uL OF ug/mLFile >37226 35.0-458.8 a»u. WESTON R711843-89B 35-318318 IH=1 .8 DRH 01 ^^ftftft-V-_>-iWWO(T^u 388808-280080--268888-240888-228080-280088-1 80000-

SAMPLE WORKSHEET FOR SEMIVOLATILES

CONTRACT NAME Weston LaboratorieaCONTRACT NUMBER 325-001-01-01______RADIAN CONTACT Rob Richardson_____

SAMPLE DESCRIPTIONSAMPLE NO. (SAM) A711043-08A ANALYTEfSl Q&] 8270 [_] TCLP

[_] OTHER _______

SAMPLE TYPE [_] AQUEOUS [£XJ SOLID [_J ORG LIQ & SORBENT[_] OTHER

SAMPLE IDENTIFIER 6584____________________ COMMENTS

SAMPLE PREPARATIONEXTRACTION METHOD [_] 3510 SEPFUN [_] 3520 CONTIN [XX] 3540 SOXHLET

[_] 3550 SONICA [_] 3580 DILUTION[_] OTHER _______________________________________

SAMPLE SIZE I0'!>3 cms DATE EXTRACTED______ mL ANALYST

SURROGATE SPIKING /eo uL OF ______ug/mL SP-S-035_____uL OF ______ug/mL ______

OTHER SPIKING ____uL OF ______ug/mL____UL OF ______ug/mL

EXTR. SOLVENT [XXJCH2CL2 [_]OTHER ________FINAL SOLVENT [ ]CH2CL2 [_]OTHER ________

FINAL CONCENTRATE VOLUME I.O mL VOLUME DELIVERED /•«>

CLEANUP PROCEDURE _____________________________________________VOLUME CLEANED ___ mL FINAL VOLUME ___ mL VOLUME DELIVERED _______ mLCOMMENT ___________________________________________________

DATE SUBMITTED ti/ftfifl SUBMITTED BY X? RECEIVED BY /Hi *

SAMPLE ANALYSIS

FRN 3 2/ DATE INJECTED >DCCg» ANALYST M6< _________________SAMPLE DILUTION ______ mL DILUTED TO___ mL VOLUME INJECTEDINTERNAL STANDARD _______________________________________EXTRACTS CIS g/mL 50 OTHERCOMMENT: ______________________

Cppm » An x ug/mL IS - mL Extract x DF

RF mL sample size

IT/ *sr o"-K ClPfT =E^CRT

Lperator 1C: fGK Cuant Rev: 4 uuant Time'"utput File: A37226::E3 Injected atjta File: >37^6::£8 Cilution Factorname: WESTON P711043-09P

fisc: 35-310@10 IH-1.0 DAH 01CEC87ID File: ICFEI::JKTitle: ECPT SEiÎl/CLATILES FCR FEILast Calibration: S71201 -16:15

§71202 OB-'?S71201 20:12

.000

ompoundcan* rrea Cone

-, . w-w, u.i.r ccr'-t.r't-d'l !Q.i*J 776 57546 50.'JO FFf -.:7) 2-FLLCRCFHENCL SLRRCGPTE 7.65 420 300335 33.00 FFf -''-

;t) Ff-ENCL-d5 SLRRCGPTE 9.52 6SO 323428 56.18 FFf '--30) *iNPFhTi-PLENE-a8 13.50 : ;(Z3 201575 50.00 FFf" •-:32) MTRCEENZEr€-d5 SLRRCGPTE 1 1 . 7 1 956 156202 !01.96 FFf55) *PCENPFHTHENE-d10 !S.!2 1S02 94565' 50.00 FF.61) 2-FLLCRCEIFf-EhYL SLRRCGPTE 16.36 1570 231026 51.91 FFf" •/.;88) 2,4,6-TRIERCK.FhEM:L SLRRCGPTE 20.21 2078 67591 68.27 FFf! >-589) *FHENP.NTHREhE-a10 21.99 2311 147192 SQ.OOFFfi 91-104) -CHRYSENE-d12 29.06 3236 69852 50.00 PPM 97105) TERFhENYL-d14 SLRRCGPTE 26.18 2861 156257 80.86 PPM 100118) *PERYLENE-d12 34.58 3955 62777 50.00 PPM 100* Compound is ISTD

aRI03065

File >37226 35.0-458.8 a»u. WESTON R711843-89B 35-318318 IH=1 .8 DRH 01^^ftftft-V-u_>-iWWO(T^

388808-

280080--

268888-

240888-

228080-

280088-

1 80000-

160008-

140888-

128800-

108000-,

80000-

68000-

40000-.

20008-a_

(-* w .

titt•it,•w_?klJ

* w .r i *> ' v >"* V - I « «

L ' i f- *; • f » . * ' ' v " J * •« "u » < • J * ~*-^ rJi i ? ;« » < ••i •? <

JJiH-JHW1

• * -' s J- Tj

1

> ~* *"

J-100

-QO?O

r®0

r i- > » -»j i r .'< + ^{* 4

,

" i

J

S4J•u

X

/r

* vi< .«>•1•* I"1

bita*T r

4*•**<V

fb

JjL 1**™**k- — *• ' -" ' ' ' *• •w*m

-60

«8

•40

-30

-29

-10

1<><r* i • i ' i • i • i • i ' i • i ' r • i • i • i ' i ' i ' I ' i • i • r ' i ' i ' i • i ' i w8 12 16 28 24 28 32 36 48 44 48

01 »«c f7

RR103066


CONTRACT NAME Weaton LaboratoriesCONTRACT NUMBER 325-001-01-01______RADIAN CONTACT Rob Richardson____

SAMPLE DESCRIPTIONSAMPLE NO. (SAM) A711043-09A ANALYTEfSl [£XJ 8270 [_J TCLP

C_j OTHER _______

SAMPLE TYPE [__] AQUEOUS [£XJ SOLID [__] ORG LIQ [SO SORBENT[_] OTHER

SAMPLE IDENTIFIER 6585______________________ COMMENTS

SAMPLE PREPARATIONEXTRACTION METHOD [_] 3510 SEPFUN [_] 3520 CONTIN [Xj_] 3540 SOXHLET

C_] 3550 SONICA [_] 3580 DILUTION[_] OTHER ___________________________________

SAMPLE SIZE /g'37 eras DATE EXTRACTED_______ mL ANALYST &£- ' '

SURROGATE SPIKING >*o uL OF ______ug/mL SP-S-035____UL OF ______ug/mL _______

OTHER SPIKING ____uL OF ______ug/mL___uL OF ______ug/mL

EXTR. SOLVENT [2Q[]CH2CL2 [_]OTHER ________FINAL SOLVENT t___]CH2CL2 [_] OTHER ________

FINAL CONCENTRATE VOLUME AO mL VOLUME DELIVERED /

CLEANUP PROCEDURE _____________________________________________VOLUME CLEANED mL FINAL VOLUME ___mL VOLUME DELIVERED _______mLCOMMENT ______________________________________________________

DATE SUBMITTED llf/lW SUBMITTED BY K RECEIVED BY /VtC?

SAMPLE ANALYSIS

FRN > >~>m DATE INJECTED °> »•« '> ANALYSTSAMPLE DILUTION _______ mL DILUTED TO___ mL VOLUME INJECTEDINTERNAL STANDARD ro /. j._____________________________________EXTRACTS CIS/ug/mL 50 OTHERCOMMENT: _______________________

Cppm » An x ug/mL IS * mL Extract x DFRF mL sample size

CREP,A37211CLflM REFCRT

erator ID: MCK .- Cuant Rev: 4 Cuant Time: 871202 11:58lutput File: A37211::E3 Injected at: 871123 16:41Data File: >37211::E1 Dilution Factor: 1.000Name: WESTUN A711043-RBMisc: 35-310@10,IH=1.0,35-450amu/.43S 30m DE-5 PCK 23NCV87

ID File: IDPEI: : JK ..... . ~_Title: EDPT SEMIVCLATILES FOR FEILast Calibration: S71201 16:15

Compound K.T. Scan* Prea Cone Lnits a

I) *1,4-CIChLCRCEEh'ZENE-d4 10.64^ 742 47922 50.00 PPM v47) 2-FLLCRCFhENCL SLRRCGPTE 7.90: 378 245659 81.52 FPW C2

11) FHENCL-d5 SLRRCGPTE 9. S5 637 2K3S62 SO.86 PFF1 b1-30) *NPFHTHPLENE-d8 13.81 M61 163411 50.00 FPn '-}32) NITRCEEhZEhE-d5 SLRRCGPTE 12.01 S23 12S924 104.62 FPP1 G755) *PCEh'PPhTHEfNE-d10 . 18.43 1774 79659 50.00 PPfl 10061) 2-FLLGRCBIPHEHYL SURROGATE 16.64 1536 204244 85.99PPH 10088) 2,4,6-TRIERCMOPhEHCL SLRRCGPTE 20.52 2051 69323 107.50 PPM £689) *PHENAISTHRENE-d10 22.32 2289 153763 50.00 PPM 98104) *CHRYSEME-d12 29.42 3225 88430 50.00 PPM 9Q105) TERPHEhYL-d14 SURROGATE 26.51 2843 196911 80.49 PPM 100118) *PERYLENE-d12 35.15 3976 66033 50.00 PPM 100

• Compound is ISTD

38File >3?2W

368888-

328000-

288080-

248008--

208000-•

168880-

120000-

30000-

40888-

i

c

l l

• £' <z$&&> r535. 8-458. 8 a«u . UESTON fl?11843-RB 35-318010, IH=1 .8,35-458i u« Tr<r' "32 •»1 if^

1 V

3 II I Iv 01 ' *ITJ c

•i'2 4)

f 1 CO•d 2 "?5? C«:o 2t

-*

I

12

Z.

'4 l-i *" !_ * -2 T! 9 35 rJE " .*a.

P-

LJ _ .

•oriC1 =1" "?5 ii

i |28 ' 24 ' 28 ' 32 ' 36 'V0 ' ' UV ' Vs' '

>''

ftR!03069


CONTRACT NAME Western LaboratoriesCONTRACT NUMBER 325-001-01-01______RADIAN CONTACT Rob Richardson_____

SAMPLE DESCRIPTIONSAMPLE NO. (SAM) A711043-RB ANALYTE(S) [XX] 8270 [_] TCLP

[_] OTHER _______

SAMPLE TYPE [ _ ] AQUEOUS [ _ ] SOLID [ _ ] ORG LIQ [ _ ] SORBENTOTHER Soxhlet Method BLANK

SAMPLE IDENTIFIER none __________________ COMMENTS

SAMPLE PREPARATIONEXTRACTION METHOD [_] 3510 SEPFUN [_] 3520 CONTIN [XXJ 3540 SOXHLET

[_] 3550 SONICA [_] 3580 DILUTION[_] OTHER ________________________________________

SAMPLE SIZE ______gms DATE EXTRACTED______ mL ANALYST

SURROGATE SPIKING /»e> uL OF _______ug/mL SP-S-035___uL OF ______ug/mL _________

OTHER SPIKING ____uL OF _______ug/mL_____uL OF ______ug/mL

EXTR. SOLVENT [5Q_]CH2CL2 [_]OTHER ________FINAL SOLVENT [2&JCH2CL2 [_]OTHER ________

FINAL CONCENTRATE VOLUME /'<> mL VOLUME DELIVERED /

CLEANUP PROCEDUREVOLUME CLEANED ___^mL FINAL VOLUME ___^mL VOLUME DELIVEREDCOMMENT

DATE SUBMITTED /WJ07 SUBMITTED BY X fi RECEIVED BY/

SAMPLE ANALYSIS

> 3-7Z.// DATE INJECTED *3 *^ ?7 ANALYST /**<•____SAMPLE DILUTION ______ mL DILUTED TO ___ mL VOLUME INJECTEDINTERNAL STANDARDEXTRACTS CIS,ug/mL 50 OTHERCOMMENT:

Cppm » An x ug/mL IS - mL Extract x DF

RF mL sample size

ftRI03070

:CF.EP,A37230

CLPhT REFCRT

'-perator ID: FCK Cuant Rev: 4 Cuant Time: 871202 14:18Jtput File: A372JO::EJ Injected at: 871202 10:56jata File: >37230::E7 Dilution Factor: 1.00(1Name: USTN A711043-07B MSPise: 35-310610 IH=1.0 MCK 02DEC871C File: IDFEI::JKTitle: BCPT SEMIVCLPTILES FCR FEILast Calibration: S71201 16: '15

Compound £.7. Scan* Prea Cone Units 2

1) *l,4-CICH_CRCEENZENE-a4 10.27 759 5£~"lS6 So'fin =FM "^7) 2-t-LLCRCFhEKL SLRRCGPTE : .. 7.57 ^0" 2S449P 7? 4^ FFI" ^M) PrENCL-d5 SURROGATE 9.55 665 3573*7 ^2*56 FP^ ^12) Ff-EKL 9.57 667 24380 IP" 1 i S ! e § F « = r ' T'G17) 2-CK.CRCFi-EKL b.66 708 193988(1 118.07 FFM }Cnj19) 1 -DICHLCRCEENZEhE 10.30 763 90537 50.50FFP '-727) h-hllRCSCCI-n-FRLFYLPMINE 1 1 . 3 1 8£6 69887M 60.16PFM '-430) *NPFf-ThPLEiÊ-d8 13.43 1176 209857 50.00 PPM 9232) NITROBENZENE-CIS SURROGATE 11.62 938 166425 104.35 PPM 9642) 1,2,4-TRICHLORGBENZENE 13.32 1162 60185 47.92 PPM 9751) 4-CHLGRG-3-METHYLFHENCL 14.97 1380 149069 124.77 PPM 9455) *ACENAPHTHENE-d10 18.05 1786 98844 50.00 PPM 10061) 2-FLUCRCBIPHENYL SURROGATE 16.29 1554 252899 85.81 PPM 10071) ACENAPHTHENE 18.13 1797 128756 46.80 PPM 9073) 4-NITROPHENOL 18.60 1858 68220M 98.97 PPM 1005) 2,4-DINITROTGLUENE 18.61 1860 36967M 44.21 PPM A38) 2,4,6-TRIBROMGPHENGL SURROGATE 20.17 2064 68323 85.39 PPM ~89) *PHENANTHRENE-d10 21.92 2294 147883 50.00 PPM 9695) PENTAChLGROPHENOL 21.64 2257 33156M 112.68 PPM 9497) PHENANThRENE 21.98 2302 36952 11.99 PPM 94101) FLUORANTHENE 25.15 2715 122902 40.51 PPM 100103) PYRENE 25.74 2793 263044 82.64 PPM 100104) *ChRYSENE-d12 28.95 3208 79394 50.00 PPM 98105) TERPHENYL-d14 SURROGATE 26.10 2839 165238 75.23 PPM 100114) EENZ(a)ANTHRACENE 28.90 3202 68730M 23.39 PPM 94I 16) CHRYSENE 29.00 3215 54146M 21.10 PPM118) *PERYLENE-d12 34.23 3890 27697 50.00 PPM 100120) BENZO(b)FLLCRANTHENE 32.65 3686 108959M 126.78 PPM 84121) BENZG(k)FLUCRANTHENE 32.65 3686 106716M 138.78 PPM 84122) EENZG(a)PYRENE 34.04 3865 37933M 71.50 PPM 75* Compound is ISTD

File >3?230 35.8-450.8 a»u. «STH R711843-07B MS 35-318818 IH=1.8 HCK 82TIC

368896--108

-30

-28!• I F I II r""**"*"UL 11 1J I lkir Wu Hi

49989- ,

i

r-58

8 12 16 28 24 28 32 36 40 44 48

»7

flR1030?2


CONTRACT NAME Weston LaboratoriesCONTRACT NUMBER 325-001-01-01______RADIAN CONTACT Rob Richardson_____

SAMPLE DESCRIPTIONSAMPLE NO. (SAM) A711043-07B ANALYTE(S1 [XX] 8270 [_J TCLP

[_] OTHER ________

SAMPLE TYPE [_] AQUEOUS [XX] SOLID [_] ORG LIQ [_] SORBENT[_] OTHER

SAMPLE IDENTIFIER 6583 ________ __________ COMMENTS

SAMPLE PREPARATIONEXTRACTION METHOD [ _ ] 3510 SEPFUN [ _ ] 3520 CONTIN [XX] 3540 SOXHLET

[ _ ] 3550 SONICA [ _ ] 3580 DILUTION[ _ ] OTHER ________________________________________

SAMPLE SIZE /?•?</• cms DATE EXTRACTED_______ mL ANALYST ££.

SURROGATE SPIKING /&& uL OF _______ug/mL SP-S-035___uL OF ______ug/mL _______

OTHER SPIKING ite> UL OF _______ug/mL_____uL OF ______ug/mL

EXTR. SOLVENT [XX]CH2CL2 [_]OTHER ________FINAL SOLVENT ( _]CH2CL2 [_] OTHER __________

FINAL CONCENTRATE VOLUME t.O aL VOLUME DELIVERED />P _______ mL

CLEANUP PROCEDURE _____________________________________________VOLUME CLEANED ___ nL FINAL VOLUME ___ mL VOLUME DELIVEREDCOMMENT

DATE SUBMITTED WlW SUBMITTED BY RECEIVED BY MC~~t/ ——————

SAMPLE ANALYSIS

FRN '311*9 DATE INJECTED <••*«» ANALYST ____________SAMPLE DILUTION ______ mL DILUTED TO___ mL VOLUME INJECTEDINTERNAL STANDARD ______________________________________EXTRACTS CIS,ug/mL 50 OTHERCOMMENT: _____________________

Cppm » An x ug/mL IS - mL Extract x DFRF mL sample size

103013

: p A -q 7 o i c

CLPNT REFCRT

jrator 1C: PICK . •' Cuant Rev: 4 Cuant Time: 871202 10:54I jtput File: A37229::E3 _ Iniected at: 871202 10:02rCata File: >37229::E7 Dilution Factor: 1.000Name: USTN P711043-07C PSDPlisc: 35-310610 IH-1.0 PICK 02CEC87

ID File: ICFEI: : jKTitle: ECPT SEMI'vCLPTILES FCR FEILast Calibration: £71201 16:15

C a m p o u n d P . T . Scan* P r e a C o n c L n 1 1 s

1) *1 ,4-DIChLCRCEENZENE-d4 1Q.50 = 767 60°2". 50.00 FFf* '-"-67) 2-FLLCRCFf-EKL SLRRCGPTE 7.58 : 409 259602 57.7C FFP1 ;:c

11) FhENCL-d5 SLFRCGPTE 9.55 : 668 323929P 81.52 FFf1 'rt12) FK-ENCL _ £.59 673 222908 105.42 FFf1 10017) 2-OLCkCF^-ENCL 9.90 - 714 131018 107.04 FFf* 10019) 1 ,4-GIOLLRCbENZENE 10.34 . 772 S7209 47.25FFM 9927) N-MTRCSCDI-n-FKCPYLPMINE 11.34 904 65242 54.57 PPM 9730) *NPPhTHPLENE-d8 13.44 1181 205312 50.00 PPM 9332) NITRCEENZENE-d5 SURRCGPTE 11.66 946 153943 98.66 PPM 9742) 1,2,4-TRICHLCRCBENZENE 13.35 1168 57254M 46.60 PPM51) 4-CHLGRG-3-METHYLPHENGL 15.00 1386 133762 114.44 PPM S355) *P.CENPFhTHENE-d10 18.08 1793 96242 50.00 PPM 10061) 2-FLUCRCBIPhENYL SURROGATE 16.31 1560 232830 81.13 PPT1 100) PCENP.PHTHENE 18.16 1803 117500 43.86 PPM 96

j) 4-NITRGPHENGL 13,58 1859 63709M 94.92 PPM 10075) 2,4-DINITRQTCLUENE 18.61 1863 33496M 41.14 PPM88) 2,4,6-TRIERGMGPHENOL SURROGATE 20.18 2069 39277 50.41 PPM 9839) *PHENPNTHRENE-d10 21.94 2301 151484 50.00 PPM 9995) PENTPCHLCRGPHENCL 21.65 2262 32763M 108.69 PPM 91101) FLUGRPNTHENE 25.16 2722 47525 15.29 PPM 100103) PYRENE 25.75 2799 177854 54.55 PPM 100104) *CHRYSENE-d12 28.94 3213 77457 50.00 PPM 96105) TERPHENYL-d14 SLRRQGP.TE 26.11 2846 158409 73.93 PPM 100118) *PERYLENE-d12 34.22 3895 22525 50.00 PPM 100120) EENZG(b)FLUCRPNTKENE 32.67 3695 47244M 67.59 PPM 79121) EENZG(k)FLLORPNThENE 32.67 3695 47130M 75.37 PPM 81122) EENZC(a)PYRENE 34.05 3873 12408M 31.08FFM 68

* Compound is ISTD

288898-

268899-

248888-

228888-

288888-) _i| i|- v v| , ... • F-78

129888-

68888-

48888-

28888-

9-

rT

; t

teeeee-l388884 i ii .I i i i i i I /) U . (I i ip, ,r38

UJ

1-68188008-j

168888-J

1488894 I I! I ] I I I :. f | ! V (-58

1-188

H98

* f V '

f !/ JMe

h2B

32 36 48 44

0_ »«c «7 ;o.i-r

f Mi.


CONTRACT NAME Western LaboratoriesCONTRACT NUMBER 325-001-01-01______RADIAN CONTACT Rob Richardson_____

SAMPLE DESCRIPTIONSAMPLE NO. (SAM) A711043-07C ANALYTEfSl [&_] 8270 [_] TCLP

[_] OTHER _______

SAMPLE TYPE [_] AQUEOUS [Xj_] SOLID [_] ORG LIQ [_] SORBENT[_] OTHER

SAMPLE IDENTIFIER 6583________________________ COMMENTS ______________________________Matrix Spike Duplicate_________________________

SAMPLE PREPARATIONEXTRACTION METHOD [_J 3510 SEPFUN [_] 3520 CONTIN [XX3 3540 SOXHLET

C_] 3550 SONICA [_] 3580 DILUTION[_] OTHER __________________________________

SAMPLE SIZE fO'll mna DATE EXTRACTED______ mL ANALYST

SURROGATE SPIKING __/_____UL OF _______ug/mL SP-S-035_uL OF _________ug/mL _

OTHER SPIKING /0» uL OF ______ug/mL SP-ifl«-061___uL OF _____ug/mL ______

EXTR. SOLVENT [XXJCH2CL2 [_]OTHER _______________________________FINAL SOLVENT [_£.]CH2CL2 [_] OTHER _____________________________

FINAL CONCENTRATE VOLUME //<9 mL VOLUME DELIVERED /'&______mL

CLEANUP PROCEDURE _____________________________________________VOLUME CLEANED ___^mL FINAL VOLUME ___^mL VOLUME DELIVERED _______mLCOMMENT ______________________________________________________

DATE SUBMITTED II//W7 SUBMITTED BY A' RECEIVED BYr/ ——————

SAMPLE ANALYSIS

FRN JT+UI DATE INJECTED ZJ6C8* ANALYSTSAMPLE DILUTION _______ mL DILUTED TO___ mL VOLUME INJECTEDINTERNAL STANDARD _____________________________________EXTRACTS CIS,ug/mL 50 OTHERCOMMENT: ______________________


HRi03Q?6

COMHOKATION

?CB LAB NOTES

RR103077

Project No.Book No.

13<# fil/f^9-C^^ //£>&$ U L

od by me, Date [lnv^dibS30781 D^--.-J- J U..

____l°"* **^1 \ \'<r

To Page No.

ProjectBook No.

From Page No._

*. ; _ c

ProUetloo AgmcyEnvlronMnUl Hont Wring and Support L*0or«tory - Cincinnati

WATER POUUTION QUALITY CONTROL SAWIES

TRUE VALUESPCBs,

untn diluted to VO!UM according to Instructions, tht SNplcs contain thtfollowing co— lounds *t conctntratlons cxprttMd as tig/ It Mr. Tht Man rwovtry(7) and the standard deviation (S) art listed below along with the true valueand the 95X confidence Interval (C.I.). The true value represents the actualwlghlng and all subsequent dilutions. The 95» confidence Interval representsthe wan recovery plus or Minus two standard deviations (7 * 25) and «tsdeveloped fro* regression equations fro* Performance Evaluation Studies.

Aroclor No. Si-ile True Value T S 95* C.I.1016

1221

1232

1242

1248

1254

1234

56

78910

1711

5.251.317.201.26

4.281.43

6.301.89

8.103.51

5.40!.«»

4.571.14

6.261.10

3.721.24

5.481.64

7.053.05

4.701.41

1.260.31

1.730.30

1.030.34

1.510.451.940.84

1.300.39

2.05 -0.52 -

2.80 -0.50 -

1.66 -0.56 -

2.46 -0.74 -

3.17 -1.37 -

2.10 -0.63 -

7.091.76

9.721.70

5.781.92

8.502.54

10.94.73

7.302.19

1262 15 9.20 8.00 2.21 3.S8 - 12.416 2.76 2.40 0.66 1.08 - 3.72

HP679/783

JJ To Page No..

Witot«ted & Understood by me, 1 Date Invented bf,?*i R103079 Date 1. . - 94 1

Project No._____ Book No.____ 37

jFrom Page No..

'• €-e-« <Z- c-»_

/ L/-MJL,/•>KJ

ll*Ji

/Wf L,/n L

£,(.."71. ;' JO/D /WJL

UG % ^^" / <JC

/oocJi^

' ' "V '

- &-*_ * <v/ &C*£v * «Ju - ue.-d.fL ^ —' I&—— 62 - x f) i cAaj /" £Md!lc~r

To Page No.

'n»od & Understood by me, j Date j Invented bfi R f Q 3 Q B Q I Da.te e -

3 isProject No.

________ Book No.

From Page No. —

R _

•firf. ^ _" (J

gj» »9,

To Page No..Witnessed & Understood by me. JDate Invented gypHT iU0308I Date . 1

// -,v--*7 1

from Page No._

—— «• -K*t fjt.t.J

064

k«f«

r \UZ

t-HL

01*

fcStjr

it.?,

H«l

& Understood by me,

Project No.Book NoFrom Page No._

. 777 S _,- -no pe

A 1//*«*- c/J

& Understood by me.

Project No.____r[ p iAS** . ht Ji S^^Xg._____________ Book No.____ 45

From Page No._ L. # W A~~yt£a. 4 f//6 <f-*—oV.<!_jbJ-

Wi»nessed & Understood by me, J Date jlnve t a VQ 3 0 8

'02.Project No-

-LE___KJ&&&OT'.> 3o~J a—7<-&*o /g/3 &//• Book No..

From Page No._

*t"5«iQ

tf.f

Ql* i uf- \ o*.* \ *tta \ **o I . . - i -- i . i _

71-I.Z 77,01'.

L.'»±».».

?.li f.

ft \fr**-t+n£ *

To Page No.Witnessed & Understood by me, | Date (invented by" |Date

5.197

ftRi0308652.172

STOP

5.2U(.234

52.2*

STOP

RUMt 412 Hoy 23> j

SflKPtEl 2MEM

I f] 1 -'16-234 263 Si ' E -5856513.592 ^ S :\H 6;37-'37566

23.24426.645 .„„ ™

5.415744.35588flRI03087 "•"•-_ »« L«

RUM 414 m 23,

-

5.1J6

9.434

52.22152.89S

STOP

t.m

54.194

STOP

4t

:13

7.911

11.15?

2.225

52.341103090 53.295

RUN , 417 NOV 23, 1987 22:25:54START

2,223

ft-R 10309STOP

48.36849.19?9.99858.595,51.2375J:8tt52.925

Ml

HOV 23' 1987 23:24:

2.599 2.4t4lW

'4.3155.886

6.236

103092 52-825

9e:23!"4.289

RR103093CTftO

2.241

9.581

,11.52412.138

13.415

52.735

CFTFPCE.V

N EIG

>37202 Scan *• pcocod êin. tima. <2 cc:!:!_ f-:_ _m/z rnt..55 ~5~17 pr«~"—r: .::-—-—— -:i:_"nt- m/2 int.- m/z int. m/2

•-.595 p? gj-g? '.5013505 ^ T l ' n q ^ 6.17273.05 I??i IIII It III iIII 111 |1.11:i iil isii JIB a«l•'•• ai m «ii B tf -a is IB

SR103095

File >37202 BFTPPXpk HD 14133

15888-

i4aaa-13880-

12909-

11008-

18880-

3888-

7000-

6888-

5888-

4888-

3800-

2008-

1888-

8-

69

L

77/

i

DEHO 35-275928, IH=8. 8, 35-458a»u/'. 4 . Scan 653i df • 9fe "îlb

198

/127\

LlL58 180

.jT*

"\

1 ,ki2

1 1 1150 200 250

L

Mflfl

442

\.

?5

296

( / .k 1. , 1 i . . 1 I 1. . . . , . . r . | . • • ' | --.-| -..-, ..--| ...

388 358 400

r88r79

'•*&

-38

-20

r18•0

17202 DFTPP DEflG 35-275020,IH=0.0,35-450amu/.43S 30m DB-5

658 NRM BIG oit*-

File: >37202 Scan*: 658 Retn. time: 12.95

m/z Int. m/z Int. m/z Int. m/z Int. m/z Int.

38.95 5.17 84.95 .93 128.95 23.95 198.00 100.00 265.15 1.5449.95 16.63 85.95 1.61 129.95 1.85 199.00 6.17 273.05 1.9450.95 57.15 91.05 1.50 135.05 2.11 203.15 1.10 274.05 3.8055.95 1.97 92.95 5.75 140.95 3.00 204.15 3.67 275.05 19.9156.95 5.75 97.95 5.30 147.05 1.92 205.00 4.00 275.95 2.9263.00 2.22 98.95 3.69 148.05 2.85 206.15 20.73 276.95 1.5165.00 1.41 101.05 2.97 155.00 1.32 207.15 5.55 281.20 1.6368.00 1.14 104.00 1.64 161.15 1.27 208.15 1.25 283.05 .9168.90 74.12 105.00 1.33 167.15 3.95 211.00 .88 296.00 4.5673.00 2.35 107.00 14.13 168.15 1.44 217.15 5.86 297.00 .9774.00 6.67 108.00 2.26 174.05 1.08 221.05 7.25 314.95 .8675.00 10.29 110.00 30.55 175.05 1.38 223.05 1.81 323.05 2.1976.00 3.10 111.00 5.43 178.95 3.27 224.05 11.40 334.20 1.2777.00 61.52 116.00 1.15 180.05 2.39 225.05 2.26 364.95 2.92

.15 4.56 117.00 11.48 181.05 1.22 227.05 5.20 372.05 1.33,d.OO 4.44118.00 1.00185.05 1.07244.00 10.05423.05 4.02.00 2.48 122.00 1.14 186.05 10.72 245.15 1.25 441.00 11.66i.95 3.93123.00 1.34187.05 3.44255.00 44.68442.00- 78.50

81.95 1.31 127.15 51.11 193.20 1.44256.15 5.89443.00' 13.4682.95 1.32 127.95 3.79 196.05 3.08 258.15 3.16 444.00 1.50

HR103096

DFTPP FOR DECEhSER 1, 1937

GC/MS PERFORMANCE STANDARD

Decaf1uorotripheny1phosphi ne

INSTRUMENT ID ___£___ DATE " ''' i '* /MCK TIME

R£PORT NO. <________ ANALYST

TUNE CHECK:

m/e

51

63

69

70

127

197

198

199

275

365

441

442

443

Ion Abundance Criteria

30 - 605 of mass 198

less than 25 of mass 69

mass 69 relative abundance


40 - 605 of mass 198


base oeak, 1005 relative abundance5 - 95 of mass 198

10 - 305 of mass 198

oreater than 15 of mass 198

less 'than mass 443

greater than 405 of mass 198

17 - 235 of mass 442

5 Relative Abundance

, '

' f / •/ )1

/

\-s ( )1V 2-

- 7>

/CO

7

/S

2-

s;- 1

•> Uo)2

lvalue in parenthesis is 5 mass 69.2?'alue in parenthesis is 5 mass 442.

Comments:

QC Form QkQ9

8270 STDS PENTPCHLGRCPhEhOL BENZIDIhE 4-4'-DOTFil* >3721'

,

;

:'T

1

f

1

5 265.5-266.!

;11

s _

2.8 13

F»*B.>,

f

•,'

;i!

ii

j.a 14.

37215 133.7-134.;

iij

I,

ii

5 15.3 15.5 IT

'Fi.«

1

;if1

.

(

t.>37215 234.7-235.7

1;

(

f1

\ ^ \03099is. a i?.a 28

GC./rS FERFCRfPKE STPhCPRCDecafluorotriphenyIphospme (CFTPP)

'/. Relative AbundanceIon Abundance Ease Pppropnate

m/z Criteria Peak Peak Status

51 30-60% of mass 198 - - 51 . 54 5' . 14 Ck68 Less tnen 2% of mass £9 1.00 '.^ LI>69 (reference only) 69. H 69. :4 Ck70 L e s s then 2 7. o f ir. a s s 69 U . 0 0 0 . 0 0 C \127 40-60% of mass !98 5;.£4 51.34 Ck197 Less then 1% of irass 198 . 0.00 0.00 C>'98 case peak, 100% relative abundance ! 00.00 100.00 C*'199 5-9% of mass ''96 P..'"-'! £.9" C>275 10-30% of mass 198 :>"-. 06 lb.'36 •>365 Greater- then '}'/. of irass "9E 1.95 1.95. Ci441 Less then mass 443 8.38 89.52 Lk442 Greater then 40% of rr.ass 198 50.96 50.96 Ck443 17-23% of mass 442 9.36 18.36 Ck

Injection Gate: 12/01/87Injection Time: 09:11

Cata File: >37215Scan: 594

<-RGFILE ~'-'C.

I _''-' -

7215 DFTPP CEfO 35-275020 IH-0.0 35-450amu 30m DBS NCK594 NRf^ BIG

File: >37215 Scan *: 594 Retn. time: 12.46

m/z Int. m/z Int. m/z Int. m/z Int. m/z Int.

38.95 4.44 81.00 4.37129.15 21.71 180.95 1.04227.05 4.5643.95 3.14 85.05 .88 130.05 1.32 185.05 1.69 244.20 9.4748.95 .98 85.95 1.44 134.05 1.08 186.05 13.22 245.20 1.5349.95 10.93 90.95 1.10 135.05 2.36 187.05 3.01 255.15 42.5150.95 48.43 93.05 5.60 141.05 2.77 192.20 1.09 256.15 5.5852.05 2.60 98.05 3.41 147.05 1.73193.20 1.26258.15 2.1855.95 1.52 99.05 3.45 148.20 2.44 196.20 3.01 273.05 1.8856.95 4.27 101.05 2.32 149.05 .94 19S.05 100.00 274.05 3.2463,00 2.30 -103.05 1,00 155.15 1.31 199.05 5.89 275.05 16.1465.00 1.31 104.95 1.33 156.15 1.81 204.15 2.89 276.05 2.6468.15 .96 107.00 14.17 161.15 1.08 205.15 4.95 277.05 1.8369.00 66.89 108.00 1.81 165.00 1.18 206.1741 sim !i f II mi i$"I *II! fill i|i '«?! :i» i:«IS:« 1:BIB:8 j| IS ll i| -f|

flRI03100

UkOS

!NST » 1: 59850 TYPE: 5987 DRTE : 12/91x87 3:17

s R*p.i Fes DO EEGY ELKS XRfiY EMV Gain Gfst Intq290 5'.3 31 24.5 73 85 115 2031 112 56 53___ = MflSS 69. fiBUNDRNCE 170419 flT REPELLER = 5.25———— - MflSS 219. ftBUNDRHCE 93125 flT REPELLER - 6.86Cll_ s HPSS 502. aBUMDRNCE 4398 ftT REPELLER = 9.25

./ / x

4 5 6 7 3 9 18 U 12

R E P E L L E R ( V )

PROFILE SCflM v*r S53&27

IHST

Emission Cufl)Repeller (V)Ion Focus IV)Draw Out (V)

IONS

El Energy (eV)Ent Lens (»V)X - RayEM Volts (V)

OffsetGain

Mass Offset

218 228 222 STBfl 592 584REL. OBUHD FWHM\vISO FwH190.98- .569 N.. 5 6 941.95 .648 >^18

592.89 , 1432.. 1.17 .'518 .418

ftR!03SOI

File..>37227 UFTPP DEMO————^________________— "- -5-27S « 1H=«.8 «(_K W2DECS7————?———————-*ican 593Hb \i9&«4 1274 'a

198

\

i f30275 I T

296 ii.A/ 323 ,^r i r/ / 365 403 I!,._ ; i . ... l. f i l.^

h68

fe0

se

593 NRM BIG ° 35-275 20 IH-0.0 MCK 02DEC87

l.: >37227 Scan »: 593 Retn. tlme; ,2

* Int- -/« mt. B/I Int«5 8 oo a7 7 0

I Ii II II! II i«i II III 1 II IRRI03I02

INITIAL CALIBRATION

RR103I03

Calibration Report

Title: PEI fiPP.IX GT FILECalibrated: 871114 00:23

Files: >37130 >37129 >37128 >37127 >37131RF RF RF RF <F

Compound 10.00 20.00 50.00 100.00 200.00 RF 7. RSD

-YRIDINE 1.27274 1.43665 1.48211 1.43683 1.73672 1.47301 11.378WIMEODIME THVLflllNE 1 .OE'029 1.16500 1.14477 1.06319 1.33014 1.15668 9.1572-ffTHYLPYRIOM (PICOLINE) 1.32348 1.3S540 1.42859 1.42824 .98730 1.31260 14.233•CTHYL METhflNE SLLFOHftTE .28180 .26746 .29181 .27479 .31188 .28955 4.8411-MlTROSCICTHYLETHYLftPIINE .66567 .72701 .73534 .70220 .79957 .72996 5.9772-FLUOROPfeO. SURROGATE - - - - - - -frtlTROSO OIETHYLftHINE .62519 .67356 .67711 .57654 .74150 .67878 6.092ETHYL ifTBnt£SHF(ME - .95947 .99717 1.00048 1.11305 1.01754 6.519SEflZCHJINONE . . _ . . . _3HEiiI-fl5 SURROGflTE .05456 .04993 .02920 .02476 .02565 .03682 38.7613I£NQL 1.55919 1.72250 1.80219 1.82116 1.77042 1.73509 6.0633ENZENE THIOt _ . . . . . .MLINE 2.11972 2.31488 2.38964 2.55842 2.41601 2.36174 6.822PEhTflChLGRflETHflhE - .51834 .52312 .51578 .57324 .53262 5.116bis(2-CHLGROETHYL)ETHER .97218 1.06686 1.09255 1.08205 1.19151 1.08103 7.2232-CHLOROPHENOL 1.26171 1.37816 1.40018 1.42574 1.47280 1.38772 5.6751,3-DICHORQBENZENE 1.29161 1.42628 1.43204 1.48114 1.61094 1.44840 7.9351,4-OICHaRDBEHZENE 1.38716 1.50449 1.51623 1.57444 1.58959 1.51438 5.278SENZEf€(€THMI (BENZYL-OH) .85194 .95251 1.00433 1.00739 1.13060 .98936 10.2011.2-OIOtOROBENZeC 1.29279 1.38119 1.38361 1.43417 1.58383 1.41512 7.573

YTHYftfNOL (0-CRESQL) 1.10578 1.18358 1.20257 1.21583 1.27071 1.19569 5.003j(2-CH.OROISOPROPYL)ETHER 1.70222 1.80812 1.83877 1.83374 1.88550 1.81367 3.764'-NlTROSOflQRPHOLIIf .64496 .54623 .70737 .66737 .76693 .56657 7.504JOPKENQNE - 1.23460 1.23255 .84793 1.92308 1.30954 34.180

i-riITROSOOI-n-PROPYLfi(1If€ .90559 .96319 .98581 .968041.08306 .98114 6.5683/4-fETHYLPHENOL (M/P-CRESOL) - 2.81970 2.94935 3.11859 2.90814 2.94895 4.251f1-rtITROSO-PYRROLIDI(£ .72136 .78094 .80907 .78678 .49822 .71927 17.763-£XflCHlQRQETWf€ .16791 .18273 .18361 .17313 .20173 .18182 7.114NITROBENZENEtfi SURROGATE - - - .00006 - .00006 -NITROBENZENE .34003 .34902 .40746 .39015 .62638 .42261 27.757N-NITROSOPIPERIDIf€ .18814 .20919 .21247 .20277 .22636 .20818 7.033ISCPfOTC .15581 .76714 .79296 .79535 .89322 .68090 43.6852-MITRGPHENOL .19211 .21275 .22769 .22960 .24885 .22220 9.5212,4-OINETHYLPHENOL .29726 .30910 .33448 .32965 .34340 .32278 5.894bis-(2-CHLCRETHCXY)l€TKtf£ .45841 .50026 .51386 .51583 .58397 .51447 8.789SENZOICftCID - - .00007 .00005 - .00006 19.161DIlCTHVLPHENETHVLflMINE .00311 .00442 .01107 .01500 .00084 .00669 65.9342,4-OICH.QRQP™. .25344 .28252 .29571 .29619 .31432 .28844 7.8341,2,4-TRICHLQROBENZEHE .28092 .29126 .29935 .29433 .33024 .29922 6.218WHTHfiLEf€ 1.04413 1.09389 1.15141 1.24546 1.35064 1.17711 10.4094-CHLOROflNILNE .40407 .43557 .45319 .43994 .46575 .43970 5.2702,5-OiaiGROPHEftt. .26323 .27963 .29867 .29878 .31854 .29177 7.221.-£XftCHLOROPR(]PEf£ .13827 .14640 .14612 .14873 .17092 .15009 8.192.HEXflCHORGBUTflDKNE .11020 .11558 .11453 .11286 .12678 .11599 5.486N-NITROSO DI-N-SUTYLflMINE .20374 .21759 .22854 .22397 .25293 .22535 7.999

RF - Response Factor (Subscript is anaunt in DC/It)

k - flverage Response Factor _ t a 3 \ l w£RSO - Percent Relative Standard Deviation

Page 1 of 3

Title: PEI flPP.IX ST FILECalibrated: 871114 00:23

Files: >37130 >37129 >37128 >37127 >37131RF RF SF RF RF

Compound 10.00 20.00 50.00 100.00 200.00 RF 7. RED

<E5GRCINOL .00080' .00128 .00025 .00007 .00085 .00065 75.0884-CHtORO-3-HETHYLPf£NDL .25496 .27885 .28611 .28798 .31538 .28466 7.602SPFRQLE .20659 .22841 .23425 .23692 .03907 .18945 44.7582-, ETHYL,WiTHflLENE .57793 .61465 .63144 .65794 .70549 .63749 7.5021-ffTHYLNftPHTHflLEff .59762 .52831 .66057 .68061 .73642 .66071 7.9941,2,4,5-TETRflCHLQRQBENZENE .56592 .57297 .58676 .62383 .67184 .60426 7.264'HEXflCHLOROCYaOPENTflOIE* .38494 .40315 .42545 .43911 .€484 .42950 9.7802,4,5-TRICHLOROPHENOL .30652 .41463 .37745 .40003 .42888 .38550 12.4702,4,6-TRIOtOROPHENOL .29086 .33058 .35701 .37681 .40557 .35216 12.464ISOSflFRQLE .44622 .47137 .50383 .52579 .57169 .50378 9.6542-FLUORD8IPHENYL SURROGATE - - .00021 .00008 .00010 .00013 54.0992-CHLQRONflFHTHflLENE 1.34387 1.39517 1.43278 1.56360 1.39904 1.42689 5.8001-CHLDRGHfiPHTHflLENE 1.34387 1.07681 1.08614 1.19135 .93247 1.12613 13.5552-NITROftNILINE .45403 .52298 .55243 .57318 .64751 .55002 12.8541,4-HfiPHTHOGUINOf£ .50070 .54386 .54954 .52791 .47987 .52038 5.6731,4-DINITRQBENZENE .24121 .27914 .28414 .29007 .34396 .28770 12.791DIHETHYLPHTHflLflTE 1.22614 1.32746 1.35017 1.43004 1.56510 1.37978 9.1742,e-OINITROTOLUEf€ .33111 .35786 .37927 .38637 .44772 .38047 11.386flCENflPHIHYLENE 1.84750 1.95817 2.04144 2.20299 2.36698 2.08381 9.8623-NITROflNILIIf .38309 .42690 .45591 .45740 .48932 .44252 9.016flCENflPHTHENE 1.25066 1.32491 1.36957 1.45823 1.55511 1.39169 8.5002,4-OMTROft€NOL .04754 .10835 .14604 .17233 .19019 .13289 42.731* "TOWEL .50262 .32335 .36935 .38265 .16552 .34870 34.967D.__,£OFURflN 1.64301 1.72545 1.80539 2.00780 2.17238 1.87081 11.558

-OINITROTOLUENE - .41221 .45355 .48189 .34437 .42300 14.119OROBENZENE .49921 .52538 .54330 .54403 .62569 .54752 8.647

1-NflPHTHYLfitlINE 1.12494 1.16455 1.16508 1.03802 1.07021 1.11256 5.11?2-WHTHYLflflIlf 1.296101.357781.443221.398191.342631.36758 4.0862,3,4,6-TETRflCHLOROFHENa .20442 .25049 .27840 .29256 .32756 .27069 17.101OIETHYLPHTWLflTE 1.41116 1.52491 1.57588 1.70398 1.91137 1.62546 11.7709H-FLUOREK - 1.58681 1.68796 1.83054 1.91695 1.75557 8.3664-CnLOROFWfVL PHENYL ETHER .53904 .59301 .60554 .64904 .71748 .52082 10.7564-NITROflNflLINE .41726 .46509 .50105 .51402 .57845 .49517 12.0754,6-DINITRO-2-ffTHYLPHENOL .12220 .18245 .21971 .24633 .27911 .20996 28.633N-NITROSOOI-N-PHENYLOIM 2.09937 2.26195 2.44411 2.73913 2.77410 2.46373 11.938OIPHENYLftHINE 2.09937 2.26195 2.44411 2.73913 2.77410 2.46373 11.9381,2-DIrWffLHYDRflZINE - - - .00736 - .00736 -2,4,6-TRIBRaMQFWfl. SURROGflTE - - - - - -fWflCETIN .31066 .35554 .38147 .39570 .44082 .37684 12.7984-8R(MPH£NYL PHENYL ETHER .17805 .19850 .20259 .20558 .22598 .20214 8.475HEXflCHLOROBENZENE .21570 .23222 .23262 .22916 .26039 .23402 6.9554-fittINOBIPHENYL .62752 .68799 .71277 .71611 .69239 .68736 5.184PROWIDE .17998 .20022 .21064 .21578 .24536 .21040 11.347PENTfiCHLORtFHENOL - .07624 .09024 .10780 .12367 .09949 20.762FENraHLOROHITROBENZENE .04381 .05132 .05248 .05351 .06307 .05284 13.010

RF - Response Factor (Subscript is anoint in UG/lt)

KF - Overage Response Factor

/Su - Percent Relative Standard Deviation

Page 2 of 3 HRI03ICalibration Report

Files.: >37130 >37129 >3712B >37127 >37131RF RF RF RF RF

Compound 10.00 20.00 50.00 100.00 200.00 RF I RED

.91654 .98894 1.01553 1.10836 1.17826 1.04193 9.603.HRflCEHE .95359 1.03879 1.06492 1.16240 1.18650 1.08124 8.778

GIBUTYLFHTHflLflTE 1.37878 1.24733 1.30180 1.45761 1.64242 1.40559 10.983EENZIDINE - - - .01710 - .01710 -FLLGRflKTHENE .88441 .94531 .99731 1.10608 1.19521 1.02566 12.180FYREHE-d10 SURROGATE - .G0030 .00027 .00012 .00011 .00020 50.089-YREte .93343 .98627 1.03082 1.17604 1.25446 1.07620 12.490TERPHEHYL-d14 SURROGflTE - - - .00005 - .00005 -P-OIMETHYL RHINO ftZOENZENE .5556? .62305 .65097 .65274 .71405 .63930 8.9734,4',1ETHLEHBIS(2CH.ORflHILIf€) .42250 .46871 .49727 .5132? .56613 .49360 10.778BUTYLEHZYLPHlHfiLflTE .92305 1.00981 1.10165 1.13319 1.23701 1.08094 11.0923,3'-DMThYLBENZIDINE .84771 .95604 .94992 .87634 .70098 .86620 11.9452-fiCETYLfitlINOFLUORENE - -.16526 .18212 .18251 .17110 .17525 4.8523,3'-DIt€THQXY6£NZIDINE - .00018 - .00018 -3,3'-OICHLOROENZIDINE .51964 .58180 .60254 .61582 .59492 .58294 6.428aiS-2-ETHYLHtXYLPHTmLflTE 2.65783 2.87267 3.12696 3.41582 3.43256 3.10117 10.9143ENZ(a)flNTHRflCENE 1 . 67045 1.77893 1.87671 1.9*03 1.98006 1.B5W 6.843CHRYSEte 1.531281.564771.580741.672851.730281.61598 5.116uI-rrGCTYLPHTWLflTE 2.65156 2.87267 3.09828 3.41582 3.43256 3.09418 10.9957,12-DIMETHYLENZ(a)flHTHRflCEf€ .32525 .54774 .58350 .59251 .66120 .54204 23.5073ENZO(b)FLUQRflNTHENE .702541.282271.275431.504082.892971.55146 52.678BENZO(k)FLUORflNTHENE .70254 1.12136 1.24556 .97815 2.89297 1.38812 52.328B£NZO(a)PYRFJ€ .92962 1.00771 1.07271 1.06642 .71229 .95775 15.5363-teTHYLCHOLflNTHRENE .50599 .55188 .59026 .60408 .59169 .56878 7.066IlflEKK1t2,3-c,d)PYRENE 1.084251.141451.091781.248411.215911.15636 6.357^ 0(a,h)flNTHRflCEf€ .89715 .92620 .972181.07536 .67530 .90924 16.194

j 9,h,i)PERYLEhE .88310 .92983 .929831.01513 .72664 .89690 11.869Uit£NZO(fl,E)PYRENE _ . . . . . .OIBENZO<fl,H)PYREHE - - -OIBEHZO(fl,I)PYREHE - - - - - - -

•SkOS

.RF - Response Factor (Subscript is amount in UG/ML)

RF - flverage Response Factor

- Percent Relative Standard Deviation

Page 3 of 3

R R I 0 3 I

ARI03I06A

DAILY CALIBRATIONS

103101

• » fn>

if s» PPH Sf3——7s-3i«g»t> ... '-,————___0& 31w*18,iH=1.8J3sr5sg(•

t-20

•18

-0

•

flRI03IOB

: t L.OC0 Calibration Check Report

Title: PEI APP.IX QT FILE

Calibrated: 871114 00:23

Check Standard Data File: >37203Injection Time: 871123 08:59

Compound RF RF %Diff Calib Meth

PYRIDINE 1.47301 1.37902 6.38 AverageN-NITROSODIMETHYLAMINE 1.15668 1.09353 5.46 Average2-METHYLPYRIDINE (PICOLINE) 1.31260 1.30228 .79 AverageMETHYL METHANE SULFONATE .28955 .34890 20.50 AverageN-NITROSOMETHYLETHYLAMINE .72996 - - Average2-FLUOROPHENOL SURROGATE - AverageN-NITROSO DIETHYLAMINE .67878 .64507 4.97 AverageETHYL METHANESULFONATE 1.01754 - - AverageBENZOQUINONE - AveragePHENOL-d5 SURROGATE .03682 - - AveragePHENOL 1.73509 1.94157 11.90 AverageBENZENE THIOL - AverageANILINE 2.36174 2.26842 3.95 AveragePENTACHLORAETHANE .53262 .51944 2.48 Averagebis(2-CHLOROETHYL)ETHER 1.08103 1.17791 8.96 Average2-CHLOROPHENOL 1.38772 1.33345 3.91 Average1,3-DICHLOROBENZENE 1.44840 1.38311 4.51 Average1 4-DICHLOROBENZENE 1.51438 1.47751 2.43 AverageNZENEMETHANOL (BENZYL-OH) .98936 1.07608 8.77 Average

',2-DICHLOROBENZENE 1.41512 1.37181 3.06 Average_'-METHYPHENOL (0-CRESOL) 1.19569 1.19840 .23 AverageBISC2-CHLOROISOPROPYDETHER 1.81367 2.02472 11.64 AverageN-NITROSOMORPHOLINE .68657 .88113 28.34 AverageACETOPHENONE 1.30954 2.42667 85.31 AverageN-NITROSODI-n-PROPYLAMINE .98114 1.09709 11.82 Average3/4-METHYLPHENOL (M/P-CRESOL) 2.94895 2.92696 .75 AverageN-NITROSO-PYRROLIDINE .71927 .80479 11.89 AverageHEXACHLOROETHANE .18182 .19313 6.22 AverageNITROBENZENE-d5 SURROGATE .00006 - - AverageNITROBENZENE .42261 .10723 74.63 AverageN-NITROSOPIPERIDINE .20818 .21623 3.87 AverageISOPHORONE .68090 .85363 25.37 Average2-NITROPHENOL .22220 .24155 8.71 Average2,4-DIflETHYLPHENQL .32278 .31608 2.08 Averagebis-(2-CHLQRETHOXYMETHANE .51447 .52110 1.29 AverageBENZOIC ACID .00006 - - AverageDIMETHYLPHENETHYLflttlNE .00689 .00900 30.69 Average2,4-DICHLOROPHENOL .28844 .32328 12.08 Average1,2,4-TRICHLOROBENZENE .29922 .31192 4.24 AverageNAPHTHALENE 1.17711 1.16700 .86 Average4-CHLOROANILNE .43970 .42920 2.39 Average2,6-DICHLOROPHENOL .29177 .32420 11.11 AverageHFXACHLOROPROPENE .15009 .20149 34.25 Average

(ACHLOROBUTADIENE .11599 .14464 24.70 Average

«F - Response Factor from daily standard file at 50.00 UG/flL,

RF - Average Response Factor from Initial Calibration

%Diff - 7. Difference from original average or curvjfep | 03 i 09

£' ' f^Calibration Check Report

Title: PEI APP.IX ;QT FILE



Compound RF RF XDiff Calib Meth—— —» —— —- —— —— —— —— —— «_ —— —— —— —— —— _«-> _- «-. __ __ __ __> __ __ __» _., M. •_ __ ... __ __ __ __. __ «_, __ __ « __ __ __ __ __ __ __, __ __, H __. __.••»___• _*•.__ __

N-NITROSO DI-N-BUTYLAMINE .22535 - - AverageRESORCINOL .00065 .01695 2508.78 Average-*- A/or4-CHLORO-3-METHYLPHENOL .28466 .33036 16.06 AverageSAFROLE .18945 .25045 32.20 Average2-METHYLNAPHTHALENE .63749 .63291 .72 Average1-METHYLNAPHTHALENE .66071 .66241 .26 Average1,2,4,5-TETRACHLOROBENZENE .60426 - - AverageHEXACHLOROCYCLOPENTADIENE .42950 - - Average2,4,5-TRICHLOROPHENOL .38550 - - Average2,4,6-TRICHLOROPHENOL .35216 - - AverageISOSAFROLE .50378 .35525 29.48 Average2-FLUOROBIPHENYL SURROGATE .00013 - - Average2-CHLQRONAPHTHALENE 1.42689 - - Average1-CHLORONAPHTHALENE 1.12613 - - Average2-NITROANILINE .55002 - - Average1,4-NAPHTHOQUINONE .52038 - - Average1,4-DINITROBENZENE .28770 .02977 89.65 AverageDIMETHYLPHTHALATE 1.37978 - - Average?,6-DINITROTOLUENE .38047 .03532 90.72 AverageENAPHTHYLENE 2.08381 - - Average-NITROANILINE .44252 - - Average

ACENAPHTHENE 1.39169 - - Average2,4-DINITROPHENOL .13289 - - Average4-NITROPHENOL .34870 .02726 92.18 AverageDIBENZOFURAN 1.87081 - - Average2,4-DINITROTOLUENE .42300 .26981 36.22 AveragePENTACHLOROBENZENE .54752 - - Average1-NAPHTHYLAMINE 1.11256 - - Average2-NAPHTHYLAMINE 1.36758 - - Average2,3,4,6-TETRACHLOROPHENOL .27069 - - AverageDIETHYLPHTHALATE 1.62546 - - Average9H-FLUORENE 1.75557 - - Average4-CHLOROPHENYL PHENYL ETHER .62082 - - Average4-NITROANALINE .49517 .17704 64.25 Average4,6-DINITRO-2-METHYLPHENOL .20996 - - AverageN-NITROSODI-N-PHENYLAMINE 2.46373 - - AverageDIPHENYLAMINE 2.46373 - - Average1,2-DIPHENYLHYDRflZINE .00736 .07888 971.61 Average*- **>»isr*«>*u>2,4,6-TRIBROMOPHENOL SURROGATE - AveragePHENACETIN .37684 .41838 11.02 Average4-BROMOPHENYL PHENYL ETHER .20214 - - AverageHEXACHLOROBENZENE .23402 .25473 8.85 Average4-AMINOBIPHENYL .68736 .67043 2.46 AveragePRONAMIDE .21040 .22828 8.50 Average

r - Response Factor from daily standard file at 50.00 UG/ML


XDiff - X Difference from original average or curve .pin^l 10

IX QT FILE



Compound RF RF XDiff Calib Meth

PENTACHLOROPHENOL .09949 .10607 6.62 AveragePENTACHLORONITROBENZENE .05284 .07034 33.13 AveragePHENANTHRENE 1.04193 1.00574 3.47 AverageANTHRACENE 1.08124 1.05742 2.20 AverageDIBUTYLPHTHALATE 1.40559 1.32544 5.70 AverageBENZIDINE .01710 - - AverageFLUORANTHENE 1.02566 1.02787 .21 AveragePYRENE-d10 SURROGATE .00020 - - AveragePYRENE 1.07620 1.08045 .39 AverageTERPHENYL-d14 SURROGATE .00005 - - AverageP-DIMETHYL AMINO AZOBENZENE .63930 .54352 14.98 Average4,4'METHLENBIS(2CHLORANILINE) .49360 .51899 5.15 AverageBUTYLBENZYLPHTHALATE 1.08094 1.04261 3.55 Average3,3'-DIMETHYLBENZIDINE .86620 .93086 7.46 Average2-ACETYLAMINOFLUORENE .17525 .19205 9.59 Average3,3'-DIMETHOXYBENZIDINE .00018 - - Average3,3'-DICHLOROBENZIDINE .58294 .67283 15.42 AverageBIS-2-ETHYLHEXYLPHTHALATE 3.10117 2.96802 4.29 AverageBENZ(a)ANTHRACENE 1.85044 1.81954 1.67 AverageCHRYSENE 1.61598 1.58234 2.08 Averageni-n-OCTYLPHTHALATE 3.09418 2.96802 4.08 Average12-DIMETHYLBENZ(a)ANTHRACENE .54204 .75676 39.61 Average

b£NZO(b)FLUORANTHENE 1.55146 - - AverageÊNZO(k)FLUORANTHENE 1.38812 - - AverageJENZO(a)PYRENE .95775 1.35084 41.04 Average3-METHYLCHOLANTHRENE .56878 .91463 60.81 AverageINDENO(1,2,3-c,d)PYRENE 1.15636 .21165 81.70 AverageDIBENZO(a,h)ANTHRACENE .90924 1.11533 22.67 AverageBENZO(g,h,i)PERYLENE .89690 .25455 71.62 AverageDIBENZO(A,E)PYRENE - AverageDIBENZO(A,H)PYRENE - AverageDIBENZO(A,I)PYRENE - Average

Response Factor from daily standard file at 50.00 UG/ML

PF - Average Response Factor from Initial Calibration

/.uiff - 7. Difference from original average or curve

<os

558000-

580080-

458008-

H00

H90

tee

h?0

HS8

h50

12 16 20 • 24 - 2-8 . . - r -,- - ^

£"yj*--::,4k2S ^ P '

Calibration Check Report

Title: FEI APP.IX GT FILECalibrated: 871114 00:23 _,,


RF RF XDiff Calib Meth

FYRIDINE 1.47301 1.38819 5.76 AverageN-rflTROSODIMETHYLAMINE 1.15668 - - Average2-METHYLPYRIDINE (PICOLINE) 1.31260 1.37179 4.51 AverageMETHYL METHANE SULFONATE .28955 .32066 10.75 AverageN-NITROSOMETHYLETHYLAMINE .72996 - - Average2-FLLIOROPHENOL SURROGATE - AverageN-NITROSO DIETHYLAMINE .67878 .56173 17.24 AverageETHYL METHANESULFONATE 1.01754 - - AverageBENZOQUINONE - - - AveragePhENOL-d5 SURROGATE .03682 .03738 1.52 AveragePHENOL 1.73509 1.86034 7.22 AverageBENZENE THIOL - - - AvprageANILINE 2.36174 - - AveragePENTACHLORAETHANE .53262 .49785 6.53 Averagebis(2-CHLOROETHYL)ETHER 1.08103 1.13793 5.26 Average2-CHLOROPHENOL 1.38772 1.27813 7.90 Average1,3-DICHLOROBENZENE 1.448401.38625 4.29 Average1 4-DICHLOROBENZENE 1.51438 1.63473 7.95 AverageNZENEMETHANOL (BENZYL-OH) .98936 1.07901 9.06 Average,2-DICHLOROBENZENE 1.41512 1.36468 3.56 Average

.-METHYPHENOL (Q-CRESOL) 1.19569 - - AverageBIS(2-CHLOROISOPROPYL)ETHER 1.81367 1.79807 .86 AverageN-NITROSOMORPHOLINE .68657 .78261 13.99 AveragePCETOPHENONE 1.30954 2.34069 78.74 AverageN-NITRQSODI-n-PROPYLAMINE .98114 1.00503 2.44 Average3/4-METHYLPHENOL (M/P-CRESOL) 2.94895 2.67781 9.19 AverageN-NITROSO-PYRROLIDINE .71927 .31349 56.42 AverageHEXACHLOROETHANE .18182 .18720 2.96 AverageNITROBENZENE-d5 SURROGATE .00006 - - AverageNITROBENZENE .42261 .10441 75.29 AverageN-NITROSQPIPERIDINE .20818 .18887 9.28 AverageISOPHCRONE .68090 .77033 13.14 Average2-NITRCPHENOL .22220 .16977 23.60 Average2,4-DIMETHYLPHENOL .32278 .28282 12.38 Averagebis-(2-CHLORETHOXY)METHANE .51447 .48751 5.24 AverageBENZOIC ACID .00006 - - Average .,DIMETHYLPHENETHYLAMINE .00689 .20466 2870.89 Average^ <*2,4-DICHLOROPHENOL .28844 .27761 3.75 Average1,2,4-TRICHLOROBENZENE .29922 .28760 3.88 AverageNAPHTHALENE 1.17711 1.08806 7.56 Average4-CHLOROANILNE .43970 .39659 9.81 Average2,6-DICHLORQPHENOL .29177 .28026 3.94 AverageHPXACHLOROPROPENE .15009 .18760 24.99 Average

(ACHLOROBUTADIENE .11599 .14763 27.27 Average

RF - Response Factor from daily standard g§L\» Wt 50.00 UG/ML


XDiff - 7. Difference from original average or curve

Check ReportTitle: PEI APP.IX QT FILE

Calibrated: 871114 00:23Check Standard Data File: >37216

Injection Time: 871201 09:40

Compound RF RF XDiff Calib Meth""* ""*" """* *""* """ ""* "™ """" ""* *"" ™~ *"~ ~" "™" "™~ "™ ~~ ""* ~" ~~ *~" *~* ~" ~" •""• ——* ——• "~ •"* •"" """• "~ ~* ~* *"• -"•• <•"• ——* -"• ™* ••—— ———— «-• ••- - -,__- — 1MJ -,_ __, ___ __ __. ___ ___ __ [_m _M ——_ _. ___

N-NITRCSO DI-N-BUTYLAMINE .22535 - - Average ^RESORCINOL .00065 .01689 2499.87 Average^^4-CHLORO-3-METHYLFHENOL .28466 .30325 6.53 AverageSAFROLE .18945 .21834 15.25 Average2-METHYLNAPHTHALENE .63749 .54045 15.22 Average1-METHYLNAPHTHALENE .66071 .56950 13.80 Average1,2,4,5-TETRACHLOROBENZENE .60426 .62146 2.85 AverageHEXACHLOROCYCLOPENTADIENE .42950 .45951 6.99 Average2,4,5-TRICHLOROPHENOL .38550 .38613 .16 Average2,4,6-TRICHLOROPHENOL .35216 .37293 5.90 AverageISOSAFROLE .50378 .50563 .37 Average2-FLUOROBIPHENYL SURROGATE .00013 - - Average2-CHLORONAPHTHALENE 1.42689 1.40067 1.84 Average1-CHLORONAPHTHALENE 1.12613 1.04238 7.44 Average2-NITROANILINE .55002 .40128 27.04 Average1,4-NAPHTHOOUINONE .52038 .50938 2.11 Averaget,4-DINITROBENZENE .28770 .29413 2.23 AverageDIMETHYLPHTHALATE 1.37978 1.46631 6.27 Average2,6-DINITROTOLUENE .38047 .31217 17.95 AverageENAPHTHYLENE 2.08381 1.97853 5.05 Average

o-NITROANILINE .44252 - - Average^CENAPHTHENE 1.39169 1.43064 2.80 AverageP.4-DINITROPHENOL .13289 .03763 71.68 Average4-NITROPHENOL .34870 .28898 17.12 AverageDIBENZOFURAN 1.87081 1.73785 7.11 Average2,4-DINITROTOLUENE .42300 -- - AveragePENTACHLOROBENZENE .54752 .52100 4.84 Average1-NAPHTHYLAMINE 1.11256 .94169 15.36 Average2-NAPHTHYLAMINE 1.36758 1.21368 11.25 Average2,,3,4,6-TETRACHLOROPHENOL .27069 .26952 .43 AverageDIETHYLPHTHALATE 1.62546 1.68139 3.44 Average9H-FLUORENE 1.75557 1.59959 8.88 Average4-CHLOROPHENYL PHENYL ETHER .62082 .59335 4.42 Average4-NITROANALINE .49517 .39591 20.05 Average4,6-DINITRO-2-METHYLPHENOL .20996 .14604 30.45 AverageN-NITROSODI-N-PHENYLAPfINE 2.46373 2.16535 12.11 AverageDIPHENYLAMINE 2.46373 2.16535 12.11 Average1,2-DIPHENYLHYDRAZINE .00736 - - Average2,4,6-TRIBROMOPHENOL SURROGATE - AveragePHENACETIN .37684 .47584 26.27 Average4-BROMOPHENYL PHENYL ETHER .20214 - - AverageHEXACHLOROBENZENE .23402 .24627 5.23 Average4-AMINOBIPHENYL .68736 .68371 .53 AveragePRONAMIDE . .21040 .24575 16.80 Average

RF - Response Factor from daily standard file at 50.00 UG/ML

^r - Average Response Factor from Initial Calibration

XDiff - X Difference from original average or curve flR I 03 I

Page 2 of 3

Title*TEI APP.IX QT FILE




PENTACHLOROPHENOL .09949 .10182 2.35 AveragePENTACHLORONITROBENZENE .05284 .08030 51.97 AveragePHENANTHRENE 1.04193 1.03892 .29 AverageANTHRACENE 1.08124 1.07145 .91 AverageDIBUTYLPHTHALATE 1.40559 1.42555 1.42 AverageBENZIDINE .01710 - - AverageFLUORANTHENE 1.02566 1.01373 1.16 AveragePYRENE-d10 SURROGATE .00020 - - AveragePYRENE 1.07620 1.05622 1.86 AverageTERPHENYL-d14 SURROGATE .00005 - - AverageP-DIMETHYL AMINO AZOBENZENE .63930 .54456 14.82 Average4,4'METHLENBIS(2CHLORANILINE) .49360 .44004 10.85 AverageBUTYLBENZYLPHTHALATE 1.08094 .96552 10.68 Average3,3'-DIMETHYLBENZIDINE .86620 .79499 8.22 Average2-ACETYLAMINOFLUORENE .17525 .18092 3.24 Average3,3'-DIMETHOXYBENZIDINE .00018 - - Average3,3'-DICHLOROBENZIDINE .58294 .57498 1.37 AverageBIS-2-ETHYLHEXYLPHTHALATE 3.10117 3.38148 9.04 AverageBENZ(a)ANTHRACENE 1.85044 1.55559 15.93 AverageCHRYSENE 1.61598 1.52685 5.52 Averagenr-n-OCTYLPHTHALATE 3.09418 3.38148 9.29 Average

12-DIMETHYLBENZ(a)ANTHRACENE .54204 .54272 .13 AverageINZO(b)FLUORANTHENE 1.55146 - - Average

dENZO(k)FLUORANTHENE 1.38812 - - AverageBENZO(a)PYRENE .95775 1.08437 13.22 Average3-METHYLCHOLANTHRENE .56878 .25427 55.30 AverageINDENO(1,2,3-c,d)PYRENE 1.15636 .00493 99.57 AverageDIBENZO(a,h)ANTHRACENE .90924 .48608 46.54 AverageBENZO(g,h,i)PERYLENE .89690 - - AverageDIBENZO(A,E)PYRENE - AverageDIBENZO(A,H)PYRENE - AverageDIBENZO(A,I)PYRENE - Average

- Response Factor from daily standard file at 50.00 UG/ML

Average Response Factor from Initial Calibration

XDiff - X Difference from original average or curve

Pa9e 3 of 3

>37228 35.0-458.0 __f ~" TIC

520000-f -J•' ' Keel

-70

r608

r48

L-38

f28rt077

I03U6

Calibration Check Report

Title: PEI APP.IX QT FILECalibrated: 871114 00:23


Compound RF RF XDiff Calib MethPYRIDINE 1.47301 1.49379 1.41 AverageN-NITROSODIMETHYLAMINE 1.15668 1.12528 2.71 Average2-METHYLPYRIDINE (PICOLINE) 1.31260 1.49837 14.15 AverageMETHYL METHANE SULFONATE .28955 .30956 6.91 AverageN-NITROSOMETHYLETHYLAMINE .72996 .71365 2.23 Average2-FLUOROPHENOL SURROGATE - AverageN-NITROSO DIETHYLAMINE .67878 .64665 4.73 AverageETHYL METHANESULFONATE 1.01754 - - AverageBENZOQUINONE - AveragePHENOL-d5 SURROGATE .03682 - - AveragePHENOL 1.73509 2.18526 25.94 AverageBENZENE THIOL - AverageANILINE 2.36174 2.47337 4.73 AveragePENTACHLORAETHANE .53262 .51470 3.37 Averagebis(2-CHLOROETHYL)ETHER 1.08103 1.27695 18.12 Average2-CHLOROPHENOL 1.38772 1.43340 3.29 Average1,3-DICHLOROBENZENE 1.44840 1.49840 3.45 Average1,4-DICHLOROBENZENE 1.51438 1.69854 12.16 AverageJENZENEMETHANOL (BENZYL-OH) .98936 1.14496 15.73 Average1,2-DICHLOROBENZENE 1.41512 1.45494 2.81 Average2-METHYPHENOL (0-CRESOL) 1.19569 - - AverageBIS(2-CHLOROISOPROPYL)ETHER 1.81367 1.99703 10.11 AverageN-NITROSOMORPHOLINE .68657 .71324 3.89 AverageACETOPHENONE 1.30954 2.32420 77.48 AverageN-NITROSODI-n-PROPYLAMINE .98114 1.06469 8.52 Average3/4-METHYLPHENOL (M/P-CRESOL) 2.94895 3.05544 3.61 AverageN-NITROSO-PYRROLIDINE .71927 .75817 5.41 AverageHEXACHLOROETHANE .18182 .16851 7.32 AverageNITROBENZENE-d5 SURROGATE .00006 - - AverageNITROBENZENE .42261 .09794 76.83 AverageN-NITROSOPIPERIDINE .20818 .19821 4.79 AverageISOPHORONE .68090 .77976 14.52 Average2-NITROPHENOL .22220 .18943 14.75 Average2,4-DIMETHYLPHENOL .32278 .29758 7.81 Averagebis-(2-CHLORETHOXY)METHflNE .51447 .53120 3.25 AverageBENZOIC ACID .00006 - - AverageDIMETHYLPHENETHYLAP1INE .00689 - - Average2,4-DICHLOROPHENOL .28844 .28820 .08 Average1,2,4-TRICHLOROBENZENE .29922 .27222 9.02 AverageNAPHTHALENE 1.17711 f. 09605 6.89 Average4-CHLOROANILNE .43970 .39921 9.21 Average2,6-DICHLOROPHENOL .29177 .28538 2.19 AverageHEXACHLOROPROPENE .15009 .15088 .53 AverageEXACHLOROBUTADIENE .11599 .12854 10.81 Average

-F- Response Factor from daily standard file at 50.00 UG/HL

EF - Average Response Factor from Initial Calibration

XDiff - X Difference from original average or curv

Cali&fat'i on 'Check Report

Title: PEI APP.IX QT FILE




N-NITROSO DI-N-BUTYLAMINE .22535 .26762 18.76 AverageRESORCINOL .00065 .01413 2074.56 Average4-CHLORO-3-METHYLPHENOL .28466 .31347 10.12 AverageSAFROLE .18945 .21911 15.66 Average2-METHYLNAPHTHALENE .63749 .55206 13.40 Average1-METHYLNAPHTHALENE .66071 .57162 13.48 Average1,2,4,5-TETRACHLOROBENZENE .60426 .59069 2.25 AverageHEXACHLOROCYCLOPENTADIENE .42950 .37088 13.65 Average2,4,5-TRICHLOROPHENOL .38550 .39296 1.94 Average2,4,6-TRICHLOROPHENOL .35216 .37740 7.17 AverageISOSAFROLE .50378 .50876 .99 Average2-FLUOROBIPHENYL SURROGATE .00013 - - Average2-CHLORONAPHTHALENE 1.42689 1.42960 .19 Average1-CHLORONAPHTHALENE 1.12613 1.04330 7.35 Average2-NITROANILINE .55002 .44945 18.29 Average1,4-NAPHTHOQUINONE .52038 .50026 3.87 Average1,4-DINITROBENZENE .28770 .32466 12.85 AverageDIMETHYLPHTHALATE 1.37978 1.48159 7.38 Average2,6-DINITROTOLUENE .38047 .32177 15.43 AverageCENAPHTHYLENE 2.08381 1.99831 4.10 AverageJ-NITROANILINE .44252 .38389 13.25 AverageACENAPHTHENE 1.39169 1.42206 2.18 Average2,4-DINITROPHENOL .13289 .09205 30.74 Average4-NITROPHENOL .34870 .23310 33.15 AverageDIBENZOFURAN 1.87081 1.74861 6.53 Average2,4-DINITROTOLUENE .42300 .43354 2.49 AveragePENTACHLOROBENZENE .54752 .50590 7.60 Average1-NAPHTHYLAMINE 1.11256 .98942 11.07 Average2-NAPHTHYLAMINE 1.36758 1.21343 11.27 Average2,3,4,6-TETRACHLOROPHENOL .27069 .25818 4.62 AverageDIETHYLPHTHALATE 1.62546 1.64654 1.30 Average9H-FLUORENE 1.75557 1.64539 6.28 Average4-CHLOROPHENYL PHENYL ETHER .62082 .59310 4.47 Average4-NITROANALINE .49517 .01127 97.72 Average4,6-DINITRO-2-METHYLPHENOL .20996 .15992 23.83 AverageN-NITROSODI-N-PHENYLAMINE 2.46373 2.19294 10.99 AverageDIPHENYLAttlNE 2.46373 2.19294 10.99 Average1,2-DIPHENYLHYDRflZINE .00736 - - Average2,4,6-TRIBROMOPHENOL SURROGATE - AveragePHENACETIN .37684 .49097 30.29 Average4-BROMOPHENYL PHENYL ETHER .20214 - - AverageHEXACHLOROBENZENE .23402 .23470 .29 Average4-AMINOBIPHENYL .68736 .63538 7.56 AveragePRONAMIDE .21040 .24267 15.34 Average

'

RF - Response Factor from daily standard file at 50.00 UG/ML

- Average Response Factor from Initial CalibrationXDiff - X Difference from original average or curve _ , rt0 fflR I uo I

Page 2 of 3

: rti g&f". TX'QT FILE

Calibrated: 871 Til 00:23



PENTACHLOROPHENOL .09949 .07533 24.28 AveragePENTACHLORONITROBENZENE .05284 .07328 38.68 AveragePHENANTHRENE 1.04193 1.01343 2.74 AverageANTHRACENE 1.08124 1.05767 2.18 AverageDIBUTYLPHTHALATE 1.40559 1.46101 3.94 AverageBENZIDINE .01710 - - AverageFLUORANTHENE 1.02566 .97417 5.02 AveragePYRENE-d10 SURROGATE .00020 - - AveragePYRENE 1.07620 1.04306 3.08 AverageTERPHENYL-d14 SURROGATE .00005 - - AverageP-DIMETHYL AMINO AZOBENZENE .63930 .56641 11.40 Average4,4'METHLENBIS(2CHLORANILINE) .49360 .44604 9.63 AverageBUTYLBENZYLPHTHALATE 1.08094 1.08806 .66 Average3,3'-DIMETHYLBENZIDINE .86620 .77792 10.19 Average2-ACETYLAMINOFLUORENE .17525 .18101 3.29 Average3,3'-DIMETHOXYBENZIDINE .00018 - - Average3,3'-DICHLOROBENZIDINE .58294 .57581 1.22 AverageBIS-2-ETHYLHEXYLPHTHALATE 3.10117 3.47653 12.10 AverageBENZ(a)ANTHRACENE 1.85044 1.59897 13.59 AverageCHRYSENE 1.61598 1.56277 3.29 AverageOI-n-OCTYLPHTHALATE 3.09418 3.47653 12.36 Average,12-DIMETHYLBENZ(a)ANTHRACENE .54204 .56579 4.38 Average

dENZO(b)FLUORANTHENE 1.55146 1.30501 15.89 AverageBENZO(k)FLUORANTHENE 1.38812 1.30501 5.99 AverageBENZO(a)PYRENE .95775 1.07858 12.62 Average3-METHYLCHOLANTHRENE .56878 .55953 1.63 AverageINDENO(1,2,3-c,d)PYRENE 1.15636 1.07206 7.29 AverageDIBENZOCa.h)ANTHRACENE .90924 - - AverageBENZO(g,h,i>PERYLENE .89690 - - AverageDIBENZO(A,E)PYRENE - AverageDIBENZO(A,H)PYRENE - AverageDIBENZO(A,I)PYRENE - Average

~"F - Response Factor from daily standard file at 50.00 UG/ML


XDiff - X Difference from original average or curve

Page 3 of 3RRI03M9

• SIsOS

QUANTITATION REPORTS FOR SEMIVOLATILE WATERS

RR103I20

871202 15:37871202 13:48

1.000

.,-7223 -----CLPK REFCRT

Operator ID: MCK Cuant Rev: "4 Cuant Timetput File: A37233::E3 Injected at

dta File: >37233::E7 Dilution Factor•ame: UESTDN P.71103S-01PMisc: 35-310810 IH-1.0 DAH 02DEC87

ID File: ICFEI::JKTitle: EDAT SEMIvCLAJILES FCR FEI . .Last Calibration: 57120': 16:15 :

Compound R\T. Scan"' Area Ccnc Lnits a

1) *1,4-CICrLCRCEENZENE-d4 i0.22 754 59677 50.00FFM L-t7) 2-FLlCRCFhEMIL 31RRCGPTE 7.55 401 2279^3 60.74 CFM -I

11) FrENOL-d5 SLRRCGPTE £-.49 c57 ! 76567 45.37 FFf11 £-»30; *rjPF(-THPL£NE-d8 .. ! 3.35 : ! 167 204972 50.00 FFf1 ' ;rl32) NlTRGBENZEhE-d5 SLRRCGPTE 11.57 932 146421 94.00FPM 9555) *PCEhPFhT(-E:K'E-d10 17.99 : 1779 100916 50.00 PPM 100til) 2-FLLCRGEIPHENYL SLRRCGPTE 16.24 1548 161227 53.58 PPM 10088) 2,4,6-TKIE'RCMCFhENCL SLRRCGPTE 20.05 2051 62840 76.92 PPM 9-489) *FHENANThREr€-d10 21.81 2282 58824 50.00 PPM 97104) *CHRYSENE-d12 28.82 3200 38213 50.00 PPM 95105) TERFHENYL-d14 SURROGATE 25.99 2831 73874 69.88 PPM 100118) *PERYLENE-d12 34.09 3887 26506 50.00 PPM 100

* Compound is ISTD

103121,

TON a?M838-81A 35-310*18 IH=1.0 DftH 82File ,-37233 35 .8-450 .8f««u . UES

8 12 16 28 24 28 32 36 48 44 48

RRI03I22

SAMPLE WORKSHEET FOR SEMIVOIATILES

CONTRACT NAME Westoft LaboratoriesCONTRACT NUMBER 325-001-01-01______RADIAN CONTACT Rob Richardson_____

SAMPLE DESCRIPTIONSAMPLE NO. (SAM) A711038-01A ANALYTE(S) [jg.] 8270 [_] TCLP

[_] OTHER _______

SAMPLE TYPE [jg.] AQUEOUS [_] SOLID [_] ORG LIQ [_] SORBENT[_] OTHER

SAMPLE IDENTIFIER 6572___________________ COMMENTS

SAMPLE PREPARATIONEXTRACTION METHOD [XX] 3510 SEPFUN [_] 3520 CONTIN [_] 3540 SOXHLET


SAMPLE SIZE ______ gms DATE EXTRACTED 10 -November-19 8 7Too mL ANALYST -T o _________

SURROGATE SPIKING t DO uL OF ________ ug/mL SP-S-035___ uL OF ______ ug/mL _________

OTHER SPIKING Jnii_ nY OF ______ ug/mLOF ______ ug/mL

EXTR. SOLVENT [XX]CH2CL2 [ _ ]OTHERFINAL SOLVENT [2Q£]CH2CL2 [ _ ] OTHER

FINAL CONCENTRATE VOLUME t-c mL VOLUME DELIVERED ______ f.Q mL

CLEANUP PROCEDURE _____ -- -— " __________________________VOLUME CLEANED — -mL FINAL VOLUME — mL VOLUME DELIVERED _______ mLCOMMENT

DATE SUBMITTED //~//-f7 SUBMITTED BY fr T 0 RECEIVED BY

SAMPLE ANALYSIS

FRN >*?fc*3 DATE INJECTED 266Cg* ANALYST fl*X__________SAMPLE DILUTION _______ mL DILUTED TO___ mL VOLUME INJECTEDINTERNAL STANDARD _________________________________EXTRACTS CIS g/mL 50 OTHERCOMMENT: ____________________________

Cppm - An x ug/mL IS » mL Extract x DFRF mL sample size

ftRi03i23

371201 13:42871201 11:50

1 .000

r:CREF,A372tS

CLPNT REFCRT

arator ID: MCK Cuant Rev: 4 Cuant Time,tput File: A37218::E3 Injpctpd atata File: >37218::E2 Dilution Factor

Name: U.ESTCN A711038-02AiMisc: 35-3IQS10 IH-1.0 35-450amu 30m DE5 CPH 1CEC87

ID File: ICFEI::JKTitle: ECPT SEMIvCLPTILES FCR FEILast Calibration: £71201 10:59

Compound R.T. Scan* Prea Cone Lnits

' > * 1 ,4-C ICrLCRCEENZENE-d4 1 D . 4 J 7\'-. Sfi' -• t 50 . 00 FFP7.) 2-FLLCRLPhEhCL SURRCGPTE - 7.65 :^9 :!Fl2tc. S5.1'- FFT

11) F(-Et-'CL-d5 SLRRCGPTE 9,65 6!2 2F4244 -15.98 FFf^SO) ^h'PFf-ThPLEhE-dS 13.57 M 29 :: 16020 50.00 FFP12; MTRCEENZENE-dS SLRRCGPTE 11.77 392 :::87f)l CQ.3SFFM55) *PCENPPhThEhE-d10 16.17 1726 151129 SO.OOPFr61) 2-FLLCRCEIFÊhYL SLRRCGPTE 16.40 1502 370542 82.23 PPM 10088) 2,4,6-TRIBRCMCPhENOL SURROGATE 20.24 2008 128899 105.36 PPM 9989) *PHENPNTI~RENE-d10 22.02 2242 246148 50.00 PPM 94104) *CHRYSENE-d12 29.00 3158 125116 50.00 PPM 98105) TERFhENYL-dl4 SURROGATE 26.18 2789 294974 85.22 PPM 100118) *PERYLENE-d12 34.41 3865 109316 50.00 PPM 100

* Compound is ISTD

File >3721B 35.8-450.8 a»u . !jff§TON-s .J f<.

488888-

448888-

488888-

368888-

328606-

288888-

248888-

288888-

168888-

126686-

88888-

48888-

£t_8-1 , . , . - ,

t.

\

GL^

^

l•i

,Ci

,y8

i I» â. at> *

-- I §A'9i:i1<**1»1<•3*n

L

*' 1 1i <* f £>?i -^ ^ -o .2!f^-i2 «•* <2

1jb

i -j.U "3-.s r%lT

A;

£C•

*JJ.'if " 'i' 1 ' ' '

"0_••o/1.3T ?Ul

_s^

i-

A' i ' r24

fl71

s-5I_»I*sJ5'*•

1

1838-020 35-318818 IH-1.0 35-458L

<4

T,

Urf

<3 -J^ =? •?V

-'s's'

t ———————————T-o1

S

; I

:iee.r98•ee:-78'.

J68•;8

'•"-49

-38

-28

-18

' 1 ' 1 ' 1 ' 1 ' 1 ' 1 • 1 • 1 • 1 ' 1 • 1^*32 36 48 44 48

//--TO

5' Y



SAMPLE DESCRIPTIONSAMPLE NO. (SAM) A711038-02A ANALYTEfS) [3QJ] 8270 [_] TCLP

[_] OTHER _______

SAMPLE TYPE [£XJ AQUEOUS [_] SOLID [_J ORG LIQ [_] SORBENT[_J OTHER



C_J 3550 SONICA [_] 3580 DILUTION[_] OTHER ________________________________________

SAMPLE SIZE _____ gma DATE EXTRACTED 1 0 -November- 1987mL ANALYST fl -3TQ

SURROGATE SPIKING f QQ uL OF ______ ug/mL SP-S-035____ uL OF ______ ug/mL

OTHER SPIKING -) *__uL OF ______ ug/mL___ uL OF ______ ug/mL

EXTR. SOLVENT [XX]CH2CL2 t _ ]OTHER ________FINAL SOLVENT [£X]CH2CL2 [ _ ] OTHER

FINAL CONCENTRATE VOLUME ]-D mL VOLUME DELIVERED |- 0______mL

CLEANUP PROCEDURE ______^—"_____________________________________VOLUME CLEANED mL FINAL VOLUME mL VOLUME DELIVERED _______mLCOMMENT ______________________________________________________

DATE SUBMITTED U'll-g7 SUBMITTED BY fl-Jd RECEIVED BY /ff £*

SAMPLE ANALYSIS

FRN > 3 /g DATE INJECTED /£CC&* ANALYST ____________SAMPLE DILUTION ______ mL DILUTED TO___ mL VOLUME INJECTEDINTERNAL STANDARD _______________________________________EXTRACTS CIS,ug/mL 50 OTHERCOMMENT: ________________________

Cppm « An x ug/mL IS • mL Extract x OF

RF mL sample size

871201 14:00871201 12:51

1 .000

l~ T T /::REF,A3721S ^

CLPM REFCRT

Cperator 1C: PCK - _ .. Cuant Rev: 4 Cuanttput File: A,;7219::t3 . Injected at

jta File: >37219::E2 Dilution Far.torame: WESTQN A711038-03A

Misc: 35-310610 IH-1.0 35-450amu 30m CE5 DAN 1DEC87

ID File: ICPEI::JK . .Title: E'CPT SEMIVCLPTILES FCR FEILast Calibration: 871201 10:5S '

Compound R.7. Scan* Prea Cone Lnits c

i) + 1 ,4-C.ICKCRCEEMEhE-d4 10.38 : 709 103430 50.00 FFf1 '{S7) 2-FLLCRCFHENCL SLRRCGPTE 7.65 . 348 408331 62.78 FF!* rJ!!.) FHENCL-d5 SLRRCCPTE S_.62 " 608 327390 48.54 FF!*1 ~-eZO) *hPFhT!-PLEÊ-d8 <3:.55 :!!27 ::61369 50.00 FFK r-32) NITRCEEr-ZEhE-dS SLRRCGPTE 11.76 890 261232 95.12 FFM r755) *PCENPF(-TÊh€-d10 !S.'6 :'734 168920 50.00 FFM 100ei> 2-FLLCRCEIFhENYL SLRRCGPTE 16.37 J499 407862 80.88 FFM 10038) 2,4,6-TRIERCMCPhENOL SLRRCGATE 20.24 2008 132501 96.90 FFM 94R9) *FHENAh-THKENE-d10 22.01 2241 274249 50.00 PPM S5104) *CHRYSENE-d12 29.00 3158 134686 50.00 PPM QS105) TERPHENYL-d14 SURROGATE 26.17 2787 301944 81.04 PPM 100118) *PERYLENE-d12 34.48 3875 182196 50.00 PPM 100

* Compound is ISTD

10312"?

1 fc^File .>3721<* 35. 9-458. 3§ia«u. UESTOH H711038-33R 35-318018 IH=1 .0 35-458

J TIC

688688-

568888-

528888-.

488888-

448888-

488888-

368888-

328888-

2S08&&*

248888-

288888-

168888-

128888-

88888-

48888-n

- 4^ a 2

13a.ifS

| £J 0

S ^ s•^ I y, JS * >

«£ if \3 ~~ iH OJ l l

111 Ii I 55 1 *5 £ 2_ ."

lii ,1 i,

o O

T»4 7«*.i si •*££

S^

jL

" | *«l Î(S

k *

in/\

i4

_J

f -•o -5L *•vi „.

3 12 16 28 24 28

«S«

U

-188

98

38

-78

8

-58

-48

-38

-28

•18

— 1 ' | — . , . , . — . — . — —— — __ — r—jV32 36 48 44 48

103U8

/ / '


CONTRACT NAME Weston LaboratoriesCONTRACT NUMBER 325-001-01-01_______RADIAN CONTACT Rob Richardson_____

SAMPLE DESCRIPTIONSAMPLE NO. (SAM) A711038-03A ANALYTE(S) [XX] 8270 [_J TCLP

[_] OTHER _______

SAMPLE TYPE [XX] AQUEOUS [_] SOLID [_J ORG LIQ [_] SORBENT[_] OTHER

SAMPLE IDENTIFIER 6582____________________ COMMENTS



SAMPLE SIZE ______gma DATE EXTRACTED 10-November-1987i. Q2.<T mL ANALYST P-CT-C)________

SURROGATE SPIKING )Qp UL OF ______ug/mL SP-S-035____uL OF ______ug/mL _______

OTHER SPIKING ____UL OF _______Ug/mL___uL OF ______ug/mL

EXTR. SOLVENT [XXJCH2CL2 [_]OTHER ________FINAL SOLVENT [XX]CH2CL2 [_]OTHER ________

FINAL CONCENTRATE VOLUME I-O mL VOLUME DELIVERED \

CLEANUP PROCEDUREVOLUME CLEANED ___ mL FINAL VOLUME ___ mL VOLUME DELIVERED _______ mLCOMMENT ______________________________________________________

DATE SUBMITTED _________ SUBMITTED BY ________ RECEIVED BY

SAMPLE ANALYSIS

DATE INJECTED '0£W ANALYST MC«.SAMPLE DILUTION _______ mL DILUTED TO___ mL VOLUME INJECTEDINTERNAL STANDARD _______________________________________EXTRACTS CIS,ug/mL 50 OTHERCOMMENT: ______________________

cppm - An x ug/mL IS » mL Extract x DFRF mL sample size

flRi03i29

uREF,'N37212

CLPNT REFCRT

, - -_ JC: £CK .., „ Cuani Rev: 4 Cuant Time: 871202 12:23tput File: AJ72 2::EJ Injected at: 871123 17:37

ata File: >37212::E1 Cilution Factor: 1.000Name: UESTCN 0711013 O'lfl A-7"0it.OV4Misc: 35-310@10,IH=1.0,35-450amu/.43S 30m DB-5 DPH 23NCV87

ID File: ICFEI: :JKTitle: ECPT SEPIVCLPTILES"FOR FEILast Calibration: £71201 16:15

Compound R.T. Scan* Prea Cone Lnits q

1) -1 ,4-CICrLCRCEENZENE-d4 10.56 7"i7 447C7 50 00 -FiM -•=7) 2-FLlCF-CFf-ENCL SLRRCGPTE 7.86 -80 14RHQ 52 59 FFN ?cM) FI-ENCL-d5 SLRRCGPTE 9.80 .37 122SC1 42 07 FFM '"-1-30) *r-PFHThPLENE-d8 13.69 M51 152293 5f].fiOFFfTl '-":32) NlTRCEENZENE-d5 SLRRCGPTE 11.91 916 116858 100.97 FFM '-555) «PCENPFHTrENE-dlO - 18.29 1761 73271 50.00 PPM 10061) 2-FLLCRCEIFHENYL SLRRCGPTE 16.50 1523 170362 77.98 FFM 10088) 2,4,6-TRIERCMCFHENCL SLRRCGPTE 20.36 2035 64195 108.23 PPM 9589) *PHENflNThRENE-d10 22.15 2272 142118 50.00 PPM 98104) *CHRYSENE-d12 29.18 3200 83546 50.00 PPM 99105) TERPHENYL-d14 SURROGATE 26.31 2823 186130 80.53 PPM 100118) *PERYLENE-d12 34.76 3932 121660 50.00 PPM 100

* Compound is ISTD

RR1Q3I30

flRI03!3i


CONTRACT NAME Wegton LaboratoriesCONTRACT NUMBER 325-001-01-01______RADIAN CONTACT Rob Richardson____

SAMPLE DESCRIPTIONSAMPLE NO. (SAM) A711038-04A ANALYTEfS) [XX] 8270 [_] TCLP

[_] OTHER _______

SAMPLE TYPE [XX] AQUEOUS [_] SOLID [_] ORG LIQ [_] SORBENT[_] OTHER

SAMPLE IDENTIFIER 6583______________________ COMMENTS


[_] 3550 SONICA [_] 3580 DILUTION[_] OTHER ___________________________________

SAMPLE SIZE _____gma DATE EXTRACTED 10-November-1987\s Qi O mL ANALYST ft-XO_____

SURROGATE SPIKING I O O UL OF _______Ug/mL SP-S-035________'____uL OF ______ug/mL ______________________

OTHER SPIKING ____uL OF ______ug/mL_uL OF ______ug/mL

EXTR. SOLVENT [XX]CH2CL2 [_]OTHERFINAL SOLVENT [XX]CH2CL2 [_]OTHER

FINAL CONCENTRATE VOLUME 1- 0 mL VOLUME DELIVERED I- 0 _____ mL

CLEANUP PROCEDUREVOLUME CLEANED ___ mL FINAL VOLUME ___ mL VOLUME DELIVEREDCOMMENT

DATE SUBMITTED l/-M-g"? SUBMITTED BY JV.4.O RECEIVED BY

SAMPLE ANALYSIS

FRN > 377./Z- DATE INJECTED ** *.» ?7 ANALYSTSAMPLE DILUTION _______ mL DILUTED TO ___ mL VOLUME INJECTEDINTERNAL STANDARDEXTRACTS CIS g/mL 50 OTHERCOMMENT:

Cppm - An x ug/mL IS - mL Extract x DF

RF mL sample size

5RI03I32

:CREF,"37214

CLPNT REFCRT

jerator 1C: MCK ' Cuant. Rev: 4 Cuant Time: S71202 13:53utput File: A37214::E3 Injected at: 871123 19:30

Data File: >37214::E1 Dilution Factor: 1.000Name: WESTCM P.711038-05PiMisc: 35-310810, IH-1.0,35-450amu/.43S 30m CB-5 DPh 23NCV87

ID File: ICFEI::JK :Title: ECPT .SEMIVCLPTILES FCR FEI - '.Last Calibration: 871201 16:15 . - .. '.

Compound R.T. :can* Prea Cone Lnits

') *1 ,4-CIChLCRCEENZENE-d4 10.61 : 7-18 4040'-' Sn.OO FFM '-67) 2-FLLCRCFhENCL "SLRRCGPTE 7.89 ' 388 134567 52.97 FFM "5

1!) hrENCL-d5 SLRRCGPTE ?.84 646 116325 44.15 FM '--.30) *NPFhTHPLENE-d8 13.75 ;1164 i"57P8 50.00 FFM c-i32) MTRCEENZENE-d5 SLRRCGATE 11.95 926 107833 104.49 PPM Si55) *PCENPPHTHENE-d10 18.35 :1774 65375 50.00 PPM 10061) 2-FLUCRCEIFHENYL SL'RRCGP.TE 16.56 1537 162635 83.43 PPM 10088) 2,4,6-TRIERCMCPhENCL SURROGATE 20.42 2049 54477 102.94 PPM 9789) *PhEMfiMTHRENE-d10 22.21 2286 125320 50.00 PPM 99104) *ChRYSENE-d12 29.28 3221 72810 50.00 PPM 98105) TERPHENYL-d14 SURROGATE 26.39 2840 163729 81.29 PPM 100118) *PERYLENE-d12 34.92 3964 109060 50.00 PPP1 100

Compound is ISTD

A'Pi i fs O i *"} *"!!R!03 f 33

t-Pieej


CONTRACT NAME Westory LaboratoriesCONTRACT NUMBER 325-QQl-Ol-Ol______RADIAN CONTACT Rob Richardson_____

SAMPLE DESCRIPTIONSAMPLE NO. (SAM) A711038-05A ANALYTEfSl [XX] 8270 [_] TCLP

[_] OTHER _______





SAMPLE SIZE ______gms DATE EXTRACTED 10-November-1987c\ 0 O mL ANALYST______________

SURROGATE SPIKING Joe uL OF _______ug/mL SP-S-035______________uL OF _________ug/mL _________________

OTHER SPIKING ____uL OF ______ug/mL____uL OF ______ug/mL

EXTR. SOLVENT [XX]CH2CL2 [_]OTHER _________FINAL SOLVENT [XX]CH2CL2 [_]OTHER ________

FINAL CONCENTRATE VOLUME \-O mL VOLUME DELIVERED ____]- O roL

CLEANUP PROCEDUREVOLUME CLEANED ___mL FINAL VOLUME ___mL VOLUME DELIVERED ________mLCOMMENT ______________________________________________________

DATE SUBMITTED }\-\i-in SUBMITTED BY ft-Jd RECEIVED BY

SAMPLE ANALYSIS

FRN ?37z/y DATE INJECTED *> .. ?•> ANALYSTSAMPLE DILUTION ______ mL DILUTED TO ___ mL VOLUME INJECTEDINTERNAL STANDARDEXTRACTS CIS/ug/mL 50 OTHERCOMMENT: _____________________

Cppm - An x ug/mL IS * mL Extract x DF

RF mL sample size

CF-EF, '\37213 ._ ._ -.-.- __ ..CLPNT REFCRT

'"-•erator 1C: rCK " Cuant Rev: 4 Cuant. Time: 871202 12~

49.tput File: A37213::E3 ~ Injected at: 871123 18

ataFile: >37213::E1 Dilution Factor: I. 000hame: UESTCN P711038-06PFlsc: 35-310810, IH-1 .0,35-450amu/.43S 30m DE-5 CPH 23NCV87

ID File: ICFEI: : JKTitle: ECPT SEMTVCLPTILES FCR PEILast Calibration: 371201 16:15 :

Compound R.T. 'Scan* Prea Cone '.nits

1 ,4-LlC,uLrRCEENZENE-a4 10.58 742 47-28 50. Of)2-^LLCRCFFENCL SLRRCGPTE - 7.86 381 167536 56.30

11) Ff-ENCL-dS SLRRCGPTE 9 .51 c40 143409 45.46 F^h1 '-c30) *t"PFI-Tr-PLENE-d8 1}L.:;5 ' 1 1 6 1 160124 50.00 PFM --32) MTRCEENZENE-d5-SLFFCGPTE 11.95 S23 120126 96.7! FFM 9-155) *PCENPFhThENE-dH3 18.55 .1771 7865Q 50. 00 PPM i j i icl> 2-FLLCRCEIFh-ENYL SLRRCCPTE 16.56 1534 174390 74. 35 FFM 10088) 2, 4, 5-TRIERCMCPHENCL SLRRCGPTE 20.43 2047 68206 107. 11 FFM 9589) *PhENPN-ThRENE-d10 22.22 2284 153913 50.00 PPM 98

104) *ORYSENE-d12 29.30 3219 87386 50.00 PPM cc105) TERPhENYL-dl4 SURRCGPTE 26.40 2838 198333 82.04 PPM 100118) *PERYLEN,E-d12 34.95 3962 131052 50.00 PPM 100

* Compound is ISTD

RRI03I36

& T33 35-9-4S8.8ja»u. VESTQH ft? 11938-860

5RI03I37



SAMPLE DESCRIPTIONSAMPLE NO. (SAM) A711038-06A ANALYTEfS) [XX] 8270 [_] TCLP

[_] OTHER _______




[_] 3550 SONICA [_] 3580 DILUTION[_] OTHER __________________________________

SAMPLE SIZE ______gma DATE EXTRACTED 10-November-19871,02.0 mL ANALYST______________

SURROGATE SPIKING (c 0 UL OF _______ug/mL SP-S-035________-________uL OF ______ug/mL _________________

OTHER SPIKING ____uL OF _______Ug/mL___uL OF _____ug/mL

EXTR. SOLVENT [XX]CH2CL2 C_]OTHER ______FINAL SOLVENT [XX]CH2CL2 [_]OTHER __________

FINAL CONCENTRATE VOLUME \ • J mL VOLUME DELIVERED >. o

CLEANUP PROCEDURE _____________________________________________VOLUME CLEANED ___ mL FINAL VOLUME ___ mL VOLUME DELIVERED ________ mLCOMMENT ______________________________________________________

DATE SUBMITTED M~M-g SUBMITTED BY A 33*0- RECEIVED BY

SAMPLE ANALYSIS

FRN > s-?z-'3 DATE INJECTED *> *.. f7 ANALYSTSAMPLE DILUTION ________ mL DILUTED TO ___ mL VOLUME INJECTEDINTERNAL STANDARD ___________________________________________EXTRACTS CIS,ug/mL 50 OTHERCOMMENT:

Cppm - An x ug/mL IS * mL Extract x DF

RF mL sample size

flRl03)38

7

RADIANCOHPOM—TIOM

METHOD BLANKS

139

CLPNT FEFC'RT

erator 1C: MCK - Cuant Rev: 4 Cuant Time: 871202 11:22Lutput File: *372I.O::E3 Injected at: 871123 15:47Cata File: >37210::E1 Dilution Factor: 1.000Name: WESTQN A711038-RBSVMisc: 35-310eiO,IH=1.0,35-450amu/.43S 30m CB-5 MCK 23NCV87

ID File: ICFEI::JK . - - ; -Title: EDPT SEPTvCLPTILES FCR FEI ... - -Last Calibration: S71201 16:15 :

C o n> p o u n d R . T. ':.: c an* P r e a C o n c L nit s c— — — —* — — — — — — — — — — — — ——- —- —._,— _ .—, —-^— -— — _— — — -— ,_» — _ _ _ _ _ _ _ ,—._.__„.__--• —- — — _ _ _ ...-. ____ _ __ — —. — .—•

1) *1 ,4-LlCrLCPLEEN2ENE-ci4 10.70' 753 42:':'G9 50.00 FFM -z57) 2-FLLCRCFf-EKL SLRRCGPTE £.02' 3^7 !57733 5^.01 FFM 36M; FHENCL-d5 SLRFCGPTE - b.9J= 652 134014 48.47 FF^ '=950) *NPPHTHPL£NE-d8 13.63! McS 1471^1 SO.HO FFM -" :32) NITRLEENZENE-ciS 3LF.RCCPTE 12.05: G32 98656 88.19 FFM b^55) *PCENPFHTrENC-d!0 . 18.42 1776 71691 50.00 FFM 10061) 2-FLLCRCEIFHENYL SLRRCGPTE !6.63'1C.3Q 140964 65.94 PPM '0088) 2,4,6-TRIERCPCPhEMjL SLRRCGPTE 20.49 '2050 58942 101.56 PPM 9789) *FHENAMHRENE-d10 22.29 2288 134704 50.00 PPM 99104) *ChRYSENE-d12 29.37 3218 79488 50.00 PPM 99105) TERPHENYL-d14 SURROGATE 26.47 2839 152535 69.37 PPM 100118) *PERYLENE-d12 35.09 3961 55544 50.00 PPM 100

* Compound is ISTD

-r«y

rile >3?2ie?3S.0-4Se.8 a_u. WESTON fl?U838-RBSV 35-310318, IH=1 .8, 3S-45JT

248888-~

228880-

280888--

188888-

168888

148880--

120088--

188089-

38980-

68888-

48888-

20888-

ft"

^ -+- -j 3^ 7 -O aL

jm4_j__ii

"3 > C

v |3 I ±_ff CO ~3 T ? y * 1

f# *? 3 5 -3. l ^T ^V - a s ^ ^ ' ^"ti

£•

~ •*

> *. ~ ÎIIill^3 P £<r.

<

2 3

*•• ~--J

Q.

I<r

L- =->!

JJ *Si S <N* 1— U< —| , ,•5£

*•• -~- '

o '

f f5 r-&Q—

s"^ — ———8 12 16 20 24 28 32 36 48 44 48


CONTRACT NAME Western LaboratoriesCONTRACT NUMBER 325-001-01-01_______RADIAN CONTACT Rob Richardson_____

SAMPLE DESCRIPTIONSAMPLE NO. (SAM) A711038-RBSV ANALYTE(S) [J_XJ 8270 [_] TCLP

[_J OTHER ________

SAMPLE TYPE [2X] AQUEOUS [_] SOLID [_] ORG LIQ [_J SORBENTOTHER method BLANK___________

SAMPLE IDENTIFIER _________________________ COMMENTS

SAMPLE PREPARATIONEXTRACTION METHOD [2££] 3510 SEPFUN [_] 3520 CONTIN [_] 3540 SOXHLET

[_] 3550 SONICA [_] 3580 DILUTION[_] OTHER ______________________________________

SAMPLE SIZE ______gms DATE EXTRACTED IP-November-1987<0 o o mL ANALYST______________

SURROGATE SPIKING I co uL OF ______ug/mL SP-S-035________"_____uL OF ______ug/mL _________________

OTHER SPIKING ____uL OF _______ug/mL____UL OF ______ug/mL

EXTR. SOLVENT [XX]CH2CL2 [_]OTHER ________FINAL SOLVENT [2QJ]CH2CL2 [_] OTHER ________

FINAL CONCENTRATE VOLUME i-o mL VOLUME DELIVERED I- O mL

CLEANUP PROCEDUREVOLUME CLEANED ___ n»L FINAL VOLUME ___ mL VOLUME DELIVEREDCOMMENT

DATE SUBMITTED \\-tl- SUBMITTED BY A X-o RECEIVED BY MC

SAMPLE ANALYSIS

FRN >377./e DATE INJECTED ^ »>* 97 ANALYST Met- ______________SAMPLE DILUTION ______ mL DILUTED TO___ mL VOLUME INJECTED /..g.~c-INTERNAL STANDARD _____________________________________________EXTRACTS CIS/ug/mL 50 OTHER ___________________________COMMENT: __________________________________________________


BRI03U2

REFCRT

Cperator ID: PCK Cuant Rev: 4 Cuant Time: 871202 15:55'" +.put File: A37234::E3 Injected at: 871202 14:43

ca File: >37234::E7 Dilution hactor: 1.000dme: kSTN £711038-016 MS

Misc: 35-310610 Ih-1.0 DAH 02DECS7

ID File: ICPEI::JKTitle: EDAT SEMIVCLPTILES FCR PEILast Calibration: 671201 16:15

Compound R.T. Scan* ^rea Cone ;..nits -a

•> *1 ,4-CIChLCRCEENZENE-d4 '0.27 759 4P3'C Ô.OOFFP1 -77.i 2-FLLCRCFhEKL SLRRCGPTE 7.54 4'in ;:3214 27.-CFFM 7-

11) PHENGL-d5 SuRRGGPTE '-.53 662 73:-7rir 2-'.44Ppr ::12) PI-ENCL 9.55 665 -645 if 57.S2 FFf1 ::Vi17) 2-ChLCRCFHENCL 9.66 706 !072'21 79.95 FF(* :-sOIS) !,4-CICHLCRCEENZENE 10.30 763 5t::24 38.^9FFf '^;27) N-MTRCSCCI-n-FRCFYLPTlNE !1 .30 S95 52916 55.81 FPF 9430) *f-'PFhTI-PLENE-d8 1.3.42 1175 162925 SO.OOPPf 9232) N:ITRCBEhZEN'E-d5 SURROGPTE 11.62 938 59527 48.08PPf $*42) 1,2,4-TRICHLCRCBENZENE 13.32 1162 41113 42.17 FFH 9851) 4-CHLCRO-3-ri!ETHYLPhENOL 15.00 1383 129841 139.98 PPM 9655) *ACENAPHThENE-d10 18.06 1787 92167 50.00 PFM 10061) 2-FLUGRGBIPHENYL SURROGATE 16.30 1555 107395 39.08 PPP1 10071) ACEHflPHTHEHE 18.13 1797 116487 45.41 PPN 9573) 4-NITROPHEHGL 18.55 1852 33236M 51.71 PPfi 100) 2,4-DINITRGTOLUENE 18.62 1861 36530M 46.85 PPfl

d) 2,4,6-TRIBRGNGPHEHGL SURROGATE 20.16 2064 28720 38.49 PPMo'9> *FNENANTHRENE-d10 21.93 2297 140681 50.00 PPM95) PENTAChLGRGPHEHOL 21.63 2258 10262M 36.66 PPM 9299) DIBUTYLPHTHALATE 23.49 2502 230851 58.37 PPM 98

103) PYRENE 25.76 2800 145210 47.96 FFM 100104) *CHRYSENE-d12 28.96 3218 67459 50.00 PPM 97105) TERPHENYL-d14 SURROGATE 26.09 2844 79507 42.60 PPM 100118) *PERYLENE-d12 34.36 3922 63446 50.00 PPM 100

* Compound is ISTD

ARI03U3

SAMPLE WORKSHEET FOR VOLATILES

CONTRACT NAME WESTQN________CONTRACT NUMBER 325-001-01-01RADIAN CONTACT RICHARDSON

SAMPLE DESCRIPTIONSAMPLE NO. (SAM) A711041-08A ANALYTEfSlTYPE [_] AQUEOUS [2Q_] SOLID [_] ORGANIC LIQUID [_] SORBENT

[_] OTHER ___________________________________

SAMPLE IDENTIFIER 6584COMMENTS ____________

SAMPLE PREPARATION DATE EXTRACTED //•/?--*"7AQUEOUS SAMPLES

__ 5 mL OR ____ mL (SMP*) DILUTED TO 5 mL H2O; DP-

SOLID SAMPLESg (SMPSZ) INTO 3°'' mL Methanol (EXTVOL)

mL Methanol (SMP*) ADDED TO 5mL H2O FOR ANALYSIS DF-

SURROGATE SPIKE: ____ UL OF ____ ug/mL __________ , LOTfCOMMENT: _____________________________________________

DATE SUBMITTED //- /* "7? SUBMITTED BY ;zgSc. RECEIVED BY

SAMPLE ANALYSIS

FRN ______ DATE ANALYZED ________ ANALYST _________INTERNAL STANDARD Vl-IS OTHER __________________AMOUNT ADDED ng __ 100 __ 250 __ OTHERCOMMENT: _______________________________

An X CIS (ppm) X DF EXTVOL 5Cppm » ___________________ X ____ DF - ___

RF SMPSZ SMP*

SURROGATE CONCENTRATION (Cs): ________ppm

ug SPIKED EXTVOLCs - X

SMP* SMPSZWVO.JSF

/JR I 03 I If

18.747

6.528

152.158\52.928

flRi 031^5 \54.222STOP

STOP

RUHi 422 HOV 24. 1987 93:19:18

SAMPLE! 12AREA*

RT AREA TYPE WIDTH AREA*1.956 626462 PV .839 8.485612.873 1255276 V8 .152 16.842774.918 25975 VP .878 .348524.272 183t9 PV .866 .138324.32S 18281 W .868 .137954.514 1735 VP .113 .823235.255 29Si PV .158 .flS' S5.79* . — 2832 W .184 .d2S«76.523 £4271860 P8 .998 64.62<>357.545 5»¥llir 88 .894 .7* 118.376 7792 PB .182 . !-?4«.18.754 22874 PB .115 .:*»!13.695 6248 PB .157 ."-3;."16.511 3139 8V .143 .*4ii..18.348 168 PV .868 .«*>!*25.745 11877 PV 3.599 . .*, • v28.267 2787 PV .332 ."i -i32.795 34659 VV 1.958 .4..«J433.847 12I> PP .W .Ml* >-39.594 3715, PP «.1?2 .•••>••*49.747 7188 8V .241 .*»,*-•52.226 287892 VV 1.528 i.:-'-'~\.

a r% I f\ <-s i , *. 54.378 288936 VV t.,'43A II 1 U O I U fi 54.949 96449 I VH . 67 t. -••»!!

TOTAL AREA»7452999

I.J84

Jl.oii

52.21153.192

STOP

RUM 424 HOV24, 1987 85:16:26

SAMPLE* 14AREA*

s-a 'HI 1 "™ -•--: 38 ,88 R :jg ••»?{i: 1

. :i5 ;

U5?f1l S :!S

flRI03|l,7'

PP .2*5

g-fg 6138. sv :i?2 4 .;.-"33.235 7998 VV . 9H-2iS «???'» .4% ,.,..;

TOTAL A«Eft«2.2622E»97WJL FACTOR=

&K8IS «wn - ^b NOV 24. 1987 87:13:46

AR I 03 I if 8

START "*" NUV ' 198? 99;11:81

.52.32153.356

£"'RUN t 438 NOV 24, 1937 n-88-1-5OTAOT i 2v- H'wy'/lO

a2W33.568

RRI03152

24.57825.899 isi 'lot -9217«25.435 fell JJ '»} -8583426.332 3311 VV '12 '2466«26.837 53845 VV ' <95134

gaa? as :ISS » i11695 PV

33.568 587177 VV

SS? HSJI JJ • :31:211 S J .: •'37.756 584648 VV 24? ,'!g?i

II 1 !i i i I1 1 § f

18339 W [In 'wSi?!!!i 1U :1 %?

.1 u i iTOTAL AREA=2.5925E+87WL FACTORS. eeeel+S

ftR!03i53

7Y 7 J RUHt 431 HOV 24, 1987 12:87:

SAMPLED 21

AREA*RT AREA TYPE yiDTH AREAZ

2.821 264310 PV .889 .584292.159 974517 W .187 1.859342.269 991293 W .893 1.891352.362 687772 W .899 1.312242.488 381650 VV .073 .728172.568 428426 W .876 .88216 .2.617 599245 VV .116 1.143342.898 1405571 W .242 2.681773.188 155706 W .849 .297883.179 327641 W .193 .625133.292 400577 W .129 .764283.453 469214 W .135 .895243.620 792647 W .169 1.512343.862 241407 W .125 .460594.824 353145 W .181 .673794.198 131280 W .889 .258484.399 819991 W .215 1.564514.761 288919 W .189 .551254.973 285881 VV .160 .545455.886 294876 W .181 .561895.339 396022 W .202 .755595.611 261821 W .187 .499545.844 295132 W .185 .563105.947 356545 W .222 .680276.318 282608 W .187 .539196.550 3382941 W .102 fr.301886.838 465469 W .148 .888187.078 352858 W .354 .671787.575 153283 W .158 .292467.786 83332 W .109 .158997.845 172847 W .215 .328268.228 217352 W .261 .414788.484 142131 W .198 .271188.700 150858 W .248 .286309.135 1427611 W .128 2.723829.557 106632 W .230 .203459.857 49784 W .152 .8948318.040 126821 W .331 .2404410.425 27312 W .134 .8521110.580 44434 W .181 .0847818.799 57662 W .210 .1180211.272 37538 W .267 .8716211.455 33269 W .222 .8634812.251 38851 BV .239 .8741312.470 11193 W .141 .8213612.886 26119 W .167 .8498313.132 18382 VP .278 .8350713.730 40976 PV .193 .0781814.444 30471 W .214 .0581414.610 13552 W .130 .0258614.777 28855 W .170 .8382615.071 37698 W .234 .8719115.818 8498 VP .156 .8162016.546 624053 PV .151 1.1996716.838 1182841 VB .158 2.1826517.851 18485 W .385 .8351218.359 188684 W .348 .1921019.715 4869 PV .216 .8892920.238 28959 W .255 .0399920.677 1211 VP .286 .0023120.979 801217 PB .156 1.5286921.438 2891 BP .1.66 .8855221.923 6961 PV .313 .01328

• Z*'531 25857 w •267 -8478122.913 9664 W .216 .0184423.383 28433 W .423 .8542524.298 6124 PV .229

13.695

32.246

ftRl03i55\52.515\53.43J

STOP

RUH* 433 NOV 24, 1987 14:84:24

SftdPLE* 23

ta <i"!'l! ..a2-388 1876 PP 8682.578 1975 PP .889

938 PP .1.7

JJ rig£85

55 :5J :!

i •13.775 9218 VP .164}*-j« u?? PB :1SJ15.496 21li BV .144

W .1557' » W -16317.46i <337227 W .166 417.884 - ff ye 16618.588 9Mf. BV 168

11-12 ^ S :}"19.34S TES66 W .174 2»-"| ,JJ?J W -147 .2594628.476 11811 PV .165 1 75»u»••*} agi w a" 3:3712221.151 -6523 W .178 96657

V8 :,« fiJIlTS'18§ 1-32629« « / i • -23. 431 (63753 J W .295 9 446ft";

24.878 M« W 358 .7568124.665 4746 VP .173 7632625.112 264% PV .188 39261525.371 28493 W .259 4.22286IM£3 ^ W >*Z26.684 228*. .W .172|/.|lt S> W .23527.824 4683 VP 2'228.491 3589 pV ilsl

|.3« 38% BV .2J,31.173 !14«1 uv ->o->

pi

4.2.911.877.83544.65545.367

r

HR103I58

STOP

RUHt 435 NOV 24, 1987 15:41:18

SAMPLE! 1AREA*

RT AREA TYPE UIOTH AREA*1.997 164388 PV .887 .367632.118 123579 VV .891 .276382.211 35522 VV .852 .879442.288 72712 VB .118 .162622.782 88187 BV .887 .179332.891 5472 VP .858 .812243.894 58845 PV .116 .113713.861 8286 PV .879 .818534.844 3194 VP .138 .887144.395 25278 PP .874 .856524.728 584215 PB .882 1.127655.439 1394936 BV .189 3.119785.865 184289 VV .242 .233246.617 99835 PB .886 .221497.843 116726 B8 .872 .261857.653 1554 BP .115 .883488.868 1585 PP .173 .883548.656 2828326 PB .896 6.3254818.111 2329878 PB .152 5.2186311.828 3273 VP .115 .8873211.243 1871 PV .118 .8841811.468 8318 VP .226 .8186812.223 3733 PV .151 .8883512.592 4655 VV .197 .8184113.424 5455 PV .385 .8122013.848 28386 VV .208 .8454114.985 211854 VV .195 .4728116.675 36503424 VB .145 81.6388218.519 1688 BP .155 .90378n

TOTAL AREA=4.4714E+07HUL FACTOR=1.0000E+00

,i n \\ U 0 I» U

STOP

RUNt 437 NOV 24, 1987 16:3l!58

SAMPLE! lAREA*

RT AREA TYPE yiQTH flOEfly.298 2«2« BV 943 .02297.238 3566 VP .858 84855•S \%* w •969 -feS*• 568 3234 W .117 .93677'•?f6 11224 BP .885 lil/M2.176 12789 PV .843 .145422.226 29668 VV .881 .337Jb3.547 6465 PB .963 .«,-;.«. l4.294 2444 B8 .866 .W7«7.922 1872 BV .113 !ji->n8.552 13123 PB \\W 'u---9.469 2821 PV .312 .*;:*812.685 1543 PV .148 .HI"'15.583 28997 PS .159 .-'16.427 4357 BV .192 '^-*17.924 54577 VV .,71 - .,,21.814 74553 VV Z.Wi ' '23.185 56588 VV 1..4924.478 74843 VV I.J4526.785 158172 VV . w28.545 98172 VV . ',:j29.382 72539 VV ..-*»32.836 399279 VV Z.'fit,33.628 162874 VV . O435.988 358273 VV 1.3.3836.638 128942 VV .- '137.438 174529 VV ..j4138.688 226559 VV . «a39.947 47489 VV . »01

RUNt 438 HOV 24, 1987 17:38:37

- SAHPLEf 2AREA*

RT AREA TYPE yiOTH AREA*1-998 79213 PV .888 88«n2.898 57367 VV .185 .' 862302.253 25881 VV .8582.387 60819 VV .1192-628 221662 VV 892.827 23284 VV .8683-823 128611 VV .H8

VP .1034.295 57832 PP 874 061944.615 1158928 PB .886 1 249975.335 4687187 PB .213 5 898586.475 282564 PB 890 386886.893 234552 BB !078 ! 254747-498 3434 BP .111 aa™8.477 4318483 PB 82 4! 681369.915 6783674 PB .172 7.28068.022 3268 PP .093 80355

11.261 13669 PP .238 8148512-25 JfS? CX -™ -«S12.487 11141 VV .235 fli?ia13.605 89888 PV 368 8976214.634 529619 VV .382 5752816.420 73184192 VB !l73 79:4825321.832 3182 PV .323 .88346S'!}? %P VV '348 ' 35726.616 2854 PV .263 .8831828.155 2917 PV .286 .8831730.552 2587 VV .249 .8028130.990 6682 VV .214 .8872631.582 5846 VP .257 .8854832.548 4249 VP .282 .8846133.345 18140 PV .208 .0110133.666 6445 VP .221 .8878635.243 2498 PV .235 .8827135.754 1945 VP .219 .0021136.630 4187 PV .312 .88455?7*i!5 JIK VP '247 -*W6S'SZ 4746 PV -203 -6851539.713 4854 PP .284 .8852748.215 28493 PV .244 .8222641.555 5649 PV .297 .8861442.580 7161 BP .426 .8077843.375 10387 PV .434 .8112844.214 16361 VP .299 81777JJ-891 7787 PV .283 ! 0884646.213 7334 PP .195 .88797£-£? 2?63 PV -328 -82250.642 2339 VV .113 .8825452. 69 18519 VV 1.118 .8114253.181 7832 VV .234 .88764

TOTAL AREA=9.2876E+87NUL FACTORS. 8888E+00

flR103!60

f l R ! 0 3 i 6 l

•$- ? ' 3AREA*

2-«S ?$%"% "IDTH flRE«*'X-ll PV .68i 4.97678W .111 8.17647w 'iff 8-'«8385rss 18677<( « :?2? •*4K2.878 382849 VV 215

3-275 58894 VV 5783.414 138469 VV .185

:| 1S X :!S43:?H 1IH Xvv :ia >»&8288 VV4.368 278682 V84.728 5667 BP .886 a«

1 1 1 i 1

I l12:i7f ,Jg| ^ • -86838

liliiMill3 7 JJflffl w I :9

26.168 3483 PV 228 a?4o

p S5.I 1I 1 I I Iil 1 1 1 M

v :H838.925 1644 PP 179

v1 1 i i 1Ii S S 1 \ III 1 1 1 ;:46.876 582121 P 'f« 4'"

RUNf 448 HOV 24, 1987 19:27:56

SAHPLEt 4AREA*

RT AREA TYPE yiOTH AREA*1.989 194435 PV .884 .587682.120 787837 VV .186 2.381242.240 656981 VV .896 1.985482.346 199817 VV .077 .693952.438 138824 VV .068 .395422.549 121255 VV .971 .366492.583 268658 VV .117 .694682.865 478712 VV .247 1.446913.128 94485 VV .898 .285343.259 112839 VV .124 .341863.398 138843 VV .116 .395473.575 214276 VV .142 .647653.889 33285 VV .187 .188683.972 45341 VV .113 .137844.139 11269 VV .871 .834864.338 146484 VB .186 .442514.789 6543 BP .885 .819784.926 7828 PV .874 .823645.831 25698 VV .152 .877675.290 84353 VV .133 .254965.546 19813 VV .134 .857475.732 35534 VV .148 .187486.244 y 25802 VV .113 .887666.473 ,299594?) VV .897 9.855236.768 "-12183Z VV .128 .368387.809 27245 VP .207 .882357.490 44793 PV .115 .135397.762 16658 VV .138 .858358.142 22452 VV .191 .867868.308 18315 VV .113 .831188.685 82B5. VP .160 .824889.840 /9T6427T PB .110 2.838359.474 —776 BP .118 .823469.989 33374 PV .199 .1888718.469 6253 VV .132 .8189818.686 14989 VP .128 .8453011.161 8182 PV .158 .8247311.369 7289 VP .171 .8228312.148 15955 VV .192 .8482212.359 11121 VV .149 .8336112.695 9645 VV .157 .8291513.833 4596 VP .248 .8138913.618 23363 PP .165 .8786114.329 18788 PV .191 .8323414.651 18320 VV .160 .8311914.944 12437 VV .174 .8375915.683 5445 VP .159 .8164616.415 < 843178: PV .152 2.5484816.694 rTSSlSn VB .158 2.3136817.742 ——5T5T BV .335 .8186518.235 39562 VV .331 .1195819.598 781 PV .093 .8823628.896 -—8585. VV .279 .8259528.835 74888591 PB .156 1.4534021.297 ——39W BP .179 .8128821.828 2189 PV .387 .8866222.375 12217 VV .256 .8369322.776 6983 VV .218 .8211123.180 21943 VV .403 .8663224.875 6211 PV .218 .8187725.265 12955 PV .314 .8391625.898 2779 VV .246 .8884026.204 6799 VV .265 .82855'26.670 33081 VV .253 .8999927.750 28010 VV .256 .8846628.2l5x 84488 VV .221 .25512Ô / S 4 « /\**«.« !»«» .-v«.- - _ ^ ^ _

I/^

RRI03163

16.538

9.97711.7(9

12.245

' 13.71414.477

6.538

16.541

STOP

RUM i 444 NOV 24, 1987 23:22:37START ,i /j /\ f—

28.589

i25.37926.775

43.468

88121,17

18.318M

26.752

131.73132.679

~" 33.791

RI03I67

RR103I68

RUN, W NOV25.,987 e2!18!3,

'8.5519.43418.298

,123 "•'

25.359

38.387

32.67833.812

flR!03I69

START

1.956

RR103HO154.227

JT 5.7796.427

25.295

28.76731.175

'fctt[33.841

35.357

21.431

STOP

RUN* 431 NOT 25. 1987 86:13114

SAMPLE* 15AREA*

RT AREA TYPE U10TH1.973 13454 8P .889 .474832.247 46847 PB .112 1.653374.316 15987 PV .195 .532474.498 1638 W .687 .&57815.24« 1958 88 .9995.782 1215 PB .1*113.678 3585 PB .29816.49f 3796 BV .24821.431 3218 PV .654 .1 !;•>."24.985 546 PV .144 .i\~t.-26.841 3577 PV .198 .'.:T_+27.793 3366 VP .449 ...,:•?28.347 57395 PV . 82 ±.4.:<i*29.543 2778 VV .315 .)••»•«39.152 1746 VP ..»9938.819 92598 PV .19731.438 19543 VB .l'?332.342 17383 VV .J1333.242 11438 VV .19333.797 1678 VP ..14735.326 269684 PV .&£35.729 239674 VB ,:i837.978 231519 PV .-»538.689 58855 VB .JliJ9.726 52348 P8 . 1442.658 594878 PB .-Ii45.822 115638 PB ..a*53.123 "5611 PV 4 '"i

RUN* 452 NOV-25, 1987 89:15:30

SAMPLE! lAREA*

RT AREA TYPE MIDTH AREA?1.967 39180 PV .893 6.542822.198 66165 VV .064 11.871752.242 75347 VB .067 12.608223.119 514 VP .856 .08681:4.324 2961 BV .875 .495485.252 1967 BP .123 .3291513.434 18017 PV .141 1.6762013.680 9788 VP .166 1.6231514.649 6757 VB .194 1.1386915.403 1469 PV .156 .2458216.489 6970 VV .160 1.1663316.839 1506 VV .158 .2529117.874 7742 VV .169 1.2955117.358 '28883/ VV .173 3.3686017.774 —3123 VB .175 .5225918.475 5376 8V .175 .8996818.857 /29119k W .286 4.8726419.238 "9411 VV .190 1.5747928.359 6660 PV .172 1.1144520.725 18262 VV .194 1.7172021.029 4302 VV .190 .7198821.425 28487 VB .205 4.7668922.265 5557 BV .194 .9298822.622 4568 VV .210 .7643923.300 39068s VV .334 6.5374624.530 ~4926 VV .250 .8242924.977 16210 VV .201 2.7125125.2% 35864 VV .332 6.0013225.925 11954 VV .341 2.0003326.465 5074 VV .222 .8498626.704 9877 VV .266 1.6527727.065 39208 VV .302 6.5608928.175 5621 PV .335 .9485928.740 6672 VV .389 1.1164629.181 14615 VV .377 2.4456138.149 6007 VV .464 1.8851831.820 5940 VV .296 .9939732.341 4345 BV .262 .7278733.768 15572 VV .674 2.6857534.668 19486 VV .619 3.26878

flRi03!7l+

/./" f SIOP

RUNi 453 NOV 25, 1987 10:14:18

AREA*RT AREA TYPE UIDTH AREA*i

1.965 46872 BV .899 1.82849*2.194 73967 VV .866 1.623832.239 88849 VV .867 1.774842.517 3587 VV .127 .878713.187 691 BP .854 .815164.297 4439 PV .875 .897404.477 1423 VV .875 .831225.219 2883 8P .138 .861516.368 4868 BV .362 .8898912.890 1333 PV .178 .8292513.348 45457 BV .145 .9974513.599 21784 VV .178 .4788814.558 26274 VB .168 .5765215.395 6787 PV .152 .1471715.798 2837 VB .281 .8447816.395 3939 PV .159 .8864316.747 7342 VV .147 .1611816.988 37442_ VV .178 .8215817.255 7894787 VV .177 1.9632117.676 TCJTB VB .174 .3141718.377 25354 BV .178 .5563318.757 ri2»Jb4" VV .218 2.8163819.131 42582 W .185 .9343619.892 5832 PP .158 .1184228.255 32161 PV .172 .7857828.621 62887 VV .192 1.3799628.924 21444 VV .186 .4785421.321 rl337W: VB .285 2.9356822.158 ~ 26277 BV .188 , .5765922.515 28268 W .201 .4445623.194 rlTTWy W .328 3.7532823.829 28TO1 W .396 .4494_fl_.24.417 16189 VV .288 .3552V24.866 68993 VV .192 1.5138925.147 187987 W .307 2.3695225.818 32583 VV .258 .7132026.346 12211 VV .196 .2679426.588 25362, VV .240 .5565126.952 U49683 ( W .265 3.2826827.552 17917 VP .243 .3931528.206 12163 PV .353 .2668928.618 9461 VV .267 .2876929.064 38165 VB .255 .8374438.032 6468 8V .193 .1419238.460 3661 VV .184 .8883330.902 20220 VV .240 .4436831.353 4826 VV .249 .1059032.223 16518 PV .222 .3624533.658 2485 PV .195 .8545334.547 12835 VB .218 .2816336.879 6788 VV .559 .1471939.635 75738 W 1.602 1.6617141.798 135645 VV 1.791 2.9764043.126 106146 VV 1.141 2.32912

TOTAL AREAM557344l, (UM0E+00

R R 1 0 3 1 7 5

RUN* 454 NO,V 25, 1987 11:12:47

SAMPLE! 3AREA*

RT AREA TYPE yiOTH AREA*1.970 4731027 PV .075 79 516902.264 49590 VB .863 .739153.763 796 PV .123 .811864.359 10685 BV .871 .159264.919 29301 PB .883 .436745.289 1468 BB .886 .821885.889 13658 VB .116 .283586.479 21876 BB .895 .314147.236 46277 BP .187 .689777.688 36041 PV .181 .537207.822 139632 VB .117 2.881248.614 6395 BB .183 .895329.583 74591 PV .134 1.111799.977 11385 VV .148 .1685018.377 59817 VB .124 .8915818.985 1284 BV .185 .8191411.280 18862 VV .128 .2811411.334 11843 VV .122 .1765211.692 197408 VV .201 2.9424112.216 85007 VV .153 1.2678512.635 55708 VV .164 .8383412.910 16716 VV .153 .2491613.353 4605 VV .113 .8686413.540 47652 VV .148 .7182613.795 55250 VV .153 .8235114.800 34135 VB .167 .5887914.766 57709 BV .156 .8601614.990 44049 W .193 .6565615.514 64333 W .198 .9589016.031 15535 VV .157 .2315516.358 2688 VV .156 .8480716.698 3977 VV .189 .8592816.976 30529 VV .158 .4550417.210 64807 VV .176 .9659617.463 81493 W .201 1.2146717.916 18053 VV .256 .1498418.590 58734 VV .194 .8754418.991 29127 VV .239 .4341419.376 11356 VV .198 .1692620.144 1394 VP .154 .8207828.511 8264 PV .177 .1231828.875 12372 VV .185 .1844121.182 7546 VV .192 .1124721.584 24083 VB .203 .3589622.405 7196 BV .187 .1872623.473 23333 VV .283 .3477825.145 5335 VV .198 .8795225.490 39689 VV .276 .5915727.239 11981 VV .335 .1773928.518 11119 VV .376 .1657330.327 14266 VP .503 .2126431.184 9300 PV .574 .1386232.523 5683 BV .218 .8847133.943 16867 VV .655 .2514134.865 19074 VV .626 .2843035.509 19544 VV .491 .2913135.932 17937 W .420 .2673538.290 180467 W 1.724 1.4974839.937 119178 W 1.379 1.77637

TOTAL AREA=6709069HUL FACTOR=i.0080E+00

flR!03!76

f ' ' • I >ABORTED ~ip V

* SEfl START

~i

fl(i,V

RUN I 456 NOV 25. 1987 12:38!47START

AREA*RT AREA TYPE WIDTH

2.869 267528* PV .873 57|2.329 4959* W .976 ..__.-2.381 41924 VB .866 .13 134.175 1538 SB .285 .933334.569 5189 BV .876 .112465.155 628 BV .981 .813616.993 1612 BB .115 .834946.77* 8834 PB .896 .191467.546 11226 PB .111 .2433*7.925 13565 PV .181 .294988.153 68125 VB .114 1.4765*8.968 9*33 BB .1*7 .195789.88* 14*83* PV .194 3.9349218.365 1274* VP .131 .2761218.774 81318 PB .126 1.7624311.391 1468 BV .196 .8318211.612 2382* W .127 .5162611.748 15939 W .124 .3367812.114 268982 W .2*4 5.8297412.649 119752 W .155 2.5887313.969 77926 W .164 1.6694113.351 24767 W .159 .5367813.8M 738* W .121 .1599513.988 62196 W .159 1.3488014.24* 62893 W .153 1.3622414.455 51793 W ,181 1.1225315.23* 8*193 W .162 1.7371815.453 62584 W .195 1.3564815.989 9*994 W .2*1 1.9699816.5*7 22599 W .162 .4898816.839 4863 W .172 .1854917.187 5615 W .174 .1217817.459 42695 W .16* .9253417.695 85522 W .176 1.8535517.95* 1*88*1 W .294 2.3588818.419 15539 W .294 .3367819.89* 85599 W .285 1.8552219.491 36327 W .248 .7373319.881 14564 W .281 .3156529.693 1769 VP .159 .83*121.926 9621 PV .177 ..885221.391 14527 W .184 .;i4»521.7*2 87*9 W .189 .1** 522.1*8 2774* VB .20322.939 8229 BV .18424.8*1 22523 VB .26425.684 4619 VV .138 _26.814 21669 VV .2.72 .4i><ij426.732 7596 VV .486 .i»4.»i

TOTAL AREft-4613%2HUL FflCTOi»l.a*90CiO*

103177

p -/o« S£8 START

RUM I 458 HOV 25. 1987 13:42:49START

•«.3*»

K.442

H.7H

27.4*5

32.SM133.741

STOP

RUM 49* HOV 29. 1967 13:42:49

SANPIEI 1

RT AREA TYPE WIDTH AREAX1.999 32*04 BP .973 4.797832.24* 46667 P8 .117 6.977484.3*9 1764 PB .117 .2637412.699 4314 PV 1.41* .6458116.442 2*72 PV .158 .3897919.7M 1*277 BV 1.398 1.5365623.12* 42321 W 1.851 6.3276127.4*9 119912 W 2.558 17.8637932.99* 322672 W 3.353 48.2441833.74* 87148 W .927 13.82998.

TOTAL AREA* 668831MX. FACTOR'1.0**9C 19*

RUH * 459 HOV 25, 1987 14:41:29

fl/?l03(78

TOTAL AREA- 697879HUL FACTOR.!.8**8E«*

ABORTED*« SEO START

RUHiSTAB? H°V2S> '9871S;19!31

IM5I

HOV 25. 1987 15:19:31

SAHPLE* 1

6.S

TOTAL AREA- 1632376KUL FACTOR.l!M**E4«*

ABORTED*** SE8 START

g" 33494 8* .869

.-i 83

STOP

461 . HOV 25. 1987 15:39:58

aRI03179 "If ,iiT' «•

1

T / V "UL FACTOR^. 8«eeE*«8

a R i 0 3 i 8 0

.\!<»*

• SEfl START

SI*? 4" HOV **' »W"l6i8eiW

16.444

f 23.411

STOP

RUM 462 HOV 25. 1987 16:8*:89

SAMPLE* 1AREA*

.2-988 8969 W «9

^ IS S :Jg:SS »g S :S:Iiw S 3H ;iH:85 88 R :

VB .155 88.62333«.w. **w 170 PV . 288 a 117722.319 18*22 PV 459 1897223.41* 6*615 W 1.113 :36994

TOTAL AREA-1.6425C+«7NUL FACTOR-1.9*MEt**

* SEfl START

RUM *STARTRUM * 463 NOV 25, 1987 16:36:55

2.831

..4S7

I,/ J

PORTED

* SEQ START

NOV 25'

9.515

14.6N15.353

'27.584

"131.15131.929

f t R l 0 3 i 8 i

^ I TOTAL AREA= 730794NUL FACTORS.0000E+00

RUN I 465 HOV 25, 1987 17:57:40START

[25.2W26.556

146.77*flRI03!82

6.456

16.355

18.177

19.95121.279

r

16.264r

18.895

* 21.476

26.81128.865

19554:57

22.889

24.665

4.5365.247

75 '6'

8.352I 9.777

13.88114.482

16.259

I OS I 85

» «« HOV 25,' 1987 28!53:

28.6N

24.653

28.811

9.768

f

/IRI03I86

N W

Mft14.447

16.224

22.934

24.631

26.715

21.327

27.92!

'rc.38314.483

16.184

U4.557' 25.33726.662

28.491

38.155

32.25133.385134.

A R I 0 3 I 8 8

WN, 474

RR103I89

STAR?T

I

I

16.138

R R 1 Q 3 1 9 Q

103191

STAR?

4.184

13.366

14.88316.117

27.351

32.243[33.487

ftRI03!92

STOP

RUNi 478 NOV 26, 1987 86:39:54

SAMPLEt 15AREA*

- .SSf "5 "Sg .IS 5J :K ':

' 1S'4711 fig S 6598i 1 1I i•as Bsas

OM . <i4o563934 py

21841 W 5I91M4TOTAL AREA* 368946

FACTORS. 0000E+00

flR!03l93

STOP

RUH* 479 NOV 26, 1987 07

SAHPLEtAREA*

1 907 ,?!?£? TYPE UIDTH> ,?; iJS!3 BP .08255334 PB .1082481 BV

18. r- "™ w

IMS 16786 Bv13.355 8780 VP14.305 8936 PV .-,«15.847 2507 VB '756.113 2191 pv 1596.474 2778 VV '15916.706 13442 VV17.18.

I D -19.608 1625 pp ,J519-962 11453 PV 17B20.321 22489 W "

6430 VV21.85522.211oorr?S ««»*»«» TT . 3H23.517 18642 VV .44824.106 8340 VV 94*24.554 27734 VV '|0i|*-f96 38637 VV .31025.495 17129 VV 314|6.032 8121 VV .'23526.633 63892 W f!227.232 U631 VV .'If27.884 13046 W 42628.300 14861 Jv 'alt28.739 36472 VV '2129.708 27090 VV "Sf30.572 30389 VV 'Sll'!21 30977 W33.357 64803 W ff7o34.211 653M VV .107

TOTAL AREA= 906458NUL FACTOR=1.0006E+00

&•480 NOV 26, 1987 88:37:89

SAHPLEi 17AREA*

RT AREA TYPE WIDTH1.910 19182 BP .8832.173 55328 PB .1093.929 4962 PV .646 882534.183 8313 VV 075 138274.360 1159 VB 868 elf™5.882 2847 PB 089 84735ll'gf \*£ S •09< •'«»"'«! J!X BP 'I47 -028891.851 1423 PV .132 .82367!?'UI oo££ 8V -147 l" 2582413.365 29898 VP .173 4939914.312 41758 PV .158 ! 694575-050 12244 VV .159 .2036615.544 2862 BP .134 .834386.131 2377 PV .172 .8395416.484 13258 W .148 228396.716 64404 VV .172 1.0712516.990 149351 W .188 2.48419o'fil 24854 VB -178 .413408.106 44042 PV .172 .732568.485 214371 W .213 3.56568

72368 VV .187 1.203*2860 VP .167 .84757J?28 w «151 • 1*51719.975 55660 W .174 .92581

20.335 111182 W .185 , 1.8493220.640 32754 W .180 .544802 -035 226721 VB .205 3.7711021.868 45683 BV .190 .7598A22.225 34577 W .200 .575llP22.899 287085 W .317 4.775523.531 29742 W .370 .4947124.121 23679 W .191 .3938624.569 114132 W .191 1.8983824.819 146854 W .272 2.4426625.511 42348 W .218 .7043826.045 14351 W .176 .2387026.232 17861 W .197 .2978926.649 237011 W .251 3.9422627.248 28404 W .219 .3393827.912 10760 W .229 .1789728.312 7829 VV .189 .1302228.756 59789 VB .237 993.5

1J741 BV 'I95 " 195296698 W .185 .1112836637 W -240 .609398236 W .243 .13699

? 'JfS oi 8 W •2B8 -8523631.910 35578 W .265 .5917833.375 3465 BV .301 .0576334.231 33087 W .286 .55834

30686 W .885 .51041If/ IS iWJ, W '964 "7588939.309 96116 W 1.327 1.59872

RI03I95

£•AREA*

26, 1987

SAHPLEi

4783 VV^g 5 :

1 1 1 1 Ii <* i i 1i Jil I1 1 i -1i i11 "i 1 1a i , i s•352 49567 I BH .332 .07461

TOTAL AREA=6.6437E+07HUL

HR103I96

RUH I 483 HOV 26. 1987 11:59139

'8.314

1 U.2W

21.713

32.4MSTOP

RtM* 483 HOV 26, 19*7 11:59:39

SAMPLE! 3

(WEA TYPE314162 BV14472 W293992382476328*66712447M77*2*8

7

.84886

.89910

.808*4

.816*8

.9*947

.82266

.159912.68624.88625.27481.537525.13188.88962.88139.68523.88299.83253

89.58947.82831.82769.82748.82856.2102*

TOTAL «£ft«2.%21E+*7MUL FfiCTOB«l.l

103197

^RUN * 485 MOV 26, 1987 13:12:85

I

I

32.4NSTOP

RUM 489 HOV 26, 1987 13:12:85

SAXPLEt 5

AREAXRT AREA TYPE WIDTH AREA*

1.996 11*799 PV .899 .435122.157 14673 W .854 .857632.21* 29187 VB .885 .114632.575 992 BP .878 .883742.956 3336 VB .867 .813183.938 3878 PP .274 .812894.299 9622 PV .875 .822884.573 35483 VB .868 .139355.237 588984 PB .123 2.31311

. 6.424 84*6* BB .884 .338137.851 174* VP .163 .886837.434 698 PP .891 .882748.418 116611 PB .886 .457969.83* 1266712 PB .141 4.9747418.959 1667 8P .116 .8865512.4*1 568 PP .243 .8822316.3*8 2311*624 P8 .155 98.761982*.733 3124 PB .191 .8122726.577 83 PP .154 ,88833

, 28.1*8 2281 PB .494 .888%• -••w: w .879 .84766

R R I Q 3 1 9 8

RON J 489 HOV 26. 1987 15:36:59

2.221 1.342

STOP

RUM 489 HOV 2*. 19*7 15:36:59

SAHPLE*_AREA*

RT AREA TYPE WIDTH ..._...1.942 193*** PV .*78 .2179*2.226 39597 VB .117 .844712.6*2 4245 BP .887 .884792.99* 8855 W .117 .81*8*3.77* 799 n .175 .888893.965 651 80 .88* .88*734.145 326 BP .85* .880374.295 89*2 PV .1*6 .818*54.6*0 9476* VB .879 .186995.31* 2422236—, P* .176 2.79)746.467 ilM4i5- 8* .485 .118116.884 1731 BV .879 .681957.12* 2593 VP .138 .882937.485 813 PP .887 .88*928.221 3*4 PB .87* .880348.474 61*3*2 PB .894 .689139.493 1752 PP .2*6 .801989.9*1 567*92* PB .153 6.4*25311.818 261*9 PP .123 .8295711.3*1 1335 PP .139 .8*15112.839 36* PP .*43 .8804114.645 175*49 PV .296 .1976316.443 79*62272 V* .188 89.262*218.8*4 1343 PV .13* .9815219.2*5 8363 W .356 .809442*.8*9 1295* P* .189 .8146223.8*9 5969 BV .262 .8867426.65* 84*0 BV .229 .8*94828.*3* 1*359 PV .412 .8117*3*.914 1*042 W .563 .8122432.565 32*91 t VH .546 .83713

TOTAL ARE*4.8573E+*7MIL FACTOR-1,I

START

F'flz

IS.744

'32.2MSTOP

RUH* 491 HOV 26. 1987 16:49:27

SAMPLE* 11AREA*

RT AREA TYPE MIOTH AREA*1.952 2*65* BP .806 3.229372.168 18424 PV .844 2.888142.218 4*35* VB .877 6.388983.923 2216 88 .5*6 .346424.279 4636 PV .874 .724725.2** 1712 PB .238 .267635.725 1346 BB .18* .2184113.335 17474 8V .139 2.7316313.586 898* VB .163 1.4838*14.548 1*448 PV .167 1.6332915.295 4587 W .235 .7178616.373 82*1 W .177 1.2828216.726 3565 W .157 .5573*16.962 151Z1 W .165 2.3716117.242 Q499O W .169 5.4782917.664 HJnr VB .169 .7999218.363 18031 PV .171 1.5691918.744 CJUTO VV .199 8.8881819.116 T5"147 W .176 2.5241819.88* 1863 BP .147 .2912320.24* 1287* PV .164 1.8868528.6*3 23999 W .175 3.7516528.91* 67M W .172 1.8526921.3*4 f3**£> VB .191 7.9421122.143 =9945 BV .185 t.5390222.5*1 7432 W .192 1.1618123.172 65497 W .291 18.2388423.816 5593 W .349 .8743324.4*1 4674 W .18* .7386624.849 25254 W .181 3.9478425.1*5 32589 W .26* 5.8944825.794 99*0 W .227 1.5488726.332 38*2 W .189 .5943526.528 32*2 W .216 .8132826.935 &&£> W .247 8.5419327.537 "5346 W .244 .9928428.18* 2893 VP .389 .4522528.6*8 357* PV .262 .5588829.846 13958 VB .239 2.1819938.818 2719 BP .281 .425853*.46* 8*1 PB .155 .12522

ARIQ3200

2I.8»4

,23.23423.174

21.141

STOP

NO* »• 19*7 18:*6i37

SAMPLE* 2

AREA*.18594.15591.88563.88273.01268.8557*1.81559.07182.286974.38484.8022*

92.66141.81249.82254.88548.82351.81359.81217.84374.46591

RRI032QI

CORPORATION

PCB RPD RESULTS

THESE SAMPLES WERE VERY DIRTY.

TO CLEARLY IDENTIFY THE MATRIX SPIKE PEAKS A PESTICIDE MIXTURE WITH A BROADRANGE OF RETENTION TIMES WAS USED AS THE SPIKING STANDARD. EVEN WITH THISSTRATEGY, THE SEDIMENT SAMPLES CONTAINED SUFFICIENT EARLY ELUTINGINTERFERENCES TO COVER THE FASTER ELUTING COMPOUNDS. REFER TO THEACCOMPANYING CHROMATOGRAMS.

MATRIX SAM£LE_ID_

WATER 6583 B-BHC 8HEPTACHLOR EPOXIDE 45DIELDRIN 48METHOXYCHLOR 45

SEDIMENT 6580 B-BHC HIDDENHEPTACHLOR EPOXIDE HIDDENDIELDRIN 56METHOXYCHLOR 100

HRIQ32Q2

W.3

STOP

RUM 4*6

AREA*

26. 19*7 13t48U9

SAMPLE*

i il:7.446 -

1 1 1 1ii 1,1 1 I

TOTAL AREH.3.2U8E+07MIL FACTOR-t.***K4M

Nfl

vi* cc C- r

•At-o

<v«»

">

N.I

U

M-0320U

'883648-3288.5858-863 43 ' -88«»9.735

U.79812.54712.955as

0282682888815330364.

.88657

22.983 J w ' SS '12? -8289924.68525.369 3-££ £ 'IS? -8827226.681

31.94832.292 8678 W '!?? -8823533.881 35 4 JJ "gj -8089633-488 6564 W 'IS '9936S34.336 5849 VV 'U? '8867834-934 14862 W 'S -8852136.858 tiSa K '12 -8153437-274 13531 PV 'SS <8116837.688 2683 VV *?»? '8139739.818 569 S 'gj -8827739.941 13377 PV 'JS •8885941.279 5234 VV "J?? '8I38141.714 3729 VV 'JJJ •0854842.258 3849 VP 'Si -_W8542.882 2526 PU ' f -88315«.943 iUff CJ '12 -8826144.522 289 w 'S? '0129445.778 3? u •88435

.WL

BRI03205

<r

STOP

RUHt 471 NOV 25, 1987 23:49:33

SAMPLE! 8AREA*

RT AREA TYPE UIOTH1.947 988836 PV .1892.196 44225 W .1142.324 36179 W .1382.552 14441 W .8952.789 9757 W .1872.918 24871 W .1363.386 952 VB .8843.448 1848 > BP .8683.883 3382 PP .1264.199 8878 PP .8754.512 144894 PB .8825.213 3845814 PB .2886.338 263912 BB .8876.745 1622 BP .8656.996 6586 PV .1787.338 2143 VP .8987.785 436 PP .8848.316 616815 PV .8968.588 4617 VP .8968.859 22898 PP .8919.732 7882157 PB .16318.836 5569 PV .18911.881 7558 VP .19211.795 5344 PP .16912.994 1832 PP .13813.428 28153 PV .19114.425 243473 W .42816.281 79897216 VB .19828.541 i 15236 BP .19524.685 1957 PV .28826.684 4887 BV .36227.982 3873. PV .33331.118 4186' PV .19231.965 311 PB .18832.298 6342 BP .44835.968 6845 VP .45848.915 176656 W 2.28541.766 98255 W .94844.625 384645 W 2.82748.728 918871 W 3.51852.835 1322396 W 3.32854.873 635449 W 1.455

TOTAL AREA*9.6616E+67 ',HIM. FACTOR-1.8888E+80

SRIQ32Q&

METALS DIGESTION PROCEDURE

RRI 03207

with Injecting the sample Into the graphite atomizer. (This additional stepcan cause sample contamination unless the filter and filtering apparatus arethoroughly cleaned and prerlnsed with dilute HN(>3.) Adjust to the finalvolume of 100 ml with Type II water. The sample 1s now ready for analysis.

8.0 QUALITY CONTROL

8.1 For each group of samples processed, preparation blanks (Type IIwater and reagents) should be carried throughout the entire sample preparationand analytical process. These blanks will be useful In determining If samplesare being contaminated.

8.2 Duplicate samples should be processed on a routine basis. Duplicatesamples will be used to determine precision. The sample load will dictate thefrequency, but 20X 1s recommended.

8.3 Spiked samples or standard reference materials should be employed todetermine accuracy. A spiked sample should be Included with each group ofsamples processed and whenever a new sample matrix Is being analyzed.

8.4 The concentration of all calibration standards should be verifiedagainst a quality control check sample obtained from an outside source.

8.5 The method of standard addition shall be used for the analysis ofall EP extracts. See Method 7000, Section 8.7, for further Information.

9.0 METHOD PERFORMANCE

9.1 No data provided.

10.0 REFERENCES

10.1 None required.

3020 - 3RevisionDate September 1986

ARIQ32Q8

METHOD 3050

ACID DIGESTION OF SEDIMENTS. SLUDGES, AND SOILS

1.0 SCOPE AND APPLICATION

1.1 This method 1s an add digestion procedure used to prepare sedi-ments, sludges, and soil samples for analysis by flame or furnace atomicabsorption spectroscopy (FLAA and GFAA, respectively) or by Inductivelycoupled argon plasma spectroscopy (ICP). Samples prepared by this method maybe analyzed by ICP for all the listed metals, or by FLAA or GFAA as Indicatedbelow (see also Paragraph 2.1):

FLAA GFAA

Aluminum Magnesium ArsenicBarium Manganese BerylliumBeryllium Molybdenum CadmiumCadmium Nickel ChromiumCalcium Potassium CobaltChromium Sodium IronCobalt Thallium MolybdenumCopper Vanadium SeleniumIron Z1nc ThalliumLead Vanadium

2.0 SUMMARY OF METHOD

2.1 A representative 1- to 2-g (wet weight) sample 1s digested 1n nitricadd and hydrogen peroxide. The dlgestate 1s then refluxed with either nitricadd or hydrochloric add. Dilute hydrochloric add Is used as the finalreflux add for (1) the ICP analysis of As and Se, and (2) the flame AA or ICPanalysis of Al, Ba, Be, Ca, Cd, Cr, Co, Cu, Fe, Mo, Pb, N1, K, Na, Tl, V, andZn. Dilute nitric acid 1s employed as the final dilution add for the furnaceAA analysis of As, Be, Cd, Cr, Co, Pb, Mo, Se, Tl, and V. A separate sampleshall be dried for a total solids determination.

3.0 INTERFERENCES

3.1 Sludge samples can contain diverse matrix types, each of which maypresent Its own analytical challenge. Spiked samples and any relevantstandard reference material should be processed to aid in determining whetherMethod 3050 1s applicable to a given waste.

3050 - 1RevisionDate September 1986

I« METHOD aoao

AGIO ozsesrxoN or SCDIMCNTS. suuooes. ANO SOILS

C -" )

7. t• •mp1-2 0

todig

7.2•nd

r«fl>ceneiMNOj:

7.2

Mix1*. C«Kfportion• ««cr»iccton

kda HNOsr«f lu»:jx wttn>ntr«t«dr«o««t

Cvioorctc•olutlon to9 ml

7.31

w«tc* «rwarn

0«ro*ld«

Add'yo« IId H O :forr«»ct.

Add M,0x•nd w«r« until•fftrvcsecnea1* ainiMal

O3050 - 5

Revision o.Date September 1986

HRIQ3210

ATOMIC ADSORPTION RAW DATA

"0

: ii ?CL>>o

c=>

J

in

I I I I I °O

\rt

SLe. « e< o —

«8ou

So

§k!±ilS-I

Si-Jo3

**® -o ui.X 0 0 4-

*Ili•X. <3:25"-u-»*lo ac tl

Is4- 4-5 a-u-o

w

-f. «3¥1U 0 £C O SO O =5

>u

•**0>£ C< a. j

0?££

u

&c<TCr

u<

x

*•ccr

^^<!"NRg

r(CCc1 'tl

U3

X

«)o-C

O^>•ss

:tc(t\5

X

vSr

^

X

7T-in^-i•

CvS

xPOo-

_i5s0o

X

rt-

w~

rP.

-tv5«

S'?;3:;

X.

-

Jrqc0V

01

nsV

l

•\*«»^

•%•1<0

If

r»fin'i

jfooXfoo

int_/<TS

c«ro

Ji

Vi.<Wcw>v>00

*1

J)*t

-yi?Or*o

>J£Cnx9

?

>fl^

OJdo

*IN|<»,(

V*4,

CQ

>

*«*30O1

SCUI

oV)

0wj

Of^

cT—o«3PO

êg

•0

'4O

sc

cS

ft«

(T

U<XV)

I•*,CQ

vJ

vicrc

x

3-

—

f*t

r

cQOiP?U)O

C*c»

^

svScr

inv«

X

C*j•~f•

•7-o

-*J3^?Do

r-0o1

^VS

o-~ -

cC951w

<y

OeO0

•3;vc

3»Q

cQW)<-

O•N*

CV:0C

*""

.V

roc

vfiro

S*•*.e

» «^crP~iLir

-3O•Oa(A

§L.U.

UO

?•WUOi'1o"o<0sIA0

1w8&"3L.4-

£

To&â<n0(A

ae

. "Jo

J5*-

>»*»4-U

81J

i ' i r^ i i ng •M«$i<a<g n ri ii 'i 'i *?*£ ju 0 in~fc*

<3PI

o

I

t ai

Oo

inO

0in «j _ -

9°J_ • « 4-

e<nao

2 =

i * B« IaJ 4

5 '. lo — ta, u u2 u o3> i J£2 f U< o oo »

|

e a eUJ < O —

_!z

o * il

•

y0o

&G«0

Ooa

in

ioc

o-C

c-Do

rc

f

s<so

ro

10

s

tr°--

cr

"0

r

0

5O

o- o

oo

I£

oCO

in

L.3U

8

1

1u&_ »*

si— «A

a 4--8-

tS

0*.c

^•1 *^g

0.

t—uJ*oo

o-

5 £-|J 4-s *MlIJIJIP' Q_ £*v

oJ

ZOB

.*!2S3<U

_.

<

_l^N*'vv*.

UJ

11

L.) Q)

n<-a.L.Oau.0

_j4-L. in4- U= 2o 40 I

einaO

(A

5— L.a 0— 9O — <5 °5 _^0 Jj°

4->"c<

r«*>oI&C

_

.0O

4-

|UI

.ine_o4-aL.4-0Ôu

_j

-j

O

1 \ +— O JU_ O 3

VIa4-£

**. (Ia

03

o a09 M£3S±vf . K =

•X. <"2 1. o f

ci*iL

c4- 4-

u.O

• *• w"c o e^ ^ =û

^* j_» JSa> a c>.?-< a. a

0

Is

a.O

f)X.

oV

Io0•>j

0*v

1

£^ti_coK

3tr

A

X

0""*

„"*oJ

0

?•«-.

-3-V)

^

{

«cr

-

-

t^ "

x

•*

X

+~s —^

.

9a9a4-in4-0L.3UO

c^ftu

9

i_D__O«to>0

SW

_;

§u.

2

>.•Mm*a3

..9 in

in —0 Oin «*•>>— Ma aa 4»9-—~ 0"* 24--= 04- L.

S»feiLu

?^ «•F ^ •u a ui0 L. 0•e 04-- W

(CONTINUED)55.2

IMEAN- 55.o STD.DEV.- o.s COEF.VAR.- 0.99 x»»«»»»»»»•»»»»•*•***•»*******•»«*•*******•**•*»*•«»*t»t«*«»*»*»t**»***»»*•*»***«36,0 E-23» READING GREATER THAN HIGHEST STANDARD.

»»»«»»*»»»«*»»*»»*******»»»***»»»*»***»**»»**»*»*»»»*»»»»tt»*»»»»*t»»«tt«*»»»t*<38.4 STANDARD 3

»**•*«*»***»*****•*t»»»»»t«t*»*»t«*»»»»**»»«t«»t»»»*«»t»**»*t«t»*t*»tt*t«t»»i»«iPB 1001 CJS37J-I3 C<-fs;

AA AA-BC BCPEAK HEIGHT (ABSORBANCE) 0.349 0.947 0.016PEAK AREA (ABS-SECONDS) 0.290 0.211 0.039

48.7

AA AA - BG BGPEAK HEIGHT (ABSORBANCE) 0.991 0.990 0.017PEAK AREA (ABS-SECONDS) 0.296 0.213 0.043

49.3

MEAN- 49.0 STD.DEV.- 0.4 COEF.VAR.- 0.37**t*t******»****«»»t»************»*»**********»»»**»*t*<PB 1OO1 cOP37S>-/ I - * - Uoo}

AA AA-BG BCPEAK HEIGHT (ABSORBANCE) 0.994 0.953 0.017•PEAK AREA (ABS-SECONDS) 0.233 0.212 0.042

49.0

\

AA AA-BG BCPEAK HEIGHT (ABSORBANCE) 0.333 0.933 0.016PEAK AREA (ABS-SECONDS) 0.236 0.214 0.042

49.6

MEAN* 49.3 STD.DEV.* 0.4 COEF.VAR.- 0.87 %»•»«**» **********t ••••*•••••» »•*••»•»•»•»**» t •••*•• **•*•**»***** t*****t»*t**tt«PB 1OO2 Cjt-lf &->iJt.

AA AA-BC BCPEAK HEIGHT (ABSORBANCE) 0.014 0.009 0.018PEAK AREA (ABS-SECONDS) 0.039 -0.006 0.043

0.0


0.1

MEAN* 0.1 STD.DEV.* 0.1 COEF.VAR.- 99.991

F»B 1003 QjUc 3oSO F /<-«.AA AA-BC BC

PEAK HEIGHT (ABSORBANCE) 0.038 0.037 0.020PEAK AREA (ABS-SECONDS) 0.091 0.003 0.048

1.9


! 3.1MEAN* 2.5 STD.DEV.* 0.8 COEF.VAR.- 32.21 X»****••»•«**• _ . . _ . _ . . . _ _ _ . . _.PB 100-4 BJUt.

AA AA-BC BC{PEAK HEIGHT (ABSORBANCE) 0.329 0.329 0.018PEAK AREA (ABS-SECONDS) 0.132 0.103 0.046

j 23.0

AA AA-BC BCPEAK HEIGHT (ABSOR1ANCE) 0.328 0.326 0.018PEAK AREA (ABS-SECONDS) 0.133 0.110 __ 0.043

j MSAN- 7!*-5

^--...fir......c^C-.--7._._._..__.___.. ............ - i'MEAN- 23.2 STD.DEV.- o.s COEF.VAR.- 2.22 x " ------- p»****t»*»»»t**t********»**»«*»*»**t1UI|t**t»»**<k**<l

•f>B loia -of-A*'*- ?*f&.AA AA-BC >«N5?/ BC

PEAK HEIGHT (ABSORBANCE) 0.366 0.332 {â/- 0.126PEAK AREA (ABS-SECONDS) 0.324 0.123 0.396

30.0

AA AA-BG BGPEAK HEIGHT (ABSORBANCE) 0.360 0.346 0.123PEAK AREA (ABS-SECONDS) 0.913 0.124 0.394

29.2

MEAN- 29.6 STD.DEV.- 0.9 COEF.VAR.. 1.82 Xt*t****»»*»**«**»**»**t*«t*t*«*»***»»**»*t*»»************t»**»»t***»*«****»t**»*PB 1019 £JU<. SoSQ f 1 1 - 1 - 7

AA AA-BC BCPEAK HEIGHT (ABSORBANCE) 0.032 0,030 0.026

PEAK AREA (ABS-SECONDS) 0.069 0.000 0.069

1.3

AA AA-BC BGPEAK HEIGHT (ABSORBANCE) 0.031 0,032 0.027PEAK AREA (ABS-SECONDS) 0,072 0.002 0.071

1.7

MEAN* 1.3 STD.DEV.- 0.3 COEF.VAR.- 19.48 X»**••****•***»*•**•**•*»•***»**»*****»*»****»»»*»**»»*•»•*** »t »»»•»*•»»*«*»»»«*»F»B 1O2O £JJe. Cftyx? 3f>K CeA.Qj I AS /.-(**•


24.9

AA AA-BC BCPEAK HEIGHT (ABSORBANCE) 0.309 0.307 0.023.PEAK AREA (ABS-SECONDS) 0.169 0.108 0.060

29.7

MEAN- 23,3 STD.DEV.- 0.6 COEF.VAR.- 2.33 X»***»**»**t**********

cm* SfC ct-ojF»B 1020


23.6 :

l AA AA-BC BC'PEAK HEIGHT (ABSORBANCE) 0,300 0.299 0.022PEAK AREA (ABS-SECONDS) 0.166 0.110 0.097

\ 26.0

'MEAN- 23.8 STD.DEV.- 0.2 COEF.VAR.- 0.91 x••«»«»»»•»«»**»»»»«»»»•»»«•»»»«*»»»»•««••»•»»«»*•***•»»*•»*»****»*•••*«»«»»*»*»<

&R1032I&. j

AA AA-BC BCPEAK HEIGHT (ABSORBANCE) ' 0.933 0.329 0.063PEAK AREA (ABS-SECONDS) 0.374 0.203 0.169

47.3

MEAN- 47.5 STD.DEV.. 0.0 COEF.VAR,. 0.04 X»«»»»«»»««*»»»»»»»»**»»»*»»»»*»»»«»*»»»»»»***»»*»«»»«**tt«t*»»*PB 1OO9 -0.2 i:^

AA AA-BG BGPEAK HEIGHT (ABSORBANCE) 0.040 0.029 0.042PEAK AREA (ABS-SECONDS) 0.114 -0.001 0.115

1.0


1.0

MEAN- 1.0 STD.DEV.- 0.0 COEF.VAR.- 2.38 X*»••»»»»«***»»*»«***«»»»»*»•**»**»»»•»»•*•»••*»»*»»»•«»»«»*»»»«»«*»» »»»»»»»t»«*P B 1 O O 9 — o J

A A AA-BC BGPEAK HEIGHT (ABSORBANCE) 0.106 0.089 0.107PEAK AREA (ABS-SECONDS) 0.357 0.023 0.334

6.5


6.9

MEAN- 6.7 STD.DEV.- 0.3 COEF.VAR.- 4.88 X*»•*•*•*•»»*•»*•**•»•*»*»»•*»»*»»•»*•»»»»•*•••»»••»*••»••»»»»•»»*»»«»» t*»»»t«»»PB 1 O 1 O ~°3

AA AA-BG BCPEAK HEIGHT (ABSORBANCE) 0.121 0.109 0.118PEAK AREA (ABS-SECONDS) 0,401 0.031 0.369

3,4


8.3

MEAN- 8.4 STD.DEV.- 0.1 COEF.VAR.- 0.82 X»»•«•*••«•»*•••*»*«•»•»*•*••*»»»*•*•»»»•»•»•»»»*»»»»»»••#•»»•»»•»••»•••»•»»»••»•

PB 1011 —03 **L'-ft- {*U10AA AA-BC BC


3.2

A A AA-BG BGPEAK HEIGHT (ABSORBANCE) 0.123 0.109 0.122

PEAK AREA (ABS-SECONDS) 0.413 0.031 0.332

8.3

MEAN* 8.3 STD.DEV.* 0.0 COEF.VAR.- 0.36 Xi »**»**•*•**»** »»»»*»** ****t »**»**•**••*****»»**»***»**»»»*»»»**»***«******»»»•*»:PB 1012 <2*-P KJJc.• AA AA-BC BCPEAK HEIGHT (ABSORBANCE) 0.020 0.008 0.022PEAK AREA (ABS-SECONDS) 0.033 -0.006 0.039

0.0


0.4

MEAN* 0.2 STD.DEV.* 0.3 COEF.VAR.- 99.99 X*»»»»«»»»»»»»»»»»»»»»»«»»»»*«»»»»»*»»«»»«»»»»t*»tt»»*F>B 1013 coP3?<.-l i : s Cioo;

i nQ9 I 7'1 O 1 3 (CONTINUED) £J| ft I U O &- ' '

AA AA-BC BCPEAK HEIGHT (ABSORBANCE) 0.360 0.336 0.020

jPEAK AREA (ABS-SECONDS) 0.281 0.227 0.034

/ *—' —' ' BHF T' a».4 " E-23t HEADING GREATER THAN HIGHEST STAHDAMu". .39,6 STANDARD 2

'»««».»•»•*«»»••«*«*•»»•»*»***•••*•*****••••••»*»»»•«»•»»*•»»»•»«••••»*•••«•••»»••

x AA AA-BC BCPEAK HEIGHT (ABSORBANCE)' 0.643 0.642 0.021PEAK AREA (ABS-SECONDS) 0.333 0.280 0.033

34.9

AA AA-BC BCPEAK HEIGHT (ABSORBANCE) 0.648 0.647 0.021.PEAK AREA (ABS-SECONDS) 0.333 0.282 0.033

(CONTINUED)1 33.3,:"«"•""•"•""""• — ••"•»-•"•"«"-" — — -"--••"' — -»*•-•••-••-..,•,».,.._»_, __ _ , _

'MEAN* 33.1 STD.DEV.- 0.3 COEF.VAR.- 0.34

33.1 E-23i READING GREATER THAN HIGHEST STANDARD.***»***»*t*******«*»***»*«*»»**«**«»**<»*»**»****«**»»**t»************«********»»

58.0 STANDARD 3»********************»»******»*»****»*«*»*»***»*t*****«**»*»**«t*«««*«t»t«t*t*»*PB 1OO1 vJ'P39{.-l ''•* Cteo) <?f/. m.


48.6

PEAK HEIGHT (ABSORBANCE)PEAK AREA (ABS-SECONDS)

49. t

MEAN* 48.9 STD.DEV.'****************** »»****»****»****4PB 10O2 <-*-*•


-0.2


AA0.5630.292

0.3Vf*Af****'

AA0.0180.048

AA0.0180.031

AA-BC0.3630.237

COEF.VAR.- 0.70 *>******»***•*•*•****»*<

AA-BC0.009-0.004

AA-BC0.009-0.006

BC0.0200.033

»*•*********»*•

BC0.0190.032

BC0.0230.037

-0.6

MEAN* -0.4 STD.DEV.* 0.

PB 1OO3 fiJbc 30 SO


1.0


0.8

WAN- 0.9 STD.DEV.* 0.•••••••ft******************************f** 1OO-* tf** c*>"

PEAK HEIGHT (ABSORBANCE)PEAK ARXA (ABS-SECONDS)

23.1

1OO-4 (CONTINUED)

PEAK HEIGHT (ABSORBANCE)KAK AMXA (ABS-SECONDS)

2S.2

mm 23.2 STO.DtV.* 0.

3 ' COEFF tl-l'JAA

0.0310.067

AA0.0320.069

1 COEF*****••*••Sf*. CAA

0.3070.177

AA0.3120.182

I COEF

.VAR.» 73.41 X

AA-BC0.0320.002

AA-BC0.0320.001

.VAR.* 10.30 X

Y!Sr*W£AA-BC0.3080.110

AA-BC0.3100.110

,VAR.« 0.37 «

BC0.0230.066

BC0.0260.068

•*••**•*«••*«***«

BC0.0260.068

BC0.0260.071

•

u,?.9 j < ftRjQ32i8

(•CAM* 34.8 STD.DEV.- 0.2 COEF.VAM.* O.J7 %. ^•»«»•«»«*»•»»»«»•»»*»««»»»»»»•• »*«»»*»*»»«-»»»*»»«*»-»»*»»»»»»«n»»**»»»»»«t«»»»»r*-m 20 os -o*? / • AO


8.8


7.8

MEAN- 8,3 STD.DEV.- 0.7 COEF.VAR.' 8.34 X*************•••****»**»***»•*«»»*»***»••**«*••***•***••»*»»•••»*•*»•••»••****••PB 2O 1 O ~Of &*> J*f* CIS) t«J/. -M-C.

AA AA-BG BGPEAK HEIGHT (ABSORBANCE) 0.423 0.420 0.032'•PEAK AREA (ABS-SECONDS) 0.247 0.160 0.086

33.4


34,0

MEAN* 33.7 STD.DEV.*

PB 2O 11 -/O

•PEAK HEIGHT (ABSORBANCE)PEAK AREA (ABS-SECONDS)

39.3


39.6

AA0.4240.243

0.4

<•• vAA

0.3060.432

AA0.3030.433

AA-BC0.4220.163

COEF.VAR.- 1.32 %

AA-BC0.4980.190

AA-BC0.49*0.190

BC0.0320.082

BC0.0840.241

BC0.0920.262

MEAN* 39.6 STD.DEV.* 0.0 COEF.VAR.* 0.04 X»***••*•****»**•***»****••*****••••••«»»•*****•*•***•**••**»•**•»•****••»**»****PB 2012 _,/ ,;4

2O12 (CONTINUED)AA AA-BC BC

PEAK HEIGHT (ABSORBANCE) 0.402 0.398 0.079,PEAK AREA (ASS-SECONDS) 0.363 0.146 0.217

30.3


30.7

MEAN- 30.6 STD.DEV." 0.1 COEF.VAR.- 0.3S*••*•••*•***»•*•••*»*•*•**•»••20 i a ,,jf /.•

AA AA-BC BCPEAK HEIGHT (ABSORBANCE) 0.3S6 0.394 0.080PEAK AREA (ABS-SECONDS) 0.4S6 0.239 0.221

4i,7

AA AA-BC BCPEAK HEIGHT (ABSORBANCE) 0.619 0.608 0.080PEAK AREA (ABS-SECONDS) 0.46k 0.241 0.223

PEAK HEIGHT (ABSORBANCE)KAK AREA (AM-SECONOSt

4*. 4i*»»->«»*j**>a>->«ta>->_«*_->«>«>->«l*»~t*»*«*i«>*>«»*>«»«»*«*>**»«»«» *"B|"P*T "t*?* *% **d*i" "I* *l"\™ * • •»••»•

BC(ABSORBANCE) *.«•* 0.4M _. ——.„_, «.*M ft it* o>art

E-2S« READING GREATER THAN HIGHEST STANDARD.

•• PEAK HEIGHT (ABSORBANCE)• PEAK AREA (ABS-SECONDS)1 38.3

(PEAK HEIGHT (ABSORBANCE)PEAK AREA (ABS-SECONDS)

38. 1

3MEAN- 38.3 STD.DEV.*i »»•••»«»»•*»»•»•***»*»*»*•»•»»»»•»F»B 2O 19 — /&

-PEAK HEIGHT (ABSORBANCE)PEAK AREA (ABS-SECONDS)

30.2

PEAK HEIGHT (ABSORBANCE)PEAK AREA (ABS- SECONDS)

30.3

MEAN* 30.3 STD.DEV.-

»**»*»*»***»*»»»»»*»»»»»*»»»»*»•«»i PB 2O2O - / 1


97.3

PB 2020 - IT i


: 96.7


37.3

AA0.7080.497

AA0.7020.505

0.3***•***»*«

AA0.4240.333

AA0.4220.541

0.2

***"****'AA

1.064o.aos

AA0.6920.469

AA0.7000.489

AA-BC0.7040.283

AA-BG0.6980.281

COEF.VAR.* 0.49 t'********»***»**«*»»*»<

AA-BC0.4160.144

AA-BC0.4U0. 146

COEF.VAR.* 0.67 X

>***************** ***•<

AA-BC1.0380.473

AA-BC0.6860.274

AA-BG0.6930.277

BG0.0730.214

BC0.0780.224

t**************

BC0.1210.389

BC0.1230.393

l**************

BC0.1090.332

BC0.0670.193

BC0.0740.212

•MEAN* 37.0 STD.DEV.- 0.3 COEF.VAR.* 0.83 Xo*******************************************************************************F»B 2021 -11 {Jit*. eLuyB l •' f

* AA AA-BC BCPEAK HEIGHT (ABSORBANCE) 0.696 0.688 0.100PEAK AREA (ABS-SECONDS) 0.978 0.282 0.296

--- 98.3

PEAK HEIGHT ( ABSORBANCE >.PEAK AREA (ABS-SECONDS)

97.0

MEAN* 97.7 STD.DEV,-••••••*••»*»»*•**•»»»***»»»**»» t»*JP» 2022 -tX A


31.2


90.2

MEAN" 30.7 STD.DEV.-•»«••••*•••»••»*•«***»•*»*»»»••••*P»» 2023 -/<? &•


4*. 3

PEAK HEIGHT (ABSORBANCE)JJPCM A«* (AB«-SE<M)| n 0

AA0.7000.384

0.9

0.6260.441

AA0.6260.437

'£*-* »* «° AA0.9790.40*

AA0.974

AA-BC0.6940.276

COEF.VAR.* 1.98 X*•»*•»•••*•»*•*••••••*r. to c i . TJ s

AA-BC0.6220.247

AA-BC0.6210.242

COEF.VAR.- 1.41 X•••••••••••••*••••••*•

AA-BC0.9730.223

AA-BOO.SM0.2l»

BG0.1000.309

*••*••»•****••*

BG0.0*90.194

gQ

0.0700.199

••••••••*••••••

BC0.0*60.1M

-BC

0.0*10. 17* '

•CAK HEIGHT _PEAK AREA (AM-aM) * ' 0.194 0.143 0.031

29.9

AA AA-BC BGPEAK HEIGHT (ABSORBANCE) 0.363 0.362 0.020PEAK AREA (ABS-SECONDS) 0.196 0.143 0.033

30.0

MEAN* 30.0 STD.DEV.* 0.0 COEF.VAR.. 0.13 Xt*******************************************************************************PB 2028 77,, OS'4- OS

202S (CONTINUED)AA AA-BC BC

'PEAK HEIGHT (ABSORBANCE) 1.981 1.944 0.192;PEAK AREA (ABS-SECONDS) 2.749 2.270 0.479t

464.6

PB 2O2S -OS i: (OooA A AA-BC BC


24.6


24.3

MEAN* 24.4 STD.DEV.* 0.2 COEF.VAR.* 0.98 X»*»*tt•»*»****»*»*»****»***»***»»***•**•*»****«*****•**»»*•*•*•*****************PB 2029 -o£ (I*. ~f*. CiA) *"* '• -***•'AA AA-BC BCPEAK HEIGHT (ABSORBANCE) 0.340 0.338 0.018PEAK AREA (ABS-SECONDS) 0.276 0.229 0.047

47.4

AA AA-BC BCPEAK HEIGHT (ABSORBANCE) 0.340 0.336 0.018•PEAK AREA (ABS-SECONDS) 0.273 0.228 0.046

i 47.2

1MEAN* 47.3 STD.DEV.* 0.2 COEF.VAR.* 0.37 X'*******»»****»*•***»»***•***••***•*»*»*»*»*»**»************»*•«*••»***********«»PB 2O3O -OS AJ. * -"M I' So° Ct-o; o y, ***-

V AA AA-BG BGPEAK HEIGHT (ABSORBANCE) 0.320 0.319 0.020PEAK AREA (ABS-SECONDS) 0.272 0.216 0.036

44.8


49.1

MEAN- 43.0 STD.DEV.- 0.2 COEF.VAR.- 0.49 X••••••t***************************** *********************************;.**********f»» 2031 -OS iJtff *f* l!S<io <?•«/

" AA AA-BCPEAK HEIGHT (ABSORBANCE) 0.322 0.920PEAK AREA (ABS-SECONDS) 0.270 0.220

49.7

AA AA-BC BCPEAK HEIGHT (ABSORBANCE) 0.91* 0.914 0.019PEAK AREA (ABS-SECONDS) 0.271 0.217 0.094

49.1

MEAN- 43.4 STD.DEV.* 0.4 COEF.VAR.* 0.89 X••••••••••••i

2O32 -o& I!

2032 (CONTINUED)HKtCHT (ABSORBANCE)AREA (ABS-SECONM) AR I 03221

MEAN- 36.8 3TD.DEV.- 0.5 COEf.vAR.. i . _3 k**************** ************ »**********»****•*• »***»»»**»*****«»»»«**•**»«**«*•,

' -X j/SfLj I ** AA-BC BC

PEAK HEIGHT (ABSORBAjfeEr ,> T f 0.418 0.416 0.017PEAK AREA < ABS-SECON tf 0.217 0.172 0.043

33.7


36.5

MEAN- 36.1 STD.DEV.- 0.3 COEF.VAR.. 1,43 tt****************************************************t**************»**»»*******PB 203-5 StJt. £050 f l l - i b

A A AA-BG BCPEAK HEIGHT (ABSORBANCE) 0.032 0.030 0.020PEAK AREA (ABS-SECONDS) 0.096 0.002 0.034

1.1


1.1 :

MEAN- 1.1 STD.DEV." 0.0 COEF.VAR.- 1.97 X»t»»»»***»»»»»»»»»»*»*»**«*»*»»»»*»»*»»»»»*»*»»»•»•«»»»»»*»»«»»»»•*»•»»»»»«»•»»»PB 3001 (jjf>3?t~l /?.* C(*r*)

•• AA AA-BC BCPEAK HEIGHT (ABSORBANCE) 0.373 0.372 0.016PEAK AREA (ABS-SECONDS) 0.299 0.261 0.038

34.0 E-71» INSTRUMENT CAN NOT SET GAIN INO ENERGt)

3001J{1 94. 7

*c ——— AA-BC BGPEAK HEIGHT (ABSORBANCE) 0.370 0.367 0.017PEAK AREA (ABS-SECONDS) o.soe 0.254 0.041

PB N3OO 1v. AA AA-BC BC

PEAK HEIGHT >ABSORBANCE) 0.373 0.369 0.016PEAK AREA (ABS BEC ONDS) 0.300 0.298 0.042

53.3 E-71t INSTRUMENT CAN NOT SET CAIN (NO ENERGY).

lift 103-222

Documents

uL OF ug/mLFile >37226 35.0-458.8 a»u. WESTON R711843-89B 35-318318 IH=1 .8 DRH 01 ^^ftftft-V-_>-iWWO(T^u 388808-280080--268888-240888-228080-280088-1 80000-