The GlucoPure Grades - Välkommen - Sepawasepawa.org/wp-content/uploads/2015/07/3_conference-Glucopures.pdf · Nordic SEPAWA conference 2015 04/05/2015 – Dr. F. Schinle Marketing

Nordic SEPAWA conference 2015

04/05/2015 – Dr. F. Schinle

Marketing & Application

BU ICS

Industrial & Home Care

The GlucoPure Grades

A New Generation of sugar

surfactants for home care applications

Presentations/Videos/HomeCare_Mood_Video_Final.wmv

Marketing & Application, BU ICS, Industrial & Home Care

GlucoPure is renewable. More than 95% of Renewable Carbon Index

2

100% renewable glucose 100% renewable, RSPO certified

fatty acid esters or triglycerides

GlucoPure Grades – Nordic SEPAWA conference 04/05/2015


GlucoPure Product Range

3

Product GlucoPure Foam GlucoPure Deg GlucoPure Wet

Active Matter 40% 60% 50%

C-chain basis RBD Coco Oil C12/14 Methylester C8/10 Methylester

Applications HDWL HDWL

HSC

Bathroom cleaner

Benefits

Superior foaming properties

Excellent formulation stability



High concentrated, contains

Ethanol

Strong wetting properties

High Soap Scum removal

HIGHLY

RENEWABLE

EXCELLENT

AQUATOX PROFILE

MILD TO

THE SKIN

HIGH

PERFORMANCE



04/05/2015 – Dr. F. Schinle


BU ICS


Discover GlucoPure Foam & Glucopure DEG


What is precious to the consumer?

5

High performance at

affordable cost

A pleasant skin feeling after

manual dishwashing

More sustainable and effective

alternatives in the market



Challenges for the experts

6

Performance Soil and hard water easily break foam and

diminish the detergent’s performance

Flexibility

Viscosity in concentrated formulations is

hard to control and hard to balance with

cold cloud point

Mildness Most surfactants are harsh to hands

Green Current green raw-materials are not

effective enough




7





HSC

Bathroom cleaner

Benefits






Ethanol



HIGHLY

RENEWABLE

EXCELLENT

AQUATOX PROFILE

MILD TO

THE SKIN

HIGH

PERFORMANCE



GlucoPure Grades are ecosafe. Excellent aqua-toxicological profile

No aquatox labelling under GHS for GlucoPure Deg & Foam

GlucoPure allow formulations with lower aquatic toxicity consistent with upcoming

EU regulations (2015)

8

Properties Cocamidopropyl

Betaine Coco Betaine Lauramine Oxide

GlucoPure Deg &

GlucoPure Foam

Readily

biodegradable Yes Yes Yes Yes

RCI (%) 63 75 86 >95

GHS

Labelling

H 412

Harmful for aquatic

organisms, long term

effect

H 412

Harmful for aquatic

organisms, long

term effect

H 400

Very toxic for aquatic

organisms

H 411

Toxic for aquatic


effect

No aquatox label



GlucoPure is mild. Zein Test shows that GlucoPure is even milder than Betaines

9

0

100

200

300

400

500

Sodium DodecylSulfate

CocamidopropylBetaine

GlucoPure Foam Lauryl Glucoside

Ze

in v

alu

e (

mg

N /

10

0 m

L)

Zein Test

The lower

the milder



GlucoPure Foam enables high performance, highly renewable

and low aquatox profile hand dishwashing liquids

10

Recipe (%a.i.) A B C D

Sodium Laureth Sulfate (2EO) 18 18 18 18

Cocoamidopropyl Betaine 12 6 - -

GlucoPure Foam - 6 12 -

Lauryl-Polyglycoside - - - 12

Renewable % of surfactants (RCI) 69% 76% 83% 85%

GHS Labelling of the co-surfactant H 412 H 412 No aquatox No aquatox

All formulations with 7.0% Ethanol and water IKW performance test “Recommendation for the quality assessment of the cleaning performance of hand dishwashing detergents” (Nitsch. C. and Hüttmann G. SÖFW-Journal, 128, 5.

Pp. 11-15, 2002) – adapted with 0.3 g HDWL/L

Number of Washed Plates

Plate Test (IKW I - Carbohydrate)

CAB

CAB +

GlucoPure GlucoPure APG

32 34 31 16



11


Sodium Laureth Sulfate (2EO) 18 18 18 18

Cocoamidopropyl Betaine (CAB) 12 6 - -

GlucoPure Foam - 6 12 -

Lauryl-Polyglycoside (APG) - - - 12

Renewable % of surfactants (RCI) 69% 76% 83% 85%

GHS Labelling of the co-surfactant H 412 H 412 No aquatox No aquatox

Plate Test (IKW II - Grease)


GlucoPure Foam enables high performance, highly renewable

and low aquatox profile hand dishwashing liquids

All formulations with 7.0% Ethanol and water IKW performance test “Recommendation for the quality assessment of the cleaning performance of hand dishwashing detergents” (Nitsch. C. and Hüttmann G. SÖFW-Journal, 128, 5.

Pp. 11-15, 2002) – adapted with 0.3 g HDWL/L

26 25 22 14

CAB

CAB +

GlucoPure GlucoPure APG



Concentrated HDWL can be formulated with low VOC

content, keeping viscosity and cold cloud point under control

12

Recipe (%a.i.) A B C D B’ C’ D’

Sodium Laureth Sulfate (2EO) 18 18 18 18 18 18 18

Cocoamidopropyl Betaine 12 6 - - 6 - -

GlucoPure Foam - 6 12 - 6 12 -

Lauryl-Polyglycoside - - - 12 - - 12

Ethanol 7 7 7 7 5.5 4 4

Viscosity (mPas) 2400 500 80 150 2000 2250 2250

Cold Cloud Point (°C) 0,6 -0,8 -5,1 0,6 -2,0 -3,2 2,4



GlucoPure Foam offers high performance at low aquatic

toxicity by replacing amine oxides in >95% RCI formulations

13

Plate Test (IKW I - Carbohydrate)


AO +

GlucoPure

AO +

APG GlucoPure APG

No solvent and no NaCl added IKW performance test “Recommendation for the quality assessment of the cleaning performance of hand dishwashing detergents” (Nitsch. C. and Hüttmann G. SÖFW-Journal, 128, 5.

Pp. 11-15, 2002)

32 24 29 16


Sodium Laurylsulfate 8 8 8 8

Lauramine Oxide (AO) 3 3 - -

GlucoPure Foam 4 - 7 -

Lauryl-Polyglycoside (APG) - 4 - 7

Renewable % of surfactants (RCI) >95% >95% >95% >95%

GHS Labelling of the co-surfactant H 400 +

H 411

H 400 +

H 411

No

aquatox

No

aquatox



GlucoPure Foam offers high performance at low aquatic

toxicity by replacing amine oxides in >95% RCI formulations

14

Plate Test (IKW II - Grease)


AO +

GlucoPure

AO +

APG GlucoPure APG

No solvent and no NaCl added IKW performance test “Recommendation for the quality assessment of the cleaning performance of hand dishwashing detergents” (Nitsch. C. and Hüttmann G. SÖFW-Journal, 128, 5.

Pp. 11-15, 2002)

23 18 21 11



Lauramine Oxide (AO) 3 3 - -


Lauryl-Polyglycoside (APG) - 4 - 7

Renewable % of surfactants (RCI) >95% >95% >95% >95%

GHS Labelling of the co-surfactant H 400 +

H 411

H 400 +

H 411

No

aquatox

No

aquatox



Formulations with GlucoPure Foam can be thickened by

NaCl keeping the cold cloud point at a very low level

15

Recipe (%a.i.) C D C’ D’



APG - 7 - 7

Sodium chloride - - 1,1 1,25

Viscosity (mPas) 20 20 1950 1850

Cold Cloud Point (°C) -11,6 -0,5 -4,9 1,5




16



Flexibility



cold cloud point



effective enough



Solution GlucoPure: the novel mild sugar surfactants with high performance and high renewable content

17

Challenges Solution



Flexibility



cold cloud point



effective enough

High foam mileage in hard and soft water

Easy viscosity adjustment and excellent

cold temperature stability

Very mild surfactant to human skin

Excellent eco-toxicological profile

Renewable content of 95% based on

carbon atoms



04/05/2015 – Dr. F. Schinle


BU ICS


Discover GlucoPure Wet


What is precious to the consumer?

19

Easy removal of soap scum

More sustainable and effective

alternatives in the market

The surfaces in my bathroom

always looking new




20

Mildness Most bathroom cleaners are harmful to

plastic and metal surfaces

Green Best co-surfactants for this market are not

green

Performance

Soap scum is a tough soil to remove

The removed soil easily redeposits on the

surface

Flexibility Bathroom cleaners have a low pH

Foam control is key




21





HSC

Bathroom cleaner

Benefits






Ethanol



HIGHLY

RENEWABLE

EXCELLENT

AQUATOX PROFILE

MILD TO

PLASTICS

HIGH

PERFORMANCE


GlucoPure Grades are ecosafe. Excellent aqua-toxicological profile

No aquatox labelling under GHS for GlucoPure WET

GlucoPure allow formulations with lower aquatic toxicity consistent with upcoming

EU regulations (2015)

22

Properties Cocamidopropyl

Betaine Coco Betaine Lauramine Oxide GlucoPure WET

Readily

biodegradable Yes Yes Yes Yes

RCI (%) 63 75 86 >94

GHS

Labelling

H 412

Harmful for aquatic


effect

H 412

Harmful for aquatic

organisms, long

term effect

H 400

Very toxic for aquatic

organisms

H 411

Toxic for aquatic


effect

No aquatox label


23

GlucoPure Wet shows superior soap scum

removal against the currently used surfactants

0

20

40

60

80

100

APG Ethoxylates GlucoPure Wet

Ave

rag

e s

oa

p s

cu

m

rem

ova

l (%

)

Ingredients (% a.i.) A B C

Alkylpolyglycoside (C8-10) 2,3 - -

C9-11 Pareth-7 - 2,3 -

GlucoPure Wet - - 2,3

Sodium Laureth Sulfate (2EO) 1,0 1,0 1,0

Appearance clear clear clear

pH value 3,7 3,7 3,7

Soap scum removal test

00:00

All formulations with 3.0% Citric Acid, 2.0% Sodium Citrate and water



24



0

20

40

60

80

100


Ave

rag

e s

oa

p s

cu

m

rem

ova

l (%

)



C9-11 Pareth-7 - 2,3 -




pH value 3,7 3,7 3,7


02:30



25



0

20

40

60

80

100


Ave

rag

e s

oa

p s

cu

m

rem

ova

l (%

)



C9-11 Pareth-7 - 2,3 -




pH value 3,7 3,7 3,7


05:00



26



0

20

40

60

80

100


Ave

rag

e s

oa

p s

cu

m

rem

ova

l (%

)



C9-11 Pareth-7 - 2,3 -




pH value 3,7 3,7 3,7


07:30




27



0

20

40

60

80

100


Ave

rag

e s

oa

p s

cu

m

rem

ova

l (%

)



C9-11 Pareth-7 - 2,3 -




pH value 3,7 3,7 3,7


10:00




GlucoPure Wet is compatible with the materials

common in bathrooms – in contrast to ethoxylates

*Stress-corrosion cracking of plastic material (DIN 53449-T)

28

Material APG Ethoxylates GlucoPure Wet

0-7d 7-14d 0-7d 7-14d 0-7d 7-14d

ABS Acrylnitrile-Butadiene-

Styrene Copolymer

PC Polycarbonate

(transparent)

PMMA Polymethylmethacrylate

(transparent)

POM1 Polyoxymethylen (grey)

POM2 Polyoxymethylen (white)

Stress-corrosion test*




29




green

Performance



surface


Foam control is key



Solution GlucoPure: the novel mild sugar surfactants with high performance and high renewable content

30

Challenges Solution

High wetting power

Excellent soap scum dispersion

GlucoPure Wet works from pH 3 to 10

Adjustable foaming profiles

No corrosion on metal surfaces

Excellent compatibility with a variety of

plastic surfaces

Excellent eco-toxicological profile

Renewable content of 95% based on

carbon atoms




green

Performance



surface


Foam control is key


Documents

The GlucoPure Grades - Välkommen - Sepawasepawa.org/wp-content/uploads/2015/07/3_conference-Glucopures.pdf · Nordic SEPAWA conference 2015 04/05/2015 – Dr. F. Schinle Marketing