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Sugar Cane Process WastesAuthor(s): Ralph StoneSource: Sewage and Industrial Wastes, Vol. 23, No. 8 (Aug., 1951), pp. 1025-1028Published by: Water Environment FederationStable URL: http://www.jstor.org/stable/25031665 .
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SUGAR CANE PROCESS WASTES By Ralph Stone
Sanitary Engineer, Los Angeles, Calif.
Sugar Cane Milling Processes
Sugar cane requires 18 months of
growth before harvesting. When the cane stalks have a satisfactory sugar content, they are cut down and trans
ported within a few hours to a sugar cane mill. There the stalks are
squeezed in rotary extractors to re lease the sap containing the sucrose
(CijjH^Ou). Refined sucrose is our common table sugar. The cellulose residue (Figure 1) is dried out by air
storage in a shed, and then burned to .
provide the heat energy for steam boilers and auxiliary power required in sugar manufacturing.
The squeezed sap is purified by skimming off the floating matter, called
"cachaza"; evaporation of the excess
water; and separation of the black
strap molasses. Sulfur is added to
provide a whiter final sugar product and small quantities of lime are em
ployed for pH control. The surface
skimming "cachaza" can be placed through a pressure or vacuum type filter to reclaim additional sugar sap. The fibrous filter residue is returned
to the fields as fertilizer. Similiarly, the blackstrap molasses can be con verted into alcohol and numerous other by-products or may be fed di
rectly to cattle. Even the ash from the burned cellulose residue employed as fuel is valuable for agricultural fertilizer. Boiler water and waste
wash water from the sugar cane mill are needed for irrigation of the cane
fields. It can be seen from this description
of the sugar cane processing that all the waste products resulting from the
production of sugar cane can and, should be re-employed as a source of
fuel, fertilizer, by-products, or irriga tion water. Hence, the intelligently designed and operated cane mills should not have waste pollution prob lems and should provide the highest operating efficiency and monetary profits.
Cauca Valley Pollution Survey
A stream pollution survey of the Cauca Valley, in Colombia, South
America, during July and August,
Cane Fields
Cachaza Fertilizer Sulfur
for Bleach
Lime for pH Control
Cane Squeezing
i?
Dried Stalks
Squeezed Juice
L1T21J _E^L^^-fJ?i??r
Irrigation Water
. Steam for H*! Heat and
Power
Recovered Juice
Filter
Purification
and
Crystallization
Products
I
^ Waste l*_ --I Water
~
Skimming Cachaza
Sugar
Molasses
Alcohol etc.
|
FIGURE 1.?Flow diagram of sugar mill operations, showing utilization and conservation of sugar, by-products, and waste water to minimize pollution of surface waters.
1025
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1026 SEWAGE AND INDUSTRIAL WASTES August, 1951
1950, demonstrated that the five-fold increase in cane production during the
preceding decade has resulted in pol lutional problems. In general, pollu tional complaints had been based on
taste, odor, and dead fish ; no attention was paid to the presence of pathogenic bacteria, which were accepted as a
matter of course.
Special field sampling equipment was employed for taking bacteriologi cal, dissolved oxygen, B.O.D., and chemical samples for laboratory analy sis. The refrigerated bottles of wa
ter and wastes were transported to the Cali water works laboratory for im
mediate examination. Samples that could not be analyzed in Cali were
flown to the National Sanitary Labo
ratory of the Ministry of Hygiene in
Bogota, where the laboratory work was terminated. Standard methods and modern scientific laboratory
equipment were employed in perform ing the analysis of the various cane
wastes, river waters, and sewage sam
ples.
The field investigations indicated
that sugar mills were the responsible agents for the pollution of the Parraga
and Guabas Rivers. Because of the
discharge of the sugar cane skimmings (cachaza) and plant wash water, the
Parraga River samples had a B.O.D. of more than 113 p.p.m. It was found that the Castilla sugar mill supplied over one-half the low flow of the Par
raga River. Similarly, although the Pichichi sugar mill attempted to con
trol its industrial waste waters by
lagooning and irrigation, at certain
times in the past there had been over
flows which had contaminated the
Guabas River basin.
The city of Cali discharges raw sew
age into the Cali River in volumes
great enough so that it represents 50
per cent of the low flow. However, the details on sewage pollution of the
Cauca Valley are outside the scope of
this paper. Besides the sugar mills mentioned,
other sugar cane plants surveyed in
cluded Manuelita, Mayaguez, and
Providencia. Numerous small and old
fashioned cane mills were also visited, but it was found that they do not pre sent a pollution problem because of
non-wasteful operating practices.
FIGURE 2.?Some mills reclaim sugar from cachaza in filter presses. to fields as fertilizer.
Cake is returned
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Vol. 23, No. 8 SUGAR CANE PROCESS WASTES 1027
FIGURE 3.?Reclamation of sugar from cachaza by vacuum filters permits chuting of cake to open cars for disposal in fields as fertilizer.
Laboratory Results
It was found that the industrial waste waters of the modern sugar
mills varied in B.O.D. content from 140 to 1,120 p.p.m. This effluent could be maintained at lower B.O.D. levels by more efficient plant operation, including the reclamation of sugar from cachaza through filtration (Fig ures 2 and 3). For example, the
Castilla sugar mill wasted more than
440,000 lb. of sugar a year through di
rect disposal of the cachaza into the
waste-water effluent. Similarly, the
high B.O.D. of the Pichichi mill waste
effluent is indicative of huge sugar
wastage.
Besides cachaza, valuable molasses
is sometimes wasted. The cachaza had
a B.O.D. content in the range of 85,000 p.p.m., but the molasses B.O.D. was
more than ten times as great with 930, 000 p.p.m. The strong pollution pos sible from such materials is evident. It also is interesting to note the pres ence of grease in some of the samples (10 to 6,640 p.p.m.) : the grease can
be explained as the result of wastage from machinery lubrication in the
sugar manufacturing plant. Table I
contains a short summary of important laboratory analyses of samplings.
The operating efficiency will de
termine the amount of water required
by a sugar mill to process a stated
quantity of sugar cane. The more ef
ficient plants require less water (1.32 to 1.55 c.f.s. per 100 tons of sugar
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1028 SEWAGE AND INDUSTRIAL WASTES August, 1951
TABLE I.?Summary of Important Chemical arid Bacteriological
Analyses of Sugar Mill Wastes and Receiving Waters
Mill Sample B.O.D. (p.p.m.)
Total Solids (p.p.m.)
E. coli (M.P.N./ 100 ml.)
Castilla
Pichichi Mayaguez
Providencia
Manuelita
Cachaza and waste water
Parraga River, upstream
Parraga River, downstream
Waste water
Waste water
Cachaza
Molasses
Waste water
Waste water
Molasses
473
113 1,120
140 84,700
930,000 250
917 261 361
2,302 144 178
290 165,970
3,800 9,500
1,300
cane) than the less efficient plants (1.77 to 2.64 c.f.s. per 100 tons of
sugar cane). Similarly, whereas the inef?icient mills will produce 8 tons of
sugar and 1.4 tons of molasses per 100 tons of raw cane, the more efficient
mills will produce 12.5 tons of sugar and 2.5 tons of molasses per 100 tons of raw cane (see Table II).
Summary and Conclusions
1. Samples of sugar mill waste ef fluents contained from 140 to 1,120 p.p.m. B.O.D., depending on the op
erating efficiency of the plant. An ef ficient sugar mill utilizes and con serves almost all the sugar, by-prod ucts, and waste water, resulting in minimum pollution of surface waters.
2. Sugar mills should filter the high B.O.D. cachaza waste skimmings, so as
TABLE IL?Comparison of Sugar Mill Operation Characteristics
Mill
Average
100 ion per of Cane
Molasses
1.4
2.3
2.5
0.8
1.6
1.7
Water Use per 100 Tons of
Cane (c.f.s.)
1.77
1.33
2.63
1.55
1.82
Molasses per 100 Tons of
Sugar (tons)
17.5
18.5
19
8
12.8
15.2
Sugar
Castilla Providencia
Pichichi Mayaguez Manuefita
8.0
12.5
9.9
10.0
12.5
(toi
Sugar
icia
ez
ta
8.0
12.5
9.9
10.0
12.5
10.6
to reclaim the sugar and fertilizer. available. This cachaza has a B.O.D. of about 85,000 p.p.m.
3. Molasses should be used for cat tle feed, or in the production of alcohol and other by-products, rather then
wasted to streams. Molasses B.O.D. is greater then 900,000 p.p.m.
4. Sugar mills should be located so
that the waste waters can be employed to irrigate the surrounding cane fields.
5. The squeezed cane stalks are
available for fuel to provide power and heat in the sugar mill. The ashes and filtered cachaza wastes are excel lent fertilizer for the cane fields.
6. It is economically advisable to conserve the valuable cane sugar and
by-products, rather than to dispose of them into and pollute the neighboring streams. Sugar cane waste pollution is the result of poor plant engineering and/or bad mill operation.
Acknowledgments
The help of many Colombian engi neers including the assistance of offi cials of the Colombian Ministry of Hy giene and the Institute of Inter-Ameri can Affairs is acknowledged. Particu lar thanks are due Dr. Hernando
Correal, chief, National Sanitary Lab
oratory, who supervised the analytical laboratory work, and Manuel Escal?n, Sanitary Engineer, who helped in the field sampling and correlation of data.
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