Soft Matter under Exogenic Impacts

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Series II: Mathematics, Physics and Chemistry – Vol. 242

edited by

and

Published in cooperation with NATO Public Diplomacy Division

Soft Matter under Exogenic Impacts

Sylwester J. Rzoska

Victor A. Mazur

Institute of Physics, Silesian University, Katowice, Poland

Odessa, Ukraine

Department of Biophysics and Molecular Physics,

State Academy of Refrigeration,Department of Thermodynamics, Institute of Energy and Ecology,

A C.I.P. Catalogue record for this book is available from the Library of Congress.

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Soft Matter under Exogenic Impacts: Fundamentals and Emerging TechnologiesProceedings of the NATO Advanced Research Workshop on

Odessa, Ukraine, 8--12 October 2005

ISBN 978-1-4020-5871-4 (PB)ISBN 978-1-4020-5870-7 (HB)ISBN 978-1-4020-5872-1 (e-book)

Part I: General Issues Asteroid impact in the black sea; a black scenario

The conductivity of hydrogen in extreme conditions

in the TIP5P model of water

Amorphization of ice by collapse under pressure,

Coupled ordering in soft matter: competition of mesoscales and dynamics of coupled fluctuations

All standard theories and models of glass transition appear to be inadequate: missing some essential physics

Part II: Glass forming liquids Positron annihilation lifetime spectroscopy

the disordered condensed systems characterization

V. T. Shvets, S. V. Savenko, J. K. Malynovski................................................... 9

1

P. Kumar, S. V. Buldyrev, H. E. Stanley...........................................................

vibrational properties, and ultraviscous water at 1 GPa

Segmental and chain dynamics in polymers

K. L. Ngai..........................................................................................................

S. Pawlus, M. Paluch, M. Mierzwa, S. Hensel-Bielowka,

23

M. A. Anisimov.................................................................................................. 75

91

and atomistic modeling – effective tools for

J. Bartoš, D. Ra ko, O.Šauša, J. Krištiak.........................................................113

R. Casalini, C. M. Roland................................................................................141

...........................................149

C. M. Roland, R. Casalini.................................................................................133

R. D. Schuiling, R. B. Cathcart, V. Badescu.....................................................

TABLE OF CONTENTS

G. P. Johari, O. Andersson............................................................................... 35

Isobaric and isochoric properties of glass-formers,

Dynamic crossover and liquid–liquid critical point

Influence of Differences in Molecular structure on Behavior of and Relaxation Processes in Diisooctyl Phthalate and Diisooctyl Maleate

E. Kami sha, K. Kami ski, S. J. Rzoska, S. Ma lanka ń ń

Orientationally disordered glassy phases

Part III: Liquid Crystals

the influence of molecular structure

mixture of liquid crystals

Annihilation of defects in liquid crystals

Part IV: Critical Liquids

environmentally significant organic chemicals mixtures

Properties of water near its critical point

Nonlinear dielectric spectroscopy near smectic A–smectic C*

Waves at the nematic–isotropic interface: nematic–non-nematic and polymer–nematic mixtures

Fluctuational equation of state and slopes of critical curves near the critical point of solvent

vi TABLE OF CONTENTS

J. Ll. Tamarit, S. Pawlus, A. Drozd-Rzoska, S. J. Rzoska.................................161

A. Drozd-Rzoska, S.J. Rzoska, M. Janik...........................................................189

M. Mierzwa, M. Paluch, S. J. Rzoska, J. Zio o, U. Maschke............................201

Glassy dynamics of rod-like liquid crystals:

M. Svetec, M. Ambroži , S. Kralj......................................................................239

V. Popa-Nita, T. J. Sluckin................................................................................253

S. V. Artemenko, V. A. Mazur.........................................................................269

V. Kulinskii, N. Malomuzh................................................................................287

V. Rogankov, O. Byutner..................................................................................305

Ordering effect on dynamics in glass-forming

Space – Preliminary Dielectric Relaxation Study

Global phase behavior of supercritical water –

A. Drozd-Rzoska, S. J. Rzoska, J. Zio o............................................................215 transition in ferroelectric liquid crystal DOBAMBC

Confined liquid crystaline 5CB in 2D Thermodynamic

S. Pawlus, J. Osinska, S. J. Rzoska, S. Kralj, G. Cordoyiannis........................229

Combined models of thermophysical properties along the coexistence curve

Intermolecular potential for simple liquids and gases

in the high pressure region

Homogeneous nucleation and growth from highly

How to generate and measure negative pressure in liquids?

in binary liquids under negative pressure

Critical properties of soft matter at restricted geometry as emerging problem: fundamentals and biological applications

Recent progresses in understanding of water interacting with biomolecules, and inside living cells and tissues

supersaturated vapor by molecular dynamics simulation

Part V: Bio-liquids and related problems

Water–biomolecule systems under extreme conditions: from confinement to pressure effects

Self-assembly of polypeptides. The effect of thermodynamic confinement

viiTABLE OF CONTENTS

V. Yu. Bardic, L. A. Bulavin, V. M. Sysoev,

Indirect methods to study liquid–liquid miscibility

A. V. Chalyi, L. A. Bulavin, K. A. Chalyy,

E. E. Ustjuzhanin, B. F. Reutov, V. F. Utenkov, V. A. Rykov...........................325

N. P. Malomuzh, K. S. Shakun..........................................................................339

N. Lümmen, B. Fischer, T. Kraska....................................................................351

A. R. Imre..........................................................................................................379

A. R. Imre, A. Drozd-Rzoska, S. J. Rzoska, T. Kraska. ..................................... 389

L. M. Chernenko, A. N. Vasil’ev, E. V. Zaitsev................................................ 399

M.-C. Bellissent-Funel......................................................................................413

R. C. Ford, J. Li................................................................................................433

G. Floudas, P. Papadopoulos...........................................................................447

Coulomb liquids under electric field – application of a new computer simulation method

viii TABLE OF CONTENTS

E. S. Yakub........................................................................................................457

A. Onuki............................................................................................................467 Solvation effects in near-critical polar fluids

Directors:

Sylwester J. Rzoska

Victor M. Mazur

Key speakers:

Gyan P. Johari

Christiane M. Alba-Simionesco

Marie-Claire-Bellisent

Thomas Kraska

Department of Biophysics and Molecular Physics,Institute of Physics, Silesian University, Katowice, Poland.

Department of Thermodynamics, Institute of Energy and Ecology,

Department of Materials Science and Engineering, McMaster University, Canada.

Lab. Chimie Physique, C.N.R.S, Université Paris-Sud Orsay, France.

Laboratoire Leon Brillouin, Gif-Dur-Yvette, France.

Institute for Physical Chemistry, University at Cologne, Köln, Germany.

Department of Physics, Univ. of Ioannina, Ioannina, and FORTH-BRI George Floudas

Attila R. Imre

Simone Capaccioli Istituto Nazionale per la Fisica della Materia and Dip. di. Fisica Univ. di Pisa,

Aleksandra Drozd-Rzoska

KFKI Atomic Energy Institute, Budapest, Hungary.

Italy.

Utrecht University, Utrecht, The Netherlands.

Institute of Physics, Silesian University, Katowice, Poland.

PARTICIPANTS

State Academy of Refrigeration, Odessa 65026, Ukraine.

Greece.

Roelof D. Schuiling

ix

A. Mickiewicz University, Department of Macromolecular Physics, Poznan,

Jerzy Zio o

Samo Kralj

Josep Lluís Tamarit

Jichen. C. Li

Mikhail A. Anisimov

Institute of Physics, Silesian University, Katowice, Poland.

Poland.

Institute of Physics, Silesian University, Katowice, Poland.

Univerza v Mariboru, Oddelek za fiziko, Maribor, Slovenia.

ETSEIB, Universitat Politècnica de Catalunya, , Barcelona, Catalunya, Spain.

Dept. Physics, Biomolecular Sci, Manchester University, Manchester, UK.

H. Eugene Stanley

C. Mike Roland

Park, USA.

Naval Research Laboratory, Washington, USA. Kia L. Ngai

Eugene Yakub

Leonid Bulavin

Nikolay Malomuzh

Naval Research Laboratory, Washington, USA.

Computer Science Dept., State Economic University, Odessa, Ukraine.

Taras Shevchenko Kiev National University, Ukraine.

Odessa National University, Odessa, Ukraine.

PARTICIPANTSx

Marian Paluch

Stefan Jurga

Center for Polymer Studies, Dept. Phys., Boston University, Boston, USA.

Dept. Chem. Engn. & Inst. for Phys. Sci. & Tech. Univ. of Maryland College

Kirill Schmulovich

Akira Onuki Department of Physics, Graduate School of Science, Kyoto University, Kyoto,

Other Participants:

George Cordoyiannis National Centre for Scientific Research “Demokritos”, Aghia Paraskevi,

Micha Mierzwa

Wies aw Su kowski

Sebastian Pawlus

Institute of Experimental Mineralogy, Chernogolovka, Russia.

Japan.

Greece.

Institute of Physics, Silesian University Katowice, Poland.

Institute of Chemistry, Silesian University, Katowice, Poland.

Institute of Physics, Silesian University, Katowice, Poland. Ma gorzata Janik Institute of Physics, Silesian University, Katowice, Poland.

Aleksandr V. Chalyi Physics Dept., National Medical University, Kiev, Ukraine.

S awomir Ma lanka

Milan Svetec Regional Dev. Agency and Fac. of Educ., University of Maribor, Maribor,

Josef Bartos

Ricardo Casalini

Institute of Chemistry, Silesian University, Katowice, Poland.

Slovenia.

Polymer Inst., Slovak Academy of Sciences, Bratislava, Slovakia.

Naval Res. Lab., Washington DC and George Mason University, Fairfax, USA.

PARTICIPANTS xi

Vlad Popa-Nita

Dmitry Yu. Ivanov

H. Schvets

Vladimir Kulinski

Sergey Artemenko

St. Petersburg State Uni. of Refrig. and Food Engn, Saint Petersburg, Russia.

Faculty of Physics, University of Bucharest, Romania.

Odessa Natl. University, Odessa, Ukraine.

Odessa Natl. University, Odessa, Ukraine.

Odessa Natl. University, Odessa, Ukraine.

Odessa Natl. University, Odessa, Ukraine.

PARTICIPANTSxii

Vitaly Rogankov

the Black Sea in the background.

Participants of the ARW NATO “Soft Matter under Exogenic Impacts: Fundamentals and Emerging Technologies” Odessa, Ukraine, 2005 at the terrace of Hotel “Morskoy”. Arrows indicate directors of the workshop. Note

Strong sensitivity even to moderate external impacts is a canonical feature of soft matter systems, the novel category covering critical liquids, polymers and

dynamics are their subsequent common features, which can be strongly influenced by external impacts. This book presents the hardly available so far comprehensive presentation of high pressures, negative pressures, random

systems. Exogenic means derived or originating externally. It is used in social

far. Using this term we would like to point out strong and comprehensive influence of various external factors on soft matter system. The most classical example of exogenic actions is an asteroid impact, the problem from the discussion presented in this volume begins.

The book was prepared to the cooperation of the prominent specialist focusing on soft matter and exogenic impacts, the direction which joins unusual experimental and theoretical difficulties with the promise of milestone results. It can serve as a guide in the novel and still puzzling research area. However, it also contains new results, appearing just in this volume. Identification of new types of physical behavior, new technological materials, ultimate verification of condensed and soft matter physics models, new applications in geophysics,

brainstorming discussion in superior conditions.

Sylwester J. Rzoska (Poland) Victor A. Mazur (Ukraine)

PREFACE

The dominance of mesoscale structures, rich phase structure, and complex

constraints, and strong electric field exogenic impacts on various soft matter

sciences, geology, biology, or medicine but hardly, if at all used in physics so

biophysics, biotechnology – all these are topics of this book.

The research activity of some of polish participants was possible dueto the Polish Committee for Sci. Res. (KBN, grant no 2PO3B 025 34, for years 2003–2003, grant. resp. S. J. Rzoska).

to the Science NATO Programme which support made it possible the Directors of the ARW NATO and all participants are very grateful

blends, liquid crystals, glass forming liquids, bioliquids and biopolymers, . . .

This book was prepared due to the Advanced Research Workshop NATO

a brainstorming discussion which took place in Hotel Morskoy, Odessa, Ukraine, 8–12 October 2005. r.

“Soft Matter under Exogenic Impacts: Fundamental and Emerging Technologies”,

xiii