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The Shell Model of the Nucleus
2. The primitive model
[Sec. 5.3 and 5.4 Dunlap]
Reason for Nuclear Shells
Type of particles Fermions Fermions
Indentity of particles electrons neutrons + protons
Charges all charged some charged
Occupancy considerations PEP PEP
Interactions EM Strong + EM
Shape Spherical Approximately spherical
ATOM NUCLEUS
The atom and nucleus have some differences – but in some essential features (those underlined) they are similar and we would expect similar quantum phenomenon
ATOM – SPECIAL NUMBERS: 2, 10, 18, 36, 54, 86
NUCLEUS – SPECIAL NUMBERS: 2, 8, 20, 28, 50, 82, 126
where there is extra strong binding.
Atomic Shell Model
0
12
0
2/1
3
3
0,
2.
2.
)!(2
! )1(2)( 0
na
ZrL
na
Zre
lnn
ln
na
ZrR l
lnna
Zr
ln
Principle Quantum No = 1)( lnr
n=1
n=2
n=3
Atomic Shell ModelThe amazing thing about the 1/r potential is that certain DEGENERGIES (same energies) occur for different principal quantum no “n” and “l”.
En
Z
mcn
Z
nc
mceZEn
2
222
2
2220
242
2
1
)()4(2
1
Principle Quantum No =
Radial node counter = nr
1)( lnr
Atomic Shell ModelStarting with the Solution of the Schrodinger Equation for the HYDROGEN ATOM
EVmc
c
)(
22
2
22
r
The natural coordinate system to use is spherical coordinates (r, , ) – in which the Laplacian operator is
2
2
2222
22
sin
1sin
sin
11
rrr
rrr
and the central potential being “felt” by the electron is the Coulomb potential
r
erV
)4()(
0
2
Nuclear
nl
We must now , however, use the shape of the nuclear potential – in which nucleons move – this is the Woods-Saxon potential, which follows the shape of the nuclear density (i.e. number of bonds).
aRr
VrV
/)(exp1)( 0
Nuclear Shell ModelFor a spherically symmetric potential – which we have if the nucleus is spherical (like the atom) – then the wavefunction of a nucleon is separable into angular and radial components.
),().(
)()()(),,(
lmnl YrR
rRr
where as in the atom the ),( lmY are the spherical harmonics
im
lmlm ePY2
1).(,
where the are Associated Legendre Polynomials made up from cos and sin terms.
THE RADIAL EQUATION is most important because it gives the energy eigenvalues.
)(lmP
RERrmc
cllrV
dr
dRr
dr
d
rmc
cnl
22
22
22
2
.2
))(1()(
1
2
)(
Nuclear Shell Model
nlnlnlnlnl
nlnlnlnl
RERrmc
llcrV
dr
dR
rdr
Rd
mc
c
RERrmc
llcrV
dr
dRr
dr
d
rmc
c
22
2
2
2
2
2
22
22
22
2
.2
)1(.)()(
2
2
)(
.2
)1(.)()(
1
2
)(
Solving the Radial Wave Equation
Now make the substitution which is known as “linearization”
nlnlnlnl UEU
rmc
llcrV
dr
Ud
mc
c
22
2
2
2
2
2
.2
)1()()(
2
)(
The similarity with the 1D Schrodinger equation becomes obvious. The additional potential terms – is an effective potential term due to “centrifugal energy”. In the case of l=0, the above equation reduces to the famous 1D form. So what we really need to do is now to solve is:
nlnlnlnl UEU
rmc
llc
aRr
V
dr
dU
mc
c
22
20
22
2
.2
)1(.)(
/)(exp12
)(
[Eq. 5.7]
rRU nlnl .
Looking at the Centrifugal Barrier
nlnlnlnl UEU
rm
llrV
dr
Ud
mc
c
2
2
2
2
2
2
.2
)1()(
2
)(
The diagram shows the effect of the centrifugal barrier for a perfectly square well nucleus. The effect of angular momentum is to force the particle’s wave Unl(r) outwards.
2
22
21
2
.
mr
LmE
mr
L
rmL
Centrifugal potential
0l 1l 2ls p d
Solutions to the Infinite Square Well
nlnlnlnlnl RER
mr
llrV
dr
dR
rdr
Rd
m
2
2
2
22
2
)1()(
2
2
]/)exp[(1)(
sSaxon Wood
2
11)(
Oscillator Harmonic
for 0
for )(
WellSquare Finite
for
for )(
WellSquare Infinite
0
2
0
0
0
aRr
VrV
R
rVrV
Rr
RrVrV
Rr
RrVrV
Solutions to the Infinite Square Well
nlnlnlnlnl RER
rmc
llcV
dr
dR
rdr
Rd
mc
c
22
2
02
2
2
2
2
)1()(2
2
)(
The solutions to this equation are the Spherical Bessel Functions
3
2
2
)(
)sin()()cos()(3)sin(3 2
)(
))cos((-)sin( 1
)(sin 0
kr
krkrkrkrkr
kr
krkrkrkr
kr
l )(krjl
2
2
)(
.2
c
Emck
Solutions to the Infinite Square WellThe zero crossings of the Spherical Bessel Functions occur at the following arguments for knl r
So that the wavenumber knl is given by:
2
2
02
2
2
2
.2
)(
nlnl
nl
nlnl
nlnl
xE
R
x
mc
cE
R
xk
xRk
And the energy of the state as:
Rkx nlnl
Coulomb Infinite Square Well Harmonic Oscillator
p1
f1
COMPARISON OF SCHRODINGER EQN SOLUTIONS
2
8
20
34
40
58Apart from 2,8 and 20 all the other numbers predicted by the primitive shell model are WRONG.
Note that the energy sequence is effective the same in all potential wells