Site Visit Report - Environmental Protection Agency · 3.49 200 19.03 7323 m³/hr 15.92 150532 m³/hr ... Site Visit Report - SV10520 - Masonite Ireland Page 10 of 66. Duct Characteristics

Site Visit Report

The site visit process is a sample on a particular day of an installation's compliance with some of its licence conditions. Where non-compliance against a particular condition has not been reported, this should not be construed to mean that there is full compliance with that condition of the licence.

Instructions and actions arising from the visit shall be addressed, or where applicable noted, by the licensee in order to ensure compliance, to improve the environmental performance of the installation and to provide clarification on certain issues.

The licensee shall take the actions specified to close out the non-compliances and observations raised in this Site Visit Report.

Licensee

Name of Installation Masonite Ireland

Licensee Masonite Ireland

Licence Register No. P0021-02

CRO Number 229654

Site Address Derryoughter, Drumsna, Carrick-on-Shannon, Leitrim

Site Visit Reference No. SV10520

Report Detail

Issue Date 25/07/2017

Prepared By David Matthews

Site Visit Detail

Date Of Inspection 31/05/2017 Announced No

Time In 09:30 Time Out 17:00

Visited by on behalf of the EPA Exova Catalyst Ireland

Licensee Personnel and Role See report.

Photo Taken No Samples Taken Yes Video Taken No

Odour Assessment No

Site Visit Report - SV10520 - Masonite Ireland Page 1 of 66

Scope

This is a report on monitoring of emissions to atmosphere at this site. Please find the detailed technical report attached.

Media

Air

Site Areas Inspected

See report.

Documents Inspected

See report.



ISO/IEC 17025 Accredited Legal Entity, UKAS Accredited Testing Laboratory No. 4279Exova (UK) Ltd trading as Exova Catalyst & Exova Catalyst Ireland

Unit C5, Emery Court, The Embankment Business Park, Stockport, SK4 3GL

Stack Emissions Testing Report Commissioned by

31st May - 1st June 2017

Job Reference Number

Installation Name & Address

Dates of the Monitoring Campaign

Stack Reference

Irish EPA IPPC Licence: P0021-02

(Prepared on behalf of the EPA by Exova Catalyst - EPA Contract No. OEE-DS-14)-

-

EMISSIONS REPORTEPA AIR EMISSIONS COMPLIANCE MONITORING

Exova Catalyst Ireland, Unit D8 North City Business Park, North Road, Finglas, Dublin 11T: +353 86 853 8247

E: [email protected] Exova Catalyst Ireland Contact: Nick Kenny (+353 86 853 8247)

County LeitrimDrumsna

Masonite Ireland

Ireland

EPA Office of Environmental Enforcement

S02B - First Stage Fibre Drier Line B

Job Reference NumberP0021-01-CAR-17-01

Team Leader

Deputy Regional Manager

TE1 TE2 TE3 TE4MM 08 922

MCERTS Level 2

Patrick O'BrienReport Approved by

John Glennon

24th July 2017Report Date

TE1 TE2 TE3 TE4

Version

MM 10 1074MCERTS Level 2

Signature of Report Approver

Version 2

Report Written by


TITLE PAGE

CONTENTS

Summary of Sampling Deviations

EXECUTIVE SUMMARY

Monitoring Objectives

Monitoring Results

Monitoring Dates & Times

Process Details

Monitoring & Analytical Methods

Sampling Location

Plant Photos / Sample Points

APPENDIX 1 - Monitoring Personnel & List of Equipment

APPENDIX 2 - Raw Data, Sampling Equations & Charts

7

CONTENTS

4

2

9

3

5

6

8

The testing performed fully meets the technical requirements in Irish EPA

Opinions and interpretations expressed herein are outside the scope of Exova Catalyst Ireland's ISO 17025 accreditation.

This test report shall not be reproduced, except in full, without the written approval of Exova Catalyst Ireland.

This version of the test report supersedes the previous version of the test report. Please destroy all previous versions to ensure no confusion arises from having multiple test reports in existence.

The testing performed fully meets the technical requirements in Irish EPA Guidance Note, AG2.

CAT-RT (Version BQ)Page 2 of 62

Masonite IrelandDrumsnaS02B - First Stage Fibre Drier Line B

Job Number: P0021-01-CAR-17-01, Version 2Sample Date/s: 31st May - 1st June 2017



Overall Aim of the Monitoring Campaign

Special Requirements

Target Parameters

Masonite Ireland, DrumsnaS02B - First Stage Fibre Drier Line B


(Page 1 of 7)

Exova Catalyst Ireland were commissioned by the EPA Office of Environmental Enforcement to carry out stack emissions testing at Masonite Ireland on the S02B - First Stage Fibre Drier Line B at Drumsna.

The aim of the monitoring campaign was to demonstrate compliance with a set of emission limit values (ELVs) as specified in the Site's Licence.

There were no special requirements.

Total Particulate Matter, Condensable VOCs, Dioxins & Furans, Formaldehyde, Total Aldehydes (as Carbon), Oxides of Nitrogen (as NO₂), Sulphur Dioxide, Carbon Monoxide

MONITORING OBJECTIVES

Executive Summary






where MU = Measurement Uncertainty associated with the Result

Parameter

Total Particulate Matter ¹

Condensable VOCs ¹ - -

Dioxins & Furans (NATO I-TEQ) - R1 Dioxins & Furans ¹

Formaldehyde ¹ - -Total Aldehydes (as Carbon) ¹ < <Oxides of Nitrogen (as NO₂) ¹ - -Sulphur Dioxide ¹ - -Carbon Monoxide ¹ - -Oxygen Wet Dry

Water Vapour Stack Gas TemperatureStack Gas Velocity

¹

- -NOTE: VOLUMETRIC FLOW RATE & VELOCITY DATA TAKEN FROM THE PRELIMINARY VELOCITY TRAVERSE.

¹ Reference Conditions (REF) are: 273K, 101.3kPa, without correction for water vapour content, 17% oxygen.

-

--

Volumetric Flow Rate (REF)

mg/m³

g/hr

12407

6942

% v/v16.4

158782

0.44

Volumetric Flow Rate (ACTUAL)

(Page 2 of 7)

3.36 100% v/v

°C

g/hr

3.49 200

19.03

7323m³/hr

15.92

150532m³/hr

2.000.38 0.09

MU

0.340.40 kg/hr

0.54

mg/m³

2.10

Dioxins & Furans Upper Limit (worst case where <LOD = LOD)

2.16 0.80

mg/m³3.32 100 2.81

-

1.95

Result Limit

17.7

µg/hr

6.70

Executive Summary

4.84 1.12

Mass Emission

201.48

MONITORING RESULTS

S02B - First Stage Fibre Drier Line BMasonite Ireland, Drumsna


kg/hr 0.2512.3+/-

Units Result

Concentration

0.0069

MU

0.0305

kg/hr

0.1

Limit+/-

Units

ng/m³0.06512

mg/m³

mg/m³ 67.140

mg/m³ 0.06 0.01520 kg/hr

Limit106700

g/hr

0.09

78.1

% v/v

10.0m/s

0.8757.3

3.13mg/m³ 192712.110654 740

783505

-






Parameter

R1 - -R1 - -

(NATO) R1 - -R1 - -R1 < <R1 - -R1 - -R1 - -R1 -R1

All results are expressed at the respective reference conditions.

31/05/2017 3014:30 - 15:00

30

31/05/2017

Oxygen30g/hr

14:30 - 15:0010654

14:30 - 15:00

mg/m³ g/hr

31/05/2017mg/m³ 78.130

14:30 - 15:00

67.1

31/05/201712407

g/hr 1927

31/05/2017kg/hrkg/hrFormaldehyde 0.34mg/m³

36031/05/2017

Sulphur Dioxide

3014:30 - 15:00Total Aldehydes (as Carbon) 0.38 0.060

10:45 - 11:38, 13:30 - 18:37

Carbon Monoxide15.55

Total Particulate Matter 12.3 32

DurationConcentration

01/06/2017

Sampling

1.95 09:45 - 10:17mg/m³

32

322.81kg/hrmg/m³

Units

(Page 3 of 7)

09:45 - 10:174.84

Oxides of Nitrogen (as NO₂)mg/m³

MONITORING DATE(S) & TIMES

mins

Masonite Ireland, Drumsna

Units

Velocity & Volumetric Flow Rate 31/05/2017% v/v

12.1mg/m³

10:10 - 10:30

09:45 - 10:17

Date(s)Mass Emission

kg/hr01/06/2017

2.16µg/hrDioxins & Furans ng/m³

01/06/20170.030517.7Condensable VOCs

S02B - First Stage Fibre Drier Line B31st May - 1st June 2017

Executive Summary

SamplingTimes






Standard Operating Conditions

Wood fibre and resin

Fuel

(Page 4 of 7)Executive Summary

PROCESS DETAILS

On

Continuous

Woodboard Production

Steam plume visible

Full Capacity

Parameter

Capacity (of 100%) and Tonnes / HourContinuous or Batch Process

Wood

Process Status

S02B - First Stage Fibre Drier Line B31st May - 1st June 2017

Abatement SystemAbatement System Running Status

Plume Appearance

Wet scrubber


Feedstock (if applicable)

Value






Pitot Tube and Thermocouple

SUMMARY OF SAMPLING DEVIATIONS

EN 16911-1 (MID) CAT-TP-41


CAT-TP-21

MONITORING & ANALYTICAL METHODS

SAL

Analysis

LOD(Average)

Yes

AnalyticalTechnique

CAT-TP-03


(Page 5 of 7)

Testing ISO

CAT-TP-23In House

Analysis17025

AnalysisLab

Total Particulate Matter EN 13284-1CAT-AP-05

Testing

CAT

0.048 mg/m³CAT

CAT-TP-01

CAT

ISOTechnical


Gravimetric

MCERTS17025

Testing

0.18 mg/m³

Executive Summary

Procedure

Yes

Yes

Standard

Yes 0.519 mg/m³Yes

Monitoring

CAT

ParameterProcedure

OX-IR

Analytical

CAT-AP-05

Condensable VOCs

Total Aldehydes (as Carbon) HPLC

Lab

Yes

CAT-TP-07

0.102 mg/m³Yes

GC-HRMSYesYes SAL 0.0008 ng/m³

YesCATCAT-TP-16 Yes

EN 1948CAT

YesDioxins & Furans CAT Yes

HPLCRPS

Formaldehyde US EPA M316SOP 1C

YesCEN/TS 13649 YesA40(U)

CAT-TP-19

Velocity & Vol. Flow Rate

GravimetricWater VapourYes

(with short name reference as appears in the table above)ANALYSIS LABORATORIES

Yes 1.2 m/s

NDIR by Horiba PG-250

ISO 17025 Accreditation Number: 4279ISO 17025 Accreditation Number: 1549

Oxides of Nitrogen (as NO₂)

0.49 mg/m³

Yes

Carbon Monoxide

CAT Yes

YesYes

Sulphur Dioxide

CAT

1 mg/m³

Oxygen

CAT-TP-05 0.1 % v/v

ISO 17025 Accreditation Number: 0605

CAT

Scientific Analysis Laboratories Ltd (SAL)RPS Laboratories Ltd (RPS)

Exova Catalyst (CAT)

CAT-TP-05 YesEN 14790

CATYes

YesEN 14789 CAT-TP-21 Yes 0.1 %

YesTGN M21 CAT-TP-21 YesChemiluminescence by Horiba PG-250

Yes

EN 14792 CAT

EN 15058

0.41 mg/m³CAT-TP-21

CATNDIR by Horiba PG-250

Dry Zirconia Cell by Horiba PG-250

CAT

1 Due to the restricted access, it was not possible to sample at all of the sample points on the available sampling lines.

Parameter RunTotal Particulate Matter, Dioxins & Furans

Deviation






Duct Characteristics Location of Sampling Platform

Platform Details

Sampling Location / Platform Improvement Recommendations

Value

Easy Access Available

Depth

4" BSP

Area 4.19

Orientation of Duct

Irish EPA Technical Guidance Note AG1 / EN 15259 Platform Requirements

Port Depth

m

Yes

YesYes

SUITABILITY OF SAMPLING LOCATION

Outside

Platform has vertical base boards (approx. 0.25m high)

Value

Sample Port Size

Circular

Value

Although this platform does not meet the requirements in EPA Guidance Note AG1 and EN 15259, it is adequate for the testing carried out on this stack.

-

m²m

Yes

33

No

General Platform Information

Permanent / Temporary PlatformInside / Outside

Yes

Platform has chains / self closing gates at top of ladders

Safe Access Available

Parameter

There are no obstructions present which hamper insertion of sampling equipment

No

-

(Page 6 of 7)

Units

Vertical

2.31Width

Platform has 2 levels of handrails (approx. 0.5m & 1.0m high)

Executive Summary

cm

-

Permanent-

Sufficient working area to manipulate probe and operate the measuring instruments

Type

EN 15259 Homogeneity Test Requirements

Sampling Plane Validation Criteria (from EN 15259)

-

Lowest Differential Pressure

--

10.120.00: 1 Yes

< 15°0.00

-

0.00

-

< 3 : 1Ratio of AboveHighest Gas Velocity

1.03°

-Yes

-

Traverse 1

m/s

Pa

---

There is no requirement to perform a EN 15259 Homogeneity Test on this Stack.

69.5

-

--

Criteria in EN 15259

-

Compliant-

-

Lowest Gas Velocitym/s

-

9.83-

-

Required

--9.98

-9 -

No Local Negative Flow

Mean Velocity-

-

- > 5 Pa Yes

-

Units

Yes

0.00-

-

-

-

--m/s

Maximum Angle of Swirl Yes

-

--






PLANT PHOTOS

Photo 1 Photo 2

Photo 3 Photo 4

Executive Summary(Page 7 of 7)

SAMPLE POINTS

where = isokinetic point sampled at

= isokinetic point not sampled at

= combustion gases sample point

= non-isokinetic sample point

Line A

Line B

A1

A4

A3

A2

A5

A8

A7

A6

B3B4 B2 B1

B8 B7 B6 B5






APPENDIX 1 - Stack Emissions Monitoring Personnel, List of Equipment & Methods and Technical Procedures Used

APPENDIX 2 - Summaries, Calculations, Raw Data and Charts

APPENDIX CONTENTS






Oven Box (2)1m Heated Line (1)

Name

Equipment I.D. Equipment I.D.

1m Heated Line (3)

Control Box DGM (1)

CAT 4.0015

-

CAT 14.65

Single Channel Heater Controller

CAT 3.73

Oven Box (1)

CAT 20.62Laboratory Balance CAT 1.18 / 1.18aTape Measure CAT 16.35

Digital Manometer (1)Horiba PG-250

CAT 23.26

-

S-Pitot (1)

L-Pitot-

Digital Temperature Meter

Heated Probe (3) -CAT 6.1

-

Instrumental Analysers

Barometer

Digital Manometer (2)

Umbilical (1)Box Thermocouples (2)Box Thermocouples (1)

CAT 11.59SELECT Logger 2 -

Dual Channel Heater Controller -500g / 1Kg Check Weights CAT 17.30Last Impinger Arm CAT 4.404Callipers

- 20m Heated Line (1)

Tubes Kit Thermocouple CAT 4.741

20m Heated Line (2)

-

Stack Thermocouple (1)

Gasmet Sampling SystemCAT 5.19

Extractive Sampling

LIST OF EQUIPMENT

5m Heated Line (1)CAT 12.66

-Stack Thermocouple (2)

Mass View (1) CAT 25.11

MCERTS Accreditation

-

JCT JCC P1 Cooler

CAT 13.27

Mass Flow Controller (1)

Stack Thermocouple (3)

Technical Endorsements

Team Leader

S-Pitot (2) CAT 21P.50

Equipment Type

Hioki 5043 (V)

-

Equipment Type

CAT 4.605

Equipment I.D.

STACK EMISSIONS MONITORING PERSONNEL

APPENDIX 1

15m Heated Line (1)

CAT 17.30

-

Technical ProcedureStandard

Heated Probe (1)

CAT 24.9-

CAT 12.53

CAT 3.103-

Mass View (2)

CAT 20.62

Site Balance

M&C PSS

CAT 4.491

-

Umbilical (2) Servomex 5200MP

Bernath 3006 FID CAT 8.16-

- 1m Heated Line (2)Heated Probe (2)

Equipment Type

Control Box DGM (2)

-

John Glennon MCERTS Level 2

Mass Flow Controller (2) CAT 6.21

Parameter

Technician Neil Kelly MCERTS Level 1 MM 16 1390 TE1

Miscellaneous Items

METHODS & TECHNICAL PROCEDURES USED

CAT 7.42

Eco Physics CLD 822Mh

MCERTS Number

-

CAT 3.103

SELECT FTIR

SELECT Horiba Model (2)

StopwatchServomex 4900

-

CAT 25.12

CAT 9.1

Position

CAT 3.73-

-

CAT 21P.59

MM 10 1075 TE1 TE2 TE3 TE4

ABB AO2020-URAS26

Bioaerosols Temperature Logger -Electronic Refrigerator -

Formaldehyde CAT-TP-19CAT-TP-07CAT-TP-23

CAT-TP-05

In House

EN 14792

Condensable VOCsCAT-TP-01

US EPA M316CEN/TS 13649

EN 13284-1

Technical ProcedureStandard

Dioxins & Furans

TGN M21Sulphur Dioxide

Water Vapour

Total Particulate Matter

Total Aldehydes (as Carbon)

CAT-TP-21CAT-TP-21

CAT-TP-21

EN 16911-1 (MID) CAT-TP-41Velocity & Vol. Flow Rate

EN 1948

Oxides of Nitrogen (as NO₂)

Carbon Monoxide

EN 14790

EN 14789EN 15058

CAT-TP-16

Oxygen

Parameter

CAT-TP-21






General Stack Details

Stack Gas Composition & Molecular Weights

CO₂ (Estimated)

O₂

Moisture (H₂O)

Where: p = M / 22.41

pi = r x p

Calculation of Stack Gas Densities

-1.2498

44.01

% v/v

Units

kg/m³ 1.205Wet Density (STP), P STW

-

0.8037

0.06

--

0.1903

Average Pitot Tube Calibration Coefficient, Cp

ppm kg/m³

Average Stack Gas Pressure

Conc Conc

MWet

r% v/v

16.3880.91

0.13163

19.03 32.00

ConcMass

Component

N₂1.4277 0.27173-

0.00118

18.02

Determinand

kg/m³

57.3

Average Barometric Pressure, Pb

m

0.8091 28.01

Result

1.96350.05

mStack Width, W

Stack Details (from Traverse)

APPENDIX 2

Stack Area, A

1.01121

1.284

67.66

Dry Density (STP), P STD

0.0006

kg/m³

0.1638

Units

Pa

Fraction Density

Dry

-

Volume

kPakPa

0.84

Value

2.31

101.8

Average Stack Gas Temperature, Ta

-0.079

°C

Average Stack Static Pressure, Pstatic

-

71.7

Molar Conc

4.19

15.92

p pi

m²

PRELIMINARY STACK SURVEY: CALCULATIONS

Stack Diameter / Depth, D

Where: P STD = sum of component concentrations, kg/m³ (not including water vapour)

P STW = sum of all wet concentrations / 100 x density, kg/m³ (including water vapour)

P Actual = P STD x (TSTP / (PSTP)) x ((Pstatic + Pb) / Ta)

P ActualW (at each sampling point) = P STW x (Ts / Ps) x (Pa / Ta)

Calculation of Stack Gas Volumetric Flowrate, Q

N/A

104468

-0.0

16.38

kg/m³ 1.205

Duct gas flow conditions

124928150532

1.066

Wet Density (STP), P STW

Gas Volumetric Flowrate REF ¹

%

Result

°C

15.9 17.0

m³/hr

REF ¹

Oxygen (Dry)

1.000

Dry Density (Actual), P Actual

m³/hr

%

Gas Volumetric Flowrate (STP, Dry)

Units

16.38

kg/m³

m³/hr

Total Pressure

Average Wet Density (Actual), P ActualW

Gas Volumetric Flowrate (Actual) m³/hr

Temperature

%

Units

Gas Volumetric Flowrate (STP, Wet)

MoisturekPa

Actual

19.0

kg/m³

101.357.3

101.7

158782

Gas Volumetric Flowrate (from Traverse)

Oxygen (Wet)






Parameter Parameter

Date of Survey Initial Pitot Leak CheckTime of Survey Final Pitot Leak CheckAtmospheric Pressure Orientation of DuctAverage Stack Static Pressure Pitot Tube, Cp

Result of Pitot Stagnation Test Number of Lines AvailableAre Water Droplets Present? Number of Lines UsedDevice Used

7.073.0

2.216 6.070.4

10.05

1.0009.83

57.0

57.7

VelocitySwirl

Yes

kPa

-

Wet Density

-

1.000

72.8

9.08.071.1

70.6 57.1

57.510.12

1.00171.71.97

4.09.981.000

71.69.92

9.900.10

9.97

1

1.00057.40.68

57.510.0670.9

557.157.1

9.069.510.04

5.0

57.6

73.8

Mean

0.34

57.4

57.1

45.0

72.07.0

1.000

-

69.9

73.89.89

21.001

1.63

Temp

--10:10 - 10:30

Sampling Line A

1.001

PRELIMINARY STACK SURVEY: VELOCITY TRAVERSE TO EN 16911-1 (MID)

Swirl

Vertical

Pass

10.12

1.001

m/sPa

0.999

m

1.001

57.2 1.001

8.0

kg/m³

5.0

°C°

72.6

m/s°C-77.6

Depth

-

Velocity

Units

APPENDIX 2

kg/m³

1.001

Point

57.2

Pa

8.03

57.5

9.999.94

9.86

Wet Density

Pa

STATIC (Units: Pa)

S-Type Pitot with KIMO MP 200 (500Pa)

101.8PassPass

∆P

-

(1 of 1)

2

Value

∆P TempSampling Line B

-81.2°

-

Traverse

2

31/05/2017

Value

-

Units

-79 0.84-

1.000

-

---

----------

-

-

--

-

---

-

-

-

-

- -

-----

- - -

-

-

-

- --

- -

-

-

--

-

-

-

-

-

--

-

--

-

- - --

-

- -

-

-

-

- --- --






Standard uncertainty associated with the volume flow rate (95% Confidence)

Pau(res) 0.00087

1.009

Standard uncertainty associated with the absolute pressure in the duct- Atmospheric Pressure

u(drift) 0.083

u(∆pi)u(k) 0.005

Uc,rel(v) 0.880.088

Performance characteristics (Uncertainty Components) UnitsValueUncertainty

m/s

u(patm) 175.692u(pstat) 1.002

u(ρ) 0.00539

Standard Uncertainty on the coefficient of the Pitot Tube

- Resolution- Calibration

u(M) 0.00009

0.105u(v) 0.045

Uc(v)

- Drift- Lack of Fit

- Water Vapour- Oxygen, wet- Carbon Dioxide, wet

-

Standard uncertainty associated with the mean velocity (95% Confidence)

- Overall corrections to dynamic measurementsStandard uncertainty associated with the molar mass of the gas- φO₂,w

0.00053-

Uc(qV,w)

- φCO₂,w- Oxygen, dry- Carbon Dioxide, dry

u(fit) 0.390

Standard Uncertainty associated with the mean local dynamic pressures-

Standard uncertainty associated with the mean velocity (95% Confidence), relative

u(vi)

Ku(pc) 175.695 Pa

Standard uncertainty associated with the mean velocity

0.00055- 12544789

%

- Static PressureStandard uncertainty associated with the density in the duct

u(φH₂O) 0.836u(φO₂,w) 0.513

-Pa

m/s

-

u(φCO₂,d) 0.002

Standard uncertainty associated with the stack temperature

Standard uncertainty associated with the local velocities

u(Cf)

u(cal) 0.535

APPENDIX 2

PRELIMINARY STACK SURVEY: VELOCITY TRAVERSE TO EN 16911-1 (MID) - MEASUREMENT UNCERTAINTY(1 of 1)

u(Tc) 1.685

1.417

6942.1 m³/hr

- u²(qV,w)- u²(qV,w)/q²V,w

-

15.916- 0.050

u(φO₂,d) 0.583

u(φCO₂,w) 0.002

- u²(a)/a²

- u(qV,w)Standard uncertainty associated with the volume flow rate (95% Confidence), relative %

- 12544789- 3541.9

Uc,rel(qV,w) 4.61

- u²(qV,w)






Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -

Blank Runs

- -

- -

Parameter

Uncertainty ±mg/m³ 1.48 1.48

Units

TOTAL PARTICULATE MATTER: RESULTS SUMMARY

Parameter Units

Uncertainty ±g/hr


Mean

16.76


% v/v

Concentration

12.27

Blank 1

Uncertainty

g/hr 1948.7

Mean

252.0

0.89 0.89

252.0

±% v/v

Parameter Units

Run 1

Water Vapour

Concentration

Mass Emission

0.19

16.76

APPENDIX 2

1948.7

mg/m³ 12.27

Run 1

Maximum

mg/m³ 0.19

General Sampling Information

FORMAT: Number Used / Number Required


Reference Conditions

Reference Conditions are: 273K, 101.3kPa, without correction for water vapour content, 17% oxygen.

Number of Sampling Lines Used

CAT-TP-01

Filter Size and MaterialOut Stack

Technical Procedure

Value

Positioning of Filter

2 / 2Number of Sampling Points Used 8 / 12

TitaniumFilter Housing Material Borosilicate GlassProbe Material

Standard

47mm Glass Fibre

Parameter

EN 13284-1

Sample Point I.D.'s A3, A4, A5, A6, B3, B4, B5 & B6






Absolute pressure of stack gas, Ps

Volume of water vapour collected, Vwstd

Volume of gas metered dry, Vmstd

Moisture content, Bwo & Rwv

Bwo as a percentageReported Water Vapour, checked with Tables in EN 14790, RwvVolume of gas metered wet, Vmstw

Volume of gas metered at Oxygen Reference Conditions, Vmstd@X%O₂ & Vmstw@X%O₂

Molecular weight of dry gas stream, Md

CO₂ (Estimated)

O₂

Volume of gas sample through gas meter, Vm m³Gas meter correction factor, Yd

% oxygen reference condition, REF%O₂ % v/v 17.00% dry oxygen measured in gas stream, ACT%O₂d

O₂ Reference Factor dry (O₂REFd) = (21 - REF%O₂) / (21 - ACT%O₂d)Vmstw@X%oxygen = (Vmstw) / (O₂REFw) m³ 0.7944

Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273)

-8.3

16.76

% v/v

APPENDIX 2

mmH₂O

-

% v/v

m³

% v/v

15.4

Barometric pressure, Pb

88.7

mmH₂O

0.1105

% wet oxygen measured in gas stream, ACT%O₂w

% v/v

0.6595

0.6320

% v/v

2.43

No

m³

0.5490

Vwstd = (0.001246)(Vlc)

Average dry gas meter temperature, Tm °C

% v/v

79.4g

0.2263Vmstd@X%oxygen = (Vmstd) / (O₂REFd)

19.35

-

Vmstw = (Vmstd)(100/(100 - Rwv))

Total mass of liquid collected, Vlc

Stack static pressure, Pstatic

g

TOTAL PARTICULATE MATTER: ISOKINETIC SAMPLING CALCULATIONS

Test Units

Total mass collected in impingers (liquid trap)9.3

O₂ Reference Factor wet (O₂REFw) = (21 - REF%O₂) / (21 - ACT%O₂w)

0.9100

16.76

Run 1

-

19.35

mmHg

762.9

763.5

m³

0.06

IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction)

Bwo = Vwstd / (Vmstd + Vwstd) 0.1676

16.18

0.83-

Ps = (Pb + (Pstatic / 13.6)

m³

m³

Average pressure drop across orifice, ∆H

Total mass collected in impingers (silica trap)

mmHg

g

39.3

O₂

Molecular weight of stack gas (wet), Ms

Total flow of stack gas: Actual (Qa), Wet (Qstw), Dry (Qstd), Wet@O₂REF (QstwO₂), Dry@O₂REF (QstdO₂)

Percent isokinetic, %I

√mmH₂O

Nozzle diameter, Dn

mm²

Total

2055.2Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273)

80.59

Nozzle area, An

2475.6QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd) m³/min 705.3

0.84

Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps)) 9.84

mm

% v/v

Pitot tube velocity constant, Kp

Average square root of velocity heads, √∆P

QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw)

%I = (4.6398E⁶)(Ts+273)(Vmstd) / (Ps)(Vs)(An)(q)(1 - (Rwv/100))

% v/v 19.41

Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)

Velocity of stack gas, Vs

Velocity pressure coefficient, Cp

7.002.65

39.12

m³/min

107.5

m/s

-m³/min

min 32

m³/min 1710.8

Ms = Md(1 - (Rwv/100)) + 18(Rwv/100)

Average stack gas temperature, Ts

%

Average of velocity heads, ∆Pavg mmH₂O

Total sampling time, q

4.19Qa = (60)(As)(Vs)

57.0

% v/v

19.35

Area of stack, As m²

7.06

°C

m³/min

Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)Conversion factor (K/mm.Hg), Cf

g/gmol 26.98

-

2475.0

-

g/gmol 28.78N₂

34.97

0.3592






Sample Runs

Filter I.D. Number

Probe Rinse I.D. Number

Where: ISO stands for Manual Isokinetic Sampling Train

Blank Runs

Filter I.D. Number

01/06/2017

g

g

0.00006

Volume Sampled (REF) m³

mg

01/06/2017

Units

APPENDIX 2

-

gg

End Filter Mass

g0.15851

Sampling Dates

0.15952

Average Volume Sampled (REF)

g

Parameter Units

Sampling Times

Blank 1

Run 1

3.11637Total Mass in Probe Rinse

09:45 - 10:17

0.00101-

Balance Uncertainty / LODCalculated Concentration

ISO

TOTAL PARTICULATE MATTER: SAMPLING DETAILS

47-41777

47-41774g

End Filter Mass

-

Parameter

Total Mass Collected

0.7944

0.7944

9.75

Start Filter Mass

-

Total Mass on Filter

mg/m³0.18

0.15918

Blank Dates -

mg/m³

-

0.15924Total Mass on Filter

End Probe Rinse Mass

-

g

g

m³

PR-47-41777

Start Filter Mass

12.27

3.10764

Sampling Device

0.00874

Start Probe Rinse Mass

Probe Rinse I.D. NumberStart Probe Rinse Mass

gPR-47-41774

mg/m³

0.00006

2.96724

Total Mass Collected0.00009

gEnd Probe Rinse Mass

mg/m³

g

g

Balance Uncertainty / LOD

mg 0.15

0.18Calculated Concentration

-Total Mass on Filter

0.19

2.96733Total Mass in Probe Rinse






Sample Runs

MU (Concurrent Water Vapour) Run 1Units

Pre-Sampling Leak Rate l/min

Overall Weighing Uncertainty

Run 1

0.21

5.3

Mean Sampling Rate l/min 17.97

Less than 50% Faded

20Yes

-

- Yes

Run 1

Water Droplets

%

%

107.5%

Isokineticity Acceptable

± mg

Units

Units

Measurement Uncertainty (MU)

Silica Gel (Concurrent Water Vapour) Units

Allowable Isokinetic Range %

Allowable MU

(PAGE 1 OF 2)

0.36

%

Units

%

Yes

Overall Weighing Uncertainty

Are Water Droplets Present

l/minLeak Test Acceptable

l/min 0.10

-

Units Run 1

TOTAL PARTICULATE MATTER: QUALITY ASSURANCE

0.32

Leak Test Results

ELV [Daily ELV for IED] mg/m³ 20.00

Allowable Leak Rate

Run 1

± mg/m³

MU Acceptable

95 - 115

0.25

No

Post-Sampling Leak Rate

Isokinetic Variation

Yes

Run 1

APPENDIX 2

Isokinetic Criterion Compliance

Weighing Uncertainty Criteria

Pre-Conditioning Temperature °C

°C

mg/m³ 1.00

Units Run 1

°CMaximum Filter Temperature

Run 1

Yes

120

Ambient Temperature Recorded? -

Filter Temperatures

-

Yes

Weighing Uncertainty Acceptable

ELV [Daily ELV for IED] mg/m³ 20.00

Post-Conditioning Temperature

Test Conditions Units

Allowable Weighing Uncertainty

180160






Blank Runs

Method Deviations

1

x

- - - - -

- - - - -

- - - - -

Blank Acceptable

Blank Acceptable

18.00

Blank

Nature of Deviation

mg/l 10

Allowable Leak Rate

(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)

2.7

Pre-Sampling Leak Rate

Yes

l/min

Acetone / Water Rinse Blank Units

Allowable Blank

Expected Sampling Rate

-

l/min

- Yes

Due to the restricted access, it was not possible to sample at all of the sample points on the available sampling lines.

2.0mg/m³

Validity of Blank vs ELV

Acetone / Water Rinse Value

0.12

(PAGE 2 OF 2)

Units

l/min

Units Blank 1

APPENDIX 2

TOTAL PARTICULATE MATTER: QUALITY ASSURANCE

Post-Sampling Leak Rate l/min 0.120.36

Blank 1

Leak Test Results

Allowable Blank

YesLeak Test Acceptable

mg/l

-

Run Number

- - - - -

- - - - -






Sampled Volume (Actual)Sampled Gas TemperatureSampled Gas PressureSampled Gas HumidityLeakMass of ParticulateUncollected Mass

Sampled Volume (Actual)Sampled Gas TemperatureSampled Gas PressureSampled Gas HumidityLeakMass of ParticulateUncollected Mass

Sampled Volume (STP)LeakMass of ParticulateUncollected Mass

≤1%% 1.00

0.14

≤1%

uTm

<5% of ELV

Run 1Symbol UnitsMeasured Quantities

% 0.56

Uncertainty in Measurement Units

mg

APPENDIX 2

TOTAL PARTICULATE MATTER: MEASUREMENT UNCERTAINTY CALCULATIONS

Measured Quantities

uUCM mg -

Units

Run 1 Units Run 1

0.5490m³

Tm

1.261.00

UCM 0.15

UCM

L

Vm

% v/v

uρm

≤1%

Lr mg

Uncertainty in Result

Vm

K 2.00.6320

2.00

% 0.88

22.35

-

Run 1 Requirement of Standard

0.09

≤2%

kPa

9.75

%

Uncertainty as a Percentage

-uL %

0.69%

Measured Quantities

uHm

0.5288.4

uVm m³

Measured Quantities Symbol

0.49

ρm 101.71.0

Run 1

Symbol

mg/m³

Run 1

≤2%

um

%

9.7501.26

m

mg

L 0.560.0Hm

0.039

Units

Sensitivity Coefficient

%

Value Standard uncertainty

0.0126

-

Sampled Volume (STP)LeakMass of ParticulateUncollected Mass

O₂ Correction FactorStack Gas O₂ ContentMU for O₂ Correction

Combined uncertainty

Expanded uncertainty (95% confidence), without Oxygen CorrectionExpanded uncertainty (95% confidence), with Oxygen CorrectionExpanded uncertainty (95% confidence), estimated with Method DeviationsReported Uncertainty


Measured Quantities

0.0394

0.39mg/m³

% 12.1

mg/m³

mg/m³

mg/m³

0.76

%

1.48mg/m³

0.1762

10.38

Parameter

%% 12.1

%

Units

0.09

mg/m³

0.1090

6.2

12.1

Run 1

1.48

mg/m³ 0.325

Run 1

% v/v 16.18-

1.48

Units

- 0.83

mg/m³

Units Run 1

Overall MU For O₂ Measurement

mg/m³

Oxygen Correction Part of MU BudgetMeasured Quantities






Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -

Blank Runs

- -

< <


Mean

542.6Uncertainty

Run 1

3.32


Water Vapour % v/v

Run 1

Uncertainty

16.76

mg/m³ 17.71

0.89

Parameter

2811.7

±% v/v

g/hr

Concentration mg/m³

Mass Emission

16.76

17.71

3.32

APPENDIX 2

0.40

Parameter

Concentration

Blank 1

Units


±mg/m³

MaximumUnits

0.40

Mean

Uncertainty

2811.7

0.89

Units

CONDENSABLE VOCS: RESULTS SUMMARY

Parameter

542.6±g/hr





CAT-AP-05

Date of Sample Analysis

2 / 2

Analytical Laboratory's Procedure

Value

Borosilicate Glass

Out Stack

SAL


Sample Point I.D.'s

Titanium

Parameter

Absorption Solution HPLC Grade Water

A3, A4, A5, A6, B3, B4, B5 & B6


Yes

Borosilicate Glass

Number of Sampling Points Used 8 / 12

Impinger MaterialFilter Housing Material

Name of Analytical Laboratory

Probe Material

47mm Glass FibreFilter Size and Material

16/06/2017ISO 17025 Accredited Analysis?

Technical Procedure CAT-TP-23In HouseStandard













CO₂ (Estimated)

O₂

Total mass collected in impingers (liquid trap)

% v/v 19.35

% v/v

0.1676

16.18No

m³ 0.2263

0.06

-

°C


% v/v

-

-

Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273)

9.3

Test Units

0.9100

% dry oxygen measured in gas stream, ACT%O₂d

Gas meter correction factor, Yd

-8.3Stack static pressure, Pstatic

% wet oxygen measured in gas stream, ACT%O₂w % v/v

m³

0.1105

mmHg

m³ 0.5490

79.4

39.3

763.5

APPENDIX 2

m³

Run 1

Vmstd@X%oxygen = (Vmstd) / (O₂REFd)

% oxygen reference condition, REF%O₂

2.43Vmstw@X%oxygen = (Vmstw) / (O₂REFw)

16.76


762.9

m³

mmH₂O

g

CONDENSABLE VOCS: ISOKINETIC SAMPLING CALCULATIONS

Barometric pressure, Pb

15.4

mmHg

% v/v 17.00

88.7

mmH₂O

m³

Average dry gas meter temperature, Tm

Ps = (Pb + (Pstatic / 13.6)


m³

Vwstd = (0.001246)(Vlc)

19.35

O₂ Reference Factor dry (O₂REFd) = (21 - REF%O₂) / (21 - ACT%O₂d)

% v/v

0.6320Volume of gas sample through gas meter, Vm

Bwo = Vwstd / (Vmstd + Vwstd)

0.7944-

g

% v/v


16.76

Total mass collected in impingers (silica trap) gTotal mass of liquid collected, Vlc

0.6595

0.83

O₂




mmH₂O

107.5

19.41

m³/min

m³/min

Average stack gas temperature, Ts

m²

0.3592

32

Velocity pressure coefficient, Cp 0.84

80.59

-7.00

Area of stack, As

705.3

-

QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw)


2055.2Conversion factor (K/mm.Hg), Cf

g/gmol

1710.8m³/min 2475.6

Total

Nozzle diameter, Dn

2.65

m³/min

Average of velocity heads, ∆Pavg

%

m/s°C

mm²

34.97

N₂Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂) g/gmol 28.78

Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273)

QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd)

19.35

minTotal sampling time, q

26.98

% v/v

√mmH₂O

Ms = Md(1 - (Rwv/100)) + 18(Rwv/100)

Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)

% v/v

-

% v/v

4.19

7.06mm

Qa = (60)(As)(Vs) m³/min


Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps))

Average square root of velocity heads, √∆P


2475.0

57.09.84

Nozzle area, An 39.12






Sample Runs

--------


Blank Runs

<-<<

319.0

-

CONDENSABLE VOCS: SAMPLING DETAILS

Sampling Times

Sampling Dates

17.71

µg

Mass in Front Impingers 10881.7

1.00

01/06/2017

Calculated Concentration

-

Blank 1

Volume in Back Impinger ml

319.0


µg

Laboratory Result for Front Impingers

Blank Dates


m³ 0.7944

µg

27.00

Mass in Back Impinger

ml

Units

µg3186.0

Volume in Front Impingers

Run 1

-

Volume in Impingers ml

ISO

Units


294.1

09:45 - 10:17

-

µg/ml

Parameter

Laboratory Result for Back Impinger

Parameter

37.00Volume Sampled (REF)Sampling Device

mg/m³

APPENDIX 2

m³

Calculated Concentration mg/m³ 0.40

0.7944

118.0

Laboratory Result for Impingers

01/06/2017

µg/ml

14067.7

µg/ml






Sample Runs

0 7 0 7

Run 1Absorption Efficiency Units

Units

Mean Sampling Rate l/min

APPENDIX 2

0.10l/min

Run 1

Run 1

Absorption Efficiency

Units

Yes

% 77.4

Leak Test Acceptable -

Allowable Isokinetic Range % 95 - 115

MU Acceptable

Allowable Absorption Efficiency

No

0.36

Isokinetic Criterion Compliance Units

%

l/min 0.21


Units

%

Run 1

Allowable MU

Run 1

CONDENSABLE VOCS: QUALITY ASSURANCE(PAGE 1 OF 2)

Leak Test Results Units


Isokinetic Variation

N/AAbsorption Efficiency Acceptable

Allowable Leak Rate

20

17.97

%

107.5

%

Less than 50% Faded

N/A

Post-Sampling Leak Rate l/min


Run 1

Silica Gel (Concurrent Water Vapour)

MU (Concurrent Water Vapour)

5.3

-

% Yes

-

% Yes

Water Droplets

120

-

Filter Temperatures


Yes

Units

Maximum Filter Temperature

-

Yes

Run 1

Run 1

°C

Units

Test Conditions

Ambient Temperature Recorded?






Blank Runs

Method Deviations

1

wx

- - - - -

- - - - -

- - - - -

- - - - -

- - - - -

UnitsLeak Test Results

l/min 0.12

l/min-

Run Number(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)

Leak Test Acceptable

Validity of Blank vs ELV

mg/m³

Allowable Leak Rate

Blank 1


There are no deviations associated with the sampling employed.

l/min

10.0Blank Acceptable - Yes

18.00

Nature of Deviation

Yes

CONDENSABLE VOCS: QUALITY ASSURANCE(PAGE 2 OF 2)

0.36

Units Blank 1

Allowable Blank

APPENDIX 2

Pre-Sampling Leak RatePost-Sampling Leak Rate l/min 0.12






Sampled Volume (Actual)Sampled Gas TemperatureSampled Gas PressureSampled Gas HumidityLeakLaboratory Result


Sampled Volume (STP)LeakLaboratory Result

Sampled Volume (STP)Leak

Hm

-

APPENDIX 2


Symbol Units

%

Symbol

CONDENSABLE VOCS: MEASUREMENT UNCERTAINTY CALCULATIONS

uVm

m³ 32.25

Run 1

≤1%%

1.0% v/v

Lr

No Requirement

Lr

Units


% 0.69

%

0.5490

1.00L

0.4693mg/m³

% 0.491.00

uHm

uρm

Run 1

0.0

Units

0.56

≤2%

0.0569

Measured Quantities Run 1

mg/m³

1.00


0.057

SymbolMeasured Quantities

0.0126

Run 1

%

%uLr

2.00

uL

≤1%

≤2%

Requirement of Standard

≤1%

mg/m³ 1.328

Tm

0.56

Units


L

0.6320

%

kPa

Vm

7.50

Measured Quantities

Value Standard uncertaintyRun 1

ρm 101.7

-7.50

288.4

Vm

uTm K 2.00.5

Measured Quantities

mg/m³

Run 1

m³

Laboratory Result





1.41

18.7

-

% 10.38

Run 1

3.323.32mg/m³

%

mg/m³

-% v/v 16.18

mg/m³ 3.32

% 18.7%

2.76mg/m³

15.6

Parameter Units

% 18.7

mg/m³ 1.328

mg/m³

0.09Overall MU For O₂ Measurement

Units Run 1Oxygen Correction Part of MU Budget

Measured Quantities

0.83






Sample Runs (UPPER NATO I-TEQ)

- -

- -

- -

- -

- -

Sample Runs (UPPER WHO TEQ Humans / Mammals)

- -

- -

- -

- -

- -

Sample Runs (UPPER WHO TEQ Fish)

TEQ1 - UPPER LIMITS (worst case where <LOD = LOD)

Uncertainty ±µg/hr 1.11540

Concentration

APPENDIX 2

ng/m³ 0.03048 0.03048

4.83909

1.11540

DIOXINS & FURANS: RESULTS SUMMARY


(PAGE 1 OF 4)

Uncertainty ±ng/m³ 0.00688


Parameter Units Run 1

0.00688

Mass Emission µg/hr

Mass Emission

1.11062

Concentration ng/m³ 0.03035

4.81834


0.03035

Uncertainty

Run 1 Mean

µg/hr 4.81834

4.83909

Parameter Units

0.00685

Mean

±ng/m³ 0.00685

Sample Runs (UPPER WHO TEQ Fish)

- -

- -

- -

- -

- -

Sample Runs (UPPER WHO TEQ Birds)

- -

- -

- -

- -

- -Uncertainty ±µg/hr

Concentration

Units Run 1

12.07666

0.03393

5.38761


Concentration ng/m³

1.24183

0.00766±ng/m³


Mass Emission

0.03393

Parameter

0.01718

µg/hr 5.38761

0.01718

ng/m³

Mean

Mass Emission µg/hr 12.07666

0.07606 0.07606

±ng/m³

0.00766

Mean

2.78364

Uncertainty

2.78364

Uncertainty






Sample Runs (LOWER NATO I-TEQ)

- -

- -

- -

- -

- -

Sample Runs (LOWER WHO TEQ Humans / Mammals)

- -

- -

- -

- -

- -

Sample Runs (LOWER WHO TEQ Fish)

4.83909

0.03035

0.00685

Mean

0.03035

Uncertainty 0.00685

(PAGE 2 OF 4)


TEQ2 - LOWER LIMITS (best case where <LOD = 0)

Uncertainty

Run 1

±ng/m³

UnitsParameter Run 1

0.00688

0.03048

Concentration

±µg/hr 1.11540

Mass Emission µg/hr

Uncertainty ±µg/hr

µg/hr

ng/m³

1.11540

APPENDIX 2

4.83909

4.81834

Mean

Parameter Units

±ng/m³

Uncertainty


0.00688

Mass Emission

1.11062 1.11062

4.81834


Sample Runs (LOWER WHO TEQ Fish)

- -

- -

- -

- -

- -

Sample Runs (LOWER WHO TEQ Birds)

- -

- -

- -

- -

- - 2.78364

5.38761µg/hr 5.38761


0.00766

0.03393

Uncertainty ±ng/m³

Uncertainty

0.00766

0.01718±ng/m³

12.07666


1.2

Mass Emission

0.01718

Units Run 1

Concentration ng/m³ 0.076060.07606

Mass Emission

0.03393

µg/hr 12.07666

Mean

Parameter

Concentration ng/m³

±µg/hr 1.2

Uncertainty

Mean






Blank Runs (UPPER NATO I-TEQ)

- -

- -

Blank Runs (UPPER WHO TEQ Humans / Mammals)

- -

- -

Blank Runs (UPPER WHO TEQ Fish)

- -

- -

Blank Runs (UPPER WHO TEQ Birds)

- -

- -


Maximum

TEQ1 - UPPER LIMITS (worst case where <LOD = LOD)

Parameter Units Blank 1

Units Blank 1

ng/m³


0.0011

APPENDIX 2


Maximum

Concentration

Blank 1

0.0018

DIOXINS & FURANS: RESULTS SUMMARY(PAGE 3 OF 4)

0.0013

0.0018

Parameter

Maximum

ng/m³

Units

0.0011

Maximum


ng/m³

Concentration

TEQ2 - LOWER LIMITS (best case where <LOD = 0)

0.0013

Parameter

Concentration

0.0011

Blank Runs (LOWER NATO I-TEQ)

- -

- -

Blank Runs (LOWER WHO TEQ Humans / Mammals)

- -

- -

Blank Runs (LOWER WHO TEQ Fish)

- -

- -

Blank Runs (LOWER WHO TEQ Birds)

- -

- -

ng/m³

Concentration

0.0000 0.0000

Maximum

Parameter

Blank 1

0.0000

Parameter Units


Maximum

0.0000

Maximum

Concentration

0.0000

Maximum

0.0000

Parameter Units

Blank 1

Concentration

Parameter

Blank 1

ng/m³ 0.0000

Units

Units Blank 1

ng/m³






- -

- -

- -



ISO 17025 Accredited Analysis?

18.16

EN 1948

1.09

Filter Housing Material Titanium

Standard


18.16


Absorption Material

Out Stack90mm Quartz Fibre

Number of Sampling Lines Used 2 / 2

Date of Sample Analysis

Filter Size and Material

10/07/2017



Analytical Laboratory's Procedure

Glassware Material

SOP 1C

Mean

Parameter Value

XAD-2Borosilicate Glass

Uncertainty ±% v/v 1.09

Yes

APPENDIX 2

Probe Material Titanium

Technical Procedure CAT-TP-07

Name of Analytical Laboratory SAL

Water Vapour % v/v

(PAGE 4 OF 4)






8 / 12

Sample Point I.D.'s A3, A4, A5, A6, B3, B4, B5 & B6

Number of Sampling Lines Used 2 / 2Number of Sampling Points Used













CO₂ (Estimated)

O₂

% v/v

Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273) m³

18.16

% wet oxygen measured in gas stream, ACT%O₂w

Vwstd = (0.001246)(Vlc) m³ 1.4338

m³ 0.1816

Units Run 1

6.4603

mmH₂O

Total mass collected in impingers (liquid trap)

m³ 7.7261

% v/v

-

mmH₂O

2.02

53.3

mmHg

g

O₂ Reference Factor dry (O₂REFd) = (21 - REF%O₂) / (21 - ACT%O₂d)

m³

% dry oxygen measured in gas stream, ACT%O₂d % v/v

°C

% v/v

26.6

15.75No

Gas meter correction factor, Yd - 0.9100

1097.4

Average dry gas meter temperature, Tm

Volume of gas sample through gas meter, Vm

Bwo = Vwstd / (Vmstd + Vwstd)

% oxygen reference condition, REF%O₂ % v/v 17.00-

Stack static pressure, Pstatic

APPENDIX 2

DIOXINS & FURANS: ISOKINETIC SAMPLING CALCULATIONS


m³ 3.1914

1150.7

Vmstw@X%oxygen = (Vmstw) / (O₂REFw) m³

% v/v 0.06


% v/v 18.16

10.3664

Total mass of liquid collected, Vlc

g

Vmstd@X%oxygen = (Vmstd) / (O₂REFd)

Test

0.76


-8.3Barometric pressure, Pb mmHg 763.5

762.9Ps = (Pb + (Pstatic / 13.6)

19.02

40.9

Total mass collected in impingers (silica trap)

-

g


7.8940

19.02O₂




2709.5


Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) m³/min

Nozzle diameter, Dn mm 7.06

Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273) m³/min 2063.3

Average stack gas temperature, Ts °C

834.1

% v/vTotal % v/v 19.08

% 113.9

Area of stack, As m²

mmH₂OAverage of velocity heads, ∆Pavg

- 34.97

2.65

N₂ % v/v

26.81

Velocity pressure coefficient, Cp -

1688.5

57.0Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps))

360

Ms = Md(1 - (Rwv/100)) + 18(Rwv/100) g/gmol

39.12

m³/min

9.88

√mmH₂O

Qa = (60)(As)(Vs)

QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw) m³/min

Total sampling time, q min

0.3592

Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂) g/gmol


80.92

2484.74.19

mm²

28.77

0.84

Average square root of velocity heads, √∆P7.01


Conversion factor (K/mm.Hg), Cf

QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd) m³/min

m/s

19.02

-

Nozzle area, An







2378-TCDD12378-PeCDD123478-HxCDD123678-HxCDD123789-HxCDD1234678-HPeCDDOCDDTotal Dioxins

2378-TCDF12378-PeCDF23478-PeCDF123478-HxCDF123678-HxCDF234678-HxCDF123789-HxCDF

0.0026

0.0061

0.1584

0.22000.00330.0660

TEQ1 TEQ2Parameter Units Result

0.0610

0.0100ngng

0.0034

0.00740.0003ng

ng0.1792

0.0110

0.0071

0.0001-

0.0570

% Rec

0.0130

0.1703 0.1703

0.0360

0.0110

DIOXINS & FURANS: SAMPLING DETAILS

0.0034

0.1584

-10.3664

NATOI-TEQ

WHO Humans / Mammals

WHOFish

WHOBirds

DL

31/05/2017

0.0180

0.22000.0033

ng

0.00710.0071

0.0100

ng

0.01100.0360

0.00310.0007

0.00260.0002

0.00550.1100

0.01000.0130

-9269

5655

APPENDIX 2

0.0000

0.00740.0003

0.1300

TEQ2TEQ2

0.0360

Volume Sampled (REF)ISO

0.1100

m³

Value

ng

0.0570

0.01000.0130

0.01100.0034

Units

-

TEQ1

Parameter

RUN 1

ng

ng

0.1100

0.03050.0007

0.0061

-

-

0.0100

0.2000

0.00070.0003

0.0130

0.00350.0058

0.36000.1100ng

9766

0.0340

0.0021

0.0074

0.1254

0.0074 0.0074

0.0100

0.09000.0305

0.0110

0.09000.0570

0.0036

0.0100

TEQ1 TEQ2 TEQ1

10:45 - 11:38, 13:30 - 18:37 Sampling Times

Sampling DatesSampling Device

0.0450

0.07400.2600

0.0000

0.01100.0034

0.1100

0.3600

0.2200

0.0110

0.00210.0021

0.03600.0055

ng

0.0055

0.0036 0.01300.0110

0.0130

0.0570

0.0061

0.0074

ng800.0025

0.00260.0030

0.09000.0061

0.0007

0.0026

590.0900

0.05700.09000.0900

0.0570

0.01300.01100.0034

0.0660

0.0180

0.00340.0034

0.04500.0570

0.0900

0.8130

0.0570

0.00070.0031

0.07100.00070.0003

0.0570

0.0110

0.0002

0.0130

0.1254

0.0034

7867

0.0000

0.00550.1100

0.0000

0.0071

-0.0036ngng

-0.3600

0.0100

0.00260.0001

0.0030

0.1792ng

94

0.0034

0.1000 0.0030

123789-HxCDF1234678-HPeCDF1234789-HPeCDFOCDFTotal Furans

TotalsTotal ConcentrationLimit of Detection

Where: ND stands for Non Detected

DL stands for Analytical Detection Limit

TEQ1 refers to Non Detected Congeners at the Detection Limit

TEQ2 refers to Non Detected Congeners at Zero

% Rec stands for the Recovery Percentage of the Sample

0.00020.0000

0.35170.0339

0.1400 0.00140.0002

0.63000.0000

ng

-

0.0305

0.02100.1905 0.1443

0.0000

0.00140.0002

ng/m³

0.0000

800.0050 0.00140.00140.0014

0.00000.1905

0.0012

0.0002

0.03030.31590.0305

0.3159 0.78850.0761

0.31460.0303

-ng

0.3146

0.0002

0.1443 0.17250.0000

0.0014 0.0014

0.00000.00020.0210

-- - - 0.0009

-

-

0.00140.00500.0063

0.35170.0339

0.00020.0000

0.63001.246063

0.0008

ngng

- -ng 2.0590 0.7885

0.0761ng/m³ -

-

- 0.0010-

-

0.0002

0.1725







2378-TCDD12378-PeCDD123478-HxCDD123678-HxCDD123789-HxCDD1234678-HPeCDDOCDDTotal Dioxins

2378-TCDF12378-PeCDF23478-PeCDF123478-HxCDF123678-HxCDF234678-HxCDF123789-HxCDF1234678-HPeCDF

0.0002

870.0000

87

0.0000

-

0.0001

0.0000

ng ND

0.0065

0.00000.0000 0.0001

0.0000 0.0002 0.0000 0.0000

ng

ng 0.0006 0.0000 0.0006

0.0000

0.0049 0.0000

0.000067

0.00480.0005

0.00060.0006

0.0033

ND0.0006

69ng

0.0000

910.0000

ND

0.0000 0.0033

0.0000

0.0000

0.0000

0.0000

0.0001

0.0000

0.0006

0.00000.0004

Parameter Units Result

0.0000ND

ng

0.00000.0000

0.0048

ng 0.0024

0.0000

ng

Units

TEQ2

Sampling Device -

-

-0.0000 0.0005

0.0006 0.0000

0.0025 0.0000

WHO Humans / Mammals

0.0024

10.3664

0.0005

ND 0.0042

0.0024 0.00000.0000

0.0000

ng

0.0004

0.0000

0.0004

TEQ2

0.0000

0.0000 0.0000ND 0.01400.0056 0.0000 0.0072

WHOBirds

0.00210.0033

ng 0.0005

m³

Value

0.0025

0.0043 0.00000.0004

0.0006 0.0000 0.0006ND

61

NATOI-TEQ

0.0015

0.0000

Sampling Dates - 31/05/2017


APPENDIX 2

DIOXINS & FURANS: SAMPLING DETAILS

0.0000

0.0005

0.0002

0.0001

ND

0.0006

TEQ1

ng ND 0.00430.0000

0.00000.0000

82

0.0000 68

280.0150

0.0000

0.0000 0.0024

0.00000.0005

ng

0.0060

0.0000

TEQ2 TEQ1

0.0000 0.0000

0.0000

ng72

0.0000ND

ng

0.0000

0.0000

ND

0.0024

0.0000

0.0033

0.00000.0000

0.0006 0.0000 0.0006

ND

0.0000

(Continued)

-

ND

0.00000.0049

0.0000

0.0000

0.0006 0.0000 0.0006

0.0002

ng

Parameter

0.0000 0.0079

0.0000

-

0.00020.0017 0.0000

96

78

0.0049

0.0060

0.0000

ND

0.0080 0.0001

0.0000ng ND 0.0060

0.0002

0.0000

BLANK 1

TEQ2 TEQ1

0.0000

0.0000ng 0.0060

% Rec

ISO

WHOFish

DL

0.0006 0.0000

0.0000 0.0006

0.0000

TEQ1

1234678-HPeCDF1234789-HPeCDFOCDFTotal Furans

TotalsTotal Concentration

Where: ND stands for Non Detected

DL stands for Analytical Detection Limit

TEQ1 refers to Non Detected Congeners at the Detection Limit

TEQ2 refers to Non Detected Congeners at Zero

% Rec stands for the Recovery Percentage of the Sample

0.0134

870.0000

-

0.00010.0080

0.0000ng/m³

0.0000

ng0.0000ng

0.0055 0.0000 0.0123 0.00000.0000

0.0000- - 0.0018

0.0001 0.0000 0.00010.0000 0.0000 0.0000ND

0.00000.0001

24

0.0011 0.0000 0.00000.0000 0.0187-

-ng

0.00010.0001

ngNDND

0.0000

0.0118 0.0000 -

0.0000

0.0113 0.0000

0.0200 0.00000.0000 0.00000.0000

0.0000

ng 0.0000 - 0.0057 0.0000 0.0046

0.00000.0080 0.0001-0.0000 0.0001

0.0011 0.00000.0013






Sample Runs

Allowable Leak Rate l/min 0.98

Leak Test Results


Less than 50% Faded

Maximum Filter Temperature

Filter Temperatures

- Yes

% Yes

Allowable MU

l/min19.53

Run 1

%

Run 1

113.9

Units

Water Droplets


(PAGE 1 OF 2)

Run 1

MU (Concurrent Water Vapour)

Units

Condenser Exit Temperature Units Run 1

Yes


APPENDIX 2

DIOXINS & FURANS: QUALITY ASSURANCE

Units Run 1

MU Acceptable %

0.39

Yes

6.020

l/min 0.45


Units Run 1

Units

Run 1

%

Allowable Isokinetic Range 95 - 115Isokinetic Variation

%

-


°C 120


%


-

No

l/min

Isokinetic Criterion Compliance

Units

Mean Sampling Rate

- No

Test Conditions

Exit Temperature Acceptable°C 20

Run 1

Maximum Temperature Recorded °C

-

Condenser Exit Temperature Units Run 1

20

YesAmbient Temperature Recorded?

Units

Maximum Allowable Temperature






Blank Runs

Method Deviations

1

wx

- - - - -

- - - - -

- - - - -

- - - - -

- - - - -

Blank Acceptable

Validity of NATO I-TEQ Blank vs ELV

Yes

-

Units Blank 1


Run Number(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)

l/min 1.00l/min 0.40

Yes

Expected Sampling Rate l/min 20.00Sampling Leak Rate

-

Blank 1

Due to the restricted access, it was not possible to sample at all of the sample points on the available sampling lines.

APPENDIX 2

(PAGE 2 OF 2)

Allowable Blank ng/m³

DIOXINS & FURANS: QUALITY ASSURANCE


Nature of Deviation

0.0100

Allowable Leak Rate









Sampled Volume (STP)Leak

≤2%

0.49

Lr

≤5%

uLr

Run 1

ng/m³ 0.0008


Measured Quantities

ρm

Vm


0.00

2.30

Lr 10.00

≤1%

≤1%

-

Hm

-


2.00

APPENDIX 2

DIOXINS & FURANS (NATO I-TEQ): MEASUREMENT UNCERTAINTY CALCULATIONS

Value

Measured Quantities


%

0.1545

101.7

0.0004

Units Run 1

uρm


10.00 No Requirement%

L

K7.7261

m³ 6.4603

uTm

1.00

ng/m³ 0.0004

%

Measured Quantities

ng/m³ 0.0030

L

%

kPa 0.5

uVm

SymbolStandard uncertainty

ng/m³

Run 1

2.0299.6

2.30

Units

1.00

%

Symbol Units

Units

≤1%

Vm

%

uHm

Run 1

1.00

0.67

Tm

%

Run 1

% v/v 1.0

m³


%

uL

Run 1

0.0

Laboratory Result






Run 1

Oxygen Correction Part of MU Budget

0.0069

22.6

ng/m³

0.0030ng/m³

ng/m³

ng/m³ 0.0032

Measured Quantities

ng/m³0.01

9.52

- 0.76% v/v 15.75

22.6

- 0.07

0.0069

UnitsParameter

%

Units Run 1

0.0062

20.5

22.6%

%

ng/m³

%

%






Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -

Blank Runs

- -

< <


Uncertainty ±mg/m³

Parameter Blank 1


FORMALDEHYDE: RESULTS SUMMARY

0.40

2.16

0.59

0.40

Parameter Units

2.16Concentration mg/m³

Parameter


g/hr

65.2

343.0 343.0

0.04 0.04

±% v/vUncertainty 0.59

Run 1

13.83Water Vapour % v/v

Mean

Units

Mass Emission

Units

13.83

±g/hr

Run 1


Mean

APPENDIX 2

Uncertainty

Maximum

65.2





Name of Analytical Laboratory CATAnalytical Laboratory's Procedure CAT-AP-05

Probe Material Stainless SteelFilter Housing Material Titanium

Value

HPLC Grade Water

Positioning of Filter Out Stack Heated HeadFilter Size and Material

Parameter

0.1μm Glass Fibre

Standard US EPA M316Technical Procedure

Number of Sampling Points Used

CAT-TP-19

Sample Point I.D.'s

1 / 12Number of Sampling Lines Used

B1

ISO 17025 Accredited Analysis?

Impinger Material PolyethyleneAbsorption Solution

1 / 2

YesDate of Sample Analysis 13/06/2017






Sample Runs

--------

Where: MFC stands for Mass Flow Controller, MV stands for Mass View Flowmeter

Blank Runs

g 1666.0

Volume Sampled (STP, Dry) m³ 0.3128

Volume Sampled (REF)

Mass in Front Impingers µg 839.0

0.82294.4128.6

Silica Trap Start Mass

Volume Sampled (STP, Wet)

Sampling Dates - 01/06/2017

µg/mlml

2.85Laboratory Result for Back ImpingerVolume in Front ImpingersVolume in Back Impinger

µg/mlSample Flow Rate

m³ 0.43730.3630

1150.0

ml

Laboratory Result for Front Impingers

Liquid Trap End Mass g 1185.3

mins 32

m³

Sampling Times - 09:45 - 10:17

APPENDIX 2

FORMALDEHYDE: SAMPLING DETAILS


Duration

l/min

Silica Trap End Mass g

Mass in Back Impinger µg

1671.0

105.5Total Mass Collected µg 944.5

9.77

Sampling Device - MFC / MV

Calculated Concentration mg/m³ 2.16

Liquid Trap Start Mass g

Total Mass Of Water Vapour g 40.3Calculated Water Vapour % v/v 13.83

<-<<Calculated Concentration mg/m³ 0.04

319.0

Blank Dates - 01/06/2017Average Volume Sampled (REF) m³ 0.4373

Total Mass Collected µg 16.0


Laboratory Result for Impingers µg/ml 0.05Volume in Impingers ml






Sample Runs

0 7 0 7

Blank Runs

Mean Sampling Rate

Yes

0.10

- No

l/min

Allowable Leak Rate l/min 0.20Leak Test Acceptable - Yes

l/min 0.109.77

Pre-Sampling Leak RatePost-Sampling Leak Rate l/min

Ambient Temperature Recorded? -

Test Conditions Units Run 1

Allowable Absorption Efficiency % N/AAbsorption Efficiency Acceptable - N/A

Water Droplets Units Run 1

Less than 50% Faded % Yes


MU Acceptable % Yes


Measurement Uncertainty (MU) % 4.2

Allowable MU % 20

MU (Concurrent Water Vapour) Units Run 1

Units Run 1

Absorption Efficiency Units Run 1

Absorption Efficiency % 88.8

APPENDIX 2

FORMALDEHYDE: QUALITY ASSURANCE

Leak Test Results Units Run 1

Blank Runs

Method Deviations

1

wx

- - - - -

- - - - -

- - - - -

Yes-

Blank 1

1.2

Post-Sampling Leak Rate l/min 0.10

Blank Acceptable

-

mg/m³

UnitsValidity of Blank vs ELV

YesAllowable Leak Rate

Nature of Deviation Run Number(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)


Allowable Blank

Pre-Sampling Leak Rate l/min 0.10


Expected Sampling Rate l/min 10.00

l/min 0.20

Leak Test Results Units Blank 1










O₂ Correction FactorStack Gas O₂ Content

Lr

0.3128


Vm 0.3128

mg/m³ 0.0128

Run 1

mg/m³


uLr

m³ 0.0063uL

% 1.02

mg/m³ 0.013

Uncertainty in ResultMeasured Quantities Units Run 1

0.162

mg/m³ 0.1620

Symbol Units Run 1

2.00

Measured Quantities Run 1

APPENDIX 2

- 0.83% v/v 16.18

Measured Quantities Units Run 1


1.00L 1.00


%

7.50%

Symbol

uVm

L 1.02% -

-

Run 1

Lr

Vm

No Requirement

Value Standard uncertaintyMeasured Quantities

Oxygen Correction Part of MU Budget

≤2%% 7.50

m³

≤2%

FORMALDEHYDE: MEASUREMENT UNCERTAINTY CALCULATIONS

Measured Quantities Symbol Units Run 1

mg/m³ 0.0432

6.90

Units

Stack Gas O₂ ContentMU for O₂ Correction




0.09

Run 1


-

% 18.5

Units

mg/m³ 0.40

% 18.518.5%

Parameter

0.17

% 15.3

% v/v 16.18

mg/m³ 0.40

mg/m³ 0.33

mg/m³ 0.40

mg/m³

% 10.38






Sample Runs (as Carbon)

- -

- -< << <- -< <- -- -< << <




Parameter

Sample Tube Type

Units Run 1

APPENDIX 2

Analytical Laboratory's Procedure A40(U)ISO 17025 Accredited Analysis? See Executive SummaryDate of Sample Analysis 14/06/2017

0.12

mg/m³

0.12

Name of Analytical Laboratory RPS


Hexanal

1 / 1

DNPH Coated Silica Gel

TOTAL ALDEHYDES (AS CARBON): RESULTS SUMMARY

Mean

mg/m³

Value

Yes


Technical Procedure CAT-TP-16Standard

Total mg/m³ 0.38 0.38

CEN/TS 13649

Parameter

0.02

0.02PropionaldehydeValeraldehyde

mg/m³mg/m³mg/m³

0.02mg/m³Acetaldehyde

0.01BenzaldehydeButyraldehyde

0.020.02

0.02

mg/m³mg/m³

0.020.01

0.01FormaldehydeHeptanal

0.16

Probe Material Stainless Steel

0.020.01

0.16

Dynamic Dilution Employed




Sample Point I.D.'s B3






Where: MV stands for Mass View (Mass Flow Controller Technology)

- - - - -< < - < << < - < <- < - - -< < - < <- < - - -- < - - -< < - < <

- < <



Duration

0.016 0.016 0.0160.0140.2

-

LOD (Total)

µg

Parameter

0.5

0.4 0.164 0.164 0.008 100.0Heptanal

MV

Volume Sampled (REF) m³ 0.0193

RUN 1

100.00.1

Parameter Units

0.2 0.4

: 1N₂ to Stack Gas Dilution Ratio

Sampling Times

0.2 0.116

0.013 100.00.2 0.2 0.4 0.014 0.014 0.014 100.0

100.0

0.2 0.4

LOD (Front)

µg

LOD (Back)

µg

0.006 90.2Benzaldehyde 0.2

Reported LOD

mg/m³

Adsorption Efficiency

%

0.016

0.014

31/05/2017

0.4

0.2 0.4

Sampling Device

0.116

0.2

0.014

Concentration (as Carbon) mg/m³

Reported Concentration

(Blank Reviewed) mg/m³

14:30 - 15:00

Propionaldehyde 0.3

mins

100.0Formaldehyde

0.44.1 0.1

-0.3783.0 0.378 0.102

0.2 0.2

0.2

0.1 7.9

30

APPENDIX 2

0.2 0.40.2 0.2 0.4 0.016

-

1.5

Butyraldehyde

0.022 0.022 0.015

14.7

3.7

7.8

TOTAL ALDEHYDES (AS CARBON): SAMPLING DETAILS

Value

Sampling Dates-

0.2 0.2 0.4 0.20.2

0.20.2

Lab Result (Front)

µg

0.4

0.4 0.015 0.015 0.015 100.0

Total

0.20.2

Lab Result (Back)

µg

Lab Result (Total)

µg

Valeraldehyde

Acetaldehyde

Hexanal 0.4 0.2 0.6 0.2






Where: MV stands for Mass View (Mass Flow Controller Technology)

< < - << < - << < - << < - << < - << < - << < - << < - <



0.4 0.016Butyraldehyde

Lab Result (Total)

µg

Concentration (as Carbon) mg/m³

0.1 0.2

Propionaldehyde

0.2

0.006Benzaldehyde 0.2 0.2

0.2

0.1

APPENDIX 2

Acetaldehyde

Formaldehyde 0.20.4

01/06/2017

TOTAL ALDEHYDES (AS CARBON): SAMPLING DETAILS

BLANK 1

Parameter Units

Sampling Dates -

Value

Sampling Device - MVAverage Volume Sampled (REF) m³ 0.0193

Parameter Lab Result (Front)

µg

Lab Result (Back)

µg

0.0150.2 0.2 0.4

0.2 0.4 0.014

0.0150.4 0.008

Heptanal 0.2 0.2Hexanal 0.2 0.2 0.4

0.013Valeraldehyde 0.2 0.2 0.4 0.014






Sample Runs

Temperature at Sample Tubes Units

Yes

90.2

Temperature40Allowable Temperature

Run 1

Yes

Temperature Acceptable -

-Ambient Temperature Recorded?

Units

°C

Adsorption Efficiency Acceptable

Run 1

NoAllowable Adsorption Efficiency

Test Conditions

(PAGE 1 OF 2)

%

Acetaldehyde %

-Leak Test Acceptable

100.0

Formaldehyde

TOTAL ALDEHYDES (AS CARBON): QUALITY ASSURANCE


Propionaldehyde

HeptanalHexanal

Yes

100.0

Adsorption Efficiency Units

100.0

l/min

Run 1

% 100.0

%

Valeraldehyde

APPENDIX 2

%

1.000l/min

0.050

%

Run 1

%


100.0

l/min

0.010

100.0Butyraldehyde

100.0


%

0.010

Benzaldehyde

l/min

95

Mean Sampling Rate

°C 11

%-

Allowable Leak Rate






Blank Runs

Method Deviations

1

x

- - - - -

- - - - -

- - - - -

0.008


mg/m³mg/m³

Run Number

N/A

Nature of Deviation

N/A

0.013 N/A

0.050

Allowable for FormaldehydeAllowable for HeptanalAllowable for Hexanal

Allowable for Acetaldehyde


mg/m³mg/m³

0.000

(PAGE 2 OF 2)

Blank 1

- Yes

APPENDIX 2

TOTAL ALDEHYDES (AS CARBON): QUALITY ASSURANCE

(x = deviation applies to the associated run)

0.014 N/A

0.016mg/m³mg/m³mg/m³mg/m³

Leak Test Results

Sampling Leak Rate

Allowed

l/min

Units

Allowable for TOTAL

0.014

l/min 1.000

mg/m³

0.015 N/A

l/min

Allowable for Propionaldehyde

N/A


Allowable for Valeraldehyde0.1

Allowable for Benzaldehyde0.006

N/A

Blank 1

2.0

Validity of Blank vs ELV Units

Allowable Leak Rate

Allowable for Butyraldehyde

0.015

N/A










O₂ Correction FactorStack Gas O₂ Content


Lr

Vm

0.0123

Units

0.0123

% 12.13

0.002

Measured Quantities

1.00

%

%


- 0.76

No Requirement

uL


-Lr

Oxygen Correction Part of MU BudgetMeasured Quantities Units Run 1

Units


Standard uncertainty

m³

APPENDIX 2


%

Vm uVm

Symbol Units Run 1

TOTAL ALDEHYDES (AS CARBON): MEASUREMENT UNCERTAINTY CALCULATIONS

Value

mg/m³

mg/m³

mg/m³

Run 1

Symbol Units

% v/v 15.76

mg/m³ 0.0022

≤2%

-1.000

0.0458

0.046

2.00

Run 1

≤5%

Run 1

Measured Quantities

1.00

L0.00025

1.00

Run 1

L mg/m³

Run 1

%

Measured Quantities

30.71

12.13 uLr

0.0076


m³

Stack Gas O₂ ContentMU for O₂ Correction



Expanded uncertainty (95% confidence), without Oxygen CorrectionExpanded uncertainty (95% confidence), with Oxygen CorrectionExpanded uncertainty (95% confidence), estimated with Method DeviationsReported UncertaintyNOTE: Uncertainties reported in mg/m ³ are based upon the summation of all Speciated VOCs Measured.

0.091

%

mg/m³ 0.09

Run 1

%

0.091mg/m³

%% 24.1

mg/m³

mg/m³ 0.091

24.1

9.53- 0.07

Overall MU For O₂ Measurement %

Parameter Units

% v/v 15.76

24.1

mg/m³ 0.047

24.1






Sample Runs

- -

- -

- -

- -

- -


NOTE: Dilution performed to achieve correct span value

30/06/2016 - 97.1%Date & Result of Last Converter Check

3.49

StandardTechnical Procedure

Heated Line Temperature

Mass Emission

2

Span Gas Reference Number CYL 4.0160Span Gas Expiry Date


Span Gas Start Pressure (bar) 100Gas Cylinder Concentration (ppm)

740.5

3.49

740.5±g/hr

67.10


180°C

Parameter

10653.8

Filtration Type / Size

CAT-TP-21

g/hr 10653.8

04/12/2019

OXIDES OF NITROGEN (as NO₂): RESULTS SUMMARY

Value


408.41

Yes


Parameter Units Mean

Span Gas Uncertainty (%)

Run 1

EN 14792

0.1µm Glass Fibre

Uncertainty

Heated Head Filter Used

Span Gas Type Nitrogen Monoxide

APPENDIX 2

67.10

Uncertainty ±mg/m³





2

A1

Zero Gas Type Nitrogen (5 Grade)

1 / 1Number of Sampling Lines Used 1 / 1Number of Sampling Points Used

Span Gas Uncertainty (%)

Sample Point I.D.'s






Graphical Trend of Data

APPENDIX 2

OXIDES OF NITROGEN (as NO₂): DATA TREND

COVER ME WITH CHART/S

0.0

10.0

20.0

30.0

40.0

50.0

60.0

70.0

80.0

90.0

14:3

0

14:3

1

14:3

2

14:3

3

14:3

4

14:3

5

14:3

6

14:3

7

14:3

8

14:3

9

14:4

0

14:4

1

14:4

2

14:4

3

14:4

4

14:4

5

14:4

6

14:4

7

14:4

8

14:4

9

14:5

0

14:5

1

14:5

2

14:5

3

14:5

4

14:5

5

14:5

6

14:5

7

14:5

8

14:5

9

15:0

0

Conc

entr

atio

n (m

g/m

³)

Oxides of Nitrogen (as NO₂) At Reference Conditions

- Run 1






Sampling Details

Quality Assurance

Zero Drift 0 0 0

Zero Drift 0 0 0

Zero Drift 0 0 0

Span Drift 0 0 0

Zero Drift Acceptable

ppm

Conditioning Unit Temperature

Run 1

Zero Down Sampling Line (Post) ppm

Zero Down Sampling Line (Post)

Yes

Units

Zero Down Sampling Line (Pre)

Run 1

ppm

31/05/2017

ppm

Units

CAL

3

Span Drift

Zero Drift


Sampling Dates

Temperature Acceptable

ppm 0.80

250

-

Allowable Temperature

0.00

4.0

± ppm 4.01

< °C- Yes

-

Average Temperature °C 1.5

Sampling Times - 14:30 - 15:00

Instrument Range

Zero Down Sampling Line (Pre) ppm

APPENDIX 2

OXIDES OF NITROGEN (as NO₂): SAMPLING DETAILS & QUALITY ASSURANCE

Parameter

80.1

CAL

1

Run 1

Zero Down Sampling Line (Post) ppm 0.80

CAL

1CA

L 2

ppm

Allowable Zero Drift

ppm

Units

Span Down Sampling Line (Post) ppm 80.70ppm -0.80

Span Gas Value ppm

Span Down Sampling Line (Pre) ppm 81.50

Run 1

ppm

Units

Span Drift 0 0 0

Span Drift 0 0 0

Span Drift 0 0 0

Method Deviations

1

x

- - -

- - -

- - -

Run Number

± ppm

Span Down Sampling Line (Pre)

4.01Span Drift Acceptable - Yes

Nature of Deviation

Allowable Span Drift

Run Ambient Temperature Range

CAL

3

ppm

ppm

Units Run 1



14

CAL

2

Span Down Sampling Line (Post)

ppm -0.80

ppmSpan Down Sampling Line (Post)

ppm

Span Down Sampling Line (Pre) ppm

Test Conditions

°C

ppm






APPENDIX 2

Units

Uncertainty of calibration gas blending 1.40

0.07

Cal gas conc. 164.4

Performance characteristics RUN 1

mg/m³

mg/m³Lack of fit

% of valueZero drift 0.98

% full scaleVolume or pressure flow dependence 0.40

Uncertainty of calibration gas 2.00

use rep at span

0.40

Repeatability at span level 0.40

Performance characteristic RUN 1 UnitsStandard deviation of repeatability at zero mg/m³Standard deviation of repeatability at span level

Dependence on voltage

0.00

% full scaleDeviation from linearity 0.21

Combined interference% full scale/10V

97.1 %

mg/m³

% range

0.15 mg/m³Drift 0.66

Losses in the line (leak)

% full scale

Atmospheric pressure dependence 0.30 % of value/kPaAmbient temperature dependence 0.18 % full scale/10K

Span drift -0.98% of full scale

UnitsResponse time 60

mg/m³ (REF)10.0

200.0

mg/m³

OXIDES OF NITROGEN (as NO₂): MEASUREMENT UNCERTAINTY CALCULATIONS

mg/m³ (STP, dry)5 %

125.0

ppmRange Used [A] 513.1

seconds

250.0mg/m³

48.18

Range UsedRation NO / NO₂Measured concentrationTGN M2 Allowable MULimit value

%

Converter efficiency

Number of readings in measurement 30 -Repeatability at zero 0.40 % full scale

% of value% of value

0.00

mg/m³

Volume or pressure flow dependence

Cal gas conc. 80.1 ppmConversion 2.05 ppm to mg/m³MCERTS Range [B] 125.0

0.60

mg/m³

% of value


Lower of [A] or [B]

k =

% at ELV

Overall Allowable uncertainty (with O₂) - at 95% Confidence 10.3 % at ELV

RUN 1

Requirement for SRM is that Uncertainty should be <10% of the value at the ELV, on a dry gas basis, or if O ₂ correction is applied less than 10% + the uncertainty associated with the O₂ correction (using sqrt of sum squares to add uncertainty components). Ref EA TGN M2.

mg/m³Atmospheric pressure dependence 0.11 mg/m³Ambient temperature dependence

mg/m³Converter efficiencyLosses in the line (leak) 0.00

COMPLIANT -

0.03 mg/m³Combined interference (from MCERTS Certificate) 0.43

2.25

Uncertainty of calibration gas

Units% of Value

Expanded uncertainty (no O₂) - at 95% Confidence 1.12 % at ELV

Overall Allowable uncertainty (no O₂) - at 95% Confidence 10.0

0.00

UnitsMeasurement uncertainty Result 48.18

mg/m³Expanded uncertainty 1.96

Uncertainty of calibration gas blending 0.39

mg/m³Combined uncertainty 1.15

2.96

Result of Compliance with Uncertainty Requirement in M2

% of Value

Expanded uncertainty (with O₂) - at 95% Confidence

mg/m³

UnitsExpanded uncertainty (with O₂) - at 95% Confidence 5.20

0.56

mg/m³Dependence on voltage

mg/m³

RUN 1

Expanded uncertainty (no O₂) - at 95% Confidence 4.66

% at ELVResult of Compliance with Uncertainty Requirement in M2 N/A -

RUN 1

0.05

mg/m³


mg/m³ (REF)

mg/m³0.04

mg/m³

Uncertainty corrected to std conds. (O₂) 3.74






Sample Runs

- -

- -

- -

- -

- -



CYL 3.0085Span Gas Expiry Date 15/07/2018

180°C

100

±g/hr 505.2

12.14

Uncertainty 3.13


1926.8

±mg/m³

Yes

Nitrogen (5 Grade)Span Gas Uncertainty (%) 2

Run 1

Parameter Value

3.13

Span Gas Reference Number

Filtration Type / Size 0.1µm Glass FibreHeated Head Filter Used

Units

Technical Procedure

Uncertainty

Parameter

505.2

Gas Cylinder Concentration (ppm)

Mean

SULPHUR DIOXIDE: RESULTS SUMMARY


407.51

12.14

Span Gas Start Pressure (bar)

Standard TGN M21

APPENDIX 2


Zero Gas Type


g/hr 1926.8Mass Emission

CAT-TP-21


Span Gas Type Sulphur Dioxide





1 / 11 / 1


Sample Point I.D.'s A1

Nitrogen (5 Grade)


Zero Gas Type







SULPHUR DIOXIDE: DATA TREND

APPENDIX 2


0.0

5.0

10.0

15.0

20.0

25.0

14:3

0

14:3

1

14:3

2

14:3

3

14:3

4

14:3

5

14:3

6

14:3

7

14:3

8

14:3

9

14:4

0

14:4

1

14:4

2

14:4

3

14:4

4

14:4

5

14:4

6

14:4

7

14:4

8

14:4

9

14:5

0

14:5

1

14:5

2

14:5

3

14:5

4

14:5

5

14:5

6

14:5

7

14:5

8

14:5

9

15:0

0

Conc

entr

atio

n (m

g/m

³)

Sulphur Dioxide At Reference Conditions

- Run 1






Sampling Details

Quality Assurance

Zero Drift 0 0 0

Zero Drift 0 0 0

Zero Drift 0 0 0

Span Drift 0 0 0 ppm -0.20

Run 1Units


°C


ppm -0.20

-

CAL

1

Parameter

0.20



ppm

APPENDIX 2

CAL

3

14:30 - 15:00

Instrument Range

ppm

Span Gas Value ppm

1.5


Yes

Yes

ppm 100

ppm

Units Run 1

31/05/2017

Zero Drift Units Run 1

0.00

Units Run 1

-

97.00

ppm

Temperature Acceptable -

4.87

SULPHUR DIOXIDE: SAMPLING DETAILS & QUALITY ASSURANCE

ppm

97.4


Average Temperature

ppm

Span Drift

Allowable Temperature

Sampling Dates

ppm

Zero Down Sampling Line (Post) ppmZero Down Sampling Line (Pre)

Allowable Zero Drift

< °C 4.0

CAL

1CA

L 2

± ppm


97.20

Sampling Times -

ppmSpan Down Sampling Line (Post)

Span Drift 0 0 0

Span Drift 0 0 0

Span Drift 0 0 0

Method Deviations

1

x

- - -

- - -

- - -

CAL

3

ppm -0.20


Yes

ppm

Run 1

4.87


CAL

2CA

L 1

Span Down Sampling Line (Post) ppm


Allowable Span Drift ± ppm

Test Conditions Units


Span Down Sampling Line (Post) ppm

Run Number


°C 14

ppm

ppm

ppm

Nature of Deviation

Span Drift Acceptable -







1.40

mg/m³

mg/m³Lack of fit

% of value

Performance characteristic RUN 1 UnitsStandard deviation of repeatability at zero use rep at span mg/m³

% of valueUncertainty of calibration gas blending % of valueUncertainty of calibration gas

1.05 mg/m³

Cal gas conc. 278.1

2.00

Standard deviation of repeatability at span level 0.07

% full scale/10VLosses in the line (leak) 0.21

0.40

Combined interference 0.10

% of full scaleAtmospheric pressure dependence 0.30 % of value/kPaAmbient temperature dependence 0.15 % full scale/10K

Drift -0.34

0.40

40.0 mg/m³ (REF)

0.02 mg/m³

Limit value

APPENDIX 2

mg/m³ (STP, dry)Measured concentration

mg/m³Volume or pressure flow dependence 0.01 mg/m³Atmospheric pressure dependence 0.10 mg/m³Ambient temperature dependence


seconds

10.0

Dependence on voltage

-0.21 % full scaleSpan drift -0.21

160

Range Used 100.0

%

Number of readings in measurement 30 -

% full scale

8.71

mg/m³

Repeatability at zero 0.40 % full scaleRepeatability at span level 0.40 % full scaleDeviation from linearity 0.72 % of valueZero drift

Conversion 2.86

Range Used [A] 285.5

% range

UnitsResponse time

mg/m³Cal gas conc.

ppm to mg/m³MCERTS Range [B] 460.0 mg/m³Lower of [A] or [B] 285.5

TGN M2 Allowable MU

Performance characteristics RUN 1 Units

SULPHUR DIOXIDE: MEASUREMENT UNCERTAINTY CALCULATIONS

97.4 ppm

ppm

k =

mg/m³0.02 mg/m³

Combined interference (from MCERTS Certificate) 0.16Ambient temperature dependence

Dependence on voltage 0.05 mg/m³Losses in the line (leak) 0.01

% at ELV

Overall Allowable uncertainty (no O₂) - at 95% Confidence 10.0 % at ELVResult of Compliance with Uncertainty Requirement in M2 N/A -

RUN 1 UnitsExpanded uncertainty (with O₂) - at 95% Confidence 25.81 % of Value

mg/m³Uncertainty of calibration gas blending 0.07 mg/m³Uncertainty of calibration gas 0.10 mg/m³

RUN 1 UnitsMeasurement uncertainty Result 8.71 mg/m³Combined uncertainty 1.14 mg/m³Expanded uncertainty 1.96 2.24 mg/m³

Uncertainty corrected to std conds. (O₂) 3.73 mg/m³ (REF)

Expanded uncertainty (with O₂) - at 95% Confidence 9.61 % at ELV

Overall Allowable uncertainty (with O₂) - at 95% Confidence 10.3 % at ELVResult of Compliance with Uncertainty Requirement in M2 COMPLIANT -


RUN 1 UnitsExpanded uncertainty (no O₂) - at 95% Confidence 25.71 % of Value

Expanded uncertainty (no O₂) - at 95% Confidence 5.60






Sample Runs

- -

- -

- -

- -

- -



100

Mass Emission

Probe Material Stainless SteelFiltration Type / Size

APPENDIX 2


Parameter Units


Uncertainty

Concentration

Value

mg/m³ 78.14

Gas Cylinder Concentration (ppm) 398.61

Mean

CARBON MONOXIDE: RESULTS SUMMARY

g/hr

Nitrogen (5 Grade)

12406.8

±g/hr

09/12/2020Span Gas Start Pressure (bar)Span Gas Expiry Date

Span Gas Uncertainty (%) 2

Technical Procedure CAT-TP-21Standard EN 15058

0.1µm Glass FibreYes


Span Gas Type Carbon Monoxide

Run 1

782.6

3.36

180°C

Span Gas Reference Number CYL 2.0111

Uncertainty

Zero Gas Type

782.6

78.14

Parameter

3.36

Heated Head Filter Used

12406.8

±mg/m³





Sample Point I.D.'s


Nitrogen (5 Grade)


A1

Zero Gas Type







APPENDIX 2

CARBON MONOXIDE: DATA TREND


0.0

20.0

40.0

60.0

80.0

100.0

120.0

140.0

160.0

180.0

14:3

0

14:3

1

14:3

2

14:3

3

14:3

4

14:3

5

14:3

6

14:3

7

14:3

8

14:3

9

14:4

0

14:4

1

14:4

2

14:4

3

14:4

4

14:4

5

14:4

6

14:4

7

14:4

8

14:4

9

14:5

0

14:5

1

14:5

2

14:5

3

14:5

4

14:5

5

14:5

6

14:5

7

14:5

8

14:5

9

15:0

0

Conc

entr

atio

n (m

g/m

³)

Carbon Monoxide At Reference Conditions

- Run 1






Sampling Details

Quality Assurance

Zero Drift 0 0 0

Zero Drift 0 0 0

Zero Drift 0 0 0

ppm

CAL

3CA

L 1

Units

14:30 - 15:00

Run 1

APPENDIX 2

CARBON MONOXIDE: SAMPLING DETAILS & QUALITY ASSURANCE

Parameter

100

CAL

2

Temperature Acceptable

Zero Drift

4.00



- 31/05/2017Instrument Range

ppm

ppm


Units

79.30


Yes

Sampling Times

ppm

Run 1

Zero Down Sampling Line (Post) ppmppm

Run 1

Allowable Zero Drift ± ppm

-

ppm

ppm0.30

-

Yes


Units

80.1

4.0

CAL

1 Zero Down Sampling Line (Pre)

Span Down Sampling Line (Post)

Average TemperatureAllowable Temperature < °C

0.10

Sampling Datesppm

79.00

1.5

Span Gas Value

Units Run 1

Span Drift

ppm

0.40


°C

Zero Drift Acceptable -

ppm

Span Drift 0 0 0

Span Drift 0 0 0

Span Drift 0 0 0

Method Deviations

1

x

- - -

- - -

- - -

YesSpan Drift Acceptable -

°C 14

CAL

1CA

L 2

Span Down Sampling Line (Pre)Span Down Sampling Line (Post)

Nature of Deviation

ppm

ppm

CAL

3

ppm

Test Conditions

4.00

ppm

ppm -0.30

Run 1

Run Number

Allowable Span Drift ± ppm




Span Down Sampling Line (Post)Span Down Sampling Line (Pre)

ppm

Units

ppm






0.40

mg/m³Lower of [A] or [B] 95.0

RUN 1

-Repeatability at zero

Performance characteristics

MCERTS Range [B] 95.0

seconds

Range Used 100.0 ppmRange Used [A] 124.9 mg/m³Cal gas conc. 80.1 ppmConversion 1.25 ppm to mg/m³

Zero drift 0.38

30

Span drift -0.38 % full scale% full scale

mg/m³Cal gas conc. 100.0 mg/m³

UnitsResponse time 60

% full scaleRepeatability at span level 0.40 % full scaleDeviation from linearity 0.22 % of value

Number of readings in measurement

APPENDIX 2

CARBON MONOXIDE: MEASUREMENT UNCERTAINTY CALCULATIONS

Uncertainty of calibration gas 2.00 % of value

Performance characteristic RUN 1 UnitsStandard deviation of repeatability at zero use rep at span mg/m³Standard deviation of repeatability at span level 0.07 mg/m³Lack of fit 0.12

% of full scaleAtmospheric pressure dependence 0.30 % of value/kPaAmbient temperature dependence 0.05 % full scale/10KCombined interference 0.73 % rangeDependence on voltage 0.40 % full scale/10VLosses in the line (leak) 1.00 % of valueUncertainty of calibration gas blending 1.40 % of value

Volume or pressure flow dependence 0.40

mg/m³Drift 0.10 mg/m³Volume or pressure flow dependence 0.00 mg/m³Atmospheric pressure dependence 0.08 mg/m³Ambient temperature dependence 0.01 mg/m³

Measured concentrationTGN M2 Allowable MULimit valuePerformance characteristics RUN 1 Units

100.0 mg/m³ (REF)6.0 %

56.11 mg/m³ (STP, dry)

k =

Ambient temperature dependence 0.01 mg/m³Combined interference (from MCERTS Certificate) 0.40 mg/m³Dependence on voltage 0.05 mg/m³Losses in the line (leak) 0.32 mg/m³Uncertainty of calibration gas blending 0.45 mg/m³

% of Value

Expanded uncertainty (no O₂) - at 95% Confidence 2.04 % at ELV

56.11 mg/m³Combined uncertainty 1.04 mg/m³Expanded uncertainty 1.96 2.04 mg/m³

Uncertainty corrected to std conds. (O₂) 3.40 mg/m³ (REF)

N/A -

RUN 1 UnitsExpanded uncertainty (with O₂) - at 95% Confidence 4.30

Result of Compliance with Uncertainty Requirement in M2 COMPLIANT -


% of Value

Uncertainty of calibration gas 0.65 mg/m³

RUN 1 UnitsMeasurement uncertainty Result

RUN 1 UnitsExpanded uncertainty (no O₂) - at 95% Confidence 3.64

Expanded uncertainty (with O₂) - at 95% Confidence 4.10 % at ELV

Overall Allowable uncertainty (with O₂) - at 95% Confidence 6.4 % at ELV

Overall Allowable uncertainty (no O₂) - at 95% Confidence 6.0 % at ELVResult of Compliance with Uncertainty Requirement in M2






Sample Runs

- -

- -

- -





OXYGEN: RESULTS SUMMARY

0.1µm Glass Fibre

Concentration % v/v 15.55 15.55



APPENDIX 2

0.36 0.36

Heated Head Filter Used Yes


EN 14789Technical Procedure CAT-TP-21

Probe Material Stainless SteelFiltration Type / Size

Parameter

Span Gas Expiry Date 07/12/2021Span Gas Start Pressure (bar) 100Gas Cylinder Concentration (% v/v) 20.49


Mean

Span Gas Uncertainty (%) 2

Parameter

Uncertainty ±% v/v

180°C


Nitrogen (5 Grade)Zero Gas Type

Span Gas Reference Number

Units Run 1

Value

Standard

CYL 11.0268Span Gas Type Synthetic Air (5 Grade)

Sample Point I.D.'s A1







APPENDIX 2

OXYGEN: DATA TREND


0.0

2.0

4.0

6.0

8.0

10.0

12.0

14.0

16.0

18.0

14:3

0

14:3

1

14:3

2

14:3

3

14:3

4

14:3

5

14:3

6

14:3

7

14:3

8

14:3

9

14:4

0

14:4

1

14:4

2

14:4

3

14:4

4

14:4

5

14:4

6

14:4

7

14:4

8

14:4

9

14:5

0

14:5

1

14:5

2

14:5

3

14:5

4

14:5

5

14:5

6

14:5

7

14:5

8

14:5

9

15:0

0

Conc

entr

atio

n (%

v/v

)

Oxygen Oxygen

- Run 1






Sampling Details

Quality Assurance

Zero Drift 0 0 0

Zero Drift 0 0 0

Zero Drift 0 0 0

Span Drift 0 0 0 % v/v

CAL

3

4.0

-0.03

% v/v 25Instrument Range% v/v 17.00

% v/v

% v/v

% v/v

0.00

17.05

-Allowable Zero Drift ± % v/v 0.85

Zero Drift

CAL

1 Zero Down Sampling Line (Pre) % v/v

-

Conditioning Unit Temperature Units Run 1

14:30 - 15:00Sampling Dates - 31/05/2017

CAL

2 Zero Down Sampling Line (Pre) % v/v

Span Gas Value

Run 1

Span Down Sampling Line (Post) % v/v

Allowable Temperature < °C

0.03Zero Down Sampling Line (Post) % v/v 0.00


Sampling Times

Average Temperature

Temperature Acceptable - Yes

Span Drift Units

°C 1.5

Yes

Units



% v/v

% v/v

17.05

Run 1

APPENDIX 2

OXYGEN: SAMPLING DETAILS & QUALITY ASSURANCE

Zero Down Sampling Line (Pre) % v/v


% v/v

CAL

1 Span Down Sampling Line (Pre)

Span Drift 0 0 0

Span Drift 0 0 0

Span Drift 0 0 0

Method Deviations

1

x

- - -

- - -

- - -

CAL

2 Span Down Sampling Line (Pre) % v/vSpan Down Sampling Line (Post)

% v/v

Span Down Sampling Line (Pre) % v/v

Allowable Span Drift ± % v/v 0.85

0.00

Span Down Sampling Line (Post) % v/v

Nature of Deviation Run Number



% v/v% v/v

Span Drift Acceptable - Yes

CAL

3

Test Conditions Units Run 1

Run Ambient Temperature Range °C 14

% v/v






Performance characteristic RUN 1 Units

APPENDIX 2

OXYGEN: MEASUREMENT UNCERTAINTY CALCULATIONS

% of value

0.03 % of valueZero drift -0.18Deviation from linearity

% full scaleSpan drift

Number of readings in measurement 30 -Repeatability at zero 0.04 % full scaleRepeatability at span level 0.04 % full scale

20.5 %vol

Performance characteristics RUN 1 UnitsResponse time 60 seconds

N/A %vol6.0 %

Performance characteristics RUN 1 Units

Measured concentrationTGN M2 Allowable MULimit value

Combined interference 0.10

Combined interference (from MCERTS Certificate) 0.01 %volDependence on voltage 0.00 %volLosses in the line (leak) 0.00 %volUncertainty of calibration gas 0.21 %vol

RUN 1 Units

% of valueUncertainty of calibration gas 2.00

Standard deviation of repeatability at zero use rep at span %volStandard deviation of repeatability at span level 0.01 %volLack of fit 0.00 %volDrift -0.02

0.02

%volVolume or pressure flow dependence 0.00 %volAtmospheric pressure dependence %volAmbient temperature dependence -0.01 %vol

-0.07 % full scale/10KAtmospheric pressure dependence 0.30 % of value/kPaAmbient temperature dependence

Volume or pressure flow dependence 0.20 % of full scale0.00 % full scale

18.60 %volRange Used 25.0 %volCal gas conc.

% rangeDependence on voltage 0.02 % full scale/10VLosses in the line (leak) 0.00

k =

Requirement for SRM is that Uncertainty should be 0.5%vol absolute or 6% relative whichever is the lower, on a dry gas basis. Ref EA TGN M2.

RUN 1 UnitsMeasurement uncertainty Result 18.60 %volCombined uncertainty 0.22 %vol

Result of Compliance with Uncertainty Requirement in M2 COMPLIANT -Expanded uncertainty (no O₂) - at 95% Confidence 2.30 % of Value

Expanded uncertainty 1.96 0.43 %vol

RUN 1 Units






Summary

See report.

FOLLOW-UP ACTIONS

You are required to complete the instructions and actions, as outlined in this report, within the specified timeframe. Where required, you shall respond to actions specified in Compliance Investigations within the required timeframe.The licensee shall maintain documentary evidence, for review by the EPA, that the prescribed corrective actions were completed within the required timeframe.

(i) Compliance Investigations

You are not required to respond directly to items contained in this EPA site visit report; where an issue requires a direct response, the EPA will generate a Compliance Investigation through the EDEN system. You will receive notification when a Compliance Investigation instruction or action is generated.

(ii) Publication of reports and licensee response.

Please note that this Site Visit Report will be made available for public viewing via the EPA’s Licence Enforcement Access Portal within one day of the issue date and will be published on the Licence Details Page of the EPA’s website, www.epa.ie, that relates to your licence 60 calendar days after the issue date.

You may if you choose submit, within 45 calendar days of the issue date of this Site Visit Report, a Licensee Public Response that will be published alongside the Site Visit Report. This Response, should you wish to avail of it, provides you with an opportunity to inform the public about how you are implementing the actions set out in the report, activities underway, timescales and target completion dates. Please be aware that the content of your Licensee Public Response must be factual and should not breach the EPAs stated online publication standards.

If you wish to submit a Licensee Public Response to an EPA Site Visit Report, you should do this by clicking on the ‘Make a Response’ link on the Site Visits page in EDEN. A .pdf document containing your response can be attached and submitted from here.

(iii) Response to Site visit report

Where you do wish to respond directly to a site visit report, you should do this by generating a ‘Licensee Return’ of the type ‘Site Updates/Notifications’ and the sub-type ‘Response to EPA Report’ in EDEN.

Please note that you are required to comply with the conditions of your licence at all times, and where noncompliance occurs you must restore compliance within the shortest possible time. These actions will be verified during subsequent EPA visits.

Please quote the above Inspection Reference Number in any future correspondence in relation to this Report.


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