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Supporting Information
Structure-Property Relationship in Laponite Materials: From Wigner Glasses to
Strong Self-Healing Hydrogels Formed by Non-Covalent Interactions
Tiago B. Becher,a Carolyne B. Braga,a Diego L. Bertuzzi,a Miguel D. Ramos Jr,a Ayaz Hassan,b Frank N.
Crespilho,b Catia Ornelasa,*
Table S1. Assignment of the vibrational modes observed in the FTIR spectra of Laponite, HN5, HNP5,
HN5NaCl, HN5CaCl2, and HN5CeCl3.
0.1 1 10 100 1000100
101
102
103
104
105
106
G' G''
Clay 5%
G' a
nd G
'' (P
a)
Strain (%)
Figure S.I.1. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5.
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5%
G' a
nd G
'' (P
a)
f in Hz
Compound -OH stretching of lattice hydroxyl group
(cm-1
)
-OH stretching from free H2O (cm-1)
H-OH bending (cm-1)
Si-O streching (cm-1)
Laponite 3630 3410 1635 960
HN5 3630 3310 1635 1000 HNP5 3630 3310 1635 1000 HN5NaCl 3630 3310 1635 1000 HN5CaCl
2 3630 3310 1635 1005
HN5CeCl3 3630 3310 1635 1005
Electronic Supplementary Material (ESI) for Soft Matter.This journal is © The Royal Society of Chemistry 2018
2
0.1 1 10 100 1000100
101
102
103
104
105
106
G' G''
Clay 4%
G' a
nd G
'' (P
a)
Strain (%)
Figure S.I.2. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN4.
0.1 1 10 100 1000100
101
102
103
104
105
106
G' G''
Clay 3%
G' a
nd G
'' (P
a)
Strain (%)
Figure S.I.3. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN3.
0.1 1 10 100 1000100
101
102
103
104
105
106
G' G''
Clay 2%
G' a
nd G
'' (P
a)
Strain (%)
Figure S.I.4. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN2.
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 4%
G' a
nd G
'' (P
a)
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 3%
G' a
nd G
'' (P
a)
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 2%
G' a
nd G
'' (P
a)
f in Hz
3
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + PBS 0.1 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%)
Figure S.I.5. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5NaCl.
0.1 1 10 100 1000100
101
102
103
104
105
106
C4% + Polymer 5 + PBS 0.1mL
G' G''
G' a
nd G
'' (P
a)
Strain (%)
Figure S.I.6. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN4NaCl.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 3% + Polymer 5mg + PBS 0.1 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%)
Figure S.I.7. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN3NaCl.
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + PBS 0.1 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 4% + Polymer 5mg + PBS 0.1 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 3% + Polymer 5mg + PBS 0.1 mL
G' i
n Pa
G''
in P
a
f in Hz
4
Variation of polymer
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 1mg + PBS 0.1 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%)
Figure S.I.8. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5NaCl, using 1 mg of polyacrylate.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 2.5mg + PBS 0.1 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%)
Figure S.I.9. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5NaCl, using 2.5 mg of polyacrylate.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + PBS 0.1 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.10. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5NaCl, using 5 mg of polyacrylate.
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 1mg + PBS 0.1 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 2.5mg + PBS 0.1 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + PBS 0.1 mL
G' i
n Pa
G''
in P
a
f in Hz
5
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + PBS 0.1 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%)
Figure S.I.11. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5NaCl, using 10 mg of polyacrylate.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 15mg + PBS 0.1 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.12. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5NaCl, using 15 mg of polyacrylate.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 20mg + PBS 0.1 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.13. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5NaCl, using 20 mg of polyacrylate.
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 10mg + PBS 0.1 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 15mg + PBS 0.1 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 20mg + PBS 0.1 mL
G' i
n Pa
G''
in P
a
f in Hz
6
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 25mg + PBS 0.1 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.14. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5NaCl, using 25 mg of polyacrylate.
Variation of PBS
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + PBS 0.01 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.15. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5PBS, using 0.01 M PBS.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + PBS 0.02 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.16. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5PBS, using 0.02 M PBS.
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 25mg + PBS 0.1 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + PBS 0.01 M
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + PBS 0.02 mL
G' i
n Pa
G''
in P
a
f in Hz
7
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + PBS 0.03 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.17. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5PBS, using 0.03 M PBS.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + PBS 0.04 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.18. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5PBS, using 0.04 M PBS.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + PBS 0.05 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.19. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5PBS, using 0.05 M PBS.
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + PBS 0.03 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + PBS 0.04 mL
G' G''
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + PBS 0.05 mL
G' G''
G' i
n Pa
G''
in P
a
f in Hz
8
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + PBS 0.1 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.20. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5PBS, using 0.1 M PBS.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + PBS 0.2 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.21. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5PBS, using 0.2 M PBS.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + PBS 0.3 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.22. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5PBS, using 0.3 M PBS.
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + PBS 0.1 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
G' i
n Pa
G''
in P
a
Clay 5% + Polymer 5mg + PBS 0.2 mL
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + PBS 0.3 mL
G' i
n Pa
G''
in P
a
f in Hz
9
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + PBS 0.4 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.23. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5PBS, using 0.4 M PBS.
Variation of NaCl
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + NaCl 0.01 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.24. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5NaCl, using 0.01 M NaCl.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + NaCl 0.03 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.25. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5NaCl, using 0.03 M NaCl.
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + PBS 0.4 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.01 M NaCl
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + NaCl 0.03 mL
G' i
n Pa
G''
in P
a
f in Hz
10
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + NaCl 0.04 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.26. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5NaCl, using 0.04 M NaCl.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + NaCl 0.05 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.27. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5NaCl, using 0.05 M NaCl.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + NaCl 0.1 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.28. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5NaCl, using 0.1 M NaCl.
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + NaCl 0.04 mL
G' G''
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + NaCl 0.05 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + NaCl 0.1 mL
G' i
n Pa
G''
in P
a
f in Hz
11
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + NaCl 0.2 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.29. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5NaCl, using 0.2 M NaCl.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + NaCl 0.3 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.30. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5NaCl, using 0.3 M NaCl.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + NaCl 0.04 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.31. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5NaCl, using 0.4 M NaCl.
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + NaCl 0.2 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + NaCl 0.3 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + NaCl 0.4 mL
G' i
n Pa
G''
in P
a
f in Hz
12
Variation of Na2SO4
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + NaSO4 0.01 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.32. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Na2SO4, using 0.01 M Na2SO4.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Na2SO4 0.03 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.33. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Na2SO4, using 0.03 M Na2SO4.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Na2SO4 0.04 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.34. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Na2SO4, using 0.04 M Na2SO4.
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Na2SO4 0.01 M
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + Na2SO4 0.03 mLG
' in
Pa G
'' in
Pa
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + Na2SO4 0.04 mL
G' i
n Pa
G''
in P
a
f in Hz
13
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Na2SO4 0.05mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.35. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Na2SO4, using 0.05 M Na2SO4.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Na2SO4 0.1mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.36. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Na2SO4, using 0.1 M Na2SO4.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Na2SO4 0.2mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.37. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Na2SO4, using 0.2 M Na2SO4.
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + Na2SO4 0.05 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Na2SO4 0.1 mL
G' G''
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + Na2SO4 0.2 mL
G' i
n Pa
G''
in P
a
f in Hz
14
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Na2SO4 0.3mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.38. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Na2SO4, using 0.3 M Na2SO4.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Na2SO4 0.4mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.39. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Na2SO4, using 0.4 M Na2SO4.
Variation of NaI
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + NaI 0.01 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.40. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5NaI, using 0.01 M NaI.
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Na2SO4 0.3 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Na2SO4 0.4 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + NaI 0.01 M
G' i
n Pa
G''
in P
a
f in Hz
G' G''
15
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + NaI 0.03 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.41. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5NaI, using 0.03 M NaI.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + NaI 0.04 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.42. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5NaI, using 0.04 M NaI.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + NaI 0.05 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.43. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5NaI, using 0.05 M NaI.
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + Nal 0.03 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + Nal 0.04 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + Nal 0.05 mL
G' i
n Pa
G''
in P
a
f in Hz
16
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + NaI 0.1 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%)
Figure S.I.44. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5NaI, using 0.1 M NaI.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + NaI 0.2 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%)
Figure S.I.45. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5NaI, using 0.2 M NaI.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + NaI 0.3 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%)
Figure S.I.46. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5NaI, using 0.3 M NaI.
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + Nal 0.1 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + Nal 0.2 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + Nal 0.3 mL
G' i
n Pa
G''
in P
a
f in Hz
17
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + NaI 0.4 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%)
Figure S.I.47. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5NaI, using 0.4 M NaI.
Variation of MgSO4
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + MgSO4 0.01mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.48. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5MgSO4, using 0.01 M MgSO4.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + MgSO4 0.03mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.49. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5MgSO4, using 0.03 M MgSO4.
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + Nal 0.4 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + MgSO4 0.01 M
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + MgSO4 0.03 mL
G' i
n Pa
G''
in P
a
f in Hz
18
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + MgSO4 0.04mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.50. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5MgSO4, using 0.04 M MgSO4.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + MgSO4 0.05mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.51. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5MgSO4, using 0.05 M MgSO4.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + MgSO4 0.1mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.52. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5MgSO4, using 0.1 M MgSO4.
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + MgSO4 0.04 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + MgSO4 0.05 mL
G' G''
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + MgSO4 0.1 mL
G' i
n Pa
G''
in P
a
f in Hz
19
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + MgSO4 0.2mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.53. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5MgSO4, using 0.2 M MgSO4.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + MgSO4 0.3mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.54. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5MgSO4, using 0.3 M MgSO4.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + MgSO4 0.4mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.55. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5MgSO4, using 0.4 M MgSO4.
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + MgSO4 0.2 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + MgSO4 0.3 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + MgSO4 0.4 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
20
Variation of CaCl2
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CaCl2 0.01mL
G' G''
G' a
nd G
'' (P
a)
Strain (%)
Figure S.I.56. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5CaCl2, using 0.01 M CaCl2.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CaCl2 0.03 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.57. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5CaCl2, using 0.03 M CaCl2.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CaCl2 0.04 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.58. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5CaCl2, using 0.04 M CaCl2.
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CaCl2 0.01 M
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + CaCl2 0.03 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + CaCl2 0.04 mL
G' i
n Pa
G''
in P
a
f in Hz
21
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CaCl2 0.05 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.59. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5CaCl2, using 0.05 M CaCl2.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CaCl2 0.1 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.60. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5CaCl2, using 0.1 M CaCl2.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CaCl2 0.2 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.61. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5CaCl2, using 0.2 M CaCl2.
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + CaCl2 0.05 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + CaCl2 0.1 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + CaCl2 0.2 mL
G' i
n Pa
G''
in P
a
f in Hz
22
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CaCl2 0.3mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.62. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5CaCl2, using 0.3 M CaCl2.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CaCl2 0.3 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.63. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5CaCl2, using 0.4 M CaCl2.
Variation of CuSO4
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CuSO4 0.01mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.64. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5CuSO4, using 0.01 M CuSO4.
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + CaCl2 0.3 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + CaCl2 0.4 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CuSO4 0.01 M
G' i
n Pa
G''
in P
a
f in Hz
G' G''
23
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CuSO4 0.03 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.65. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5CuSO4, using 0.03 M CuSO4.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CuSO4 0.04 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.66. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5CuSO4, using 0.04 M CuSO4.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CuSO4 0.05 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.67. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5CuSO4, using 0.05 M CuSO4.
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CuSO4 0.03 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100101
102
103
104
105
106
Clay 5% + Polymer 5mg + CuSO4 0.04 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CuSO4 0.05 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
24
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CuSO4 0.1 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.68. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5CuSO4, using 0.1 M CuSO4.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CuSO4 0.1 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%)
Figure S.I.69. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5CuSO4, using 0.2 M CuSO4.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CuSO4 0.3 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.70. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5CuSO4, using 0.3 M CuSO4.
0.1 1 10 100101
102
103
104
105
106
Clay 5% + Polymer 5mg + CuSO4 0.1 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CuSO4 0.2 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CuSO4 0.3 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
25
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CuSO4 0.04 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.71. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5CuSO4, using 0.4 M CuSO4.
Variation of CeCl3
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CeCl3 0.01mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.72. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5CeCl3, using 0.01 M CeCl3.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CeCl3 0.03 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.73. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5CeCl3, using 0.03 M CeCl3.
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CuSO4 0.4 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CeCl3 0.01 M
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CeCl3 0.03 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
26
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CeCl3 0.04 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.74. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5CeCl3, using 0.04 M CeCl3.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CeCl3 0.05 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.75. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5CeCl3, using 0.05 M CeCl3.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CeCl3 0.1 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.76. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5CeCl3, using 0.1 M CeCl3.
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.04 mL CeCl3
G' a
nd G
'' (P
a)
f in Hz
G' G''
0.1 1 10 100101
102
103
104
105
106
Clay 5% + Polymer 5mg + CeCl3 0.05 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CeCl3 0.1 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
27
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CeCl3 0.2 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.77. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5CeCl3, using 0.2 M CeCl3.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CeCl3 0.3 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.78. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5CeCl3, using 0.3 M CeCl3.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CeCl3 0.4 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.79. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5CeCl3, using 0.4 M CeCl3.
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CeCl3 0.2 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CeCl3 0.3 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + CeCl3 0.4 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
28
Variation of KCl
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + KCl 0.01mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.80. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5KCl, using 0.01 M KCl.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + KCl 0.03mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.81. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5KCl, using 0.03 M KCl.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + KCl 0.04mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.82. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5KCl, using 0.04 M KCl.
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + KCl 0.01 M
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + KCl 0.03 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + KCl 0.04 mL
G' i
n Pa
G''
in P
a
f in Hz
29
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + KCl 0.05mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.83. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5KCl, using 0.05 M KCl.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + KCl 0.1mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.84. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5KCl, using 0.1 M KCl.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + KCl 0.2mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.85. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5KCl, using 0.2 M KCl.
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + KCl 0.05 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + KCl 0.1 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + KCl 0.2 mL
G' i
n Pa
G''
in P
a
f in Hz
30
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + KCl 0.3mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.86. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5KCl, using 0.3 M KCl.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + KCl 0.4mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.87. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5KCl, using 0.4 M KCl.
Variation of KNO3
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + KNO3 0.01mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.88. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5KNO3, using 0.01 M KNO3.
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + KCl 0.3 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + KCl 0.4 mL
G' i
n Pa
G''
in P
a
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + KNO3 0.01 M
G' i
n Pa
G''
in P
a
f in Hz
G' G''
31
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + KNO3 0.03mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.89. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5KNO3, using 0.03 M KNO3.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + KNO3 0.04mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.90. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5KNO3, using 0.04 M KNO3.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + KNO3 0.05mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.91. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5KNO3, using 0.05 M KNO3.
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + KNO3 0.03 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + KNO3 0.04 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + KNO3 0.05 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
32
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + KNO3 0.1mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.92. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5KNO3, using 0.1 M KNO3.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + KNO3 0.2mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.93. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5KNO3, using 0.2 M KNO3.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + KNO3 0.3mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.94. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5KNO3, using 0.3 M KNO3.
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + KNO3 0.1 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + KNO3 0.2 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + KNO3 0.3 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
33
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + KNO3 0.4mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.95. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5KNO3, using 0.4 M KNO3.
Variation of ZnSO4
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + ZnSO4 0.01mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.96. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5ZnSO4, using 0.01 M ZnSO4.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + ZnSO4 0.03mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.97. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5ZnSO4, using 0.03 M ZnSO4.
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + KNO3 0.4 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + ZNSO4 0.01 M
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + ZnSO4 0.03 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
34
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + ZnSO4 0.04mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.98. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5ZnSO4, using 0.04 M ZnSO4.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + ZnSO4 0.05mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.99. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5ZnSO4, using 0.05 M ZnSO4.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + ZnSO4 0.1mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.100. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5ZnSO4, using 0.1 M ZnSO4.
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + ZnSO4 0.04 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + ZnSO4 0.05 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + ZnSO4 0.1 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
35
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + ZnSO4 0.1mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.101. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5ZnSO4, using 0.2 M ZnSO4.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + ZnSO4 0.3mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.102. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5ZnSO4, using 0.3 M ZnSO4.
Figure S.I.103. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5ZnSO4, using 0.4 M ZnSO4.
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + ZnSO4 0.2 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + ZnSO4 0.3 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0,1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + ZnSO4 0.4mL
G' G''
G' a
nd G
'' (P
a)
Strain (%)0.1 1 10 100
100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + ZnSO4 0.4 mL
G' i
n Pa
G''
in P
a
f in Hz
G' G''
36
Variation of Ca(NO3)2
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Ca(NO3)2 0.01 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.104. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Ca(NO3)2, using 0.01 M Ca(NO3)2.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Ca(NO3)2 0.03 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.105. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Ca(NO3)2, using 0.03 M Ca(NO3)2.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Ca(NO3)2 0.04 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.106. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Ca(NO3)2, using 0.04 M Ca(NO3)2.
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.01 M CaN2O6
G' i
n Pa
G''
in P
a
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.03 mL CaN2O6
G' a
nd G
'' (P
a)
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.04 mL CaN2O6
G' a
nd G
'' (P
a)
f in Hz
G' G''
37
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Ca(NO3)2 0.05 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.107. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Ca(NO3)2, using 0.05 M Ca(NO3)2.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Ca(NO3)2 0.1mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.108. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Ca(NO3)2, using 0.1 M Ca(NO3)2.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Ca(NO3)2 0.2 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.109. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Ca(NO3)2, using 0.2 M Ca(NO3)2.
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.05 mL CaN2O6
G' a
nd G
'' (P
a)
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.1 mL CaN2O6
G' a
nd G
'' (P
a)
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.2 mL CaN2O6
G' a
nd G
'' (P
a)
f in Hz
G' G''
38
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Ca(NO3)2 0.3 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.110. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Ca(NO3)2, using 0.3 M Ca(NO3)2.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Ca(NO3)2 0.4 mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.111. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Ca(NO3)2, using 0.4 M Ca(NO3)2.
Variation of Ba(NO3)2
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Ba(NO3)2 0.01mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.112. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Ba(NO3)2, using 0.01 M Ba(NO3)2.
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.3 mL CaN2O6
G' a
nd G
'' (P
a)
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.4 mL CaN2O6
G' a
nd G
'' (P
a)
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + Ba(NO3)2 0.01 M
G' a
nd G
'' (P
a)
f in Hz
39
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Ba(NO3)2 0.03mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.113. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Ba(NO3)2, using 0.03 M Ba(NO3)2.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Ba(NO3)2 0.04mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.114. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Ba(NO3)2, using 0.04 M Ba(NO3)2.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Ba(NO3)2 0.05mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.115. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Ba(NO3)2, using 0.05 M Ba(NO3)2.
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.03 mL Ba(NO3)2
G' a
nd G
'' (P
a)
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.04 mL Ba(NO3)2
G' a
nd G
'' (P
a)
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.05 mL Ba(NO3)2
G' a
nd G
'' (P
a)
f in Hz
G' G''
40
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Ba(NO3)2 0.1mL
G' G''
G' a
nd G
'' (P
a)
Strain (%)
Figure S.I.116. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Ba(NO3)2, using 0.1 M Ba(NO3)2.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Ba(NO3)2 0.2mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.117. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Ba(NO3)2, using 0.2 M Ba(NO3)2.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Ba(NO3)2 0.3mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.118. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Ba(NO3)2, using 0.3 M Ba(NO3)2.
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.1 mL Ba(NO3)2
G' a
nd G
'' (P
a)
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.2 mL Ba(NO3)2
G' a
nd G
'' (P
a)
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.3 mL Ba(NO3)2
G' a
nd G
'' (P
a)
f in Hz
G' G''
41
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Ba(NO3)2 0.4mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.119. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Ba(NO3)2, using 0.4 M Ba(NO3)2.
Variation of Sr(NO3)2
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Sr(NO3)2 0.01mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.120. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Sr(NO3)2, using 0.01 M Sr(NO3)2.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Sr(NO3)2 0.03mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.121. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Sr(NO3)2, using 0.03 M Sr(NO3)2.
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.4 mL Ba(NO3)2
G' a
nd G
'' (P
a)
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
G' G''
Clay 5% + Polymer 5mg + Sr(NO3)2 0.01 M
G' a
nd G
'' (P
a)
f in Hz
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.03 mL Sr(NO3)2
G' a
nd G
'' (P
a)
f in Hz
G' G''
42
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Sr(NO3)2 0.04mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.122. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Sr(NO3)2, using 0.04 M Sr(NO3)2.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Sr(NO3)2 0.05mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.123. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Sr(NO3)2, using 0.05 M Sr(NO3)2.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Sr(NO3)2 0.1mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.124. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Sr(NO3)2, using 0.1 M Sr(NO3)2.
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.04 mL Sr(NO3)2
G' a
nd G
'' (P
a)
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.05 mL Sr(NO3)2
G' a
nd G
'' (P
a)
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.1 mL Sr(NO3)2
G' a
nd G
'' (P
a)
f in Hz
G' G''
43
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Sr(NO3)2 0.2mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.125. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Sr(NO3)2, using 0.2 M Sr(NO3)2.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Sr(NO3)2 0.3mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.126. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Sr(NO3)2, using 0.3 M Sr(NO3)2.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Sr(NO3)2 0.4mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.127. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Sr(NO3)2, using 0.4 M Sr(NO3)2.
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.2 mL Sr(NO3)2
G' a
nd G
'' (P
a)
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.3 mL Sr(NO3)2
G' a
nd G
'' (P
a)
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.4 mL Sr(NO3)2
G' a
nd G
'' (P
a)
f in Hz
G' G''
44
Variation of Al2(SO4)3
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Al2(SO4)3 0.01mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.128. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Al2(SO4)3, using 0.01 M Al2(SO4)3.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Al2(SO4)3 0.03mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.129. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Al2(SO4)3, using 0.03 M Al2(SO4)3.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Al2(SO4)3 0.04mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.130. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Al2(SO4)3, using 0.04 M Al2(SO4)3.
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.01M Al2(SO4)3
G' a
nd G
'' (P
a)
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.03 mL Al2(SO4)3
G' a
nd G
'' (P
a)
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.04 mL Al2(SO4)3
G' a
nd G
'' (P
a)
f in Hz
G' G''
45
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Al2(SO4)3 0.05mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.131. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Al2(SO4)3, using 0.05 M Al2(SO4)3.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Al2(SO4)3 0.1mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.132. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Al2(SO4)3, using 0.1 M Al2(SO4)3.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Al2(SO4)3 0.2mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.133. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Al2(SO4)3, using 0.2 M Al2(SO4)3.
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.05 mL Al2(SO4)3
G' a
nd G
'' (P
a)
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.1 mL Al2(SO4)3
G' a
nd G
'' (P
a)
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.2 mL Al2(SO4)3
G' a
nd G
'' (P
a)
f in Hz
G' G''
46
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Al2(SO4)3 0.3mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.134. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Al2(SO4)3, using 0.3 M Al2(SO4)3.
0.1 1 10 100 1000100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + Al2(SO4)3 0.4mL
G' G''
G' a
nd G
'' (P
a)
Strain (%) Figure S.I.135. Data obtained on Strain Sweep test (left) and Frequency Sweep test (right) for HN5Al2(SO4)3, using 0.4 M Al2(SO4)3.
SAXS data
Figure S.I.136. SAXS data obtained for HN5PBS (black dots), and fit curve obtained on SASFit for a model of a monodisperse flat cylinder with 9.5 nm radius, 0.9 nm width and a mass fractal structure with D=2.2 (blue line).
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.3 mL Al2(SO4)3
G' a
nd G
'' (P
a)
f in Hz
G' G''
0.1 1 10 100100
101
102
103
104
105
106
Clay 5% + Polymer 5mg + 0.4 mL Al2(SO4)3
G' a
nd G
'' (P
a)
f in Hz
G' G''
0.01 0.1 1105
106
107
108
109
1010
1011
HN5PBS fit
I (a.
u.)
q (angstroms-1)
47
Figure S.I.137. SAXS data obtained for HN5NaI (black dots), and fit curve obtained on SASFit for a model of a monodisperse flat cylinder with 9.5 nm radius, 0.9 nm width and a mass fractal structure with D=1.9 (blue line).
Figure S.I.138. SAXS data obtained for HN5Na2SO4 (black dots), and fit curve obtained on SASFit for a model of a monodisperse flat cylinder with 9.5 nm radius, 0.9 nm width and a mass fractal structure with D=2.0 (blue line).
Figure S.I.139. SAXS data obtained for HN5KCl (black dots), and fit curve obtained on SASFit for a model of a monodisperse flat cylinder with 9.5 nm radius, 0.9 nm width and a mass fractal structure with D=2.2 (blue line).
0.01 0.1 1105
106
107
108
109
1010
1011
q (angstroms-1)
HN5NaI fit
I (
a.u)
0.01 0.1 1105
106
107
108
109
1010
1011
q (angstroms-1)
HN5Na2SO4
fit
I (a.
u)
0.01 0.1 1105
106
107
108
109
1010
1011
q (angstroms-1)
HN5KCl fit
I (a.
u)
48
Figure S.I.140. SAXS data obtained for HN5KNO3 (black dots), and fit curve obtained on SASFit for a model of a monodisperse flat cylinder with 9.5 nm radius, 0.9 nm width and a mass fractal structure with D=2.1 (blue line).
Figure S.I.141. SAXS data obtained for HN5MgSO4 (black dots), and fit curve obtained on SASFit for a model of a monodisperse flat cylinder with 9.5 nm radius, 0.9 nm width and a mass fractal structure with D=2.8 (blue line).
Figure S.I.142. SAXS data obtained for HN5Ba(NO3)2 (black dots), and fit curve obtained on SASFit for a model of a monodisperse flat cylinder with 9.5 nm radius, 0.9 nm width and a mass fractal structure with D=2.6 (blue line).
0.01 0.1 1105
106
107
108
109
1010
1011
q (angstroms-1)
HN5KNO3
fit
I (
a.u)
0.01 0.1 1105
106
107
108
109
1010
1011
q (angstroms-1)
HN5MgSO4
fit
I (a.
u)
0.01 0.1 1105
106
107
108
109
1010
1011
q (angstroms-1)
HN5Ba(NO3)2
fit
I (a.
u)
49
Figure S.I.143. SAXS data obtained for HN5Sr(NO3)2 (black dots), and fit curve obtained on SASFit for a model of a monodisperse flat cylinder with 9.5 nm radius, 0.9 nm width and a mass fractal structure with D=2.7 (blue line).
Figure S.I.144. SAXS data obtained for HN5CuSO4 (black dots), and fit curve obtained on SASFit for a model of a monodisperse flat cylinder with 9.5 nm radius, 0.9 nm width and a mass fractal structure with D=3.2 (blue line).
Figure S.I.145. SAXS data obtained for HN5ZnSO4 (black dots), and fit curve obtained on SASFit for a model of a monodisperse flat cylinder with 9.5 nm radius, 0.9 nm width and a mass fractal structure with D=3.1 (blue line).
0.01 0.1 1105
106
107
108
109
1010
1011
q (angstroms-1)
HN5Sr(NO3)2
fit
I (
a.u)
0.01 0.1 1105
106
107
108
109
1010
1011
q (angstroms-1)
HN5CuSO4
fit
I (a.
u)
0.01 0.1 1105
106
107
108
109
1010
1011
q (angstroms-1)
HN5ZnSO4
fit
I (a.
u)
50
Figure S.I.146. SAXS data obtained for HN5Ca(NO3)4 (in blue), and fit curve obtained on SASFit for a model of a monodisperse flat cylinder with 9.5 nm radius, 0.9 nm width and a mass fractal structure with D=3.31.
Figure S.I.147. SAXS data obtained for HN5Al2(SO4)3 (in blue), and fit curve obtained on SASFit for a model of a monodisperse flat cylinder with 9.5 nm radius, 0.9 nm width and a mass fractal structure with D=3.0.
Figure S.I.148. SAXS data obtained for HN5CeCl3 (in blue), and fit curve obtained on SASFit for a model of a monodisperse flat cylinder with 9.5 nm radius, 0.9 nm width and a mass fractal structure with D=2.8.
0.01 0.1 1105
106
107
108
109
1010
1011
q (angstroms-1)
HN5Ca(NO3)2
fit
I (
a.u)
0.01 0.1 1105
106
107
108
109
1010
1011
q (angstroms-1)
HN5Al2(SO4)3
fit
I (a.
u)
0.01 0.1 1105
106
107
108
109
1010
1011
q (angstroms-1)
HN5CeCl3 fit
I (a.
u)
