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Tank Storage Istanbul 2011 29-30 November 2011

Grand Cehavir Hotel, Istanbul, Turkey

News regarding venting of atmosheric

and low-pressure storage tanks

News regarding use of flame arresters (why do p/v-vents not function as flame arrester?)

Dipl.-Ing. Axel Sommer

PROTEGO Braunschweiger Flammenfilter GmbH

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New International Standard: Venting of atmospheric and low-pressure

storage tanks ISO 28300

EN 14015

Annex L

API 2000

5th edition

TRbF 20

ISO 28300 Petroleum,

petrochemical and natural gas industries Venting of atmospheric

and low-pressure storage tanks

API 2000

6th edition

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Background and development of ISO 28300 Standard

ISO 28300 was mainly developed based on the API 2000 standard 1998 6th Edition and the EN 14015 Standard Annex L and the German TRbF 20

Contradiction towards the venting requirements for normal venting

Contradiction towards the use of vents as flame arresters

Committee goal: This standard shall consider all state of the art

knowledge concerning tank venting and safety and provide best practice to the user

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Why new calculation methods for determining normal venting requirements?

Prof. Salatino from the University of Napoli predicted that the calculation method of API 2000 may underpredict thermal breathing

The German TRbF 20 standard developed by Dr. Hans Foerster from the Federal Institute if Physiks (PTB) also results in higher values for thermal breathing

The EN 14015 Standard developed by Dr. Wheyl from BASF also results in higher breathing values

All the above methods depend on a detailed thermodynamic model and provide higher inbreathing rates than the API 2000 standard

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Validation of results for inbreathing

Prof. Salatino Model calculation at University of Napoli, 1999

Tank: V = 63000 m3; D = 70 m; H = 15 m T = 40 C Water (rain) flow density Refined model calculation - Dynamic simulation (pressure

differential at vent) - Different start temperatures of roof, shell

and product

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Validation of results for inbreathing

Prof. Salatino Model calculation at University of Napoli, 1999

ISO 28300

API 2000 TRbF 20

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Validation of results for inbreathing

Life field tests and model calculation at Hoechst in 1980 and 1981

Tank: V = 617 m3; D = 8,5 m; H = 10,6 m

17 C T 26 C

Water (rain) flow density: about 60 kg/m2h

TRbF-model calculation

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Validation of results for inbreathing

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Summary The new section is based on the European EN 14015 Standard.

The approach used is more general than API (the API approach is centered around hexane or similar services).

Calculated vent rates with the new approach can be substantially higher for certain tank sizes than what is shown in API-2000.

A research paper from Prof. Salatino and research results from Hoechst in Frankfurt, which had been provided by Dr. Hans Foerster from the PTB justified this change.

An advantage of the new calculation method is that it does allow to consider full and partial insulation of the tank for normal in- and out-breathing.

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ISO 28300 venting requirements

inpumpoutthermalout VVV +=

Normal out-breathing and normal inbreathing flows are defined as the combination of tank vent flows due to:

Liquid flows into and out of the tank

Ambient weather (thermal) effects

outpumpinthermalin VVV +=

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Liquid filling capacities - out-breathing

special calculation have to be done for spike products, and at storage temperature > 40C and vapour pressure > 50 mbar:

out-breathing rate = filling rate

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Liquid filling capacities - inbreathing

in-breathing rate = discharging rate

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General assumptions and approximations: Uniform (time dependent) temperatures of wall, tank

atmosphere, ambient air and rainwater-film

Primary result is the temperature of the tank atmosphere in dependence on time ; volume flow rates are then deduced by an isobaric approach (constant ratio of volume to temperature)

Tank atmosphere is air at ambient pressure

Wall thickness is according to common tank standards ( 4 mm)

No heat flux via tank bottom

Basis: Model calculations for a fixed roof above ground storage tank of steel

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Determining of normal & emergency venting requirements

General Basic Equation for ISO 28300 Model:

dtdT

TVV g

g

=

( )dt

dTcVTTAkQ gggsg ==

Energy balance to describe temperature distribution with respect to time

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convection convection

solar irradiation

Heat flows during heating by solar radiation (outbreathing)

far IR radiation loss

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Solution if solving differential equation:

0 900 1800 2700 3600 4500 5400 6300 7200

Time t in s

0

20

40

60

80

Volu

me F

low

V in

m3 /h

15

20

25

30

Tem

pera

ture

in

o C

VG,BVG,B

WW

GG

Maximum volume flow

Maximum volume flow occurs at maximum delta T

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Thermal out-breathing simplified as in ISO 28300

in0,9

outoutthermal RVCV T=

Cout = 0,2 latitude : > 58

Cout = 0,25 latitude : 58-42

Cout = 0,32 latitude : < 42

Rin = reduction factor insulation

Vt = tank volume

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Heat flows during cooling by rain (inbreathing)

Rain water flow to wall

Rain water drain from wall

convection and

evaporation

conduction

convection

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0 180 360 540 720 900Time t in s

0

60

120

180

240

300

Volu

me F

low

V in

m3 /h

15

25

35

45

55

Tem

pera

ture

in

o C

VG,BVG,B

WW

GG

Maximum volume flow

Maximum volume flow occurs at maximum delta T

Solution if solving differential equation:

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Thermal - inbreathing

in0,7

ininthermal RVCV T=

Rin = reduction factor insulation

Vt = tank volume

latitude < 25 C 25C < 25 C 25C> 58 2,5 4 4 4

42 - 58 3 5 5 5< 42 4 6,5 6,5 6,5

Cinvapour pressure

haxane or similar higher than hexane, or unkown

storage temperature

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Calculation Examples Tank 1

Tank:

Height: 5m

Diameter: 7m

Tank volume: 192.4 m3

Pump in rate: 96 m3/h

Pump out rate: 96 m3/h

Vertical tank

No insulation

MAWP: + 7.5 mbar

MAWV: - 2.5 mbar

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Inbreathing Requirements (Total) for Tank 1

Inbreathing requirements Tank 1

0

50

100

150

200

250

300

350

400

API 2000 EN 14015,North, VPHexane

EN 14015,North, VP>

Hexane

EN 14015, 42-58, VP Hexane

EN 14015, 42-58, VP>Hexane

EN 14015,South, VPHexane

EN 14015,South, VP>

Hexane

TRbF 20

Vent

ing

requ

irem

ents

[m3/

h]

Pump out Thermal

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Outbreathing Requirements (Total) for Tank 1

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116 117 123 130

118 122 109

Outbreathing requirements Tank 1

0

50

100

150

200

250

API 2000, FP=37.8C

EN 14015,North

EN 14015, 42-58

EN 14015,South

TRbF 20 TRbF 20-2 TRbF 20-3

Vent

ing

requ

irem

ents

[m3/

h]

Pump in Thermal

H/D = 0.5H/D = 2

H/D = 0.71

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Calculation Examples Tank 2

Very Large Size Tank (outside of scope of API 2000):

Height: 15 m

Diameter: 75 m

Tank volume: 66,268 m3

Pump in rate: 1,400 m3/h

Pump out rate: 1,400 m3/h

Vertical tank

No insulation

MAWP: + 7.5 mbar

MAWV: - 2.5 mbar

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Inbreathing Requirements (Total) for Tank 2

Inbreathing requirements Tank 5

0

2000

4000

6000

8000

10000

12000

14000

16000

18000

API 2000 EN 14015,North, VPHexane

EN 14015,North, VP>

Hexane

EN 14015, 42-58, VPHexane

EN 14015, 42-58, VP>Hexane

EN 14015,South, VPHexane

EN 14015,South, VP>

Hexane

TRbF 20

Vent

ing

requ

irem

ents

[m3/

h]

Pump out Thermal

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Outbreathing Requirements (Total) for Tank 2

Outbreathing requirements Tank 5

0

1000

2000

3000

4000

5000

6000

7000

8000

9000

10000

API 2000, FP=37.8C

EN 14015, North EN 14015, 42-58 EN 14015, South TRbF 20

Vent

ing

requ

irem

ents

[m3/

h]

Pump in Thermal

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Tank volume 592,000 barrel (94.120 m) Stored liquid Bitume Pump in 4542 barrel/h (722 m/h) Pump out 5458 barrel/h (867 m/h) Insulation Calciumsilicate Insulation thickness 2

Calculation example considering insulation:

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Overview Venting Requirements (API 20