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STOIC HIOMETRY CALCULATIONS COACH COX

STOICHIOMETRY CALCULATIONS COACH COX. MOLE TO MOLE CONVERSIONS Converting from moles of one substance in a chemical reaction to moles of another substance

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Page 1: STOICHIOMETRY CALCULATIONS COACH COX. MOLE TO MOLE CONVERSIONS Converting from moles of one substance in a chemical reaction to moles of another substance

STOIC

HIOM

ETRY

CALCULA

TIONS

CO

AC

H C

OX

Page 2: STOICHIOMETRY CALCULATIONS COACH COX. MOLE TO MOLE CONVERSIONS Converting from moles of one substance in a chemical reaction to moles of another substance

MOLE TO MOLE CONVERSIONS

Converting from moles of one substance in a chemical reaction to moles of another substance in a chemical reaction

Page 3: STOICHIOMETRY CALCULATIONS COACH COX. MOLE TO MOLE CONVERSIONS Converting from moles of one substance in a chemical reaction to moles of another substance

MOLE TO MOLE: EXAMPLE 1

If you dropped 0.040 moles of potassium into a beaker of water, how many moles of hydrogen would you produce?

Step 1: Write a balanced chemical equation.

____K(s) + ____ H2O(l) ____ KOH(aq) + ____ H2(g)

Step 2: Start with your known, and use Dimensional Analysis with the correct mole ratio from the balanced equation to find the unknown

- Draw your pathway!

Page 4: STOICHIOMETRY CALCULATIONS COACH COX. MOLE TO MOLE CONVERSIONS Converting from moles of one substance in a chemical reaction to moles of another substance

MOLE TO MOLE: EXAMPLE 1 ANSWER

Balanced Equation: 2K(s) + 2 H2O(l) 2 KOH(aq) + 1 H2(g)

1 mol H2

Pathway: 0.040 mol K ------------------------------------> moles of H2

2 mol K

0.040 mol K x 1 mol H2 = .02 mol H2 produced

2 mol K

Page 5: STOICHIOMETRY CALCULATIONS COACH COX. MOLE TO MOLE CONVERSIONS Converting from moles of one substance in a chemical reaction to moles of another substance

MOLE TO MOLE: EXAMPLE 2

Using the same number of moles of potassium, how many moles of H2O will be used?

Balanced Equation: 2K(s) + 2 H2O(l) 2 KOH(aq) + 1 H2(g)

Work out the question the exact same way you did Example 1!

Page 6: STOICHIOMETRY CALCULATIONS COACH COX. MOLE TO MOLE CONVERSIONS Converting from moles of one substance in a chemical reaction to moles of another substance

MOLE TO MOLE: EXAMPLE 2 ANSWER

Balanced Equation: 2K(s) + 2 H2O(l) 2 KOH(aq) + 1 H2(g)

2 mol H2O

Pathway: 0.040 mol K ------------------------------------> moles of H2O

2 mol K

0.040 mol K x 2 mol H2O = .04 mol H2O will be used

2 mol K

Page 7: STOICHIOMETRY CALCULATIONS COACH COX. MOLE TO MOLE CONVERSIONS Converting from moles of one substance in a chemical reaction to moles of another substance

MOLE TO MOLE: EXAMPLE 3

One disadvantage of burning propane, C3H8, is that CO2 is produced as a product. The released CO2 increases the growing concentration of carbon dioxide in the atmosphere. How many moles of CO2 are produced when 10.45 moles of C3H8 is burned in a propane gas grill?

___ C3H8(g) + ___ O2(g) ___ CO2(g) + ___ H2O(l)

Work it out the same way, balance the equation first!

Page 8: STOICHIOMETRY CALCULATIONS COACH COX. MOLE TO MOLE CONVERSIONS Converting from moles of one substance in a chemical reaction to moles of another substance

MOLE TO MOLE: EXAMPLE 3 ANSWER

Balanced Equation: 1 C3H8(g) + 5 O2(g) 3 CO2(g) + 4 H2O(g)

3 mol CO2

Pathway: 10.45 mol C3H8 ------------------------------------> moles of CO2 1 mol C3H8

10.45 mol C3H8 x 3 mol CO2 = 31.35 mol CO2 will be produced

1 mol C3H8

Page 9: STOICHIOMETRY CALCULATIONS COACH COX. MOLE TO MOLE CONVERSIONS Converting from moles of one substance in a chemical reaction to moles of another substance

MOLE TO MOLE: EXAMPLE 4

The reaction between methane and, CH4, and sulfur produces carbon disulfide, CS2, a liquid used in the production of cellophane.

___CH4 + ___S8 ___CS2 + ___H2S

a. Balance the equation.

b. Calculate the moles of CS2 produced when 1.78 moles of S8 is consumed.

c. How many moles of H2S is produced during this same reaction?

Page 10: STOICHIOMETRY CALCULATIONS COACH COX. MOLE TO MOLE CONVERSIONS Converting from moles of one substance in a chemical reaction to moles of another substance

MOLE TO MOLE: EXAMPLE 4 ANSWER

a. Balanced Equation: 2 CH4 + 1 S8 2 CS2 + 4 H2S

b. 1.78 mol S8 x 2 mol CS2 = 3.56 mol CS2 will be produced

1 mol S8

c. 1.78 mol S8 x 4 mol H2S = 7.12 mol H2S will be produced

1 mol S8

Page 11: STOICHIOMETRY CALCULATIONS COACH COX. MOLE TO MOLE CONVERSIONS Converting from moles of one substance in a chemical reaction to moles of another substance

MOLE TO MASS CONVERSIONS

Converting from moles of one substance in a chemical reaction to mass of another substance in a chemical reaction

Page 12: STOICHIOMETRY CALCULATIONS COACH COX. MOLE TO MOLE CONVERSIONS Converting from moles of one substance in a chemical reaction to moles of another substance

MOLE TO MASS EXAMPLE 1

Determine the mass of NaCl produced when 1.25 moles of chlorine gas reacts with sodium

Step 1: Write a balanced equation

___ Cl2 + ___ Na ___ NaCl

Step 2: Start with your known, and use Dimensional Analysis with the correct mole ratio from the balanced equation to find the unknown

- Draw your pathway!

Page 13: STOICHIOMETRY CALCULATIONS COACH COX. MOLE TO MOLE CONVERSIONS Converting from moles of one substance in a chemical reaction to moles of another substance

MOLE TO MASS: EXAMPLE 1 ANSWER

Balanced Equation: 1 Cl2 + 2 Na 2 NaCl

Pathway: 1.25 mol Cl2 ------------------------------------------> grams NaCl produced

1.25 mol Cl2 x 2 mol NaCl x 58.443 g NaCl = 146.11 grams NaCl produced

1 mol Cl2 1 mol NaCl

Page 14: STOICHIOMETRY CALCULATIONS COACH COX. MOLE TO MOLE CONVERSIONS Converting from moles of one substance in a chemical reaction to moles of another substance

MOLE TO MASS EXAMPLE 2

Determine the mass of the sodium needed to complete this same reaction.

Balanced Equation: 1 Cl2 + 2 Na 2 NaCl

Work out the question the exact same way you did Example 1!

Page 15: STOICHIOMETRY CALCULATIONS COACH COX. MOLE TO MOLE CONVERSIONS Converting from moles of one substance in a chemical reaction to moles of another substance

MOLE TO MASS: EXAMPLE 2 ANSWER

Balanced Equation: 1 Cl2 + 2 Na 2 NaCl

Pathway: 1.25 mol Cl2 ------------------------------------------> grams Na needed

1.25 mol Cl2 x 2 mol Na x 22.990 g Na = 57.475 grams Na needed

1 mol Cl2 1 mol Na

Page 16: STOICHIOMETRY CALCULATIONS COACH COX. MOLE TO MOLE CONVERSIONS Converting from moles of one substance in a chemical reaction to moles of another substance

MASS TO MASS CONVERSIONS

Converting from the mass of one substance in a chemical reaction to the mass of another substance in a chemical reaction

Page 17: STOICHIOMETRY CALCULATIONS COACH COX. MOLE TO MOLE CONVERSIONS Converting from moles of one substance in a chemical reaction to moles of another substance

MASS TO MASS CONVERSIONS

EVERYTHING MUST GO THROUGH MOLES!!!

(MOLE TO MOLE conversions)

Page 18: STOICHIOMETRY CALCULATIONS COACH COX. MOLE TO MOLE CONVERSIONS Converting from moles of one substance in a chemical reaction to moles of another substance

MASS TO MASS EXAMPLE 1

Determine the mass of H2O produced from the decomposition of 25.0 g of ammonium nitrate (NH4NO3)

Step 1: Write a balanced equation

___ NH4NO3 ___ H2O + ___ N2O

Step 2: Start with your known, and use Dimensional Analysis to convert from:

a. mass of known to moles of known using the periodic table

b. moles of known to moles or unknown using the correct mole ratio moles to

mass of the unknown using the periodic table

- Draw your pathway!

Page 19: STOICHIOMETRY CALCULATIONS COACH COX. MOLE TO MOLE CONVERSIONS Converting from moles of one substance in a chemical reaction to moles of another substance

MASS TO MASS: EXAMPLE 1 ANSWER

Balanced Equation: 1 NH4NO3 2 H2O + 1 N2O

Pathway: 25 g NH4NO3 ---------------------------------------> grams H2O produced

25 g NH4NO3 x 1 mol NH4NO3 x 2 mol H2O x 18.015 g H2O = 97.829 g NH4NO3 1 mol NH4NO3 1 mol H2O

= 9.207 grams of H2O produced

Page 20: STOICHIOMETRY CALCULATIONS COACH COX. MOLE TO MOLE CONVERSIONS Converting from moles of one substance in a chemical reaction to moles of another substance

MASS TO MASS EXAMPLE 2

Calculate the number of grams of NH3 produced by the reaction of 5.4 g of hydrogen with an excess of nitrogen

___ N2(g) + ___ H2(g) ___ NH3(g)

Page 21: STOICHIOMETRY CALCULATIONS COACH COX. MOLE TO MOLE CONVERSIONS Converting from moles of one substance in a chemical reaction to moles of another substance

MASS TO MASS: EXAMPLE 2 ANSWER

Balanced Equation: 1 N2(g) + 3 H2(g) 2 NH3(g)

Pathway: 5.4 g H2 ---------------------------------------> grams NH3 produced

5.4 g H2 x 1 mol H2 x 2 mol NH3 x 17.031 g NH3 = 2.016 g H2 1 mol H2 1 mol NH3

= 91.2375 grams of NH3 produced

Page 22: STOICHIOMETRY CALCULATIONS COACH COX. MOLE TO MOLE CONVERSIONS Converting from moles of one substance in a chemical reaction to moles of another substance

PARTICLES TO PARTICLES CONVERSIONS

Converting from the particles of one substance in a chemical reaction to the particles of another substance in a chemical reaction

Page 23: STOICHIOMETRY CALCULATIONS COACH COX. MOLE TO MOLE CONVERSIONS Converting from moles of one substance in a chemical reaction to moles of another substance

PARTICLES TO PARTICLES CONVERSIONS

EVERYTHING MUST GO THROUGH MOLES!!!

(MOLE TO MOLE conversions)

Page 24: STOICHIOMETRY CALCULATIONS COACH COX. MOLE TO MOLE CONVERSIONS Converting from moles of one substance in a chemical reaction to moles of another substance

PARTICLES TO PARTICLES CONVERSIONS: EXAMPLE 1

Sodium hydrogen carbonate decomposes with heat to produce carbon dioxide gas, water, and solid sodium carbonate. 2.2 x 1023 formula units of sodium hydrogen carbonate react to form ________ molecules of carbon dioxide.

___ NaHCO3(s) ___ Na2CO3(s) + ___ CO2(g) + ___ H2O(g)

Page 25: STOICHIOMETRY CALCULATIONS COACH COX. MOLE TO MOLE CONVERSIONS Converting from moles of one substance in a chemical reaction to moles of another substance

PARTICLES TO PARTICLES CONVERSIONS: EXAMPLE 1ANSWER

Balanced Equation: 2 NaHCO3(s) 1 Na2CO3(s) + 1 CO2(g) + 1 H2O(g)

Pathway: 2.2 x 1023 fun NaHCO3 ---------------------------------------> molecules CO2

2.2 x 1023 fun NaHCO3 x 1 mol NaHCO3 x 1 mol CO2 x 6.02x1023 molecules CO2 = 6.02x1023 fun NaHCO3 2 mol NaHCO3 1 mol CO2

= 1.1 x 1023 molecules of CO2 produced