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International Molybdenum Association Rue Père Eudore Devroye 245 · 1150 Brussels · Belgium Tel: +32 2 770 8878 · Fax: + 32 2 770 8898 e-mail: [email protected] · www.imoa.info Selecting Stainless Steel for Optimum Performance Sponsor: International Molybdenum Association (IMOA)

Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

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Page 1: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

International Molybdenum AssociationRue Père Eudore Devroye 245 · 1150 Brussels · BelgiumTel: +32 2 770 8878 · Fax: + 32 2 770 8898e-mail: [email protected] · www.imoa.info

Selecting Stainless Steel forOptimum PerformanceSponsor:International MolybdenumAssociation (IMOA)

Page 2: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

2

• Evaluate the environment• Select the right finish and design• Specify the right stainless steel

Learn why some stainless steel applications look fantastic after80 years while others look bad after 6 months

Achieve Long Term Success

Today’s Goal

Page 3: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

3

Learning ObjectivesAttendees will learn to:

• Evaluate the corrosiveness of the application environmentbased on weather patterns and exposure to corrosivepollution, salt (chlorides), and other factors

• Compare the probable relative performance of architecturalmetals based on the service environment

• Determine which finish options and design will provide thedesired level of performance

• Select the right stainless steel for maximum performancegiven the environment, finish, and design

Page 4: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

4

DisclaimerThe International Molybdenum Association (IMOA) hasmade every effort to ensure that the information in thispresentation is technically correct. However, IMOA doesnot represent or warrant the accuracy of the informationcontained in the presentation, supporting literature orsoftware or its suitability for any general or specific use.

The viewer is advised that the material contained hereinis for information purposes only; it should not be used orrelied upon for any specific or general application withoutfirst obtaining competent advice. IMOA, its members andconsultants specifically disclaim any and all liability orresponsibility of any kind for loss, damage, or injuryresulting from the use of the information contained in thispresentation and the supporting literature and software.

Page 5: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

5 < 11% Chromium

Carbon Steel

Rust

Stainless Steel

> 11% Chromium

Passive Film

How Does A Stainless Steel Work?Stainless steel is iron plus at least 11% chromium. If enoughchromium is added, a protective passive film will form.

Page 6: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

6

Major Alloying Elements• Iron (Fe)• Chromium (Cr)

• Improves corrosion resistance• Molybdenum (Mo)

• Improves resistance to pitting and crevice corrosioncaused by salt (chlorides) and pollution

• Nickel (Ni)• Improves ductility, toughness, and weldability

• Nitrogen (N)• Improves strength and pitting and crevice corrosion resistance

Page 7: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

7

Families of Stainless Steels• Austenitic

• 300-series (304, 316)• Strengthened by cold work• Nonmagnetic

• Ferritic• 400-series (430, 447)• Magnetic

• Duplex• Austenitic/ferritic (2205)• More corrosion resistant• Higher strength• Magnetic

Page 8: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

8

Low Carbon or “L” Grades• “L” refers to low carbon levels

• Examples: 304L and 316L• Specify “low carbon” for welding• When there is no price premium for low carbon

stainless steel, make it your standard specification

Page 9: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

9

Architectural Stainless Steels(Nominal Chemical Composition, Wt. Pct.)

0.030.15352222050.080.06211173160.080.06---9183040.120.03------17430

C, maxNMoNiCr

Page 10: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

10

0

5

10

15

20

25

30

35

40

45

50

430 316/316L 317L 317LMN 447 6% Mo

Index of Relative Pitting Corrosion ResistanceIn

crea

sing

Corro

sion

Resis

tanc

e

430 304/304L

316/316L

444 317L 2205 317LMN 904L 447 2507 6% Mo

Page 11: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

11

Strength Comparison

Zinc AA 3003 Copper 304/316 SS

Carbonsteel

Structuralsteel

Structuralsteel

HSLAsteel

2205 SS

Page 12: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

12

Phot

os c

ourte

sy o

f Alle

ghen

y Lu

dlum

and

TM

R Co

nsul

ting

Annual Cost ofMetallic Corrosion(US$ billions)

• Total US Cost• Direct cost = $296• Indirect cost = $255.4• Total cost = $551.4

• Construction*• Direct cost = $50• Indirect cost = $63.6• Total cost = $113.6• Avoidable = 20 to 25%

* May be underestimated.Does not include infrastructureand industrial construction

Page 13: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

13

• Functioning pier• Built about 60 years ago

(1937-1941)• Stainless rebar

• Non-functioning pier• Built about 30 years ago• Carbon steel rebar

Photo courtesy of the Nickel Institute

Two Piers, Progreso, Mexico

Page 14: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

14

* Low pollution, ** Moderate pollutionNational Building Research Institute, South Africa

0.005590.0090.040.025Copper0.00330.023NA0.111Zinc0.02290.2121.150.810Weathering Steel0.04320.3710.8462.190Mild Steel

0.000280.0050.0050.019Al 30030.000030.00040.00060.002Type 4300.000030.000080.00010.0004Type 3040.000030.000030.00010.0003Type 316

Rural*Marine**Severe Marine*

Severe Marine**

Metal

20-Year South African Exposure DataAverage Annual Corrosion Rate (mm/yr)

Page 15: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

15

Type 304 Type 316Ph

otos

cou

rtesy

of T

MR

Cons

ultin

g

Kure Beach, 57 Years250 m (800 ft) from the ocean never washed

Page 16: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

16

Phot

o co

urte

sy o

f the

Nick

el In

stitu

te

Kure Beach, 48 yearsCarbon steel with 60 Zn, 20 Al, 20 Mg coating 250 m (800 ft) from the ocean

Page 17: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

17

Phot

o co

urte

sy o

f the

Nick

el In

stitu

te

Kure Beach, 58 yearsAnodized aluminum, 250 m (800 ft) from the ocean

Page 18: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

18Gateway Arch, St. Louis, USA

Phot

o co

urte

sy o

f the

US

Natio

nal P

arks

Ser

vice

Select Type 304• Rural/suburban• Urban areas

• Low and moderate corrosivity• Not suitable for salt exposure

or moderate to high industrialpollution unless:

• Smooth finish• Regular cleaning• Some staining between

cleanings is acceptable

Page 19: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

19

Frederick R. WeissmanArt Museum

Phot

os c

ourte

sy o

f the

Nick

el In

stitu

te

Select Type 316• Urban areas

• Moderate and high corrosivity• Industrial

• Low and moderate corrosivity• Marine and deicing salt

• Low to moderate corrosivity

Page 20: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

20

Type 316 railingsHong Kong Convention Center -seawater spray exposure, rough finish

Phot

o co

urte

sy o

f the

Nick

el In

stitu

te• Industrial pollution• Developing countries• High sulfur dioxides levels• High particulate levels

• Coastal or deicing salt• Splashed by or immersed in salt

water• Corrosive, sheltered, unwashed

applications• Significant deicing salt deposits

Select MoreCorrosion ResistantStainless Steels

Page 21: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

21

Site and Design Evaluation System• Designed for applications where

corrosion staining is not acceptable

• Do not use this system if• Appearance does not matter• Structural integrity is the primary concern

Page 22: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

22

Stainless Steel Selection Scoring System

A more corrosion resistant stainless steel such as 2205,317LMN, 904L, super duplex, super ferritic, or a 6%molybdenum super austenitic stainless steel may beneeded

≥5

Type 317L or a more corrosion resistant stainless steel issuggested

4

Type 316/316L or 444 is generally the most economicalchoice

3

Type 303/304L is generally the most economical choice0 to 2Stainless Steel SelectionTotal Score

Page 23: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

23

* Potentially a highly corrosive location. Have a stainless steelcorrosion expert evaluate the site.

Environmental PollutionSection 1: Environment (Select the highest applicable score)Rural

Industrial Pollution (Aggressive gases, iron oxides, chemicals, etc.)

Urban Pollution (Light industry, automotive exhaust)

Low or moderate

Points

High *4

3

High *3Moderate2Low0

Very low or no pollution0

Page 24: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

24

ModerateHigh

ModerateHigh

ModerateLowHighHigh

PollutionLevel

1435Chicago129139Rio de Janeiro2627New York

109100Moscow1640Pittsburgh59Stockholm49375Calcutta90377Beijing

Sulfur Dioxideµgm/m3

SuspendedParticulate µgm/m3City

1995 Urban Pollution Levels, World Health Organization Data

Rating Pollution Levels

Page 25: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

25

Page 26: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

26

European Acid Rain Map

Dow

nloa

ded

from

http

://w

ww

.grid

a.no

/db/

map

s/pr

od/le

vel3

/id_1

177.

htm

Page 27: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

27Chicago,Type 316

Pittsburgh,Type 304

Evaluation ScoresCase Study 01

22EnvironmentPittsburghChicagoSection

Phot

os c

ourte

sy o

f TM

R Co

nsul

ting

Page 28: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

28

Weisman Art Museum, Type 316

Window frame,Type 304

Evaluation ScoreCase Study 02

22EnvironmentWindowMuseumSection

Phot

os c

ourte

sy o

f the

Nick

el In

stitu

te

Page 29: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

29Jones Beach

light poles, Type 316

Miami Beachlight pole, Type 304

Evaluation ScoresCase Study 03

22Environment

JonesBeach

MiamiBeach

Section

Phot

o co

urte

sy o

f AIS

IPh

oto

cour

tesy

of T

MR

Cons

ultin

g

Page 30: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

30Singapore Turf Club,

Type 316 roof

Evaluation ScoresCase Study 04

2EnvironmentSingaporeSection

Phot

os c

ourte

sy o

f Ewi

ng C

ole,

Pho

togr

aphe

r: Er

hard

Pfe

iffer

Page 31: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

31Hong Kong

Convention Centerrailings, Type 316

Cheung Kong Center,Type 316

Evaluation ScoresCase Study 05

33Environment

RailingsCheungKong

Section

Phot

o co

urte

sy o

f Nick

el In

stitu

te

Phot

o co

urte

sy o

f Out

okum

pu

Page 32: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

32Canary Island railing,

2205 stainless steel

Canary Islandlight pole,Type 316

Evaluation ScoreCase Study 06

0Environment

Canary IslandsSection

Phot

os c

ourte

sy o

f Out

okum

pu

Page 33: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

33Mapfre Office Tower,Barcelona, Type 316

Evaluation ScoreCase Study 07

2EnvironmentMapfre TowerSection

Phot

o co

urte

sy o

f ACE

RINO

X

Page 34: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

34Bank Boston, São Paulo,

Brazil, Type 316

Evaluation ScoreCase Study 08

4EnvironmentBank BostonSection

Phot

o co

urte

sy o

f Núc

leo

Inox

Page 35: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

35Australian Coastal fence,

Type 316 gate and Type 304 post

Evaluation ScoresCase Study 09

00EnvironmentGatePostSection

Phot

o co

urte

sy o

f the

Aus

tralia

n St

ainl

ess

Stee

l Dev

elop

men

t Ass

ocia

tion

Page 36: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

36

Gantry Plaza Park Railings and

Seating New York City

Type 316

Evaluation ScoreCase Study 10

00Environment

NonSplashedSplashedSection

Page 37: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

37Thames River Barrier, London,

England, Type 316

Evaluation ScoreCase Study 11

0Environment

Thames RiverBarrierSection

Page 38: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

38

Section 2: Coastal Exposure (Select the highest applicable score) If there is exposure to both coastal and deicing salt, obtain assistancefrom a stainless steel corrosion expertCoastal or Marine Salt Exposure

Points

Severe Marine (Continuous immersion) *10Severe Marine (Continuous splashing) *8Marine (Some salt spray or occasional splashing) *5High (< 30 m (100 ft) from salt water)4Moderate (30 m to 1.6 km (100 ft to 1 mile) from salt water)3Low (> 1.6 to 16 km (1 to 10 miles) from salt water) **1

* Potentially a highly corrosive location. Have a stainless steel corrosion expert evaluatethe site.

**This range shows how far chlorides are typically found from large salt water bodies.Some locations of this type are exposed to chlorides but others are not.

Coastal or Deicing Salt Exposure

Page 39: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

39

Section 2: Deicing Salt (Chloride) Exposure (Select the highestapplicable score). If there is exposure to both coastal and deicing salt,obtain assistance from a stainless steel corrosion expertDeicing Salt Exposure (Distance from road or ground)

Points

High salt exposure (< 2 to 50 m (6.5 to 164 ft) or 1 to 3 floors) * **4Moderate salt exposure (< 3 to 100 m (10 to 328 ft) or 1 to 22 floors) **3Low salt exposure (< 10 to 500 m (33 to 1600 ft) or 2 to 34 floors) **2

Very low salt exposure (≥10 m to 1 km (33 to 3,280 ft) or 3 to 60 floors)**1

Traffic and wind levels on nearby roads are too low to carry chlorides tothe site and no deicing salt is used on sidewalks0

No salt was detected on a sample from the site and no change inexposure conditions is expected.0

* Potentially a highly corrosive location. Have a stainless steel corrosion expertevaluate the site.

** The range shows how far this chloride concentration has been found from smallrural and large high traffic roads. Test surface chloride concentrations.

Page 40: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

40

Australian Chloride Deposition Map

Salt Deposition Rategrams/sq. meter/day

4 or more321.51

0 1000

Kilometers

Dow

nloa

ded

from

the

CS

IRO

web

site

http

://w

ww

.cm

it.cs

iro.a

u

Page 41: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

41

Salt (Chloride) Concentration in the Air

Page 42: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

42

Salt (Chloride) Concentration in the Rain

Page 43: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

43

Section 3: Local Weather Pattern (Select only one)

Hot, humidity above 50%, very low or no rainfall ***2Regular very light rain or frequent fog1Temperate climate, infrequent rain, humidity above 50%1

Tropical or subtropical, wet, regular or seasonal very heavyrain0

Temperate or cold climate, occasional heavy rain0Hot or cold climates with typical humidity below 50%-1

-1Points

Temperate or cold climates, regular heavy rain

Local Weather Patterns

*** If there is also salt or pollution exposure, have a stainless steelcorrosion expert evaluate the site.

Page 44: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

44

Critical Temperature/Humidity Combinationsfor Salt (Chloride) Corrosion

5045---0 (32)50417610 (50)50307625 (77)

Temperature °C (°F)Critical

SodiumChloride

Critical Humidity Level, %CalciumChloride

MagnesiumChloride

Page 45: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

45

United States and Canadian Corrosion Map

The

Cat

alys

t, Is

sue

No.

2, 1

997,

AR

MC

O In

c.

Page 46: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

46

Extremely severe

Severe

Moderate

Mild

Negligible

Corrosion Map for Mexico

Map downloaded from http://www.corrosion-doctors.org

Page 47: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

47

Extremely severe

Severe

Moderate

Mild

Negligible

Corrosion Map for Central America

Map downloaded from http://www.corrosion-doctors.org

Page 48: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

48

Extremely severe

Severe

Moderate

Mild

Negligible

Corrosion Map for Cuba

Map downloaded from http://www.corrosion-doctors.org

Page 49: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

49

Extremely severe

Severe

Moderate

Mild

Negligible

Corrosion Map for Venezuela

Map downloaded from http://www.corrosion-doctors.org

Page 50: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

50

Extremely severe

Severe

Moderate

Mild

Negligible

Brazilian Corrosion Map

Map

dow

nloa

ded

from

http

://w

ww

.cor

rosi

on-d

octo

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Page 51: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

51

Extremely severe

Severe

Moderate

Mild

Negligible

Corrosion Map for Argentina

Map

dow

nloa

ded

from

http

://w

ww

.cor

rosi

on-d

octo

rs.o

rg

Page 52: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

52

Extremely severe

Severe

Moderate

Mild

Negligible

Corrosion Map for Chile

Map

dow

nloa

ded

from

http

://w

ww

.cor

rosi

on-d

octo

rs.o

rg

Page 53: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

53

Extremely severe

Severe

Moderate

Mild

Negligible

Corrosion Map for Columbia

Map

dow

nloa

ded

from

http

://w

ww

.cor

rosi

on-d

octo

rs.o

rg

Page 54: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

54

Extremely severe

Severe

Moderate

Mild

Negligible

Corrosion Map for China

Map

dow

nloa

ded

from

http

://w

ww

.cor

rosi

on-d

octo

rs.o

rg

Page 55: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

55

Extremely severe

Severe

Moderate

Mild

Negligible

Corrosion Map for JapanM

ap d

ownl

oade

d fro

m h

ttp://

ww

w.c

orro

sion

-doc

tors

.org

Page 56: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

56

Extremely severe

Severe

Moderate

Mild

Negligible

Corrosion Map for IndiaM

ap d

ownl

oade

d fro

m h

ttp://

ww

w.c

orro

sion

-doc

tors

.org

Page 57: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

57

Extremely severe

Severe

Moderate

Mild

Negligible

Corrosion Map for New ZealandM

ap d

ownl

oade

d fro

m h

ttp://

ww

w.c

orro

sion

-doc

tors

.org

Page 58: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

58

Extremely severe

Severe

Moderate

Mild

Negligible

Corrosion Map for PortugalM

ap d

ownl

oade

d fro

m h

ttp://

ww

w.c

orro

sion

-doc

tors

.org

Page 59: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

59

Extremely severe

Severe

Moderate

Mild

Negligible

Corrosion Map for SpainM

ap d

ownl

oade

d fro

m h

ttp://

ww

w.c

orro

sion

-doc

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.org

Page 60: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

60

Extremely severe

Severe

Moderate

Mild

Negligible

Corrosion Map for Great Britain

Map

dow

nloa

ded

from

http

://w

ww

.cor

rosi

on-d

octo

rs.o

rg

Page 61: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

61

Extremely severe

Severe

Moderate

Mild

Negligible

Corrosion Map for South AfricaM

ap d

ownl

oade

d fro

m h

ttp://

ww

w.c

orro

sion

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.org

Page 62: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

62

Truck on elevated highway

Phot

os c

ourte

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f Nick

el In

stitu

te

Type 304 Stainless Steel Arbor• Deicing salt exposure• Rough, sand blasted finish• Sculpture park• Minneapolis, USA

Page 63: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

63

Type304

Type316

Phot

os c

ourte

sy o

f Aus

tral W

right

Met

als

Coastal Applications

Page 64: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

64

Type 316 roof2D finishCurved 400 meterlong building andwalkway canopiesStanding seam roofModular design keptcosts down

Photo courtesy of Ewing Cole

Singapore Turf ClubArchitect: Ewing Cole

Page 65: Selecting Stainless Steel for Optimum · PDF file2 •Evaluate the environment •Select the right finish and design •Specify the right stainless steel Learn why some stainless

65Chicago,Type 316

Pittsburgh,Type 304

Evaluation ScoresCase Study 01

-1-1Weather23 or 4Deicing salt22Environment

PittsburghChicagoSection

Phot

os c

ourte

sy o

f TM

R Co

nsul

ting

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66

Weisman Art Museum, Type 316

Window frame,Type 304

Evaluation ScoresCase Study 02

-1-1Weather33Deicing salt22Environment

WindowMuseumSection

Phot

os c

ourte

sy o

f the

Nick

el In

stitu

te

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67Jones Beach

light poles, Type 316

Miami Beachlight pole, Type 304

Evaluation ScoresCase Study 03

-11Weather33Coastal salt22Environment

JonesBeach

MiamiBeach

Section

Phot

o co

urte

sy o

f AIS

IPh

oto

cour

tesy

of T

MR

Cons

ultin

g

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68Singapore Turf Club,

Type 316 roof

Evaluation ScoreCase Study 04

-1Weather3Coastal salt2Environment

SingaporeSection

Phot

os c

ourte

sy o

f Ewi

ng C

ole,

Pho

togr

aphe

r: Er

hard

Pfe

iffer

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69Hong Kong

Convention Centerrailings, Type 316

Cheung Kong Center,Type 316

Evaluation ScoresCase Study 05

00Weather53Coastal salt33Environment

RailingsCheungKong

Section

Phot

o co

urte

sy o

f Nick

el In

stitu

te

Phot

o co

urte

sy o

f Out

okum

pu

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70Canary Island railing,

2205 stainless steel

Canary Islandlight pole,Type 316

Evaluation ScoreCase Study 06

1Weather3 to 5Coastal salt

0EnvironmentCanary IslandsSection

Phot

os c

ourte

sy o

f Out

okum

pu

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71Mapfre Office Tower,Barcelona, Type 316

Evaluation ScoreCase Study 07

1Weather3Coastal salt2Environment

Mapfre TowerSection

Phot

o co

urte

sy o

f ACE

RINO

X

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72Bank Boston, São Paulo,

Brazil, Type 316

Evaluation ScoreCase Study 08

1Weather0Coastal salt4Environment

Bank BostonSection

Phot

o co

urte

sy o

f Núc

leo

Inox

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73Australian Coastal fence,

Type 316 gate and Type 304 post

Evaluation ScoresCase Study 09

00Weather44Coastal salt00Environment

GatePostSection

Phot

o co

urte

sy o

f the

Aus

tralia

n St

ainl

ess

Stee

l Dev

elop

men

t Ass

ocia

tion

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74

Gantry Plaza Park Railings and

Seating New York City

Type 316

Evaluation ScoreCase Study 10

-1-1Weather37Coastal salt00Environment

NonSplashedSplashedSection

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75Thames River Barrier, London,

England, Type 316

Evaluation ScoreCase Study 11

0Weather5Coastal salt0Environment

Thames RiverBarrierSection

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76

Section 4: Design Considerations (Select all that apply)

Horizontal finish grain orientation1Horizontal surfaces1Sheltered location or unsealed crevices***1Surface finish roughness > Ra 1 µm (40 µin)2Surface finish roughness Ra 0.5 µm (20 µin) < X ≤ Ra 1 µm (40 µin)1Surface finish roughness Ra 0.3 µm (12 µin) < X ≤ Ra 0.5 µm (20 µin)-1

Surface finish is pickled, electropolished, or roughness ≤ Ra 0.3 µm (12µin)-2

Vertical surfaces with a vertical or no finish grain0

0Points

Boldly exposed for easy rain cleaning

Design Considerations

*** If there is also salt or pollution exposure, have a stainless steelcorrosion expert evaluate the site.

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77

Ra 0.5 micronsor 20 micro-inches

Incr

easin

g Co

rrosio

n Ra

te

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78

Photo courtesy of Austral Wright

Type 316 railings beside a beach

0.74 µm

2.1 µm

Specifying thesurface roughnessis as important asselecting the rightstainless steel.

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79

No. 4 Finish, DryPolished, AluminumOxide Abrasive

Ra 0.7 microns

No. 4 Finish, WetPolished, SiliconCarbide Abrasive

> Ra 0.3 microns

Phot

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sy o

f Out

okum

pu

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80

Typical Sheet Surface Roughness Range

0.01 -0.02

0.4 -0.8

SuperNo. 8

0.02-0.10

0.8 -4

No. 8

0.06- 0.2

2.4 -8

No. 7

0.14 -0.2

5.5 -8.0

Hair-line

0.18-0.64

7 -25

No. 4

0.25 -1.1

10 -43

No. 3

0.01 -0.10

0.5 -4

BA

0.06- 0.5

2.4 -20

2B

0.13-1.0

5 -39

2D

RaMicron

RaMicro-inch

Finish

Based on a Nickel Institute survey of North American and European suppliers whichdetermined the surface roughness range that might be typically supplied for eachfinish. The surface roughness range will vary with thickness.

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81

Tighten Specifications• Flatness

• Require stretcher or tension leveling• Chemistry

• Sulfur ≤ 0.005 for exterior and swimming pool applications• Iron Contamination

• Require iron free certification in compliance with ASTM A 380• Exterior and Swimming Pool Finishes

• Surface roughness ≤ Ra 20 micro-inches

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82 Wall

Roof

Eave

45°

15 to 60°

Chloride Accumulation In Sheltered Locations

Chlo

rides

oz/

inch

2

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83

Phot

os c

ourte

sy o

f JSS

A an

d AS

SDA

Sheltered ComponentsIncreased corrosion risk

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84

Avoid Use

If the design will be exposed to salt (chlorides) and moisture,avoid crevices or seal them to prevent corrosion

Phot

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stitu

te

Sites for Crevice Corrosion

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85

Photo courtesy of Nickel Institute

Type 316 Light Fixture

• Highly polished light fixture• Unsealed crevices accumulated

salt and water causing corrosion• Eliminate corrosion by cleaning

the fixture and sealing thecrevices

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86

Phot

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Peeling coatingCrevice

• Coatings are not necessary, require regular replacement,and can cause corrosion

• Using the right stainless steel is more cost effective

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87

Galvanic Corrosion Requires...• Dissimilar metals• Electrical connection between metals

(i.e., metal-to-metal contact)• Moisture is present and connects the metals

Solution• Prevent direct metal to metal contact

• Inert washers• Paint• Other non-conducting barriers

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88

Galvanic SeriesMetals and Alloys in Sea Water

MagnesiumZincAluminum AlloysMild SteelLow Alloy SteelCast IronMuntz MetalYellow BrassRed BrasscopperAluminum BronzeSilverStainless SteelMonelGold

AnodicMore Likely tocorrode

More NobleCathodic

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89

Phot

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• Stainless steel fasteners in carbonsteel cover

• Good ratio = no impact on corrosion rate• Galvanized fasteners in stainless

steel• Bad ratio = rapid corrosion

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90Chicago,Type 316

Pittsburgh,Type 304

Evaluation ScoresCase Study 01

-1-1Weather2-1 to -2Design

23 or 4Deicing salt22Environment

PittsburghChicagoSection

Phot

os c

ourte

sy o

f TM

R Co

nsul

ting

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91

Frederick R. Weisman Art Museum,Type 316

Window frame,Type 304

Evaluation ScoresCase Study 02

-1-1Weather0-1Design

33Deicing salt22Environment

WindowMuseumSection

Phot

os c

ourte

sy o

f the

Nick

el In

stitu

te

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92Jones Beach

light poles, Type 316

Miami Beachlight pole, Type 304

Evaluation ScoresCase Study 03

-11Weather-13Design

33Coastal salt22Environment

JonesBeach

MiamiBeach

Section

Phot

o co

urte

sy o

f AIS

IPh

oto

cour

tesy

of T

MR

Cons

ultin

g

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93Singapore Turf Club,

Type 316 roof

Evaluation ScoreCase Study 04

-1Weather-1Design

3Coastal salt2Environment

SingaporeSection

Phot

os c

ourte

sy o

f Ewi

ng C

ole,

Pho

togr

aphe

r: Er

hard

Pfe

iffer

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94Hong Kong

Convention Centerrailings, Type 316

Cheung Kong Center,Type 316

Evaluation ScoresCase Study 05

00Weather2-1 or -2Design

53Coastal salt33Environment

RailingsCheungKong

Section

Phot

o co

urte

sy o

f Nick

el In

stitu

te

Phot

o co

urte

sy o

f Out

okum

pu

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95Canary Island railing,

2205 stainless steel

Canary Islandlight pole,Type 316

Evaluation ScoreCase Study 06

1Weather-1 or -2Design

3 to 5Coastal salt0Environment

Canary IslandsSection

Phot

os c

ourte

sy o

f Out

okum

pu

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96Mapfre Office Tower,Barcelona, Type 316

Evaluation ScoreCase Study 07

1Weather0Design

3Coastal salt2Environment

Mapfre TowerSection

Phot

o co

urte

sy o

f ACE

RINO

X

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97Bank Boston, São Paulo,

Brazil, Type 316

Evaluation ScoreCase Study 08

1Weather-1Design

0Coastal salt4Environment

Bank BostonSection

Phot

o co

urte

sy o

f Núc

leo

Inox

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98Australian Coastal fence,

Type 316 gate and Type 304 post

Evaluation ScoresCase Study 09

00Weather-12Design

44Coastal salt00Environment

GatePostSection

Phot

o co

urte

sy o

f the

Aus

tralia

n St

ainl

ess

Stee

l Dev

elop

men

t Ass

ocia

tion

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99

Gantry Plaza Park Railings and

Seating New York City

Type 316

Evaluation ScoreCase Study 10

-1-1Weather11Design

37Coastal salt00Environment

NonSplashedSplashedSection

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100Thames River Barrier, London,

England, Type 316

Evaluation ScoreCase Study 11

0Weather-2Design

5Coastal salt0Environment

Thames RiverBarrierSection

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101

Maintenance Schedule

Section 5: Maintenance Schedule (Select only one)

Washed at least monthly-3Washed four or more times per year-2Washed at least annually-1

0Points

Not washed

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102

Standard Cleaning• Rain• Hot water power wash• Mild chloride-free detergent• Degreaser

• 5% ammonia and water (window cleaners)• Alcohol• Vinegar and water• Citrus cleaner

• 200 mesh or finer calcium carbonate abrasive(except on colored or mirror-like finishes)

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103

150 East 42nd Street, New York CityCleaned for the first time after 30 years of service

Phot

o co

urte

sy o

f Alle

ghen

y Lu

dlum

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104

Before

After Phot

os c

ourte

sy o

f IKM

and

Nick

el In

stitu

te

Reusing Stainless Steel

• Stainless entrance/lobby• Lobby renovation in 2002• Most of the stainless steel

was refinished and reused• Architect IKM

525 William Penn PlacePittsburgh, PennsylvaniaCompleted in 1952

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105

Remedial Cleaning• Adhesives

• Alcohol, citric cleaner or other solvent recommended by adhesivesupplier

• Paint and marker pens• Solvents or chemical paint remover and soft brush

• Cement or mortar• Rinse off with water while still wet• If it has dried, use power washing and if necessary abrasives

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106

Phot

o co

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el In

stitu

te

Embedded Iron Corrosion• Remove by

• Mechanical cleaning• Chemical cleaning

(“Passivation”)• Confirm cleaning by test to

• ASTM A 967, ChemicalPassivation Treatments forStainless Steel Parts

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107

Phot

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el In

stitu

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Muriatic Acid Corrosion• Tile, stone, masonry or concrete

are sometimes cleaned withMuriatic (hydrochloric) acid

• Muriatic acid is very corrosive tostainless steel!

• Avoid Muriatic acid containingcleaners

• Use citric acid or other non-corrosive cleaners

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108

Phot

o co

urte

sy o

f ASS

DA

Removing WeldingHeat Tint

• Mechanical methods• Grinding• Abrasive blasting

• Chemical methods• Pickle paste• Pickling

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109

Evaluation ScoresCase Study 01

0-1Maintenance53Total

-1-1Weather2-1 to -2Design

23 or 4Deicing salt22Environment

PittsburghChicagoSection

A more corrosionresistant stainless steelsuch as 2205, 904L,317LMN, super duplex,super ferritic or a 6%molybdenum superaustenitic stainless steelmay be needed

≥ 5

Type 316/316L or 444 isgenerally the mosteconomical choice

3

Stainless SteelSelection

TotalScore

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110

Evaluation ScoresCase Study 02

00Maintenance43Total

-1-1Weather0-1Design

33Deicing salt22Environment

WindowMuseumSection

Type 317L or a morecorrosion resistantstainless steel issuggested

4

Type 316/316L or 444 isgenerally the mosteconomical choice

3

Stainless SteelSelection

TotalScore

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111

Evaluation ScoresCase Study 03

00Maintenance39Total

-11Weather-13Design

33Coastal salt22Environment

JonesBeach

MiamiBeach

Section

A more corrosionresistant stainless steelsuch as 2205, 904L,317LMN, super duplex,super ferritic or a 6%molybdenum superaustenitic stainless steelmay be needed

≥ 5

Type 316/316L or 444 isgenerally the mosteconomical choice

3

Stainless SteelSelection

TotalScore

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112

Evaluation ScoreCase Study 04

0Maintenance3Total

-1Weather-1Design

3Coastal salt2Environment

SingaporeSectionType 316/316L or 444 isgenerally the mosteconomical choice

3

Stainless SteelSelection

TotalScore

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113

Evaluation ScoresCase Study 05

-3-2Maintenance72 or 3Total

00Weather2-1 or -2Design

53Coastal salt33Environment

RailingsCheungKong

Section

Type 316/316L or 444 isgenerally the mosteconomical choice

3

A more corrosion resistantstainless steel such as2205, 904L, 317LMN,super duplex, super ferriticor a 6% molybdenum superaustenitic stainless steelmay be needed

≥ 5

Type 304/304L is generallythe most cost-effectivechoice

2

Stainless SteelSelection

TotalScore

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114

Evaluation ScoreCase Study 06

0Maintenance3 to 5Total

1Weather-1 or -2Design

3 to 5Coastal salt0Environment

CanaryIslandsSection

A more corrosion resistantstainless steel such as 2205,904L, 317LMN, super duplex,super ferritic or a 6%molybdenum super austeniticstainless steel may be needed

≥ 5

Type 316/316L or 444 is generallythe most economical choice

3Stainless Steel Selection

TotalScore

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115

Evaluation ScoreCase Study 07

-3Maintenance3Total

1Weather0Design

3Coastal salt2Environment

Mapfre TowerSectionType 316/316L or 444 isgenerally the mosteconomical choice

3

Stainless SteelSelection

TotalScore

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116

Evaluation ScoreCase Study 08

-2Maintenance2Total

1Weather-1Design

0Coastal salt4Environment

Bank BostonSectionType 304/304L is generallythe most cost-effectivechoice

2

Stainless SteelSelection

TotalScore

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117

Evaluation ScoresCase Study 09

00Maintenance36Total

00Weather-12Design

44Coastal salt00Environment

GatePostSection

A more corrosion resistantstainless steel such as 2205,904L, 317LMN, super duplex,super ferritic or a 6%molybdenum super austeniticstainless steel may be needed

≥ 5

Type 316/316L or 444 isgenerally the most economicalchoice

3

Stainless Steel SelectionTotalScore

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118

Evaluation ScoreCase Study 10

00Maintenance37Total

-1-1Weather11Design

37Coastal salt00Environment

NonSplashedSplashedSection

A more corrosion resistantstainless steel such as2205, 904L, 317LMN,super duplex, super ferriticor a 6% molybdenum superaustenitic stainless steelmay be needed

≥ 5

Type 316/316L or 444 isgenerally the mosteconomical choice

3

Stainless Steel SelectionTotalScore

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119

Evaluation ScoreCase Study 11

0Maintenance3Total

0Weather-2Design

5Coastal salt0Environment

Thames RiverBarrierSection Type 316/316L or 444

is generally the mosteconomical choice

3

Stainless SteelSelection

TotalScore

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120

How Can I Reduce the Score?• Design for rain washing• Select smooth surface finishes• Use vertical finish grain orientation• Eliminate sheltered areas and horizontal surfaces• Eliminate or seal crevices• Design to facilitate manual washing• Use natural or artificial barriers to reduce deicing salt

road mist exposure

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121

Conclusions• Carefully evaluate each site and application• If technical questions arise, contact

(insert appropriate organization name)• In more corrosive environments, have a metallurgical engineer

with architecture experience evaluate the site and applications