TURK STANDARDI

TS EN 590

$ubat 20'14

TS EN 590+41:2010 yerine

tcs 75.160.20

Otomotiv yakrtlan - Dizel (motorin) - Gerekler ve deney y6ntemleri

Automotive fuels - Diesel - Requirements and test methods

Carburants pour automobiles - Carburantspour moteur

diesel (gazole) - Exigences et methodes

d'essai

Kraft stoffe f U r Kraftf ah rzeu ge - Dieselkraft stoff

Anforderungen und Prtlfuerfahren

TURK STANDARDLARI ENSTiTUSU

Necatibey Caddesi No.112 Bakanlrklar/ANKARA

TSE DEN izrN ALINI{ADAN SIANDARD|N &R BOLU|\iUIIAMAI',|| iL I,BAS EDiLEMEZ, QOGALTILAMAZ

ICS 75.160.20TURK STANDARDI TS EN 590 : 2014-02

Bu standard, CEN/TC 19 "Gaseous and liquid fuels, lubricants and related products of petroleum,synthetic and biological origin - Biyolojik ve sentetik esaslr gaz ve srvr yakrlar, yaglama yaglal veilgili Urunlei' Teknik Komitesi tarafrndan hazrrlanmrg, cEN tarafrndan 26.01.2013 tarihindeonaylanmrg ve Turk Standardlan Enstitosu Teknik Kurulu'nu n 13.02.2014 tarihli toplanttstnda T0rkStandardt olarak kabul edilerek yayrmrna karar verilmigtir.

Bu standardda kullanllan bazt kelimeler ve/veya ifadeler patent haklanna konu olabitir. Bdyle birpatent hakktntn belirlenmesi durumunda TSE sorumlu tutulamaz.

Bu standard yayrnlandrgrnda TS EN 590+41:2010 standardrntn yerini alrr.

cEN uyeleri srrasryra,Armanya, Avusturya, Bergika, Birregik KraIrk, Burgaristan, eek cumhuriyeti,Danimarka, Estonya, Finrandiya, Fransa, Hrrvatlstan, HoIanda, lrranda,lspanya, lsve!, lsvigre, ltarya,lzlanda, Krbns, Letonya, Litvanya, Li,ksemburg, Macaristan, Makedonya, Marta, Norveg, poronya,Portekiz, Romanya, Slovakya, slovenya, Turkiye ve yunanistan'rn milli standard kuruluglandrr.

TS EN 590 2014 slandardr. ENBrussels) rzniyle basrlmtslrr.

iiye rllkeleane

590:2013 standardr ile bircbir aynr otup, Avruf,a Standardizasyon Xomitesitinl renue Marnix i7. B-.tOOO

TS EN 590 : 2014-02

EUROPEAN STANDARD

NORME EUROPEENNE

EUROPAISCHE NORM

EN 590

September 20'13

lcs 75.160.20 Supersedes EN 590:2009+4'1 :201 O

English Version

Automotive fuels - Diesel - Requirements and test methods

Caduranls pour automobiles - Carburants pour moteurdiesel (gazole) - Exiqences et methodes d'essai

Kraftstoffe fur Kraftfahzeuge - Dieselkraftsloff -Anforderungen und Prufverfahren

Thas European Standard was approved by CEN on 26 July 2013.

CEN members are bound to comply with the CEN/CENELEC lntemal Regulations \4rhich slipulale the conditions for giving this EuropeanSlandard the status of a national standard wilhout any alteration. Up-to{ile lists and bibliographacal references coniemiig such nalionalstandards may be obtained on applic€tion lo ihe CEN-CENELEC Management Centre or ttany CEN member.

This European Standard exists in three official versions (English, French, German). A version in any other language made by translationunder the respoisibility of a CEN member anto ils own language and notified to the CEN-CENELei vanagem-enttentre hai lhe samestalus as the official versions.

CEN members are the national standards bodies ofAustria, Belgium, Bulgaria, Croatia, Cyprus, Czech Repubtic, Denmark, Estonaa,Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, tdland, lreland, ldly, Latvia, Lithuania,Luxembourg, Malla, Netherlands Norway, Poland, Portugal, Romania, Slovakia, Siov;nia, Spain, Sweden, Switzerland, Tu*ey and UnitedKingdom.

EEUROPEAN COMMITTEE FOR STANDARDIZATIONCOMITE EUROPEEN DE NORN,IALISATIONEUROPAIScHES KoMITEE FUR NoRMUNc

Management Csntro: AvEnue Marnlx 17, B-IOOO Brussols

O 2013 CEN All righls of exploitalion in any form and by any means reserved

',lorldwide for CEN nationat Members.Rel No. EN 590:2013 E

ruRK STAN0ARDLARININ TEI'F hAKKI TSE Y! ArTTiR. SIANDARDtN BU NUSHASTNTN KiILLAN|M izNr TSE TARAFTNDANTURKiYE VAGON SANAYiiA.S.'A VER,LiliSTiF. BAStLt A IARiHi: 15.07.20i5TSE'DEN iZ'N ALIN[,1ADAN STANDARDIN BiR BOLUiTUiIAMAMt TLTTBAS EDiLEMEZ, COGALTTLAMAZ.

EN 590:2013 (E)

Contents

TS EN 590 : 2014-02

Page

Foreword...........3

2 Normative references

3 Sampling

4

55.'t5.25.2.15.2.25.35.45.55.65.7

Pump marking

Other (bio, components...............Generally applicable requirements and related test methods............., ...............7Climate dependent requirements and related test methods................. ...............9Precision and dispute ............. 10

Annex A (normative) Details of interJaboratory test programme......... ......................... 11

TURK STAND.AROLARININ TILiF HAKKI TSE'YE AiTiiR. STANDARDIN BU NUSIAS]N]N KULLANItt,I iZNiTSE TARAFINDANTURKiYE VAGON SANAYiiA_S_'A VER LMiSTiR. BASTLMA't ARiHi: 15.07.2015TSE'DEN iziN ALTNMADAN STANDARDTN BiR BoLiM0/rAtvAMl ilfiBAs EDiLHi,4Ez. QocALTiLAMAZ.

2

TS EN 590 :2014-02EN 590:2013 (E)

Foreword

This document (EN 590:2013) has been prepared by Technical Committee CEN/TC l9 "Gaseous and liquidfuels, lubricants and related products of petroleum, synthetic and biological origin", the secretariat of which isheld by NEN.

This European Standard shall be given the status of a national standard, either by publication of an identicaltext or by endorsement, at the latest by March 2014, and conflicting national standards shall be withdrawn atthe latest by March 20'14.

Attention is drawn to the possibility that some of the elements of this document may be the subject of patentrights. CEN land/or CENELEC] shall not be held responsible for identifying any or all such patent rights.

This document supersedes EN 590:2009+A1 :2010.

This document has been prepared under a mandate given to CEN by the European Commission and theEuropean Free Trade Association [5]

The requirements of the European Fuels Directive 98n1lEC [1], including amendments 2003117|EC 121,

2009/30/EC [3] and 2011/63/EC [4], have been included. Dates are included with all normative test methodreferences in order to comply with the requirements of the European Commission; with the accompanyingassurance by CEN/TC 19 that any referenced updated versions will always give samilar accuracy and thesame or better precision (see [4]).

Significant technical changes between this European Standard and the previous edition are:

- lnclusion of the revised EN '14214 FAME specification.

- Specific requirements concerning the limitation of use of methylcyclopentadienyl manganese tricarbonyl(MMT) as required by the EC have been incorporated.

- Addition of the Fuel lgnition Tester (EN 16144) as an alternate test method to the CFR engine test.

- Addition of Simulated Distillation by gas chromatography (GC), EN ISO 3924, as an alternate test methodto distillation by EN ISO 3405.

- lntroduction of the improved EDXRF determination technique for low sulfur contents, EN ISO 13032, in

replacement of EN ISO 20847.

Annex A is normative and contains the precision data generated on the test methods, which are the result ofinter-laboratory testing, carried out by working groups of CEN/TC 19. Many of the test methods included in

this standard were the subject of inter-laboratory testing to determine the applicability of the method and itsprecision in relation to blends of automotive diesel fuel containing 10 Yo (VN) or higher of different sources offatty acid methyl esters (FAME).

According to the CEN-CENELEC lnternal Regulations, the national standards organisations of the followingcountries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, CzechRepublic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece,Hungary, lceland, lreland, ltaly, Latvia, Lithuania, Luxembourg, Malta, Netheriands, Norway, Poland, Portugal,Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom.

TORK SIANDARDLARIN]N TELIF HAKKI TSE.YE AITTiR STANDARDIN BU NUSHASININ KULLAN M iZNI TSE TARAFINDANTURKiYE VAGON SANAYIi A,S.'A VERILIViSTiR. BASiL[,4A TARiHi: 15.07.20]5TSE'DEN iZiN ALINMAOAN STANDARDIN B1R AO!UMU,'TAMAIVI iLTiBAS EDiLEI\T1EZ, QOGAITILAIVAZ

EN 590:2013 (E)TS EN 590 : 2014-02

1 Scope

This European Standard specifies requirements and test methods for marketed and delivered automotivediesel fuel. lt is applicable to automotive diesel fuel for use in diesel engine vehicles designed to run onautomotive diesel fuel containing up to 7 ,0 o/o(Vt\tl Fatty Acid Methyl Ester.

NOTE For the purposes of this European Standard, the letms "o/o ltn/ml" and ""k (VM" are used to representrespectively the mass fraction and the volume fraction.

2 Normative references

The following documents, in whole or in part, are normatively referenced in this document and areindispensable for its application. For dated references, only the edition cited applies. For undated references,the latest edition of the referenced document (including any amendments) applies.

EN 116:'19971), Diesel and domestic heating fuels - Determination of cold fitter plugging point

prEN 12662:2012'?), Liquid petroleum products - Determination of total contamination in middle distiltates,diesel fuels and tatty acid methyl esters

EN 12916:20061), Petroleum products - Determination of aromatic hydrocarbon types in middle d,Sr//afes -High perfomance liquid chromatography method with refractive index detection

EN14078:20091), Liquid petroleum products - Determination of fatty acid methyl ester (FAME) content inmiddle disti ates - lnfrared spectrometry method

EN 14214'.20123), Liquid petroteum products - Fatty acid methyl esters (FAME) for use in dieset engines andheating applications - Requirements and test methods

EN 15'195:20071), Liquid petroteum products - Determination of ignition delay and derived cetane number(DCN) of middle distillate fuels by combustion in a constant volume chamber

EN 15751:20091), Aulomotive fuels - FaW acid methyt ester (FAME) fuel and blends with diesel fuel -Determination of oxidation stability by accelerated oxidation method

(DCN) of middle distillate fuels - Fixed range injection period, constant volume combustion chamber method

EN 16329:2013, Diesel and domestic heating fuels - Determination of cold filter ptugging point - Linear coolingbath method

prEN 16576:2013'?) , Automotive fuets - Detemination of manganese and iron content in middle distillate fuels -lnductively coupled plasma optical emission spectrometry (Cp OES) method

EN 2301 5:1994, Petroleum products - Determination of ctoud point (lSO 3O1S:1992)

EN ISO 2160:1998, Petroleum products - Corrosiyeness to copper - Copper strip test (lSO 2160:1998)

EN ISO 2719:2002 , Determination of flash point - pensky-Madens closed cup method (lSO 2719:2002)

1) Under revision.

2) ln preparation.

3) This document is currently impacted by EN 14214:2O12lFptA1:2013.

4 ,oaK sTANDARDLART:'rIN TEL,F HAKK, rsE'yE AirriR. STANDARDTN BU NUSHASTNTN KULLANTM izNi rsE TARAFTN,ANTURKJYE VAGON SANAY|i A,S.'AVERiLMiSTiN BASII MATARiHi ]507,2015TsE'DEN iziN ALTNMADAN srANDArtoiN BiR u0t [iMti/] AUAMt iL riBAS EDTLETJEZ. CoGALTiLAMAZ

TS EN 590 : 2014-02EN 590:2013 (E)

ENlSO3104:1996, Petroleum products - Transparent and opaque liquids - Determination of kinematicviscosiy and calculation of dynamic viscosity (tSO 3104:1994)

EN ISO 3'170:2004, Petroleum liquids - Manuat sampling (lSO 31tO:2004)

EN ISO 317'l:19991), Petroleum tiquids - Automatic pipeline sampling (tSO 31t1:1988)

EN fSO 3405:2011 , Petroleum products - Determination ot distiltation characteistics at atmospheric pressure(lSO 3405:2011)

EN ISO 3675:1998, Crude petroleum and liquid petroleum products - Laboratory determination of density -Hydrometer method (lSO 3675:1998)

EN ISO 3924:2010, Petroleum products - Determination of boiling range distibution - Gas chromatographymethod (lSO 3924:2010)

EN|SO4259:2006, Petroleum products - Determination and apptication of precision data in relation tomethods of test (lSO 4259:2006)

EN ISO 4264:20074), Petroleum products - Calculation of cetane index of middle-distillate fuels by the four-vaiable equation (lSO 4264:2007)

EN ISO 5165:19981), Petroleum products - Determination of the ignition qual| of dieseltuets - Cetane enginemethod (lSO 5165:1998)

EN ISO 6245:2002 , Petroleum producls - Determination ofash f/SO 6245:2001)

EN ISO 10370:1995, Petroleum products - Determination of carbon residue - Micro method (tSO 10370:1993)

EN ISO 12156-1:2006, Diesel fuel - Assessment of /ubrlc ity using the high-frequency reciprocating rig (HFRR)- Pad 1:Test method (lSO 12156-1:2006)

EN ISO 12185:1996, Crude petroleum and petroleum products - Determination of density - Oscitlating U-tubemethod (lSO 1 21 85: 1 996)

EN lSO 12205:1996, Petroleum products - Determination of the oxidation stabitity of middle-distitlate fuets(tSO 12205:1995)

EN ISO 12937:200Q, Petroleum products - Determination of water - Coulometric Kal Fischer titration method(tSO 12937:2000)

EN ISO 13032:2012, Petroleum products - Determination of low concentration of suffur in automotive fuels -Energy-dispersive X-ray fluorescence spectrometic method (lSO 1 3032:ZO1 2)

EN ISO 13759:1996, Petroleum products - Determination of alkyl nitrate in diesel fuels - Spectromatric method(lSO 13759:1996)

EN ISO 20846:20'1 1, Petroleum products - Determination of sulfur content of automotive fuels - lJttravioletfluorescence method (lSO 20846:201 1 )

EN ISO 20884:201 1, Petroleum products - Determination of sulfur content of aulomotive fuets - Wavelength-dispersive X-ray fluorescence spectrometry (l SO 20A84:201 1 )

4) This document is currently impacted by EN tSO 42U:2007 tA1.2013.

lURK SfANDARDLARININTELiF HAK(1]SE'YETORKiYE VAGON SANAYI

^1.S.'A VERIiMiSTiF I

TSE'DEN lZiN ALINi/ADAN S] ANDARDIN BiR B(

AiTTiR STANDARoIN BU NOSHASIN1N KULLANIM izNiTSE TARAFINASILMA TABiHi' 15 07 2015LUMU,TAMAVI,LTiaAS ED'LEMEZ. CCGALTITAMAz

5

EN 590:2013 (E) TS EN 590 :2014-02

3 Sampling

samples shall be taken as described in EN lSo 3170 0r EN tso 3171 and/or in accordance with therequirements of national standards or regulations for the sampling of automotive diesel fuel. The nationalrequirements shall be set out in detail or shall be referred to by reference in a NationalAnnex to this EuropeanStandard.

ln view of the sensitivity of some of the test methods referred to in this European Slandard, partacular attentionshall be paid to compliance with any guidance on sampling containers which is included in the test methodstandard.

4 Pump marking

lnformation to be marked on dispensing pumps used for delivering automotive diesel fuel, and the dimensionsof the mark shall be in accordance with the requirements of natio-nal standards or regulations for the markingof pumps for automotave diesel fuel. Such requirements shall be set out in detail oi shall be referred to byreference in a National Annex to this European Standard.

Labelling shall be clearly visible, easily legible and displayed at any point where diesel with metallic additivesis made available to consumers. The label shall coniain: "Contains metallic additives' in the nationallanguage(s) and shall be laid down in the NationalAnnex to this document.

5 Requirements and test methods

5.1 Dyes and markers

The use of dyes or markers js allowed.

5.2 Additives

5.2.1 General

ln order to improve the performance quality, the use of additives is allowed. Suitable fuel additives withoutknown harmful side-effects are recommended in the appropriate amount, to help to avoid deterioration ofdriveability and emissions control durability. other technical means with equivalent effect may also be used.

loTF Deposit forming tendency test methods suitable for routine control purposes have not yet been identified anddeveloped.

5.2.2 Methylcyclopentadienyl manganese tricarbonyl (MMT)

When methylcyclopentadienyl manganese tricarbonyl (MMT) is used, a specific labelling is required (see alsoClause 4).

MMT is a metallic additive that can be used in diesel. The presence of the MMT in diesel shall be timited to6 mg of manganese per ritre from 'r January 2011. The rimit shal be 2 mg of manganes" p"i ritr" tro,1 January 2014.

NoTE These requirements are subiect to review following an assessment by the European commission.

5.3 Fafty acid methyt ester (FAME)

Diesel fuel may contain up to 7,0 % (vM ol FAME complying with EN .14214:2012, in which case the ctimate-dependent requiremenls set out in S.4.2 of EN 14214.201i dL not appty.

NOTE 1 A suitabre method for the separation and identification of FAME is given in EN 14331 [6].

TIJRK STAND.ANDIAF}NIN TEL hAKXI TSE'YE A TTiN. STANSARDIN AU NUSHAS1NIN Kt]LLAN1]\4 iZNi TSE TARAFINDANIURKiYf VAGON SANAYiT A S ,A VER LMiSTiH. Elrls Ua I nn+lt, t5.02 20t5aSE DEN rzrN ALTNMADAN SIANDAaDtN aiR BOLuv,l, rqr,,rov, ,r t,aeS lJ,L rr,rez. gOCar r rt eluZ.

TS EN 590 :20i4-02EN 590:2013 (E)

climate dependent requirements P.l flyE as a blending component for use in diesel fuel according to thisdocument are set out in 5 4.3 of EN 14214:2012. rn" ri""itic grao"s shall be specified on a national basisaccording to locat climatic conditrons and the FAME volume in ihe diesel fuel.

The finished blend of diesel fuel shall also comply with the climate dependent requirements set out in 5.6. ofthis document.

cold flow additives, when used in FAME, should be specificafiy matched to the base diesel fuel and FAMEquality to ensure conect performance.consistent with the requirJments set out in this European standard. Thechoice could result in incompatibility between tne coto ttow'aoJitives used in the FAME and the diesel fuel.The choice of cold flow additive technology should be a "ontr"ctr"l

matter between the fuel blender and theFAME supplier taking into account the cli;;tic-dependent reffiments or the finished dieset fuel.

NorE 2 - cold ffow requirements for FAME as a blend component in diesel fuel are set out an Tables 3a and 3b and theNational Annex of EN 14214:2012. in order to "ontror

,"rirl, "onient

or satrratea monogtycerides in the final EN 590blend to ensure trouble-free operation. work is on-going to ioentirv a iurtaore test method for saturated monogtyc€rides ora performance test to control this aspect of tow temierjure p",f;,f;;e l

ln order to improve the oxidation.,stability of . FAME, it is strongly recommended to add oxidation stabitityenhancing additives to FAME at-the production stage and'beiore storage, providing an oxadation stabilitysimilar to that obtained with 1 ooo,mgikg.or z o-ol-te-rt-uutylJ--hydroxytolrene (BHT, officially designated byIUPAC as 2,6-bis(.1, 1 -dimethytethyt)-4_mJtnytphenog.

The- similar action may be read as providing oxidation stability performance at least equal to that obtained with1 000 mg/kg of BHT.

cAUTloN - There is a potential risk of precipitate formation with oxidation stability enhancingadditives at low temperatures in low aromatic i."iic trei.'6"rtion shoutd therefore be taken in thechoice of oxidation stability enhancing aoOltives to aiciic ar"O" feUe.

5.4 Other (bio-) components

Limits for addlng FAME are set for technical reasons. Limits for IAME d9 not apply to other (renewabte)hydrocarbons such as Hvdrokeated veg_etabre oir tHvoi cas io Liquid (GTL) or'ei6,n"., io iiqrio (erl)derived hydrocarbons' since these paraffinic oieser coffinenis are aflowed in any proportions provided thatthe final blend complies with the requirements of eN sgo. in" ,." ot r"n.*rble feedstock at refineries is alsoallowed provided that the final fuel meets the requirem"nt. oief.iSSO.

NOTE A draft fuel specification for paraffinic diesel fuel has been developed [7].

5.5 Generaily appricabre requirements and rerated test methods5'5'1 when tested by the methods indicated In Table 1, automotive diesel fuel shall be in accordance with thelimits specified in Tabre 'r. The test methods risted in Tabie t have been assessed for apprication toautomotive dieser containing FAME. precision data from inter-raooratory test programmes are given innormative Annex A, where these were found to be different froni tne precision data given in the test methodsfor neat petroleum products.

5'5'2 The limiting value for the carbon residue given in Table '1 is based on product prior to addition of ignitionimprover, if used. lf a value exceeding the limit'is out.in"Jo-n nn-i.t'"d fuel in the market, EN lso 13759 shallbe used as an indicator of the presence of a nitrate-containing- compound. lf an ignition improver is thusproved present, the rimit varue for the carbon r"rior" oitt "

pioo"rct under test cannot be appried. The use ofadditives does not exempl the manufacturer tro, ,*"iing" ih"-requirement of maximum 0,30 o/o rm/m) orcarbon residue prior to addition of additives

5'5 3 Diesel fuel shall be free from any adulterant or contaminant that may render the fuel unacceplable foruse in diesel engine vehicles.

NorE For further information on preventrng contamrnation by water or sedfient that may occur in the suppty charnor for cross-contaminarion. it is advisabre ro "r,,"&

ciiirnn i iioiliiii ".'cerna r s367_3 lgj respectivery.

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7

EN 590:2013 (E)TS EN 590 : 2014-02

TURK STANDARDLARININ 'I E LiI iTAKKITS:'YE AITTIR STANDARD N BU NUSHASININ KULLANIM iZN] ]SE TARAFINDANTURKiYE VAGON SANAYiTA.S. A VERiLMiSTaR. aAStL[,4A TARiFi] t5 07 2Oi5

TSE'DEN iZiN ALINMADAN STANOARDiN BiR AOLUMU/TAMAMI ]LTiBAS EDiLEMEZ. COGALTILAMAZ-

Table 1 - Generally applicable requirem6nts and test methods for automotive diesel fuel

Property Unit Limits Test method "(See Clause 2)mtntmum maximum

Cetane number 51,0 EN ISO 5165 D

EN 15195

EN 16144Cetane index 46,0 EN rSO 4264Density at 15 "C kg/m3 820,0 845,0 EN tSO 3675 c

EN tSO 12185Polycyclic aromatic hydrocarbons d % (m/ml 8,0 EN 12916Sulfur content mg/kg '10,0 EN rSO 20846 "

EN tSO 20884EN ISO 13032

Manganese content r

until 2013- 12-31from 2014 to 01-Ol onwards

mg/l6,02,0

prEN 16576

Flash point Above 55,0 EN tSO 2719Carbon residue s

(on 10 % distillation residue)% (m/m) 0,30 EN tSO 10370

Ash content o/o (m/m) 0,010 EN tSO 6245Water content m9/kg 200 EN rso 12937Total contamination mg/kg 24 EN 12662 h

Copper strip corrosion(3 h at 50 :C)

rating class 1 EN rso 2160

Fatty acid methyl ester (FAME) contenti %(vM 7,0 EN '14078

oxidation stabitty l g/m'h 20

EN tSO 12205EN 15751

Lubricity, corrected wear scar diameter (wsd 1,4) at60 "c

pm 460 EN lso'12156-1

Viscosity at 40 "C mm'/s 2,000 4,500 EN rso 3104Distillation r'lo/o (VM rccovercd at 250 'CYo (VM recovercd at 350 'C95 % (UM recovered at

Yoo/o

'c

(VM(VM 85

<65

360

EN tSO 3405 'EN rSO 3924

NoTERequirement5inboldrefertotheEuropeanFuetsolre2009/30/EC I3l and 2011/63/EU [4].

See also 5.7.4.

See also 5.7.2.

For the purposes of this European Standard, polycyclic aromatic hydrocarbons are defined as the total aromatic hydrocarbon contenlless the mono-aromalic hydrocarbon content, both as detemined bt EN 12916.See also 5.7.3.

See also 5.2.2.

See also 5.5.2 and Annex A.Further investigation into the total contaminalion test method to improve the prec.ision, particularly in lhe presence of FA[4E, is beingcanied out by CEN.

FAME shall moet tho roquirements of EN 14214, soe [31.When dieselfuel contains more than 2 %(V/v) FAME, oxidation stability as determined by EN .ls7sl is lhe requirement.For the calculation of the cetane index the 10 o/o, 50 % and 90 o/o ry 4 recovery poinls are also needed.The limits for distirration at 250 "c and 350 'c are induded fordieserfuer in rine with EU common customs tariff.EN ISO 3924 gives instrudions to convert to ISO 3405€quivalent data. See also 5_7.5.

j

I

8

TS EN 590 :2014-02EN 590:2013 (E)

5.6 Climate dependent requirements and related test methods

5.6.1 For climate-dependent requirements, options are given to allow for seasonal grades to be setnationally. The options are for temperate climates six CFPP (cold filter ptugging point) gradei and for arctic orsevere winter climates five different classes. Climate-dependent requirements ire given in Table 2 (temperateclimates) and Table 3 (arctic or severe winter climates). When tested by the methods given in Table 2 andTable 3, automotive diesel fuel shall be in accordance with the limits specified in these tables.

Table 2 - Climate-related requirements and test methods - Temperate climates

Property Unit Limits Test method '(See Clause 2)Grade

AGrade

BGrade

cGrade

DGrade

EGrade

FCFPP "C, max. +5 0 -5 -10 -15 -20 EN 116

EN 16329See also 5 7.1

Table 3 - climate-related requirements and test methods - Arctic or severe winter climates

Pro perty Units Limits Test method a

(See Clause 2)class0

class1

class2

class3

class4

CFPP "C, max. -20 -26 -32 -38 -44 EN'116bEN '16329

Cloud point "C, max. -10 -'16 -22 -34 EN 23015Density at 15 "C kg/m",min.

kg/m3, max.800,0845,0

800,0845,0

800,0840,0

800,0840,0

800,0840,0

EN rSO 3675 "EN ISO 12185

Viscosity at 40 'C mm2/s, min.mm2/s, max.

1,5004,000

1,5004,000

1,5004.000

1,4004,000

't ,2004.000

EN lso 3104

Cetane number EU e m tntmum 51 ,0 51,0 51 .0 51 ,0 51 .0 ENENEN

tso 5165 d

1 519516144

Cetane number r mtnrmum 49,0 49,0 48,0 47 ,0 47 ,0 EN tSO 5165 d

EN 15195EN 16144

Cetane index minimum 46,0 46,0 46,0 43,0 43,0 EN ISO 4264Distillation e h

recovered at 180 "C

recovered at 340 "C

o/o (VlV), max.

o/o (VM, min.

1 0,0

95,0

10,0

95,0

1 0,0

95,0

10,0

95,0

1 0,0

95,0

EN tSO 3405 I

EN rSO 3924

See also 5.7.1.

See also 5.7.6.

See also 5.7.2.

See also 5.7.4.

Il^:9^T!1i9..-.*h"le - the European Fuels Direclive 98/70 EC[1] incruding amendments 2oo3tiltEC l2),2009/30/EC [3] and 20'11/63/EU [4] appties.

!]l-9o_ujEigg--where the European Fuels Directive 98/70 EC[1] inctuding amendments 2@3nZEC I2l,2@9/30/EC [3] and 2011/63/EU [4] does not appty.EU Common Customs Tariff definition of gas oil may not apply to the grades defined for use in arctic or severewinter climates

For the calculation of the cetane index the io ok (vM, 50 % (vM and go o/o (y/y) recovery points are also needed.uee atso 5. /.5

T,RK-STANDAROLARININ TELiF HAKKI TSE'YE AiTTIR, STANDARDIN BU NUSHASININ KULLANIM iZNiTSE TARAFINDANTURKryE VAGON SANAYIi A.S_ A VERiLMiSliB. AASttMA IARaHir t 5 07.2015TSE'DEN iZiN ALINMADAN STANDARDIN BiR AOLLJMU/tAMAMI iLTiBAS EDiLEMEZ, COGALTILAMAZ

9

TS EN 590 : 2014-02EN 590:2013 (E)

5'6'2 ln a National Annex to this European Standard, each country shall detail requirements for a summerand a winter grade and may include (an) intermediate and/or regional grade(s) which shati be lustitieo bynational meteorological data.

5.7 Precision and dispute

5'7'1 AII test methods referred to in this European Standard inctude a precisaon statement. ln cases ofdispute' the procedures for resolving the dispute and interpretation of the results based on tesr methodprecision, described in EN ISO 4259. shall be used

5.7.2 ln cases of dispute concerning density, EN ISO 3675 sha be used.

5.7.3 ln cases of dispute concerning sulfur content, either EN lso 20846 or EN lso 20884 shalt be used.

5'7.4 ln cases of dispute concerning cetane number, EN ISO 5165 shall be used. For the determination ofcetane number alternative methods to those indicated an Table 1 and Table 3 may also be used,-piovided tnatthese methods originate from a recognised method series, and have a valid precision statement, derived inaccordance with EN lSo 4259, which demonstrates precision at least equal to that of the referenced method.The test result, when using an alternative method, shall also have a demonstrable relationstrip io tire resuttobtained when using the referenced method.

5.7.5 ln cases of dispute concerning distillation, EN ISO 34OS sha be used.

5.7.6 ln cases of dispute concerning CFpp, EN 1 16 shall be used

TUBI( STANDAADLARININ TELIF I]AKhI TSE YE.AiTTiR SIANDAROIN BU NOSHASININ KULLANIM iZNi TSE TARAFINDANTURhr/tVACO^JSANAYIASAVt q"M,St.n BASrt Vp tAor-r..f O,ZittS " _'TSE'DEN iziN ALtNMAI)AN SIaNDARDIN BrF BoLitr,,lunalllaur irria"aiiollaMEz. CocALTlrAMAz.

10

TS EN 590 : 2014-02EN 590:2013 (E)

Annex A(normative)

Details of inter-laboratory test programme

T€bleA:1 presents the precision data obtained in inter-laboratory testing programmes by CEN/TC 19 [10] andthe El [11], that differ from those of test methods listed in Tabli t anO that at the time of pubtication of thisEuropean Standard were not yet revised.

NOTE The following methods were found to have precision data for 5 % (vM F AME btends simitar to the pubtishedvalues:

Ash content. EN ISO 6245,

Oxldation stability: EN tSO 12205,

CFPP: EN 116.

Table A.1 - Precision data updates

CEN/TC 19 data for5 Yo (VM FAME blend

r= 0,001 1XR=0,018X

EN tSO 2719

EN tSO '10370 r=0,1430.f5R=0,2125.Xos

Mrere

r is repeatability (EN tSO 4259)R is reproducibitity (EN tSO 4259)X is the mean of two results being compared

TORK STANDAROLARININ TE!'F HAKKI TSE'YE AiTTiR- STANDARDIN BU NOSHASININ KULLAN}M iZNiTSE TARAFINDANIURKYE VAGON SANAyiiA_S..A VERiLt\,iiSTiR. BASILMA rARiHi: 15.07201tTSE'DEN iziN ALINMADAN STANDARDIN BiR aoLtuuteruarvr rrrdei-iolLEMEz. QocALTTLAMAZ_

11

Property Test method Unit

Viscosity at 40 "C EN rSO 3104 mm'/s

Flash point r=2,0R=3,5

Carbon residue

t1l

12)

I3l

EN 590:2013 (E) TS EN 590 :2014-02

Bibliography

Directive.gErolEc of the European parriament and of the councir of 13 october .r99g rerating to thequality of petrol and diesel fuels and amending Council Directive g3tlZlEEC

Directive 2003/'17lEc of the European parriament and of the councir of 3 March 2oo3 amendingDirective 98/70/Ec relating to the quality of petrol and djeset fuels and amending Councit oirective93t12tEEC

oirective 2009/30/EC of the European parriament and of the councir of 23 Aprir 2009 amendingDirective 98/70/Ec as regards the specification of petror, oieseiano gas-oir and introducing a "mechanism to monitor and reduce greenhouse gas emissions and amending councir Directive'1999/32lEC as regards the specification of fuer ised by inrand walerway vessers and repearingDirective 93/12lEEC

Directive 201 1/63/EU of 1 June 2011 amending, for th€ purpose of its adaptation to technicar progress,Directive 98/70/EC of the European parriamenland ot tne iouncrt retating to the quarity or peiroi'"Jdiesel fuels

Mandate M/394 - Mandate to cEN on the revision of EN sgo to increase rhe concentration of FAMEand FAEE to 10o/o vlv, 13 November 2006

EN 14331:2004, Liquid petroleum products - Separation and characterisation of fatty acid methylesters (FAME) from middre disti ates - Liquid chromatography (Lc)/gas chromatogiapny Gc1';etnoacEN/TS 15940, Automotive fuers - paraffinic ctiesel fuel from synthesis or hydrotreatment -Requirements and tes, methods

CEN/TR 15367-1 , Petroreum products - Guide for good housekeeping - pad 1 . Automotive dieset fuers

CEN/TR 15367-3, petroreum products - Guide tor good housekeeping - paft 3. cross contamination

cEN/TR 15'160, Petroreum and rerate.d products - Appricabirity of dieset fuet test methods for FattyAcid Methyl Esters (FAME) - tnformation and resutts on ,ounO ioii tests

El Research Report on lp 398 and EN ISO 10370, under publication, avaitable from the Energylnstitute, 6 1 New Cavendish Street, London WI G ?AR, engfanJ -

12 *?I5ililDjlplllllliN rELiF rrAKKr rsE'yE ArrriR. STATDARDTN BU NU.HASTNTN KULLANTM izN,rsE TARAF,NDANTURKVE vAGoN sANAy iA s.,A vERtMisriR. aAsrL n,te ririr.,-rr,,.iIor zorsTSE,DEN iziN ALINMADAN STANDARDjN ain aoL iLIaij,ieLl;.MI.;I i Ii;As ToiLEMFZ. coGALTILAIJAZ

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