Upload
others
View
5
Download
0
Embed Size (px)
Citation preview
SPARKS
CH301
ELECTRON CONFIGURATION, TRENDS, and BONDING
UNIT 2 Day 6
Important Information
Assigned: - LM18 and HW 11 - Study these topics in fundamentals in eBook: Ionic and Covalent Bonding Nomenclature Know name/symbols for elements through #92 - Nomenclature quiz Monday. Non-graded LM that may be useful for study: - Laude LM Lectures 5, 6, 7 - NGM10 – covalent nomenclature - NGLM11 ionic nomenclature - NGLM07 Periodic Table Basics
INDIVIDUAL QUIZ: NO TALKING!
The trend on the periodic table is that atomic radii: a) Increases as you move from L to R across b) Decreases as you move from R to L across c) Increases as you move from T to B down d) Increases as you move from B to T up e) Both b and c
INDIVIDUAL QUIZ: NO TALKING!
The trend on the periodic table is that ionization energy increases as you move a) from L to R across and from T to B down. b) from R to L across and from T to B down. c) from L to R across and from B to T up. d) from R to L across and from B to T up. e) From L to R across and does not change as
you move from T to B.
What are we going to learn today?
−Electron Configuration, Trends, and Bonding
• Relate the valence shell electron configuration to
ionization energy
• Relate the valence shell electron configuration to
bonding
• Understand the similarities and differences between
ionic and covalent bonding
• Recognize and name compounds based on elemental
composition
IONIZATION ENERGY
7
0
500
1000
1500
2000
2500
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Atomic Number
Ionization
Energy
(kJ/mol)
H
He
Li
Be
B
C
N
O
F
Ne
Na
Mg
Al
Si P
S
Cl
Ar
K
Ca
Based on this trend in ionization energies this element is A. argon B. carbon C. magnesium D. sulfur
Trends provide useful information! Why can Sr be dangerous?
• What biologically important element would you expect it to be chemically similar to?
Where are the electrons in Ne? 1s22s22p6 very stable gas Z=10
Where are the electrons in Na? [Ne]3s1 not so stable metal Z=11
Where are the electrons in K? [Ar]4s1 not so stable metal Z=19 Easier or harder to ionize than Na?
ELECTRON LEAVES.. WHERE DOES IT GO?
Metals tend to give up electrons to nonmetals, in each case the valence is “satisfied” Sometimes is complicated… eg in the sodium in water demo Sometimes is more obvious… 2Na(s) + Cl2(g) 2NaCl(s) Sometimes they are already gone!
Formation of Ionic Compound – Downhill in Energy
IELi = 520 kJ/mol
Electron Affinity of fluorine
oE change when a gas phase atom gains an electron.
o= EAF = -328 kJ/mol
oNote that net energy change is still positive – less stable! Why does LiF form?
The structure of lithium fluoride
Ionic Compound… downhill in energy…..
Ionic Compounds…
Not a discrete pair of ions…it is a whole collection
Coulomb’s Law Lattice energy depends on Coulomb’s Law and the crystal structure (the way the ions are packed together). Assuming the same crystal structure, which do you think would have the larger lattice energy: a)NaF b)NaBr?
POLL: CLICKER QUESTION
Ionic Radius
What is your expectation of the lattice energy for MgO – large or small?
Which would have the larger lattice energy?
A. CaS
B. NaCl
POLL: CLICKER QUESTION
Polyatomic Ions
Calcium Carbonate Ca2+ CO3
2- Know the names and formulas for all the common polyatomic ions. See the Data & Tables under “more” on the eBook
Naming Ionic Compounds
Choose the formula that corresponds to: sodium oxide
a)NaO
b)NaO2
c)Na2O
d)Na2O2
POLL: CLICKER QUESTION
Naming Ionic Compounds
You need to be able to name common ionic compounds and with elemental ions and polyatomic ions. WEBSITE – FUNDAMENTALS – DO THE WORKSHEETS
What have we learned?
NUCLEAR CHARGE FELT BY VALENCE ELECTRONS IS SHIELDED BY THE CORE ELECTRONS ATOMS BEHAVE IN CERTAIN PREDICTABLE WAYS WHICH CAN BE CORRELATED TO THE ELECTRON CONFIGURATIONS IONIC BONDS TEND TO FORM BETWEEN METALS AND NONMETALS COVALENT BONDS TEND TO FORM BETWEEN NONMETALS AND NONMETALS NAMING COMPOUNDS IS IMPORTANT AND NECESSARY
Learning Outcomes
Identify metals and non-metals and predict types of compounds (ionic/covalent) Between different elements Relate coulombs law and lattice energy Name basic binary ionic compounds including polyatomic ions