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Citation The Review of Physical Chemistry of Japan (1966), 36(1)
Issue Date 1966-10-30
URL http://hdl.handle.net/2433/46872
Right
Type Others
Textversion publisher
Kyoto University
Vol. 36, 1966
The Review of Physical e strv ~Jap ol. 36 No VYI~
No.
19661
1
RMVIEVYoR
THE
ru~sic~~ OF IAPAN
CN~~IISTRY
Founded ie 1926
CONTENTS
Jiro Osogf, Kiyoahi Shimizn aad Hidato Takizawa: Effect of Pressure on the
Dissociation of Electrolytic Solution (III)-Electrical Conductivity of Hesam-
mine Cobalt (III) .Sulphate at Highf Pressures ................:........................
Jiro Osvgi, Tetuo Mizakami and Tadafumi Tachibana :: The Effect of Pressure on
the Keto-enol Equilibriaof Acetone. and Cyclohesanone ................:.............
Jiro Oavgi and-Himihiko Hara : _Efiecl of Pressure on the Electrical Conductivity
of Organic'Substances (I) Pyrolyud Polyavyloai[rile. .............................
Jiro Oaugi and Kimihiko Hara : High-pressure Melting fn Polyethylene ..............
Jiro Oaugi, Ryosuke Namikawa and Yoahiyvki Tanskal Chemical. Reaction at
High Temperature (III) Reaction of Silicon and Pliosphorus at High Tempera-
1
g
Lure and High Pressure
I{lyoshi Kitamara : Inacfival
of Bacterial N-Protein
za
29
35
Klyoshi IS:itamara : Inactivation of Enzymes under High Presu~e (II) Inactivation
of Bacterial N-Proteinase and ~-Amylase. of Barley under High Pressure ......... 44
J1ro Osugi and KiyoshI Shimizn, Yoshiyolci Taos]reand Kosaku Kadono: Pre-
paration and Chemical Properuesof Cubic Boron Arsenide, BAs ..................... 54
THE PHYSICOCHEMICAL SOCIBTY OF JAPAN
The Review of Physical Chemistry of Japan Vol. 36 No. 1 (1966)
THE REVIEWOF PHYSICAL CHEMISTRY OF JAPAN
(BtJtsttri-Kagaku no Shinpo)
President: Shinkicbi Horiha, Professor Emecitus; M. J. A.
Members of Council:
Aauma Okuda (Chic()
J: Osugi %. %odera
R Goto
T. Yamamoto
T. Fujinaga
S. Tasaka
Board of lidltora:
j. Osugi (Chief)
Y. Rachi
H. Takagi
H. HatBna
W. Jono
R. Gota
E. Suito
Kyoto Uaiverrily
I. Tsujikewa
A. %aji
A. Saika
W: Jooo (Associate) UniversUy of Xobe
R. Goto ( n )Kyoto Univasify
E.-$uito ( n ) Kyofo l/niversily
Secretary(
S. Shida
T. %itagawa
)d. Tamura
H._Matsuyama- .
T. Makila
R Susuki
K_ Hirota
S. Seki
T. Ishiao
T, Imoto
R.:Fujishiro
O. Toyama
S. Ono
5. Tsuchihashj
5. Hasegawa
H. Togawa
R.Shimiau
T. Fujiwara
Tokyo Insfifu/e of Technology
Yokokama Universiy
Xyofo Univenily
Dothislsa Univenily
Kyoto Techeical Ursiveisiry
Ritrumeikaa Univenity '
Univerryy aJ Osaka
University aJ Osako
Bimefi Institute of Terhnology
Muaicipal Universily.aJ Osaka
MuniciyaJ Urtivarsily- of Osaka
PnfeUUrol Univeaity of Osaka
Profedvsal University aJ Osako
University of Kohe
Okayoma. University
Dorhisko Unioersity
M. Sata
The Review of Physical Chemistry of Japan Vol. 36 No. 1 (1966)
:October 30, 1966
CommmloaNoae to the Editor shoud be addresud-to Soardofliditors, The Physico-Chemical Society
of Japan, College of Science BYoto University, &yoto,-Jepaa
Bnsfness Correspondences should be addressed to; Secretary,'The Physico=Chemical Society of Japan,
College of Science, Ryoto University, Ryoto, Japaa.
Pnrehnae Order should be addressed to::Ma~usen,-Co.; Ltd., Nihonbaahi, Chuo-ku, Tokyo, Japan.
TEE
Published lry
PHYSICO-CHEMICAL SOCIBTY OF JAPAN
(Nippon Butsuri-Kegaku Kenkyu Rai)
College oC Science„%yotoUniversity; Ryoto, Japan
Printed~by RAWAKITA INSATSU Cl).,-Ryoto, Japan
The Review of Physical Chemistry of Japan bol 36 No 1 (1966)
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betterment of peopl~ , ~yy liv techniques are Iicens~fiY!;'apd products :have been
.,v~y.,~r: ~~ exported to more tli~n; 3'0.'cguntries.
These include urea, ammonium sulphate, synthetic
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T®1~0 K®ATSIJ ~' Nndu~tr~'se~; lnc .
Mitsui Daini Bekkdh, 2;4ghome,~NifiOnhas~~'.~Nongaku-Cha, Chuo•ku, Tokyo Cahle address : "TDATSU/ND TDNYD" -
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The Review of Physical Chemistry of Japan Vol. 36 No. 1 (1966)
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NISSO(Ingredient
NI-CHLONCalcium Hypochlorite 70°/, min, granular & tablet)
;/Visso
• Sodium Cyanide
• Sodium Hydrosulphite
• TDI (Tolylene Diisocyanate)
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• Sulfisoxazole (Sulphafurazole)
• Benzoyl Peroxide (21.22%)
Manufarturer& Exporter of Chemicals
NIPPON SODA CO., LTD, Head Offfee : Otemachl, Tokyo, Japan
Cable Address : "SODANIPPOH" TOKYO
~u? .]1The Review of Physical Chemistry of Japan Vol.
L
36 No. 1 (1966)
I. Ca!*, Ready For Use The Tri-band ESR
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The JES36S is a new versatile ESR instrument with excellent features :- Super Sensitivity
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Tri~Measurement at X, K & Q Bands The JES-38S which is provided with a unique low~impedanee magnet, a direct read~aff circuit of the magnetic field and a linear field sweep method has the following records.
~~~-
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Standard Frequency•••9,400 Mc (X-band)Cavity Resonator
Variable Range
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500.13,000 Bauss
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ESR Signal of Crs' in single crystal of ruby N. B.: Absorption slgnais distinctly aDDeer in a
wide range by the linear field sweep unit.
JAPANELECTRONOPTICS LABORATORY CO.,lTO. New Tokyo Bldg., Tokyo, Japan
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The Review of Physical Chemistry of Japan Vol. 36 No 1 (1966)
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a.
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G/ihrafsd with the /Nas/er fro.-Piston Gauge !n Kobe Sfaal.
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KOBE STEEL• MACHINERY DIVISION HEAD OFFICE: 36, 1•chome, Wakinohama-cha, Fukiai-ku,
Robe, Japan OVERSEAS OFFICES: New York, DussiddroT. New Delhi TOKYO OFFICE: Yanagiya Bldg., No. 2-l, Tori 2-Chome,
Chuo-ka, Tokyo, Japaa
Liquid Pressure up to 15,000kg/cm~
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Super Hlgh Pressure Generator Unit Super High Praswra Reaction Vessel Super High Pressure Measurement Gauge Super High Prsswre Equipment
Other Malor Products
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The Review of Physical Chemistry of Japan Vol.
I
36 No. 1 (1966)
~~.
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~' ._ ~>r v
Single crystals of HORIBr1 INSTRUMENTS, INC., offered as complete products ready to use which are free from impurity absorption. have squired worldwide reputations.
Our scintillators, such as NaI (Tl), CsI (TI) or CaI2 are also credited and used internationally by the nuclear scientists, for the established qualifies.
Limit of transparancy (microns)
Refractive index:
Soluhil ity '•
Specific gravity: gr/cm~
Melting point: °C
Maximum diameter: mm
Maximum height: mm
NaCI KCI KBr KI LiF AgCI KRS-5' KRS-6• CsI
~-IS X21 -~27 X31 ~fi x-30 X40 -y34 -y70
1.555 L499 L559 1.667 1.394 2.071 2.629 233fi 1.987
35.i 28.5 53.5 ] 27.5 0.27 8.9 x 10'5 0.07 032 44
2.1fi 1.59 2.75 3.13 2.64 S.Sfi i.7 7.19 4.53
801 77fi 730 680 843 455 4I5 424 621
120 120 120 120 100 60 60 60 60
IW 100 100 70 60 ]00 60 100 100
s KRS•5 is a compound single crystal of TII and TIBr,
and TIBr. ss g/100 gr water at normal temperature.
and KRS-fi is a compound single crystal of TICI
HORIBA IN STRUME NTS, ING.
Head office & Factory: \akagawara 1liyanohigashi-machi,
Kissyoin, I.Iinami-ku, Kyoto Tel : 37-gt21
Tokyo branch office: \o. 2-10, 1Fi=hihatchobori, Chuo-ku,
Tokyo Tel: ii2-7661
The Review of Physical Chemistry of Japan Vol. 36 No. 1 (1966)
PRODUCTS FOR
PRODUCTS
TODAY
FOR TOMORROW
KA.TV`EGAFUCHI now serves more than 100 industries
varying from food to feed, soaps to textiles, electric wires
to plastics.
KA?tEGAFUCHI's variety of products include industrial
chemicals, polymers, oil & fat products and fermentation
products. Such diversified operation ranks KANEGA-
FUCHI aunique position in the industry.
KA~IEGAFUCHI's research activities which enabled
successful achievement of today's products are continually
producing a flow of new products to meet the challenge
of tomorrow
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PRINCIP~A"L~''PRODUCTS
•KAKEVINYL (PVC &
copolymer, PVC compound)
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fiber)
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o Caustic soda, FIydrochloric acid,
KAXECHLOR (transformer oil,
beat transfer medium), Butanol, Acetone
O Bakery }•east, RNP (ribo-
nucleo-protein), b1IKAMY- Peed (animal feed additives)
• illargarine. Shortening oil,
Soap, Glycerine
KANEGAFUCHI CHEMICAL INDUSTRY
14, 2-chome, Awezi-machi, Higashi-ku, Osaka, Japan
Cable address: CHEM[G-ANE
CO, LTD.
The Review of Physical Chemistry of Japan Vol. 36 No. 1 (1966)
ASAHI CHEMICAL INDUSTRY CO., LTD.
Capital: ~15,000A00.000
President: KAGAYAKI ;v1IYAZAKI
Head Office: 25, 1-c6ome. Dojima-hamadori, Kita-ku Osaka, Japan
Tokyo Office: 12, Lchome. Yurakucho, Chiyoda-ku Tokyo, Japan
Other Branch Offices: Nobeoka, Fuji, Fukuoka, Sapporo, Nagoya, Fukui, Kanazawa, New York
Plants: Nobeoka. Fuji, Kawasaki, Sakanoichi, Wakayama
Laboratories: Tokyo (Technical Research Laboratory) Takatsuki (Textile Research Laboratory)
Asahi's history dates as far back as 1923 when
the late Mr. Jun Noguchi, who was the firs[
president of the company, erected a synthetic ammonia plan[ in Nobeoka, present site of the
company's major plants. This is a memorable
plant in that the fist commercial production of synthetic ammonia in the world by the Casale
process was successfully started at this plant. Thereafter Asahi's production activity rontim
ved to expand, with the exception oC the war
years, into great many fields. Using ample elec-tric power from its own power plants and stand-
ing on the firmly established basis that primary
raw materials are available within the company.
Asahi has been producing chemical fibers, s}•n-
thetit resin, explosives, chemiral fertilizers, chemical seasoning, industrial nitrocellulose and
several scores of chemicals of ammonia, soda and
chlorine derivatives.
This fact points up to Asahi's special feature
as a chemical compan}•. Asahi ranks first in the
production of viscose rayon in Japan and its cuprammonium rayon capacity is largest in the world. Using acrylonitrile monomer produced
by Sohio process at its Kawasaki plant. Asahi
produces polyacrylic fiber "Cashimilon" by its own process. Production acrylonitrile monomer
and of polyazrylic 56er is also the largest in
Japan. Asahischemital seasoning(monosodium
glutamate) Asahi Aji, ranks second in output of similar chemical seasonings. Sun-Nitrq Asahi's
unique chemical fertilizer, is building up for it-
self aspectacular sales. Asahi's industrial nitro-
cellulose and electrolytic soda production is the
largest in Japan. Asahi is also at the top in pro-
duction volume of all the explosives manufac-
turers in Japan. Recently Asahi launched into
three new fields of operation, i. e. nylon 6, syn-
thetic rubber polybu[adiene "ASADENE" and
new building material "Silikaltsuiit".
At present. Asahi's products arc exported to
50 diKerent countries. Export of the process is
also making headway. 15'orthy of mention in
this connection is the export of viscose rayon
manufacturing techniques to Che Baroda Rayon
Corporation, India and Dawood Industries Lim-
ited, Pakistan, and of polyazrylic fiber manu-
facturing techniques to ANIC S. p. A., Italy.
Through all these activities, the excellence of
Asahis techniques is highly evaluated. Asahi now has many powerful affiliates, in-
cludiag Asahi-Dow Limited and Shin Nihon
Chemical Industry Co., Ltd. and is proceeding
on the road to further growth as a multiple-
purpose chemical compan}•.