUSDP).

AICS All chemicals listed on the Australian Inventory of Chemical Substances (AICS).


AdditionalInformation

RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoidexposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken.Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air


Page 3 of 4


RMT

ANCOR 1Product Name

powered or air supplied respirators should be considered where prolonged or repeated use is necessary.

ABBREVIATIONS:ACGIH - American Conference of Industrial Hygienists.ADG - Australian Dangerous Goods.BEI - Biological Exposure Indice(s).CAS# - Chemical Abstract Service number - used to uniquely identify chemical compounds.CNS - Central Nervous System.EC No - European Community Number.HSNO - Hazardous Substances and New Organisms.IARC - International Agency for Research on Cancer.mg/m³ - Milligrams per Cubic Metre.NOS - Not Otherwise Specified.pH - relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline).ppm - Parts Per Million.RTECS - Registry of Toxic Effects of Chemical Substances.STEL - Short Term Exposure Limit.SWA - Safe Work Australia.TWA - Time Weighted Average.

HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factors including: frequencyand duration of use; quantity used; effectiveness of control measures; protective equipment used and method ofapplication. Given that it is impractical to prepare a Chem Alert report which would encompass all possiblescenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.

PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this Chem Alert report is provided as a guide only.Factors such as method of application, working environment, quantity used, product concentration and theavailability of engineering controls should be considered before final selection of personal protective equipment ismade.

Report Status This document has been compiled by RMT on behalf of the manufacturer of the product and serves as themanufacturer's Safety Data Sheet ('SDS').

It is based on information concerning the product which has been provided to RMT by the manufacturer orobtained from third party sources and is believed to represent the current state of knowledge as to the appropriatesafety and handling precautions for the product at the time of issue. Further clarification regarding any aspect ofthe product should be obtained directly from the manufacturer.

While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provideany warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss,injury or damage (including consequential loss) which may be suffered or incurred by any person as aconsequence of their reliance on the information contained in this SDS.

Prepared By Risk Management Technologies5 Ventnor Ave, West PerthWestern Australia 6005Phone: +61 8 9322 1711Fax: +61 8 9322 1794Email: [email protected]: www.rmt.com.au

28 Jan 2010

End of ReportSDS Date

Page 4 of 4


RMT

SODIUM SULPHITEProduct Name


Supplier Name RHEOCHEM LTD

Address 11 Alacrity Place, Henderson, WA, AUSTRALIA, 6166

Telephone +61 8 9410 8200

Fax +61 8 9410 8299

Emergency 1800 127 406 (Australia); 011 64 3 3530199 (International)

Web Site http://www.rheochem.com.au/

Synonym(s) SODIUM SULFITE

Use(s) ANTIOXIDANT · FOOD PRESERVATIVE · LABORATORY REAGENT · PAPER INDUSTRY ·PHOTOGRAPHIC DEVELOPER · REDUCING AGENT · WATER TREATMENT

SDS Date 12 November 2012



R31 Contact with acids liberates toxic gas.

S25 Avoid contact with eyes.S46 If swallowed, contact a doctor or Poisons Information Centre immediately and show container or

label.

Hazchem Code

Packing Group

UN Number DG Class

Subsidiary Risk(s)



None Allocated


SAFETY PHRASES

RISK PHRASES


Ingredient Identification Classification Content

SODIUM CARBONATE <0.1%Xi;R36CAS: 497-19-8EC: 207-838-8

SODIUM SULPHITE >97%Not AvailableCAS: 7757-83-7EC: 231-821-4

SODIUM SULPHATE <2.5%Not AvailableCAS: 7757-82-6EC: 231-820-9

WATER <0.1%Not AvailableCAS: 7732-18-5EC: 231-791-2


Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing untiladvised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes.


Page 1 of 5

SDS Date: 12 Nov 2012



Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with runningwater. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.

Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once).Urgent hospital treatment is likely to be needed. If swallowed, do not induce vomiting.


First Aid Facilities Eye wash facilities and safety shower are recommended.


Flammability Non flammable. May evolve toxic gases (sulphur oxides) when heated to decomposition.

Fire and Explosion Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation.Remain upwind and notify those downwind of hazard. Wear full protective equipment including SelfContained Breathing Apparatus (SCBA) when combating fire.

Extinguishing Use an extinguishing agent suitable for the surrounding fire.



Spillage Contact emergency services where appropriate. Use personal protective equipment. Clear area of allunprotected personnel. Prevent spill entering drains or waterways. Contain spillage, then collect andplace in suitable containers for reuse or disposal. Avoid generating dust.


Storage Store in a cool, dry, well ventilated area, removed from oxidising agents, acids and foodstuffs.Ensure containers are adequately labelled, protected from physical damage and sealed when not inuse. Check regularly for leaks or spills. Also store removed from air and moisture.

Handling Before use carefully read the product label. Use of safe work practices are recommended to avoideye or skin contact and inhalation. Observe good personal hygiene, including washing hands beforeeating. Prohibit eating, drinking and smoking in contaminated areas.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Ingredient ReferenceTWA STEL

ppm mg/m³ ppm mg/m³

Sodium Carbonate (total dust) SWA (AUS) -- 10 -- --

Exposure Standards


Engineering Controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.

PPE

Eye / Face Wear dust-proof goggles.

Hands Wear PVC or rubber gloves.

Body When using large quantities or where heavy contamination is likely, wear coveralls.

Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator. At high dust levels, wear aFull-face Class P3 (Particulate) respirator.

9. PHYSICAL AND CHEMICAL PROPERTIES

WHITE CRYSTALLINE SOLIDAppearance

Page 2 of 5



ODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rate9.0 to 10.5pHNOT AVAILABLEVapour density2.6Specific gravitySOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEPartition coefficientNOT AVAILABLE% Volatiles




Material to Avoid Incompatible with oxidising agents (eg. hypochlorites) and acids (eg. nitric acid). Sensitive to air andmoisture.

May evolve toxic gases (sulphur oxides) when heated to decomposition.Hazardous DecompositionProducts

Polymerization is not expected to occur.Hazardous Reactions


Eye Low irritant. Contact may result in irritation, lacrimation, pain, redness, conjunctivitis and possiblecorneal damage.

Inhalation Low irritant. Over exposure may result in mucous membrane irritation of the respiratory tract, withcoughing. Some individuals are hypersensitive to sulphites, and may experience asthma likesymptoms (wheezing and shortness of breath) immediately following exposure.

Skin Low irritant. Contact may result in irritation, redness, rash and dermatitis.

Ingestion Low to moderate toxicity. Ingestion may result in gastrointestinal irritation, nausea and vomiting.Well tolerated due to the oxidation of sulphites in the body to sulphates, however with largequantities sulphurous acid is formed. Some individuals may have an allergic reaction. The acuteoral LD50 (male rat) is 3.56 g/kg/14 days.

Low to moderate toxicity. This product has the potential to cause adverse health effects with overexposure. Use safe work practices to avoid eye or skin contact and inhalation. Some individuals arehypersensitive to sulphites and may experience respiratory problems following exposure. Individualsknown to be hypersensitive or with existing respiratory problems (eg asthma) are advised to avoidexposure.


Toxicity Data SODIUM CARBONATE (497-19-8)LC50 (inhalation) 800 mg/m³/2 hours (guinea pig)LD50 (ingestion) 4090 mg/kg (rat)LD50 (intraperitoneal) 117 mg/kg (mouse)LD50 (subcutaneous) 2210 mg/kg (mouse)

SODIUM SULPHITE (7757-83-7)LD50 (ingestion) 820 mg/kg (mouse)LD50 (intraperitoneal) 950 mg/kg (mouse)LD50 (intravenous) 175 mg/kg (mouse)LDLo (ingestion) 2825 mg/kg (rabbit)LDLo (intravenous) 400 mg/kg (cat)LDLo (subcutaneous) 600 mg/kg (rabbit)

SODIUM SULPHATE (7757-82-6)LD50 (ingestion) 5989 mg/kg (mouse)

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SODIUM SULPHATE (7757-82-6)LD50 (intravenous) 1220 mg/kg (rabbit)LDLo (intravenous) 1220 mg/kg (mouse)TDLo (ingestion) 14 g/kg (mouse - 8-12 days pregnant)TDLo (subcutaneous) 806 mg/kg/26 weeks intermittently (mouse)


Environment Limited ecotoxicity data was available for this product at the time this report was prepared. Ensureappropriate measures are taken to prevent this product from entering the environment.


Waste Disposal Cover spill with soda ash or sodium bicarbonate. Mix and spray with water, may be effervescent.Wait until reaction is complete, scoop into a large beaker and cautiously add equal volume ofsodium hypochlorite (reaction may be vigorous). Add more water, stir and allow to stand (~1hr).Dilute and neutralise. Absorb with sand/similar dispose of to an approved landfill site, or alternatively(for small amounts) flush to sewer with large excess of water.


DG Class/ Division

Subsidiary Risk(s)

Packing Group


None Allocated

None Allocated


None Allocated


None Allocated

None Allocated

None Allocated

None Allocated

None Allocated

None AllocatedNone Allocated

None AllocatedProper Shipping Name

UN Number

LAND TRANSPORT(ADG)

SEA TRANSPORT(IMDG / IMO)

AIR TRANSPORT(IATA / ICAO)




Inventory Listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.

Poison Schedule A poison schedule number has not been allocated to this product using the criteria in the Standardfor the Uniform Scheduling of Medicines and Poisons (SUSMP)


RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.

WORKPLACE CONTROLS AND PRACTICES: Unless a less toxic chemical can be substituted for ahazardous substance, ENGINEERING CONTROLS are the most effective way of reducing exposure.The best protection is to enclose operations and/or provide local exhaust ventilation at the site ofchemical release. Isolating operations can also reduce exposure. Using respirators or protectiveequipment is less effective than the controls mentioned above, but is sometimes necessary.

PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this ChemAlert report is provided asa guide only. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.

Additional Information

Page 4 of 5



HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.

ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberGHS Globally Harmonized SystemIARC International Agency for Research on CancerLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetrePEL Permissible Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly

alkaline).ppm Parts Per MillionREACH Regulation on Registration, Evaluation, Authorisation and Restriction of ChemicalsSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsTLV Threshold Limit ValueTWA/OEL Time Weighted Average or Occupational Exposure Limit

Abbreviations

DescriptionRevision

Standard SDS ReviewStandard SDS Review

1.2


Initial SDS creation 1.0

Revision History

Report Status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier ofthe product and serves as their Safety Data Sheet ('SDS').

It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed torepresent the current state of knowledge as to the appropriate safety and handling precautionsfor the product at the time of issue. Further clarification regarding any aspect of the productshould be obtained directly from the manufacturer, importer or supplier.

While RMT has taken all due care to include accurate and up-to-date information in this SDS, itdoes not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMTaccepts no liability for any loss, injury or damage (including consequential loss) which may besuffered or incurred by any person as a consequence of their reliance on the informationcontained in this SDS.

Prepared By Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au

SDS Date:

End of SDS

Revision:12 November 20121.2

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11 Alacrity Place, Henderson, WA, AUSTRALIA, 6166

+61 8 9410 8200

1800 127 406 (Australia); 011 64 3 3530199 (International)

+61 8 9410 8299


RHEOCHEM LTD

POTASSIUM CHLORIDE (RHEOCHEM)

DRILLING FLUID ADDITIVE • FERTILISER • INHIBITOR

KCL • MURIATE OF POTASH • POTASH • SYLVITE

01 Nov 2010

Fax

Supplier Name

Address

Telephone

Emergency

Web Site

Synonym(s)

Use(s)

SDS Date

Product Name

NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA





UN No.

Packing Group

DG Class

Hazchem Code

Subsidiary Risk(s)


Ingredient Formula CAS No. Content

POTASSIUM CHLORIDE KCl 7447-40-7 >97%

Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by aPoisons Information Centre, a doctor, or for at least 15 minutes.

Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continueflushing with water until advised to stop by a Poisons Information Centre or a doctor.


Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed,do not induce vomiting.



Fire andExplosion

Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwindand notify those downwind of hazard. Wear full protective equipment including Self Contained BreathingApparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.

Extinguishing Prevent contamination of drains or waterways.

Flammability Non flammable. May evolve toxic gases (potassium oxides, chlorides) when heated to decomposition.



Page 1 of 4

Reviewed: 04 Nov 2010

Printed: 04 Nov 2010

RMT

POTASSIUM CHLORIDE (RHEOCHEM)Product Name

Spillage If spilt (bulk), use personal protective equipment. Contain spillage, then collect and place in suitable containers fordisposal. Avoid generating dust.

Handling

Store in a cool, dry, well ventilated area, removed from oxidising agents and foodstuffs. Ensure containers areadequately labelled, protected from physical damage and sealed when not in use.

Storage

Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skincontact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating,drinking and smoking in contaminated areas.



8. EXPOSURE CONTROLS/ PERSONAL PROTECTIONExposure Stds No exposure standard(s) allocated.


EngineeringControls

Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation isrecommended.

Personal Protective Equipment is not required under normal conditions of use.At high dust levels, wear: dust-proof goggles and a Class P1 (Particulate) respirator. With prolonged use, wear: rubber or cotton or PVC glovesand coveralls.

PPE

9. PHYSICAL AND CHEMICAL PROPERTIESAppearance WHITE SOLID Solubility (water) 340 g/L @ 20°C

Odour ODOURLESS Specific Gravity 2.0

pH NOT AVAILABLE % Volatiles NOT AVAILABLE

Vapour Pressure NOT AVAILABLE Flammability NON FLAMMABLE

Vapour Density NOT AVAILABLE Flash Point NOT RELEVANT

Boiling Point 1413°C Upper Explosion Limit NOT RELEVANT

Melting Point 773°C Lower Explosion Limit NOT RELEVANT

Evaporation Rate NOT AVAILABLE




Material to Avoid Incompatible (potentially explosive) with oxidising agents (eg. hypochlorites).

HazardousDecompositionProducts

May evolve toxic gases (potassium oxides, chlorides) when heated to decomposition.

Hazardous Reactions Polymerization will not occur.


Low toxicity. Use safe work practices to avoid eye or skin contact and inhalation. Acute potassium poisoning viaingestion is rare as a large single dose usually induces vomiting, and potassium is rapidly excreted by the body,however this product does have the potential to cause cardiovascular disorders.

Eye Low to moderate irritant. Contact may result in irritation, lacrimation, pain and redness.

Inhalation Low irritant. Over exposure may result in irritation of the nose and throat, with coughing.

Skin Low irritant. Prolonged or repeated contact may result in mild irritation, rash and dermatitis.

Ingestion Low toxicity. Ingestion may result in gastrointestinal irritation, nausea, vomiting, abdominal pain and diarrhoea.Ingestion of large quantities may result in blood clotting changes, cardiac arrhythmias, increased respiration,muscle weakness, convulsions and coma.

Toxicity Data POTASSIUM CHLORIDE (7447-40-7) LD50 (Ingestion): 1500 mg/kg (mouse) LD50 (Intraperitoneal): 620 mg/kg (mouse)


Page 2 of 4



RMT


LD50 (Intravenous): 117 mg/kg (mouse) LDLo (Ingestion): 20 mg/kg (man) LDLo (Intraperitoneal): 900 mg/kg (guinea pig) LDLo (Intravenous): 77 mg/kg (guinea pig) LDLo (Subcutaneous): 2120 mg/kg (frog) TDLo (Ingestion): 60 mg/kg/days (woman)

Environment Limited ecotoxicity data was available for this product at the time this report was prepared. Ensure appropriatemeasures are taken to prevent this product from entering the environment.


Waste Disposal Collect and place in sealable containers and dispose of to an approved landfill site. Contact the manufacturer foradditional information.







Shipping Name

UN No.

Packing Group

DG Class

Hazchem Code

Subsidiary Risk(s)

None Allocated

Poison Schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the UniformScheduling of Drugs and Poisons (SUSDP).

AICS All chemicals listed on the Australian Inventory of Chemical Substances (AICS).


AdditionalInformation

RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoidexposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken.Remember that some respirators may be extremely uncomfortable when used for long periods. The use of airpowered or air supplied respirators should be considered where prolonged or repeated use is necessary.

ABBREVIATIONS:ACGIH - American Conference of Industrial Hygienists.ADG - Australian Dangerous Goods.BEI - Biological Exposure Indice(s).CAS# - Chemical Abstract Service number - used to uniquely identify chemical compounds.CNS - Central Nervous System.EC No - European Community Number.HSNO - Hazardous Substances and New Organisms.IARC - International Agency for Research on Cancer.mg/m3 - Milligrams per Cubic Metre.NOS - Not Otherwise Specified.pH - relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline).ppm - Parts Per Million.RTECS - Registry of Toxic Effects of Chemical Substances.STEL - Short Term Exposure Limit.SWA - Safe Work Australia.TWA - Time Weighted Average.

HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factors including: frequencyand duration of use; quantity used; effectiveness of control measures; protective equipment used and method ofapplication. Given that it is impractical to prepare a Chem Alert report which would encompass all possiblescenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.

PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this Chem Alert report is provided as a guide only.Factors such as method of application, working environment, quantity used, product concentration and theavailability of engineering controls should be considered before final selection of personal protective equipment is


Page 3 of 4



RMT


made.

Report Status This document has been compiled by RMT on behalf of the manufacturer of the product and serves as themanufacturer's Safety Data Sheet ('SDS').

It is based on information concerning the product which has been provided to RMT by the manufacturer orobtained from third party sources and is believed to represent the current state of knowledge as to the appropriatesafety and handling precautions for the product at the time of issue. Further clarification regarding any aspect ofthe product should be obtained directly from the manufacturer.

While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provideany warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss,injury or damage (including consequential loss) which may be suffered or incurred by any person as aconsequence of their reliance on the information contained in this SDS.

Prepared By Risk Management Technologies5 Ventnor Ave, West PerthWestern Australia 6005Phone: +61 8 9322 1711Fax: +61 8 9322 1794Email: [email protected]: www.rmt.com.au

01 Nov 2010

End of ReportSDS Date

Page 4 of 4



RMT

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