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School of something FACULTY OF OTHER Nigerian Energy Crops – Properties and Improvement via Torrefaction Nwigwudu Ikechukwu Supervisor: Prof. Jenny .M. Jones 2 nd August, 2012ugust, 2012 (Project overview) School of Chemical and Process, Engineering Femi S. Akinrinola 27 th January, 2015 Supervisors : Prof. Jenny .M. Jones & Alan Williams Torrefaction and Combustion Properties of Some Nigerian Biomass

Thesis Overview

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This presentation is on Torrefaction of biomass. This thesis includes numbers of objectives that aimed at investigating torrefaction and combustion properties of some Nigerian biomass. Some potential energy crops and woods from Nigeria, namely Terminalia superba, Gmelina arborea, Lophira alata, Nauclea diderrichii, and also one abundant agricultural residue, palm kernel expellers (PKE), were characterized for their combustion properties. Some of the drawbacks in the utilisation of biomass as feedstocks in power stations is their heterogeneous nature and high moisture content at first harvest (hydroscopic and hydrophilic) which makes them susceptible to bacterial degradation during storage. In addition, their fibrous nature that makes them very difficult to grind, and their low heating value reduces their competitiveness in the energy generation market. Biomass feedstocks can differ noticeably in term of morphological, physical, and chemical properties. The problems associated with the characteristics of biomass thus increase the processing cost in its supply chain, especially during feedstock preparation, handling, and transportation. A feasible solution to solve the problems associated with solid biomass is to pre-treat the fuels using some of the methods that were described in Chapter 1. One of the pre-treatment solutions which is of great interest in the last decade is torrefaction. Here, an investigation is carried out of how this thermochemical treatment affects the physical and chemical properties of biomass thereby presenting a more premium fuel. A feasible solution to solve the problems associated with solid biomass is to pre-treat the fuels using some of the methods that were described in Chapter 1. One of the pre-treatment solutions which is of great interest in the last decade is torrefaction. Here, an investigation is carried out of how this thermochemical treatment affects the physical and chemical properties of biomass thereby presenting a more premium fuel. A feasible solution to solve the problems associated with solid biomass is to pre-treat the fuels using some of the methods that were described here. One of the pre-treatment solutions which is of great interest in the last decade is torrefaction. Here, an investigation is carried out of how this thermochemical treatment affects the physical and chemical properties of biomass thereby presenting a more premium fuel.

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Page 1: Thesis Overview

School of somethingFACULTY OF OTHER

Nigerian Energy Crops – Properties and Improvement via Torrefaction

Nwigwudu Ikechukwu

Supervisor: Prof. Jenny .M. Jones

2nd August, 2012ugust, 2012

(Project overview)

School of Chemical and Process, Engineering

Femi S. Akinrinola

27th January, 2015

Supervisors : Prof. Jenny .M. Jones & Alan Williams

Torrefaction and Combustion Properties of Some Nigerian Biomass

Page 2: Thesis Overview

The Challenges

Environmental concerns

Energy security

Power outage: Demand versus Supply

Global challenges

Local (Nigeria) challenges

Fewer people are connected to grid

Environmental pollution from sawmills.

Images source: creative common, assessed 26/01/2015.

Page 3: Thesis Overview

Obligations/Targets

The Renewable Energy Directive 2009/28/EC

Renewables’ share of electricity generation increased from 13.6 per cent in 2013 Q3 to 17.8 per cent in 2014 Q3.

Nigeria

45% of this energy quota is Bioenergy in 2014 Q3

Source: Department of Energy & Climate Change, United Kingdom, (2015).

Page 4: Thesis Overview

Issues with biomass

Page 5: Thesis Overview

Aim and objectives

The aim of this study is to evaluate the energy potential of Nigerian woods and a residue for large scale electricity generation.

Key objectives

To assess the energy potential of some of the biomass resources in Nigerian and see how they compare with European biomass.

To carry out torrefaction studies on some European and Nigerian biomass.

To examine the fate of nitrogen in the fuel during torrefaction as well as the behaviour of lignocellulosic component of the fuel upon torrefaction.

To investigate the products of torrefaction in terms of their composition, chemical and physical characteristics.

To understand the pyrolytic characteristics of thermally treated biomass.

To study the combustion behaviour of thermally treated biomass and also to assess the reactivities of the chars from torrefied fuels.

Page 6: Thesis Overview

Methodology

Steps Approach

Sourcing of common Nigerian raw fuels Gmelina, Terminalia, Nauclea, Lophira and PKE

Characterisation of the sourced fuels Proximate and ultimate analyse, metal analysis, fouling and slagging indices, ash fusion tests and lignocellulose analysis

Pyrolysis & combustion studies of the sourced fuels

TGA analysis, fuel reactivity, PyGCMS analysis and single particle combustion study

Treatment of the sourced fuels Torrefaction

Characterisation of the treated biomass Proximate and ultimate analyse, metal analysis, fouling and slagging indices, ash fusion tests, grindability , lignocellulose analysis

Pyrolysis & combustion studies of treated biomass

TGA analysis, fuel reactivity, PyGCMS analysis and single particle combustion study

Page 7: Thesis Overview

Introduction to Torrefaction

Torrefaction – a mild thermochemical process Temperature range is 230-290o C.

Torrefied Biomass Becomes friable and

hydrophobic. Improved calorific value

(18-23MJ/kg) Improved grindability Improved storage,

handling and transport Reduced possibility of

contamination Increased bulk energy

density

Page 8: Thesis Overview

Result

Page 9: Thesis Overview

Key findings

Nigerian fuels have low N, S, Cl.

High carbon content resulted in relatively higher CV than the European biomass

(19.2-21.2 MJ/kg for the raw fuels to 21.2-25.6 MJ/kg for the torrefied fuels).

The low alkali index of the fuels suggest they are not predicted to cause severe

fouling problems.

Generally, torrefaction showed significant improvement on the fuel properties with

respect to calorific value and grindability except for PKE where little effect was

seen in its grindability performance.

Torrefaction process led to loss of N in the fuels.

Upon torrefaction, the fuel becomes less reactive and thermally stable.

In summary, these fuels showed high potential for large scale electricity production.

However, further studies should examine the sustainability of supply chain for this

fuel to ensure good Carbon reduction.

Page 10: Thesis Overview

THANK YOU