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Fairmont WV SDG # KR050629

Report To:

Reilly Industries, Inc. 300 N. Meridian Street Suite 1500 Indianapolis, IN 46204-1763

Report By:

META Environmental, Inc. 49 Clarendon Street Watertown, MA 02472

August 27, 2005

ai5 oi' DU>3

Identifying and allocating sources of pollutants In complex environments.

AR119999

Final Laboratory Report

META Environmental, Inc. 49 Clarendon Street Watertown, MA 02472

Phone: 617-923-4662 Fax: 617-923-4610 e-Mail: meta(a),metaenv.com

Certiflcation

This certifies that this package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the coiiditions detailed herein. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Director and Quality Assurance Officer, as verified by the following signatures.

JamesARoush ^ ' ^ ~ Date ^z-^Âs^ Laboratory Manager, META Environmental, Inc.

"^-Y^-V^ , , ^ / David M. Mauro Date ' ' •* President, META Environmental, Inc.

08/27/05 Page 2 KR050629 laboratory report

METAtH^ AR120000

Sample Delivery Group Narrative

Project:

Client:

Fairmont WV

Reilly Industries, Inc.

Report Contact: John Jones

Date of Receipt; 2/05/03,6/26/05

Sample Summary:

The samples received for this project are summarized in the attached sample login forms.

META Project Number: K06001

SDG Numbers: GT030205, KR050629

Cha in of Cus tody

Samples of black semisolid material were received firom Environmeiital Strategies, LLC in good condition. The internal temperatures of the shipment containers were as follows:

Samples received Date:

6/26/05 Temperature °C 15.2

Internal chain of custody procedures were followed after sample receipt. Samples were stored in a locked refrigerator. A sample custody logbook contains the record of sample removal firom the secure sample storage area to the sample preparation laboratory. The custody record for the sample extracts is present on the sample extraction logbook page.

The disposal of samples and extracts will be authorized 1 month after the release of this data report. Sample disposal will be documented.

08/27/05 KR050629 laboratory report

Page 3

META m AR120001

Methods

The samples varied in their properties from free-flowing organic liquids to black semisolid material apparently high in organic content. All samples were treated as organic liquids and prepared by waste dilution with methylene chloride (DCM) using EPA Method 3580.

The sample diluents were spiked v^th surrogate compounds and analyzed by GC/FID (EPA Method 8100M; META SOP No. MET4007) and by GC/MS (EPA Method 8270M; META SOP No. 4008).

A portion of each sample was placed in clean glass jars and sent to Galbraith Laboratories in Knoxville TN for specific gravity (ASTM D1963) and Ultimate and Proximate Analysis (ASTM D3l76mod/ASTM D5142).

Another portion of each sample was placed in clean glass jars and sent to Dr. James Hower and the Center for Applied Energy Research at the University of Kentucky for petrographic analysis using light microscopy.

Results

Sample results were presented in summary forms (CLP Form 1 equivalent) which follow this narrative.

Quality Control

Analyte Flags The reporting limits were determined as the sample equivalent of the lowest linear initial calibration standard. Analytes measured between one half of the lowest standard and the lowest standard were reported as "estimated" and flagged with the letter "J." No value was reported above the calibration range. Undetected analytes were flagged with the letter, "U."

Holding Times The samples were received in two batches. The first batch contained 6 samples of black semisolid material from the Monongahela River received on June 29,2005. Those samples were prepared for GC/FID fingerprint and extended PAH profiles by GC/MS within 14 days of collection. The extracts were analyzed within 40 days of preparation.

There are no holding times for the physical properties tests or the petrographic analysis. 08/27/05 Page 4 KR050629 laboratory report

M E T A J ) ^ AR120002

The second set of samples consisted of crude coal tar and refined tar products received by META in February 2003 from Reilly Industries, Inc. Those samples were stored in secured refirigerators at 4 *'C imtil removed for analysis on 8/2/05.

Blanks Low concentrations of some PAHs were detected in the method blanks. However, the concentrations in the blanks were several orders of magnitude lovver than the native sample concentrations and do not affect the restilts.

Internal Standards All samples were spiked with internal standards prior to instrumental analysis. All internal standard areas met QC criteria.

Surrogate Spikes All samples were spiked with surrogate compoimds toluene-d8, phenanthrene-dlO, and perylene-dl2. When detectable, the surrogate spikes met QC criteria with few exceptions.

Matrix Spikes Due to the very high concentrations of PAHs in the samples, matrix spike samples were not prepared.

References

1. META Environmental, Inc., Laboratory Quality Assurance Plan, January 2003.

2. U.S. EPA, SW-846, Fourth Edition

08/27/05 Page 5 KR050629 laboratory report

METAtH^

AR120003

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META ENVIRONMENTAL SAMPLE RECEIPT

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R050629-01 R050629-02 R050629-03 R050629-(M R050629-05 R050629-06

Hold ID

Sampte 1 Sample 2 Sample 3 Sample 4 Sample 5 Sample 6

Matrix

Soil Soil Boll Soli Soli Soil

Prap Method

2512 2512 2512 2512 2512 2512

Clainup Method Am lysis Method

4007/4008 4007/4008 4007/4008 4007/4008 4007/4008 4007/4008

Oat* Sampled

6/22/2005 8/22/2005

. 8/22/2005 6/22/2005 6/20/2005 6/21/2005

Date Received

6/29/2005 6/29/2005 6/29/2005 6/29/2005 6/29/2005 6/29/2005

Client/ Project

K06001 K06001 K06001 K06001 K06001 K06001

Container/ Storage

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Comments/Looger '

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Date: k j W O ^ Page 1 of 1 0îe:_kI^M-AR120005

CHAIN O F CUSTODY RECORD

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n Minneapolis Omce: 123 North 3rd St, #706, Minneapolis, MN 55401 Tel: (612) 343-0510. Fax: (612)343-0506 AR120006

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META ENVIRONMENTAL SAMPLE RECEIPT

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QT030205-04 'Middle coal tar distillates Tar 2512/4007 GT030205-0S :Heavy oil Tar 2512/4007

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2/5/2003 G13012-60 2/5/2003 G13012-60

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Page l of 1 AR120008

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1 benzene 2 toluene 3 ethylbenzene 4 jn/p-xylene 5 styrene 6 o-xylene 7 1.2,4-trimethylben2ene 8 naphthalene 9 2-methylnaphthalene 10 1-methylnaphthalene 11 Bcenaphthylene 12 acenaphthcne 13 dibenzofiiran 14 tluorene 15 phenanthrene 16 anthracene 17 fluoranOieae 18 pyrene 19 t>enz(a)anthracene 20 chrysene 21 benzo(b)fluonuithene 22 benzo(k)fluoranthene 23 bcnzo(a)pyrene 24 indeno(1^3-«d)pyrcne 25 dibenz(aji)anthracene 26 benzo(gii,i)perylene

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Laboratory ID: KR050629-01/10x

Method: EPA 8100 mod.

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1 benzene 2 toluene 3 ethylbenzene 4 m/p-xylene 5 stymie 6 o-xylene 7 l^,4-trimethylben2ene 8 naphthalene 9 2-methylnaphthaIene 10 l-methybaphthalene 11 acenaphthylene 12 acenaphthene 13 di'benzofuran 14 fluorene 15 phenanthrene 16 anthracene 17 fluoranthene 18 pyrene 19 benz(a)anthracene 20 ctaysiBne 21 beiizo(b)fluoranthene 22 benzp(k)fluoranthene 23 bcnzo(a)pyrene 24 indenp(1^3-cd)pyrene 25 dibenz(aji)anthracene 26 benzo(g,h4)peO''^^

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Method:

Sample 2

KR050629-02/10X

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AR120011

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GC/FD) Fingerprint C071815.D\FID2B 1 benzene

2 toluene 3 ethylbenzene 4 m/p-xylene 5 styrene 6 o-xylene 7 1^,4-trimethylbenzene 8 naphthalene 9 2-methytaaphthalene 10 l-mcthylnsphlhalene 11 acenaphthylene 12 acenaphthene 13 dibenzoiuran 14 fluorene 15 phenanthime. 16 anthracene 17 fluoranthene 18 pyrene 19 bcnz(a)anthr3cene 20 chiysene 21 benzo(b)fluoianthene 22 benzo(]c)fluorai]theiie 23 ben2o(a)pyrene 24 indeno(1^3-cd)pyrene 25 dibenz(aji)anthracene 26 benzo(g4i,i)peiylene

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ISJ - 2,4-difluorotoluene IS2 - o-terphenyl Field ID: Sample 3

Laboratory ID: KR050629-03/1 Ox Method: EPA 8100 mod.

KR030639.ppt M E T A < ^ AR120012

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1 benzene 2 toluene 3 ethylbenzene 4 m/p-xylene 5 styrene 6 o-xylenc 7 1,2,4-trimethyIbenzene 8 naphthalene 9 2-methyhiaphthalene 10 1 -methybiaphthalene 11 acenaphthylene 12 acenaphthene 13 dilienzoiuran 14 fluorene 15 phenanthrene 16 anthracene 17 fluoranthene 18 pyrene 19 benz(a)antlir3cene 20 chrysene 21 benzb(b)fluoranthene 22 benzoOc)fluoranthene 23 benzo{a)pyrene 24 indeno(l,23'Kx])pyrene 25 dibenz(a^)anthiacene 26 benzo(g,h,i)peiylene

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0.00 5.00 10.00 15.00 20.00 25.00 30.00 35.00 40.00 45.00 50.00 55.00 Time (min.)

151 - 2,4-difluorotoluene 152 - o-terphenyl Field ID: Sample 4


KR.0J0629. ppc METAtt^ AR120013

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300000

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260000

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1 benzene 2 toluene 3 ethylbenzene 4 m/p-xylene 5 styrene 6 o-xylene 7 1^,4-triinethyIbenzene 8 naphthalene 9 2-iTiethylnaphthalene 10 1-methylnaphthalene 11 acenaphthylene 12 acenaphthene 13 dibenzofiiran 14 fluorene 15 phenanthrene 16 anthracene 17 fluoranthene 18 pyrene 19 benz(a)anthracene 20 chrysene 21 benzo(b)fluoranthene 22 benzo(k)fluoranthene 23 benzo(a)pyrene 24 indeno(1^3<d)pyrene 25 dib«nz(a^)anthracene 26 ben2o(g,h,i)pcrylene

20:00 25.00 30.00

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ISJ -2,4-difluorotoluene IS2 - o-terphenyl Field ID: Sample 5


KR0iO«29.ppl META ^ AR120014

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1 benzene 2 toluene 3 ethylbenzene 4 m/p-xylene 5 styrene 6 o-xylene 7 1^,4-trimethylbenzene 8 naphthalene 9 2-methylnaphthaIene 10 l-methylnaphthalene 11 acenaphthylene 12 acenaphthene 13 ditjerizofuran 14 fluortne 15 phenanthrene 16 anthracene 17 fluoranthene 18 pyrene 19 benz(a)anthTacene 20 chrysene 21 benzo(b)fluor3nthene 22 benzo(k)fluoranthene 23 benzo(a)pyrene 24 indeno(I^^-cd)pyrene 25 dibenz(aji)anthracene 26 benzo(g,b,i)peiyIene

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151 - 2,4-difluorotoluene 152 - o-terphenyl Field ID: Sample 6

Laboratory ID: KR050629-06/1 Ox

Method: EPA 8100 mod. METAftQ

AR120015

GC/FID Fingerprint

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C080314.D\FID2B - 1 2 3 4 5 6 7 8 9 10

benzene toluene ethylbenzene m/p-xylene styinene o-xylene 1.2,4-trimefhylbenzehe naphthalene 2-methyhiaphthalene 1 -methyinaphfhalene

11 acenaphthylene 12 acenaphthene 13 dibenzofiiran 14 fluorene 15 phenanthrene 16 anthracene 17 fluoranthene 18 pyrene 19 benz(a)anthracene 20 chrysiene 21 benzo(b)fluoranthene 22 benzoOc)fluoninthene 23 bcnzo(a)pyrcne 24 indeno(l^^-cd)pyrene 25 dibenz(aji)snthracene 26 benzo(g,h,i)perylene

5.00 io:oo 15.00 20.00 25.00 30.00 Timfi (min.)

35:00 40.00 45.00 50.00 55.00

151 - 2,4-difluorotoluene 152 — o-terphenyl 551 — 2-fluorobiphenyl 552 — 5a-androstane

Field ID: Coal tar pitch Laboratory ID: GT030205-01

V-Method: EPA 8100 mod.

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benzene toluene ethylbenzene m/p-xylene styrene; o-xyleiie 1 ,4-trimethylbenzene naphthalene 2-methylnaphthalene l-methylnaphthalene acenaphthylene acenaphthene dibenzofiiran fluorene phenanthrene anthracene fluoranthene pyrene benz(a)anthracene chiysene benzo{b)fluoranthene benzo(k)fluorantfaene benzo(a)pyrene indeno^l ;2^-cd)pyrene dibenz(ajh)3nthracene

26 benzo(g.h,i)peiylene

10:00 15:00 20:00 25:00 30:00 35.00 40.00 45.00 50.00 55.00 1 — I — p — I — I — r -

Time (min.) 151 — 2,4-difluorotoluene 152 - o-terphenyl 551 - 2-fluorobiphenyl 552 - 5a-androstane

3T030205.ppl

Field ID: Laboratory ID:

Method: V

Crude coal tar GT030205-02

EPA 8100 mod. y META

AR120017

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benzene toluene ethylbenzene m/p-xylene styrene o-xylene 1,2,4-tn"methylbenzene naphthalene [ 2-methyln8phthalene l-methylnaphthalene acenaphthylene acenaphthene dibenzofiuan fluorene phenanthrene anthracene fluoranthene pyrene benz(a)antlmtcene chrysene berizo(b)fluoranthene benzo(k)fluaranthene benzo(a)pyrene indeno(l ^3-cd)pyrene dibenz(a^)anthracene benzo(g,h,i)perylene i

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40.00 45.00 50.00 55.00 I I • I "

151 ~ 2,4-difluorotoluene 152 - o-terphenyl 551 — 2-fluorobiphenyl 552 - 5a-androstane

GTO30205.ppt

Field ID: Middle coal tar distillates

Laboratory ID: GT030205-04

Method: EPA 8100 mod. ^

AR120018

GC/FID Fingerprint

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C080313.D\FID2B 1 2 Z 4 S 6 7 8 9 10

bwzene . toluene ethylbetutene m/p-xylene styrene o-xylcne 1 ,4-trimethylbenzene naphthalene 2-iiiethylnaphthalcne \ -mcthytoaphthaltsne

11 acenaphthylene 12 acenaphthene 13 dibenzofiiran 14 fluorene 15 phenanthrene 16 anthracene 17 fluoranthene 18 pyrene 19 benz(a)anthracene 20 chiysene 21 benzo(b)fluoranthene 22 benzo(k)fluoianthene 23 benzo(a)pyrene 24 indeno(l,2;}-cd)pyrcne 25 dibenz(a^)anthracene 26 benzo(gjv,l)perylene

5.00 10.00 -r •' T ' ' ^

15.00 20.00 25.00 Time (min.)

1 — 1 — I — I — I — I — r -

30.00 35.00 40.00 45.00 5o:oo 55:00.

ISJ -2,4-difluorotoluene IS2 - o-terphenyl 551 - 2-fluorobiphenyl 552 — 5a-androstane

Field ID: Heavy oil

Laboratory ID: GT030205-05

C?7030203.pp( V

Method: EPA 8100 mod. META i»A_ AR120019

' y \v . - ' ^ - - . . ^^ •= •

A;^^S®SSa2S^^S^-^:

• . .• I

• • • • ; K

v;-. a , ^ - v - •^.^^V isl-^K-^-, .;

• . '• " X r . - . •":••••.< ^ t W : ; ; - ' : ! , ' • " < . ' " • - . . - i ^ ' - V r - - . . , • v , ; ; - . - ^ ^ , ^ ; . A i . ; , ' -

?• i ' : ' : . . . i r f . • . - " • ^ ' i V . • • { : > • ' • • • ; ' : y ^ •<..•• r 1 ^ ' . ' ' , ' ' . ' = ' * V > • • • ' • { ; • . • " ' /•• •.•• • • , • • • : : - • ; . ' • • ; ' . :: ^ , . ' i ; - ; ' - > ! - ' f t ; • : i v s . • • • • : f ; . - -

V . . . \ - r ' • • / ^ \ - ; ^ • • : . - • • • ; ; > . ' ^ - ; ' v ; ' ' ' , - x - - , ; ; i N ^ ; - - - . . •

I ' . v , . : . . • • • > i - • • - . . : • ; • • ' i . - : : ' ' ; • ; ' • • ' ^ ' i - : ' ' = ^ ^ . • v ^ ' . ; ; v : . - ' : ' . : ^ . • • • . • • . • ' • • ; • . - . - - ' . • ' , ' . ' : • < . . . • ; • > . . - • . . ; • • • ' i " • • • ' ' . , • . ' -

................ . .. -.,. Vrf-:vv•;:.. --:.. ' ^ • ^ • p ; M m : - f - & . f m , - -•••••: • y ^ . ^ m ^ . ' ^ ^ ^ - ' ^ r m ^ y - ' ^ ^ ^ ^

• : . ••••• . : ; ; i -fc •.••-:;v^v •:'•;•• :.. •..!.• •: ;- r i v :--r:" v'. . • , - ^ . \ . . . \ ^ : . i ^ : . : / ^ : ; . / . ^ i ; ^ . : - ;:.,:.;.•,• •

' ^ \ , ; ^ : • ^ ^ - ! . . • ^ • - : : • ^ ^ ^ - - ^ ^ : • , v : : - . - ; ; . J ; . ; • ; • • • • ; ^ • ^ : : • ; ^ % > • ^ o • : r • ^ ^ . ;• • : .

• • ' i ^ . , • ^ - ' " ' . ' / • j - " - " f:. '^'•... '• • • " ' • ' • ' . ' • • ' • . V ' • ' • ' • • - ' • * • ' ' - J * * ^ ^ ' ^ , ' ' • • • ' : j ' - - . " " ' - - . • : . • ^ • ' ' . \ " , ' i / ^ ' V - - ' - • ^

AR120020

Analytical Results for Volatile and Semivolatile Organics META Environmental, Inc.

Field ID: Blank

Client Project

Lab ID File ID:

Date Sampled: Date Received: Dale Prepared: Date Cleanup: Date Analyzed: Instrument Operator:

Batch QC:

Reilly Industries, Inc. Fairmont WV

KD050711-SB E072711.D

NA NA 7/11/2005 NA 7/28/2005 El Camino RS

KD050711-SB

Preparation Method: Cleanup Method(s): Analysis Method:

Matrix: Preservation: Decanted:

Sample Size (g): Percent Solid: Extract Volume (pi): Prep DF: Analysis DF: Injection Volume (pi):

EPA 3580 NA EPA 8270 M

solid None None

2.00 100% 2000 1.00 1.00 1.00

Analyte Concentration (mg/kg dry wt.) RL

0.050 0.050 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.050 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010

EDL

0.025 0.025 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.025 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0:005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005

Comments

PAH COMPOUNDS:

Benzene Toluene Ethylbenzene m/p-Xylenes Styrene o-Xylene Isopropylbenzene n-Propylbenzene 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene t-Butyi benzene sec-Butylbenzene p-lsopropyttoluene n-Butyfl)enzene CI - Benzene C2 - Benzene C3 - Benzene C4 - Benzene C5 - Benzene trans-Decalin cis-Decalin Naphthalene 2-Methylnaphthalene 1-Methyl naphthalene 01 - Naphthalene 02 - Naphthalene 03- Naphthalene 04- Naphthalene Acenaphthylene Acenaphthene Dibenzofuran Fluorene 01 - Fluorene 02 - Fluorene 03 - Ruorene Phenanthrene Anthracene

0.037 J U U U U U U U U U U U U U U U U U U U U

0.012 0.006 J

U 0.006

0.024

8/30/2005 KR050629 META i f A _

AR120021


Field ID: Blank

Client Project

Lab ID File ID:

Date Sampled: Date Received: Date Prepared: Date Cleanup: Date Analyzed: Instrument Operator

Batch QC:


kD050711-SB E072711.D


KDb50711-SB





solid None None

2.00 100% 2000 1.00 1.00 1.00

Analyte Concentration (mg/kg dry wt) RL

0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010

0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010

EDL

0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.0(D5 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005

0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005

Comments

CI - Phenanthrene/Anthracene C2 - Phenanthrene/Anthracene C3 - Phenanthrene/Anthracene C4 - Phenanthrene/Anthracene Dibenzothiophene 01 - Dibenzothiophene 02 - Dibenzothiophene 03 - Dlt>enzothiophene 04 - Dibenzothiophene Benzo(b)naphtho(2,1 -d)thiophene Fluoranthene Pyrene CI - Ruoranthene/Pyrene C2 - Ruoranthene/Pyrene C3 - Ruoranthene/Pyrene Benz[a]anthracene Chrysene CI - Benz(a)anthracene/Chrysene C2 - Benz(a)anthracene/Chrysene 03 - Benz(a)anthracene/Chrysene 04 - Benz(a)anthracene/Chrysene 8enzo[b]fluoranlhene 8enzo[k]nuoranthene Benzo(e)pyrene Benzo[a]pyrene Perylene Indenof 1,2,3-cdJpyrene Dit}enz[a, h]anthracene Benzo[g,h,i]perylerie Coronene

Retene Benzo(b/c)fluorenes 2-Methylpyrene 4-Methylpyrene 1-Melhylpyrene Heptadecane Pristane Octadecane Phytane

0.009 J U U U U U U U U U

0.009 J 0.008 J

U U U U U U U U U U U U U u u u u u

u u u u u

0.008 J u

0.008 J U

8/30/2005 KR050629 M E T A t ^

AR120022


Field ID: Blank

Client Project

Lab ID File ID:


Batch GO:


KD050711-SB E072711.D


KD050711-SB

Preparation Method: Cleanup Melhod(s): / inalysis Method:



EPA 3580 NA EPA 8270M

solid None None

2.00 100% 2000 1.00 1.00 1.00

Analyte Concentration (mg/kg dry wt.) RL EDL Comments

2,6,10-trimethyldodecane 2,6,10-trimethyltridecane Norpristane

U U U

0.010 0.010 0.010

Limits 50-120 50-120 50-120

0.005 0.005 0.005

Extraction Surrogate Recoveries (%) Toluene-d8 Phenanthrene-dl 0 Perylene-d12

74 82 69

NA - Not applicable B - Analyte detected In the Blank J - Estimated value; detected between the RL and DL U - Analyte not detected at>6ve OL D - Analyte reported from a diluted extract E - Estimate, result detected above calibration range. I - Concentration/Peak ID uncertain due to potential interference. RL - Reporting limit is the sample equivalent of the lowest linear calibration concentration. EDL - Estimated detection limit Is 50% of RL

8/30/2005 KRn50629 M E T A f ^

AR120023


Field ID: Sample 1

Client Project

Lab ID File ID:

Date Sampled: Date Received: Date Prepared: Dale Cleanup: Date Analyzed: Instrument Operator:

Batch QC:


KD05062W51-D E072712.D

6/22/2005 6/29/2005 7/11/2005 NA 7/28/2005 El Camino RS

KD050711-SB





solid None None

1.05 58% 2000 1.00 200.00 1.00

Analyte Concentration (mg/kg dry w t ) RL

32.8 32.8 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6,56 6.56 6.56 6.56 6.56 32.8 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56

EDL

16.4 16.4 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 16.4 3.28 3.28 3.28 3.28 3:28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28

Comments

PAH COMPOUNDS:

Benzene Toluene Ethylbenzene m/p-Xylenes Styrene o-Xylene Isopropylbenzene n-Propylbenzene 1,3,5-Trimethylbenzene 1,2,4-TrimetJTylbenzene t-Butylt>enzene sec-Butylbenzene p-lsopropyltoluene n-Butylbenzeno 01 - Benzene 02 - Benzene 03 - Benzene 04 - Benzene 05 - Benzene trahs-Decalin cls-Decalin Naphthalene 2-Methylnaphthalene 1-Methylnaphthalene 01 - Naphthalene C2 - Naphthalene 03- Naphthalene 04- Naphthalene Acenaphthylene Acenaphthene Dibenzofuran Fluorene C I - Ruorene 02-Ruorene 03 - Ruorene Phenanthrene Anthracene

98.1 22.7 13.0 58.4 58.0 42.5 16.6

B J

U 51.1 73.8 14.8 25.3

6.32 J U U

48.6 78.2 39.9 25.5

U U

3,240 B 1,080 B

798 1,190 B

807 305

91.2 904 869

1,750 2,460

386 137 89.4

8.100 B 3,390

8/30/2005 KR050629 META iA__

AR120024


Field ID:

Client Project-

Lab ID File ID:

Date Sampled: Date Received: Date Prepared: Date Cleanup: Date Analyzed: Instrument Operator:

Batch QC:

Sample 1


Kb050629-01-D E072712.D

6/22/2005 6/29/2005 7/11/2005 NA 7/28/2005 El Camino RS

KD050711-SB

Preparation Method: Cleanup Method(s): /Analysis Method:

Matrbc Preservation: Decanted:



solid None None

1.05 58% 2000 1.00 200.00 1.00

Analyte Concentration (mg/kg dry wt.) RL

6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.58 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 8.56 6.56

6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56 6.56

EDL

3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28

3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28 3.28

Comments

CI - Phenanthrene/Anthracene C2 - Phenanthrene/Anthracene C3 - Phenanthrene/Anthracene C4 - Phenanthrene/Anthracene Dibenzothiophene CI - Dibenzothiophene C2 - Dibenzothiophene 03 - Dibenzothiophene 04 - Dibenzothiophene Benzo(b)naphtho(2,1-d)thiophene Fluoranthene Pyrene CI - Ruoranthene/Pyrene 02 - Ruoranthene/Pyrene C3 - Ruoranthene/Pyrene Benz[a]anthracena Chrysene 01 - Benz(a)anthracene/Chrysene 02 - Benz(a)anthracene/Chrysene 03 - Benz(a)anthracene/Chrysene C4 - Benz(a)anthracene/Chrysene Benzo[b]fluoranthene Benzo[klfluoranthene Benzo(e)pyrene Benzoiajpyrene Perylene lndeno[1,2,3-cdlpyrene Dibenz[a,h]anthracene Benzo[g,h,i]perylene Coronene

Retene Benzo(t}/c)fluorenes 2-Mefhytpyrene 4-Methylpyrene 1-Methylpyrene Heptadecane Pristane Octadecane Phytane

1,890 566 155 38.6

580 191 109 44.8 13.3

228 5,890 4,140 2,280

467 131

2,200 1,880

613 144 79.8 38.5

1.210 1,450

845 1.670

382 857 206 647 185

675 209 133 134 20.5

105 26.9

113

B

8/30/2005 KR050629 M E T A t ^

AR120025


Field ID: Sample 1

Client Project

Lab ID File ID:


Batch QC:


KD050629-01-D E072712.D

6/22/2005 6/29/2005 7/11/2005 NA 7/28/2005 El Camino RS

KD050711-SB





solkl None None

1.05 58% 2000 1.00 200.00 1.00

Analyte Concentration (mg/kg dry wt ) RL EDL Comments

2,6,10-trimethyldodecane 2,6,10-trimethyltridecane Norpristane

5.66 J 11.5 31.7

6.56 6.56 6.56

Limits 50-120 50-120 50-120

3.28 3.28 3.28

Extraction Surrogate Recoveries (%) Toluene-d8 Phenanthrene-dlO Perylene-d12

DO DO DO

NA - Not appllcat}le B - Analyte detected in the Blank J - Estimated va|ue; detected between the RL and DL U - Analyte not detected atxive DL. D - Analyte reported from a diluted extract E - Estimate, result detected above calibration range. I - Concentration/Peak ID uncertain due to potential interference. RL - Reporting limit is the sample equivalent of the lowest linear calibration concentration. EDL - Estimated detection limit is 50% of RL DO - Not reported due to excessive dilution

8/30/2005 KR050629 META 1 ^ ^

AR120026


Field ID: Sample 2

Client project

Lab 10 File ID:

pate Sainpled: Date Received: Date Prepared: pate Cleanup: Date Analyzed: instrument Operator

Batch QC:


KD050629-02-D E072713.D

6/22/2005 6/29/2005 7/11/2005 NA 7/28/2005 El Camino RS

KD050711-SB





solid None None

0.74 72% 2000 1.00 200.00 1.00

Analyte ion (mg/k(

58.4 19.5 18.7 75.6 57.6 34.7 8.48

54.9 125 17.9 12.7

3)

B J

U

7.12 J 5.56 J

53.2 116 67.4 23.6

18,900 5.100 2.620 4.850 1,950

566 124

1.780 4.570 6,410 7,380

787 162 135

23,100 8,420

U

U U DB B

B

DB 0

RL

37.5 37.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 37.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5

EDL

18.8 18.8 3.75 3.75 3.75 3.75 3.75 3.75 3.75 3.75 3.75 3.75 3.75 3.75 18.8 3.75 3.75 3.75 3.75 3.75 3.75 3.75 3.75 3.75 3.75 3.75 3.75 3.75 3.75 3.75 3.75 3.75 3.75 3.75 3.75 3.75 3.75

Comments

PAH COMPOUNDS:

Benzene Toluene £ttryHienzene rn/p-Xytenes Styrene o-Xylene Isopropylbenzene n-Propy1l)enzene 1,3,5-Trimethyltjenzene 1,2,4-Trimethyltjenzene t-Butylbenzene $eo-Butylbenzene p-lsopropyitoluene n-Butylbenzene CI - Benzene C2 - Benzene C3 - Benzene 04 - Benzene C5 - Benzene trans-Decalin cis-Decalin Naphthalene 2-Methylnaphthalene 1 -Methylnaphthalene 01 - Naphthalene 02 - Naphthalene C3- Naphthalene 04- Naphthalene Acenaphthylene Acenaphthene Dibenzofuran Fluorene CI - Fluorene C2 - Ruorene C3 - Fluorene Phenanthrene Anthracene

8/30/2005 KR050629 META^^^

AR120027


Field ID: Sample 2

Client Project

Lab ID RIe ID:

Date Sampled: Date Received: Date Prepared: Date Cleanup: Date Analyzed: Instalment Operator:

Batch QC:

Reilly Industries, Inc. FaimiontWV

KD050629-02-D E072713.D

6/22/2005 6/29/2005 7/11/2005 NA 7/28/2005 El Camino RS

KD050711-S8



Sample Size (g): Percent Solid: Extract Volume (pi): Prep DF: Analysis DF: InjecUon Volume (pi):

EPA3.Sa0 NA EPA 8270 M

solid None None

0.74 72% 2000 1.00 200.00 1.00

Analyte lion (mg/kg)

3,530 B 726 171

36.9 1.850

368 132

46.8 13.4

415 12.600 B 8.910 B 3.750

567 145

4.050 3,500

863 201

86.5 47.6

2.380 2,730 1,650 3,340

794 1,770

468 1,370

389

14.7 1,170

324 204 220

38.1 B 111 82.2 B 84.1

RL

7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5

7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5

EDL

3.75 3.75 3.75 3.75 3.75 3.75 3,75 3.75 3.75 3.75 3.75 3.75 3.75 3,75 3.75 3.75 3.75 3.75 3.75 3.75 3.75 3.75 3.75 3,75 3,75 3.75 3.75 3.75 3.75 3.75

3.75 3.75 3.75 3.75 3.75 3.75 3.75 3.75 3.75

Comments

01 - Phenanthrene/Anthracene 02 - Phenanthrene/Anthracene 03 - Phenanthrene/Anthracene C4 - Phenanthrene/Anthracene Dibenzothtophene CI - Dibenzothiophene 02 - Dit}enzothiophene C3 - Dibenzothbphene C4 - Dibenzothiophene Benzo(b)naphtho(2,1-d)thlophene Ruoranthene Pyrene 01 - Fluoranfhene/Pyrene 02 - Fluoiranthene/Pyrene C3 - Fluoranthene/Pyrene Bec\z[a]anthracene Chrysene 01 - Benz(a)anthracene/Chrysene C2 - Benz(a)anfhrac6ne/Chrysene 03 r Benz(a)anthracene/Chrysene C4 - Benz(a)anthracene/Chrysene Benzo[b]fluoranthene Benzo(k]fIuQranthene Benzo(e)pyrene Benzojajpyrene Perylene lndeno[1,2,3-cd]pyrene Dibenz(a,h]anthracene Benzo[g,h,i]perylene Coronene

Retene Benzo(b/c)fluorenes 2-Melhylpyrene 4-Methylpyrene 1-Methylpyrene Heptadecane Pristane Octadecane Phytane

8/30/2005 KR050629 META J > A _

AR120028


Field ID:

Client Project

Lab ID File ID:

Date Sampled: Date Received: Data Prepared: Date Cleanup: Date Analyzed: Instrument Operator

Batch QC:

Sample 2


KD050629-02-D E072713.D

6/22/2005 6/29/2005 7/11/2005 NA 7/28/2005 El Camino RS

KD050711-SB





solid None None

0.74 72% 2000 1.00 200.00 1.00

Analyte Concentration (mg/kg) RL EDL Comments

2.6,10-trimethyldodecane 2,6,10-trimethyltridecane Norpristane

U U U

7.5 7.5 7.5

3.75 3.75 3.75

Extraction Surrogate Recoveries (%) ToIuene-d8 Phenanthrene-dlO Perylene-d12

DO DO DO

Limits 50 -120 50-120 50-120

NA - Not applicable B - Analyte detected in the Blank J - Estimated value; detected between the RL and DL U - Analyte not detected above DL D - Analyte reported from a diluted extract E - Estimate, result detected above calibration range. I - Concentration/Peak ID uncertain due to potential interference. RL - Reporting limit is the sample equivalent of the lowest linear calibration concentration. EDL - Estimated detection limit is 50% of RL DO - Not reported due to excessive dilution

8/30/2005 KR050629 JMIETAJ^;Q__

AR120029


Field ID: Sample 3

Client: Project

-Lab ID File ID:

Date Sampled: Dale Received: Date Prepared: Date Cleanup: Date Analyzed: Instrument Operator.

Batch QC:

Reilly Industries, Inc. FainnontWV

KD050629-03-D E072714.D

6/22/2005 6/29/2005 7/11/2005 NA 7/28/2005 El Camino RS

KD050711-SB


Matrix Preservation: Decanted:



solid None None

0.86 75% 2000 1.00 200.00 1.00

Analyte Concentratton (mg/kg) RL

30.8 30.8 6.16 6.16 6.16 6.16 6.16 6.16 6.16 6.16 6.16 6.16 6.18 6.16 30.8 6.16 6.16 6.16 6.16 6.16 6.16 6.16 6.16 6.16 6.16 6.16 6.16 6.16 6.16 6.16 6.16 6,16 6.16 6.16 6.16 6.16 6.16

EDL

15.4 15.4 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 15.4 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08

Comments

PAH COMPOUNDS:

Benzene Toluene Ethylbenzene m/p-Xylenes Styrene o-Xylene Isopropylbenzene n-Propylbenzene 1,3.5-Trimelhy)benzene 1,2,4-Trimethylbenzene t-Butylbenzene sec-Butylbenzene p-lsopropyltoluene n-Butylt»nzene 01 - Benzene 02 - Benzene C3 - Benzene 04 - Benzene C5 - Benzene trans-Decalin cis-Decalin Naphthalene 2-Methylnaphthaleni3 1 -Methylnaphthalene 01 - Naphthalene 02 ^ Naphthalene 03- Naphthalene 04- Naphthalene Acenaphthylene Acenaphthene Dibenzofuran Fluorene 01 - Fluorene CZ - Fluorene 03 - Fluorene Phenanthrene Anthracene

51.8 19.4 16.2 84.5 93.6 37.4 18.7

U 99.1

197 30.6 32.0 6.02 J 5.48 J

U 58.6

170 78.3 25.8

U U

10,500 B 3,520 B 2,040 3,500 B 1,480

398 96.5

1,750 1,610 3.010 3,850

545 137 116

10.800 B 4.770

8/30/2005 KR050629 METAtkQ

AR120030


Field ID: Sample 3

Client Project

Lab ID File ID:


Batch QC:

Reilly Industries, Inc. Fairniont WV

KD050629-03-D E072714.D

6/22/2005 6/29/2005 7/11/2005 NA 7/28/2005 El Camino RS

KD050711-SB

Preparation Method: Cleanup Methbd(s): Analysis Method:


Sample Size (g): Percent Solid: Fxtract Volume (pi): Prep DF: Analysis DF: Injection Volume (pi):


solid None None

0.86 75% 2000 1.00 200.00 1.00

Analyte Concentration (mg/kg) RL

6.16 6.16 6.16 6.16 6.16 6.16 6.16 6.16 8.16 6.16 6.16 6.16 6.18 6.16 6.16 6.16 6.16 6.16 6.16 6.16 6.16 6.16 6.16 6.16 6.16 6.16 6.16 6.16 6.16 6.16

6.16 6.16 6.16 6.16 6.16 6.16 6.16 6.16 6.16

EDL

3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3,08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08

3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08

Comments

01 - Phenanthrene/Anthracene 02 - Phenanthrene/Anthracene 03 - Phenanthrene/Anthracene 04 - Phenanthrene/Anthracene Dibenzothiophene 01 - Dibenzothiophene 02 - Dibenzothiophene 03 - Dltienzothiophene :C4 - Dibenzothiophene Benzo(b)naphtho(2,1-d)thiophene Ruoranthene Pyrene 01 - Fluoranthene/Pyrene 02 - Fluoranthene/Pyrene C3 - Fluoranthene/Pyrene Benz[a]anthracene Chrysene 01 - Benz(a)anlhracene/Chrysene 02 - Benz(a)anthracene/Chrysene 03 - Benz(a)anthracene/Ohrysene 04 - Benz(a)anthracene/Chrysene Benzo[b]fiuoranlhene Benzo[k]fluoranthene Benzo{e)pyrene Benzo[ajpyrene Perylene Indenoll ,2,3-cd]pyrenie Dibenz[a,h]anthracene 8enzo[g,h,i]peryiene Coronene

Retene Benzo(b/c)fluorenes 2-Methylpyrene 4-Methylpyrene 1-Methylpyrene Heptadecane Pristane Octadecane Phytane

2,410 635 152 30.9

837 233 106 41.6 10.2

250 7.180 5,040 2,650

485 122

2,510 2,150

655 158 62.7 35.8

1,400 1.680

968 1.950

454 1,020

251 774 220

11.2 802 222 150 160 17.9 B 93.4 34.2 B

102

8/30/2005 KRn.'?0629 META^K^

AR120031

Analytical Results for Volatile and Semivolatile Organics META Environmental, Iric.

Field ID: Sample 3

Client Project

UbID File ID:

Date Sampled: Date Received: Date Prepared: Date Cleanup: Dale Analyzed: Instrument Operator

Batch QC:

Reilly Industries^ Inc. Fairmont WV

KD050629-03-D E072714.D

6/22/2005 6/29/2005 7/11/2005 NA 7/28/2005 El Camino RS

KD050711-SB

Preparation Method: Cleanup Melhod(s): Analysis Method:




solid None None

0.86 75% 2000 1.00 200.00 1.00


2,6,10-trimethy(dodecane 2,6,10-lrimethyltridecane Norpristane .

4.46 J 8.61

33.5

6.16 6.16 6.16

Umits 50-120 50-120 50-120

3.08 3.08 3.08

Extraction Surrogate Recoveries (%) Tdluene-dS Phenanthrene-dlO Perylene-d12

DO DO DO

N A - Not applicatile B - Analyte detected In the Blank J - Estimated value; detected between the RL and DL U - Analyte not detected above DL D - Analyte reported from a diluted extract E - Estimate, result detected atxsve calibration range. I - Concentration/Peak ID uncertain due to potential Interference. RL - Reporting limit is the sample equivalent of the lowest linear calibration concentration. EDL - Estimated detection limit is 50% of RL DO - Not reported due to excessive dilution

8/30/2005 KR050629 _ M E T A J ^

AR120032


Field ID: Sample 4

Client Project

l a h l D File ID:

Date Sampled: Date Received: Date Prepared: Date Cleanup; Date Analyzed: Instrument Operator

Batch QC:


KD050629-04-D E072715,D

6/22/2005 6/29/2005 7/11/2005 NA 7/28/2005 El Camino RS

KD050711-SB





solid None None

0.73 60% 2000 1.00 200.00 1.00


45.8 45.8 9.16 9.16 0.16 9.16 9.16 9.16 9.16 9.18 9.16 9.16 9.16 9.16

45,8 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16

EDL

22,9 22,9 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4,58 22.9 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58

Comments

PAH COMPOUNDS:

Benzene Toluene Ethyl tjenzene m/p-Xylenes Styrene o-Xylene Isopropylbenzene n-Propylbenzene 1,3,5-Trimethylt>onzene 1,2,4-Trimethylbenzene t-Butyi benzene sec-Butylbenzene p-lsopropyltoluene ivButylbenzene 01 - Benzene 02 - Benzene 03 - Benzene 04 - Benzene 05 - Benzene trans-Decalin cis-Decalin Naphthalene 2-Methylnaphthalene 1 -Methylnaphthalene 01 - Naphthalene 02 - Naphthalene C3- Naphthalene 04- Naphthalene Acenaphthylene Acenaphthene Dibenzofuran Fluorene 01 - Ruorene 02 - Fluorene 03 - Fluorene Phenanthrene Anthracene

63.8 B 29.0 J 9.63

24.3 95.4 9.83

U U

30.4 58.3 11.9 9.77

U U U

20.0 60.8 48.4 19.5

4,290 1,050 1.780 1.770 1,530

457 94.2

2,560 1.230 3,770 4,920

630 154 106

15,000 6,390

U U B B

8/30/2005 KR050629 M E T A J ^

AR120033


Field ID: Sample 4

Client Project

Lab ID File ID:

Date Sampled: Date Received: Date Prepared: Date Cleanup: Date /Analyzed: Instrument Operator

Batch QC:


KD050629-04-D E072715.D

6/22/2005 6/29/2005 7/11/2005 NA 7/28/2005 El Camino RS

KD050711-SB





solid None None

0.73 60% 2000 1.00 200.00 1.00


9.16 9.16 9.16 9.16 9,16 9,16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16

9,16 9.16 9.16 9.16 9.16 9.16 9.16 9.16 9.16

EDL

4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4,58 4,58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58

4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58 4.58

Comments

01 - Phenanthrene/Anthracene 02 - Phenanthrene/Anthracene 03 - Phenanthrene/Anthracene 04 - Phenanthrene/Anthracene Dibenzothtophene 01 - Dibenzothiophene 02 - Dibenzothtophene 03 - Dibenzothiophene 04 - Dibenzothiophene Benzo(b)naphtho(2,1 -d)thiophene Ruoranthene Pyrene Cl - Ruoranthene/Pyrene 02 - Fluoranthene/Pyrene 03 - Fluoranthene/Pyrene Benz[a]anthracene Chrysene 01 - Benz(a)anthracene/Chrysene 02 - Benz(a)anlhracene/Ohrysene 03 - Benz(a)anthracene/Chrysene 04 - Benz(a)anthracene/Chrysene Benzo[b]fluaranthene Benzo[k}fluoranthene Benzo(e)pyrene Benzoiajpyrene Perylene lndeno[1,2.3-cd]pyrene Dibenz[a,h]anthracene Benzo[g,h,i]perylene Coronene

Retene Benzo(b/c)fluorenes 2-Methylpyrene 4-Methy)pyrene 1-Methylpyrene Heptadecane Pristane Octadecane Phytane

3,050 B 737 174 36.8

1,170 297 118 41.7 10.8

364 10,200 E 7,290 E 3,560

608 153

3,740 3,140

898 212 91.4 38.9

2,150 2.540 1.500 3,080

683 1,600

387 1.210

342

9.28 1.090

308 212 217

12.3 47.6 35.8 57.8

8/30/2005 KR050629 M E T A t ^ ^

AR120034


Field ID:

Client Project

Lab ID File ID:

Dale Sampled: Date Received: Date Prepared: bate Cleanup: Date Analyzed: Instrument Operator:

Batch QC:

Sample 4


KD050629-04-D E072715.D

6/22/2005 6/29/2005 7/11/2005 NA 7/28/2005 El Camino RS

KD050711-SB





solid None None

0.73 60% 2000 1.00 200.00 1.00


2,6,10-trimethytdodecane 2,6,10-trimettiyltridecane Norpristane

U 5.09 J

16.6

9.16 9.16 9.16

Umits 50-120 50-120 50-120

4.58 4.58 4.58

Extraction Surrogate Recoveries (%) Toluene-dS Phenanthrene-dlO Perylene-d12

DO DO DO

NA - Not applicable B - Analyte detected In the Blank J - Estimated value; detected between the RL and DL U - Analyte not delected above DL D - Analyte reported from a diluted extract E - Estimate, result detected above calibration range. I - Concentration/Peak ID uncertain due to potential interference. RL - Reporting limit is the sample equwalent of the lowest linear calibration concentration. EDL - Estimated detection limit is 50% of RL DO - Not reported due to excessive dilution

8/30/2005 iôncncoQ META J ^ ^ ^ ^

AR120035


Field ID: Sample 5

Client Project

Lab ID File ID:


Batch QC:


KD050629-05-D E072716.D

6/20/2005 6/29/2005 7/11/2005 NA 7/28/2005 El Camino RS

KD050711-SB


Matrbc Preservation: Decanted:



solid None None

0.77 63% 2000 1.00 200.00 1.00


41.5 41.5 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 41.5 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3

EDL

20.8 20.8 4.15 4.15 4.15 4.15 4,15 4.15 4,15 4.15 4,15 4,15 4.15 4.15 20,8 4.15 4.15 4.15 4.15 4.15 4.15 4.15 4.15 4.15 4,15 4.15 4.15 4.15 4.15 4.15 4.15 4.15 4.15 4.15 4.15 4.15 4.15

Comments

PAH COMPOUNDS:

Benzene Toluene Ethylbenzene m/p-Xylenes Styrene o-Xylene Isopropylbenzene n-Propyiljenzene 1,3,5-Trimethylbenzene 1.2.4-Trimethylbenzene t-Butylberizene sec-Butylt}enzene p-lsopropyltoluene n-Butylbenzene 01 - Benzene 02 - Benzene 03 - Benzene C4 - Benzene 05 - Benzene trans-Decalin cis-Decalin Naphthalene 2-Methytnaphthalene 1 -Methylnaphthalene 01 - Naphthalene 02 - Naphthalene 03- Naphthalene 04- Naphthalene Acenaphthylene Acenaphthene Dibenzofuran Ruorene 01 - Fluorene 02 - Fluorene C3 - Fluorene Phenanthrene Anthracene

55.1 23.8 27.5 94.5 84.6 44.1 20.7

101 213 32.2 30.6 10.8 10.1

73.1 201 112 43.5

16.200 5,000 2,750 4.890 2.150

636 150

1.260 3,860 4,910 5,650

657 183 129

14,000 6.360

B J

U U B B

8/30/2005 M E T A J ^

AR120036


Field ID: Sample 5

Client Project

Lab ID File ID:


Batch QC:

Reilly Indusb-ies, Ina Fairmont WV

KD050629-05-D E072716.b

6/20/2005 6/29/2005 7/11/2005 NA 7/28/2005 El Camino RS

KD050711-SB





solid None None

0.77 63% 2000 1.00 200.00 1.00


8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8,3 8,3 8.3 8.3 8,3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3

8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3 8.3

EDL

4.15 4.15 4.15 4.15 4.15 4.15 4.15 4,15 4.15 4.15 4.15 4.15 4.15 4.15 4.15 4.15 4.15 4.15 4.15 4.15 4.15 4.15 4.15 4.15 4.15 4.15 4.15 4.15 4.15 4.15

4.15 4.15 4.15 4.15 4.15 4.15 4.15 4.15 4.15

Comments

CI - Phenanthrene/Anthracene 02 - Phenanthrene/Anthracene 03 - Ptienanthrene/Anlhracene 04 - Phenanthrene/Anthracene Dit>enzothiophene 01 - Dibenzothiophene C2 - Dibenzothiophene 03 - Dibenzothiophene 04 - Dibenzothtophene Benzo(b)naphtho(2,1-d)thlophene Fluoranthene Pyrene CI - Fluoranthene/Pyrene 02 - Fluoranthene/Pyrene C3 - Fluoranthene/Pyrene Benz[a]anlhracene Chrysene 01 - Benz(a)anlhracene/Chrysene 02 - Benz(a)anthracene/Chrysene 03 - Benz(a)anthracene/Chrysene 04 - Benz(a)anthracene/Chrysene Benzo[blfluoranthene Benzo[k]fluoranthene Benzo(e)pyrene Benzoiajpyrene Perylene Indenofl .2.3-cd]pyrene Dibenz[a.h]anlhracene Benzo[g.h.i]perylene Coronene

Retene Benzo(b/c)fluorenes 2-Methylpyrene 4-Methylpyrene 1-Melhylpyrene Heptadecane Pristane Octadecane Phytane

2.640 663 161 35.3

1.020 256 110 40.4 10.8 241

8,010 5,600 2.580 474 138

2,510 2,060 636 153 60.3 33,6

1,350 1.580 930

1.850 426 944 271 722 193

8.02 J 783 245 150 147 92.3 112 120 93.2

B

B

8/30/2005 META J>A_

AR120037


Field ID: Sample 5

Client Project

Lab ID File ID:


Batch QC:

Reilly Industries. Inc. FairrtiontWV

KD050629-05^3 E072716.D

6/20/2005 6/29/2005 7/11/2005 NA 7/28/2005 El Camino RS

KDa50711-SB





solid None None

0.77 63% 2000 1.00 200.00 1.00


2,6.10-lrimethyhJodecane 2.6.10-trimethyitrklecane Norpristane

6.01 J 13.1 41.5

8.3 8.3 8.3

4.15 4.15 4.15


DO DO DO

Limits 50 -120 50 -120 50 -120

NA - Not applicable B - Analyte detected in the Blank J - Estimated value; detected between the RL and DL U - Analyte not delected above D L D - Analyte reported from a diluted extract E - Estimate, result detected above calibration range. I - Concentration/Peak ID uncertain due to potential interference. RL - Reporting limit is the sample equivalent of the lowest linear calibration concentration. EDL - Estimated detection linhlt is 50% of RL DO - Not reported due to excessive dilution

8/30/2005 KR050629 M E T A ^ ^

AR120038


Field ID: Sample 6

Client Project

Lab ID File ID:

Date Sampled; Date Received: Date Prepared: Date Cleanup: Date Analyzed: Instrument operator

Batch QC:

Reilly Industries. Inc. Fairmont WV

KD050629-06-D , E072717.D

6/21/2005 6/29/2005 7/11/2005 NA 7/28/2005 El Camino RS

KD050711-SB


Matrix: Presen/abon: Decanted:

Sampte Size (g): Percent Solid: Extract Volume (pi): Prep DF: Analysis DF: Injection Volume (pi):


solid None None

0.70 70% 2000 1.00 200.00 1.00

Analyte ion (mg/kg)

73.4 39,4 13,0 55.7 90.0 22.2

37.5 82.7 13.0

B J

U U

5.84 J

24.0 40.1 77.7 56.0 25.0

14.700 4,860 2,420 4,580 Z090

686 162

2,480 3,830 6,500 7,720

845 186 149

25.600 9.920

u U J

u u B B

B

DB D

RL

40.5 40.5 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09

40.5 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09

EDL

20.2 20.2 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 20.2 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04

Comments

PAH COMPOUNDS:

Benzene Toluene Ethyl t>enzene m/p-Xylenes Styrene o-Xylene lsopropylt>enzene n-Propylbenzene 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene t-Butylbenzene sec-Butylbenzene p-lsopropyttoluene n-Bulytbenzene CI - Benzene 02 - Benzene 03 - Benzene 04 - Benzene 05 - Benzene trans-Decalin cis-Decalin Naphthalene 2-Methylnaphthalene 1 -Methylnaphthalene 01 - Naphthalene 02 - Naphthalene 03- Naphthalene C4- Naphthalene Acenaphthylene Acenaphthene Dibenzofuran Fluorene, 01 - Fluorene 02 - Fluorene C3 - Fluorene Phenanthrene Anthracene

8/30/2005 META j | ^ A _

AR120039


Field ID: Sample 6

Client Project

Lab ID File ID:


Batch QC:


KD05062&O6-D E072717.D

6/21/2005 6/29/2005 7/11/2005 NA 7/28/2005 El Camino RS

KD050711-SB



Sample Size (g): Percent Solid: Exfract Volume (pi): Prep DF: Analysis DF: Injection Volume (pi):


solid None None

0.70 70% 2000 1.00 200.00 1.00


8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09

8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09 8.09

EDL

4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04

4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04 4.04

Comments

01 - Phenanthrene/Anthracene C2 - Phenanthrene/Anthracene 03 - Phenanthrene/Anthracene C4 - Phenanthrene/Anthracene Dibenzothtophene CI - Dibenzothiophene C2 - Dibenzothtophene C3 - Dibenzothtophene C4 - Dibenzothiophene Benzo{b)naphtho(2,1-d)thfophene Ruoranthene Pyrene 01 - Fluoranthene/Pyrene 02 - Ruoranlhene/FVene 03 - Fluoranthene/Pyrene Benzlajanthracene Chrysene OI - Benz(a)anthracene/Ohrysene C2 - Behz(a)anthracene/Chrysene C3 - Benz(a)anthracene/Chrysene 04 - Benz(a)anlhracene/Chrysene Benzo[blfluoranthene Benzo[kJfluoranthene Benzo(e)pyrene Benzo[aJpyrene Perylene lndenoI1,2,3-cd]pyrene Dibenzla,h]anthracene Benzofe,h.i]perylene Coronene

Retene Benzo(b/c)fluorenes 2-Melhylpyrene 4-Methylpyrene 1-Methylpyrene Heptadecane Pristane Octadecane Phytane

4.060 865 199 49.2

2.040 422 149 53.3 14.8

507 14.500 10.300 4,500 706 167

4,930 4.130 1,040 224 91.9 56.9

2.920 3.380 2.030 4.110 982

2,160 492

1.660 467

12.1 1.380 399 256 276 225 123 323 109

B

8/30/2005 KR050629 META < K 0 _ _

AR120040


Field ID: Sample 6

Client Project:

Lab ID File ID:


Batch QC:

Reilly Industries, Inc. FainnontWV

KD050629-06-D E072717.D

6/21/2005 6/29/2005 7/11/2005 NA 7/28/2005 El Camino RS

KD050711-SB



Sample Size (g): Percent Solid: Extract Volume (pi): Prep DF: /Analysis DF: Injection Volume (pi):


solid None None

0.70 70% 2000 1.00 200.00 1.00


2.6.10-trimethyldodecane 2,6.10-trimelhyllridecane Norpristane

27.9 13.8 36.6

8.09 8.09 8.09

Limits 50-120 50-120 50-120

4.04 4.04 4.04

Extraction Surrogate Recoveries (%) Toluene-d8 Phenanthrene-d 10 Perylene-d12

DO DO DO

NA - Not applicable B - Analyte detected in the Blank J - Estimated value; detected between the RL and DL U - Analyte not detected above DL. D - Analyte reported from a diluted extract E - Estimate, result detected above calibration range. I - Concentration/Peak ID uncertain due to potential interference. RL - Reporting limit is the sample equivalent of the lowest linear calibration concentration. EDL - Estimated detection limit is 50% of RL DO - Not reported due to excessive dilution

8/30/2005 MPTfA i l O

AR120041


Field ID: Method Blank

Client Project

Lab ID File ID:

Date Sampled: Date Received: Date Prepared: Date Cleanup: Date Analyzed: Instrument Operator:

Batch QC:


GT050802-MB D0802A10.D


GT050802-MB





NAPL None None

0.01 100% 2000 1.00 1.00 1.00


P / ^ COMPOUNDS:

Benzene Toluene Ethyl tsenzene m/p-Xylenes Styrene o-Xylene Isopropylbenzene rwPropylbenzene 1.3,5-Trimethylbenzene 1,2,4-Trimethylbenzene t-Butylbenzene sec-Butylbenzene p-lsopropyltoluene n-Butylbenzene CI - Benzene 02 - Benzene C3 - Benzene C4 - Berizene 05 - Benzene trans-Decalin cis-Decalin Naphthalene 2-Methylnaphthalene 1-Methylnaphthalene CI - Naphthalene 02 r- Naphthalene C3- Naphthalene C4- Naphthalene AcenaphUiylene Acenaphthene Dibenzofuran Ruorene 01 - Fluorene C2 - Fluorene 03 - Fluorene Phenanthrene Anthracene

U U U U U U U U U U U U U U u u u u u u u u u u u u u u

11.4 8.39

U U U U U

2.71

10.0 10.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 10.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2,0

5,0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1,0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

8/30/2005 GT030205 METAtK>)

AR120042



Client Project

Lab ID File ID:

Date Sampled: Date Received: Date Prepared: Date Cleanup: Date Analyzed: Instmment Operator

Batch QC:


GT050802-MB D0802A10.D


GT050802-MB



Sample Size (g): Percent Solid: Extract Volume (pi): Prep DF: Analysis DF: Injeclton Volume (pi):


NAPL None None

0.01 100% 2000 1.00 1.00 1.00

Atralyte Concentration (mg/kg) RL EDL Comments

CI - Phenanthrene/Anthracene 02 - Phenanthrene/Anthracene 03 - Phenanthrene/Anthracene C4 - Phenanthrene/Anthracene Dibenzothtophene CI r Dibenzothiophene 02 - Dibenzothiophene 03 - Dibenzothiophene 04 - Dibenzothiophene Benzo(b)naphtho(2.1 -d)thlophene Fluorantherw Pyrene 01 - Ruoranthene/Pyrene 02 - Ruoranthene/Pyrene 03 - Fluoranthene/FVene Benz[alanthracane Chrysene CI - Benz(a)anthracene/Chrysene 02 - Benz(a)anttiracene/Chrysene 03 - Benz(a)anthracene/Chrysene 04 - Benz(a)anthracene/Chry5ene Benzo[blfluoranthene Benzo(k]fluoranthene Benzo(e)pyrene Benzoiajpyrene Perylene lndeno[1,2,3-cdjpyrene 01benz[a,h]anttnracene Benzo^,h.i]perylene Coronene

Retene Benzo(b/c)nuorene3 2-Methyfpyrene 4-MethylpyrenB 1-Methylpyrene Heptadecane Pristane Octadecane Phytane

2.16 1.91

1.63

U U U U U U u u u u

J u u u u u u u u u u u u u u J u u u

u u u u u u u u u

2.0 2.0 2.0 2,0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2,0 2,0 2.0 2.0 2.0 2.0 2.0 2.0

2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0

1.0 1.0 1,0 1.0 1.0 1,0 1,0 1.0 1.0 1,0 1.0 1.0 1,0 1,0 1,0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

8/30/2005 METAIKD

AR120043



Client Project

Lab ID File ID:

Dale Sampled: Date Received: Dale Prepared: Date Cleanup: Date Analyzed: Instrument Operator

Batch QC:


GT050802-MB D0802A10.D


GT050802-MB

Preparation Method: Cleanup Mettiod(s): Analysis Method:

Matrix; Preservation: Decanted:

Sample Size (g): Percent Solid: Extract Volume (pi): PrepDF: Analysis DF: Injection Volume (pi):


NAPL None None

0.01 100% 2000 1.00 1.00 1.00


2,6i10-trimethyldodecane 2,6,10-trimethyllridecane Norpristane

U U U

2.0 2.0 2.0

1.0 1.0 1.0


79 84 71

Limits 50-120 50-120 50-120

NA - Not applicable B - Analyte detected in the Blank J - Estimated value; detected between the RL and DL U - Analyte not detected above D L D - Analyte reported from a diluted extract E - Estimate, result detected atxive calibration range. I - Concentration/Peak ID uncertain due to potential interference. RL - Reporting limit is the sample equivalent of the lowest linear calibration concentration. EDL - Estimated detection limit is 50% of RL

8/30/2005 f5T0.^0205 M E T A < ^

AR120044


Field ID: Method Blank Spike

Client Project: _

Lab ID File ID:


Batch QC:


GT050802-MBS D0802A09.D


GT050802-MB



Sample Size (g): Percent Solid: Extinct Volume (pi): Prep DF: Analysis DF: Injection Volume (pi):


NAPL None None

0.01 100% 2000 1.00 1,00 1.00

Analyte Concenh'ation (mg/kg) RL EDL Comments

PAH COMPOUNDS:

Benzene Toluene Ethylbenzene m/prXylenes Styrene o-Xylisno Isopropylbenzene rvPropylbenzene 1,3,5-Trimetiiyibenzene 1,2,4-Trimethylbenzene t-Butylt}enzene sec-Butylbenzene p-lsopropyltoluene n-Bulytbenzene 01 - Benzene C2 - Benzene 03 - Benzene 04 - Benzene C5 - Benzene trans-Decalin cis-Decalin Naphthalene 2-Melhylnaphlhalene 1 -Methylnaphthalene 01 - Naphthalene 02 - Naphthalene 03- Naphtiialene 04- Naphthalene Acenaphthylene Acenaphthene Dibenzofuran Fluorene CI - Fluorene 02 - Fluorene 03 - Fluorene PhenanUirene Anthracene

Spike Amount

2500.00 2500.00 2500.00 2500.00 2500.00 2500.00 2500.00 2500.00 2500.00 2500.00 2500.00 2500.00 2500.00 2500.00

2500.00 2500.00 2500.00

2500.00 2500.00 2500.00 2500.00

2500.00 2500.00

2,590 3,140 3.280 3.400 3.100 3,290 3,390 3,380 3.510 3,430 3,340 3.420 3.480 3,490

3.440 3.570 3.640

3.920 3.940 3.930 4,210

3.860 3.950

U U U U U U U

U u u u B B

U U

u B

10.0 10.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 10.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0

5.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

% Recovery

104% 126% 131% 136% 124% 132 % 136% 135% 140% 137% 134% 137% 139 % 140%

138% 143 % 146%

157 % 158% 157% 168%

154% 158%

8/30/2005 GT030205 META J ^ A _

AR120045



Client Project

Lab ID File ID:

Dale Sampled: Dale Received: Date Prepared: Date Cleanup: Date Analyzed: Insbument Operator

Batch QC:

Reilly IndusWes. Inc. Fairmont WV

GT050802-MBS D0802A09.D


GT050802-MB

Preparation Method: Cleanup Mettiod(s): Analysis Method:


Sample Size (g): Percent Solid: Exbact Volume (pi): PrepDF: Analysis DF: Injection Volume (pi):


NAPL None None

0.01 100% 2000 1.00 1.00 1.00


01 - Phenanthrene/Z^thracene 02 - Phenanthrene/Anthracene 03 - Phenanthrene/AnUiracene 04 - PhenanthreneZ/Vnthracene Dibenzothiophene 01 - Dibenzothiophene 02 - DibenzoUiiophene 03 - Dibenzothtophene 04 - Dibenzothtophene Benzo(b)naphthp(2.1-d)thiophene Fluoranthene Pyrene 01 - Fluoranthene/Pyrene 02 - Ruoranthene/Pyrene C3 - Fluoranthene/Pyrene Benz[a]anthracene Chryserie 01 - Benz(a)anthracene/Chrysene 02 - Bsnz(a)anthracene/Chrysene 03 - Benz(a)anthracene/Chrysene 04 - Benz(a)anthracene/Chrysene Benzo[blfluoranthene Benzo[k]fluoranthene Benzo(e)pyrena Benzoiajpyrene Perylene lndeno[1,2.3-cd]pyrene Dibenz[a.h]anthracene Benzo^.h,i]perylene Coronene

Retene Benzo(h/c)fluorenes 2-Methylpyrene' 4-Methyfpyrene 1-Methylpyrene Heptadecane Pristane Octadecane Phytane

2500.00 2500.00

2500.00 2500.00

2500.00 2500.00

2500.00

2500.00 2500.00 2500.00

12.2

23.0 3,780 3.750

3.710 3,620

3,750 3.630

3,770

3,680 3.810 3,320

U U U U

U U U U

B B U U U

U U U U

U B

U U U U U U U U U

2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0

2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0

1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1,0 1.0 1,0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

151% 150%

148 % 145%

150% 145 %

151 %

147 % 152% 133%

8/30/2005 r>Tmnonc METAtK^)

AR120046



Client Project

UbID File ID:

Date Sampled: Date Received: Date Prepared: Date Cleanup: Date Analyzed: Insbument Operator

Batch QC:


GT050802-MBS D0802A09.D


GT050802-MB

Preparation Mettiod: Cleanup Method(s): Analysis Method:




NAPL None None

0.01 100% 2000 1.00 1.00 1.00

Analyte Concenh'ation (mg/kg) RL EDL Comments

2,6,10-bîmelhytdodecane 2,6,10-trimeUiy1bidecane Norpristane

U U U

2.0 2.0 2.0

1.0 1.0 1.0

Extraction Surrogate Recoveries (%) Toluene-d8 Phenanthrene-d10 Perytene-d12

74 84 69

Limits 50 -120 50 -120 50 -120

NA - Not applicable B - Analyte detected in the Blank J - Estimated value; detected behween the RL and DL U - /\nalyte not detected above DL. D - Analyte reported from a diluted extract E - Estimate, result detected above calibration range. I - Concentration/Peak ID uncertain due to potential Interference. RL - Reporting limit is the sample equivalent of the lowest linear calibration concentratioa EDL - Estimated detection limit is 50% of RL

8/30/2005 M E T A t ^

AR120047


Field ID: Coal Tar Pitch

Client Project:

Lab ID File ID:


Batch QC:


-GT030205-01 D0802A07.D

NA 2/5/2003 8/2/2005 NA 8/3/2005 El Camino RS

GT050802-MB

Preparation Mettrod: Cleanup Melhod(s): Analysis Method:




Solid None None

0.01 100% 2000 1.00 1.00 1.00


9.71 9.71 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 9.71 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1,94

EDL

4.86 4.86 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 4.86 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970

Comments

PAH COMPOUNDS:

Benzene Toluene Ethylbenzene m/p-Xylenes Styrene o-Xylene Isopropylbenzene n-Propylt>enzene 1.3,5-Trimethylbenzene 1,2,4-Trimethylbenzene t-Butylbenzene sec-Butylbenzene p-lsopropyltoluene n-6utylt>enzene 01 - Benzene 02 - Benzene C3 - Benzene C4 - Benzene 05 - Benzene trans-Decalin cis-Decalin Naphthalene 2-MeUiylnaphthalene 1-Methytnaphthalene 01 - Naphthalene 02 - Naphthalene C3- Naphthalene 04- Naphthalene Acenaphthylene Acenaphthene Dibenzofuran Fluorene 01 - Ruorene C2 - Ruorene 03 - Ruorene Phenanthrene Anthracene

U 6.9 J 3.86 3.12

8.47

1.81

U

U U U J U U U U U

8.4 6.28

U U U U

59.8 57.6 62.1 70.5 35.7 15.8 8.48 2.19 B

445 94.6

366 192 86.3 71.5

6.510 878

B

DB D

8/30/2005 GT0an205 META(K)

AR120048



Client Project

U b I D Rle ID:

Date Sampled: Dale Received: Date Prepared: Date Cleanup: Date Analyzed: Instrument Operator

Batch QC:


GT030205-01 D0802A07,D

NA 2/5/2003 8/2/2005 NA 8/3/2005 El Camino RS

GT050802-MB



Sample Size (g): Percent Solid: Exbact Volume (pi): Prep DF: Analysis DF: Injection Volume (pi):


Solid None None

0.01 100% 2000 1.00 1.00 1.00

Analyte Ifon (mg/kg)

1.540 434 177

98.6 406 148

73.8 34,0 15,3

1.700 13.900 11.900

6,410 1.700

676 6.460 8.720 2.420

794 383 140

9.940 5.640 6.430 8,980 2,810 6,180 2.010 6.340 1.770

46.2 1.600

510 560 556

DB DB

D D

D D D D D DB

D

U U U U

RL

1.94 1,94 1.94 1,94 1,94 1.94 1.94 1.94

' 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1,94 1,94 1,94 1.94 1.94 1.94

1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94 1.94

EDL

0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0.970 0,970

0,970 0,970 0.970 0.970 0.970 0.970 0.970 0.970 0.970

Comments

01 - Phenanthrene/Anthracene 02 - Phenanthrene/Anthracene 03 - Phenanthrene/Anthracene 04 - Phenanthrene/Anthracene Dibenzothiophene 01 - Dibenzothiophene 02 - Dit}enzothiophene 03 - Ditwnzothiophene 04 - Dibenzothtophene Benzo(b)naphtho(2.1-d)thiophene Fluoranthene Pyrene 0 1 ' Fluoranthene/Pyrene 02 - Ruoranthene/Pyrene 03 - Ruoranthene/Pyrene Benz[a]anthracene Chrysene 01 - Benz(a)anthracene/Chrysene 02 - Benz(a)anthracene/Ohrysene 03 - Benz(a)anlhracene/Chrysene 04 - Benz(a)anthracene/Chrysene Benzo[blfiuoranthene Benzo[kjfluoranthene Benzo(e)pyrene Benzoiajpyrene Perylene Indenoll ,2,3-cd]pyrene Dibenz[a,h]anthracene Benzo^,h.i]perylene Coronene

Retene Benzo(t>/c)fluorenes 2-Methylpyrene 4-Methytpyrene 1-Melhylpyrene Heptadecane Pristane Octadecane Phytane

8/30/2005 GT030205 _METAjf^^

AR120049



Client Project

Lab ID Rle ID:


Batch QC:


GT030205-01 D0802A07.D

NA 2/5/2003 8/2/2005 NA 8/3/2005 El Camino RS

GT050802-MB





Solid None None

0.01 100% 2000 1.00 1.00 1.00

Analyte Concenbation (mg/kg) RL EDL Comments

2,6.10-trimethyldodecane 2,6,10-lrimethyllridecane Norpristane

U U U

1.94 1.94 1.94

0.970 0.970 0.970

ExtracUon Surrogate Recoveries (%) Toluene-d8 Phenanthrene-dlO Perylene-d12

78 89 87

Limits 50-120 50-120 '50-120

NA - Not applicable B - Analyte detected In the Blank J - Estimated value; detected beNveen the RL and DL U - Analyte not detected above D L D - Analyte reported from a diluted extract E - Estimate, result delected atxive calibration range. I - Concenfration/Peak ID uncertain due to potential interference. RL - Reporting limit is the sample equivalent of the lowest linear calibration concenU-ation. EDL - Estimated detection limit is 50% of RL DO - Not reported due to excessive dilution

8/30/2005 M E T A ^ ^

AR120050


Field ID: Crude Coal Tar

Client Project

U b I D File ID:

Date Sampled: Date Received: Dale Prepared: Dale Cleanup: Date Analyzed: Instalment Operator

Batch QC:

Reilly Indusbies, Inc. Fairmont WV

GT0302b5-02 D0802A08.D

NA 2/5/2003 8/2/2005 NA 8/3/2005 El Camino RS

GT050802-MB


Matrix: Presentation: Decanted:

Sample Size (g): P'ercent Solid: Exfa-act Volume (pi): PrepDF: Analysis DF: Injection Volume (pi):


NAPL None None

0.05 100% 2000 1.00 1.00 1.00

Analyte Concenbation (mg/kg) RL

1.82 1.82

0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 1.82

0.365 0,365 0.365 0.365 0.365 0.365 0.365 . 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365

EDL

0.910 0.910 0.182 0,182 0.182 0.182 0.182 0.182 0.182 0.182 0,182 0.182 0,182 0,182 0.910 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182

Comments

PAH COMPOUNDS:

Benzene Toluene Ethylbenzene m/p-Xylenes Styrene o-Xylene Isopropylbenzene n-Propylbenzene 1,3,5-Trimettiylbenzene 1,2,4-Trlmethylbenzene t-Butylbenzene sec-Butylbenzene p-lsopropyttoluene rvButyt benzene 01 - Benzene C2 - Benzene 03 - Benzene C4 - Bervzene C5 - Benzene trans-Decalin cIs-Decalln Naphthalene 2-Melhylnaphlhalene 1 -Methylnaphthalene 01 - Naphthalene 02 - Naphtiialene 03- Naphtiialene 04- Naphthalene AcenaphUiylene Acenaphthene Dibenzofuran Fluorene 01 - Fluorene C2 - Fluorene 03 - Fluorene Phenanthrene Anthracene

2.900 1,550

59.6 992 793 291

1.58 2.36

211 329

8.62 6.01

1,050 637 349

78.5 11.4 0.848

32.400 6,310 2,690 5,460 1,300

366 62,9

14,000 1.540 7.210

11.000 818 173 80.5

28.400 10.200

D D

D D

U U

D D

I U D D D D D

DB DB D D D

DB D

8/30/2005 GT030205 M E T A t ^

AR120051


Field ID: Crude Coal Tar

Client Project

U b I D File ID:

Date Sampled: Date Received: Date Prepared: Date Cleanup: Dale Analyzed: Insbument Operator

Batch QC:

Reilly Industries, Ina Fairmont WV

GT030205-02 D0802A08.D

NA 2/5/2003 8/2/2005 NA 8/3/2005 El Camino RS

GT050802-MB

Preparation Mettiod: Cleanup Melhod(s): Analysis Method:




NAPL None None

0.05 100% 2000 1.00 1.00 1.00


0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.385 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365

0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365 0.365

EDL

0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182

" 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182

0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182 0.182

Comments

CI - PhehanUirene/Anlhracene 02 -Phenanlhrene/Aiithracene 03 - Phenanthrene/Anthracene C4 - Phenanthrene/Anthracene Dibenzothiophene 01 - Dibenzothiophene C2 - Dibenzothiophene 03 - Dibenzothiophene C4 - Dibenzothiophene Benzo(b)naphtho(2,1 -d)thiophene FluoranUiene Pyrene 01 - Fluoranthene/Pyrene 02 - FluoranUiene/Pyrene C3 - Fluoranthene/Pyrene Benz[alanthracene Chrysene 01 - Benz(a)anlhracene/Chrysene C2 - Benz(a)anthracene/Chrysene 03 - Benz(a)anthracene/Chrysene 04 - Benz(a)anlhracene/Chrysene Benzo[b]fluoranthene Benzo[k]fluoranthene Benzo(e)pyrene Benzo[a]pyrene Perylene lndeno{1.2,3-cd]pyrene Dibenz[a.h]anlhracene Benzo[g.h.i]perylene Coronene

Retene Benzo(b/c)fluorenes 2-Methylpyrene 4-Methylpyrene 1-Methylpyrene Heptadecane Pristane Octadecane Phytane

3.340 644 204

41.8 2.710

393 145 48.8 14.3

1.400 22,800 16,500

6,410 980 272

8,460 8,140 1.290

305 165

69.4 9,590 2.260 4.330 7,710 2,320 5,040 1,900 4,380 1,160

10.5 1.850

422 262 398

82.2 30.4

232 25.8

D

D

D DB DB D

D D

D D D D D DB D D D

D D D D

8/30/2005 METAj^^Q__

AR120052


Field ID:

Client Project

U b I D File ID:


Batch QC:

Crude Coal Tar

Reilly Indusbies, Inc. Fairmont WV

GT030205-02 D0802A08,D

NA 2/5/2003 8/2/2005 NA 8/3/2005 El Camino RS

GT050802-MB

Preparation Mettiod: Cleanup MeUiod(s): Analysis Method:


Sample Size (g): Percent Solid: Exbact Volume (pi): Prep DF: Analysis DF: Injection Volume (pi):


NAPL None None

0,05 100% 2000 1.00 1.00 1.00

Analyte Concenbation (mg/kg) RL EDL Comments

2,6,10-lrimethyldodecane 2,6,10-trimethylbklecane Norpristane

204 6.51

51.6

0.365 0.365 0.365

0.182 0.162 0.182

Extract/on Surrogate Recoveries (%) Toluene-d8 Phenanthrene-dl 0 Perylene-d12

85 91 105

Limits 50-120 50-120 50-120

NA - Not applicable B - Analyte detected in the Blank J - Estimated value; detected between the RL and DL U - Analyte not detected above OL D - Analyte reported from a diluted extaracL E - Estimate, result detected above calibration range. I - Concentration/Peak ID uncertain due to potential interference. RL - Reporting limit is the sample equivalent of the lowest linear calibration concentration. EDL - Estimated detection limit is 50% of RL DO - Not reported due to excessive dilution

8/30/2005 MPTA IVO

AR120053


Field ID: Middle Coal Tar Distillates

Client Project

UbID File ID:


Batch QC:


GT030205-04 D0802A05.D

NA 2/5/2003 8/2/2005 NA 8/3/2005 El Camino RS

GT050802-MB



Sample Size (g): Percent Solid: Extract Volume (pi); Prep DF: Analysis DF: Injection Volume (pi):


NAPL None None

0.03 100% 2000 1.00 1.00 1.00


3.08 3.08 0,615 0.615 0.615 0.615 0.615 0.615 0.615 0,615 0,615 0.615 0.615 0.615 3.08 0.615 0,615 0.615 0.615 0.615 0,615 0.615 0.615 0.615 0.615 0.615 0.615 0.615 0.615 0.615 0.615 0.615 0.615 0.615 0.615 0.615 0.615

EDL

1.54 1.54 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 1.54

0,308 0,308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308

Comments

PAH COMPOUNDS:

Benzene Toluene Ethylbenzene m/p-Xyienes Styrene o-Xylene Isopropylbenzene n-Propylbenzene 1,3,5-Trimettiylbenzene 1,2,4-Trimelhylbenzene t-Butylbenzene sec-Butylbenzene p-lsopropyitoluene n-Butylbenzene 01 - Benzene C2 - Benzene 03 - Benzene C4 - Benzene 05 - Benzene trans-Decalin cis-Decalin Naphthalene 2-Methylnaphthalene 1 -Methylnaphthalene 01 - Naphtiialene 02 - Naphthalene 03- Naphtiialene 04- Naphtiialene Acenaphthylene Acenaphthene Dibenzofiiran Fluorene CI - Fluorene 02 - Ruorene 03 - Fluorene Phenanthrene Anthracene

23.1 203 229 118

1.12 83.6 11.6 6.26

27.1 40.2

0.729 4.31

11.1 131 183 119 60.3 17.9

27.000 13,500 6.780

12,300 4,700 1,390

277 135

27,600 16,500 24,000 2.380

609 347

37,300 8,970

U U D D D D

B DB D D D

DB D

8/30/2005 META •K)

AR120054

Analytical Results for Volatile and Semivolatile Organics META Environmental, |nc.


Client Project

UbID File ID:


Batch QC:

Reilly Indusbies, Inc. FairrtiontWV

GTO30205-04 D0802A05.D

NA 2/5/2003 8/2/2005 NA 8/3/2005 El Camino RS

GT050802-MB

Preparation Method: Cleanup MeUiod(s): Analysis Method:


Sample Size (g): Percent Solkl: ExtiBCt Volume (pi): Prep DF: Analysis DF: injection Volume (pi):


NAPL None None

0.03 100% 2000 1.00 1.00 1.00

Analyte Concenti^tion (mg/kg) RL

0.615 0.615 0,615 0,815 0,615 0.615 0.615 0.615 0.615 0.615 0.615 0.615 0.615 0.615 0.615 0.615 0.615 0.615 0.615 0.615 0.615 0.615 0.615 0.615 0.615 0.615 0,615 0,615 0,615 0,615

0,615 0,615 0.615 0.615 0.615 0.615 0.615 0.615 0.615

EDL

0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0,308 0,308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0,308 0,308 0,308 0.308 0.308 0.308 0.308

0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308 0.308

Comments

CI - Phenanthrene/Anthracene 02 - Phenanthrene/Arittiracene 03 - Phenanthrene/Anttiracene C4 - Phenanthrene/Anthracene Dibenzothtophene 01 - Dlt>enzothiophene 02 - Dibenzottitophene 03 - Dibenzottitophene C4 - Ditienzottitophene Benzo(b)naphUio(2,1-d)ttiiophene Fluoranthene Pyrene 01 - Ruoranthene/Pyrene C2 - Fluoranttiene/Pyrene 03 - Fluoranttiene/Pyrene Benz[a]anUirac8ne Chrysene 01 - Benz(a)anthracene/Chrysene 02 - Benz(a)anlhracene/Chrysene 03 - Benz(a)anlhracene/Chrysene 04 - Benz(a)anUiracene/Chrysene Benzo[b]fluoranthene Benzo{kjnuoranthene Benzo(e)pyrene Benzoiajpyrene Perylene lndeno[1,2,3-cdjpyrene D it}enz[a,h]a nthracene Benzo(g,h,i]perytene Coronene

Retene Benzo(b/c)nuorenes 2-Melhylpyrene 4-Melhyl pyrene 1-Mettiylpyrene Heptadecane Pristane Octadecane Phytane

5.750 1,170

283 65.0

4,490 681 256

86.5 21.1

678 21,300 14,400 4,610

837 285

3.060 2.940

687 123 55.1 17.4

1.390 905 693

1.030 301 309 113 234 27.3

28.3 1,410

340 218 214 220 92.8 21.1

245

DB DB

8/30/2005 MPTA 4tO

AR120055



Client Project

Lab ID File ID:


Batch QC:


GT030205-04 D0802A05.D

NA 2/5/2003 8/2/2005 NA 8/3/2005 El Camino RS

GT050802-MB

Preparation Mettiod: Cleanup MeUiod(s): Analysis Mettiod:


Sample Size (g): Rercent Solid: Exfa act Volume (pi): Prep DF: Analysis DF: injection Volume (pi):


NAPL None None

0.03 100% 2000 1.00 1.00 1.00

Analyte Concenti^tion (mg/kg) RL EDL Comments

2,6,10-trimeUiyldodecane 2.6,10-bimethyltridecane Norpristane

20.9 9.69

40.9

0.615 0.615 0.615

Umits 50-120 50-120 50-120

0.308 0.308 0.308

Extraction Surrogate Recoveries (%) Toluene-d8 PhenanUirene-dl 0 Perylene-d12

46 50 48

NA - Not applicable B - Analyte detected in ttie Blank J - Estimated value; detected between the RL and DL U - Analyte not detected above DL D - Analyte reported from a diluted extiact E • Estimate, result detected above calibration range. I - Concentration/Peak ID uncertain due to potential interference. RL - Reporting limit is the sample equivalent of the lowest linear calibration concentration. EDL - Estimated detection limit is 50% of RL DO - Not reported due to excessive dilution

8/30/2005 M E T A J f ^

AR120056


Field ID:

Client Project

Lab ID File ID:

Date Sampled: Date Received: Date Prepared: Date Cleanup: Date Analyzed: Insburhent Operator

Batch QC:

Heavy Oil

Reilly Industries, Inc. FaimiontWV

GT030205-05 D0802A06.D

NA 2/5/2003 8/2/2005 HA. 8/3/2005 El Camino RS

GT050802-MB

Preparation Mettiod: Cleanup Method(s): Analysis Mettiod:


Sample Size (g): Percent Solid: Extract Volume (pi): PrepDF: Analysis DF: Injection Volume (pi):


NAPL None None

0.03 100% 2000 1.00 1.00 1.00

Analyte

PAH COMPOUNDS:

Benzene Toluene EUiytt}enzene m/p-Xyfenes Styrene o-Xylene lsopropylt>enzene n-Propylbenzene 1,3,5-Trimethylbenzene 1,2,4-Trimettiylbenzene t-Bulylbenzene sec-Butylt>enzene p-lsopropyttoluene n-Butyt benzene 01 - Benzene C2 - Benzene 03 - Benzene 04 - Benzene C5 - Benzene b^ns-Oecalin cis-Oecalin Naphtiialene 2-Mettiylnaphthalene 1 -Mettiylnaphttialene 01 - Naphttialene 02 - Naphthalene 03- Naphthalene C4- Naphthalene Acenaphthylene Acenaphthene Dibenzofuran Fluorene CI - Fluorene 02 - Fluorene 03 - Fluorene Phenanttirene Anthracene

on (mg/kg)

27.5 271 190 135 0.786

224 5.5

10.4 25.3 48.8

1.1 2.42 9.41

176 243 117 40.3 11.7

3,380 1,730 1,510 1,940 1,180

546 214 87.2

17,700 6,400

14,200 3.930 1,390

789 58,700 8,960

U

U U D D D D

B DB D D D

DB D

RL

3.5 3.5 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 3.5 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699

EDL

1.75 1.75

0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 1.75 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350

Comments

8/30/2005 GT030205 META^kQ

AR120057


Field ID: Heavy Oil

Client Project

Ub ID File ID:

Date Sampled: Date Received: Date Prepared: Date Cleanup: Date Analyzed: Inslrurtient Operator:

Batch QC:


GT030205-05 D0802A06.D

NA 2/5A2003 8/2/2005 NA 8/3/2005 El Camino RS

GT050802-MB

Preparation Method: Cleanup Mettiod(s): Analysis Mettiod:


Sample Size (g): Percent Solid: Extinct Volume (pi): PrepDF: Analysis DF: Injection Volume (pi):


NAPL None None

0.03 100% 2000 1.00 1.00 1.00


0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.899 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699

0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699 0.699

EDL

0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0,350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350

0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350

Comments

CI - Phenanttirene/Anttiracene C2 - Phenanthrene/Anthracene C3 - Phenanthrene/Anthracene C4 - Phenanthrene/Anttiracene Dit>enzottiioptiene 01 - Ditienzottiiophene 02 - Dibenzothtophene 03 - Dibenzottiiophene C4 - Dibenzothiophene Benzo(b)naphttX3(2,1 -d)thtophene Fluoranthene Pyrene 01 - Ruoranthene/Pyrene 02 - Ruoranttiene/Pyrene C3 - Ruoranttiene/Pyrene Benz[a]anthracene Chrysene CI • Benz(a)anthracene/Chrysene C2 - Benz(a)anthracene/Chrysene 03 - Benz(a)anttiracene/Chrysene 04 - Benz(a)anttiracene/Chrysene Benzo[b]fluoranthene Benzoikjfluoranthene Benzo(e)pyrene Benzoiajpyrene Perylene lndeno[1,2,3-cdjpyrene Dibenz[a,h]anthracene Benzofe,h,i]perylene Coronene

Retene Benzo(b/c)fluorenes 2-Methylpyrene 4-Methylpyrene 1-Mettiylpyrene Heptadecane Pristane Octadecane Phytane

12,700 3.180

873 310

6,210 1,400

625 239

78.3 2.270

53.600 41,300 16,200 3,750 1.330

12,000 9,520 2.710

643 302 97.1

8.130 3,060 3,460 4.870 1.440 1.610

597 1.280

151

162 4,260 1,270 1,010 1.000

11.7

D D D

D D

D DB DB D D

D D

D D D D D DB

D D D D

2.21 69.0 6,3

8/30/2005 METAIKD

AR120058


Field ID: Heavy Oil

Client Project

UbIO File ID:


Batch QC:


GT030205-05 D0802A06.D

NA 2/5/2003 8/2/2005 NA 8/3/2005 El Camino RS

GT050802-MB

Preparation Mettiod: Cleanup Mettiod(s): Analysis Mettiod:

Matrix Preservation: Decanted:

Sampte Size (g): Percent Solid: Extract Volume (pi): Prep DF: Analysis DF: Injection Volume (pi):


NAPL None None

0.03 100% 2000 1.00 1.00 1.00

Analyte Ccncenti^tion (mg/kg) RL EDL Comments

2.6.10-trimethyldodecane 2,6.10-trimettiytb'idecane Norpristane

4.74 5.89

40.6

0.699 0.699 0.699

Umits 50-120 50-120 50-120

0.350 0.350 0.350

Extracb'on Surrogate Recoveries (%) Toluene-d8 Phenanttirene-dIO Perylene-d12

68 74 81

NA - Not applk:abla B - Analyte detected in the Blank J - Estimated value; detected between the RL and DL U - Analyte not detected above DL. P - Analyte reported from a diluted extract E - Estimate, result detected atx)ve calibration range. I - ConcenbBtton/Peak ID uncertain due to potential interference. RL - Reporting limit is the sample equivalent of ttie lowest liriiear calibration concentration. EDL - Estimated detection limit is 50% of RL DO - Not reported due to excessive dilution

8/30/2005 META^KO

AR120059

> . • . • • :• .••••• - s ^ A . : . S : . - : V ' ^ v ' ? ; v - ; . . .

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yymm:immm:m:.mm&^smm'i-

:^¥•^^r AR120060

WmiMAOM - W ^ ^ M AfiOfiArOR IE S. f NC.

^T^KSR^S^SfeSBSS

Ray Siegener META Environmental Inc 49 Clarendon St Watertown MA 02472

LABORATORY REPORT

Report Date:

Purchase Order #: Fax#:

08/12/05

6255 617-923-4610

SAMPLE ID LAB ID ANALYSIS AS RECEIVED

KR050629-01 W-9169 Specific Gravity

Ultimate Moisture Cartjon Hydrogen Nitrogen Sulfijr Chlorine Ash Oxygen (by difference)

Proximate Karl Fischer Water Volatile @ 950'C Ash @750°C Fixed Carbon

Specific Gravity

Ultimate Moisture Carbon Hydrogen Nitrogen Sulfur Chlorine Ash Oxygen (by difference)

Proximate Kari Fischer Water Volatile @ QSCC Ash @750°C Fixed Carbon

1.40 1.33

43.49 26.04 6.49 <0.5 1.26 0.0061 31.16 35.04

43.48 7.83 31.16 17.53

1.43

25.12 26.46 5.33 <0,5 3,86 0,0037 22.49 41.86

25,12 27.73 22.49 24.66

*

% % % % % % % %

% % % %

% % % % % % % %

% % % %

KR050629-03 W-9170

This report shall not be reproduced, except in full, wittiout ttie written approval of ttie laboratory. Page 1 of 5

M:>;i;r.fl-Pn Rnv t i l f i i n I Ifnnxville.TN 37950-1610 Shipping: 2323 Sycamore Dr. | Knoxville. TN 37921-17C

AR120061

WWWi wrZy^t A e 0 R A r o fi I c $.*» N c.

LABORATORY REPORT

Ray Siegener META Environmental Inc

Report Date: Lab ID #:

08/12705 W-9169-75


KR050629-05 W-9171 Specific Gravity

Ultimate Moisture Carbon Hydrogen Nitrogen Sulfur Chlorine Ash Oxygen (by difference)

Proximate Kari Fischer Water Volatile @ 950''C Ash @750''C Fixed Carbon

Specific Gravity

Ultimate Moisture Carbon Hydrogen Nitrogen Sulfur Chlorine /ksh Oxygen (by difference)

Proximate Kari Fischer Water Volatile @ 950X Ash @750°C Fixed Carbon

1.37

36.83 28.94 5,28 0.53 1.67 0.0089 20.49 43.08

36.83 23.98 20.49 18.70

1.33

<0.06 93.15 4.40 1,03 0.52 <0.002 0.61 0.29

<0.06 52.47 0.61 46.92

% % % % % % % %

% % % %

-% % % % % % % %

% % % %

GT030205-01 W-9172

This report shall not tje reproduced, except In full, wittiout ttie written approval of the laboratory. Page 2 of 5

Mailine: P.O. Box 516101 Knoxville,TN 37950-1610 Shipping: 2323 Sycamore Dr. j Knoxville.TN 37921-171

AR120062

^K:?djSk!i=:^<m^7ÛL A B O R A T O R l £ S. I NC.

LABORATORY REPORT



08/12/05 W-9169-75


GT030205-02 W-9173

GT030205-04 W-9174

Specific Gravity

Ultimate Moisture Cartjon Hydrogen Nitrogen Sulfur Chlorine Ash Oxygen (by difference)

Proximate Kari Fischer Water Volatile @950''C Ash @750°C Fixed Carbon

Specific Gravity

Ultimate Moisture CariDon Hydrogen Nitrogen Sulftjr Chlorine Ash Oxygen (by difference)

Proximate Kari Fischer Water Volatile @ 950°C Ash (g750X Fixed Carbon

11.19 55.01 7.46 0.70 0.60 0.0190 0,44 35.77

11.19 69.16 0.44 19.21

1.10

0.27 91.69 6.20 0.64 0.62 0.0024 0.31 0.54

0.27 98,29 0,31 1.13

70

% % % % %

% %

This report shall not be reproduced, except in full, without ttie written approval of ttie laboratory. Page 3 of 5

Mail ing: P.O. Box 51610 | Knoxvil le,TN 37950-1610 Shipping: 2323 Sycamore Dr. | Knoxville, T N 37921-17

AR120063

i^miffmfii

• W ^ -rii'LA B O R A T O R I B S . I N t

LABORATORY REPORT



08/12/05 W-9169-75


GT030205-05 W-9175 Specific Gravity

Ultimate Moisture Cariaon Hydrogen Nitrogen Sulfur Chlorine Ash Oxygen (by difference)

Proximate Kari Fischer Water Volatile @ 950°C Ash @750°C Fixed Cartson

1.15

1.24 90.27 5.88 0.80 0.59 0.0090 0.37 2.08

1.24 97.74 0,37 0.65

% % % % % % % %

% % % %

This ref>ort shall not be reproduced, except in full, without the written approval of ttie laboratory. Page 4 of 5

Mailing: P.O. Box 516101,Knoxville,TN 37950-1610 Shipping: 2323 Sycamore Dr. | Knoxville, TN 37921-170(

AR120064

WiiMsitAmi: ,W^1MABORATORICS.^ - INC.

LABORATORY REPORT



08/12/05 W-9169-75

QUALITY ASSURANCE INFORMATION:

* Duplicate analyses were performed as part of our internal Quality Control Program. There is no additional charge for duplicate values.

** We regret that there was insufficient sample for specific gravity determination.

Authorized Release of Data

WML:yb This report shall not be reproduced, except in full, wittiout the written approval of ttie laboratory. Page 5 of 5

Mailing: P.O. Box 51610 | Knoxville, TN 37950-1610 Shipping: 2323 Sycamore Dr. | Knoxvilie.TN 37921-17C

AR120065

:HAIN OF CUSTODY RECORD 'ROJECTNAME f^ i^ônf- ^ H / \ / :OMPANY vDDRESS '^"^NE

.JL

fiÛ^î 2003 \N^M-1S

FAX META JkR Environmental. Inc.

49 Clarendon Street Watertown, MA 02472 TEL: (617) 923.4662 FAX: (617) 923-4610 WWW.METAENV.COM

A M P L E D B Y '\ AiAw, i k ^ ^ A n e t (Signitm)

ENGINEERING & CHEMISTRY

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:•-. ^ ' CONTAfNER ^

AMi>LE lu u, £ 2 SAMPLE ID - „, ^ ^Z SAMPLE NO,. 5 s ^ 3 . . (SAMPLELOCATION) ^ a 2 i d l MATRIX PRESERVATIVE

k'/2^ro67.^-ol I - £ > 3

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AR120066

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AR120067

Results of Petrographic Analysis of Black Semisolid Material

KROl KR03 KR04 KR05 KR06

coal high vol

3.0 t

3.0 24.0

med vol anthracite coke fine

10.0 7.5 6.0 16.0 12.0

coarse/ ribbon

2.5 2.0 2.5 3.5 3.5

inertinite

1.5 0.5 0.5 2.5 1.0

minerals tar/pitch "pitch"

groundmass 70.0 82.0 88.5 66.0 52.0

fine inclusions

1.0

0.5

wood

I.O 0.5 2.5 3.5

minerals slag glass

1.5 3.5

0.5 0,5

spinel mullite

t

sediments clay

1.0

quartz/other minerals

10.5 2.5 1.5 6.0 3.5

GTOl 100.0

Lab ID KROl KR03 KR04 KR05 KR06

GTOI

Field ID Sample 1 Sample 3 Sample 4 Sample 5 Sample 6

coal tar pitch

Center for Applied Energy Research University of Kentucky Page 1 of 1 August 22,2005

AR120068

CHAIN OF CUSTODY RECORD PROJECT NAME K O G ^ \ ' ( : ' 0

COMPANY VJiwJ. .A ADDRESS PHONE _ EMAIL SAMPLED BY

FAX t-fi'/K^^ •wn <£ .fj,-\rÔ

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Documents

SDMS DocID Laboratory Report - semspub.epa.gov · SDMS DocID 2108013 %. '^L Laboratory ... and Ultimate and Proximate Analysis ... The second set of samples consisted of crude coal