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Date:
Subject:
From:
To:
255921
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
REGION 5 CENTRAL REGIONAL LABORATORY
536 SOUTH CLARK STREET
CHICAGO, ILLINOIS 60605
November 26, 2002
Review of Region 5 Data for Hegeler Zinc
R. Dilg, Chemist, IITRI/ESATContractor to Region 5 Central Regional LaboratorySubmitted to CRL on:
Attached are the results for: Hegeler Zinc
CRL data set number: E2J2801
Samples analyzed for: 18 for ICP Metals in soils and 7 for TCLP ICP metals
Results are reported for sample designations: E2J2801-01 to -22
DEC/ 0 9 /2002Dat^/Management Coordinator and Date Received
V
Date Transmitted: iff 0 9/ 2°°2
Please have the U.S. EPA Project Manager/Officer call the CRL Sample Coordinator at 3-7444for any comments or questions.
Please sign and date this form below and return it with any comments to:
Sylvia GriffinData Management CoordinatorRegion 5 Central Regional LaboratoryML- IOC
Received by and Date
Comments:
Rev. 4/10/02
Method Number: CRL METALS 003, 004, 025, & 1 311 Site Name: Hegeler ZincDate Generated: November 25, 2002 Task Order Number: 05-0-02Author: R.Dilg, IITRI-ESAT TDF Number: 5-02-079
Job No.: 102-052 -001Batch ID No.: E2J2801Parameter: ICP - total metals in soil &
ICP - TCLP metals analysis
ICP NARRATIVE PART 1
This part of the narrative covers the analysis of 18 soil samples from the named site sampled for ICPanalysis of total metals in soil.
For a listing of sample ID's, laboratory ID's, and sampling dates refer to the initial RLIMS reportpages where such a listing can be found.
The soil samples were received in good condition. The soils were dried at 105 °C overnight. The drysoils were ground using a laboratory ball mixer / grinder. Routine CRL hot block digestion procedures
WCRL SOP Metals 004 and Metals 025) were used to prepare the soil samples for GFAA and ICP^knalysis. The digested soil samples ( RLIMS Batch EK20404 ) were analyzed using the Optima
3300 DV ICP unit using analysis run method 'Sed 11132001 ESAT for the total metals analysis. Thesame digests were used for GFAA analyses, the results of which are reported separately.
ICP RUN RESULTS
Analyte mdl's determined during late summer of 2001 and rl values calculated from that informationfor ESAT analysis work for the Optima 3300 DV were used. The calculated rl values were used inreporting sample analysis results for this data case.
Because many samples contained high levels of zinc, a second analysis run was conducted wherediluted samples were run to determine and report Zn. All Zn sample results were reported from thisrun.
^malvsis RUN E2J2801 - Optima 3300 DV
The following lists the case pertinent out-of-control QC audit check results based on default QA / QC(traditional) limits:
RUNE2J2801:
Blanks: (Blank values are truncated rather than rounded)RUN 1:
Instrblkl: AI308 24.4 ug/LCa315 10.2Fe273 31.8Mn257 - 0.76 "
Digest blank: Mn257 -1.38 "(EK20404-BLK1)
GOOOOJ
ima 3300 DV (continued)(I-
RUN 2:
Instr blk2:
Instr blk3:
Instr bM:
Digest blank:(EK20404-BLK1)
Instr blk2:
Instr blk3:
AI308Cu324Fe273Mn257
Cu324Mn257V310
Zn213
Zn213
Zn213
Zn213
12.56.5
15.0- 1.3
- 5.3- 1.8-13.7
- 4.7
- 4.2
51.1
41.9
M9/Lti
ti
n
tf
»
ti
M9/L
n
M
M
Matrix spite audits:
E2J2801-01:
(EK20404-MS1)
RUN 2
(EK20404-MS3)
RUN 2
CdCuPbZn
Ba
Zn
*f
**62.4%
f
R
Qaudit not valid ; sample concentration greater than twice the spike concentration
RL check Soln: RL1:
RL2:(See paragraph below regarding rfs)
Presently no "contror actions are being implemented with the observed RL anatyte values actuallydetermined during the analysis run. RL check solution values currently are being analyzed forpurposes of generating a benchmark set of values which can be used to monitor the appropriatenessof any given RL level of analyte concentration.
Sample anaMe qualifications:
To date, compilation of control chart information is still on-going for some of the check audits fromOptima analysis runs for soils. Too little reliable data is currently available for some QA audits. Untilsuch time when compilation and evaluation of QA data is more complete, the default limits will beused.
Sample results for As, Sb, Se, and Tl were not reported by ICP; see GFAA results for these analyte
OOOOJ.O
Analysis RUN E2J2801 - Optima 3300 DV (continued) '
For Ba, all sample results are useable. The first Ba matrix spike audit concentration was at acomparable level as the samples and met QA audit control limits. This audit then is therefore anappropriate measure of matrix effects. Since the second Ba matrix spike audit concentration was at ahigher level than that for the samples it is a less appropriate measure of matrix effects on Ba, its lowrecovery should not significantly affect the Ba values for this data set.
For Fe, the ICP analyst contends that all Fe results are usable. The originally compiled control limitsfor the SRM were used rather than the later compilation which was used by the LIMS. The Fe SRMvalue met the original limits.
For Ag, the result for E2J2801-18 was flagged "L" and is estimated due to low bias indicated by theraw result being more negative than the negative value of the reporting limit for Ag. The Ag result forE2J2801-19 was flagged "J " since it had a result between the MDL and the rl value and is estimatedbecause of this.
Other comments
-afield QC samples included two pairs of field duplicates being designated: E2J2801-05 and -06, and%||2J2801-15 and -16. For the first pair Mn results did not exhibit good correlation. For the second
pair, results for Ba, Ca, Cu, Fe, Mg, Mn, Pb, and Zn did not exhibit good correlation.
R5CRL Files
The following pathways were used for storing analysis information to the R5CRL file server for thethis data set: Optima 3300 DV results:
(Vol2 on 'R5crl')[H:] \IITRI-Metals \Rdilg \E2J2801 \lcp \Optima 3300DV \Methods_ESAT(Vol2 on 'R5crl')[H:] \IITRI-Metals \Rdilg \E2J2801 \lcp \Optima 3300DV \narrative(Vol2 on 'R5crl')[H:] \IITRI-Metals \Rdilg \E2J2801 \lcp \Optima 3300DV \Results_ESAT(Vol2 on 'R5crl')[H:] \IITRI-Metals \Rdilg \E2J2801 \lcp \Optima 3300DV \SIFs_ESAT(Vol2 on 'R5crl')[H:] \IITRI-Metals \Rdilg \E2J2801 \lcp \Optima 3300DV\SS processed data
* ICP NARRATIVE PART 2
This second part of the narrative covers the analysis of 7 soil sample TCLP extracts from the namedsite sampled for ICP analysis of selected analytes.
For a listing of sample ID's, laboratory ID's, and sampling dates refer to the initial RLIMS reportpages where such a listing can be found.
The samples were extracted using TCLP Method 1311 on 10-30-2002. An extraction blank wasincluded. Extraction fluid #1 was used for all seven samples and the blank. The extracts werepreserved for metals analysis by using nitric acid and lowering the pH to less than 2. The preservedextracts were prepared for ICP analysis on 11-4-2002 by using routine CRL hot block (water)digestion procedures. A tenfold dilution of the preserved extract solution was digested for theanalysis of each extract sample. The digested samples ( Prep batch EK20403 ) were analyzed on11-15-2002 using the Optima 3300 DV ICP unit using analysis run method water_080300_m_ESAT.Analyte holding times were met.
000011
ICP RUN RESULTS
Analyte mdl's determined during late summer of 2001 and rl values calculated from that informationfor ESAT analysis work for the Optima 3300 DV were used. The calculated rl values were used inreporting sample analysis results for this data case.
3300 DV
The digested TCLP extracts (Prep Batch EK20403) were analyzed along with other sets of TCLPextracts. Copies of the raw analysis run printouts are included with this deliverable. A number of rawprintout pages did not print out well due to the printer ink supply running out during the middle of theanalysis run. Using the "Reprocessing" feature of the WinLab software the affected data were laterreprinted and are included with TCLP run pages of this deliverable at the end of the raw run dataprintouts.
Routine ESAT ICP reporting limits for the anatytes were used for reporting the extract analyte valuesfound rather than site specific action tevefe-as-limrts The extract analyte values reported reflect thetenfold dilution used to digest the extracts.
/ QC summary reports are the traditional set based on "default" QA/ QC limits. <
The following lists the case pertinent out-of-control QC audit check results based on default QA / QC(traditional) limits:
RUN E2J2201 :
Blanks: (Blank values are truncated ralher than rounded)
Extract blank: Ba455(EK20403-BLK2) Cd226
Cr267
2.10.8 "0.35 "
AQC's: LCMVs: LCM1(1):
LCM1(2):
LCM1(3):
LCM1(4):
Ag328
Ag328
Ag328
Ag328
* upper concentration level exceeded ; LCM2 check audits used for control purposes
Matrix spike: E2J2801 -09: Se 116%R(EK20403-MS1)
Analysis RUN E2J2201 - Optima 3300 DV (continued!
RL check Soln: RL 1:(See paragraph below regarding rl's)
RL2:
Presently no "control" actions are being implemented with the observed RL analyte values actuallydetermined during the analysis run. RL check solution values currently are being analyzed forpurposes of generating a benchmark set of values which can be used to monitor the appropriatenessof any given RL level of analyte concentration.
Sample analvte qualifications:
QA / QC summary reports are the traditional set based on "default" QA/ QC limits.
For As, the sample result for E2J2801-13 is flagged "J" since it had a result between the MDL andthe rl value and is estimated because of this.
Pb, the sample result for E2J2801-11 is flagged "J" since it had a result between the MDL andrl value and is estimated because of this.
For Se, the sample result for E2J2801-04 is flagged "J" since it had a result between the MDL andthe rl value and is estimated because of this. It is also flagged "K" due to possible high bias asindicated from the matrix spike audit result.
Other comments
Copies of laboratory notebook entries for the Method 1311 extraction information are included withthis deliverable.
R5CRL Files
he following pathways were used for storing analysis information to the R5CRL file server for theis data set: Optima 3300 DV results:
(Vol2 on 'R5crl')[H:] \IITRI-Metals \Rdilg \E2J2801TCLP \lcp \Optima 3300DV \Methods_ESAT(Vol2 on 'R5crl')[H:] \IITRI-Metals \Rdilg \E2J2801TCLP \lcp \Optima 3300DV \narrative(Vol2 on 'R5crl')[H:] \IITRI-Metals \Rdilg \E2J2801TCLP \lcp \Optima 3300DV \Results_ESAT(Vol2 on 'R5crl')[H:] \IITRI-Metals \Rdilg \E2J2801TCLP \lcp \Optima 3300DV \SIFs_ESAT(Vol2 on 'R5crl')[H:] \IITRI-Metals \Rdilg \E2J2801TCLP \lcp \Optima 3300DV \SS processed data
ooooia
IITRIIIT RESEARCH INSTITUTE
IIT Research Institute ESAT Region 5536 South Ctarit t, S*M* 734;T«l«phon« (312) 353-S3O2 (312) 353-S3O7
Supertax!, US EPA Region 577 West Jackson BoulevardChicago n, 60604
Pn>ject:Hegelei ZincProject Number (none)
Project Manager Howard PharaReported:
Nov-26-02 14:43
2003ZG02S01E2J2801-01(Soil)
MetabbylCr
*+*
Barf.!""BeryKaai
/^Maunai"JLmmChraaumCatoMCapperIra*LeadMacacaarafiaaiaarirNicfcdPttmfrM
Sa>crSediMVuadiMZwc
Saapted:Received:
Fl-p'Ron,, Qolrtieis MDL
I3N* 24IT* 010l-» 006032* 072MM 1.4It 07213 062
I2M 04042M4 17
22M 3433M 163N 0.1239 080
7M 38IJ 02632* 1225 19
7t«M 25
Oct-23-02 09:45Oct-28-02 12:03
Reporting
Limit Units
7 6 m£/Vg
030
0 16
072
46
072
20
IJ
38
I I
84
036
26
120
080
38
60
80
DOution Balcfc Prepared Analyzed
1 EK20404 No*-06-02 Nov- 12-02» • • •
• • m m
m m * m
^* • » •
.
.
.
.• • • •
.
.• » ai •
• * • •
•> • <i •
« * • •
50 Nov-21-02
KidiardUilg.Lliqnist
OO0056RqmrtName: E2J2801
Page 2 of20
IITRIIIT RESEARCH INSTITUTE
IIT Research Institute ESAT Region 5
536 South Clark Street, Suite 734; Chicago, IL 6O605Telephone (312) 353-8302 Facsimile (312) 353-8307
Superfund, US EPA Region 577 West Jackson BoulevardChicago IL, 60604
Project:Hegeler ZincProject Numberlnone] Reported:
Project ManagerHoward Pham Nov-26-02 14:43
2003ZG02S03
E2J2801-03(Soil)Sampled: Oct-23-02 10:35Received: Oct-28-02 12:03
Metals by ICP
\nalyte
AluminumBariumBeryllium
/*»-lmium%|liumChromiumCobaltCopperIronLeadMagnesiumManganeseNickelPotassiumSilverSodiumVanadiumZinc
Result
8900100
0.92
58
210009.4
8.5
98
30000720
5800800
19
780
U
120
19
11000
Flags/Qualifiers ^JTJL
2.4
0.10
0.0600.22
1.4
0.22
0.62
0.40
1.2
3.4
2.6
0.12
0.80
38
0.26
12
1.9
5.0
ReportingLimit
7.6
0.30
0.16
0.72
4.6
0.72
2.0
1.3
3.8
11
8.4
0.36
2.6
120
0.80
38
6.0
16
Units Dilution Batch Prepared Analyzed
mg/kg 1 EK20404 Nov-06-02 Nov- 12-02ii ii n n n
„
" "
„
„
II II H II H
-n n ii it n
n n it n n
ii n n n ii
n n n n n
i, ii ,, it .1
H n u n n
„ii ii n n n
„
10 " " Nov-21-02
Kicnaru L/iig, L,nemist
00005;Report Name: E2J2801
Page 3 of20
IITRIIIT RESEARCH INSTITUTE
ESAT Region 5IIT Research
536 South Ctawfc StoMt, Sirite 734; <T«tophon« (31Z) 353-83O2 Firilali (312) 353-OO7
Soperfund. US EPA Region 577 West Jadcsoa BoulevardChicago IL, 60604
Project :Hcgelcr ZincProject Numberlnonel Reported:
Project Manager-Howard Pham Nov-26-02 14:43
2M3ZG02S05
E2J2801-05(SoiI)Sampled: Oet-23-02 11:00
Received: Oet-28-02*12:03
MetabbyKT
taatyic
Barwai
BerjUmm
3G7ChrMMM
Cobalt
C**»erITMLadMafBCMBl
Ma^aMK
Nickel
Titmnm
SivcrS^NM
Vaudaiai
ZMC
HiResult 0"»
II*•47
12
»J
IS
INN
2*
37M
22*
21
IN*
V
IM
21
2SM
V
24
0 10
0060
022
1 4
022
062
040
12
34
26
012
080
38
026
12
19
25
ReportingLimit Units Dflutxn Batch PicpMtd Analyzed
76 rng.lg 1 EK2M04 Nov-06-02 No v- 12-020.30 . . . .
0.16 . . . .0 7 2 . . . .
46 ^0 7 2 . . . .
20
13
38I I . . . .
84
OJ6
26
1200 8 0 . . . .3 8 . . . .
60
80 * 5 ' * Nov-21-02
'.)
Kjcnara tnig. L.netntsi
OOOOJdReport Name: E2J2801
Page 4 of 20
IITRINT RESEARCH INSTITUTE
I IT Research Institute ESAT Region 5536 South Clark Street, Suite 734; Chicago, IL 60605Telephone (312) 353-8302 Facsimile (312) 353-83O7
Superfund, US EPA Region 577 West Jackson BoulevardChicago IL, 60604
Project;Hegeler ZincProject Number: [none] Reported:Project ManagerHoward Pham Nov-26-02 14:43
2003ZG02D05
E2J2801-06(SoiI)Sampled: Oct-23-02 11:00
Received: Oct-28-02 12:03
Metals by ICP
Vnalyte
AluminumBariumBeryllium
tt^tffc
ChromiumCobaltCopperIronLeadMagnesiumManganeseNickelPotassiumSilverSodiumVanadiumZinc
Result
11000
96
0.66
1.4
5800
13
9.8
17
18000
22
3700
150
19
1200
U
99
22
2300
Flags/Qualifiers MJJL
2.4
0.10
0.060
0.22
1.4
0.22
0.62
0.40
1.2
3.4
2.6
0.12
0.80
38
0.26
12
1.9
2.5
Reporting
Limit Units Dilution Batch Prepared Analyzed
7.6 mg/kg 1 EK20404 Nov-06-02 Nov-12-02
0.30 " " " /
0.16 " " " " /
0.72 " " " " " ^^~
4.6
0.72
2.0 "
1.3
3.811
8.4
0.36
2.6
120
0.80
38
6.0
8.0 5 Nov-21-02
Kicnara uiig, unemist
000033Report Name: E2J2801
Page 5 of 20
IITRIIIT RESEARCH INSTITUTE
IIT Research 1
536 Smith(312)353-6302
M. 60605(312)353-8307
Supofimd. US EPA Region 577 West Jackson Boulevard
Chicago IL, 60604
ProjecrHegeler Zinc
Project Number (none)Project Manager Howard Pham
Reported:
Nov-26-02 14:43
2M3ZG02S06
E2J2801-07(SoiI)
Sampled: Oct-23-02 11:12
Received: Oct-28-02 12:03
laatyte Result
Almmmmm 2MN
Biriw l»
BcfyflMBi 1.1
•" M* MIttOtmrn IMM
QUOTUM M
€«** IS
Coffer 43
Ircai 27SM
Lad 2*MMapMpM SJ»J
RvM»fHB(9C 30VNickel 43•4^— 1— ^ ^I^ArvunMifll ZIW
Sarcr U
S^MM IJ»
VaMdiaai 35
ZMC I2M*
FiiesOoJifien MDL
2 4
010
0060
022
14
022
062
040
12
3 4
26
012
080
38
026
12
19
5 0
ReportingLimit
'6
030
( 16
072
4 6
072
20
13
3 8
II
84
(J6
26
!20
080
38
40
16
Units Dilution Batch Pieyaul Analyzed
meVg 1 EX20404 Nov-06-02 Nov-12-02. . . .
• * . . .
.
^• • p • •
* • p • •
• » • P •
.
• * P P •
W P P P P
• •> • p p
• p p p •
.
.
.
.
1 0 • • Nov-21-02
o
0000^0Report Name: E2J2801
Page 6 of 20
IITRIIIT RESEARCH INSTITUTE
NT Research Institute ESAT Region 5536 South Clark Street, Suite 734; Chicago, IL. 60605Telephone (312) 353-8302 Facsimile (312) 353-8307
Superfund, US EPA Region 577 West Jackson BoulevardChicago IL, 60604
Project: Hegeler ZincProject Numberfnone]
Project ManagerHoward PhamReported:
Nov-26-02 14:43
2003ZG02S07
E2J2801-08(Soil)
Metals by ICP
\nalyte
AluminumBariumBeryllium
£ jiiiiumfla\ jB
VnciurnChromiumCobaltCopperIronLeadMagnesiumManganeseNickelPotassiumSilverSodiumVanadiumZinc
Result
17000
110
2/1
28
15000
13
7.9
37
26000
70
4300
250
27
1100
V
120
23
4600
Sampled:Received:
Flags/Qualifiers MDL
2.4
0.10
0.060
0.22
1.4
0.22
0.62
0.40
1.2
3.4
2.6
0.12
0.80
38
0.26
12
1.9
2.5
Oct-23-02 12:55Oct-28-02 12:03
Reporting
Limit Units
7.6 mg/kg
0.30
0.16
0.72
4.6
0.72
2.0
1.3
3.8
11
8.4
0.36
2.6
120
0.80
38
6.0
8.0
Dilution Batch Prepared Analyzed
1 EK20404 Nov-06-02 Nov-12-02ii n n ii
n n n U
«
n n ii n
n it n «
n » it ii
,,
n n n n
„„„n ii n tt
n n ii n
ii it n n
„„
5 " " Nov-21-02
Kicnard uilg, cnemist
OOOOSi
Report Name: E2J2801
Page 7 of 20
IITRIIIT RESEARCH INSTITUTE
IIT Research Institute ESAT Region 5
(312) (312)353-8307
Svperfind. US EPA Region S77 West Jackson BonfcrardChicago IL, 60604
Project: Hegeler ZincProject Number [none]Project Manager Howard Pham
Reported:
Nov-26-02 14:43
2M3ZG02S08E2J2801-09(SoiI)
Sanpkd: Oct-23-02 13:37
Received: Oct-28-02 12:03
MctabbylCr
Urfyte
Mmmimmm
BariMM
BeryK»^mimmdammChrwauM
CafcakCapper
ITMLead
MagattMai
Mragaawae
NiduJ
PMaaaiM
Safeer
SvJaaai
VaaadiM
Zaac
FlReadi 0"
I2*MSS
•.72
12
34M
15
ts31
22Mt
2M
2CM
lit
13
1IM
V
75
2*
IJM
2 4
010
0060
022
14
022
062
040
12
34
26
012
080
38
026
12
19
050
RepottingLimit
"6
130
016
072
46
072
20
1.3
38
11
84
OJ6
26
120
080
38
60
1 6
Units Dilubon BMcb Pleyaed Analyzed
mgV? 1 EK20404 Nov-06-02 Nov- 12-02• • * • •
r
.
• • ^g
•m m m m m
* • • • •
* • « • •
• • • ai •
* • • • •
* • m m m
• m m m m
V M M * •
m m m m m
* * at m m
-
Nov-21-02
KKtiara Lnig, L,nemtstReport Name: E2J2801
Page 8 of20
IITRIIIT RESEARCH INSTITUTE
IIT Research Institute ESAT Region 5536 South Clark Street, Suite 734; Chicago, IL 60605Telephone (312) 353-8302 Facsimile (312) 353-8307
Superfund, US EPA Region 577 West Jackson BoulevardChicago IL, 60604
Project:Hegeler Zinc
Project Number: [none]Project ManagerHoward Pham
Reported:
Nov-26-02 14:43
2003ZG02S09
E2J2801-10(Soil)Sampled: Oct-23-02 14:10Received: Oct-28-02 12:03
Metals by ICP
taalyte
AluminumBariumBeryllium
j^Hmium%|iium
ChromiumCobaltCopperIronLeadMagnesiumManganeseNickelPotassiumSilverSodiumVanadiumZinc
Result
6000
80
0.67
12
16000
6.4
6.1
59
27000
250
2800
520
14
600
U
120
17
2700
Flags/Qualifiers MDL
2.4
0.10
0.060
0.22
1.4
0.22
0.62
0.40
1.2
3.4
2.6
0.12
0.80
38
0.26
12
1.9
2.5
ReportingLimit
7.6
0.30
0.16
0.72
4.6
0.72
2.0
1.3
3.8
11
8.4
0.36
2.6
120
0.80
38
6.0
8.0
Units Dilution
mg/kg 1
"„
„
„
II H
II H
II II
II II
It II
n
n i,
"
M n
n n
„
„
5
Batch Prepared Analyzed
EK20404 Nov-06-02 Nov-12-02ir n H
M n n
n n . n
n n n
H n n
it n n
n n n
n n n
n it n
n » «i
" "
n n n
n n n
n » n
II N II
II II II
Nov-21-02
Kicnard Uilg, unemist
GOOOSJ
Report Name: E2J2801
Page 9 of20
IITRIRESEARCH INS 111 If!
IIT Research tastttat* ESAT Region 5
536 South Ctarfc StrMt,Tctephon* (312) 353-83O2
734; Chicago, IL 60605(312)353-8307
SaperfuDd, US EPA Region 5 Project Hegel er Zinc77 West Jackson Boulevard Project Number 1 none]Chicago IL, 60604 Project Manager Howard Pham
Reported:Nov-26-02 14:43
2M3ZG02S10E2J2801-ll(Soil)
MetabbylCP
taalyie
AfaMBM
Bariaai
BeryBu
^^daMUX'^fffia^
ChrvaNM
Cafeaft
Capper
Ira*Lea*
riijaiiiaai
riaajiafir
Nkkrf
ruaaiiaai
Star
S^MBI
VantfMai
ZiK
o
Sampled:
Received:
Flajs'Resnh Qwlifim MDL
MM 24
27t 010
1.1 0060
15 022
21M» 14
M 022
12 062
I7f 040
74M> IJ>
12* 34
3SM 2,6
CTf 012
55 080
•!• 38
V 0.26
2M 12
2f 1 9
34M 25
Oct-23-02 14:35
Oct-28-02 12:03
Rcportiiig
Limit Units
7 6 mg/kg
030
016
072
46
072
20
1.3
38
I I
84
036
26
120
080
38
60
80
Dilutioa BaKh Prepared Analyzed
1 EK20404 Nov-06-02 Nov-12-02. . .
• Wl » •
•1 * •> •
^• • * •
.• m m m
. . .• • • •
• • • •
.
.• • • •
.* » • •
• • • •
5 ' • Nov-21-02
k^
OOOOS4
'ReportName: E2J2801
Page 10 of 20
IITRIIIT RESEARCH INSTITUTE
IIT Research Institute ESAT Region 5536 South Clark Street, Suite 734; Chicago, IL 60605Telephone (312) 353-8302 Facsimile (312) 353-8307
Superfund, US EPA Region 577 West Jackson BoulevardChicago IL, 60604
Prqject:Hegeler ZincProject Numberfnone] Reported:Project ManagerHoward Pham Nov-26-02 14:43
2003ZG02S11E2J2801-12(Soil)
Sampled: Oct-24-02 08:15Received: Oct-28-02 12:03
Metals by ICP
taalyte
Aluminum
BariumBeryllium
^*tmiumllliumChromiumCobaltCopperIronLeadMagnesiumManganeseNickelPotassiumSilverSodiumVanadiumZinc
Result
8300
140
0.92
9.6
30000
19
9.9
110
44000
290
3900
770
21
1000
U
190
29
2300
Flags/Qualifiers MDL
2.4
0.10
0.060
0.22
1.4
0.22
0.62
0.40
1.2
3.4
2.6
0.12
0.80
38
0.26
12
1.9
2.5
ReportingLimit
7.6
0.30
0.16
0.72
4.6
0.72
2.0
1.3
3.811
8.4
0.36
2.6
120
0.80
38
6.0
8.0
Units Dilution Batch Prepared Analyzed
mg/kg 1 EK20404 Nov-06-02 Nov-12-02i i n u n "
n n n H ii
n
"
„
"
ii n ii n n
„»ti ti it ii ti
II H It H 11
II It II tl H
I,
II II II H II
II II H It It
" 5 " " Nov-21-02
Kicnara uiig, ChemistReport Name: E2J2801
Page 11 of 20
IITRI tastitate ESAT Region 5IIT
536 South Ctawfc MrMt, Mto 734s (Tatophon* (312)353-8302 ricahali (312)353-8307
IIT
Supofuod. US EPA Regioo 577 West Jackson BoulevardChicago IL, 60604
ProjectHegeler ZincProject Number (none)
Project MnagerHoward PhamReported:
Nov-26-02 14:43
2M3ZG02S13E2J2Ml-14(SoU)
Sampled: Oct-24-02 08:40Received: Oct-28-02 12:03
Metals by ICF
laalyle Ren** f__|___ CaMft
Bariaai 2SIBerYKM 14~\lauaai IS«_£ICMB Z/*v
ChraaMM 17Cobalt ItCapper 95Iran 4"7tMLead 4ltMHBi liaai 319Maaaaaeae 67Nkkd 3Sntanf¥TTT 7MSaVer VSaaiaai 3MVaaadim MZiac 92t
Flags/
2.4
010
00600.22
14
0.22
062
040
1.2
3.4
26
012
OK)
31
OJ6
12
19
050
Reporting
Limit
76
330
316
072
46
072
20
13
3.8
1184
OJ6
26
120
080
38
60
16
Units DfluDon Batch Prepared Analyzed
me/kg 1 EK20404 Nov-06-02 Nov-12-02m * m * •
m m m m m
m m m m m
| g.
.
.
•.
.
.
+ m m m m
* m m m m
.
.,
Nov-21-02
//-<?<£>-O>-Kicnara Lnig, coemtsi
OOOOSo
Report Name: E2J2801
Page 12 of 20
IITRIIIT RESEARCH INSTITUTE
IIT Research Institute ESAT Region 5536 South Clark Street, Suite 734; Chicago, IL 60605Telephone (312) 353-8302 Facsimile (312) 353-8307
Superfiind, US EPA Region 577 West Jackson BoulevardChicago IL, 60604
Project;Hegeler ZincProject Number: [none]
Project ManagerHoward PhamReported:
Nov-26-02 14:43
2003ZG02S14E2J2801-15(Soil)
Sampled: Oct-24-02 08:52
Received: Oct-28-02 12:03
Metals by ICP
Vnalyte
Aluminum
Barium
Beryllium^Smium^Ifcium
Chromium
Cobalt
Copper
Iron
LeadMagnesium
Manganese
Nickel
Potassium
Silver
Sodium
Vanadium
Zinc
Result
7900
86
1.3
25
250012
11
630
60000
4200
490
160
25
320
U
88
22
32000
Flags /Qualifiers MDL
2.4
0.10
0.060
• 0.22
1.4
0.22
0.62
0.40
1.2
3.4
2.6
0.12
0.80
38
0.26
12
1.92.5
Reporting
Limit
7.6
0.30
0.16
0.72
4.6
0.72
2.0
1.3
3.8
11
8.4
0.36
2.6
120
0.80
38
6.0
8.0
Units Dilution Batch Prepared
mg/kg 1 EK20404 Nov-06-02H II II II
ii n ii n
„ii n n n
n n n n
„II II H H
H ii n n
H it n n
„H II II tl
H . n n n
„„ii ii » n
ti n n ii
" 5 " "
Analyzed
Nov-12-02n
n
n
' n
it
n
n
n
n
it
•i
n
•»""
Nov-21-02
Kicnard Lmg, t^nemistReport Name: E2J2801
Page 13 of 20
IITRIIIT Research htstftat* ESAT Region 5
Tctophon* (312) 353O02 FacataBe (312) 353-8307
IIT RESEARCH INSTITUTE
Saperfaod. US EPA Region 5 Project:Hegeler Zinc
77 West Jadooo Boulevard Project Number [none] Reported:Chicago IL. 60604 r pject Manager Howard Pham Nov-26-02 14:43
20t3ZG62D14
E2J2Ml-16(SoiI)Sampled: Oct-24-02 08:52Received: Oct-28-02 12:03
byKT
taalytt
AtaauMmBaramBcrj«m-VtaumJLmmChraaUMiCckaJtCipatrbwLeadMlgJHBJM
InrirMichel
mania*SNtr$••!••" — -" —ZaK
Resok
S4M
II*
Ml
21
37IM12
1*
92
4IM*321
43N
rm23
1*M
V
IN
22
35M
Flap/OUUDCR (LfDI
24
010
0060
022
14
OJ22
062
040
1J
34
i6
012
080
38
026
12
19
2,5
Reporting
Limil
7.6
D30
0 16
072
46
072
20
1.3
38
I I
84
036
26
120
080
38
60
80
Units Daution Batch Prepared Analyzed
mg/kf 1 EK20404 Nov-06-02 Nov-12-02
•• • • * •
r • • • •
^* • * • • •!••
• m " • •
• • • • •
• • • * •
. . . .
* • • » •
* m • » •
* • m • *
•» » • • •
* * • • •
• • • • •
.
5 * ' Nov-21-02
Report Name: E2J2801uiig. unonui Page 14 of 20
IITRIIIT RESEARCH INSTITUTE
IIT Research Institute ESAT Region 5536 South Clark Street, Suite 734; Chicago, IL 60605Telephone (312) 3534302 Facsimile (312) 353-8307
Supertund, US EPA Region 577 West Jackson BoulevardChicago IL, 60604
Project;Hegeler ZincProject Number: [none]
Project ManagerHoward Pham
Reported:
Nov-26-02 14:43
2003ZG02S15
E2J2801-17(Soil)
Sampled: Oct-24-02 09:05
Received: Oct-28-02 12:03
Metals by ICP
\nalyte
Aluminum
Barium
Beryllium
Mrcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Silver
Sodium
Vanadium
Zinc
Result
7500
130
0.87
3.4
1900
12
3.6
47
89000
790
380
6511
4700
0.96
1900
30
710
Flags/Qualifiers MDL
2.4
0.10
0.060
0.22
1.4
0.22
0.62
0.40
1.2
3.4
2.6
0.12
0.80
38
0.26
12
1.9
0.50
ReportingLimit
7.6
0.30
0.16
0.72
4.6
0.72
2.0
1.3
3.8
11
8.4
0.36
2.6
120
0.80
38
6.0
1.6
Units Dilution Batch
mg/kg 1 EK20404n ii n
H n n
n n H
n H n
N n n
n n II
n n n
f. H II
H II II
It It H
.,
It II II
tl II II
„
„
„
n
Prepared
Nov-06-02"n
n
u
n
n
n
n
n
n
"
it
n
»•••"
Analyzed
Nov-12-02"it
it
it
n
n
u
»it
ti
ti
n
»-»
Nov-21-02
w
Kicnara uiig, Lnemist
0000^3
Report Name: E2J2801
Page 15 of 20
IITRI IIT Research Institute ESAT Region 5S36 South Ctarfc ttraet, Mte 734j CWc^o, H. 6O605Tctophon* (312) 353-S3O2 FacsMte (312) 353-B3O7
Soperfnod. US EPA Region 577 West Jackson BoolevwdChioco IU 60604
Project: Hegeier ZincProject Number [none]
Project Mnager Howard Phara
Reported:
Dec-04-02 11:15
2M3ZG02S16
E2J2801-18(Soil)
Suipled: Oct-24-02 09:10
Received: Oct-28-02 12:03
MetabbyKT
ferine
AJaaUBaai
Bariaai
ttrjmmm
•"VauaaifJUaa,
Caraatiaai
Cabatt
Caaacr
Iraa
LeadMijaiaMMaagaaeatNickelftmrimm
SaverSadiaaiVaaadiaaiZ«K
f^f^wf^**
ISM*
22*
23
19
SIM
27
7.4
12*
I4MM
MM
4tt
IM
27
24M
V
UM
7*34M
2-4
010
0060
0^2
14
0^2
062
040
1-2
3.4
2.6
012
080
38
L OJ6
12
19
2.$
Keponmf
Lima
7.6
OJO
016
072
46
072
20
U
3.8
11
84
OJ6
26
120
080
38
60
80
Units DOoboa Back Prepared Analyzed
rngAg 1 EK20404 Nov-06-02 Nov-12-02.
. . . .
. . . .
. . . . ^ |
. . .
'.
» • m m m
* m » m m
* * • • at
.
.
• * m m m
. . .
» • • • •
• •> • * •
5 Nov-21-02
Kicnara Uilg. (Joemtst
000070Report Name: E2J2801
Page 16 of 20
IITRIIIT RESEARCH INSTITUTE
IIT Research Institute ESAT Region 5536 South Clark Street, Suite 734; Chicago, IL 60605Telephone (312) 353-8302 Facsimile (312) 353-8307
Superfund, US EPA Region 577 West Jackson BoulevardChicago IL, 60604
ProjectrHegeler ZincProject Number: [none]
Project ManagerHoward PhamReported:
Nov-26-02 14:43
2003ZG02S17E2J2801-19(SoiI)
Metals by ICP
Vnalyte
AluminumBariumBeryllium
/••NJmiuni%tfjumChromiumCobaltCopperIronLeadMagnesiumManganeseNickelPotassiumSilverSodiumVanadiumZinc
Result
4400
330
0.79
63
8700
10
12
480
37000
1200
2700
200
20
340
0.71
180
14
22000
Sampled:Received:
Flags/Qualifiers MDL
2.4
0.10
0.060
0.22
1.4
0.22
0.62
0.40
1.2
3.4
2.6
0.12
0.80
38
J 0.26
12
1.9
10
Oct-24-02 09:32Oct-28-02 12:03
Reporting
Limit Units
7.6 nig/kg
0.30
0.16
0.72
4.6
0.72
2.0
1.3
3.8
11
8.4
0.36
2.6
120
0.80
38
6.0
32
Dilution Batch Prepared Analyzed
1 EK20404 Nov-06-02 Nov-12-02i, „ n
H II II II
H u n i i
II n II n
n n It it
H it n it
It H It II
II H It II
It ii II n
,.
ii t, n n
1. II n „
II II tl tl
,,
H II II II
n
20 " " Nov-21-02
Kicnard Ung, cnemist
oooo;±Report Name: E2J2801
Page 17 of20
IITRI IIT Research Institute ESAT Regton 5
536 Soiith Ctefc SfaMt, Strite 734; CMcavo, ITetaphon* (312) 353-8302 FacsMte (312) 353-8307
INSTITUTE
Sopofuod, US EPA Region 5
77 West Jackson BonlewdChicago tL, 60604
Project: Hegeler Zinc
Project Numberlnone)
Project ManagerHoward Pham
Reported:
Nov-26-02 14:43
2M3ZG02S18E2J2MI-20(SoiI)
Saapled: Oct-24-02 09:50Received: Oct-28-02 12:03
MdabbyKT
lolytt
AlmmimmmBmrimmBerjflkuafif-i-lo..
CarWMiM
CakeJtCippcr
Ira*LeadMUfitmmIttnfmntNickeltttMmimmSatorSetiM
ViaidiMZtec
3
FlRemit 0"
3SMIN•.75
3*I4M
14
II93»
71M>
MM42*2MM
3M4.1
2M1*
I9M1
IBS/lifiel» MDL
240.10
0060
02214
022
062
040
12
34
26
01208038
0261219
10
Reporting
Lhnd
76
OJO
016
072
46
072
20
IJ
381184
03626120ago386032
Uoits D3atio0 Babdi IVcpvccd Analyzed
mg^ 1 EK20404 Nov-06^2 Nov- 12-02*. . . • •
• • * • •
* m m m m
. . . ^.
»
* • m * m
n m m m m
'* m m * •
+ m m m m
+ » m m m
+ m m m •
•• m m • •
» • » * •
* • • » •
20 ' ' Nov-21-02
U
0000 ?^
Report Name: E2J2801
Page 18 of 20
IITRIIIT RESEARCH INSTITUTE
. IIT Research Institute ESAT Region 5
536 South Clark Street, Suite 734; Chicago, IL 606O5Telephone (312) 353-8302 Facsimile (312) 353-8307
Superfund, US EPA Region 577 West Jackson BoulevardChicago IL, 60604
ProjectHegeler ZincProject Numbenfnone] Reported:
Project ManagerHoward Pham Nov-26-02 14:43
2003ZG02S19
E2J2801-21(Soil)Sampled: Oct-24-02 09:51Received: Oct-28-02 12:03
Metals by ICP
\nalyte
AluminumBariumBeryllium
fijif""1"SKiumChromiumCobaltCopperIronLeadMagnesiumManganeseNickelPotassiumSilverSodiumVanadiumZinc
Result
4300
270
0.72
78
6800
11
11
490
36000
1500
1400
270
17
360
1.6
180
14
22000
Flags /Qualifiers MDL
2.4
0.10
0.060
0.22
1.4
0.22
0.62
0.40
1.2
3.4
2.6
0.12
0.80
38
0.26
12
1.9
10
Reporting
Limit
7.6
0.30
0.16
0.72
4.6
0.72
2.0
1.3
3.8
11
8.4
0.36
2.6
120
0.80
38
6.0
32
Units Dilution Batch Prepared Analyzed
mg/kg 1 EK20404 Nov-06-02 Nov-12-02" » »
"II II ii II n
n H n n n
H n n n II
n n H H n
n n it n it
n « it n n
n u n n n
II II II N II
n n M n n
.,II II It II H
n n ii n n
n n n n n
„ ,1 M
20 " Nov-21-02
Kicnara uilg, Chemist
000073
Report Name: E2J2801
Page 19 of 20
IITRIIIT RESEARCH INSTITUTE
IIT Research Institute ESAT Rvgfcm 5
Tctaohon* (312) 353-83O2 Fat •!••• (312) 353OO7
Soperfund. US EPA Region S Project Mcgelcr Zinc77 West Jackson Boulevard Project Number [ none) Reported:Chicago IL. 60604 Project Manager Howard Pham Nov-26-02 14:43
Notes aad DefiiitioBs
» Spice audit not valid. The ample caacemnboo exceeds twice the concentration of the spike added. No qulifiatian made for thisQCaodiL
J The identification of the aoalyte is acceptable; the reported value is an estimate.
L The identification of the analyte is acceptable; the reported value may be biased low. The actual value is expected to be greaterthan the repotted varae.
U Not Detected
tfR Not Reported
6OOO ?4
Report Name: E2J2801
Page 20 of 20
IITRINT RESEARCH INSTITUTE
IIT Research Institute ESAT Region 5
536 South Clark Street, Suite 734; Chicago, IL 606O5Telephone (312) 353-8302 Facsimile (312) 353-8307
Superfund, US EPA Region 577 West Jackson BoulevardChicago IL, 60604
ProjecfcHegeler ZincProject Number: [none]
Project ManagenHoward PhamReported:
Nov-19-02 16:22
ANALYTICAL REPORT FOR SAMPLES
Sample ID
2003ZG02S02
2003ZG02S04
2003ZG02S08
2003ZG02S10
2003ZG02S12
2003ZG02D14
Ui03ZG02S20
Laboratory ID
E2J2801-02
E2J2801-04
E2J2801-09
E2J2801-11
E2J2801-13
E2J2801-16
E2J2801-22
Matrix
Soil
Soil
Soil
Soil
Soil
Soil
Soil
Date Sampled
Oct-23-02 10:35
Oct-23-02 10:35
Oct-23-02 13:37
Oct-23-02 14:35
Oct-24-02 08:35
Oct-24-02 08:52
Oct-24-02 09:52
Date Received |
Oct-28-02 12:03
Oct-28-02 12:03
Oct-28-02 12:03
Oct-28-02 12:03
Oct-28-02 12:03
Oct-28-02 12:03
Oct-28-02 12:03
Kicnara ung, unemistReport Name: E2J2801
Page 1 of9
IITRII IT
Tctophmw (312) 3534302
irrSvperted. US EPA Repoa 5 Project Hegekr Zinc77 WatJ*ckmBoiilcv»d Project Number [noi ] Reported:
Project KtengerHowvd Pham Nov-19-02 16:22
Saapted: Oct-234R 10:35Received: Oct-28-02 12:03
TCLTMctebbyKT
Ftap/ ReponiBgQnlifim MDL LkM (j, DOotioa Batch Pftpwed Ai^yzed
Z73 60.0 200 ug/L 10 EK20403 NwMH-02 Nov-15-02
S42 3.00 900
« . 7 3 4 0 1 0 0 . . . .
U 3 0 0 9.00 • • • • •
15» 25.0 r.O ' • • • t •
U 73.0 2 5 0 • * • • •U 5 0 0 1 7 0 . . . .
// -bfe-O3- Report Name: E2J2801Page 2 of 9
IITRII IT RESEARCH INSTITUTE
IIT Research Institute ESAT Region 5
536 South Clark Stravt, Suit* 734; Chicago, IL 60605T«l0phon« (312) 353-8302 Facsimile (312) 3534307
Superfund, US EPA Region 577 West Jackson BoulevardChicago IL, 60604
Project:Hegeler Zinc
Project Number: [none]Project ManagerHoward Pham
Reported:
Nov-19-02 16:22
TCLP Metals by ICP
2003ZG02S04E2J2801-04(Soil)
Sampled: Oct-23-02 10:35Received: Oct-28-02 12:03
\nalyte ResultFlags /
QualifiersReporting
Limit Units Dilution Batch Prepared Analyzed
Arsenic
Barium
Cadmium
omium
Fad
Selenium
Silver
281
782
21.1
U
5790
96.8
U
J.K
60.0
3.00
3.40
3.00
25.0
73.0
5.00
200
9.00
10.0
9.00
87.0
250
17.0
ug/L 10 EK20403 Nov-04-02 Nov-15-02
Kicnaro Dug,Report Name: E2J2801
Page 3 of9
IITRI 536 South iT»l«p*ion« (312) 353-MCtt tasMto (312) 353-8307
IIT nwin
Suptrfupd. US EPA Region 5 PnqecL-Hegder ZincrrWotJadcniBoiifevwd Project Nvober [none] Reported
Project MvueerHowvd Pham Nov-19-02
2M3ZG02S68E2J2Wl-4»(SoiI)
Suipled: Oct-23-4>2 13:37Received: Oct-2»-02 12:03
TCLTMrtahbyiCF
FUp/ ReponiagMDL Limd Units DibtiaB Bacfc Prepared Aiutyzed
U 60.0 200 ug/L 10 EK20403 Now-04-02 Nov-15-022 2 4 3.00 9.00 . . . .
I M 3.40 1 0 0 . . . .
U 3.00 900
317 25.0 »70
U 730 250
U S.OO 1 7 0 . . . .
000300Report Name: E2J2801
Page 4 of9
IITRIIIT RESEARCH INSTITUTE
NT Research Institute ESAT Region 5
536 South Clark Street, Suite 734; Chicago, IL 60605Telephone (312) 3534302 Facsimile (312) 3534307
Superfund, US EPA Region 577 West Jackson BoulevardChicago IL, 60604
ProjectHegeler ZincProject Number: [none]Project ManagerHoward Pham
Reported:
Nov-19-02 16:22
TCLP Metals by ICP
2003ZG02S10
E2J2801-ll(Soil)
Sampled: Oct-23-02 14:35Received: Oct-28-02 12:03
\nalyte Result
Flags/Qualifiers MDL
Reporting
Limit Units Dilution Batch Prepared Analyzed
Arsenic
Barium
Cadmium
Lead
Selenium
Silver
394
884
121
U
30.1
V
V
60.0
3.00
3.40
3.00
25.0
73.0
5.00
200
9.00
10.0
9.00
87.0
250
17.0
ug/L 10 EK20403 Nov-04-02 Nov-15-02
OOOJ01
Kicnara uiig, unemisrReport Name: E2J2801
Page 5 of9
IITRI IITR<
irrSvpofuadLUSEPARcgioaS PrcjeccHegder Zinc77 We* Jadaoa BoafcvMd Project Nwnber|w»el Reported:
Project MMt crHowvd Pham Nov-19-02 16:22
2M3ZGt2S12E2J2Ml-13(Soil)
1: Oct-24-02 08:35
Received: Ort-2»-«2 12:03
TCLTMctabbrlCr
Q-««« MDL L-a
MJ J 600 200 ug/L 10 EK20403 Nov-04-02 Nov-15-02
2 4 t 3.00 9.00 • • • " •
14J 3.40 100 . . . .
U 3.00 9.00 . . . .
U 250 17.0
U 73.0 2 5 0 • • ' • •
U 5.00 17.0 . . . .
o
Report Name: E2J2801
Page 6 of9
IITRIIIT RESEARCH INSTITUTE
IIT Research Institute ESAT Region 5536 South Clark Street, Suite 734; Chicago, IL 60605Telephone (312) 353-8302 Facsimile (312) 353-8307
Supcrfund, US EPA Region 577 West Jackson BoulevardChicago IL, 60604
Projecf-Hegeler Zinc
Project Number: [none]Project ManagerHoward Pham
Reported:
Nov-19-02 16:22
TCLP Metals by ICP
2003ZG02D14E2J2801-16(Soil)
Sampled: Oct-24-02 08:52Received: Oct-28-02 12:03
\nalyte ResultFlags/
Qualifiers MDLReporting
Limit Units Dilution Batch Prepared Analyzed
Arsenic
Barium
Cadmium
ead
Selenium
Silver
353
545
3<U
U
U
U
U
60.0
3.00
3.40
3.00
25.0
73.0
5.00
200
9.00
10.0
9.00
87.0
250
17.0
ug/L 10 EK20403 Nov-04-02 Nov-15-02
-o> >-Kicnara uug, unemist
Report Name: E2J2801Page 7 of9
IITRIIfT RESEARCH
SupofiBd. US EPA Region 577 Weal Jadaon BoulevardOucagoIL, 60604
Project Hegder Zinc
Project Number[n«K]Project fcta^erHoward Pham Nov-19-02 16:22
2M3ZG02S20E2J2Ml-22(SoiI)
ipfcd: Oct-14-«2 09:52Received: Oet-2S-0112:03
TCLTMcttlibylCr
QariifirnReponmg
Units
u543
U
SBrtrU
U
60.0
300
340
300250
730500
200
9.00
10.0
900
«70
250
17.0
10 EK20403 Nor-04-02 Nov-lS-02
Report Name: E2J2801
Page 8 of 9
IITRIIIT Research Institute ESAT Region 5
536 South Clark Straot, Suit* 734; Chicago, IL 60605Talophon* (312) 3534302 Facsimile (312) 353-8307
IIT RESEARCH INSTITUTE
Superfund, US EPA Region S Project:Hegeler Zinc77 West Jackson Boulevard Project Number: [none] Reported:Chicago IL, 60604 Project ManagcrHoward Pham Nov-19-02 16:22
Notes and Definitions
J The identification of the analyte is acceptable; the reported value is an estimate.
K The identification of the analyte is acceptable; the reported value may be biased high. The actual value is expected to be less thanthe reported value.
U Not Detected
NR Not Reported
.--TV
-O 3_ Report Name: E2J2801Kicnara uug, cemist p 9 of 9