Josiphos Rh/SL-J001; Rh/SL-J002; Rh/J006 [Rh(cod)(Lig)]OTf THF or MeOH/1-20 bar

Rh/SL-J001; Rh/SL-J002 [Rh(cod)(Lig)]OTf THF or DCM/5-90 bar

Rh/SL-J002; Rh/SL-J011[Rh(cod)(Lig)]BF4 * MeOH or TFE/2-50 bar

Rh/SL-J002 [Rh(cod)(Lig)]BF4 * MeOH/1-50 bar

Rh/SL-J001; Rh/SL-J006 [Rh(cod)(Lig)]OTf THF or MeOH/1-20 bar

Rh/SL-J002; Rh/SL-J007; Rh/SL-J505 [Rh(cod)(Lig)]BF4 * MeOH/1-20 bar

Rh/SL-J505; Rh/SL-J504 [Rh(cod)(Lig)]OTf THF or MeOH/1-20 bar

Rh/SL-J502 [Rh(cod)Cl]2/Lig Toluene/1-50 bar

Ir/SL-J001; Ni/SL-J001 [Rh(cod)(Lig)]BF4 * MeOH/5-80 bar

Ru/SL-J001; Os/SL-J001 [OsCl2(NNC)(Lig)] iPrOH/Base/5-80 bar

Ir/SL-J005; Rh/SL-J003; Rh/SL-J002; Rh/SL-J011 [Rh(cod)(Lig)]BF4 * or[Ir(cod)Cl]2/Lig/TABI/acid Toluene/20-80 bar

Ir/SL-J008; Ir/SL-J005 [Ir(cod)Cl]2/Lig/TABI/acid Toluene/20-80 bar

Rh/SL-J212; Rh/SL-J009; [Rh(cod)(SL-J226)]BF4; [Rh(cod)Cl]2/Lig or [Rh(cod)(Lig)]BF4 * MeOH/1-20 bar

Mandyphos Rh/SL-M004 [Rh(cod)(Lig)]BF4 * MeOH/5-50 bar

Rh/SL-M004 [Rh(cod)(Lig)]BF4 * MeOH/5-50 bar

Rh/SL-M001; Rh/SL-M004 [Rh(cod)(Lig)]BF4 * MeOH/5-60 bar

Walphos Rh/SL-W001; Rh/SL-W008 [Rh(cod)(Lig)]BF4 * MeOH/5-50 bar

Ir/SL-W008 [Ir(cod)(Lig)]Cl Toluene/5-60 bar

Rh/SL-W001; Rh/SL-W008 [Rh(cod)(Lig)]BF4 * MeOH/5-60 bar

Rh/SL-W003 [Rh(cod)(Lig)]BF4 * MeOH/5-60 bar

Ru/SL-W008 [RuX2(Lig)] (X=Cl, Br, I) MeOH/HCl/10-100 bar

Taniaphos Rh/SL-T001 [Rh(cod)(Lig)]BF4 *MeOH/5-50 bar

Rh/SL-T001 [Rh(cod)(Lig)]BF4 *MeOH/5-50 bar

Rh/SL-T001 [Rh(cod)(Lig)]BF4 * MeOH/5-50 bar

Rh/SL-T001 [Rh(cod)(Lig)]BF4 *MeOH/5-50 bar

Rh/SL-T001 [Rh(cod)(Lig)]BF4 * MeOH/5-50 bar

Ru/SL-T001 [RuX2(p-cymene)]/Lig (X=Cl, I) MeOH/5-80 bar

Ru/SL-T001 [RuX2(p-cymene)]/Lig (X=Cl, I) MeOH/5-80 bar

Ir/SL-T002 [Ir(cod)(Lig)]PF6/I2 toluene/5-50 bar

Rh/SL-T001 [Rh(cod)(Lig)]BF4 * MeOH/5-50 bar

MeObiphep Rh/SL-A101; Ru/SL-A101 [Rh(cod)(Lig)]BF4 *MeOH/5-50 bar [Ru(OAc)2(Lig)] MeOH/1-20 bar

Rh/SL-A101; Ru/SL-A101 [Rh(cod)(Lig)]BF4 *MeOH/5-50 bar [Ru(OAc)2(Lig)] MeOH/1-20 bar

Ru/SL-A101; Ir/SL-A101 [Ir(cod)(Lig)]PF6/I2 benzene/5-50 bar

Ru/SL-A101 [Ru(OAc)2(Lig)] MeOH/1-20 bar

Ru/SL-A101 [Ru(OAc)2(Lig)] MeOH/1-20 bar

Ru/SL-A101 [Ru(OAc)2(Lig)] MeOH/1-20 bar

Ru/SL-A101; Rh/SL-A116 [Rh(cod)(Lig)]BF4 *EtOAc/20-100 bar [Ru(OAc)2(Lig)] MeOH/1-20 bar

Rh/SL-A101 [Rh(cod)Cl]2/Lig Toluene/1-50 bar

Ru/SL-A101; Ru/SL-A109; Ru/SL-A120 [RuX2(Lig)] (X=Cl, Br, I) MeOH/HCl/10-100 bar

Ru/SL-A101; Ru/SL-A109; Ru/SL-A120 [RuX2(Lig)] (X=Cl, Br, I) MeOH/HCl/10-100 bar

Ir/SL-A101; Ru/SL-A101; Ru/SL-A109; Ru/SL-A120 [Ir(cod)(Lig)]BARF/I2 AcOH/AcONa/5-100 bar [Ru/SL-A120 RuX2(Lig)] (X=Cl, Br, I) MeOH/HCl/10-100 bar

Ru/SL-A101; Os/SL-A101; Ir/SL-A101 [RuCl2(Lig)(NN)] [OsCl2(Lig)(NN)] iPrOH/5-20 bar [Ir(cod)(Lig)]PF6/I2 benzene/5-50 bar

Ir/SL-A101 [Ir(cod)(Lig)]PF6/I2 benzene/5-50 bar

Ir/SL-A101 [Ir(cod)(Lig)]PF6/I2 toluene/5-50 bar

Trifer/Chenphos Rh/SL-F131; Rh/SL-F356 [Rh(cod)(Lig)]BF4 * MeOH/1-20 bar

Rh/SL-F131; Rh/SL-F356 [Rh(cod)(Lig)]BF4 * MeOH/1-20 bar

Rh/SL-F131; Rh/SL-F356 [Rh(cod)(Lig)]BF4 * MeOH or THF/1-20 bar

Butiphane Rh/SL-P005 [Rh(cod)(Lig)]BF4 * MeOH/1-5 bar

Rh/SL-P005 [Rh(cod)(Lig)]BF4 * MeOH/1-5 bar

Rh/SL-P005 [Rh(cod)(Lig)]BF4 * MeOH/1-5 bar

Rh/SL-P005 [Rh(cod)(Lig)]BF4 * MeOH/1-5 bar

Rh/SL-P005 [Rh(cod)(Lig)]BF4 * MeOH/1-5 bar

Rh/SL-P005 [Rh(cod)(Lig)]BF4 * THF/1-50 bar

POX Ru/SL-N003; Ru/SL-N004 [RuCl2(Lig)(PPh3)] Toluene/NaOH/5-50 bar

Ir/SL-N003; Ir/SL-N004 [Ir(cod)Cl]2/Lig/TABI/acid Toluene/20-80 bar [Ir(cod)(Lig)]BARF DCM/20-100 bar

Ir/SL-N003 [Ir(cod)(Lig)]BARF DCM/20-100 bar

Ir/SL-N003 [Ir(cod)(Lig)]BARF DCM/20-100 bar

Ubaphox SK-X002 [Ir(cod)(Lig)]BARF DCM/20-100 bar

YOUR Substrates ‒ OUR Solutions

SOLVIAS LIGANDSyour first choice for asymmetric hydrogenation

Solvias AGRömerpark 2

4303 KaiseraugstSwitzerland

Tel. +41 61 845 60 00 Fax +41 61 845 69 00

info@solvias.comwww.solvias.com

THE ESSENTIAL INGREDIENT ‒ Order nowWhile research quantities <5 g are available through our distribution partners (Strem and Sigma Aldrich), larger quantities including commercial quantities will be available directly from Solvias.

H PN

P HN

Fe HPN

OMe

MeO

H PN

OMe

MeO

Fe

SL-M001-1[210842-74-3]

SL-M001-2[223725-09-5]

SL-M004-1[494227-37-1]

SL-M004-2[849925-12-8]

C52H50FeN2P2 C64H74FeN2O4P2

Mandyphos

P

H CH3

P

CF3

CF3

F3CCF3

Fe

P

H CH3

P

Fe

P

H CH3

P

CF3

CF3

F3CCF3

Fe

SL-W001-1[387868-06-6]

SL-W001-2[849925-17-3]

SL-W003-1[388079-60-5]

SL-W003-2[849925-19-5]

SL-W008-1[494227-32-6]

SL-W008-2[849925-22-0]

C46H32F12FeP2 C42H48FeP2 C46H44F12FeP2

Walphos

PP

HCH3Fe

. C2H5OH

PP

HCH3Fe P

P

HCH3Fe

PP

HCH3Fe

P

CF3

F3C

F3CCF3

P

H CH3FeP

MeO

MeO

P

H CH3FePP

CF3

F3C

F3CCF3

H CH3Fe PP

HCH3Fe

P

F3C

F3C

P

HCH3Fe

P

PO

OH

CH3Fe PCH3

PHFe

P PH CH3

Fe

SL-J001-1[155806-35-2]

SL-J001-2[162291-02-3]

SL-J002-1[155830-69-6]

SL-J002-2[277306-29-3]

SL-J003-1[167416-28-6]

SL-J003-2[158923-07-0]

SL-J005-1[184095-69-0]

SL-J005-2[223121-07-1]

SL-J006-1[292638-88-1]

SL-J006-2[849923-15-5]

SL-J007-1[360048-63-1]

SL-J007-2[849923-88-2]

SL-J008-1[166172-63-0]

SL-J008-2[166172-66-3]

SL-J009-1[158923-11-6]

SL-J009-2[194020-16-1]

SL-J011-1[246231-79-8]

SL-J011-2[849924-37-4]

SK-J212-1[849924-41-0]

SK-J212-2[849924-42-1]

SL-J502-1[223120-71-6]

SL-J502-2[223121-01-5]

SL-J505-1[849924-76-1]

SL-J505-2[849924-77-2]

C36H44FeP2 . C2H5OH C32H40FeP2 C36H56FeP2 C40H40FeP2 C40H40F12FeP2 C42H56FeO2P2 C44H36F12FeP2 C32H52FeP2 C34H38F6FeP2 C28H36FeO2P2 C32H40FeP2 C34H44FeP2

Josiphos

HNP

P

FeHN

P

P

Fe

SL-T001-1[1003012-96-1]

SL-T001-2[850444-36-9]

SL-T002-1[1016985-24-2]

SL-T002-2[914089-00-2]

C43H39FeNP2 C43H63FeNP2

Taniaphos

MeOMeO

P

P

MeOMeO

P

P

MeOMeO

P

P

SL-A101-1[133545-16-1]

SL-A101-2[133545-17-2]

SL-A116-1[150971-45-2]

SL-A116-2[150971-43-0]

SL-A120-1[394248-45-4]

SL-A120-2[362634-22-8]

C38H32O2P2 C26H40O2P2 C46H48O2P2

MeObipheb

N

P

P

N

Fe

Fe

Fe N

P

P

Fe

Fe

SL-F131-1[899811-43-9]

SL-F131-2[900505-82-0]

SL-F356-1[952586-19-5]

SL-F356-2[1036373-39-3]

C50H54Fe3N2P2 C42H53Fe2NP2

Trifer/Chenphos

PS

P

Rh(COD)BF4 complexRh(cod)BF4 complex

SK-P005-1a[511543-00-3]

SK-P005-2a[849920-73-6]

C28H40BF4P2RhS

Butiphane

N

O PFe

(PPh3)RuCl2 complex(PPh3)RuCl2 complex

N

OP

Fe

SK-N003-1z[849921-25-1]

SK-N003-1z[212133-11-4]

SK-N004-1[1226898-27-6]

SK-N004-2[178557-28-3]

C46H43Cl2FeNOP2Ru C29H30FeNOP

POX

O

N O

P

Ir(COD)(BARF)Ir(cod)(BARF)

SK-X002-1a[880262-16-8]

SK-X002-2a[405235-55-4]

C77H58BF24IrNO2P

Ubaphox

COOR''

H, R

NHCOR' COOR'', P(O)(OR")2

R NHCOR''

COOR''

H,R NH2, R'

CO2RCO2R''

H,R

XR'COR''

H,R H,R'

H, R, CO2R

NHCOR"

R, H R'

H,R

CO2H

H,R

OHR'

H,R H,R R X

O OR

XO

OR

XO

R', H Ar R

O

R R'

NR

N

R

R'R

R'' H, R

*[Rh(cod)(Lig)]BF4 = prepared in situ from [Rh(cod)2]BF4 or isolated ML-complex